CN108611200A - Environment-protective toilet cleanser and preparation method thereof - Google Patents
Environment-protective toilet cleanser and preparation method thereof Download PDFInfo
- Publication number
- CN108611200A CN108611200A CN201810616682.7A CN201810616682A CN108611200A CN 108611200 A CN108611200 A CN 108611200A CN 201810616682 A CN201810616682 A CN 201810616682A CN 108611200 A CN108611200 A CN 108611200A
- Authority
- CN
- China
- Prior art keywords
- mass parts
- environment
- toilet
- protective
- alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 134
- 235000019441 ethanol Nutrition 0.000 claims abstract description 87
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000002253 acid Substances 0.000 claims abstract description 35
- 239000003599 detergent Substances 0.000 claims abstract description 26
- -1 alkyl glycosides Chemical class 0.000 claims abstract description 25
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 24
- 229930182470 glycoside Natural products 0.000 claims abstract description 22
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims description 84
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 32
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 28
- 238000003756 stirring Methods 0.000 claims description 28
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 26
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims description 26
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 16
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 16
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 14
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 14
- 239000004327 boric acid Substances 0.000 claims description 14
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 14
- 239000001103 potassium chloride Substances 0.000 claims description 14
- 235000011164 potassium chloride Nutrition 0.000 claims description 14
- 239000001509 sodium citrate Substances 0.000 claims description 14
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 14
- 239000003205 fragrance Substances 0.000 claims description 12
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 12
- 239000004299 sodium benzoate Substances 0.000 claims description 12
- 235000010234 sodium benzoate Nutrition 0.000 claims description 12
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 11
- 239000000194 fatty acid Substances 0.000 claims description 11
- 229930195729 fatty acid Natural products 0.000 claims description 11
- 150000004665 fatty acids Chemical class 0.000 claims description 11
- KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 8
- 241000628997 Flos Species 0.000 claims description 7
- 244000178870 Lavandula angustifolia Species 0.000 claims description 7
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 7
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 7
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- 239000001102 lavandula vera Substances 0.000 claims description 7
- 235000018219 lavender Nutrition 0.000 claims description 7
- 229920001289 polyvinyl ether Polymers 0.000 claims description 7
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 7
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 7
- 235000017550 sodium carbonate Nutrition 0.000 claims description 7
- 229960004418 trolamine Drugs 0.000 claims description 7
- 235000009467 Carica papaya Nutrition 0.000 claims description 6
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 claims description 5
- 229940057402 undecyl alcohol Drugs 0.000 claims description 5
- 240000006432 Carica papaya Species 0.000 claims description 4
- 150000001336 alkenes Chemical group 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 11
- 230000000694 effects Effects 0.000 abstract description 7
- 230000001681 protective effect Effects 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 description 13
- 230000007797 corrosion Effects 0.000 description 13
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 229910052573 porcelain Inorganic materials 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 239000002105 nanoparticle Substances 0.000 description 6
- 239000000725 suspension Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- 229960003237 betaine Drugs 0.000 description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 4
- 235000017557 sodium bicarbonate Nutrition 0.000 description 4
- 210000002700 urine Anatomy 0.000 description 4
- 235000006264 Asimina triloba Nutrition 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 239000005711 Benzoic acid Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
- 241000219173 Carica Species 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 229910052588 hydroxylapatite Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 2
- 230000010355 oscillation Effects 0.000 description 2
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- KCXFHTAICRTXLI-UHFFFAOYSA-N propane-1-sulfonic acid Chemical compound CCCS(O)(=O)=O KCXFHTAICRTXLI-UHFFFAOYSA-N 0.000 description 2
- 235000013599 spices Nutrition 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- OBMBUODDCOAJQP-UHFFFAOYSA-N 2-chloro-4-phenylquinoline Chemical group C=12C=CC=CC2=NC(Cl)=CC=1C1=CC=CC=C1 OBMBUODDCOAJQP-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 101710171243 Peroxidase 10 Proteins 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229910052586 apatite Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000004113 cell culture Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000012531 culture fluid Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002338 glycosides Chemical class 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000005543 nano-size silicon particle Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000013616 tea Nutrition 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
- C11D1/652—Mixtures of anionic compounds with carboxylic amides or alkylol amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
A kind of environment-protective toilet cleanser is provided, the detergent for toilet include the three ethyl alcohol hydramine of aliphatic acid of 58 mass parts, 24 mass parts isomery alcohol polyethenoxy ether and 48 mass parts alkyl glycosides.Environment-protective toilet cleanser of the present invention has the advantages that cleaning toilet effect is good, reliable and stable and environmentally protective.
Description
Technical field
The present invention relates generally to cleaning fields, and particularly, are related to environment-protective toilet cleanser and preparation method thereof.
