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CN108560264B - Clothing care solution and application thereof - Google Patents

Clothing care solution and application thereof Download PDF

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Publication number
CN108560264B
CN108560264B CN201810179666.6A CN201810179666A CN108560264B CN 108560264 B CN108560264 B CN 108560264B CN 201810179666 A CN201810179666 A CN 201810179666A CN 108560264 B CN108560264 B CN 108560264B
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care solution
surfactant
clothes
clothing
ammonium chloride
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CN108560264A (en
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石荣莹
徐秋梅
王小淳
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Shanghai Hutchison Whitecat Co ltd
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Shanghai Hutchison Whitecat Co ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/11—Compounds containing epoxy groups or precursors thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention belongs to the technical field of daily chemicals, and particularly relates to a clothes care solution. The clothes care solution provided by the invention comprises components such as a surfactant, an odor neutralizer, a preservative and the like, the components are uniformly mixed with water under the action of an organic solvent, and functional components of the clothes care solution such as the surfactant, the odor neutralizer, the preservative and the like enter clothes fibers through high-temperature atomization of the water, so that the antistatic property and the stiffness and smoothness of the clothes are improved. The example results show that after the clothes are treated by the clothes care solution in the scheme for 1 day, the clothes are good in stiffness, and the antistatic performance of the clothes reaches an excellent level.

Description

Clothing care solution and application thereof
Technical Field
The invention belongs to the technical field of daily chemicals, and particularly relates to a clothes care solution and application thereof.
Background
With the development of society, the requirement of people on daily wearing is continuously improved, people want to wear the clothes comfortably both in work occasions and daily social activities, once the clothes are charged with static electricity, the clothes are tightly attached to the human body, the attractiveness of the clothes is affected, and wearers feel uncomfortable. In order to eliminate static electricity, people add the laundry detergent with the antistatic effect when washing clothes, but after the antistatic laundry detergent is used, the stiffness of the clothes is not obviously improved, and the clothes still have static electricity after being worn.
Disclosure of Invention
In order to solve the problems, the invention provides the clothing care solution, and after the clothing is treated by the clothing care solution, the clothing stiffness can be improved, and the antistatic performance of the clothing can be improved.
In order to achieve the purpose, the invention provides a clothes care solution which comprises, by mass, 0.01-1% of a surfactant, 0.01-1% of an odor neutralizer, 0.001-1% of a preservative, 0.01-1% of an alkaline regulator, 0.5-10% of an organic solvent and the balance of water;
the surfactants include a first surfactant including a nonionic surfactant and a second surfactant including a cationic surfactant and/or an amphoteric surfactant.
Preferably, the mass ratio of the first surfactant to the second surfactant is 1: 5 to 10.
Preferably, the nonionic surfactant comprises one or more of fatty alcohol-polyoxyethylene ether, gemini quaternary ammonium salt, alkyl glycoside and cashew-based glucamide.
Preferably, the cationic surfactant comprises one or more of dialkyl dimethyl ammonium chloride, dodecyl trimethyl ammonium chloride and tetradecyl trimethyl ammonium chloride, and the number of carbons of two alkyl groups in the dialkyl dimethyl ammonium chloride is independently C8-C12;
the amphoteric surfactant comprises one or two of betaine and imidazoline.
Preferably, the off-flavour neutralising agent comprises cyclodextrin and/or zinc ricinoleate.
Preferably, the preservative comprises one or more of 1, 2-benzisothiazol-3-one, methylisothiazolinone, and 1, 3-dimethylol-5, 5-dimethylhydantoin.
Preferably, the alkaline modifier comprises an alcamines compound.
Preferably, the organic solvent includes an alcohol solvent and/or an ether solvent.
Preferably, the clothing care solution further comprises 0.05-0.1% of essence by mass percentage.
The invention also provides application of the clothing care solution in the technical scheme as an ironing agent or a fumigant.
