CN108610960A - ceramic surface material and surface coating - Google Patents
ceramic surface material and surface coating Download PDFInfo
- Publication number
- CN108610960A CN108610960A CN201810399271.7A CN201810399271A CN108610960A CN 108610960 A CN108610960 A CN 108610960A CN 201810399271 A CN201810399271 A CN 201810399271A CN 108610960 A CN108610960 A CN 108610960A
- Authority
- CN
- China
- Prior art keywords
- silicon
- oxide
- content
- boron
- poly
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 98
- 239000000463 material Substances 0.000 title claims abstract description 92
- 239000011248 coating agent Substances 0.000 title claims abstract description 9
- 238000000576 coating method Methods 0.000 title claims abstract description 9
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims abstract description 40
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 37
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 36
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229910052751 metal Inorganic materials 0.000 claims abstract description 31
- 239000002184 metal Substances 0.000 claims abstract description 31
- 239000000203 mixture Substances 0.000 claims abstract description 31
- 239000000945 filler Substances 0.000 claims abstract description 27
- 239000003960 organic solvent Substances 0.000 claims abstract description 23
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims abstract description 21
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 20
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910001404 rare earth metal oxide Inorganic materials 0.000 claims abstract description 19
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims abstract description 18
- 150000001875 compounds Chemical class 0.000 claims abstract description 17
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 17
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 17
- 239000010439 graphite Substances 0.000 claims abstract description 17
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 16
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 15
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 14
- 230000007704 transition Effects 0.000 claims abstract description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 63
- -1 polysiloxanes Polymers 0.000 claims description 60
- 229920001296 polysiloxane Polymers 0.000 claims description 44
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 37
- 239000010703 silicon Substances 0.000 claims description 37
- 229910052710 silicon Inorganic materials 0.000 claims description 36
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 35
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 34
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 34
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 33
- 229910052804 chromium Inorganic materials 0.000 claims description 33
- 239000011651 chromium Substances 0.000 claims description 33
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 33
- 229910052759 nickel Inorganic materials 0.000 claims description 30
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 26
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 26
- 229910052796 boron Inorganic materials 0.000 claims description 25
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims description 24
- SEURRRHUNSCTGP-UHFFFAOYSA-N N.[Si].[C] Chemical compound N.[Si].[C] SEURRRHUNSCTGP-UHFFFAOYSA-N 0.000 claims description 22
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 22
- 229910052726 zirconium Inorganic materials 0.000 claims description 22
- JOSYKQYGXFZOEP-UHFFFAOYSA-N N.[B].[Si] Chemical compound N.[B].[Si] JOSYKQYGXFZOEP-UHFFFAOYSA-N 0.000 claims description 21
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 20
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 20
- 229910000062 azane Inorganic materials 0.000 claims description 20
- 239000010936 titanium Substances 0.000 claims description 20
- 229910052719 titanium Inorganic materials 0.000 claims description 20
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 20
- 239000004411 aluminium Substances 0.000 claims description 19
- 229910052782 aluminium Inorganic materials 0.000 claims description 19
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 19
- 229910052810 boron oxide Inorganic materials 0.000 claims description 19
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 19
- 229910052582 BN Inorganic materials 0.000 claims description 18
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 18
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 18
- 229920001709 polysilazane Polymers 0.000 claims description 18
- 239000013078 crystal Substances 0.000 claims description 17
- 229910052727 yttrium Inorganic materials 0.000 claims description 17
- INJRKJPEYSAMPD-UHFFFAOYSA-N aluminum;silicic acid;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O INJRKJPEYSAMPD-UHFFFAOYSA-N 0.000 claims description 16
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 16
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims description 16
- 239000010443 kyanite Substances 0.000 claims description 16
- 229910052850 kyanite Inorganic materials 0.000 claims description 16
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims description 16
- 229910052863 mullite Inorganic materials 0.000 claims description 16
- 239000010434 nepheline Substances 0.000 claims description 16
- 229910052664 nepheline Inorganic materials 0.000 claims description 16
- 229910000484 niobium oxide Inorganic materials 0.000 claims description 16
- URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 claims description 16
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 16
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims description 16
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 16
- 239000005995 Aluminium silicate Substances 0.000 claims description 15
- QYEXBYZXHDUPRC-UHFFFAOYSA-N B#[Ti]#B Chemical group B#[Ti]#B QYEXBYZXHDUPRC-UHFFFAOYSA-N 0.000 claims description 15
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 15
- 235000012211 aluminium silicate Nutrition 0.000 claims description 15
- 229910052802 copper Inorganic materials 0.000 claims description 15
- 239000010949 copper Substances 0.000 claims description 15
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 15
- 239000011777 magnesium Substances 0.000 claims description 15
- 229910052749 magnesium Inorganic materials 0.000 claims description 15
- 229910052596 spinel Inorganic materials 0.000 claims description 15
- 239000011029 spinel Substances 0.000 claims description 15
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 14
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 14
- 229910000423 chromium oxide Inorganic materials 0.000 claims description 14
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical group [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 14
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 14
- 229910052580 B4C Inorganic materials 0.000 claims description 13
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 claims description 13
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims description 13
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 13
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 9
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 229910000314 transition metal oxide Inorganic materials 0.000 claims description 6
- 230000003197 catalytic effect Effects 0.000 claims description 5
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 230000008859 change Effects 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000002270 dispersing agent Substances 0.000 claims description 4
- 238000009736 wetting Methods 0.000 claims description 4
- 238000003763 carbonization Methods 0.000 claims description 3
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- 239000003973 paint Substances 0.000 claims description 2
- 230000037452 priming Effects 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 3
- JBANFLSTOJPTFW-UHFFFAOYSA-N azane;boron Chemical compound [B].N JBANFLSTOJPTFW-UHFFFAOYSA-N 0.000 claims 1
- FANANXQSVYPRCQ-UHFFFAOYSA-N azane;silicon Chemical compound N.[Si] FANANXQSVYPRCQ-UHFFFAOYSA-N 0.000 claims 1
- 238000005260 corrosion Methods 0.000 description 30
- 230000007797 corrosion Effects 0.000 description 29
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 16
- 239000000306 component Substances 0.000 description 16
- 239000002585 base Substances 0.000 description 14
- 239000002131 composite material Substances 0.000 description 9
- 239000000377 silicon dioxide Substances 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 230000003628 erosive effect Effects 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 150000003624 transition metals Chemical class 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 5
- 235000012239 silicon dioxide Nutrition 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 229910010293 ceramic material Inorganic materials 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 230000035939 shock Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 3
- 208000037656 Respiratory Sounds Diseases 0.000 description 3
- CKUAXEQHGKSLHN-UHFFFAOYSA-N [C].[N] Chemical compound [C].[N] CKUAXEQHGKSLHN-UHFFFAOYSA-N 0.000 description 3
- HMDDXIMCDZRSNE-UHFFFAOYSA-N [C].[Si] Chemical compound [C].[Si] HMDDXIMCDZRSNE-UHFFFAOYSA-N 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 235000006708 antioxidants Nutrition 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 229910052746 lanthanum Inorganic materials 0.000 description 3
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 229910052573 porcelain Inorganic materials 0.000 description 3
- 239000005297 pyrex Substances 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000005538 encapsulation Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 230000035876 healing Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- 229910001051 Magnalium Inorganic materials 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- GXDVEXJTVGRLNW-UHFFFAOYSA-N [Cr].[Cu] Chemical group [Cr].[Cu] GXDVEXJTVGRLNW-UHFFFAOYSA-N 0.000 description 1
- UMVBXBACMIOFDO-UHFFFAOYSA-N [N].[Si] Chemical compound [N].[Si] UMVBXBACMIOFDO-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 238000010504 bond cleavage reaction Methods 0.000 description 1
- 239000010782 bulky waste Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000005255 carburizing Methods 0.000 description 1
- 238000005524 ceramic coating Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 235000019628 coolness Nutrition 0.000 description 1
- 239000008358 core component Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 150000003376 silicon Chemical class 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- 238000007751 thermal spraying Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/16—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers in which all the silicon atoms are connected by linkages other than oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/14—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0812—Aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0862—Nickel
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0881—Titanium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/382—Boron-containing compounds and nitrogen
- C08K2003/385—Binary compounds of nitrogen with boron
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Ceramic Products (AREA)
Abstract
The present invention provides a kind of ceramic surface materials comprising：The organosilicon of 20.0wt%~70.0wt%, the organic solvent of 20.0wt%~70.0wt%, the filler of 1.0wt%~50wt%, the auxiliary agent of 0.1wt%~3.0wt%, wherein organic solvent are one or more in butyl acetate, dimethylbenzene, n-butyl ether, butyl acetic acid esters, hexahydrotoluene, normal octane and butyl titanate；The filler is made of graphene, graphite, transition group metallic oxide, composition silicate, rare earth oxide, nonmetallic, nonmetallic compound, magnesium-yttrium-transition metal boride, whisker and metal.Component in the above-mentioned ceramic surface material of the application mutually acts synergistically, and has better comprehensive performance when making it as coating.