Background technology
With the development and the improvement of people's living standards of society, people also put forward higher requirements quality of life, especially
It is to require higher to living environment.Environment-protective toilet cleanser is the cleaning essential magic weapon of lavatory in daily life, currently, market
Environment-protective toilet cleanser be broadly divided into three categories：Acidic products, neutral products and basic products, wherein with the cleaning of acidic products
Best results.Currently, the composition of acid detergent for toilet is by chemical analysis such as acid, surfactant and corrosion inhibiter, but it is more in these acid
Using hydrochloric acid and phosphoric acid, although with compared with strong corrosive, antibacterial and bactericidal effect is limited, and Long Term Contact or sucking meeting pair
Health impacts.
Therefore, it is good how to research and develop a kind of cleaning effect, pollution is small, and there is no the environment-protective toilet cleansers of harm to human body
It is the problem of those skilled in the art's urgent need to resolve.
Invention content
The present invention provides a kind of environment-protective toilet cleanser, wherein the detergent for toilet includes the three ethyl alcohol alcohol of aliphatic acid of 5-8 mass parts
Amine, 2-4 mass parts isomery alcohol polyethenoxy ether and 4-8 mass parts alkyl glycosides.
In some embodiments, in the environment-protective toilet cleanser, the isomeric alcohol polyethenoxy ether is poly- for ten alcohol of isomery
The mixture of one or more compositions of ethylene oxide ether, isomery undecyl alcohol polyoxyethylene ether and isomerous tridecanol polyoxyethylene ether.
In some embodiments, in the environment-protective toilet cleanser, which includes the fatty triethylenetetraminehexaacetic acid of 6-7 mass parts
Alcohol hydramine, 3-4 mass parts isomery alcohol polyethenoxy ether and 6-7 mass parts alkyl glycosides.
In some embodiments, in the environment-protective toilet cleanser, which further includes the benzoic acid of 2-4 mass parts
The mixture of sodium, the sodium citrate of 3-6 mass parts, the potassium chloride of 0.1-2 mass parts and 3-5 mass parts being made of acid；
The wherein described mixture includes boric acid and hydrochloric acid, and the mass ratio of the boric acid and the hydrochloric acid is 3-5/1.
In some embodiments, in the environment-protective toilet cleanser, which further includes the bicarbonate of 2-3 mass parts
The hydrogen peroxide of sodium, the potassium carbonate of 0.5-3 mass parts and 0.2-1.8 mass parts.
In some embodiments, in the environment-protective toilet cleanser, which further includes butanediol and ethyl alcohol, the fourth
The sum of mass fraction of glycol and the ethyl alcohol is 1-2.
In some embodiments, in the environment-protective toilet cleanser, the mass ratio of the butanediol and the ethyl alcohol is
1-3/1。
In some embodiments, in the environment-protective toilet cleanser, which further includes the perfume (or spice) of 0.5-2.5 mass parts
Material.
In some embodiments, in the environment-protective toilet cleanser, the fragrance is Flos Rosae Rugosae extract, papaya extractives
With the mixture of one or more compositions in Herba Lysimachiae foenumgraeci extract.
Another aspect of the present invention provides a kind of preparation method of environment-protective toilet cleanser, wherein the preparation method includes following step
Suddenly：
Step 1: potassium chloride, sodium bicarbonate, sodium carbonate, mixture, sodium citrate, sodium benzoate and deionized water are mixed
It closes, stirs evenly and be heated to 50 DEG C -70 DEG C, and keep 1-3h at 60 DEG C, obtain the first intermediate blend；
Step 2: fatty acid triethanol amine, isomery alcohol polyvinylether and alkyl glycosides to be mixed evenly and be heated to
40 DEG C -50 DEG C, and 1-2h is kept, and obtain the second intermediate blend；
Step 3: being added second intermediate blend to first intermediate blend, stir while adding, stirs
Time is 20-4min, is stood to room temperature；10 DEG C are heated on the basis of room temperature, are kept 20-50min, room temperature are reduced to, in room temperature
On the basis of heat 5 DEG C -10 DEG C, keep 20-30min, be reduced to room temperature, despumation obtains third intermediate blend；
Step 4: hydrogen peroxide, lavender extracting solution, butanediol and ethyl alcohol are sequentially added the third intermediate blend
In stir evenly, obtain detergent for toilet.
Specific implementation mode
The existing various exemplary embodiment that the present invention will be described in detail, the detailed description are not considered as the limit to the present invention
System, and it is understood as the more detailed description to certain aspects of the invention, characteristic and embodiment.
It should be understood that heretofore described term is only to describe special embodiment, being not intended to limit this hair
It is bright.In addition, for the numberical range in the present invention, it is thus understood that it is also specifically disclosed that every between the upper and lower bound of the range
A median.Median and any other statement value in any statement value or stated ranges or in the range in
Between each of between value smaller range be also included in the present invention.These small range of upper and lower bounds can include independently
Or it excludes in range.
Unless otherwise stated, all technical and scientific terms used herein has the routine in field of the present invention
The normally understood identical meanings of technical staff.Although the present invention only describes preferred method and material, the present invention's
Implement or can also be used and similar or equivalent any method and material described herein in testing.The institute mentioned in this specification
There is document to be incorporated by reference into, to disclosure and description and the relevant method of the document and/or material.It is incorporated to any
When document conflicts, it is subject to the content of this specification.