The invention provides a clothing care solution which comprises 0.01 percent of1% of surfactant, 0.01-1% of odor neutralizer, 0.001-1% of preservative, 0.01-1% of alkaline regulator, 0.5-10% of organic solvent and the balance of water; wherein the surfactant comprises a first surfactant and a second surfactant, the first surfactant comprises a nonionic surfactant, and the second surfactant comprises a cationic surfactant and/or an amphoteric surfactant. In the invention, the surfactant, the odor neutralizer and the preservative are respectively components with antistatic, odor removing and preservative functions. When the garment care solution is applied as a fumigant or an ironing agent, the garment care solution is atomized at high temperature, functional components in the garment care solution are added into fibers of the garment, and the second surfactant can be better adsorbed on the fibers of the garment under the action of the first surfactant, neutralize negative charges on the garment, improve the antistatic performance of the garment, and enable the garment to be smooth and wrinkle-removed. The results of the examples show that after the clothes are treated by the clothes care solution according to the above scheme of the invention for 1 day, the treated clothes have good stiffness, and the resistance of the clothes is still maintained at 4.0 x 106～6.0×107Omega, the conductivity is good, which shows that the antistatic performance of the clothes is extremely excellent.
Drawings
FIG. 1 is a graph showing the effect of the clothes ironed with water according to comparative example 1;
fig. 2 is a graph showing the effect of the clothes ironed by the clothes care solution in example 1.
Detailed Description
The invention provides a clothes care solution which comprises, by mass, 0.01-1% of a surfactant, 0.01-1% of an odor neutralizer, 0.001-1% of a preservative, 0.01-1% of an alkaline regulator, 0.5-10% of an organic solvent and the balance of water;
the surfactants include a first surfactant including a nonionic surfactant and a second surfactant including a cationic surfactant and/or an amphoteric surfactant.
Unless otherwise specified, the various agents for the laundry care solution according to the invention are commercially available products known to the person skilled in the art.
The clothing care solution provided by the invention comprises 0.01-1% of surfactant by mass percentage, and preferably 0.2-0.8%. In the present invention, the surfactant includes a first surfactant and a second surfactant, and the mass ratio of the first surfactant to the second surfactant is preferably 1: 5-10, more preferably 1: 6 to 7.
In the present invention, the first surfactant includes a nonionic surfactant. In the present invention, the nonionic surfactant preferably includes one or more of fatty alcohol polyoxyethylene ether, Gemini quaternary ammonium salt (hereinafter, referred to as Gemini surfactant), alkyl glycoside (hereinafter, referred to as APG), and cashew-based glucamide, and more preferably one or more of fatty alcohol polyoxyethylene ether, Gemini surfactant, and APG. In the invention, the fatty alcohol-polyoxyethylene ether comprises fatty alcohol-polyoxyethylene (7) ether and/or fatty alcohol-polyoxyethylene (9) ether. In the present invention, when the nonionic surfactant is a mixture of a plurality of components, the present invention has no particular requirement on the mass ratio of the components in the mixture.
In the present invention, the second surfactant includes a cationic surfactant and/or an amphoteric surfactant. In the present invention, when the second surfactant is a mixture of a cationic surfactant and an amphoteric surfactant, the present invention has no particular requirement on the mass ratio of the components in the mixture.
In the present invention, the cationic surfactant preferably includes one or more of dialkyl dimethyl ammonium chloride, dodecyl trimethyl ammonium chloride and tetradecyl trimethyl ammonium chloride, and more preferably dialkyl dimethyl ammonium chloride, dodecyl trimethyl ammonium chloride or tetradecyl trimethyl ammonium chloride. In the present invention, the number of carbons of the two alkyl groups in the dialkyldimethylammonium chloride is preferably from C8 to C12, and more preferably from C9 to C10. In the present invention, when the cationic surfactant is a mixture of a plurality of components, the present invention does not require a specific mass ratio of each component in the mixture, and it is sufficient to adopt a method well known to those skilled in the art.
In the present invention, the amphoteric surfactant preferably includes a betaine-type amphoteric surfactant and/or an amine oxide-type amphoteric surfactant. In the present invention, the betaine-type amphoteric surfactant is preferably alkyldimethyl betaine and/or cocamidopropyl betaine, and is more preferably cocamidopropyl betaine. The alkyl group of the alkyldimethyl betaines is not particularly required in the present invention and those well known to those skilled in the art can be used. In the present invention, the type of the amine oxide-based amphoteric surfactant is preferably an alkyldimethylamine oxide and/or a cocamidopropyl amine oxide, and more preferably a cocamidopropyl amine oxide. In the present invention, when the amphoteric surfactant is a mixture of a plurality of components, the present invention has no particular requirement on the mass ratio of the components in the mixture.
The invention takes the nonionic surfactant with wetting and emulsifying properties as the first surfactant, takes the cationic surfactant and/or the amphoteric surfactant as the second surfactant, and the second surfactant can be better adsorbed on the surface of the fiber of the clothes under the action of the first surfactant, and the first surfactant and the second surfactant have synergistic effect, so that the invention not only can neutralize the charge, but also can remove wrinkles, and further can make the clothes soft, smooth and antistatic.