Description
Technical field
The present invention relates to surface material technology field more particularly to ceramic surface materials and surface coating.
Background technology
In Aeronautics and Astronautics device, station boiler, biomass boiler, garbage burning boiler, petrochemical heating furnace, middle unskilled labourer
In the production run of industry boiler, various engines and other heat power equipments, the high temperature corrosion of heating surface, erosive wear and it is stained with
Dirty slagging etc. causes above equipment the very big hidden danger of safe operation, at the same can also influence above equipment heat exchange efficiency and
Exchange capability of heat.High temperature corrosion and erosive wear cause the direct destruction of heating surface, heat exchange surface Slagging to directly result in heat exchange
Ability declines, heat power equipment therrmodynamic system is unbalance and the thermal efficiency reduces, and the fire box temperature raising also resulted in can also cause boiler tube
The problems such as overheating operation, excessively high NO_x formation and discharge aggravation and exhaust gas temperature；Slagging can also aggravate to change simultaneously
Hot surface corrodes.The above problem directly affects safety in production, energy-saving and emission-reduction, product quality and production capacity, and reduce equipment uses the longevity
Life, massive losses are brought to enterprise.
For above-mentioned high temperature corrosion, Slagging and erosive wear problem, traditional solution is optimization design, optimization
Operation, promoted heat-transfer surface basic material grade, using metal thermal spraying and built-up welding deposition silicates ceramic surface material with have
Machine silicon class ceramic surface material, but there is no fundamentally solve high temperature corrosion, erosive wear and Slagging for the above method
Problem, security risk still have.
Surfacing is a kind of important engineering material, is to be coated on body surface to form film under certain condition
And with protection, decoration, insulation, anti-corrosion, shockproof or the specific functions such as heat-resisting liquid or solid material.And composite organic is resistance to
High temperature corrosion self-healing ceramic surface material is a kind of novel environment-friendly function material, which has high temperature resistant, Applicable temperature
Range is wide, corrosion-resistant, high rigidity, high durable and it is not viscous many advantages, such as, be a kind of ideal surfacing.
In order to solve the problems, such as high temperature corrosion, erosive wear and the Slagging in the production runs such as boiler, researcher's research and development
The silicates ceramic material of a series of high temperature resistant resistive connection slag grinds to strengthen the stability of boiler in process of production
The person of studying carefully further enhances the performance of ceramic surface material simultaneously, is desirably to obtain the preferable ceramic surface material of comprehensive performance, from
And ensure that the heating equipments such as boiler being capable of stable operation in industry.Such as：Application No. is 201410687121.8 Chinese patents
Disclose a kind of high temperature resistant dirt-resistant slagging ceramic surface material comprising：Filler, binder and water, wherein filler include oxygen
Change zirconium, silicon nitride, silicon carbide, titanium dioxide, kaolin and rare earth oxide, the ceramic surface material which provides is resistant to
1050 DEG C of high temperature, but the surfacing comprehensive performance especially sulfur corrosion of reducing resistance atmosphere and chlorine corrosion ability is not still
It is very high.Application No. is 201510542509.3 Chinese patents to disclose a kind of high-temperature corrosion resistance dirt-resistant slagging ceramic watch plane materiel
Material comprising：Filler, binder and water, wherein filler include graphite, boron nitride and rare earth oxide, the pottery which provides
Porcelain surfacing is resistant to 850 DEG C of high temperature, but the surfacing comprehensive performance especially heat-resisting ability still cannot meet height
Warm environmental demand, and the patent of existing organosilicon high temperature corrosion resistance surfacing then generally existing organosilicon heat up pyrolytic process
Ceramic layer porosity is higher, there are through-wall crack, and used self-healing packing material is mostly alkali metal glass, metal oxide
And higher nonmetallic compound of melting temperature etc., so that self-healing ceramic surface material is most widely warm in commercial Application
It is relatively low to spend section (250~800 DEG C) self-healing capability, chlorine corrosion and reducible sulfur corrosion cannot be resisted very well, corrosion is caused to be situated between
Matter penetrates surfacing corrosion base material.
Invention content
Present invention solves the technical problem that being to provide a kind of preferable ceramic surface material of comprehensive performance, it is in particular in
The corrosion-resistant of ceramic surface material, high temperature resistant and self-healing capability are preferable.
In view of this, this application provides a kind of ceramic surface material, it is composed of the following components：
The organic solvent be selected from butyl acetate, dimethylbenzene, n-butyl ether, butyl acetic acid esters, hexahydrotoluene,
It is one or more in normal octane and butyl titanate；
The filler by graphene, graphite, transition group metallic oxide, composition silicate, rare earth oxide, it is nonmetallic,
Nonmetallic compound, magnesium-yttrium-transition metal boride, whisker and metal form.
Preferably, the organosilicon is selected from polysilazane, poly- silicon boron azane, polysiloxanes, silicones azane, poly- silicon-carbon
It is one or more in alkane, poly- silicon-carbon azane and polyborazine.
Preferably, the transition group metallic oxide is in zirconium oxide, chromium oxide, titanium oxide, molybdenum oxide and niobium oxide
It is one or more；The metal is one or more in chromium, nickel, titanium, aluminium and yttrium；The composition silicate is selected from copper chromium
It is one or more in spinelle, magnesium aluminate spinel, mullite, nepheline, kaolin, kyanite, alumina silicate and zirconium silicate；It is described
Rare earth oxide is one or more in cerium oxide, yttrium oxide and lanthana；It is described it is nonmetallic in silicon and boron one
Kind or two kinds；The nonmetallic compound in boron carbide, silicon boride, boron nitride, silicon nitride, silicon carbide and boron oxide one
Kind is a variety of；The magnesium-yttrium-transition metal boride is one or more in titanium boride, zirconium boride, chromium boride and nickel borides；
The whisker is selected from one or both of silicon carbide whisker and silicon nitride crystal whisker；The auxiliary agent is selected from silane coupling agent, wetting
It is one or more in dispersant and catalytic curing agent.