Without departing substantially from the scope or spirit of the invention, the specific implementation mode of description of the invention can be done more
Kind is improved and variation, this will be apparent to those skilled in the art.Other realities obtained by the specification of the present invention
It is apparent obtain to apply mode for technical personnel.Present specification and embodiment are merely exemplary.
It is the term of opening, i.e., about "comprising" used herein, " comprising ", " having ", " containing " etc.
Mean including but not limited to.
Heretofore described " mass parts " or " % " unless otherwise instructed, by mass.
The present invention provides a kind of environment-protective toilet cleanser, wherein the detergent for toilet includes the three ethyl alcohol alcohol of aliphatic acid of 5-8 mass parts
Amine, 2-4 mass parts isomery alcohol polyethenoxy ether and 4-8 mass parts alkyl glycosides.
Wherein, aliphatic acid is C in three ethyl alcohol hydramine of the aliphatic acid16-C20Long chain fatty acids, it is preferable that aliphatic acid three
Aliphatic acid is C in ethyl alcohol hydramine18-C20Long chain fatty acids, for example, in three ethyl alcohol hydramine of aliphatic acid aliphatic acid be C18Long-chain
Aliphatic acid is C in aliphatic acid, three ethyl alcohol hydramine of aliphatic acid19Long chain fatty acids alternatively, aliphatic acid in three ethyl alcohol hydramine of aliphatic acid
For C20Long chain fatty acids.
There is isomery alcohol polyethenoxy ether good wettability, emulsibility and detergency, the present invention to be added in detergent for toilet
Three ethyl alcohol hydramine of aliphatic acid, isomery alcohol polyethenoxy ether and the alkyl glycosides of specific component, make three ethyl alcohol hydramine of aliphatic acid, isomery
Alcohol polyethenoxy ether and alkyl glycosides cooperate, and promote removal urine stain, the ability of dirt of detergent for toilet.
In some embodiments, in the environment-protective toilet cleanser, the isomeric alcohol polyethenoxy ether is poly- for ten alcohol of isomery
The mixture of one or more compositions of ethylene oxide ether, isomery undecyl alcohol polyoxyethylene ether and isomerous tridecanol polyoxyethylene ether.
In some embodiments, in the environment-protective toilet cleanser, which includes the fatty triethylenetetraminehexaacetic acid of 6-7 mass parts
Alcohol hydramine, 3-4 mass parts isomery alcohol polyethenoxy ether and 6-7 mass parts alkyl glycosides.For example, the detergent for toilet includes 6 matter
The alkyl glycosides for measuring the three ethyl alcohol hydramine of aliphatic acid of part, the isomery alcohol polyethenoxy ether and 6 mass parts of 3 mass parts, alternatively, this is clean
Lavatory agent includes the alkyl sugar of the three ethyl alcohol hydramine of aliphatic acid of 7 mass parts, the isomery alcohol polyethenoxy ether of 4 mass parts and 7 mass parts
Glycosides
In some embodiments, in the environment-protective toilet cleanser, which further includes the benzoic acid of 2-4 mass parts
The mixture of sodium, the sodium citrate of 3-6 mass parts, the potassium chloride of 0.1-2 mass parts and 3-5 mass parts being made of acid；
The wherein described mixture includes boric acid and hydrochloric acid, and the mass ratio of the boric acid and the hydrochloric acid is 3-5/1.
In some embodiments, in the environment-protective toilet cleanser, which further includes the bicarbonate of 2-3 mass parts
The hydrogen peroxide of sodium, the potassium carbonate of 0.5-3 mass parts and 0.2-1.8 mass parts.
In some embodiments, in the environment-protective toilet cleanser, which further includes butanediol and ethyl alcohol, the fourth
The sum of mass fraction of glycol and the ethyl alcohol is 1-2.
In some embodiments, in the environment-protective toilet cleanser, the mass ratio of the butanediol and the ethyl alcohol is
1-3/1.For example, the mass ratio of the butanediol and the ethyl alcohol is 1/1,2/1 or 3/1.
In some embodiments, in the environment-protective toilet cleanser, which further includes the perfume (or spice) of 0.5-2.5 mass parts
Material.The fragrance is the mixture of one or more compositions in Flos Rosae Rugosae extract, papaya extractives and Herba Lysimachiae foenumgraeci extract.
Further include nano particle suspension, the nanometer in certain embodiments, in the environment-protective toilet cleanser, in the detergent for toilet
Particle suspension includes nano-titanium dioxide, nano silicon dioxide and Tween-80.