The clothing care solution provided by the invention comprises 0.01-1% of odor neutralizer by mass percentage, and preferably 0.1-0.8%. In the present invention, the odor neutralizer preferably comprises cyclodextrin and/or zinc ricinoleate, and more preferably cyclodextrin or zinc ricinoleate. When the odor neutralizer is a mixture of two components, the invention has no special requirement on the mass ratio of the components in the mixture. The odor neutralizing agent can eliminate odor penetrating through clothes or being placed on the clothes for a long time.
The clothing care solution provided by the invention comprises 0.001-1% of preservative by mass percentage, and is further preferably 0.002-0.005%. In the present invention, the preservative preferably includes one or more of 1, 2-benzisothiazol-3-one (hereinafter, referred to as BIT), methylisothiazolinone (hereinafter, referred to as MIT), and 1, 3-dimethylol-5, 5-dimethylhydantoin (hereinafter, referred to as DMDMH), and more preferably BIT, MIT, or DMDMH. When the preservative is a mixture, the invention has no special requirement on the mass ratio of each component in the mixture. The addition of the preservative can ensure the long-term storage stability of the clothes care solution. In the invention, the shelf life of the clothes care solution at room temperature can reach 36 months.
The clothing care solution comprises 0.01-1% of alkaline regulator by mass percentage, and the preferable content is 0.01-0.05%. In the present invention, the alkaline modifier preferably includes an alcohol amine compound. In the present invention, the alkanolamine compound is preferably diethanolamine and/or triethanolamine, and more preferably diethanolamine or triethanolamine. When the alkaline regulator is a mixture, the invention has no special requirement on the mass ratio of each component in the mixture. According to the invention, the pH value of the clothing care solution is adjusted to be alkalescent of 7.5-9 by using the alkaline regulator, so that the cleaning performance of the clothing care solution can be further improved. In the invention, the clothes care solution can have a good effect of removing floating and sinking stains on clothes.
The clothing care solution comprises 0.5-10% of organic solvent by mass percentage, and the preferred content is 3-5%. In the present invention, the organic solvent preferably includes an alcohol solvent and/or an ether solvent. In the invention, the alcohol solvent preferably comprises one or more of ethanol, propanol, isopropanol, ethylene glycol and 1, 3-propylene glycol, and further preferably ethanol or propanol; the ether solvent preferably includes butyl glycol ether and/or butyl diethylene glycol ether, and more preferably butyl glycol ether. When the organic solvent is a mixture, the invention has no special requirement on the mass ratio of each component in the mixture. The invention uses organic solvent, which can fully dissolve each functional component in the clothing care solution, thereby ensuring the stability of the performance and the appearance of the clothing care solution.
The clothing care solution disclosed by the invention preferably further comprises 0.05-0.1% of essence by mass percentage, and more preferably 0.05-0.08% of essence by mass percentage. In the present invention, the essence preferably comprises one or more of flower fragrance, fruit fragrance, aldehyde fragrance and costus root. When the essence is a mixture of several components, the invention has no special requirements on the mass ratio of the components in the mixture. In the invention, the essence can improve the smell of clothes and give a fragrant and pleasant feeling to a wearer.
The clothing care solution also comprises the balance of water. In the invention, the clothing care solution contains a large amount of water, on one hand, functional components in the clothing care solution can be fully dissolved, and on the other hand, the water is used as a medium, so that the functional components in the clothing care solution can enter clothing fibers, and a foundation is provided for the exertion of the effects of static resistance, wrinkle removal, odor neutralization and the like of the clothing care solution.
In the present invention, the preparation method of the laundry care solution is not particularly limited, and the components are mixed by a method for preparing the composition well known to those skilled in the art; preferably, the method comprises the step of mixing the components of the clothes care solution in the technical scheme to obtain the clothes care solution. The present invention does not require special means for such mixing, as would be known to one skilled in the art. In the present invention, the mixing preferably comprises the steps of: and sequentially mixing the surfactant, the organic solvent, the odor neutralizer and the preservative with water at room temperature, then adding the alkaline regulator, and uniformly mixing to obtain the clothes care solution. In the present invention, the mixing is preferably performed under stirring conditions. The invention has no special requirements on the specific implementation mode of stirring, and can realize uniform mixing of all components.
