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CN108468103A - A kind of stealthy fiber and its manufacturing method - Google Patents

A kind of stealthy fiber and its manufacturing method Download PDF

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Publication number
CN108468103A
CN108468103A CN201810279814.1A CN201810279814A CN108468103A CN 108468103 A CN108468103 A CN 108468103A CN 201810279814 A CN201810279814 A CN 201810279814A CN 108468103 A CN108468103 A CN 108468103A
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doughnut
mass parts
spinning
stealthy
dry
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CN201810279814.1A
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不公告发明人
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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/08—Addition of substances to the spinning solution or to the melt for forming hollow filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/05—Cellulose or derivatives thereof
    • D06M15/09—Cellulose ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/13—Alginic acid or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

A kind of durable have electro-magnetic wave absorption and shielding action, and low cost, low-maintenance, the stealthy fiber of long-life.It is characterized in that：Doughnut surface is coated with the film layer that stealth material is formed, and internal spray has stealthy powder.Manufacturing method, which is characterized in that a diameter of 7~1000 μm of the doughnut.Different stealthy raw materials is attached on doughnut by the present invention by interior sprinkling and outer coating two ways, improves absorbing property and durability.

Description

A kind of stealthy fiber and its manufacturing method
Technical field
The present invention relates to a kind of high-performance fiber field, specially stealthy fiber.
Background technology
In modern war, the technology development of absorbing material is to improve one of the key technology of stealth technology.Absorbing material The principle of work and power is that the energy of incident electromagnetic wave is converted to heat energy loss to fall, to avoid the reflection of electromagnetic wave.To realize This high efficiency absorption to electromagnetic wave must satisfy two conditions：First electromagnetic wave can enter inside absorbing material without Strong reflection can occur in incidence surface；Next electromagnetic wave for entering material internal is expeditiously converted to thermal energy.Often The absorbing material seen concentrates on ferrite, metal powder, ceramics, conducting polymer and carbon material, main mechanism It is attributed to resistance loss, magnetic loss and dielectric loss.With the development of modern science, wave-absorbing and camouflage material is proposed " thin, Gently, wide, strong " etc. the higher requirement of aspect of performance, preparing the NEW TYPE OF COMPOSITE wave-absorbing powder for meeting above-mentioned requirements has important section Learn meaning and practical value.
Absorbing material is also known as stealthy or camouflage material, is to the very small material of wave reflection.The absorption of wave mainly passes through two Kind mode：First, resonance reduces the reflection of wave by resonance that is, when the thickness of material is equal to the 1/4 of wave wavelength.Second is that supporting by the arm It is miscellaneous, by the way that electrical loss or magnetic loss substance are added in the material, conducted under electromagnetic field effect using electrical loss substance electric current by To the limitation of finite conductivity, so that the wave into material is converted into thermal energy and lose.Or utilize magnetic loss substance internal dipole Son limitation of movement under electromagnetic field determines magnetic conductivity limitation and electromagnetic energy is made to be converted into thermal energy.
Currently, foam type absorbing material is in terms of stealthy and shielding, mostly in foamed plastics, foam rubber and foamed ceramics On the basis of studied, or add carbon fiber and ferrite to make absorbent in epoxy resin, be fabricated to coating type, patch-type, layer Template and foam type.Such as a kind of novel wave absorbing coating that European GAMMA companies release, absorbent is done using polycrystalline iron fiber, It is light-weight, and can realize efficient absorption radar wave in very wide frequency range.The U.S. produces and exports the stealthy painting in Europe at present Material can reach 12--25db in 2--18GHz frequency range internal absorption factors.Japan is mixed using ferrite class absorbing material with mortar As wall covering, for shielding electromagnetic waves etc..In contrast, the processing technology of above-mentioned absorbing material is complicated, and technology is wanted Ask stringent, and cost of manufacture is high.