The preparation method of nano particle suspension：Titanium dioxide white nano particle, the silica of different-grain diameter are weighed respectively
Nano particle 100mg is dissolved in PBS, and is settled to 100mL respectively, after being tentatively suspended with magnetic stirrer, sonic oscillation 2h,
1mg/mL nano particle deposits contamination suspension, high pressure sterilization is made.Using using cell after the preceding 5min by Stock suspensions sonic oscillation
Culture solution and plus the cell culture fluids of 0.5 ‰ Tween-80s be diluted to 25 μ g/mL concentration.
Nano particle suspension has high surface, surface group and adsorptivity, quickly removes the dirt of lavatory inner wall.
In some embodiments, in the environment-protective toilet cleanser, which further includes the 4- ethylene of 20-30 mass parts
Acryloyl-oxyethyl -2- dimethyl propyl sulfonic acid the sweet teas of yl pyridines propane sulfonic acid glycine betaine (4-VPPS) and 20-30 mass parts
Dish alkali (DMAPS).
4-vinylpridine propane sulfonic acid glycine betaine and acryloyl-oxyethyl -2- dimethyl propyl sulphonic acid betaines are all
There is effective powerful soil release performance, excellent compatibility and good environment to mix by green surfactant, 4-VPPS and DMAPS
Property, and show good emulsibility, washing performance, solubilising, wetability, dissolubility and stability.
In some embodiments, in the environment-protective toilet cleanser, the detergent also 5-10 mass parts include poly- (4- second
Alkenyl pyridine methylene carboxylic acid glycine betaine) (P4VPMC).
Poly- (4-vinylpridine methylene carboxylic acid glycine betaine) can effectively remove the egg in the urine alkali adsorbed on closestool inner wall
White and macromolecular substances, increase the cleaning capacity of detergent for toilet.
In some embodiments, in the environment-protective toilet cleanser, which further includes the nanometer hydroxyl of 10-15 mass parts
Base apatite.
Nanometer hydroxyapatite has the micropore that special crystal structure and natural pore passage structure are formed, and has good
Adsorption, ion exchangeable and thermal stability, nitrogenous compound and hard water in nanometer hydroxyapatite adsorbing urine alkali
In metal contamination.
Another aspect of the present invention provides a kind of preparation method of environment-protective toilet cleanser, wherein the preparation method includes following step
Suddenly：
Step 1: deionized water is added in potassium chloride, sodium bicarbonate, sodium carbonate, mixture sodium citrate and sodium benzoate
In stir evenly and be heated to 50 DEG C -70 DEG C, and keep 1-3h at 60 DEG C, obtain the first intermediate blend；
Step 2: fatty acid triethanol amine, isomery alcohol polyvinylether and alkyl glycosides to be mixed evenly and be heated to
40 DEG C -50 DEG C, and 1-2h is kept, and obtain the second intermediate blend；
Step 3: being added second intermediate blend to first intermediate blend, stir while adding, stirs
Time is 20-4min, is stood to room temperature；10 DEG C are heated on the basis of room temperature, are kept 20-50min, room temperature are reduced to, in room temperature
On the basis of heat 5 DEG C -10 DEG C, keep 20-30min, be reduced to room temperature, despumation obtains third intermediate blend；
Step 4: hydrogen peroxide, lavender extracting solution, butanediol and ethyl alcohol are sequentially added the third intermediate blend
In stir evenly, obtain detergent for toilet.
Embodiment
Embodiment 1
A kind of environment-protective toilet cleanser, wherein the detergent for toilet include the three ethyl alcohol hydramine of aliphatic acid of 5 mass parts, 2 mass parts it is different
Structure alcohol polyethenoxy ether, the alkyl glycosides of 4 mass parts, the sodium benzoate of 2 mass parts, the sodium citrate of 3 mass parts, 0.1 mass
The potassium chloride of part and the mixture of 3 mass parts being made of acid；
The wherein described mixture includes boric acid and hydrochloric acid, and the mass ratio of the boric acid and the hydrochloric acid is 3/1, described different
Structure alcohol polyoxyethylene ether is heterogeneous ten alcohol polyoxyethylene ether.
In said program, which further includes the sodium bicarbonate of 2 mass parts, the potassium carbonate of 0.5 mass parts and 0.2 mass
The hydrogen peroxidase 10 .2 of part.
In said program, which further includes butanediol and ethyl alcohol, the mass fraction of the butanediol and the ethyl alcohol
The sum of be 1；The mass ratio of the butanediol and the ethyl alcohol is 1/1.
In said program, which further includes the fragrance of 0.5 mass parts, and the fragrance is Flos Rosae Rugosae extract, pawpaw
The mixture of one or more compositions in extract and Herba Lysimachiae foenumgraeci extract.
