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CN108570243A - A kind of fiberglass regrown material multiple tube and preparation method thereof - Google Patents

A kind of fiberglass regrown material multiple tube and preparation method thereof Download PDF

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Publication number
CN108570243A
CN108570243A CN201810319643.0A CN201810319643A CN108570243A CN 108570243 A CN108570243 A CN 108570243A CN 201810319643 A CN201810319643 A CN 201810319643A CN 108570243 A CN108570243 A CN 108570243A
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CN
China
Prior art keywords
fiberglass
multiple tube
weight
resin
additive amount
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810319643.0A
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Chinese (zh)
Inventor
何英平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangzhou Hua Ying Anticorrosion Equipment Co Ltd
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Guangzhou Hua Ying Anticorrosion Equipment Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangzhou Hua Ying Anticorrosion Equipment Co Ltd filed Critical Guangzhou Hua Ying Anticorrosion Equipment Co Ltd
Priority to CN201810319643.0A priority Critical patent/CN108570243A/en
Publication of CN108570243A publication Critical patent/CN108570243A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00Compositions of unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/005Additives being defined by their particle size in general
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/20Recycled plastic

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)
  • Revetment (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of fiberglass regrown material multiple tubes and preparation method thereof, include the raw material of following parts by weight:Resin 10 20, rubble 23 30, quartz sand or river sand 25 30, fiberglass granular wastes and/or fiberglass powder scrap 10 40, additive amount is 1 3% curing agent of weight resin, and additive amount is 1 3% accelerating agent of weight resin, and additive amount is 2 8% colorant of weight resin.The present invention provides a kind of using fiberglass granular wastes or fiberglass powder scrap as one of the raw material for preparing multiple tube, and economy, has excellent performance, is convenient for production environmental protection.