Preferably, the granularity of the filler is 50~900nm.
Preferably, the organosilicon be polysilazane, poly- silicon boron azane, polysiloxanes, silicones azane, poly- silicon-carbon alkane,
Poly- silicon-carbon azane and polyborazine it is one or more when, the polysilazane, poly- silicon boron azane, polysiloxanes, poly- silica nitrogen
The content of alkane, poly- silicon-carbon alkane and poly- silicon-carbon azane independently is 0.5~70wt%.
Preferably, the organosilicon be polysilazane, poly- silicon boron azane, polysiloxanes, silicones azane, poly- silicon-carbon alkane,
When the mixture of poly- silicon-carbon azane and polyborazine, the polysilazane, polysiloxanes, silicones azane, gathers poly- silicon boron azane
The content of silicon-carbon alkane and poly- silicon-carbon azane independently is 0.5~67wt%.
Preferably, the organosilicon of stating is polysilazane, poly- silicon boron azane, polysiloxanes, silicones azane, poly- silicon-carbon
When the mixture of alkane, poly- silicon-carbon azane and polyborazine, the content of the organosilicon is 30wt%~60wt%, the poly- silicon nitrogen
The content of alkane is 10wt%~20wt%, and the content of the poly- silicon boron azane is 10wt%~20wt%, and the polysiloxanes gathers
Silica azane, poly- silicon-carbon alkane, poly- silicon-carbon azane and polyborazine content independently be 2wt%~5wt%.
Preferably, the organic solvent is butyl acetate, dimethylbenzene, n-butyl ether, butyl acetic acid esters, methyl ring
Hexane, normal octane and butyl titanate it is one or more when, the butyl acetate, dimethylbenzene, n-butyl ether, butyl second
Acid esters, hexahydrotoluene, normal octane and butyl titanate content independently be 0.5wt%~70wt%.
Preferably, the organic solvent is butyl acetate, dimethylbenzene, n-butyl ether, butyl acetic acid esters, methyl ring
When the mixture of hexane, normal octane and butyl titanate, the butyl acetate, dimethylbenzene, n-butyl ether, butyl acetic acid
Ester, hexahydrotoluene, normal octane and butyl titanate content independently be 0.5wt%~67wt%.
Preferably, when the rare earth oxide is cerium oxide, yttrium oxide and lanthana, the cerium oxide, yttrium oxide and oxygen
The content for changing lanthanum independently is 0.1wt%~2wt%；
The content of the graphite is 0.1wt%~3wt%；The content of the graphene is 0.1wt%~3wt%；
The metal is chromium, nickel, titanium, aluminium and when yttrium, the chromium, nickel, titanium, aluminium and yttrium content independently be 0.1wt%
~20wt%；
The composition silicate is copper picotite, magnesium aluminate spinel, mullite, nepheline, kaolin, kyanite, silicic acid
When aluminium and zirconium silicate, the copper picotite, magnesium aluminate spinel, mullite, nepheline, kaolin, kyanite, alumina silicate and silicic acid
The content of zirconium independently is 0.1wt%~20wt%；
It is described it is nonmetallic be silicon and boron when, the content of the silicon and boron independently is 0.1wt%~20wt%；
When the nonmetallic compound is boron carbide, silicon boride, boron nitride, silicon nitride, silicon carbide and boron oxide, the carbon
The content for changing boron, silicon boride, boron nitride, silicon nitride, silicon carbide and boron oxide independently is 0.1wt%~20wt%；
When the magnesium-yttrium-transition metal boride is titanium boride, zirconium boride, chromium boride and nickel borides, the titanium boride, boronation
The content of zirconium, chromium boride and nickel borides independently is 0.1wt%~20wt%；
When the whisker is silicon carbide whisker and silicon nitride crystal whisker, the content of the silicon carbide whisker and silicon nitride crystal whisker is only
It is on the spot 0.1wt%~5wt%；
When the transition metal oxide is zirconium oxide, chromium oxide, titanium oxide, molybdenum oxide and niobium oxide, the zirconium oxide,
Chromium oxide, titanium oxide, molybdenum oxide and niobium oxide content independently be 0.1wt%~20wt%.
Preferably, when the rare earth oxide is cerium oxide, yttrium oxide and lanthana, the cerium oxide, yttrium oxide and oxygen
The content for changing lanthanum independently is 0.3wt%~1.5wt%；
The content of the graphite is 0.2wt%~2wt%；The content of the graphene is 0.2wt%~2wt%；
The metal is chromium, nickel, titanium, aluminium and when yttrium, the chromium, nickel, titanium, aluminium and yttrium content independently be 0.2wt%
~3wt%；
It is described it is nonmetallic be silicon and boron when, the content of the silicon and boron independently is 0.2wt%~3wt%；
The composition silicate is copper picotite, magnesium aluminate spinel, mullite, nepheline, kaolin, kyanite, silicic acid
When aluminium and zirconium silicate, the copper picotite, magnesium aluminate spinel, mullite, nepheline, kaolin, kyanite, alumina silicate and silicic acid
The content of zirconium independently is 0.2wt%~3wt%；
When the nonmetallic compound is boron carbide, silicon boride, boron nitride, silicon nitride, silicon carbide and boron oxide, the carbon
The content for changing boron, silicon boride, boron nitride, silicon nitride, silicon carbide and boron oxide independently is 0.2wt%~3wt%；
When the magnesium-yttrium-transition metal boride is titanium boride, zirconium boride, chromium boride and nickel borides, the titanium boride, boronation
The content of zirconium, chromium boride and nickel borides independently is 0.2wt%~3wt%；
When the whisker is silicon carbide whisker and silicon nitride crystal whisker, the content of the silicon carbide whisker and silicon nitride crystal whisker is only
It is on the spot 0.2wt%~2wt%；
When the transition metal oxide is zirconium oxide, chromium oxide, titanium oxide, molybdenum oxide and niobium oxide, the zirconium oxide,
Chromium oxide, titanium oxide, molybdenum oxide and niobium oxide content independently be 0.2wt%~3wt%.
Present invention also provides a kind of surface coating, including investment precoat and priming paint, the investment precoat is said program
The ceramic surface material.
This application provides a kind of ceramic surface materials comprising：The organosilicon of 20.0wt%~70.0wt%,
The organic solvent of 20.0wt%~70.0wt%, the filler of 1.0wt%~50wt%, the auxiliary agent of 0.1wt%~3.0wt%,
Middle organic solvent is selected from butyl acetate, dimethylbenzene, n-butyl ether, butyl acetic acid esters, hexahydrotoluene, normal octane and titanium
It is one or more in acid butyl ester；The filler is by graphene, graphite, transition group metallic oxide, composition silicate, rare earth oxygen
Compound, nonmetallic, nonmetallic compound, transition metal boride, whisker and metal form.Ceramic watch plane materiel provided by the present application
Organosilicon in material is formed after discharging the gases such as carbon dioxide, methane by pyrolytic reaction under first time heating and the condition of high temperature
Spatial networks nitrogen carbon borosilicate composite ceramic material structure, and react to form covalent bond and ceramic with other inorganic components, simultaneously
Rare earth oxide in filler is conducive to crystal grain refinement, and filling crystal grain gap forms network, the fillers such as composition silicate and metal
Interaction forms melting softening or even flowable state composite ceramics constituent element at high temperature, can be filled in automatically by silicone thermal parallel off
The hole and destroy the crackle generated that the gas of solution generates, to improve the high temperature of ceramic surface material and the toughness of room temperature,
Thermal stability, high temperature corrosion and thermodynamic behaviour etc..To sum up, the said components synergistic effect in the application, makes ceramics
Surfacing has preferable performance, such as：High temperature resistant, high heat exchange property, corrosion-resistant, wear-resistant, high emissivity, dirt-resistant knot
Slag and self-healing capability.
