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CN108514026A - A kind of fresh-cut fruit and vegetable composite preservative and its application method - Google Patents

A kind of fresh-cut fruit and vegetable composite preservative and its application method Download PDF

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CN108514026A
CN108514026A CN201810336655.4A CN201810336655A CN108514026A CN 108514026 A CN108514026 A CN 108514026A CN 201810336655 A CN201810336655 A CN 201810336655A CN 108514026 A CN108514026 A CN 108514026A
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CN108514026B (en
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袁超
崔波
于滨
刘鹏飞
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Qilu University of Technology
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
    • A23B7/00Preservation of fruit or vegetables; Chemical ripening of fruit or vegetables
    • A23B7/14Preserving or ripening with chemicals not covered by group A23B7/08 or A23B7/10
    • A23B7/153Preserving or ripening with chemicals not covered by group A23B7/08 or A23B7/10 in the form of liquids or solids
    • A23B7/154Organic compounds; Microorganisms; Enzymes
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
    • A23B7/00Preservation of fruit or vegetables; Chemical ripening of fruit or vegetables
    • A23B7/16Coating with a protective layer; Compositions or apparatus therefor
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

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Abstract

本发明公开了一种鲜切果蔬复合保鲜剂及其使用方法,属于果蔬加工技术领域。本发明首先采用由抗坏血酸、肉桂精油、β‑环糊精和壳聚糖组成的复合浸泡液对鲜切果蔬进行短时浸泡,晾干后通过魔芋葡甘聚糖和卡拉胶复合凝胶进行喷涂,通过二次复合保鲜工艺对鲜切果蔬进行处理,在果蔬表面形成天然缓释杀菌剂、保水剂和双层保护膜,有效保护鲜切果蔬表面,解决了鲜切果蔬保鲜过程中变质、脱水和氧化等问题。The invention discloses a composite preservative for fresh-cut fruits and vegetables and an application method thereof, belonging to the technical field of fruit and vegetable processing. In the present invention, the fresh-cut fruits and vegetables are soaked for a short time in a composite soaking liquid composed of ascorbic acid, cinnamon essential oil, β-cyclodextrin and chitosan, and then sprayed with konjac glucomannan and carrageenan composite gel after drying. , the fresh-cut fruits and vegetables are processed through the secondary composite fresh-keeping process, and natural slow-release fungicides, water-retaining agents and double-layer protective films are formed on the surface of fruits and vegetables to effectively protect the surface of fresh-cut fruits and vegetables, and solve the deterioration and dehydration of fresh-cut fruits and vegetables in the fresh-keeping process and oxidation issues.

Description

一种鲜切果蔬复合保鲜剂及其使用方法A composite preservative for fresh-cut fruits and vegetables and its application method

技术领域technical field

本发明涉及果蔬加工技术领域,具体涉及一种鲜切果蔬复合保鲜剂及其使用方法。The invention relates to the technical field of fruit and vegetable processing, in particular to a composite preservative for fresh-cut fruits and vegetables and a method for using the same.

背景技术Background technique

鲜切果蔬,又称轻加工果蔬、切割果蔬、调理果蔬,起源于20世纪50年代的美国,主要是为了满足消费者的即食需求。它是指新鲜果蔬经分级、清洗、去皮、修整、切分、包装等处理后,供消费者或餐饮业立即食用的果蔬加工产品。美国零售店首先出现了鲜切产品,但由于产品的质量和货架期很差,而被限制了发展,然而随着美国经济发展迅速,技术的革新,鲜切产业开始突破瓶颈,快速发展。如出现了所谓的“去皮马铃薯工业”,即当时美国的餐饮业和食品服务业需要一种既新鲜又使用方便的马铃薯,刚开始只供应去皮的整个马铃薯,随后各种切片,如小方块、薄片、薯条等都可供应。不仅如此,鲜切果蔬产业也得到发展,这使得美国的鲜切产品开始进入了商业化生产。目前鲜切果蔬的生产在欧美发达国家已形成完备的体系,表现为技术规范化、产品标准化、设备先进化、市场网络化和管理现代化。我国鲜切果蔬的市场化进行起步较晚,直到20世纪90年代,随着人们生活水平的提高,生活节奏的加快和果蔬市场的细分,人们才在消费选购时对鲜切果蔬开始关注。近年来,由于互联网的快速发展,鲜切果蔬不仅在餐饮业占据重要的地位,更成为零售业中的佼佼者,特别是在北京、深圳、上海等一线城市中。鲜切果蔬也成为企业、学校以及航空、高铁配餐所必不可少的方式,既满足了营养、科学、健康的配餐,又让消费者们适应了快节奏的现代生活。2015年,我国将鲜切果蔬纳入生产许可管理范围。因此,虽然我国鲜切果蔬产业起步较晚,但发展非常迅速,市场前景广阔。Fresh-cut fruits and vegetables, also known as lightly processed fruits and vegetables, cut fruits and vegetables, and conditioned fruits and vegetables, originated in the United States in the 1950s, mainly to meet consumers' ready-to-eat needs. It refers to processed fruits and vegetables that are processed by consumers or the catering industry for immediate consumption after fresh fruits and vegetables are graded, cleaned, peeled, trimmed, cut, packaged, etc. Fresh-cut products first appeared in American retail stores, but their development was limited due to poor product quality and shelf life. However, with the rapid economic development and technological innovation in the United States, the fresh-cut industry began to break through the bottleneck and develop rapidly. For example, the so-called "peeled potato industry" appeared. At that time, the catering industry and food service industry in the United States needed a potato that was both fresh and easy to use. At first, only peeled whole potatoes were supplied, and then various slices, such as small Cubes, chips, chips, and more are all available. Not only that, the fresh-cut fruit and vegetable industry has also developed, which has led to the commercial production of fresh-cut products in the United States. At present, the production of fresh-cut fruits and vegetables has formed a complete system in developed countries in Europe and the United States, which is manifested in technical standardization, product standardization, advanced equipment, market networking and modern management. The marketization of fresh-cut fruits and vegetables in my country started relatively late. It was not until the 1990s, with the improvement of people's living standards, the acceleration of the pace of life and the segmentation of the fruit and vegetable market, that people began to pay attention to fresh-cut fruits and vegetables when purchasing. . In recent years, due to the rapid development of the Internet, fresh-cut fruits and vegetables not only occupy an important position in the catering industry, but also become a leader in the retail industry, especially in first-tier cities such as Beijing, Shenzhen, and Shanghai. Fresh-cut fruits and vegetables have also become an indispensable way of catering for enterprises, schools, airlines, and high-speed rail. It not only satisfies nutritional, scientific, and healthy catering, but also allows consumers to adapt to the fast-paced modern life. In 2015, my country included fresh-cut fruits and vegetables in the scope of production license management. Therefore, although my country's fresh-cut fruit and vegetable industry started late, it has developed very rapidly and has broad market prospects.