The invention also provides application of the clothing care solution in the technical scheme as an ironing agent or a fumigant. In the invention, when the clothing care solution is used as an ironing agent, the clothing care agent is preferably added into an ironing device to iron clothing to be treated. In the present invention, the ironing device comprises, but is not limited to, a steam iron or a garment steamer. In the present invention, when the laundry care solution is used as an ironing agent, the ironing condition is preferably steam ironing. The present invention does not require special embodiments for said ironing, as is well known to the person skilled in the art.
In the present invention, when the laundry care solution is used as a fumigant, the laundry care solution is preferably added to a fumigation apparatus to fumigate laundry to be treated. The invention has no special requirements on the fumigation equipment, and the fumigation equipment is well known to those skilled in the art. In the present invention, when the laundry care solution is used as a fumigant, the fumigation condition is preferably steam fumigation. The present invention does not require special embodiments of the fumigation, as will be appreciated by those skilled in the art.
The clothes care solution can be used for treating clothes and comprises cotton, hemp, silk, wool, synthetic fibers or blended fabrics. When the clothing care solution is used for treating clothing made of different materials, the clothing care solution has no special requirements on the treatment mode of the clothing made of different materials, and the clothing care solution is prepared by adopting the method well known by the technical personnel in the field.
In order to further illustrate the present invention, the following detailed description of the laundry care solution and its application are provided in conjunction with the accompanying drawings and examples, which should not be construed as limiting the scope of the present invention.
Comparative example 1
The washed clothes which are not stiff and smooth are ironed by a steam iron by using water as a medium, and the ironing result is shown in figure 1. As can be seen from fig. 1, after the clothes are ironed by using water as a medium, the clothes still have a few wrinkles. After the treated clothes are worn, static electricity exists.
Example 1
The components and the dosage of the clothes care solution in the embodiment are shown in table 1, and the preparation method comprises the following steps: the components in table 1 were stirred at room temperature to obtain a clear and transparent laundry care solution having a pH of 8.0.
The clothes care solution of the embodiment is tested according to the standard Q310104000004C 085-2018, and all indexes are qualified.
The method takes the washed stiff and smooth clothes as the treatment objects: the liquid for clothing care obtained in this example was directly put into a steam iron to iron the clothing that was not stiff and smooth after washing, and the ironing result is shown in fig. 2, and as can be seen from fig. 2, after the liquid for clothing care obtained in this example was used to iron the stiff and smooth clothing, the wrinkles of the clothing were completely removed, and the stiffness of the clothing was better.
Comparing the clothes ironed and finished in the comparative example 1 and the example 1, after 10 persons compare, 9 persons believe that after the clothes care solution is adopted, the clothes are obviously stiff and smooth, wrinkles are completely removed, and the satisfaction degree reaches 90%, as shown in table 2.
The clothes which pass through and have peculiar smell are taken as treatment objects: the clothes passing through the garment steamer are ironed by means of the garment steamer, compared with the conventional clothes ironed by using water alone, and compared with 10 people, 9 people think that after the garment care solution is adopted, the clothes are obviously fresh, the peculiar smell on the clothes is completely removed, and the satisfaction degree reaches 90%, as shown in table 3. In the invention, the odor removal effect of the clothes is judged by the sense of smell of 10 testers, and in order to reduce the influence of human factors on the judgment result, the clothes in the comparative example has the same style as the clothes in the example 1, and no mark is made on the clothes.
Compared with the clothes ironed by water alone, the clothes ironed by the clothes care solution obtained in the embodiment are detected whether the stains are left. In comparison with 10 persons, 10 persons considered that no scar remained, and the satisfaction degree reached 100%, as shown in table 4. In the invention, the scar removing effect of the infant clothes is judged by visual perception of 10 testers, and in order to reduce the influence of human factors on the judgment result, the clothes of the comparative example and the clothes of the embodiment 1 have the same style, and no mark is made on the infant clothes.
Taking clothes stuck with floating ash as a treatment object: the garment is ironed by the garment steamer, floating dust on the garment can be removed after ironing, and the garment care solution provided by the embodiment has a good cleaning effect.
The synthetic fiber cloth is taken as a treatment object, and is sprayed according to 0.3 g/square meter, and the antistatic conditions of the fabric before and after treatment for 1 day are respectively tested. The invention adopts the method of GB1410-2006 to detect the surface resistance of the clothes to reflect the quality of the antistatic property of the clothesThe larger the surface resistance value of the clothes is, the poorer the antistatic performance is, and on the contrary, the antistatic performance is better. According to Wilson's theory, Rs>1013Is poor in antistatic property; 1012<Rs<1013Is antistatic; 1011<Rs<1012Good antistatic property; 1010<Rs<1011The antistatic property is excellent; rs (Rs)<1010Is particularly excellent in antistatic property (unit: omega). The test results are shown in Table 5.