Specific implementation mode
For a further understanding of the present invention, the preferred embodiment of the invention is described with reference to embodiment, still
It should be appreciated that these descriptions are only the feature and advantage further illustrated the present invention, rather than to the claims in the present invention
Limitation.
For the bad problem of ceramic surface material comprehensive performance in the prior art, the embodiment of the invention discloses a kind of potteries
Porcelain surfacing, organic solvent, filler and auxiliary agent and organosilicon in the ceramic surface material form collaboration system, for difference
The specific requirement of use environment so that ceramic layer has anti-oxidant, corrosion-resistant, wear-resistant, automatically cleaning, high tenacity, some higher thermal conductivity
The high combination property of rate and emissivity, and there is excellent selfreparing self-healing capability.Specifically, this application provides a kind of potteries
Porcelain surfacing, it is composed of the following components：
The organic solvent be selected from butyl acetate, dimethylbenzene, n-butyl ether, butyl acetic acid esters, hexahydrotoluene,
It is one or more in normal octane and butyl titanate；
The filler by graphene, graphite, transition group metallic oxide, composition silicate, rare earth oxide, it is nonmetallic,
Nonmetallic compound, transition metal boride, whisker and metal form.
In this application, organosilicon is selected from polysilazane, poly- silicon boron azane, polysiloxanes, silicones azane, poly- silicon-carbon
It is one or more in alkane, poly- silicon-carbon azane and polyborazine；In a particular embodiment, the organosilicon is polysilazane, gathers
The mixture of silicon boron azane, polysiloxanes, silicones azane, poly- silicon-carbon alkane, poly- silicon-carbon azane and polyborazine.Institute in the application
Basic component of the organosilicon as surface ceramic coating is stated, as bridge and other component collective effects；Specifically, described have
After machine silicon discharges the gases such as carbon dioxide, methane under first time heating and the condition of high temperature by pyrolytic reaction, space networks are formed
Shape nitrogen carbon borosilicate composite ceramic material structure, and react to form covalent bond and ceramic with other inorganic components.
In this application, the organosilicon is polysilazane, poly- silicon boron azane, polysiloxanes, silicones azane, poly- silicon-carbon
Alkane, poly- silicon-carbon azane and polyborazine it is one or more when, the polysilazane, poly- silicon boron azane, polysiloxanes, poly- silica
The content of azane, poly- silicon-carbon alkane and poly- silicon-carbon azane independently is 0.5~70wt%；The organosilicon is polysilazane, poly- silicon
Boron azane, polysiloxanes, silicones azane, poly- silicon-carbon alkane, poly- silicon-carbon azane and polyborazine mixture when, the poly- silicon nitrogen
Alkane, poly- silicon boron azane, polysiloxanes, silicones azane, poly- silicon-carbon alkane and poly- silicon-carbon azane content independently be 0.5~
67wt%.In a particular embodiment, the content of the organosilicon is 30wt%~60wt%, at this point, the polysilazane contains
Amount is 10wt%~20wt%, and the content of the poly- silicon boron azane is 10wt%~20wt%, the polysiloxanes, poly- silica nitrogen
Alkane, poly- silicon-carbon alkane, poly- silicon-carbon azane and polyborazine content independently be 2wt%~5wt%.If the content of organosilicon exceeds
Above range can not then effectively form space net structure, to the spatial stability of nitrogen carbon borosilicate composite ceramic material structure
Property can reduce, ceramic surface ceramic is insufficient or excessively fully, directly affects the self-healing capability of ceramic surface material and resistance to
Corrosive nature.
The solvent of the application ceramic surface material is organic solvent, and the organic solvent is selected from butyl acetate, dimethylbenzene, just
It is one or more in butyl ether, butyl acetic acid esters, hexahydrotoluene, normal octane and butyl titanate；It is being embodied
In example, the organic solvent is butyl acetate, dimethylbenzene, n-butyl ether, butyl acetic acid esters, hexahydrotoluene, just pungent
Alkane and butyl titanate.The content of the organic solvent is 20wt%~70wt%, in a particular embodiment, the organic solvent
Content is 30wt%~60wt%.Specifically, the organic solvent is butyl acetate, dimethylbenzene, n-butyl ether, butyl
Acetic acid esters, hexahydrotoluene, normal octane and butyl titanate it is one or more when, the butyl acetate, dimethylbenzene, n-butyl ether,
Butyl acetic acid esters, hexahydrotoluene, normal octane and butyl titanate content independently be 0.5wt%~70wt%；
The organic solvent is butyl acetate, dimethylbenzene, n-butyl ether, butyl acetic acid esters, hexahydrotoluene, normal octane and titanium
When the mixture of acid butyl ester, the butyl acetate, dimethylbenzene, n-butyl ether, butyl acetic acid esters, hexahydrotoluene, just
The content of octane and butyl titanate independently is 0.5wt%~70wt%；In a particular embodiment, the butyl acetate, diformazan
The content of benzene independently is 10wt%~40wt%, the n-butyl ether, butyl acetic acid esters, hexahydrotoluene, just pungent
The content of alkane and butyl acetate independently is 2wt%~5wt%.If the content of organic solvent exceeds above range, can influence
Film forming characteristics before the non-Cheng Tao of ceramic surface material and surface drying characteristic, to influence the heat scission reaction of ceramic surface material,
Directly affect ceramic surface material at Tao Xingneng, the final self-cleaning property and toughness for influencing ceramic surface material.
In this application, the auxiliary agent is auxiliary agent well known to those skilled in the art, is not limited particularly this application
System, the auxiliary agent described in the specific embodiment of the application in silane coupling agent, wetting dispersing agent and catalytic curing agent one
Kind is a variety of.The content of the auxiliary agent is 0.1wt%~3.0wt%, and more specifically, the content of each auxiliary agent is only in the auxiliary agent
It is on the spot 0.5wt%~1.0wt%.If the independent content of auxiliary agent exceeds above range, ceramic surface material will have a direct impact on
Dispersibility, coupling performance and curing performance, cause ceramic surface material at Tao Xingneng, influence ceramic surface material and matrix knot
The self-healing capability of conjunction ability and ceramic surface material.
Heretofore described filler finally determines the performance of ceramic surface material as core component.In the application
The filler is by graphene, graphite, transition group metallic oxide, composition silicate, rare earth oxide, nonmetallic, non-metallic
Object, transition metal boride, whisker and metal is closed to form.The granularity of the filler is 50~900nm.
In the filler, the graphite contributes to ceramic layer film formation and mask erosion type medium to ooze with graphene
Enter, improves the case hardness of base material under high temperature to metal base carburizing；Graphite forms carbon dioxide at high temperature with graphene, with
Silicone thermal cracking temperature matches, and is conducive to cracked gas and is discharged from ceramic layer；Meanwhile graphene also has at high temperature with graphite
Help other reactions inside promotion and catalytic ceramics layer, and carbide ceramics is generated with other materials.
