CN108503045A - 复合高效净水剂及其制备方法 - Google Patents
复合高效净水剂及其制备方法 Download PDFInfo
- Publication number
- CN108503045A CN108503045A CN201810324686.8A CN201810324686A CN108503045A CN 108503045 A CN108503045 A CN 108503045A CN 201810324686 A CN201810324686 A CN 201810324686A CN 108503045 A CN108503045 A CN 108503045A
- Authority
- CN
- China
- Prior art keywords
- bentonite
- powder
- water
- kunming
- yunnan
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 15
- 239000002131 composite material Substances 0.000 title claims abstract description 14
- 238000000746 purification Methods 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 39
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 20
- 239000012141 concentrate Substances 0.000 claims abstract description 19
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 18
- 150000002910 rare earth metals Chemical class 0.000 claims abstract description 18
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 17
- 239000000440 bentonite Substances 0.000 claims abstract description 17
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000010457 zeolite Substances 0.000 claims abstract description 17
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 15
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 15
- 241000894006 Bacteria Species 0.000 claims abstract description 12
- UMPKMCDVBZFQOK-UHFFFAOYSA-N potassium;iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[K+].[Fe+3] UMPKMCDVBZFQOK-UHFFFAOYSA-N 0.000 claims abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 10
- 239000004615 ingredient Substances 0.000 claims abstract description 4
- 229910052681 coesite Inorganic materials 0.000 claims abstract 4
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract 4
- 239000000377 silicon dioxide Substances 0.000 claims abstract 4
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract 4
- 229910052682 stishovite Inorganic materials 0.000 claims abstract 4
- 229910052905 tridymite Inorganic materials 0.000 claims abstract 4
- 238000003756 stirring Methods 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 229910017604 nitric acid Inorganic materials 0.000 claims description 3
- 230000000737 periodic effect Effects 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 3
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 3
- 239000011574 phosphorus Substances 0.000 abstract description 3
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 3
- 239000012629 purifying agent Substances 0.000 abstract description 3
- 244000005700 microbiome Species 0.000 abstract description 2
- 239000003403 water pollutant Substances 0.000 abstract description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 description 6
- 239000011707 mineral Substances 0.000 description 6