Example 2
The components and the amounts of the clothes care solution of the embodiment are shown in table 1. The preparation method comprises the following steps: adding deionized water into a preparation cylinder, sequentially adding a nonionic surfactant, stirring uniformly at room temperature, adding a cationic surfactant, an amphoteric surfactant and a solvent, continuously stirring uniformly, adding cyclodextrin or zinc ricinoleate, a preservative and essence, finally adding triethanolamine, and adjusting the pH value of the clothes care solution to 7.8 to obtain the clear and transparent clothes care solution with certain fragrance.
The performance of the clothes care solution provided by the embodiment is detected according to the standard Q310104000004C 085-2018, and the result shows that the clothes care solution is qualified.
The using effect of the clothing care solution obtained in the embodiment is tested according to the method of the embodiment 1, the test result is the same as the embodiment 1, and the clothing ironed by the clothing care solution is stiff and smooth, has no wrinkles, has fragrant and pleasant smell and has no scar residues. The statistical results of the satisfaction of the testers are shown in tables 2-4 respectively. The results of the antistatic effect test are shown in Table 5.
Example 3
The components and the amounts of the clothes care solution of the embodiment are shown in table 1. The preparation method is the same as that in example 2, except that the pH of the obtained care solution is 7.80, and all indexes of the clothes care solution obtained in the embodiment all meet the standard Q310104000004C 085-2018.
The using effect of the clothing care solution obtained in the embodiment is tested according to the method of the embodiment 1, the test result is the same as the embodiment 1, and the clothing ironed by the clothing care solution is stiff and smooth, has no wrinkles, has fragrant and pleasant smell and has no scar residues. The statistical results of the satisfaction of the testers are shown in tables 2-4 respectively. The results of the antistatic effect test are shown in Table 5.
Example 4
The components and the amounts of the clothes care solution of the embodiment are shown in table 1. The preparation method is the same as that in example 2, except that the pH of the obtained care solution is 8.31, and all indexes of the clothes care solution obtained in the embodiment all meet the standard Q310104000004C 085-2018.
The using effect of the clothing care solution obtained in the embodiment is tested according to the method of the embodiment 1, the test result is the same as the embodiment 1, and the clothing ironed by the clothing care solution is stiff and smooth, has no wrinkles, has fragrant and pleasant smell and has no scar residues. The statistical results of the satisfaction of the testers are shown in tables 2-4 respectively. The results of the antistatic effect test are shown in Table 5.
Example 5
The components and the amounts of the clothes care solution of the embodiment are shown in table 1. The preparation method is the same as that in example 2, except that the pH of the obtained care solution is 8.15, and all indexes of the clothes care solution obtained in the embodiment all meet the standard Q310104000004C 085-2018.
The using effect of the clothing care solution obtained in the embodiment is tested according to the method of the embodiment 1, the test result is the same as the embodiment 1, and the clothing ironed by the clothing care solution is stiff and smooth, has no wrinkles, has fragrant and pleasant smell and has no scar residues. The statistical results of the satisfaction of the testers are shown in tables 2-4 respectively. The results of the antistatic effect test are shown in Table 5.
TABLE 1 examples 1-5 liquid laundry care compositions
Figure BDA0001588387890000081
Figure BDA0001588387890000091
Table 2 examples 1-5 test results of effect of stiff and smooth clothes after ironing by using clothes care solution
Sample(s) Example 1 Example 2 Example 3 Example 4 Example 5
Satisfaction number of people 9 8 7 7 9
As can be seen from table 2, the clothing care solution provided in embodiments 1 to 5 of the present invention is not stiff and smooth after ironing, wrinkles on the clothing can be removed, the ironed clothing is stiff and smooth, and the satisfaction of the test user on the clothing care solution of the present invention can reach 90%.
Table 3 examples 1-5 test results of odor removal effect of clothes care solution
Sample(s) Example 1 Example 2 Example 3 Example 4 Example 5
Satisfaction number of people 9 9 10 10 10
The test results in table 3 show that the clothing care solution provided by the embodiments 1 to 5 of the invention can be used for ironing clothing which passes through temporarily, and has excellent effect of removing peculiar smell of the clothing, and the satisfaction degree is more than 90%;
and the treated clothes have fresh and pleasant fragrance.