Description

A kind of fiberglass regrown material multiple tube and preparation method thereof
Technical field
The invention belongs to concrete duct Material Fields, and in particular to a kind of fiberglass regrown material multiple tube and its preparation Method.
Background technology
It is reduced increasingly in natural resources and energy today relatively in short supply, the recycling of resource has special meaning Justice.In decades, fiberglass is widely used to all trades and professions with many excellent characteristics such as its high-strength light, corrosion-resistant, but The leftover pieces and old glass generated in the increase of China's application time and the continuous growth of yield, production process with fiberglass The amount of glass steel part the like waste gradually increases, in addition fiberglass is corrosion-resistant, is not easy weathering, its waste is most at present As the processing of building waste goods consumer waste filling and embedding, foreign countries also have using the method burned or crack processing, mostly have to environment There is larger pollution.Therefore, remove to prepare some value products as solution glass using glass fibre reinforced plastic waste as a kind of raw material The cycling and reutilization problem of glass steel waste is a direction for being worth research.
The pipeline that the country uses at present is all made of generally the materials such as cement, cast iron, PVC, but these materials are generally deposited It is poor in corrosion resistance, and crushing resistance and insufficient strength, make the lost of life of pipeline, not only not environmentally, and also it is uneconomical, it can be more Ground wasting manpower and material resources.Therefore, research and develop it is a kind of being resistant to burn into pipeline not easy to crack, extend pipeline life, reduce at This, reduces and replaces number, have great importance for energy conservation and environmental protection.
Invention content
The present invention provides cost-effective one kind, energy conservation and environmental protection, property to solve one of problem above in the prior art Energy fiberglass regrown material multiple tube and preparation method thereof excellent, convenient for production.
To achieve the above object, the present invention provides a kind of fiberglass regrown material multiple tube, includes the original of following parts by weight Material:Resin 10-20, rubble 23-30, quartz sand or river sand 25-30, fiberglass granular wastes and/or fiberglass powder scrap 10- 40, additive amount is the curing agent of the 1-3% of the weight resin, and additive amount is the accelerating agent of the 1-3% of the weight resin, is added Dosage is the colorant of the 2-8% of the weight resin.
Preferably, the resin is adjacent benzene-type resin.
Preferably, the curing agent is methyl ethyl ketone peroxide.
Preferably, the accelerating agent is cobalt water or benzene.
Preferably, the ballast grain sizes are 2-6 mesh.
Preferably, the quartz sand or river sand grain size are 20-80 mesh.
Preferably, the grain size of the fiberglass granular wastes is 200-300 mesh, and the grain size of the fiberglass powder scrap is 300-400 mesh.
Preferably, the raw material of the multiple tube is following parts by weight:The resin 16, the rubble 26, the quartz sand Or the river sand 27, the fiberglass granular wastes and/or the fiberglass powder scrap 37.
Preferably, the additive amount of the curing agent is the 2% of the weight resin, and the additive amount of the accelerating agent is described The 2% of weight resin, the additive amount of the colorant are the 5% of the weight resin.
In addition, also providing a kind of preparation method of above-mentioned fiberglass regrown material multiple tube, include the following steps:
(1) releasing agent is coated in the mold of the multiple tube;
(2) raw material Centrifugal rolling motivation is put by its corresponding parts by weight respectively uniformly to be mixed;
(3) start Centrifugal rolling motivation, run 5-15 minutes, the Centrifugal rolling motivation stops operating;
(4) it demoulds, takes out the multiple tube for preparing and completing, and the multiple tube is placed in shaping platform sizing.
Compared with prior art, the present invention has the following technical effects:
The present invention provides a kind of fiberglass regrown material multiple tubes and preparation method thereof, and preparation method is simple for this, Cost is relatively low, using the mixing such as fiberglass granular wastes or fiberglass powder scrap as one of the raw material for preparing multiple tube, becomes Waste be changed into values, alleviates the pollution problem of environment, environmentally protective, improves resource utilization, and reduces production cost, increases enterprise Benefit;Preparation section is simple and efficient, and the multiple tube uniform color prepared, inner surface is smooth, and service life is long, hardness Greatly, resistance to compression degree is strong, and comprehensive performance is good.
Specific implementation mode
With reference to embodiment, the present invention is described in further detail, and embodiments of the present invention are not limited thereto. The method is conventional method unless otherwise instructed, and the raw material can obtain unless otherwise instructed from open commercial sources. Following embodiment is in parts by mass.
Embodiment 1
A kind of fiberglass regrown material multiple tube, includes the raw material of following parts by weight:Resin 10-20, rubble 23-30, stone Sand or river sand 25-30, origin source widely recycle the broken fiberglass granular wastes and/or glass being prepared of discarded glass comminuted steel shot Glass powdered steel waste material 10-40, additive amount are the curing agent of the 1-3% of the weight resin, and additive amount is the weight resin The accelerating agent of 1-3%, additive amount are the colorant of the 2-8% of the weight resin.The preferably adjacent benzene-type resin of the resin, it is described solid The preferred methyl ethyl ketone peroxide of agent, the preferred cobalt water of the accelerating agent or benzene, the preferred 2-6 mesh of ballast grain sizes, the quartz sand Or the preferred 20-80 mesh of river sand grain size, the grain size of the fiberglass granular wastes is preferably 200-300 mesh, the glass powdered steel The preferred 300-400 mesh of grain size of waste material.Wherein, the grain size of fiberglass granular wastes and fiberglass powder scrap also has suitable big It is small, i.e., the size of particle and powder cannot too greatly can not be too small, when the fiberglass granular wastes and/or glass powdered steel are useless When the grain size of material is 200-400 mesh, it can ensure that the fully dispersed of fiberglass granular wastes and/or fiberglass powder scrap and protect Hold enough viscosity.