The transition group metallic oxide can be selected from one kind in zirconium oxide, chromium oxide, titanium oxide, molybdenum oxide and niobium oxide
Or it is a variety of, the coefficient of thermal expansion of transition group metallic oxide is consistent with the coefficient of thermal expansion of metal base or swollen higher than the heat of base material
Swollen coefficient；And transition group metallic oxide and metal base binding ability are stronger, to contribute to ceramic surface material and gold
Belong to the binding ability and thermal shock resistance of base material.
The metal be chosen in particular from it is one or more in aluminium, nickel, titanium, chromium and yttrium, in a particular embodiment, the metal
Including aluminium, nickel, titanium, chromium and yttrium.The metal ceramic layer that adjustable ceramic surfacing is formed in ceramic surface material
Coefficient of thermal expansion is closer to metal base；Above-mentioned metal can form metal oxide under high temperature simultaneously.
The nonmetallic compound in boron carbide, silicon boride, boron nitride, silicon nitride, silicon carbide and boron oxide one
Kind is a variety of.In a particular embodiment, the nonmetallic compound is selected from boron carbide, silicon boride, boron nitride, silicon nitride, carbonization
The mixture of silicon and boron oxide.The boron carbide, silicon boride and boron nitride are in ceramic surface material in lower temperature and middle height
Has the characteristics that anti-oxidant, corrosion-resistant, wear-resistant and self-lubricating when warm；It is above-mentioned nonmetallic anti-with oxygen under high temperature degree simultaneously
Silica and boron oxide etc. should be generated, product interreaction re-forms boron glass, is filled with liquid phase more than after softening point temperature
The ceramic layer hole and crackle to be formed since silicone thermal cracks plays the role of selfreparing healing；Silicon nitride and silicon carbide are
With high temperature resistant, corrosion-resistant and anti abrasive filler.Silicate and decomposition in the boron oxide and ceramic surface material
Silica forms complex phase Pyrex, this kind of complex phase Pyrex are different with ratio different softening point temperature, so as to adjust
The selfreparing self-healing temperature of ceramic layer, with specific application environment matching criteria.
It is described it is nonmetallic be chosen in particular from one or both of boron and silicon, in a particular embodiment, it is described it is nonmetallic be boron
And silicon.The nonmetallic silicon and boron are in lower temperature and high temperature with anti-oxidant, corrosion-resistant, wear-resistant and self-lubricating spy
Point；Nonmetallic reacted with oxygen under high temperature degree above-mentioned simultaneously generates silica and boron oxide etc., and product interreaction is again
Boron glass is formed, the ceramic layer hole and crackle to be formed since silicone thermal cracks is filled with liquid phase more than after softening point temperature,
Play the role of selfreparing healing.
The transition metal boride is one or more in titanium boride, zirconium boride, chromium boride and nickel borides；Having
In body embodiment, the transition metal boride is the mixture of titanium boride, zirconium boride, chromium boride and nickel borides.The transition
Race's metal boride has the advantages that high temperature resistant, corrosion-resistant, wear-resistant and higher thermal expansion coefficient, to be conducive to and Metal Substrate
Material matched coefficients of thermal expansion；It also has better compatibility with metal base, metal packing and Pyrex simultaneously.
The whisker is selected from one or both of silicon carbide whisker and silicon nitride crystal whisker；In a particular embodiment, described
Whisker is selected from silicon carbide whisker and silicon nitride crystal whisker.The silicon carbide whisker and silicon nitride crystal whisker are plasticizing substance, Neng Gouzeng
The toughness for adding the ceramic layer of ceramic surface material formation, is allowed to adapt to metal base.
Further include composition silicate in above-mentioned filler, the composition silicate is chosen in particular from copper picotite, magnalium point
It is one or more in spar, mullite, nepheline, kaolin, kyanite, alumina silicate and zirconium silicate；Above-mentioned composition silicate exists
Silica can be introduced by reacting under high temperature, thus improve the corrosion-resistant of ceramic surface material, bond strength and mechanical property
Energy.
Rare earth oxide in filler specifically can be selected from cerium oxide, yttrium oxide and lanthana.The rare earth oxide due to
The lattice defect of itself can ceramic surface material formed coating in selective enrichment, fill up the seam generated in temperature-rise period
Gap can promote interpenetrating between component.
Using the ceramic surface material as base, the content of the filler is 1.0wt%~50wt%；In specific embodiment
In, the content of the filler is 1.5wt%~40wt%.Specifically, the rare earth oxide is cerium oxide, yttrium oxide and oxidation
When lanthanum, the content of the cerium oxide, yttrium oxide and lanthana independently is 0.1wt%~2wt%；The content of the graphite is
0.1wt%~3wt%；The content of the graphene is 0.1wt%~3wt%；The metal is chromium powder, nickel powder, titanium valve, aluminium powder
When with yttrium powder, the chromium powder, nickel powder, titanium valve, aluminium powder and yttrium powder content independently be 0.1wt%~20wt%；It is described compound
It is described when silicate is copper picotite, magnesium aluminate spinel, mullite, nepheline, kaolin, kyanite, alumina silicate and zirconium silicate
Copper picotite, magnesium aluminate spinel, mullite, nepheline, kaolin, kyanite, alumina silicate and zirconium silicate content independently be
0.1wt%~20wt%；When the transition metal oxide is zirconium oxide, chromium oxide, titanium oxide, molybdenum oxide and niobium oxide, institute
The content for stating zirconium oxide, chromium oxide, titanium oxide, molybdenum oxide and niobium oxide independently is 0.1wt%~20wt%.
In a particular embodiment, when the rare earth oxide is cerium oxide, yttrium oxide and lanthana, the cerium oxide, oxygen
The content for changing yttrium and lanthana independently is 0.3wt%~1.5wt%；The content of the graphite is 0.2wt%~2wt%；Institute
The content for stating graphene is 0.2wt%~2wt%；The metal is chromium, nickel, titanium, aluminium and when yttrium, the chromium, nickel, titanium, aluminium and
The content of yttrium independently is 0.2wt%~3wt%；The composition silicate be copper picotite, magnesium aluminate spinel, mullite,
When nepheline, kaolin, kyanite, alumina silicate and zirconium silicate, the copper picotite, magnesium aluminate spinel, mullite, nepheline, height
Ridge soil, kyanite, alumina silicate and zirconium silicate content independently be 0.2wt%~3wt%；The transition metal oxide is oxygen
Change zirconium, chromium oxide, titanium oxide, molybdenum oxide and when niobium oxide, the zirconium oxide, chromium oxide, titanium oxide, molybdenum oxide and niobium oxide
Content independently is 0.1wt%~3wt%.If the content of rare earth oxide is more than above range, ceramic surface material can be influenced
Dispersion performance and space net structure stability；The ceramic surface material if graphite and graphene content are beyond above range
Filming performance can have a certain impact, while its corrosion resistance can also be fluctuated and unstable, the ceramic surface of formation
The toughness of material and metal base can also have a certain impact；If the content of composition silicate exceeds above range, can be to ceramics
Self-healing capability, corrosion resistance and the toughness of surfacing have a certain impact；If metal and transition group metallic oxide
Content exceeds above range, can have a certain impact to the corrosion-resistant and thermal shock resistance of then ceramic surface material.
In a particular embodiment, it is described it is nonmetallic be silicon and boron, in the case, the content of the silicon and boron independently is
0.1wt%~20wt%；In a particular embodiment, the content of the silicon and boron independently is 0.2wt%~3wt%.If not golden
Belong to independent content and exceed above range, can have an impact to the self-healing capability of ceramic surface material, to influence ceramic surface
The corrosion resistance of material.
In a particular embodiment, the nonmetallic compound be boron carbide, silicon boride, boron nitride, silicon nitride, silicon carbide and
When boron oxide, the boron carbide, silicon boride, boron nitride, silicon nitride, silicon carbide and boron oxide content independently be 0.1wt%
~20wt%；In a particular embodiment, the content of the boron carbide, silicon boride, boron nitride, silicon nitride, silicon carbide and boron oxide
It independently is 0.2wt%~3wt%.If the independent content of nonmetallic compound exceeds above range, can be to ceramic surface material
Self-healing capability and self-healing controllability have an impact, while certain influence is generated to its wear-resisting property and toughness.
In a particular embodiment, when the whisker is silicon carbide whisker and silicon nitride crystal whisker, the silicon carbide whisker and nitrogen
The content of SiClx whisker independently is 0.1wt%~5wt%；In a particular embodiment, the silicon carbide whisker and nitridation silicon wafer
The content of palpus independently is 0.2wt%~2wt%.If the independent content of whisker exceeds above range, can be to ceramic surface material
Toughness and thermal shock resistance affect.
In a particular embodiment, when the transition metal boride is titanium boride, zirconium boride, chromium boride and nickel borides, institute
The content for stating titanium boride, zirconium boride, chromium boride and nickel borides independently is 0.1wt%~20wt%；In a particular embodiment, institute
The content for stating titanium boride, zirconium boride, chromium boride and nickel borides independently is 0.2wt%~3wt%.If magnesium-yttrium-transition metal boride
Independent content exceed above range when, can to the thermal shock resistance of ceramic surface material, corrosion resistance and with base material binding ability
It has a certain impact.
Preferably, herein described ceramic surface material, including：
Using the ceramic surface material as base, the content of the organosilicon mixture is 35wt% (wherein, polysilazanes
Content is 10wt%, the content of poly- silicon boron azane is 10wt%, polysiloxanes, silicones azane, poly- silicon-carbon alkane, poly- silicon-carbon azane
Content with polyborazine is all 3wt%)；
The content of the organic solvent is that (wherein, the content of butyl acetate is 2wt% to 23wt%, the content of dimethylbenzene is
11wt%, n-butyl ether, butyl acetic acid esters, hexahydrotoluene, normal octane and butyl titanate content be all 2wt%)；
The content of the preferred auxiliary agent is 1.5wt% (wherein, silane coupling agent, wetting dispersing agent and catalytic curing agent
Content be all 0.5wt%)；
The total content of the filler mixture be 40.5wt% (wherein, the content of boron carbide be 1.5wt%, silicon boride
Content is 1.5wt%, the content of boron nitride is 1.5wt%, the content of silicon nitride is 1.5wt%, the content of silicon carbide is
1.5wt%, boron oxide content be 1.5wt%, the content of titanium boride is 2wt%, the content of zirconium boride is 2wt%, chromium boride
Content be 2wt%, the content of nickel borides is 2wt%, the content of zirconium oxide is 0.6wt%, the content of chromium oxide is
0.8wt%, titanium oxide content be 0.8wt%, the content of molybdenum oxide is 0.8wt%, the content of niobium oxide is 0.8wt%, copper
The content of picotite is 1wt%, the content of magnesium aluminate spinel is 1wt%, the content of mullite is 1wt%, the content of nepheline
For 1wt%, kaolinic content be 1.8wt%, the content of kyanite is 1.8wt%, the content of alumina silicate is 3wt%, silicic acid
The content of zirconium is 3wt%, the content of graphite is 0.2wt%, the content of graphene is 0.2wt%, the content of cerium oxide is
0.4wt%, yttrium oxide content be 0.4wt%, the content of lanthana is 0.4wt%, the content of silicon carbide whisker is
1.2wt%, silicon nitride crystal whisker content be 1.2wt% content be all 1wt%, silica flour content be 0.55wt%, boron powder
Content is 0.55wt%, the content of aluminium powder is 0.2wt%, the content of nickel powder is 0.2wt%, the content of titanium valve is 0.2wt%, chromium
The content of powder is 0.2wt%, the content of yttrium powder is 0.2wt%).
" independently being " of content indicates that the content of each component can be selected in range intervals in said components in the application
It selects, the selection of content is unaffected between each component, but is the need to ensure that total content cannot exceed total size value.
Ceramic surface material each component provided by the present application and each component content make ceramic watch plane materiel by Optimized Matching
Material has higher comprehensive performance as coating material.
The preparation method of herein described ceramic surface material is prepared according to mode well known to those skilled in the art.
In order to keep the various components in surfacing more uniform, the preparation method of herein described ceramic surface material is preferably under
State step progress：
Organosilicon is mixed with organic solvent, obtains solvent-laden composite organic liquid；By the filler by refining
It is mixed with the solvent-laden composite organic liquid after processing, adds auxiliary agent uniform stirring, filtering encapsulation, obtain ceramic watch
Plane materiel material.
Present invention also provides application of the ceramic surface material in industrial furnace.The application ceramic surface material can
Coated on above-mentioned industrial furnace tube skin to form ceramic surface material, stabilization of the safeguard industries with stove in use
Property.Industrial furnace described above can be the industrial furnaces well known to those skilled in the art such as boiler, kiln and heating furnace.
For a further understanding of the present invention, ceramic surface material provided by the invention is carried out with reference to embodiment detailed
Illustrate, protection scope of the present invention is not limited by the following examples.
1~embodiment of embodiment 10
Organosilicon is mixed with organic solvent, obtains solvent-laden composite organic liquid；By the filler by refining
It is mixed with the solvent-laden composite organic liquid after processing, adds auxiliary agent uniform stirring, filtering encapsulation, obtain ceramic watch
Plane materiel material.The content for the ceramic surface material each component that embodiment 1 to embodiment 10 provides is as shown in table 1.
The ceramic surface material of Examples 1 to 10 is sprayed to the main combustion of water-cooling wall of Mr. Yu's 1000MW generating plant pulverized coal boilers respectively
Area's water-cooling wall, superheater and reheater surface, 600t/d bulky refuse furnace of power-plant boilers water coolings wall surface, the life of 130t/h large sizes
Substance boiler water wall and high temperature superheater surface, coating thickness are 30~100 μm.Using after 1 year according to country or industry
Interior general examination criteria carries out performance detection to product, and testing result is as shown in table 2.
1 1~embodiment of embodiment of table, 10 ceramic surface material each component content and specification data table (wt%)
The performance parameter tables of data for the ceramic surface material that 2 1~embodiment of embodiment 10 of table provides
The explanation of above example is only intended to facilitate the understanding of the method and its core concept of the invention.It should be pointed out that pair
For those skilled in the art, without departing from the principle of the present invention, the present invention can also be carried out
Some improvements and modifications, these improvement and modification are also fallen within the protection scope of the claims of the present invention.
The foregoing description of the disclosed embodiments enables those skilled in the art to implement or use the present invention.
Various modifications to these embodiments will be apparent to those skilled in the art, as defined herein
General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, of the invention
It is not intended to be limited to the embodiments shown herein, and is to fit to and the principles and novel features disclosed herein phase one
The widest range caused.