目前,我国鲜切果蔬行业整体技术水平还很薄弱,鲜切果蔬在加工处理过程中的机械处理损伤了果蔬组织,普遍存在着表面褐变、果肉软化及营养损失等问题,使产品质量下降,并进一步导致了产品贮藏寿命的减少。国内现有的鲜切果蔬保鲜方法包括化学药剂法,低温冷藏法、热处理法,气调法、辐照法、涂膜法等,但这些方法的应用都存在这样那样的问题,或者只能解决鲜切果蔬某一方面的问题,例如化学法可以防止褐变和抑制微生物但不能防止水分蒸发,热处理法也可以防止褐变和抑制微生物但会导致质构变软,辐照法可以杀死表面微生物但会使褐变加剧,而涂膜法也存在涂膜不均匀等问题。这就迫切需要研究一种有效的方法保护鲜切果蔬的切面,能同时降低水分损失和氧化褐变,减少微生物污染,以保持鲜切果蔬的感官品质和营养品质,延长货架期,提高经济价值。At present, the overall technical level of my country's fresh-cut fruit and vegetable industry is still very weak. The mechanical treatment of fresh-cut fruits and vegetables in the processing process damages the fruit and vegetable tissue, and there are widespread problems such as surface browning, pulp softening and nutrient loss, which reduce product quality. And further led to the reduction of product shelf life. The existing fresh-cut fruit and vegetable preservation methods in China include chemical agent method, low-temperature refrigeration method, heat treatment method, modified atmosphere method, irradiation method, film coating method, etc., but the application of these methods all has various problems, or can only solve them. Some aspects of fresh-cut fruits and vegetables, such as chemical methods can prevent browning and inhibit microorganisms but cannot prevent water evaporation, heat treatment can also prevent browning and inhibit microorganisms but will cause texture softening, irradiation can kill the surface However, microorganisms can aggravate browning, and the coating method also has problems such as uneven coating. There is an urgent need to study an effective method to protect the cut surface of fresh-cut fruits and vegetables, which can simultaneously reduce water loss and oxidative browning, and reduce microbial pollution, so as to maintain the sensory quality and nutritional quality of fresh-cut fruits and vegetables, extend shelf life, and increase economic value. .

发明内容Contents of the invention

为弥补现有技术的不足,本发明提供一种全方位鲜切果蔬复合保鲜剂及其使用方法,解决了现有技术中鲜切果蔬保鲜过程中变质、脱水和氧化等问题。In order to make up for the deficiencies of the prior art, the present invention provides an all-round fresh-cut fruit and vegetable composite preservative and its application method, which solves the problems of deterioration, dehydration and oxidation in the fresh-cut process of fresh-cut fruits and vegetables in the prior art.

本发明是通过如下技术方案实现的:The present invention is achieved through the following technical solutions:

一种鲜切果蔬复合保鲜剂,其特殊之处在于:包括浸泡液和喷涂凝胶溶液;所述浸泡液由以下原料制成:低粘度壳聚糖、β-环糊精、肉桂精油、抗坏血酸、去离子水;所述喷涂凝胶溶液由以下原料制成:魔芋葡甘聚糖、卡拉胶、去离子水。A composite preservative for fresh-cut fruits and vegetables, which is special in that it includes a soaking solution and a spray gel solution; the soaking solution is made of the following raw materials: low-viscosity chitosan, β-cyclodextrin, cinnamon essential oil, ascorbic acid , deionized water; the spray gel solution is made of the following raw materials: konjac glucomannan, carrageenan, and deionized water.

其中,每100份浸泡液中包括低粘度壳聚糖0.5-1.5份、β-环糊精1.5-3份、肉桂精油0.5-2份、抗坏血酸1-2.5份,其余为去离子水。Wherein, every 100 parts of soaking liquid includes 0.5-1.5 parts of low-viscosity chitosan, 1.5-3 parts of beta-cyclodextrin, 0.5-2 parts of cinnamon essential oil, 1-2.5 parts of ascorbic acid, and the rest is deionized water.

所述浸泡液的配置方法如下:在去离子水中加入低粘度壳聚糖和β-环糊精加热到50-60℃搅拌溶解,加入肉桂精油密封后在50-60℃下搅拌2-6h,然后加入抗坏血酸溶解后得浸泡液。The configuration method of the soaking liquid is as follows: add low-viscosity chitosan and β-cyclodextrin to deionized water and heat to 50-60°C, stir and dissolve, add cinnamon essential oil to seal, and stir at 50-60°C for 2-6h, Then add ascorbic acid to dissolve and get soaking solution.

本发明中,在浸泡液配方中,抗坏血酸起到护色作用,防止氧化褐变的产生。肉桂精油是目前抑菌效果最好的精油能有效抑制大多数微生物。β-环糊精有两个作用,一是可以包埋肉桂精油使肉桂精油缓慢释放,抑菌时间更久,同时掩盖肉桂精油轻微的刺激性气味,二是可以起到保水作用,β-环糊精表面的大量羟基可以与水分形成氢键,保持水分不易挥发。而低粘度壳聚糖分子上氨基所带正电荷和细菌细胞膜上负电荷的相互作用,具有抗菌、杀菌作用,低粘度壳聚糖还具有良好的成膜性,其膜层具有通透性、阻水性,可以对各种气体分子增加穿透阻力,形成了一种微气调环境,使果蔬组织内的二氧化碳含量增加,氧气含量降低,抑制了果蔬的呼吸代谢和水分散失,减缓果蔬组织和结构衰老。In the present invention, in the soaking liquid formula, ascorbic acid plays a color-protecting role and prevents the generation of oxidative browning. Cinnamon essential oil is the essential oil with the best antibacterial effect at present and can effectively inhibit most microorganisms. β-cyclodextrin has two functions. One is that it can embed cinnamon essential oil to release cinnamon essential oil slowly, inhibit bacteria for a longer time, and at the same time cover up the slight pungent smell of cinnamon essential oil. The other is that it can retain water. β-cyclodextrin A large number of hydroxyl groups on the surface of dextrin can form hydrogen bonds with water to keep the water from volatile. The interaction between the positive charge of the amino group on the low-viscosity chitosan molecule and the negative charge on the bacterial cell membrane has antibacterial and bactericidal effects. The low-viscosity chitosan also has good film-forming properties, and its film layer has permeability. Water resistance can increase the penetration resistance of various gas molecules, forming a micro-atmosphere adjustment environment, increasing the carbon dioxide content and reducing the oxygen content in the fruit and vegetable tissues, inhibiting the respiratory metabolism and water loss of fruits and vegetables, and slowing down the process of fruit and vegetable tissues and Structural aging.

所述浸泡液中低粘度壳聚糖的粘度为100-200mPa·s。The viscosity of the low-viscosity chitosan in the soaking solution is 100-200 mPa·s.

所述浸泡液中肉桂精油为水蒸气蒸馏法提取,肉桂醛含量>65%。The cinnamon essential oil in the soaking liquid is extracted by steam distillation, and the cinnamaldehyde content is >65%.