In addition, a kind of preparation method of above-mentioned fiberglass regrown material multiple tube is provided in another embodiment, including Following steps:
(1) releasing agent is coated in the mold of the multiple tube;
(2) raw material Centrifugal rolling motivation is put by its corresponding parts by weight respectively uniformly to be mixed;
(3) start Centrifugal rolling motivation, run 5-15 minutes, the Centrifugal rolling motivation stops operating;
(4) it demoulds, takes out the multiple tube for preparing and completing, and the multiple tube is placed in shaping platform sizing.
Wherein, the raw material of different type and grain size can be sufficiently mixed by handling the raw material using Centrifugal rolling motivation so that Whole preparation process is efficient and excellent product quality.The fiberglass granular wastes or the fiberglass powder scrap are that will report Gained after useless or discarded glass fiber reinforced plastics product is broken.
Embodiment 2
On the basis of embodiment 1, the preferred embodiment of fiberglass regrown material multiple tube of the present invention, including following weight The raw material of part:The resin 16, the rubble 26, the quartz sand or the river sand 27, the fiberglass granular wastes and institute State fiberglass powder scrap 37, wherein grain size is fiberglass granular wastes described in 200-300 purposes and grain size is 300-400 mesh The fiberglass powder scrap ratio be 3:7, the additive amount of the curing agent is the 2% of the weight resin, the promotion The additive amount of agent is the 2% of the weight resin, and the additive amount of the colorant is the 5% of the weight resin.
Using the preparation method in embodiment 1, fiberglass regeneration can be prepared with the composition of raw materials described in the present embodiment 2 Material cladding pipe, wherein in the preparation method step 3, the Centrifugal rolling motivation is run 10 minutes, the fiberglass of gained The performance test results of regrown material multiple tube are as follows:
Embodiment 3
On the basis of embodiment 1, the preferred embodiment of fiberglass regrown material multiple tube of the present invention, including following weight The raw material of part:The resin 10, the rubble 23, the quartz sand or the river sand 25, the fiberglass granular wastes or institute Fiberglass powder scrap 40 is stated, the additive amount of the curing agent is the 3% of the weight resin, and the additive amount of the accelerating agent is The 3% of the weight resin, the additive amount of the colorant are the 8% of the weight resin.
Using the preparation method in embodiment 1, fiberglass regeneration can be prepared with the composition of raw materials described in the present embodiment 3 Material cladding pipe, wherein in the preparation method step 3, the Centrifugal rolling motivation is run 8 minutes, and the fiberglass of gained is again The performance test results of green material multiple tube are as follows:
Embodiment 4
On the basis of embodiment 1, the preferred embodiment of fiberglass regrown material multiple tube of the present invention, including following weight The raw material of part:The resin 15, the rubble 26, the quartz sand or the river sand 28, the fiberglass granular wastes or institute Fiberglass powder scrap 32 is stated, the additive amount of the curing agent is the 1.5% of the weight resin, the additive amount of the accelerating agent It is the 1.5% of the weight resin, the additive amount of the colorant is the 5% of the weight resin.
Using the preparation method in embodiment 1, fiberglass regeneration can be prepared with the composition of raw materials described in the present embodiment 4 Material cladding pipe, wherein in the preparation method step 3, the Centrifugal rolling motivation is run 13 minutes, the fiberglass of gained The performance test results of regrown material multiple tube are as follows:
Embodiment 5
On the basis of embodiment 1, the preferred embodiment of fiberglass regrown material multiple tube of the present invention, including following weight The raw material of part:The resin 20, the rubble 27, the quartz sand or the river sand 28, the fiberglass granular wastes or institute Fiberglass powder scrap 32 is stated, the additive amount of the curing agent is the 2% of the weight resin, and the additive amount of the accelerating agent is The 2% of the weight resin, the additive amount of the colorant are the 7% of the weight resin.
Using the preparation method in embodiment 1, fiberglass regeneration can be prepared with the composition of raw materials described in the present embodiment 5 Material cladding pipe, wherein in the preparation method step 3, the Centrifugal rolling motivation is run 15 minutes, the fiberglass of gained The performance test results of regrown material multiple tube are as follows:
By embodiment 1-5, the multiple tube that the present invention is prepared using the raw material of different weight number is surveyed by relevant criterion Examination it is found that the raw material using different weight number carries out mixture prepared final multiple tube by ratio from low to high, Preferable resistance to compression, bending resistance, tension, shearing resistance, anti-impact, freeze proof and chemical-resistance are all had, wherein preparation-obtained final Multiple tube all has uniform color, the influential cracking of no performance, layering, pin hole, flash, burr, depainting or defect, interior The good appearance properties such as surface is smooth, i.e. formula of the invention and preparation method have preferable universality;Wherein, real It is most highly preferred embodiment of the invention to apply example 2, and every test performance of prepared multiple tube is optimal.
In addition, the present invention is described multiple as preparing using the mixing such as fiberglass granular wastes and/or fiberglass powder scrap One of the raw material for closing pipe, not only saves raw material, also solves the recycling of fiberglass granular wastes and fiberglass powder scrap Process problem makes important contribution for environmental protection and energy saving.
It should be noted that embodiment described above is only used for explaining the present invention, do not constitute to any of the present invention Limitation.If the spirit and scope of the present invention are not departed to the various changes or modifications of the present invention, if these modification and variations Belong within the scope of the claim and equivalent technologies of the present invention, then the present invention is also intended to include these modification and variations.