Claims (12)
1. a kind of ceramic surface material, composed of the following components：
The organic solvent is selected from butyl acetate, dimethylbenzene, n-butyl ether, butyl acetic acid esters, hexahydrotoluene, just pungent
It is one or more in alkane and butyl titanate；
The filler is by graphene, graphite, transition group metallic oxide, composition silicate, rare earth oxide, nonmetallic, non-gold
Belong to compound, magnesium-yttrium-transition metal boride, whisker and metal to form.
2. ceramic surface material according to claim 1, which is characterized in that the organosilicon is selected from polysilazane, poly- silicon
It is one or more in boron azane, polysiloxanes, silicones azane, poly- silicon-carbon alkane, poly- silicon-carbon azane and polyborazine.
3. ceramic surface material according to claim 1, which is characterized in that the transition group metallic oxide is selected from oxidation
It is one or more in zirconium, chromium oxide, titanium oxide, molybdenum oxide and niobium oxide；The metal is in chromium, nickel, titanium, aluminium and yttrium
It is one or more；The composition silicate be selected from copper picotite, magnesium aluminate spinel, mullite, nepheline, kaolin, kyanite,
It is one or more in alumina silicate and zirconium silicate；The one kind of the rare earth oxide in cerium oxide, yttrium oxide and lanthana
Or it is a variety of；It is described nonmetallic selected from one or both of silicon and boron；The nonmetallic compound be selected from boron carbide, silicon boride,
It is one or more in boron nitride, silicon nitride, silicon carbide and boron oxide；The magnesium-yttrium-transition metal boride is selected from titanium boride, boron
Change one or more in zirconium, chromium boride and nickel borides；The one kind of the whisker in silicon carbide whisker and silicon nitride crystal whisker
Or two kinds；The auxiliary agent is one or more in silane coupling agent, wetting dispersing agent and catalytic curing agent.
4. according to claims 1 to 3 any one of them ceramic surface material, which is characterized in that the granularity of the filler is 50
~900nm.
5. ceramic surface material according to claim 2, which is characterized in that the organosilicon is polysilazane, poly- silicon boron
Azane, polysiloxanes, silicones azane, poly- silicon-carbon alkane, poly- silicon-carbon azane and polyborazine it is one or more when, the poly- silicon
Azane, poly- silicon boron azane, polysiloxanes, silicones azane, poly- silicon-carbon alkane and poly- silicon-carbon azane content independently be 0.5~
70wt%.
6. ceramic surface material according to claim 2, which is characterized in that the organosilicon is polysilazane, poly- silicon boron
Azane, polysiloxanes, silicones azane, poly- silicon-carbon alkane, poly- silicon-carbon azane and polyborazine mixture when, the poly- silicon nitrogen
Alkane, poly- silicon boron azane, polysiloxanes, silicones azane, poly- silicon-carbon alkane and poly- silicon-carbon azane content independently be 0.5~
67wt%.
7. the ceramic surface material according to claim 2 or 6, which is characterized in that the organosilicon of stating is polysilazane, gathers
Silicon boron azane, polysiloxanes, silicones azane, poly- silicon-carbon alkane, poly- silicon-carbon azane and polyborazine mixture when, it is described organic
The content of silicon is 30wt%~60wt%, and the content of the polysilazane is 10wt%~20wt%, the poly- silicon boron azane
Content is 10wt%~20wt%, the polysiloxanes, silicones azane, poly- silicon-carbon alkane, poly- silicon-carbon azane and polyborazine
Content independently is 2wt%~5wt%.
8. ceramic surface material according to claim 1, which is characterized in that the organic solvent is butyl acetate, diformazan
Benzene, n-butyl ether, butyl acetic acid esters, hexahydrotoluene, normal octane and butyl titanate it is one or more when, the second
The content independence of acid butyl ester, dimethylbenzene, n-butyl ether, butyl acetic acid esters, hexahydrotoluene, normal octane and butyl titanate
Ground is 0.5wt%~70wt%.
9. ceramic surface material according to claim 1, which is characterized in that the organic solvent is butyl acetate, diformazan
Benzene, n-butyl ether, butyl acetic acid esters, hexahydrotoluene, normal octane and butyl titanate mixture when, the acetic acid fourth
Ester, dimethylbenzene, n-butyl ether, butyl acetic acid esters, hexahydrotoluene, normal octane and butyl titanate content independently be
0.5wt%~67wt%.
10. ceramic surface material according to claim 3, which is characterized in that the rare earth oxide is cerium oxide, oxidation
When yttrium and lanthana, the content of the cerium oxide, yttrium oxide and lanthana independently is 0.1wt%~2wt%；
The content of the graphite is 0.1wt%~3wt%；The content of the graphene is 0.1wt%~3wt%；
The metal is chromium, nickel, titanium, aluminium and when yttrium, the chromium, nickel, titanium, aluminium and yttrium content independently be 0.1wt%~
20wt%；
The composition silicate be copper picotite, magnesium aluminate spinel, mullite, nepheline, kaolin, kyanite, alumina silicate and
When zirconium silicate, the copper picotite, magnesium aluminate spinel, mullite, nepheline, kaolin, kyanite, alumina silicate and zirconium silicate
Content independently is 0.1wt%~20wt%；
It is described it is nonmetallic be silicon and boron when, the content of the silicon and boron independently is 0.1wt%~20wt%；
When the nonmetallic compound is boron carbide, silicon boride, boron nitride, silicon nitride, silicon carbide and boron oxide, the carbonization
Boron, silicon boride, boron nitride, silicon nitride, silicon carbide and boron oxide content independently be 0.1wt%~20wt%；
When the magnesium-yttrium-transition metal boride is titanium boride, zirconium boride, chromium boride and nickel borides, the titanium boride, zirconium boride, boron
The content for changing chromium and nickel borides independently is 0.1wt%~20wt%；
When the whisker is silicon carbide whisker and silicon nitride crystal whisker, the content of the silicon carbide whisker and silicon nitride crystal whisker is independently
For 0.1wt%~5wt%；
When the transition metal oxide is zirconium oxide, chromium oxide, titanium oxide, molybdenum oxide and niobium oxide, the zirconium oxide, oxidation
Chromium, titanium oxide, molybdenum oxide and niobium oxide content independently be 0.1wt%~20wt%.
11. ceramic surface material according to claim 1, which is characterized in that the rare earth oxide is cerium oxide, oxidation
When yttrium and lanthana, the content of the cerium oxide, yttrium oxide and lanthana independently is 0.3wt%~1.5wt%；
The content of the graphite is 0.2wt%~2wt%；The content of the graphene is 0.2wt%~2wt%；
The metal is chromium, nickel, titanium, aluminium and when yttrium, the chromium, nickel, titanium, aluminium and yttrium content independently be 0.2wt%~
3wt%；
It is described it is nonmetallic be silicon and boron when, the content of the silicon and boron independently is 0.2wt%~3wt%；
The composition silicate be copper picotite, magnesium aluminate spinel, mullite, nepheline, kaolin, kyanite, alumina silicate and
When zirconium silicate, the copper picotite, magnesium aluminate spinel, mullite, nepheline, kaolin, kyanite, alumina silicate and zirconium silicate
Content independently is 0.2wt%~3wt%；
When the nonmetallic compound is boron carbide, silicon boride, boron nitride, silicon nitride, silicon carbide and boron oxide, the carbonization
Boron, silicon boride, boron nitride, silicon nitride, silicon carbide and boron oxide content independently be 0.2wt%~3wt%；
When the magnesium-yttrium-transition metal boride is titanium boride, zirconium boride, chromium boride and nickel borides, the titanium boride, zirconium boride, boron
The content for changing chromium and nickel borides independently is 0.2wt%~3wt%；
When the whisker is silicon carbide whisker and silicon nitride crystal whisker, the content of the silicon carbide whisker and silicon nitride crystal whisker is independently
For 0.2wt%~2wt%；
When the transition metal oxide is zirconium oxide, chromium oxide, titanium oxide, molybdenum oxide and niobium oxide, the zirconium oxide, oxidation
Chromium, titanium oxide, molybdenum oxide and niobium oxide content independently be 0.2wt%~3wt%.