Invention content
Durable there is electro-magnetic wave absorption and shielding action, and low cost, low-dimensional the object of the present invention is to provide a kind of Shield, the stealthy fiber of long-life.
A kind of stealthy fiber, it is characterised in that：Doughnut surface is coated with the film layer that stealth material is formed, and inside has Stealthy powder.Manufacturing method, which is characterized in that a diameter of 7~1000 μm of the doughnut；Fiber wall thickness≤34nm , it is as follows：
（1）Solvent is added in slice raw material, spinning solution is made, the slice raw material is that PET of the water content less than 0.01% is cut Piece and PBT slices；
（2）By 100-200 mass parts carbon nanotube, 20-30 mass parts polyethylene glycol oxide, 1-8 mass parts titanate esters, 5-16 mass Dispersion 30 minutes is sanded in part polyvinyl alcohol under high shear, and fineness of materials is made to be less than 30um, controls normal pressure and temperature 80 ~90 DEG C, 5.5 hours maintenance effect time, obtain stealthy powder；
The spinning of doughnut：The spinning process of doughnut is to use dry-jet wet spinning, and metering revolution speed is 11-20r/ Min, spinning pressure 0.2-0.3Mpa, the spinning head that slurries are formed from two concentric tubes squeezes out, after the dry-spinning path of 70mm, It is solidified in the aqueous solution that the content of dimethylformamide for being 25 DEG C in temperature is 10-13%, hollow-fibre membrane of coming into being is drawn through three It stretches, two washings, is wound with the speed of 45m/min, doughnut is made, in this spinning process, the sprinkling of spinning head inner cavity is hidden Body powder, pressure are 2.5 × 10-3MPa。
（3）By 3-15 mass parts TiCl4, 8-11 mass parts polyethylene glycol, 7-20 mass parts sodium carboxymethylcellulose, 5-15 Mass parts chitosan, the mixing of 0.5-5 mass parts alginates, alginate is aqueous solution, by alginate under room temperature It is dissolved in water to be made, degree of polymerization 100-700, aqueous solution mass fraction is 2-10%, and high-speed stirred obtains colloidal sol；Alginate For sodium alginate.
（4）By step（2）Obtained doughnut is immersed in step（3）In obtained sol solutions, surface film knot is formed Then structure is dried, drying mode is drying after naturally dry or solvent displacement, and film thickness is 1-6 um.
Step（1）The solvent is dimethylformamide, dimethylacetylamide, ethylene carbonate, sodium sulfocyanate, zinc oxide Or at least one of dilauryl thiodipropionate
The doughnut is 10~100 μm of multi-walled pipes, 3~10 μm of few wall pipe, 3~5 μm of double-wall pipes, 0.3~3 μm of single wall One or more compounds in pipe.
Beneficial effects of the present invention：
（1）The present invention passes through TiCl4, polyethylene glycol, sodium carboxymethylcellulose, chitosan and alginate formed from recombination Then sol system is attached to doughnut surface of polyester, have stable structure, good absorbing property and durability；
（2）Doughnut has the structure and performance that fiber can be changed in more governing factors, can pass through the knot of control doughnut The aperture of micropore can effectively adhere to absorbing material on structure and fibre wall；The cavity of inside hollow fibre can also be placed in suction wave Substance, the preparation method of stealthy doughnut of the invention are then the sprinklings used when preparing stealthy powder by doughnut Doughnut is added in mode.For realizing that the continuous production of stealthy doughnut has important practical value.
（3）Use the degree of polymerization for 100-700, aqueous solution mass fraction is the alginate of 2-10%, especially alginic acid Sodium can be more conducive to be formed from recombination sol system than other compositions, improve adhesion property.
Different stealthy raw materials is attached on doughnut by the present invention by interior sprinkling and outer coating two ways, is improved Absorbing property and durability.
（4）The suction wave ranging from 8-75GHz widebands audio range frequency range internal absorption factor of the present invention reaches 30db or more.
Specific implementation mode
Embodiment 1
（1）Spinning solution is made in the solvent dimethylformamide that the slice raw material of 300 parts by weight is added to 1000 parts by weight, described It is PET slice and PBT slice of the water content less than 0.01% to be sliced raw material；