Preparation method：
Step 1: deionized water is added in potassium chloride, sodium bicarbonate, sodium carbonate, mixture sodium citrate and sodium benzoate
In stir evenly and be heated to 50 DEG C -70 DEG C, and keep 1-3h at 60 DEG C, obtain the first intermediate blend；
Step 2: fatty acid triethanol amine, isomery alcohol polyvinylether and alkyl glycosides to be mixed evenly and be heated to
40 DEG C -50 DEG C, and 1-2h is kept, and obtain the second intermediate blend；
Step 3: being added second intermediate blend to first intermediate blend, stir while adding, stirs
Time is 20-4min, is stood to room temperature；10 DEG C are heated on the basis of room temperature, are kept 20-50min, room temperature are reduced to, in room temperature
On the basis of heat 5 DEG C -10 DEG C, keep 20-30min, be reduced to room temperature, despumation obtains third intermediate blend；
Step 4: hydrogen peroxide, lavender extracting solution, butanediol and ethyl alcohol are sequentially added the third intermediate blend
In stir evenly, obtain detergent for toilet.
Embodiment 2
A kind of environment-protective toilet cleanser, wherein the detergent for toilet include the three ethyl alcohol hydramine of aliphatic acid of 8 mass parts, 4 mass parts it is different
Structure alcohol polyethenoxy ether, the alkyl glycosides of 8 mass parts, the sodium benzoate of 4 mass parts, the sodium citrate of 6 mass parts, 2 mass parts
Potassium chloride and 5 mass parts by the mixture that forms of acid；
The wherein described mixture includes boric acid and hydrochloric acid, and the mass ratio of the boric acid and the hydrochloric acid is 5/1, described different
Structure alcohol polyoxyethylene ether is heterogeneous ten alcohol polyoxyethylene ether, isomery undecyl alcohol polyoxyethylene ether and isomerous tridecanol polyoxyethylene ether
One or more compositions mixture..
In said program, which further includes the sodium bicarbonate of 3 mass parts, the potassium carbonate of 3 mass parts and 1.8 mass parts
Hydrogen peroxide.
In said program, which further includes butanediol and ethyl alcohol, the mass fraction of the butanediol and the ethyl alcohol
The sum of be 2；The mass ratio of the butanediol and the ethyl alcohol is 3/1.
In said program, which further includes the fragrance of 2.5 mass parts, and the fragrance is Flos Rosae Rugosae extract, pawpaw
The mixture of one or more compositions in extract and Herba Lysimachiae foenumgraeci extract.
Preparation method：
Step 1: deionized water is added in potassium chloride, sodium bicarbonate, sodium carbonate, mixture sodium citrate and sodium benzoate
In stir evenly and be heated to 50 DEG C -70 DEG C, and keep 1-3h at 60 DEG C, obtain the first intermediate blend；
Step 2: fatty acid triethanol amine, isomery alcohol polyvinylether and alkyl glycosides to be mixed evenly and be heated to
40 DEG C -50 DEG C, and 1-2h is kept, and obtain the second intermediate blend；
Step 3: being added second intermediate blend to first intermediate blend, stir while adding, stirs
Time is 20-4min, is stood to room temperature；10 DEG C are heated on the basis of room temperature, are kept 20-50min, room temperature are reduced to, in room temperature
On the basis of heat 5 DEG C -10 DEG C, keep 20-30min, be reduced to room temperature, despumation obtains third intermediate blend；
Step 4: hydrogen peroxide, lavender extracting solution, butanediol and ethyl alcohol are sequentially added the third intermediate blend
In stir evenly, obtain detergent for toilet.
Embodiment 3
A kind of environment-protective toilet cleanser, wherein the detergent for toilet include the three ethyl alcohol hydramine of aliphatic acid of 6 mass parts, 3 mass parts it is different
Structure alcohol polyethenoxy ether, the alkyl glycosides of 5 mass parts, the sodium benzoate of 3 mass parts, the sodium citrate of 4 mass parts, 1.5 mass
The potassium chloride of part and the mixture of 4 mass parts being made of acid；
The wherein described mixture includes boric acid and hydrochloric acid, and the mass ratio of the boric acid and the hydrochloric acid is 4/1, described different
Structure alcohol polyoxyethylene ether is isomery undecyl alcohol polyoxyethylene ether.
In said program, which further includes the sodium bicarbonate of 2.5 mass parts, the potassium carbonate of 1.5 mass parts and 0.9 matter
Measure the hydrogen peroxide of part.
In said program, which further includes butanediol and ethyl alcohol, the mass fraction of the butanediol and the ethyl alcohol
The sum of be 1.6；The mass ratio of the butanediol and the ethyl alcohol is 2/1.
In said program, which further includes the fragrance of 1 mass parts, and the fragrance is Flos Rosae Rugosae extract.
Preparation method：
Step 1: deionized water is added in potassium chloride, sodium bicarbonate, sodium carbonate, mixture sodium citrate and sodium benzoate
In stir evenly and be heated to 50 DEG C -70 DEG C, and keep 1-3h at 60 DEG C, obtain the first intermediate blend；
Step 2: fatty acid triethanol amine, isomery alcohol polyvinylether and alkyl glycosides to be mixed evenly and be heated to
40 DEG C -50 DEG C, and 1-2h is kept, and obtain the second intermediate blend；
Step 3: being added second intermediate blend to first intermediate blend, stir while adding, stirs
Time is 20-4min, is stood to room temperature；10 DEG C are heated on the basis of room temperature, are kept 20-50min, room temperature are reduced to, in room temperature
On the basis of heat 5 DEG C -10 DEG C, keep 20-30min, be reduced to room temperature, despumation obtains third intermediate blend；
Step 4: hydrogen peroxide, lavender extracting solution, butanediol and ethyl alcohol are sequentially added the third intermediate blend
In stir evenly, obtain detergent for toilet.