所述喷涂凝胶溶液中魔芋葡甘聚糖与卡拉胶质量比为5.5:4.5;魔芋葡甘聚糖和卡拉胶混合凝胶比单纯使用魔芋葡甘聚糖或卡拉胶有更好的质构和成膜效果,魔芋葡甘聚糖极易脱水收缩,形成膜韧性强,卡拉胶成膜浓度低,但膜韧性不足,二者按5.5:4.5比例混合形成凝胶膜效果最好。The mass ratio of konjac glucomannan and carrageenan in the spray gel solution is 5.5:4.5; konjac glucomannan and carrageenan mixed gel has better texture than konjac glucomannan or carrageenan alone And film-forming effect, konjac glucomannan is very easy to syneresis, forming a strong film toughness, carrageenan film-forming concentration is low, but the film toughness is not enough, the mixture of the two at a ratio of 5.5:4.5 to form a gel film has the best effect.

所述喷涂凝胶溶液通过去离子水调节pH值为9-11。The pH value of the spray gel solution is adjusted to 9-11 by deionized water.

本发明的一种新鲜果蔬复合保鲜剂的使用方法,其特殊之处在于:包括以下步骤:The using method of a kind of fresh fruit and vegetable composite antistaling agent of the present invention, its special feature is: comprise the following steps:

(1)浸泡液配置:在去离子水中加入壳聚糖和β-环糊精加热到50-60℃搅拌溶解,加入肉桂精油密封后在50-60℃下搅拌2-6h,然后加入抗坏血酸溶解后得浸泡液;(1) Soaking liquid configuration: Add chitosan and β-cyclodextrin to deionized water and heat to 50-60°C and stir to dissolve, add cinnamon essential oil to seal, stir at 50-60°C for 2-6h, then add ascorbic acid to dissolve after soaking solution;

(2)浸泡:将准备好的鲜切果蔬放入浸泡液浸泡2-10min,取出后沥干水分,置于室内通风干燥处晾制1-2h,使温度降低到室温,表面干燥没有明显水分;(2) Soaking: Soak the prepared fresh-cut fruits and vegetables in the soaking solution for 2-10 minutes, take them out, drain the water, and place them in a ventilated and dry place indoors for 1-2 hours to cool down to room temperature, and the surface is dry without obvious moisture ;

(3)喷膜:将魔芋葡甘聚糖和卡拉胶按比例混合,加入去离子水调节pH,加热到80-90℃搅拌使其溶解,制成2%混合凝胶溶液,降温到60-80℃将凝胶溶液均匀喷涂到浸泡后的果蔬表面;(3) Spray film: Mix konjac glucomannan and carrageenan in proportion, add deionized water to adjust pH, heat to 80-90°C and stir to dissolve, make 2% mixed gel solution, cool down to 60- Spray the gel solution evenly on the surface of soaked fruits and vegetables at 80°C;

(4)风干:喷涂后的果蔬在室温下风干至表面无明显水分;(4) Air-drying: the sprayed fruits and vegetables are air-dried at room temperature until there is no obvious moisture on the surface;

(5)包装:对处理后的鲜切果蔬进行包装,然后储藏。(5) Packaging: The processed fresh-cut fruits and vegetables are packaged and then stored.

其中,步骤(5)中采用PE保鲜膜或OPP自封袋对处理后的鲜切果蔬进行包装,然后置于0-5℃低温储藏或常温储藏。Wherein, in step (5), the processed fresh-cut fruits and vegetables are packaged with PE plastic wrap or OPP ziplock bags, and then stored at a low temperature of 0-5°C or at room temperature.

本发明的有益效果是:本发明采用复合保鲜剂技术综合解决鲜切果蔬存在的切口暴露于空气容易引起微生物滋生、氧化褐变和水分挥发等问题,保证鲜切果蔬的新鲜。在浸泡液配方中,抗坏血酸起到护色作用,防止氧化褐变的产生。肉桂精油是目前抑菌效果最好的精油能有效抑制大多数微生物。β-环糊精有两个作用,一是可以包埋肉桂精油使肉桂精油缓慢释放,抑菌时间更久,同时掩盖肉桂精油轻微的刺激性气味,二是可以起到保水作用,β-环糊精表面的大量羟基可以与水分形成氢键,保持水分不易挥发。而低粘度壳聚糖分子上氨基所带正电荷和细菌细胞膜上负电荷的相互作用,具有抗菌、杀菌作用,低粘度壳聚糖还具有良好的成膜性,其膜层具有通透性、阻水性,可以对各种气体分子增加穿透阻力,形成了一种微气调环境,使果蔬组织内的二氧化碳含量增加,氧气含量降低,抑制了果蔬的呼吸代谢和水分散失,减缓果蔬组织和结构衰老。The beneficial effects of the present invention are: the present invention adopts the composite antistaling agent technology to comprehensively solve the problems that the incisions of fresh-cut fruits and vegetables are exposed to the air, which may easily cause microbial growth, oxidative browning and water volatilization, and ensure the freshness of fresh-cut fruits and vegetables. In the formulation of the soaking solution, ascorbic acid acts as a color protector and prevents oxidative browning. Cinnamon essential oil is the essential oil with the best antibacterial effect at present and can effectively inhibit most microorganisms. β-cyclodextrin has two functions. One is that it can embed cinnamon essential oil to release cinnamon essential oil slowly, inhibit bacteria for a longer time, and at the same time cover up the slight pungent smell of cinnamon essential oil. The other is that it can retain water. β-cyclodextrin A large number of hydroxyl groups on the surface of dextrin can form hydrogen bonds with water to keep the water from volatile. The interaction between the positive charge of the amino group on the low-viscosity chitosan molecule and the negative charge on the bacterial cell membrane has antibacterial and bactericidal effects. The low-viscosity chitosan also has good film-forming properties, and its film layer has permeability. Water resistance can increase the penetration resistance of various gas molecules, forming a micro-atmosphere adjustment environment, increasing the carbon dioxide content and reducing the oxygen content in the fruit and vegetable tissues, inhibiting the respiratory metabolism and water loss of fruits and vegetables, and slowing down the process of fruit and vegetable tissues and Structural aging.

本发明为防止浸泡形成的壳聚糖膜层不均匀,减缓肉桂精油向外散发,阻隔氧气,在浸泡晾干形成第一层保护层后,紧接着用魔芋葡甘聚糖和卡拉胶混合凝胶喷涂,魔芋葡甘聚糖和卡拉胶混合凝胶比单纯使用魔芋葡甘聚糖或卡拉胶有更好的质构和成膜效果,魔芋葡甘聚糖极易脱水收缩,形成膜韧性强,卡拉胶成膜浓度低,但膜韧性不足,二者按5.5:4.5比例混合形成凝胶膜效果最好。形成的混合凝胶第二层膜层,可以使肉桂精油在较长时间内在膜层内保持较高浓度,进一步阻隔氧气和水分挥发,达到更好保鲜效果。In order to prevent the unevenness of the chitosan film layer formed by soaking, slow down the outward emission of cinnamon essential oil, and block oxygen, after soaking and drying to form the first protective layer, the chitosan is mixed and coagulated with konjac glucomannan and carrageenan. Glue spraying, konjac glucomannan and carrageenan mixed gel has better texture and film-forming effect than konjac glucomannan or carrageenan alone. Konjac glucomannan is easy to syneresis and forms a film with strong toughness , the carrageenan film-forming concentration is low, but the film toughness is not enough, and the mixture of the two in the ratio of 5.5:4.5 to form a gel film has the best effect. The formed second film layer of the mixed gel can keep the cinnamon essential oil at a relatively high concentration in the film layer for a long period of time, further blocking the volatilization of oxygen and water, and achieving a better fresh-keeping effect.