- 239000010865 sewage Substances 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 239000013049 sediment Substances 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- -1 double succimides Chemical compound 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 229910052765 Lutetium Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- JMAHHHVEVBOCPE-UHFFFAOYSA-N [Fe].[Nb] Chemical compound [Fe].[Nb] JMAHHHVEVBOCPE-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 description 1
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 1
- 241000385540 bacterium 10 Species 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000035568 catharsis Effects 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000010436 fluorite Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 210000002966 serum Anatomy 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
- C02F3/348—Biological treatment of water, waste water, or sewage characterised by the microorganisms used characterised by the way or the form in which the microorganisms are added or dosed
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/08—Chemical Oxygen Demand [COD]; Biological Oxygen Demand [BOD]
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Microbiology (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Water Treatment By Sorption (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
本发明涉及净水剂以及制备方法，尤其是复合净水剂以及制备方法。本发明所述的复合高效净水剂由膨润土、沸石粉、云南昆明武定迤纳厂初精矿稀土原粉、高铁酸钾、碳酸钠、水处理工程菌组成，各成分的重量百分比为：膨润土25～30％、沸石粉25～30％、云南昆明武定迤纳厂初精矿稀土原粉5～15％、高铁酸钾9～15％、碳酸钠10～15％、水处理工程菌3～10％；所述的膨润土中SiO2的含量大于等于60％，所述的沸石粉中SiO2的含量大于等于60％。本发明所述的复合高效净水处理剂，一方面对水中污染物具有良好的吸附作用，另一发面利用固定化微生物的脱氮、COD、BOD、磷、脱色、去除重金属。
Description
技术领域
本发明涉及净水剂以及制备方法，尤其是复合净水剂以及制备方法。
背景技术
中国专利申请号201610625822.8公开了“一种铜矿废水的快速处理方法”，以聚合氯化铝、高铁酸钾、二甲基二烯丙基氯化铵、钾长石、双丁二酰亚胺、石英砂、聚丙烯酰胺、二乙烯三胺五甲叉膦酸、尿素、柠檬酸、活性污泥所组成的混合物作为净化剂，配合以聚合硫酸铁、膨润土、沸石粉、脂肪醇聚氧乙烯醚硫酸钠、明矾为组成成分的絮凝剂，辅以深度氧化、絮凝、超声、树脂吸附、过滤、杀菌、膜分离等工艺，有效降低了铜矿废水中的铜含量、COD值，能够满足行业的要求，具有较好的应用前景。
中国专利申请号200510094693.6公开了一种“新型造纸污水净水剂的制作方法”，主要为解决现有技术中造纸污水处理成本高，有的处理后不能达标以及沉渣不能综合利用问题。该发明的制作步骤为：(a)按重量份将膨润土3－5份，铝矾土2－4份，高龄土1－3份，硅藻土1－2份，混合后水洗；(b)将水洗后的上层乳浆压滤成固体，取压滤后的固体5－7份与沸石粉3－5份混合，在混合物中加入酸溶液搅拌均匀，在40℃－60℃的温度下放置16－24小时；(c)将经放置16－24小时的混合物进行水洗至pH值为5－8；(d)干燥、粉碎、包装即为成品。
发明内容
本发明的目的是提供一种净水效率高且能防止二次污染的复合高效净水剂。
本发明的另一目的是提供这种净水剂的制备方法。
本发明所述的复合高效净水剂由膨润土、沸石粉、云南昆明武定迤纳厂初精矿稀土原粉、高铁酸钾、碳酸钠、水处理工程菌组成，各成分的重量百分比为：膨润土25～30％、沸石粉25～30％、云南昆明武定迤纳厂初精矿稀土原粉5～15％、高铁酸钾9～15％、碳酸钠10～15％、水处理工程菌3～10％；所述的膨润土中SiO2的含量大于等于60％，所述的沸石粉中SiO2的含量大于等于60％。
所述的水处理工程菌为市场所售的，如为威宝菌或super—CM生物菌等。
所述的云南昆明武定迤纳厂初精矿稀土原粉为云南昆明武定迤纳厂铌—铁摇床选出的初精矿稀土原粉。
云南昆明武定迤纳厂初精矿稀土原粉，由于矿床的形态岩性和结构特点，IOCC矿床，与其它矿床相比，最大的特点是矿体为广泛发育的砾岩筒型，主要由热液缺氧化物和磁铁矿以及镜铁矿与其它矿体共存，构成了大型矿床。稀土原粉中稀有元素锆、镧、铈、镥的含量较高，稀土原粉中的纳质、钾质均被绢云母氧化和硅化，这在很多矿床的围岩蚀变中是没有的。