Embodiment 4
A kind of environment-protective toilet cleanser, wherein the detergent for toilet include the three ethyl alcohol hydramine of aliphatic acid of 7 mass parts, 3 mass parts it is different
Structure alcohol polyethenoxy ether, the alkyl glycosides of 6 mass parts, the sodium benzoate of 3 mass parts, the sodium citrate of 5 mass parts, 1.8 mass
The potassium chloride of part and the mixture of 4 mass parts being made of acid；
The wherein described mixture includes boric acid and hydrochloric acid, and the mass ratio of the boric acid and the hydrochloric acid is 4/1, described different
Structure alcohol polyoxyethylene ether is isomerous tridecanol polyoxyethylene ether.
In said program, which further includes the sodium bicarbonate of 2.6 mass parts, the potassium carbonate of 2.6 mass parts and 1.3 matter
Measure the hydrogen peroxide of part.
In said program, which further includes butanediol and ethyl alcohol, the mass fraction of the butanediol and the ethyl alcohol
The sum of be 1.3；The mass ratio of the butanediol and the ethyl alcohol is 2.5/1.
In said program, which further includes the fragrance of 2.2 mass parts, and the fragrance is Flos Rosae Rugosae extract, pawpaw
The mixture of one or more compositions in extract and Herba Lysimachiae foenumgraeci extract.
Preparation method：
Step 1: deionized water is added in potassium chloride, sodium bicarbonate, sodium carbonate, mixture sodium citrate and sodium benzoate
In stir evenly and be heated to 50 DEG C -70 DEG C, and keep 1-3h at 60 DEG C, obtain the first intermediate blend；
Step 2: fatty acid triethanol amine, isomery alcohol polyvinylether and alkyl glycosides to be mixed evenly and be heated to
40 DEG C -50 DEG C, and 1-2h is kept, and obtain the second intermediate blend；
Step 3: being added second intermediate blend to first intermediate blend, stir while adding, stirs
Time is 20-4min, is stood to room temperature；10 DEG C are heated on the basis of room temperature, are kept 20-50min, room temperature are reduced to, in room temperature
On the basis of heat 5 DEG C -10 DEG C, keep 20-30min, be reduced to room temperature, despumation obtains third intermediate blend；
Step 4: hydrogen peroxide, lavender extracting solution, butanediol and ethyl alcohol are sequentially added the third intermediate blend
In stir evenly, obtain detergent for toilet.
Comparative example 1
A kind of environment-protective toilet cleanser comprising the light-coloured vinegar of 5 mass parts, the hydrochloric acid of 5 mass parts, the oxalic acid of 65 mass parts, 5 mass
The essence of the hypochlorous acid and 3 mass parts of part..
Cleaning effect is tested：
1. environment-protective toilet cleanser corrosion resistance measurement is tested
1.1 test method：According to GB/T 21241-2007《Sanitary ware cleaning agent》It tests the embodiment of the present invention 1, implement
The corrosivity to ceramic tile and cast iron of environment-protective toilet cleanser prepared by environment-protective toilet cleanser and comparative example three prepared by example 2 and embodiment 3.
According to GB/T 21241-2007《Sanitary ware cleaning agent》Regulation, urinal and closestool tailored version environment-protective toilet cleanser corrode ceramic tile
Property want qualified, Z30Iron corrosion Ji other≤1 grade, rank is higher, and corrosivity is stronger.
1.2 testing results are shown：6 sections of environment-protective toilet cleansers are determined as qualification to the corrosivity of ceramic tile, but to metal
Corrosivity has differences, and the results are shown in Table 1：
1 environment-protective toilet cleanser corrosion resistance measurement test data of table
| Index | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Comparative example 1 |
| Ceramic tile | It is qualified | It is qualified | It is qualified | It is qualified | It is qualified |
| Z30Iron corrosion rank | 0 grade of corrosion | 0 grade of corrosion | 0 grade of corrosion | 0 grade of corrosion | 1 grade of corrosion |
By table 1 it is found that the environment-protective toilet cleanser of 1-5 preparations of the embodiment of the present invention is qualified to the corrosivity of ceramic tile, to Z30
Iron corrosion rank is 0 grade, and comparative example a pair of Z30Iron corrosion rank is 1 grade, to Z30There are larger corrosion for cast iron
Property, it was demonstrated that environment-protective toilet cleanser prepared by the present invention has the advantages that corrosivity is low, is conducive to the popularization of the environment-protective toilet cleanser and answers
With.