Claims (10)

1. a kind of fiberglass regrown material multiple tube, which is characterized in that include the raw material of following parts by weight:Resin 10-20, rubble 23-30, quartz sand or river sand 25-30, fiberglass granular wastes and/or fiberglass powder scrap 10-40, additive amount are the tree The curing agent of the 1-3% of fat weight, additive amount are the accelerating agent of the 1-3% of the weight resin, and additive amount is the resin weight The colorant of the 2-8% of amount.
2. fiberglass regrown material multiple tube according to claim 1, which is characterized in that the resin is adjacent benzene-type tree Fat.
3. fiberglass regrown material multiple tube according to claim 1, which is characterized in that the curing agent is peroxidating first Ethyl ketone.
4. fiberglass regrown material multiple tube according to claim 1, which is characterized in that the accelerating agent be cobalt water or Benzene.
5. fiberglass regrown material multiple tube according to claim 1, which is characterized in that the ballast grain sizes are 2-6 mesh.
6. fiberglass regrown material multiple tube according to claim 1, which is characterized in that the quartz sand or river sand grain size For 20-80 mesh.
7. fiberglass regrown material multiple tube according to claim 1, which is characterized in that the fiberglass granular wastes Grain size is 200-300 mesh, and the grain size of the fiberglass powder scrap is 300-400 mesh.
8. according to claim 1-7 any one of them fiberglass regrown material multiple tubes, which is characterized in that the multiple tube Raw material is following parts by weight:The resin 16, the rubble 26, the quartz sand or the river sand 27, the glass steel particles Waste material and/or the fiberglass powder scrap 37.
9. fiberglass regrown material multiple tube according to claim 8, which is characterized in that the additive amount of the curing agent is The 2% of the weight resin, the additive amount of the accelerating agent are the 2% of the weight resin, and the additive amount of the colorant is institute State the 5% of weight resin.
10. a kind of preparation method according to claim 1-9 any one of them fiberglass regrown material multiple tubes, feature exists In including the following steps:
(1) releasing agent is coated in the mold of the multiple tube;
(2) raw material Centrifugal rolling motivation is put by its corresponding parts by weight respectively uniformly to be mixed;
(3) start Centrifugal rolling motivation, run 5-15 minutes, the Centrifugal rolling motivation stops operating;
(4) it demoulds, takes out the multiple tube for preparing and completing, and the multiple tube is placed in shaping platform sizing.
CN201810319643.0A 2018-04-11 2018-04-11 A kind of fiberglass regrown material multiple tube and preparation method thereof Pending CN108570243A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810319643.0A CN108570243A (en) 2018-04-11 2018-04-11 A kind of fiberglass regrown material multiple tube and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201810319643.0A CN108570243A (en) 2018-04-11 2018-04-11 A kind of fiberglass regrown material multiple tube and preparation method thereof

Publications (1)

Publication Number Publication Date
CN108570243A true CN108570243A (en) 2018-09-25

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0593449A1 (en) * 1989-11-29 1994-04-27 Wavin Bv Plastic pipe with a wall made up of a plastic-filler layer.
JPH08159367A (en) * 1994-12-12 1996-06-21 Sekisui Chem Co Ltd Pipe reclaiming member, and stain-proofing method of conduit by this pipe reclaiming member
CN2288333Y (en) * 1997-06-20 1998-08-19 上海电力学院 Composite pipeline of ultra-high molecular weight polyethylene and glass fibre reinforced plastics
CN101148337A (en) * 2007-11-12 2008-03-26 石家庄市银杏砂制品有限公司 Drainage system pipe and manufacturing method thereof
CN202674571U (en) * 2012-05-26 2013-01-16 大庆中浮石油技术开发有限公司 Environment-friendly high-strength glass reinforced plastic sand pipe
CN103591393A (en) * 2013-11-13 2014-02-19 武汉理工大学 Glass fiber reinforced plastic prestressed concrete cylinder pipe (PCCP) and manufacturing method thereof
CN205842005U (en) * 2016-08-04 2016-12-28 广州市双时复合材料有限公司 A kind of glass reinforced plastic pipe
CN107599273A (en) * 2017-09-13 2018-01-19 山东省呈祥电工电气有限公司 Enhancing by polymer Prestressed concrete cylinder pipe road moulding process

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0593449A1 (en) * 1989-11-29 1994-04-27 Wavin Bv Plastic pipe with a wall made up of a plastic-filler layer.
JPH08159367A (en) * 1994-12-12 1996-06-21 Sekisui Chem Co Ltd Pipe reclaiming member, and stain-proofing method of conduit by this pipe reclaiming member
CN2288333Y (en) * 1997-06-20 1998-08-19 上海电力学院 Composite pipeline of ultra-high molecular weight polyethylene and glass fibre reinforced plastics
CN101148337A (en) * 2007-11-12 2008-03-26 石家庄市银杏砂制品有限公司 Drainage system pipe and manufacturing method thereof
CN202674571U (en) * 2012-05-26 2013-01-16 大庆中浮石油技术开发有限公司 Environment-friendly high-strength glass reinforced plastic sand pipe
CN103591393A (en) * 2013-11-13 2014-02-19 武汉理工大学 Glass fiber reinforced plastic prestressed concrete cylinder pipe (PCCP) and manufacturing method thereof
CN205842005U (en) * 2016-08-04 2016-12-28 广州市双时复合材料有限公司 A kind of glass reinforced plastic pipe
CN107599273A (en) * 2017-09-13 2018-01-19 山东省呈祥电工电气有限公司 Enhancing by polymer Prestressed concrete cylinder pipe road moulding process

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Application publication date: 20180925