（2）By 100 mass parts carbon nanotubes, 30 mass parts polyethylene glycol oxides, 8 mass parts titanate esters, 16 mass parts polyvinyl alcohol Dispersion 30 minutes is sanded under high shear, it is 20um to make fineness of materials, controls 90 DEG C of normal pressure and temperature, when maintenance effect Between 5.5 hours, obtain stealthy powder；
The spinning of doughnut：The spinning process of doughnut is to use dry-jet wet spinning, and metering revolution speed is 11r/min, is spun Silk pressure is 0.3Mpa, and the spinning head that slurries are formed from two concentric tubes squeezes out, and is 25 in temperature after the dry-spinning path of 70mm DEG C content of dimethylformamide be 13% aqueous solution in solidify, come into being hollow-fibre membrane through three stretch, two washing, with The speed of 45m/min is wound, and doughnut is made, and in this spinning process, stealthy powder is sprayed in spinning head inner cavity, and pressure is 2.5×10-3MPa。
（3）By 3 mass parts TiCl4, 11 mass parts polyethylene glycol, 20 mass parts sodium carboxymethylcelluloses, 15 mass parts shells Glycan, the mixing of 5 mass parts alginates, alginate is aqueous solution, and alginate, which is dissolved in water, under room temperature is made, The degree of polymerization is 700, and aqueous solution mass fraction is 10%, and high-speed stirred obtains colloidal sol；Alginate is sodium alginate.
（4）By step（2）Obtained doughnut is immersed in step（3）In obtained sol solutions, surface film knot is formed Then structure is dried, drying mode is drying after naturally dry or solvent displacement, and film thickness is 4 um.
Embodiment 2
（1）Spinning solution is made in the dilauryl thiodipropionate solvent that 300 parts by weight slice raw material is added to 1000 parts by weight, The slice raw material is PET slice and PBT slice of the water content less than 0.01%；
（2）100 mass parts carbon nanotubes, 20 mass parts polyethylene glycol oxides, 1 mass parts titanate esters, 5 mass parts polyvinyl alcohol are existed Dispersion 30 minutes is sanded under high shear, makes fineness of materials 15um, controls 80 DEG C of normal pressure and temperature, maintenance effect time 5.5 hours, obtain stealthy powder；
The spinning of doughnut：The spinning process of doughnut is to use dry-jet wet spinning, and metering revolution speed is 20r/min, is spun Silk pressure is 0.3Mpa, and the spinning head that slurries are formed from two concentric tubes squeezes out, and is 25 in temperature after the dry-spinning path of 70mm DEG C content of dimethylformamide be 10% aqueous solution in solidify, come into being hollow-fibre membrane through three stretch, two washing, with The speed of 45m/min is wound, and doughnut is made, and in this spinning process, stealthy powder is sprayed in spinning head inner cavity, and pressure is 2.5×10-3MPa。
（3）By 3 mass parts TiCl4, 8 mass parts polyethylene glycol, 7 mass parts sodium carboxymethylcelluloses, 5 mass parts shells it is poly- Sugar, the mixing of 0.5 mass parts alginate, alginate is aqueous solution, and alginate, which is dissolved in water, under room temperature is made, The degree of polymerization is 100, and aqueous solution mass fraction is 2%, and high-speed stirred obtains colloidal sol；Alginate is sodium alginate.
（4）By step（2）Obtained doughnut is immersed in step（3）In obtained sol solutions, surface film knot is formed Then structure is dried, drying mode is drying after naturally dry or solvent displacement, and film thickness is 6 um.
Comparative example 1
Nozzle cavity does not spray stealthy powder, remaining is the same as embodiment 1.
Comparative example 2
Use the degree of polymerization for 900, the potassium alginate that aqueous solution mass fraction is 30%, the sodium alginate of alternate embodiment 1 is water-soluble Liquid, remaining is same as Example 1.
Comparative example 3
20 mass parts polyethylene glycol oxides, 1 mass parts titanate esters, 5 mass parts polyvinyl alcohol are not added, only add carbon nanotube, He is the same as embodiment 2.
Table 1
Specific resistance Ω .cm 8-75GHz wideband wave band attenuations（db） Specific resistance Ω .cm after 20 washings Wideband wave band attenuation db after 20 washings
Embodiment 1 103 37 7*103 25
Embodiment 2 0.5*103 35 6*103 22
Comparative example 1 4*104 18 9*104 10
Comparative example 2 3*103 30 3*104 17
Comparative example 3 8*103 22 104 11
It follows that when stealthy powder is not sprayed in inside, absorbing property, resistive performance are all significantly worse than the technical side of the present invention Case, when effect colloidal sol film structure is not formed in outside, absorbing property and resistive performance decline apparent after washing repeatedly.