2. environment-protective toilet cleanser cleaning effect measures experiment
2.1 test method：Using 6 porcelain facings of artificial urine process, keep 6 porcelain facing covering last layers yellow
The spot of color, spot dry 48h at room temperature；Environment-protective toilet cleanser difference prepared by embodiment 1 to 5 and comparative example 1
Be sprayed onto 6 pieces indicates the porcelain facing of sample 1, sample 2, sample 3, sample 4, sample 5 and sample 6 respectively simultaneously, while being rushed with clear water
It washes, observes the cleaning situation of 6 pieces of porcelain facings；Simultaneously using the porcelain facing whiteness after portable whiteness instrument test processes.
2.2 test results are as shown in table 2
| Index | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Comparative example 1 |
| Whiteness | 90 | 92 | 91 | 92 | 75 |
By above-mentioned table 2 it is found that the whiteness effect of the cleaning porcelain facing of environment-protective toilet cleanser prepared by the present invention is good, and the present invention
Environment-protective toilet cleanser corrosivity it is low, mild environmental protection has wall built-up good, and cleaning effect is good, the advantages of having disinfection effect concurrently,
The water closet pan porcelain facing after washing can be made to reflect faint blue light simultaneously, a kind of comfort of people is given, can more meet the requirement of modern；
The present invention is carried out with preferred embodiment although having been combined and being presently believed to be most practical, it should
Understand that the present invention is not limited only to above-mentioned disclosed embodiment, those skilled in the art are it is conceivable that the present invention's
Technical scheme of the present invention is changed and is improved in purport and spirit, without departing from determining in the appended claims
The scope of the present invention of justice.
Claims (10)
1. a kind of environment-protective toilet cleanser, wherein the detergent for toilet includes the three ethyl alcohol hydramine of aliphatic acid of 5-8 mass parts, 2-4 mass parts
The alkyl glycosides of isomery alcohol polyethenoxy ether and 4-8 mass parts.
2. environment-protective toilet cleanser according to claim 1, wherein the isomeric alcohol polyethenoxy ether is ten alcohol polyoxy second of isomery
The mixture of one or more compositions of alkene ether, isomery undecyl alcohol polyoxyethylene ether and isomerous tridecanol polyoxyethylene ether.
3. environment-protective toilet cleanser according to claim 1, wherein the detergent for toilet includes the aliphatic acid three of 6-7 mass parts
Ethyl alcohol hydramine, the isomery alcohol polyethenoxy ether of 3-4 mass parts and the alkyl glycosides of 6-7 mass parts.
4. environment-protective toilet cleanser according to claim 1, wherein the detergent for toilet further includes the sodium benzoate of 2-4 mass parts, 3-
The mixture of the sodium citrate of 6 mass parts, the potassium chloride of 0.1-2 mass parts and 3-5 mass parts being made of acid；
The wherein described mixture includes boric acid and hydrochloric acid, and the mass ratio of the boric acid and the hydrochloric acid is 3-5/1.
5. environment-protective toilet cleanser according to claim 1, wherein the detergent for toilet further include 2-3 mass parts sodium bicarbonate,
The hydrogen peroxide of the potassium carbonate and 0.2-1.8 mass parts of 0.5-3 mass parts.
6. environment-protective toilet cleanser according to claim 1, wherein the detergent for toilet further includes butanediol and ethyl alcohol, the fourth two
The sum of mass fraction of alcohol and the ethyl alcohol is 1-2.
7. environment-protective toilet cleanser according to claim 6, wherein the mass ratio of the butanediol and the ethyl alcohol is 1-3/
1。
8. environment-protective toilet cleanser according to claim 1, wherein the detergent for toilet further includes the fragrance of 0.5-2.5 mass parts.
9. environment-protective toilet cleanser according to claim 1, wherein the fragrance be Flos Rosae Rugosae extract, papaya extractives and
The mixture of one or more compositions in Herba Lysimachiae foenumgraeci extract.