12. a kind of surface coating, including investment precoat and priming paint, which is characterized in that the investment precoat is claim 1~11
Any one of them ceramic surface material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810399271.7A CN108610960B (en) | 2018-04-28 | 2018-04-28 | Ceramic surface material and surface coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810399271.7A CN108610960B (en) | 2018-04-28 | 2018-04-28 | Ceramic surface material and surface coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108610960A true CN108610960A (en) | 2018-10-02 |
| CN108610960B CN108610960B (en) | 2020-05-08 |
Family
ID=63661424
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810399271.7A Active CN108610960B (en) | 2018-04-28 | 2018-04-28 | Ceramic surface material and surface coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108610960B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111892424A (en) * | 2020-07-07 | 2020-11-06 | 航天特种材料及工艺技术研究所 | A wide temperature range anti-ablation coating formed on base material and preparation method thereof |
| CN115851015A (en) * | 2022-12-28 | 2023-03-28 | 常州瑞赛激光技术有限公司 | Hole sealing agent for reducing pores of thermal spraying coating of ceramic anilox roller and preparation method |
| CN116120826A (en) * | 2023-03-28 | 2023-05-16 | 广东中科精纳新材料技术有限公司 | Preparation method of normal-temperature self-drying high-temperature anti-corrosion nano ceramic coating |
| CN118652050A (en) * | 2024-08-20 | 2024-09-17 | 福建省德化县三峰陶瓷有限公司 | Ceramic glaze, handicraft ceramic and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101760057A (en) * | 2009-12-28 | 2010-06-30 | 上海金力泰化工股份有限公司 | Ceramic coating and preparation method thereof and method for preventing cracking of ceramic coating |
| CN105110766A (en) * | 2015-08-28 | 2015-12-02 | 兆山科技（北京）有限公司 | Ceramic paint and application thereof |
| WO2016007612A1 (en) * | 2014-07-08 | 2016-01-14 | Kansas State University Research Foundation | Silicon-based polymer-derived ceramic composites comprising h-bn nanosheets |
-
2018
- 2018-04-28 CN CN201810399271.7A patent/CN108610960B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101760057A (en) * | 2009-12-28 | 2010-06-30 | 上海金力泰化工股份有限公司 | Ceramic coating and preparation method thereof and method for preventing cracking of ceramic coating |
| WO2016007612A1 (en) * | 2014-07-08 | 2016-01-14 | Kansas State University Research Foundation | Silicon-based polymer-derived ceramic composites comprising h-bn nanosheets |
| CN105110766A (en) * | 2015-08-28 | 2015-12-02 | 兆山科技（北京）有限公司 | Ceramic paint and application thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111892424A (en) * | 2020-07-07 | 2020-11-06 | 航天特种材料及工艺技术研究所 | A wide temperature range anti-ablation coating formed on base material and preparation method thereof |
| CN115851015A (en) * | 2022-12-28 | 2023-03-28 | 常州瑞赛激光技术有限公司 | Hole sealing agent for reducing pores of thermal spraying coating of ceramic anilox roller and preparation method |
| CN116120826A (en) * | 2023-03-28 | 2023-05-16 | 广东中科精纳新材料技术有限公司 | Preparation method of normal-temperature self-drying high-temperature anti-corrosion nano ceramic coating |
| CN116120826B (en) * | 2023-03-28 | 2024-01-16 | 广东中科精纳新材料技术有限公司 | Preparation method of normal-temperature self-drying high-temperature anti-corrosion nano ceramic coating |
| CN118652050A (en) * | 2024-08-20 | 2024-09-17 | 福建省德化县三峰陶瓷有限公司 | Ceramic glaze, handicraft ceramic and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108610960B (en) | 2020-05-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108531078A (en) | ceramic surface material and surface coating | |
| CN108587458A (en) | ceramic surface material and surface coating | |
| CN108641594A (en) | ceramic surface material and surface coating | |
| CN108485516A (en) | ceramic surface material and surface coating | |
| CN103725074B (en) | A kind of high temperature resistant heat insulation coating and its preparation method and application | |
| CN108610960A (en) | ceramic surface material and surface coating | |
| CN102585571B (en) | Infrared energy-saving coating with anti-corrosion and anti-coking functions and preparation method thereof | |
| CN102992813B (en) | High-temperature glaze coating, preparation method thereof, binder and using method of coating | |
| CN105152630B (en) | Ceramic paint and application thereof | |
| CN103589201A (en) | High-emissivity infrared energy-saving radiation paint and preparation method thereof | |
| CN102417356B (en) | Nano silicon carbide series infrared radiation paint and its preparation method | |
| CN105110766B (en) | Ceramic paint and application thereof | |
| CN102815951A (en) | Flame-resistant corrosion-resistant coating | |
| CN115160835B (en) | A micro-nano multi-scale anti-coking anti-wear coating, composite material and preparation method thereof | |
| CN109897532A (en) | A kind of graphene coating material and preparation method thereof protected in advance for four main tubes of boiler high temperature corrosion | |
| CN104987032A (en) | Fouling and slagging resistance and high temperature and corrosion resistance ceramic paint and preparation and usage method thereof | |
| CN108774462A (en) | A kind of room curing and high temperature resistant anticorrosive paint and preparation method thereof | |
| CN109265181A (en) | Boiler water wall high-temperature anticorrosion dirt-resistant Anti-slagging ceramic coating | |
| CN1235990C (en) | High-temperature far infrared paint and preparing method thereof | |
| CN104710183B (en) | Quick-drying iron runner castable as well as preparation method ad use method thereof | |
| CN105330159B (en) | A kind of glaze and its processing method of coke oven door liner tile | |
| CN106752132A (en) | High heat conduction anticorrosion ceramic coating for metallic recuperator and its preparation method and application | |
| CN114196238A (en) | Anti-coking coating and preparation process thereof | |
| CN102030564A (en) | Composite material of light mullite brick and silicon carbide coating and production method of composite material | |
| CN112939618A (en) | Anti-skinning zircon-based alkali-resistant brick for cement kiln and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP02 | Change in the address of a patent holder |
Address after: Room 174, 1st Floor, Building 24, No. 99 Beigao Road, Shunyi District, Beijing, 101300 Patentee after: ZHAOSHAN TECHNOLOGY (BEIJING) CO.,LTD. Address before: 101399 164 jinmayuan 2nd Street, Gaoliying Town, Shunyi District, Beijing Patentee before: ZHAOSHAN TECHNOLOGY (BEIJING) CO.,LTD. |
|
| CP02 | Change in the address of a patent holder |