Table 4 test results of whether stains are left after clothes are ironed by clothes care solutions in examples 1 to 5
Sample(s) Example 1 Example 2 Example 3 Example 4 Example 5
Satisfaction number of people 10 10 10 10 10
The test results in table 4 show that the clothes care solutions provided in embodiments 1 to 5 of the present invention have no scar residue after ironing clothes, do not affect the appearance of the clothes, and achieve a user satisfaction of 100%.
TABLE 5 results of testing antistatic Properties of comparative example 1 and examples 1 to 5
Figure BDA0001588387890000101
As can be seen from the data in Table 5, after the synthetic fiber fabric is treated by the clothes treating fluid, the fabric still has excellent antistatic performance after being placed for 1 day, and the antistatic performance of the synthetic fiber fabric after being treated by water is not obviously improved.
In conclusion, after the garment care solution provided by the invention is used as an ironing agent or a fumigant to treat the garment, the antistatic performance of the garment can be obviously improved, and the comfort level and the aesthetic degree of a garment wearer are improved.
In addition, compared with pure water, the clothes care solution provided by the invention has an obvious effect of improving the stiffness of clothes after the clothes are treated, can also remove granular stains or floating and sinking on the clothes, has a certain cleaning effect, and is suitable for emergency treatment of the clothes under temporary or sudden conditions.
The clothing care solution provided by the invention is simple in use method, is suitable for families or individuals, and can save cost compared with dry cleaning, so that the clothing care solution has a higher market popularization value.
The foregoing is merely a preferred embodiment of the invention and is not intended to limit the invention in any manner. It should be noted that, for those skilled in the art, without departing from the principle of the present invention, several improvements and modifications can be made, and these improvements and modifications should also be construed as the protection scope of the present invention.

Claims (8)

1. A clothes care solution comprises, by mass, 0.01-1% of a surfactant, 0.01-1% of an odor neutralizer, 0.001-1% of a preservative, 0.01-1% of an alkaline regulator, 0.5-10% of an organic solvent and the balance of water;
the surfactant comprises a first surfactant and a second surfactant, wherein the first surfactant comprises a nonionic surfactant, and the second surfactant comprises a cationic surfactant and/or an amphoteric surfactant;
the nonionic surfactant comprises one or more of fatty alcohol-polyoxyethylene ether, alkyl glycoside and cashew-based glucamide;
the cationic surfactant comprises one or more of dialkyl dimethyl ammonium chloride, dodecyl trimethyl ammonium chloride and tetradecyl trimethyl ammonium chloride, and the number of carbons of two alkyls in the dialkyl dimethyl ammonium chloride is independently C8-C12;
the amphoteric surfactant comprises one or two of betaine and amine oxide.
2. The laundry care solution of claim 1, wherein the mass ratio of the first surfactant to the second surfactant is 1: 5 to 10.
3. The laundry care solution of claim 1, wherein the odor neutralizer comprises cyclodextrin and/or zinc ricinoleate.
4. The garment care solution of claim 1 wherein the preservative comprises one or more of 1, 2-benzisothiazol-3-one, methylisothiazolinone, and 1, 3-dimethylol-5, 5-dimethylhydantoin.
5. The laundry care solution of claim 1, wherein the alkalinity regulator comprises an alcamines compound.
6. The laundry care solution of claim 1, wherein the organic solvent comprises an alcohol solvent and/or an ether solvent.
7. The clothing care solution according to any one of claims 1 to 6, wherein the clothing care solution further comprises 0.05 to 0.1 mass percent of essence.
8. Use of the garment care solution of any one of claims 1 to 7 as an ironing or fumigating agent.
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CN109440467B (en) * 2018-10-11 2021-05-04 苏州市职业大学 Finishing agent for preventing embroidery from fluffing and preparation method and using method thereof
CN109338721A (en) * 2018-10-15 2019-02-15 北京泛博化学股份有限公司 A kind of animal wool azelon modification protection agent and its preparation method and application
CN109777647A (en) * 2019-03-04 2019-05-21 广东欧蝶兰高新科技日用品有限公司 A kind of clothing removes peculiar smell composition
CN113293613B (en) * 2021-04-30 2023-05-26 纳爱斯浙江科技有限公司 Low-foam fabric softening degerming agent and preparation method thereof
CN117661290A (en) * 2022-08-30 2024-03-08 青岛海尔洗衣机有限公司 Control method and control device for removing static electricity from clothing by clothing treatment equipment

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