10. a kind of preparation method according to claim 1 to 9 any one of them environment-protective toilet cleanser, wherein the preparation method packet
Include following steps：
Step 1: potassium chloride, sodium bicarbonate, sodium carbonate, mixture, sodium citrate, sodium benzoate and deionized water are mixed, stir
It mixes uniformly and is heated to 50 DEG C -70 DEG C, and keep 1-3h at 60 DEG C, obtain the first intermediate blend；
Step 2: fatty acid triethanol amine, isomery alcohol polyvinylether and alkyl glycosides are mixed, stirs evenly and be heated to 40
DEG C -50 DEG C, and 1-2h is kept, and obtain the second intermediate blend；
Step 3: being added second intermediate blend to first intermediate blend, stir while adding, mixing time
For 20-4min, stand to room temperature；10 DEG C are heated on the basis of room temperature, are kept 20-50min, room temperature are reduced to, in the base of room temperature
5 DEG C -10 DEG C are heated on plinth, keeps 20-30min, and room temperature, despumation is reduced to obtain third intermediate blend；
Step 4: hydrogen peroxide, lavender extracting solution, butanediol and ethyl alcohol are sequentially added in the third intermediate blend,
It stirs evenly, obtains detergent for toilet.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810616682.7A CN108611200A (en) | 2018-06-15 | 2018-06-15 | Environment-protective toilet cleanser and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810616682.7A CN108611200A (en) | 2018-06-15 | 2018-06-15 | Environment-protective toilet cleanser and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108611200A true CN108611200A (en) | 2018-10-02 |
Family
ID=63665202
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810616682.7A Pending CN108611200A (en) | 2018-06-15 | 2018-06-15 | Environment-protective toilet cleanser and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108611200A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112029593A (en) * | 2020-07-21 | 2020-12-04 | 名臣健康用品股份有限公司 | Foam type toilet cleaning liquid composition and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050019293A1 (en) * | 2003-07-23 | 2005-01-27 | Colgate-Palmolive Company | Liquid dish cleaning compositions containing vitamin E acetate |
| EP1214389B1 (en) * | 1999-09-22 | 2005-12-14 | Cognis IP Management GmbH | Surfactant mixtures |
| US20130172227A1 (en) * | 2010-09-10 | 2013-07-04 | Lion Corporation | Liquid detergent composition |
| CN107760464A (en) * | 2017-10-30 | 2018-03-06 | 胡国剑 | A kind of detergent for toilet and preparation method thereof |
| CN108004051A (en) * | 2017-12-18 | 2018-05-08 | 广州昊杰麟科技有限公司 | A kind of kitchen heavy oil pollution cleanser and preparation method |
-
2018
- 2018-06-15 CN CN201810616682.7A patent/CN108611200A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1214389B1 (en) * | 1999-09-22 | 2005-12-14 | Cognis IP Management GmbH | Surfactant mixtures |
| US20050019293A1 (en) * | 2003-07-23 | 2005-01-27 | Colgate-Palmolive Company | Liquid dish cleaning compositions containing vitamin E acetate |
| US20130172227A1 (en) * | 2010-09-10 | 2013-07-04 | Lion Corporation | Liquid detergent composition |
| CN107760464A (en) * | 2017-10-30 | 2018-03-06 | 胡国剑 | A kind of detergent for toilet and preparation method thereof |
| CN108004051A (en) * | 2017-12-18 | 2018-05-08 | 广州昊杰麟科技有限公司 | A kind of kitchen heavy oil pollution cleanser and preparation method |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112029593A (en) * | 2020-07-21 | 2020-12-04 | 名臣健康用品股份有限公司 | Foam type toilet cleaning liquid composition and preparation method thereof |
| CN112029593B (en) * | 2020-07-21 | 2022-08-30 | 名臣健康用品股份有限公司 | Low-viscosity foam type toilet cleaning liquid composition with foam spraying effect and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2757677T3 (en) | Hard surface cleaning composition for personal contact areas | |
| JP5818546B2 (en) | Antibacterial agent | |
| BR102013019428A2 (en) | CLEANING AND DISINFECTION AGENT FOR MEDICAL INSTRUMENTS | |
| ES2675780T3 (en) | Dissolution of use, kit and method for cleaning floors | |
| MX2012014376A (en) | Dilutable biocidal compositions and methods of use. | |
| CN105925395A (en) | Veterinary foam cleaning agent and preparation method thereof | |
| CN110591833A (en) | Toilet cleaning agent and preparation method thereof | |
| JP2022001880A (en) | Method and composition for rapid detection of protein soils | |
| CN104830578A (en) | High-efficiency toilet cleaning agent and preparation method thereof | |
| US10519403B2 (en) | Sanitary cleaner | |
| CN108611200A (en) | Environment-protective toilet cleanser and preparation method thereof | |
| CN105754735B (en) | A kind of kitchen cleaning agent and preparation method thereof | |
| WO2013112207A1 (en) | Compositions and methods for cleaning management | |
| WO2009125305A2 (en) | Sanitary cleaner | |
| EP2853583B1 (en) | Hard surface cleaning composition | |
| CN108342258A (en) | Liquid cleanser composition | |
| AU2014233610B2 (en) | Hard surface cleaning composition for personal contact areas | |
| RU2811470C2 (en) | Biodegradable lipase-based cleaning composition for decomposition of low-melting acylglycerides of various spatial configuration and regulation of foam stability and surface hydrophilization | |
| CN108342257A (en) | Liquid cleanser composition | |
| WO2018124091A1 (en) | Powder detergent composition for textile products | |
| WO2018124090A1 (en) | Powder detergent composition for textile article | |
| WO2023210744A1 (en) | Method for cleaning object surface | |
| JP2023162913A (en) | disinfectant composition | |
| CN117551511A (en) | Foam cleaning agent easy to rinse and preparation method thereof | |
| HK1189618A (en) | Hard surface cleaning composition for personal contact areas |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20181002 |
|
| WD01 | Invention patent application deemed withdrawn after publication |