云南昆明武定迤纳厂初精矿稀土原粉还有如下特点：一，初精矿稀土原粉的盐基度为45-50％，包裹体中均温度频值在550-600度左右；二，初精矿稀土原粉中有着较强阳离子电荷以及硫酸钠；三，初精矿稀土原粉中其它流体组合中含有氯化钠、硫酸钙、氯化镁等；四、初精矿稀土原粉中萤石单体矿物、石英单体矿物、方解石单体矿物等。该矿的初精矿稀土原粉在水处理净化中起到了及其的重要作用，可以降解废水中难降解的COD、氟离子、磷酸根离子、氨氮，并能使其脱色，去除沉淀重金属。起到了极好的催化和氧化作用。由于该稀土原粉具有特殊的电子结构和独特的物理-化学特性、及其强的吸附性能，。在污水处理过程中更加的快速和稳定。发挥着不可替代的作用。
本发明所述的复合高效净水剂的制备方法由以下步骤组成：
一、将膨润土、沸石粉、云南昆明武定迤纳厂初精矿稀土原粉充分混合，加入水，至含水量为18～25％；
二、用模具或造粒机成型，除去游离水分；
三、进入间歇窑或旋转连续窑逐步升温至500～600℃，然后通入空气或氧气焙烧2～3小时；
四、逐步冷却至常温，出窑；
五、分别进入浓盐酸、浓硝酸、浓硫酸池中浸泡1～3天或分别喷淋洗涤30～60分钟；干燥，干燥温度60～80度，通过雷磨机分筛80目～120目，即得初品；
六、在得到的初品中加入高铁酸钾、碳酸钠、水处理工程菌，通过搅拌混合，搅拌速度为每分钟80转，搅拌20分钟得到成品。
本发明所述的复合高效净水处理剂，一方面对水中污染物具有良好的吸附作用，另一发面利用固定化微生物的脱氮、COD、BOD、磷、脱色、去除重金属。改善了膨润土和沸石粉能力不足的状况，同时又能提高水处理效率，处理时间快、设备简单、操作方便，出水水质高且稳定；不存在二次污染，沉淀物对河道中的淤泥能起到固定净化作用，并且能够防止有机物重新释放污染水体。河道污水、生活污水、处理后的沉淀物可生产肥料和土壤改良产品。
具体实施方法
通过以下实施例对本发明做进一步的说明，实施例不构成对本发明的限制。
实施例1：
本实施例所述的复合高效净水剂各成分的重量百分比为：膨润土30％、沸石粉30％、云南昆明武定迤纳厂初精矿稀土原粉10％、高铁酸钾10％、碳酸钠10％、水处理工程菌10％；所述的膨润土中SiO2的含量为60％，所述的沸石粉中SiO2的含量为60％。
将上述配比原料中的膨润土、沸石粉、云南昆明武定迤纳厂初精矿稀土原粉，充分混合，加入水，至含水量为18～25％；采用模具或造粒机成型，除去游离水分；进入间歇窑或旋转连续窑逐步升温至500～600℃，然后通入空气或氧气焙烧2～3小时；逐步冷却至常温，出窑；分别进入浓盐酸、浓硝酸、浓硫酸池中各浸泡2天或分别喷淋洗涤30～60分钟，干燥，干燥温度60一80度，通过雷磨机，分筛80目～120目，即得初品；加入高铁酸钾、碳酸钠和super—CM生物菌，通过搅拌混合，搅拌速度为每分钟80转，搅拌20分钟得到成品复合高效净水剂。
Claims (2)
1.一种复合高效净水剂，其特征在于由膨润土、沸石粉、云南昆明武定迤纳厂初精矿稀土原粉、高铁酸钾、碳酸钠、水处理工程菌组成，各成分的重量百分比为：膨润土25～30％、沸石粉25～30％、云南昆明武定迤纳厂初精矿稀土原粉5～15％、高铁酸钾9～15％、碳酸钠10～15％、水处理工程菌3～10％；所述的膨润土中SiO2的含量大于等于60％，所述的沸石粉中SiO2的含量大于等于60％。
2.如权利要求1所述的复合高效净水剂的制备方法，其特征在于由以下步骤组成：
一、将膨润土、沸石粉、云南昆明武定迤纳厂初精矿稀土原粉充分混合，加入水，至含水量为18～25％；
二、用模具或造粒机成型，除去游离水分；
三、进入间歇窑或旋转连续窑逐步升温至500～600℃，然后通入空气或氧气焙烧2～3小时；
四、逐步冷却至常温，出窑；
五、分别进入浓盐酸、浓硝酸、浓硫酸池中浸泡1～3天或分别喷淋洗涤30～60分钟；干燥，干燥温度60～80度，通过雷磨机分筛80目～120目，即得初品；
六、在得到的初品中加入高铁酸钾、碳酸钠、水处理工程菌，通过搅拌混合，搅拌速度为每分钟80转，搅拌20分钟得到成品。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810324686.8A CN108503045B (zh) | 2018-04-12 | 2018-04-12 | 复合高效净水剂及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810324686.8A CN108503045B (zh) | 2018-04-12 | 2018-04-12 | 复合高效净水剂及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108503045A true CN108503045A (zh) | 2018-09-07 |
| CN108503045B CN108503045B (zh) | 2021-03-16 |
Family
ID=63381880
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810324686.8A Active CN108503045B (zh) | 2018-04-12 | 2018-04-12 | 复合高效净水剂及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108503045B (zh) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111995170A (zh) * | 2020-07-10 | 2020-11-27 | 广西夏阳环保科技有限公司 | 一种造纸废水复合处理药剂及其处理方法 |
| CN112371096A (zh) * | 2020-11-04 | 2021-02-19 | 中国科学院新疆理化技术研究所 | 去除水中多种重金属的有机-无机复合材料的制备方法及用途 |
| CN112645453A (zh) * | 2020-11-30 | 2021-04-13 | 中天华诺建设有限公司 | 用于降低污水中氮含量的复合菌剂 |
| WO2021139416A1 (zh) * | 2020-01-06 | 2021-07-15 | 南京大学 | 一种同步脱氮除磷的复合功能材料及其制备方法 |
| CN114105313A (zh) * | 2021-12-09 | 2022-03-01 | 苏州中晟环境修复有限公司 | 一种以固定化微生物技术结合生物炭联合处理富营养化水体的方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1762844A (zh) * | 2004-10-20 | 2006-04-26 | 哈尔滨工业大学 | 水处理除污染药剂 |