Claims (5)

1. a kind of stealthy fiber, it is characterised in that：Stealthy fiber is the film that doughnut surface is coated with that stealth material is formed Layer, there is stealthy powder in inside.
2. a kind of manufacturing method of stealthy fiber, which is characterized in that a diameter of 7~1000 μm of the doughnut, it is specific to walk It is rapid as follows：
（1）Solvent is added in slice raw material, spinning solution is made, the slice raw material is that PET of the water content less than 0.01% is cut Piece and PBT slices；
（2）By 100-200 mass parts carbon nanotube, 20-30 mass parts polyethylene glycol oxide, 1-8 mass parts titanate esters, 5-16 mass Dispersion 30 minutes is sanded in part polyvinyl alcohol under high shear, and fineness of materials is made to be less than 30um, controls normal pressure and temperature 80 ~90 DEG C, 5.5 hours maintenance effect time, obtain stealthy powder；
The spinning of doughnut：The spinning process of doughnut is to use dry-jet wet spinning, and metering revolution speed is 11-20r/ Min, spinning pressure 0.2-0.3Mpa, the spinning head that slurries are formed from two concentric tubes squeezes out, after the dry-spinning path of 70mm, It is solidified in the aqueous solution that the content of dimethylformamide for being 25 DEG C in temperature is 10-13%, hollow-fibre membrane of coming into being is drawn through three It stretches, two washings, is wound with the speed of 45m/min, doughnut is made, in this spinning process, the sprinkling of spinning head inner cavity is hidden Body powder, pressure are 2.5 × 10-3MPa；
（3）By 3-15 mass parts TiCl4, 8-11 mass parts polyethylene glycol, 7-20 mass parts sodium carboxymethylcellulose, 5-15 mass Part chitosan, the mixing of 0.5-5 mass parts alginates, high-speed stirred obtain colloidal sol；
（4）By step（2）Obtained doughnut is immersed in step（3）In obtained sol solutions, surface film structure is formed, so After dry, drying mode is dry after naturally dry or solvent displacement, and film thickness is 1-6 um.
3. method as claimed in claim 2, which is characterized in that step（1）The solvent is dimethylformamide, dimethyl second At least one of amide, ethylene carbonate, sodium sulfocyanate, zinc oxide or dilauryl thiodipropionate.
4. method as claimed in claim 2, which is characterized in that multi-walled pipes, 3~10 μs of the doughnut for 10~100 μm One or more compounds in few wall pipe of m, 3~5 μm of double-wall pipes, 0.3~3 μm of single-walled pipe.
5. method as claimed in claim 2, which is characterized in that alginate is sodium alginate.
CN201810279814.1A 2018-04-01 2018-04-01 A kind of stealthy fiber and its manufacturing method Pending CN108468103A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113777679A (en) * 2021-08-13 2021-12-10 中国航天空气动力技术研究院 A kind of topological stealth structure and preparation method thereof
CN116497593A (en) * 2023-05-17 2023-07-28 上海派志数据科技有限公司 Preparation method of stealth carbon fiber

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Publication number Priority date Publication date Assignee Title
CN101871136A (en) * 2010-06-11 2010-10-27 东华大学 A kind of infrared stealth fiber and its preparation method
US20120237752A1 (en) * 2008-06-05 2012-09-20 Performance Indicator, Llc Photoluminescent fibers, compositions and fabrics made therefrom
CN103521091A (en) * 2013-10-25 2014-01-22 滁州品创生物科技有限公司 Composite hollow fiber membrane
CN104990459A (en) * 2015-07-06 2015-10-21 苏州工业园区高性能陶瓷纤维工程中心有限公司 Radar stealth and infrared stealth integrated stealth tarpaulin and making method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120237752A1 (en) * 2008-06-05 2012-09-20 Performance Indicator, Llc Photoluminescent fibers, compositions and fabrics made therefrom
CN101871136A (en) * 2010-06-11 2010-10-27 东华大学 A kind of infrared stealth fiber and its preparation method
CN103521091A (en) * 2013-10-25 2014-01-22 滁州品创生物科技有限公司 Composite hollow fiber membrane
CN104990459A (en) * 2015-07-06 2015-10-21 苏州工业园区高性能陶瓷纤维工程中心有限公司 Radar stealth and infrared stealth integrated stealth tarpaulin and making method thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113777679A (en) * 2021-08-13 2021-12-10 中国航天空气动力技术研究院 A kind of topological stealth structure and preparation method thereof
CN116497593A (en) * 2023-05-17 2023-07-28 上海派志数据科技有限公司 Preparation method of stealth carbon fiber
CN116497593B (en) * 2023-05-17 2024-09-24 上海派志数据科技有限公司 Preparation method of stealth carbon fiber

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Application publication date: 20180831