本发明的保鲜剂及使用方法可以用于苹果、梨、桃、杏、香蕉、火龙果、猕猴桃、甜瓜、哈密瓜等常见水果的鲜切保鲜,或用于草莓、葡萄、桑葚等采后不易保存水果的直接保鲜,也可用于土豆、甘薯、芋头、黄瓜、南瓜、冬瓜、豆角、芦笋等蔬菜的鲜切保鲜。The antistaling agent and usage method of the present invention can be used for fresh-cut preservation of common fruits such as apples, pears, peaches, apricots, bananas, dragon fruit, kiwi fruit, melons, and cantaloupe, or for strawberries, grapes, mulberries, etc., which are difficult to preserve after harvest. The direct preservation of fruits can also be used for fresh cutting and preservation of vegetables such as potatoes, sweet potatoes, taro, cucumbers, pumpkins, wax gourds, beans, and asparagus.

具体实施方式Detailed ways

下面结合具体实施方式对本发明作进一步详细的说明,以帮助本领域的技术人员对本发明的发明构思、技术方案有更完整、准确和深入的理解,本发明的保护范围包括但不限于以下实施例,在不偏离本申请的精神和范围的前提下任何对本发明的技术方案的细节和形式所做出的修改均落入本发明的保护范围内。The present invention will be described in further detail below in conjunction with specific embodiments, to help those skilled in the art have a more complete, accurate and in-depth understanding of the inventive concept and technical solutions of the present invention, the protection scope of the present invention includes but is not limited to the following examples , Any modifications made to the details and forms of the technical solution of the present invention shall fall within the protection scope of the present invention without departing from the spirit and scope of the present application.

实施例1Example 1

鲜切苹果处理Fresh Cut Apple Processing

浸泡液配制:在1000ml去离子水中加入8g低粘度壳聚糖(粘度100-200mPa·s,1%,20℃)和20gβ-环糊精加热到55℃搅拌溶解,加入10g肉桂精油密封后55℃温度下搅拌4h,然后加入20g抗坏血酸溶解后得浸泡液。Preparation of soaking solution: Add 8g of low-viscosity chitosan (viscosity 100-200mPa s, 1%, 20°C) and 20g of β-cyclodextrin to 1000ml of deionized water, heat to 55°C and stir to dissolve, add 10g of cinnamon essential oil and seal it at 55°C Stir at ℃ for 4 hours, then add 20g of ascorbic acid to dissolve and obtain soaking solution.

浸泡:将准备好的鲜切苹果放入上述55℃浸泡液浸泡2min,取出后沥干水分,置于室内通风干燥处晾制1h,使温度降低到室温,表面干燥没有明显水分。Soaking: Soak the prepared fresh-cut apples in the above 55°C soaking solution for 2 minutes, take them out, drain the water, and place them in a ventilated and dry place indoors for 1 hour to cool down to room temperature, and the surface is dry without obvious moisture.

喷膜:将魔芋葡甘聚糖和卡拉胶按5.5:4.5比例混合,加入去离子水中调节pH=10左右,加热到85℃搅拌使其溶解,制成2%混合凝胶溶液。降温到70℃将凝胶溶液均匀喷涂到浸泡后的果蔬表面。Spray film: Mix konjac glucomannan and carrageenan at a ratio of 5.5:4.5, add deionized water to adjust pH = about 10, heat to 85°C and stir to dissolve to make a 2% mixed gel solution. Cool down to 70°C and evenly spray the gel solution onto the surface of soaked fruits and vegetables.

风干:喷涂后果蔬在室温下风干至表面无明显水分。Air-drying: After spraying, the vegetables are air-dried at room temperature until there is no obvious moisture on the surface.

包装:用PE保鲜膜对处理后的鲜切苹果进行包装,然后置于0-5℃低温储藏。Packaging: Pack the processed fresh-cut apples with PE plastic wrap, and then store them at a low temperature of 0-5°C.

实施例2Example 2

鲜切梨处理Fresh Cut Pear Processing

浸泡液配制:在1000ml去离子水中加入10g低粘度壳聚糖(粘度100-200mPa·s,1%,20℃)和20gβ-环糊精加热到55℃搅拌溶解,加入10g肉桂精油密封后55℃温度下搅拌4h,然后加入10g抗坏血酸溶解后得浸泡液。Preparation of soaking solution: Add 10g of low-viscosity chitosan (viscosity 100-200mPa s, 1%, 20°C) and 20g of β-cyclodextrin to 1000ml of deionized water, heat to 55°C and stir to dissolve, add 10g of cinnamon essential oil and seal it at 55°C Stir at ℃ for 4 hours, then add 10 g of ascorbic acid to dissolve to obtain soaking solution.

浸泡:将准备好的鲜切梨放入上述55℃浸泡液浸泡2min,取出后沥干水分,置于室内通风干燥处晾制2h,使温度降低到室温,表面干燥没有明显水分。Soaking: Soak the prepared fresh-cut pears in the above 55°C soaking solution for 2 minutes, take it out, drain the water, and place it in a ventilated and dry place indoors for 2 hours to cool down to room temperature, and the surface is dry without obvious moisture.

喷膜:将魔芋葡甘聚糖和卡拉胶按5.5:4.5比例混合,加入去离子水中调节pH=10左右,加热到85℃搅拌使其溶解,制成2%混合凝胶溶液。降温到70℃将凝胶溶液均匀喷涂到浸泡后的果蔬表面。Spray film: Mix konjac glucomannan and carrageenan at a ratio of 5.5:4.5, add deionized water to adjust pH = about 10, heat to 85°C and stir to dissolve to make a 2% mixed gel solution. Cool down to 70°C and evenly spray the gel solution onto the surface of soaked fruits and vegetables.

风干:喷涂后果蔬在室温下风干至表面无明显水分。Air-drying: After spraying, the vegetables are air-dried at room temperature until there is no obvious moisture on the surface.

包装:用PE保鲜膜对处理后的鲜切梨进行包装,然后置于常温储藏。Packaging: Pack the processed fresh-cut pears with PE plastic wrap, and then store them at room temperature.

实例3Example 3

鲜切甜瓜处理Fresh Cut Melon Processing

浸泡液配制:在1000ml去离子水中加入10g低粘度壳聚糖(粘度100-200mPa·s,1%,20℃)和20gβ-环糊精加热到55℃搅拌溶解,加入10g肉桂精油密封后55℃温度下搅拌4h,然后加入10g抗坏血酸溶解后得浸泡液。Preparation of soaking solution: Add 10g of low-viscosity chitosan (viscosity 100-200mPa s, 1%, 20°C) and 20g of β-cyclodextrin to 1000ml of deionized water, heat to 55°C and stir to dissolve, add 10g of cinnamon essential oil and seal it at 55°C Stir at ℃ for 4 hours, then add 10 g of ascorbic acid to dissolve to obtain soaking solution.

浸泡:将准备好的鲜切甜瓜放入上述55℃浸泡液浸泡4min,取出后沥干水分,置于室内通风干燥处晾制2h,使温度降低到室温,表面干燥没有明显水分。Soaking: Soak the prepared fresh-cut melon in the above 55°C soaking solution for 4 minutes, take it out, drain the water, and place it in a ventilated and dry place indoors for 2 hours to cool down to room temperature, and the surface is dry without obvious moisture.

喷膜:将魔芋葡甘聚糖和卡拉胶按5.5:4.5比例混合,加入去离子水中调节pH=10左右,加热到85℃搅拌使其溶解,制成2%混合凝胶溶液。降温到70℃将凝胶溶液均匀喷涂到浸泡后的果蔬表面。Spray film: Mix konjac glucomannan and carrageenan at a ratio of 5.5:4.5, add deionized water to adjust pH = about 10, heat to 85°C and stir to dissolve to make a 2% mixed gel solution. Cool down to 70°C and evenly spray the gel solution onto the surface of soaked fruits and vegetables.

风干:喷涂后果蔬在室温下风干至表面无明显水分。Air-drying: After spraying, the vegetables are air-dried at room temperature until there is no obvious moisture on the surface.

包装:用PE保鲜膜对处理后的鲜切甜瓜进行包装,然后置于0-5℃低温储藏。Packaging: Pack the treated fresh-cut melons with PE plastic wrap, and then store them at a low temperature of 0-5°C.

实例4Example 4

新鲜草莓处理Fresh Strawberry Treatment

浸泡液配制:在1000ml去离子水中加入5g低粘度壳聚糖(粘度100-200mPa·s,1%,20℃)和20gβ-环糊精加热到55℃搅拌溶解,加入10g肉桂精油密封后55℃温度下搅拌4h,然后加入10g抗坏血酸溶解后得浸泡液。Preparation of soaking solution: Add 5g of low-viscosity chitosan (viscosity 100-200mPa s, 1%, 20°C) and 20g of β-cyclodextrin to 1000ml of deionized water, heat to 55°C and stir to dissolve, add 10g of cinnamon essential oil and seal it at 55°C Stir at ℃ for 4 hours, then add 10 g of ascorbic acid to dissolve to obtain soaking solution.

浸泡:将准备好的新鲜草莓放入上述55℃浸泡液浸泡8min,取出后沥干水分,置于室内通风干燥处晾制1h,使温度降低到室温,表面干燥没有明显水分。Soaking: Soak the prepared fresh strawberries in the above 55°C soaking solution for 8 minutes, take them out, drain the water, and place them in a ventilated and dry place indoors for 1 hour to cool down to room temperature, and the surface is dry without obvious moisture.

喷膜:将魔芋葡甘聚糖和卡拉胶按5.5:4.5比例混合,加入去离子水中调节pH=10左右,加热到85℃搅拌使其溶解,制成2%混合凝胶溶液。降温到70℃将凝胶溶液均匀喷涂到浸泡后的果蔬表面。Spray film: Mix konjac glucomannan and carrageenan at a ratio of 5.5:4.5, add deionized water to adjust pH = about 10, heat to 85°C and stir to dissolve to make a 2% mixed gel solution. Cool down to 70°C and evenly spray the gel solution onto the surface of soaked fruits and vegetables.

风干:喷涂后果蔬在室温下风干至表面无明显水分。Air-drying: After spraying, the vegetables are air-dried at room temperature until there is no obvious moisture on the surface.

包装:用OPP自封袋对处理后的草莓进行包装,然后置于常温储藏。Packaging: Pack the treated strawberries with OPP ziplock bags, and then store them at room temperature.

实例5Example 5

鲜切土豆片处理Fresh Cut Potato Chip Processing

浸泡液配制:在1000ml去离子水中加入10g低粘度壳聚糖(粘度100-200mPa·s,1%,20℃)和20gβ-环糊精加热到55℃搅拌溶解,加入10g肉桂精油密封后55℃温度下搅拌4h,然后加入20g抗坏血酸溶解后得浸泡液。Preparation of soaking solution: Add 10g of low-viscosity chitosan (viscosity 100-200mPa s, 1%, 20°C) and 20g of β-cyclodextrin to 1000ml of deionized water, heat to 55°C and stir to dissolve, add 10g of cinnamon essential oil and seal it at 55°C Stir at ℃ for 4 hours, then add 20g of ascorbic acid to dissolve and obtain soaking solution.

浸泡:将准备好的鲜切土豆片放入上述55℃浸泡液浸泡10min,取出后沥干水分,置于室内通风干燥处晾制1.5h,使温度降低到室温,表面干燥没有明显水分。Soaking: Soak the prepared fresh-cut potato slices in the above-mentioned 55°C soaking solution for 10 minutes, take it out, drain the water, and put it in a ventilated and dry place indoors for 1.5 hours to let the temperature drop to room temperature, and the surface is dry without obvious moisture.

喷膜:将魔芋葡甘聚糖和卡拉胶按5.5:4.5比例混合,加入去离子水中调节pH=10左右,加热到85℃搅拌使其溶解,制成2%混合凝胶溶液。降温到70℃将凝胶溶液均匀喷涂到浸泡后的果蔬表面。Spray film: Mix konjac glucomannan and carrageenan at a ratio of 5.5:4.5, add deionized water to adjust pH = about 10, heat to 85°C and stir to dissolve to make a 2% mixed gel solution. Cool down to 70°C and evenly spray the gel solution onto the surface of soaked fruits and vegetables.

风干:喷涂后果蔬在室温下风干至表面无明显水分。Air-drying: After spraying, the vegetables are air-dried at room temperature until there is no obvious moisture on the surface.

包装:用PE保鲜膜对处理后的鲜切土豆片进行包装,然后置于常温储藏。Packaging: Pack the processed fresh-cut potato slices with PE plastic wrap, and then store them at room temperature.

实例6Example 6

新鲜芦笋处理fresh asparagus treatment

浸泡液配制:在1000ml去离子水中加入5g低粘度壳聚糖(粘度100-200mPa·s,1%,20℃)和20gβ-环糊精加热到55℃搅拌溶解,加入10g肉桂精油密封后55℃温度下搅拌4h,然后加入10g抗坏血酸溶解后得浸泡液。Preparation of soaking solution: Add 5g of low-viscosity chitosan (viscosity 100-200mPa s, 1%, 20°C) and 20g of β-cyclodextrin to 1000ml of deionized water, heat to 55°C and stir to dissolve, add 10g of cinnamon essential oil and seal it at 55°C Stir at ℃ for 4 hours, then add 10 g of ascorbic acid to dissolve to obtain soaking solution.

浸泡:将准备好的新鲜芦笋放入上述55℃浸泡液浸泡5min,取出后沥干水分,置于室内通风干燥处晾制1h,使温度降低到室温,表面干燥没有明显水分。Soaking: Soak the prepared fresh asparagus in the above 55°C soaking solution for 5 minutes, take it out, drain the water, and place it in a ventilated and dry place indoors for 1 hour to cool down to room temperature, and the surface is dry without obvious moisture.

喷膜:将魔芋葡甘聚糖和卡拉胶按5.5:4.5比例混合,加入去离子水中调节pH=10左右,加热到85℃搅拌使其溶解,制成2%混合凝胶溶液。降温到70℃将凝胶溶液均匀喷涂到浸泡后的果蔬表面。Spray film: Mix konjac glucomannan and carrageenan at a ratio of 5.5:4.5, add deionized water to adjust pH = about 10, heat to 85°C and stir to dissolve to make a 2% mixed gel solution. Cool down to 70°C and evenly spray the gel solution onto the surface of soaked fruits and vegetables.

风干:喷涂后果蔬在室温下风干至表面无明显水分。Air-drying: After spraying, the vegetables are air-dried at room temperature until there is no obvious moisture on the surface.

包装:用OPP自封袋对处理后的新鲜芦笋进行包装,然后置于0-5℃低温储藏。Packaging: Pack the processed fresh asparagus in OPP ziplock bags, and then store them at a low temperature of 0-5°C.

对比试验Comparative Test

感官实验sensory experiment

采用10分制评定方法。分四级标准对芦笋的色泽,鲜嫩度,形态,腐烂度和风味5项指标进行打分。产品极好,头部,茎部饱满,没有任何瑕疵的为10分,7分以上的产品还好,仍然新鲜,但稍微有点缺陷,可以作为评价商业价值的标准,5分的头部有水渍状,茎部有一定老化,轻度异味,3分以下不可食用。具体评分标准见下表。A 10-point rating system is used. The color, freshness, shape, rottenness and flavor of asparagus are scored according to four grades. The product is excellent, the head and stem are plump, without any blemishes, 10 points, the product with a score of 7 or more is good, still fresh, but slightly flawed, which can be used as a standard for evaluating commercial value, and the head with a score of 5 has water Stain-like, the stem is aged to a certain extent, mild odor, inedible below 3 points. See the table below for specific scoring criteria.

表1 感官评定标准Table 1 Sensory evaluation criteria

表2 感官得分表Table 2 Sensory score table

由感官品质变化结果可以看出,在冷藏条件下经本方法保鲜处理的芦笋感官品质下降缓慢,可以起到良好的保鲜效果。经处理后储藏12天时芦笋在感官上仍极好,得分都在8.5分以上,18天后在感官上发生轻微变化,仍在8分以上,储存到24天时感官上发生明显变化,但还可以被消费者接受,而未经处理的芦笋在12天时茎部就有一定程度的老化失水,到18天时就与经处理过的芦笋有明显差距。冷藏下30天后未经处理的芦笋头部萎焉且轻度腐烂,茎部失水严重,而保鲜涂膜处理的芦笋头部稍微失绿,茎部轻度失水,保鲜效果较明显。It can be seen from the results of sensory quality changes that the sensory quality of asparagus fresh-keeping treated by this method declines slowly under refrigeration conditions, and can play a good fresh-keeping effect. After being treated for 12 days, the asparagus is still very good in sensory, with scores above 8.5. After 18 days, there is a slight change in sensory, and the score is still above 8. After storage for 24 days, there is a significant change in sensory, but it can still be used Consumers accept it, but untreated asparagus has a certain degree of aging and dehydration in the stem portion in 12 days, and there is a significant gap with the processed asparagus in 18 days. After 30 days of refrigeration, the heads of untreated asparagus were wilted and slightly rotten, and the stems were seriously dehydrated, while the heads of asparagus treated with fresh-keeping coating were slightly chlorotic, the stems were slightly dehydrated, and the fresh-keeping effect was more obvious.

菌落总数测定Determination of the total number of colonies

菌落总数测定方法参照GB4789.2-2010。结果见表3。The determination method of the total number of colonies refers to GB4789.2-2010. The results are shown in Table 3.

表3 芦笋菌落总数变化Table 3 Changes in the total number of asparagus colonies

冷藏条件下,未处理芦笋在18天切口部位可以观察到腐败,24天后腐败严重,30天后头部萎焉且轻度腐烂,切口部位腐烂严重。而保鲜涂膜处理的芦笋18天后未见微生物滋生,30天后只见轻微失水,未见腐败,保鲜效果明显。Under refrigerated conditions, untreated asparagus can be observed to be rotten at the incision site after 18 days, and the rot is serious after 24 days. However, the asparagus treated with fresh-keeping coating film did not see microbial growth after 18 days, and only slight dehydration was seen after 30 days, and no corruption was seen, and the fresh-keeping effect was obvious.

失重率测定Determination of weight loss rate

失重率按下式进行测定:The weight loss rate is determined according to the following formula:

表4 芦笋失重率变化Table 4 Changes in weight loss rate of asparagus

果蔬失水会引起形态,质地,结构等多方面的变化,采收后的绿芦笋含水量极高,但因其组织比较幼嫩,呼吸作用非常旺盛,水分极易蒸发散失,从而导致芦笋嫩茎失水过快,保鲜期大大缩短。失重率可以作为衡量芦笋保鲜效果的一个重要指标。由表4可以看出,冷藏下保鲜处理的绿芦笋失重率升高的较缓慢。30天时处理组的失重率均小于15%而未处理组的失重率已接近25%,说明此保鲜处理能显著降低绿芦笋的失重率。The dehydration of fruits and vegetables will cause changes in shape, texture, structure and many other aspects. Green asparagus after harvesting has a very high water content, but because of its relatively young tissues, the respiration is very strong, and the water is easily evaporated and lost, resulting in tender asparagus. The stem loses water too quickly, and the fresh-keeping period is greatly shortened. The weight loss rate can be used as an important indicator to measure the preservation effect of asparagus. It can be seen from Table 4 that the weight loss rate of green asparagus treated with fresh-keeping under refrigeration increases slowly. At 30 days, the weight loss rate of the treatment group was less than 15%, while the weight loss rate of the untreated group was close to 25%, indicating that this fresh-keeping treatment can significantly reduce the weight loss rate of green asparagus.

维生素C含量测定Determination of vitamin C content

采用2,6-二氯靛酚法测定维生素C含量。从绿芦笋尖部开始往下准确称取5g样品置于研钵中,加入等量2%的草酸溶液,避光研磨呈浆状后,转入100mL容量瓶中,1%的草酸溶液冲洗,倒入容量瓶中,定容至刻度,摇匀,过滤溶液备用。倒入10mL滤液在100mL锥形瓶中,滴定滤液用标定过的2,6-二氯靛酚溶液,出现微红色后停止滴定,15s内不褪色。记下用量,同时以10mL1%的草酸溶液做空白滴定,按照同样的方法,重复三次。The content of vitamin C was determined by the 2,6-dichloroindophenol method. Accurately weigh 5g of the sample starting from the tip of the green asparagus and place it in a mortar, add an equal amount of 2% oxalic acid solution, grind it in the dark to form a slurry, transfer it to a 100mL volumetric flask, rinse with 1% oxalic acid solution, Pour into a volumetric flask, set the volume to the mark, shake well, and filter the solution for later use. Pour 10mL of the filtrate into a 100mL Erlenmeyer flask, and titrate the filtrate with the calibrated 2,6-dichloroindophenol solution. Stop the titration after the reddish color appears, and the color will not fade within 15s. Write down the dosage, and at the same time do blank titration with 10mL of 1% oxalic acid solution, and repeat the same method three times.

根据2,6-二氯靛酚的用量,计算绿芦笋中维生素C的含量,以每100g样品(鲜重)中含有的维生素C的质量表示,即mg/100 g。计算公式为:According to the amount of 2,6-dichloroindophenol, calculate the content of vitamin C in green asparagus, expressed by the quality of vitamin C contained in every 100g sample (fresh weight), ie mg/100g. The calculation formula is:

式中,V1—滴定样品提取液所用的的染料体积,单位mL;In the formula, V 1 —the volume of dye used for titrating the sample extract, in mL;

V2—空白滴定消耗的染料体积,单位mL;V 2 —the volume of dye consumed by blank titration, unit mL;

T— 1mL染料相当于维生素C的质量,单位mg/mL; T— 1mL dye is equivalent to the quality of vitamin C, unit mg/mL;

m—10mL样品提取液中含样品的质量,单位g。m—the mass of the sample contained in the 10mL sample extract, in g.

表5 芦笋维生素C含量变化Table 5 Changes of vitamin C content in asparagus

芦笋中维生素C的含量非常丰富,可作为评价其贮藏品质变化的重要指标。冷藏条件下保鲜处理和未处理芦笋的维生素C的变化如表5所示,随着贮存时间的延长,保鲜组与对照组维生素C含量都呈下降趋势,但保鲜组维生素C含量下降更缓慢。说明本方法保鲜处理能有效降低绿芦笋的维生素C损失。The content of vitamin C in asparagus is very rich, which can be used as an important indicator to evaluate the change of its storage quality. The changes of vitamin C in fresh-keeping treated and untreated asparagus under refrigerated conditions are shown in Table 5. With the prolongation of storage time, the vitamin C content of the fresh-keeping group and the control group showed a downward trend, but the vitamin C content of the fresh-keeping group decreased more slowly. It shows that the fresh-keeping treatment of this method can effectively reduce the vitamin C loss of green asparagus.

分光光度计法测定叶绿素的含量。从绿芦笋尖部以下约15cm处准确称取1g样品,放入研钵中,加入纯丙酮5mL,研成匀浆,再加入80%的丙酮继续研磨至组织变白,定容到25mL,暗置3~5min后提取。在大试管中倒入绿色清液5mL,用移液管吸取,摇匀测定。80%丙酮作为空白对照和提取液在波长663nm、645nm下读取光密度值,重复三次取平均值。计算叶绿素总含量,以每100g样品(鲜重)中含有的叶绿素的质量表示,单位为mg/100g,计算公式如下:The content of chlorophyll was determined by spectrophotometer. Accurately weigh 1g of the sample from about 15cm below the tip of the green asparagus, put it into a mortar, add 5mL of pure acetone, grind it into a homogenate, then add 80% acetone and continue grinding until the tissue turns white, dilute to 25mL, darken Extract after 3~5min. Pour 5mL of the green clear solution into a large test tube, draw it up with a pipette, and shake it up for determination. 80% acetone was used as the blank control and the extract solution to read the optical density values at wavelengths of 663nm and 645nm, and repeated three times to obtain the average value. Calculate the total chlorophyll content, expressed as the mass of chlorophyll contained in every 100g sample (fresh weight), the unit is mg/100g, the calculation formula is as follows:

Ct=20.2D645+8.02D663 Ct= 20.2D6458.02D663

式中D—特定波长下的光密度值;In the formula, D—the optical density value at a specific wavelength;

V—丙酮提取叶绿素的最终体积,单位mL; V—the final volume of chlorophyll extracted by acetone, unit mL;

m—样品的鲜重,单位g。 m—the fresh weight of the sample, in g.

表6 芦笋叶绿素含量变化Table 6 Changes of chlorophyll content in asparagus

芦笋的绿色是其重要的感官指标,采后其表皮的叶绿素会逐渐分解,颜色变黄。低温储藏绿芦笋的叶绿素含量下降趋势如表6所示。经保鲜涂膜处理后的芦笋叶绿素含量普遍减少缓慢,与对照组相比差异较大。可见经处理后的芦笋有明显的优势,保鲜涂膜处理可以延缓叶绿素的分解,在较长时间内能够保持绿芦笋的色泽。The green color of asparagus is an important sensory indicator. After harvesting, the chlorophyll on the skin of asparagus will gradually decompose, and the color will turn yellow. The decline trend of chlorophyll content of green asparagus stored at low temperature is shown in Table 6. The chlorophyll content of asparagus treated with fresh-keeping coating generally decreased slowly, which was significantly different from that of the control group. It can be seen that the treated asparagus has obvious advantages. The fresh-keeping coating treatment can delay the decomposition of chlorophyll, and can maintain the color of green asparagus for a long time.

Claims (9)

1.一种鲜切果蔬复合保鲜剂,其特征在于:包括浸泡液和喷涂凝胶溶液;所述浸泡液由以下原料制成:低粘度壳聚糖、β-环糊精、肉桂精油、抗坏血酸、去离子水;所述喷涂凝胶溶液由以下原料制成:魔芋葡甘聚糖、卡拉胶、去离子水。1. A composite preservative for fresh-cut fruits and vegetables, characterized in that: it comprises soaking liquid and spray gel solution; said soaking liquid is made of the following raw materials: low-viscosity chitosan, β-cyclodextrin, cinnamon essential oil, ascorbic acid , deionized water; the spray gel solution is made of the following raw materials: konjac glucomannan, carrageenan, and deionized water. 2.根据权利要求1所述的一种鲜切果蔬复合保鲜剂,其特征在于:每100份浸泡液中包括低粘度壳聚糖0.5-1.5份、β-环糊精1.5-3份、肉桂精油0.5-2份、抗坏血酸1-2.5份,其余为去离子水。2. A kind of fresh-cut fruit and vegetable composite preservative according to claim 1, characterized in that: 0.5-1.5 parts of low-viscosity chitosan, 1.5-3 parts of β-cyclodextrin, cinnamon 0.5-2 parts of essential oil, 1-2.5 parts of ascorbic acid, and the rest are deionized water. 3.根据权利要求1或2所述的一种鲜切果蔬复合保鲜剂,其特征在于:所述浸泡液的配置方法如下:在去离子水中加入低粘度壳聚糖和β-环糊精加热到50-60℃搅拌溶解,加入肉桂精油密封后在50-60℃下搅拌2-6h,然后加入抗坏血酸溶解后得浸泡液。3. A kind of fresh-cut fruit and vegetable composite antistaling agent according to claim 1 or 2, characterized in that: the configuration method of the soaking liquid is as follows: add low-viscosity chitosan and β-cyclodextrin to deionized water and heat Stir to dissolve at 50-60°C, add cinnamon essential oil to seal, stir at 50-60°C for 2-6h, then add ascorbic acid to dissolve to obtain soaking solution. 4.根据权利要求1或2所述的一种鲜切果蔬复合保鲜剂,其特征在于:所述浸泡液中低粘度壳聚糖的粘度为100-200 mPa. s。4. A fresh-cut fruit and vegetable composite preservative according to claim 1 or 2, characterized in that: the viscosity of the low-viscosity chitosan in the soaking solution is 100-200 mPa . s. 5.根据权利要求1或2所述的一种鲜切果蔬复合保鲜剂,其特征在于:所述浸泡液中肉桂精油为水蒸气蒸馏法提取,肉桂醛含量>65%。5. A composite preservative for fresh-cut fruits and vegetables according to claim 1 or 2, characterized in that: the cinnamon essential oil in the soaking solution is extracted by steam distillation, and the cinnamaldehyde content is >65%. 6.根据权利要求1所述的一种鲜切果蔬复合保鲜剂,其特征在于:所述喷涂凝胶溶液中魔芋葡甘聚糖与卡拉胶质量比为5.5:4.5。6. A fresh-cut fruit and vegetable composite antistaling agent according to claim 1, characterized in that: the mass ratio of konjac glucomannan to carrageenan in the spray gel solution is 5.5:4.5. 7.根据权利要求1或6所述的一种鲜切果蔬复合保鲜剂,其特征在于:所述喷涂凝胶溶液pH值为9-11。7. A fresh-cut fruit and vegetable composite fresh-keeping agent according to claim 1 or 6, characterized in that: the pH value of the spray gel solution is 9-11. 8.根据权利要求1所述的一种新鲜果蔬复合保鲜剂的使用方法,其特征在于:包括以下步骤:8. the using method of a kind of fresh fruit and vegetable composite antistaling agent according to claim 1, is characterized in that: comprise the following steps: 浸泡液配置:在去离子水中加入低粘度壳聚糖和β-环糊精加热到50-60℃搅拌溶解,加入肉桂精油密封后在50-60℃下搅拌2-6h,然后加入抗坏血酸溶解后得浸泡液;Soaking solution configuration: Add low-viscosity chitosan and β-cyclodextrin to deionized water and heat to 50-60°C and stir to dissolve, add cinnamon essential oil to seal, stir at 50-60°C for 2-6h, then add ascorbic acid to dissolve get soaking solution; 浸泡:将准备好的鲜切果蔬放入浸泡液浸泡2-10min,取出后沥干水分,置于室内通风干燥处晾制1-2h,使温度降低到室温,表面干燥没有明显水分;Soaking: Soak the prepared fresh-cut fruits and vegetables in the soaking solution for 2-10 minutes, take them out, drain the water, and place them in a ventilated and dry place indoors to dry for 1-2 hours, so that the temperature drops to room temperature, and the surface is dry without obvious moisture; 喷膜:将魔芋葡甘聚糖和卡拉胶按比例混合,加入去离子水调节pH,加热到80-90℃搅拌使其溶解,制成2%混合凝胶溶液,降温到60-80℃将凝胶溶液均匀喷涂到浸泡后的果蔬表面;Spray film: Mix konjac glucomannan and carrageenan in proportion, add deionized water to adjust pH, heat to 80-90°C and stir to dissolve, make 2% mixed gel solution, cool to 60-80°C The gel solution is evenly sprayed onto the surface of soaked fruits and vegetables; 风干:喷涂后的果蔬在室温下风干至表面无明显水分;Air-drying: The sprayed fruits and vegetables are air-dried at room temperature until there is no obvious moisture on the surface; 包装:对处理后的鲜切果蔬进行包装,然后储藏。Packaging: Packaging the processed fresh-cut fruits and vegetables, and then storing them. 9.根据权利要求8所述的一种新鲜果蔬复合保鲜剂的使用方法,其特征在于:步骤(5)中采用PE保鲜膜或OPP自封袋对处理后的鲜切果蔬进行包装,然后置于0-5℃低温储藏或常温储藏。9. The method of using a composite preservative for fresh fruits and vegetables according to claim 8, characterized in that: in step (5), the processed fresh-cut fruits and vegetables are packaged with PE plastic wrap or OPP ziplock bags, and then placed in 0-5 ℃ low temperature storage or normal temperature storage.
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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108782746A (en) * 2018-04-28 2018-11-13 徐州工程学院 The fresh-keeping plastics of Fresh-cut apple and its application
CN109601613A (en) * 2019-02-15 2019-04-12 江苏莱顿博瑞生物科技有限公司 A kind of antistaling agent and preparation method thereof for Fresh-cut Apples
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101161082A (en) * 2007-11-23 2008-04-16 陈绳良 A method for preparing natural fruit vegetables antistaling agent using capsule technique
CN101744045A (en) * 2009-12-24 2010-06-23 江南大学 Fresh bamboo shoot coating preservative prepared by edible material
CN101965863A (en) * 2010-08-26 2011-02-09 天津绿新低温科技有限公司 Fruit and vegetable micro encapsulated fresh-keeping agent and preparation method thereof
CN102696756A (en) * 2012-06-14 2012-10-03 山东理工大学 Agaricus bisporus film-spraying and fresh-keeping method
CN104920604A (en) * 2014-12-18 2015-09-23 山东省花生研究所 Method for inhibiting aspergillus flavus pollution of peanut by garlic essential oil-chitosan compound coating
US20170013850A1 (en) * 2014-03-18 2017-01-19 Vural Gokmen A solution for extending shelf life of ready-to-eat fresh fruits and/or vegetables and an application method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101161082A (en) * 2007-11-23 2008-04-16 陈绳良 A method for preparing natural fruit vegetables antistaling agent using capsule technique
CN101744045A (en) * 2009-12-24 2010-06-23 江南大学 Fresh bamboo shoot coating preservative prepared by edible material
CN101965863A (en) * 2010-08-26 2011-02-09 天津绿新低温科技有限公司 Fruit and vegetable micro encapsulated fresh-keeping agent and preparation method thereof
CN102696756A (en) * 2012-06-14 2012-10-03 山东理工大学 Agaricus bisporus film-spraying and fresh-keeping method
US20170013850A1 (en) * 2014-03-18 2017-01-19 Vural Gokmen A solution for extending shelf life of ready-to-eat fresh fruits and/or vegetables and an application method thereof
CN104920604A (en) * 2014-12-18 2015-09-23 山东省花生研究所 Method for inhibiting aspergillus flavus pollution of peanut by garlic essential oil-chitosan compound coating

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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CN110896998A (en) * 2019-12-06 2020-03-24 中国农业大学 A kind of double-layer coating method and formula for inhibiting postharvest disease of apple
CN111066879A (en) * 2019-12-23 2020-04-28 福州康来生物科技有限公司 Hericium erinaceus preservation process
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CN112262884A (en) * 2020-10-22 2021-01-26 甘肃世邦星达生物科技有限公司 Fruit and vegetable coating agent
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