| CN101306850A (zh) * | 2008-07-09 | 2008-11-19 | 昆明铜龙科技开发有限公司 | 复合高效硅藻土净水剂及制备方法 |
-
2018
- 2018-04-12 CN CN201810324686.8A patent/CN108503045B/zh active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1762844A (zh) * | 2004-10-20 | 2006-04-26 | 哈尔滨工业大学 | 水处理除污染药剂 |
| CN101306850A (zh) * | 2008-07-09 | 2008-11-19 | 昆明铜龙科技开发有限公司 | 复合高效硅藻土净水剂及制备方法 |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021139416A1 (zh) * | 2020-01-06 | 2021-07-15 | 南京大学 | 一种同步脱氮除磷的复合功能材料及其制备方法 |
| CN111995170A (zh) * | 2020-07-10 | 2020-11-27 | 广西夏阳环保科技有限公司 | 一种造纸废水复合处理药剂及其处理方法 |
| CN111995170B (zh) * | 2020-07-10 | 2023-07-14 | 合山市春旭环保科技有限责任公司 | 一种造纸废水复合处理药剂及其处理方法 |
| CN112371096A (zh) * | 2020-11-04 | 2021-02-19 | 中国科学院新疆理化技术研究所 | 去除水中多种重金属的有机-无机复合材料的制备方法及用途 |
| CN112645453A (zh) * | 2020-11-30 | 2021-04-13 | 中天华诺建设有限公司 | 用于降低污水中氮含量的复合菌剂 |
| CN112645453B (zh) * | 2020-11-30 | 2021-11-26 | 中天华诺建设有限公司 | 用于降低污水中氮含量的复合菌剂 |
| CN114105313A (zh) * | 2021-12-09 | 2022-03-01 | 苏州中晟环境修复有限公司 | 一种以固定化微生物技术结合生物炭联合处理富营养化水体的方法 |
| CN114105313B (zh) * | 2021-12-09 | 2023-07-21 | 苏州中晟环境修复有限公司 | 一种以固定化微生物技术结合生物炭联合处理富营养化水体的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108503045B (zh) | 2021-03-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108503045A (zh) | 复合高效净水剂及其制备方法 | |
| US3066095A (en) | Water purification agents and method of using same | |
| CN100542976C (zh) | 用粉煤灰和高岭土生产复合聚硅酸铝铁絮凝剂的方法 | |
| CN107162093A (zh) | 一种水产养殖水质净化剂及其制备方法 | |
| KR101405360B1 (ko) | 수처리용 응집제 조성물 및 이를 이용한 수처리 방법 | |
| KR20010000709A (ko) | 수처리용 흡착제 | |
| KR100413338B1 (ko) | 고성능 흡착 수처리제 및 수처리 시스템 | |
| CN106430754A (zh) | 一种铜矿废水的快速处理方法 | |
| CN104445558A (zh) | 超强效复合絮凝剂 | |
| Lian et al. | A comprehensive study of phosphorus removal and recovery with a Fe-loaded sulfoaluminate cement (FSC) adsorbent | |
| CN106673112A (zh) | 一种脱氮除磷滤料及其制备方法 | |
| KR101334861B1 (ko) | 다공성 펠릿형 수처리제의 제조방법 | |
| CN105152260A (zh) | 一种城镇废水固化消除剂及其制备方法 | |
| US4076620A (en) | Process for the disposal of sewage | |
| CN102303918A (zh) | 酸性高铁高锰矿井水的处理方法及粉煤灰的改性方法 | |
| CN101665279A (zh) | 一种去除水中低浓度磷的絮凝剂 | |
| Masłoń et al. | Efficiency of brick dust and powdered ceramsite in the phosphorus removal from wastewater | |
| CN101665278A (zh) | 一种复合水处理除磷絮凝剂 | |
| RU2411191C1 (ru) | Коагулянт-адсорбент для очистки промышленных стоков от тяжелых металлов, способ получения коагулянта-адсорбента для очистки промышленных стоков от тяжелых металлов и способ использования коагулянта-адсорбента для очистки промышленных стоков от тяжелых металлов | |
| JP2001347104A (ja) | 粉末状浄化処理剤および上水および排水の浄化処理方法 | |
| CN106745627A (zh) | 一种易回收的污水除磷剂及其制备方法和应用 | |
| CN102166452B (zh) | 一种硝酸分解磷矿过程中所得酸解液的助滤净化方法 | |
| JPH10277541A (ja) | ゼオライト系水質浄化剤 | |
| CN112047417B (zh) | 一种硅藻土污水处理剂及其制备方法 | |
| CN108640175A (zh) | 一种新型净水剂的生产方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |