CN108467761A - Machine oil for compressor and the compressor with it - Google Patents
Machine oil for compressor and the compressor with it Download PDFInfo
- Publication number
- CN108467761A CN108467761A CN201810383039.4A CN201810383039A CN108467761A CN 108467761 A CN108467761 A CN 108467761A CN 201810383039 A CN201810383039 A CN 201810383039A CN 108467761 A CN108467761 A CN 108467761A
- Authority
- CN
- China
- Prior art keywords
- polyol ester
- compressor
- machine oil
- quality
- antioxidant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
- C10M105/32—Esters
- C10M105/38—Esters of polyhydroxy compounds
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04C—ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT PUMPS
- F04C29/00—Component parts, details or accessories of pumps or pumping installations, not provided for in groups F04C18/00 - F04C28/00
- F04C29/02—Lubrication; Lubricant separation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/02—Viscosity; Viscosity index
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/09—Characteristics associated with water
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04C—ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT PUMPS
- F04C2210/00—Fluid
- F04C2210/14—Lubricant
- F04C2210/142—Ester
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Compressor (AREA)
Abstract
The invention discloses a kind of machine oil for compressor and the compressor with it, the machine oil for compressor includes:First polyol ester and the second polyol ester, first polyol ester is synthesized by pentaerythrite with the polyhydric aliphatic acid of carbon number 6~12, second polyol ester is synthesized by least one of neopentyl glycol, trimethylolpropane and dipentaerythritol polyalcohol and oleic acid, the mass ratio of first polyol ester and second polyol ester is w, is met:5/95≤w≤95/5.Machine oil according to the present invention for compressor, by using the mixing of the first polyol ester and the second polyol ester according to a certain percentage thereby using there is lower solubility between the machine oil and refrigerant of compressor, and lubricity is preferable, therefore, it is fully cooled even if can also be realized when refrigeration dosage is relatively low.
Description
Technical field
The invention belongs to the machine oil manufacturing technology fields of compressor, in particular to a kind of machine oil for compressor
And the compressor with it.
Background technology
Currently, most domestic domestic air conditioning uses hydrofluorocarbon R410A and R32 as refrigerant, coordinate with the refrigerant
The lubricating oil used is polyol ester or polyvinylether.But the intermiscibility of current polyol ester and polyvinylether and refrigerant compared with
Greatly, to ensure that moving component has the oil lubrication of enough viscosity in compressor, need to improve polyol ester and polyvinylether
Viscosity grade causes cost increase.And lubricating oil and refrigerant intermiscibility are excessive, and it also can be in order to reach the performance of air-conditioning system
It is required that filling more refrigerants, the waste of refrigerant will also result in.
Invention content
The present invention is directed at least solve one of the technical problems existing in the prior art.For this purpose, the present invention proposes that one kind is cold
The solubility for freezing machine oil and refrigerant is relatively low, the performance of system and the reliability of compressor in the case of less refrigerant enclosed volume
The more stable machine oil for compressor and the compressor with it.
The machine oil for compressor according to a first aspect of the present invention includes:First polyol ester, first polyalcohol
Ester is synthesized by pentaerythrite with the polyhydric aliphatic acid of carbon number 6~12;Second polyol ester, second polyol ester is by new penta 2
At least one of alcohol, trimethylolpropane and dipentaerythritol polyalcohol and oleic acid synthesis;First polyol ester with it is described
The mass ratio of second polyol ester is w, is met:5/95≤w≤95/5.
Machine oil according to the present invention for compressor, by using the first polyol ester and the second polyol ester according to one
The mixing of certainty ratio between the machine oil and refrigerant of compressor thereby using there is lower solubility, and lubricity is preferable, because
This, is fully cooled even if can also be realized when refrigeration dosage is relatively low.
In some embodiments, further include for the machine oil of compressor:Squeeze antiwear additive, antioxidant, sour agent for capturing, metal
At least one of activating agent.
In some embodiments, further include for the machine oil of compressor:Squeeze antiwear additive, the quality for squeezing antiwear additive
For b, the quality sum of first polyol ester and second polyol ester is a, is met:0.05%≤b/a≤10%.
In some embodiments, the quality for squeezing antiwear additive is b, first polyol ester and more than second yuan described
The quality sum of alcohol ester meets for a:0.1%≤b/a≤5.0%.
In some embodiments, the quality for squeezing antiwear additive is b, first polyol ester and more than second yuan described
The quality sum of alcohol ester meets for a:0.5%≤b/a≤3.0%.
In some embodiments, further include for the machine oil of compressor:Antioxidant, the antioxidant are phenolic antioxidant,
The quality of the antioxidant is c, and the quality sum of first polyol ester and second polyol ester is a, is met:
0.01%≤c/a≤3%.
In some embodiments, the quality of the antioxidant is c, first polyol ester and second polyol ester
Quality sum be a meet:0.05%≤c/a≤1.5%.
In some embodiments, further include for the machine oil of compressor:Antioxidant, the antioxidant are amine antioxidants,
The quality of the antioxidant is c, and the quality sum of first polyol ester and second polyol ester is a, is met:
0.01%≤c/a≤2%.
In some embodiments, the quality of the antioxidant is c, first polyol ester and second polyol ester
Quality sum be a, meet:0.05%≤c/a≤1.0%.
In some embodiments, further include for the machine oil of compressor:The quality of sour agent for capturing, the acid agent for capturing is d,
The quality sum of first polyol ester and second polyol ester is a, is met:0.01%≤d/a≤2.0%.
In some embodiments, the quality of the sour agent for capturing is d, first polyol ester and second polyalcohol
The quality sum of ester is a, is met:0.02%≤d/a≤1.0%.
In some embodiments, further include for the machine oil of compressor:Metal active agent, the quality of the metal active agent
For e, the quality sum of first polyol ester and second polyol ester is a, is met:0.0001%≤e/a≤
0.01%.
Compressor according to a second aspect of the present invention, including:Shell, the shell is interior to be equipped with according to a first aspect of the present invention
Machine oil;Compression mechanism, the compression mechanism are installed in the shell.
Compressor according to the present invention is by using machine oil according to the present invention, to make compressor in less refrigerant
The performance of system and the reliability of compressor are more stable in the case of enclosed volume.
The additional aspect and advantage of the present invention will be set forth in part in the description, and will partly become from the following description
Obviously, or practice through the invention is recognized.
Description of the drawings
The above-mentioned and/or additional aspect and advantage of the present invention will become in the description from combination following accompanying drawings to embodiment
Obviously and it is readily appreciated that, wherein:
Fig. 1 is the structural schematic diagram of compressor according to the ... of the embodiment of the present invention;
Fig. 2 is the cycle schematic diagram of refrigeration equipment according to the present invention;
Fig. 3 is the mixture intermiscibility schematic diagram of machine oil and refrigerant according to the present invention.
Reference numeral:
Compressor 100;
Shell 1;Compression mechanism 2;Machine oil 3;Condenser 4;Expansion valve 5;Evaporator 6.
Specific implementation mode
The embodiment of the present invention is described below in detail, examples of the embodiments are shown in the accompanying drawings, wherein from beginning to end
Same or similar label indicates same or similar element or element with the same or similar functions.Below with reference to attached
The embodiment of figure description is exemplary, and is only used for explaining the present invention, and is not considered as limiting the invention.
The machine oil 3 according to the ... of the embodiment of the present invention for compressor is described referring to Fig. 1-Fig. 3 and with its compression
Machine 100.
In compressor 100, needing to be filled with makes moving component in compressor 100 have the machine oil 3 of enough viscosity to lubricate, and also needs
It is filled with cooling refrigerant, that is, needs the mixture for being filled with machine oil 3 and refrigerant, so that compressor 100 can be transported normally
Turn.Wherein, the machine oil 3 for being used for compressor can be refrigerator oil 3.
Machine oil 3 according to the ... of the embodiment of the present invention for compressor includes:First polyol ester and the second polyol ester, the
One polyol ester is synthesized by pentaerythrite with the polyhydric aliphatic acid of carbon number 6~12, and the second polyol ester is by neopentyl glycol, three hydroxyl first
At least one of base propane and dipentaerythritol polyalcohol and oleic acid synthesis.In some specific examples, the first polyalcohol can
With the polyol ester that the aliphatic acid for being 9 by the aliphatic acid and/or carbon number of pentaerythrite and carbon number 8 synthesizes, the second polyol ester can
To be the polyol ester synthesized by least one of neopentyl glycol, trimethylolpropane and dipentaerythritol polyalcohol and oleic acid.
The mass ratio of first polyol ester and the second polyol ester is w, is met:5/95≤w≤95/5.For example, more than first
The mass ratio w=27/73 of first alcohol ester and the second polyol ester either w=53/47 or w=82/18.
For example refrigerant is difluoromethane and five fluoromethane mix refrigerants, the liquid of the first polyol ester and the refrigerant
Mixture dissolves each other completely at 15~30 DEG C, and the liquid mixture of the second polyol ester and the refrigerant is in oil content (weight
Than) be 3%~70% when, which occurs two separate at 70 DEG C or less.
For example refrigerant is difluoromethane, difluoromethane and five fluoromethane mix refrigerants, when machine oil 3 and the refrigeration dosage form
At liquid mixture oil content (weight ratio) be 3%~40% when, which two layers occur at 70 DEG C or less
Separation;When the liquid mixture that machine oil 3 and the refrigerant are formed is when oil content (weight ratio) is 60% or more, which mixes
Object mixes at 20 DEG C~40 DEG C.
Fig. 3 is to be measured according to professional standard " 0699 refrigerator oils 3 of SH-T and refrigerant compatibility test method ".By the party
The refrigerator oil 3 that method measures in the hatched example areas of Fig. 3, i.e., is formed with refrigerant liquid mixture when machine oil 3 and the refrigerant
For liquid mixture when oil content (weight ratio) is 3%~40%, which occurs two separate at 60 DEG C or less, separation
Have different solubility respectively two layers, wherein containing liquid coolant it is more for rich refrigerant layer, it is more for richness containing refrigerator oil 3
Oil reservoir.
Here, the situation of machine oil 3 and the liquid mixture of refrigerant formation in oil content (weight ratio) 70% or more,
It occurs mainly in inside compressor 100, in order to ensure that 100 compression mechanism 2 of compressor can adequately be lubricated, it is desirable that freezing
Machine oil 3 and refrigerant are wanted to dissolve each other, and such machine oil 3 can fully be lubricated compression mechanism 2.If occurred in the region
If layering, it is rich refrigerant layer to be lubricated to compression mechanism 2, can not be to compressor since the viscosity of rich refrigerant layer is too low
Structure 2 carries out sufficient lubrication, may lead to 100 integrity problem of compressor.Therefore it is required that when the liquid of machine oil 3 and refrigerant formation
In oil content (weight ratio) 60% or more, which mixes body mixture at 20 DEG C~40 DEG C.
Since the machine oil 3 of the present invention has lower solubility with refrigerant, can use in systems less
Refrigerant reach the ability of refrigerating plant requirement.
The present invention by refrigeration equipment performance the study found that the first polyol ester is matched with the second polyol ester as above-mentioned
Machine oil 3 than mixing has lower solubility, and viscosity is enough, in the case where 3 viscosity of machine oil reduces, even if making
Less refrigeration dose is enclosed in cool equipment, refrigeration equipment has higher Energy Efficiency Ratio, is shown in Table described in 1.
Table 1
The viscosity of the refrigerator oil 3 of present invention kinematic viscosity at 40 DEG C be 68mm2/s hereinafter, it is optimal be 32mm2/s~
56mm2/s, because 100 temperature range of operation of compressor is minimum can to reach -20 DEG C, to avoid causing due to low refrigerant solubility
Viscosity is excessively high under oil low-temperature, therefore it is required that oil viscosity index is 95 or more.
The machine oil 3 that first polyol ester of mentioned component is mixed to form with the second polyol ester is with refrigerant with lower
Solubility, therefore the refrigerating capacity of refrigerating plant requirement can be reached in compressor 100 with less refrigerant.
The machine oil 3 for compressor according to embodiments of the present invention, by using the first polyol ester and more than second yuan
The mixing of alcohol ester according to a certain percentage is moistened thereby using there is lower solubility between the machine oil 3 and refrigerant of compressor
Slip is preferable, therefore, is fully cooled even if can also be realized when refrigeration dosage is relatively low.
In some embodiments, further include for the machine oil of compressor 3:Squeeze antiwear additive, antioxidant, sour agent for capturing, gold
Belong at least one of activating agent, is added in the machine oil 3 for compressor and squeezes antiwear additive, antioxidant, sour agent for capturing, metal
It is one or more in activating agent, there can be better performance thereby using the machine oil 3 in compressor.
In some embodiments, further include squeezing antiwear additive for the machine oil of compressor 3, addition, which squeezes, in machine oil 3 resists
Grinding agent can improve the lubricating ability of machine oil 3 under heavy loading, reduce the friction coefficient between movement component, improve the wear-resistant of component
Damage ability reduces component abrasion, improves the projected life of compressor 100, squeezes antiwear additive at least from molecular formula c or molecular formula d
One is selected in the group that the alkyl polyoxyalkylene phosphate of representative is formed, molecular formula c and molecular formula d are as follows:
Wherein, R4 is an alkyl with 1~8 carbon atom, and R5 is H or alkane with 1~3 carbon atom
Base.
When it is mentioned component to squeeze antiwear additive, the quality for squeezing antiwear additive is b, the first polyol ester and the second polyalcohol
The quality sum of ester is a, is met:0.05%≤b/a≤10% can make machine oil 3 have preferable squeeze with this mass ratio
Wear-resistant characteristic.
In further embodiments, it squeezes antiwear additive and can also be phosphorus-containing compound, specifically, squeezing antiwear additive can be
It is one or more in phosphate, phosphate amine salt and phosphite ester etc..
When it is phosphorus-containing compound to squeeze antiwear additive, the quality for squeezing antiwear additive is b, the first polyol ester and described second
The quality sum of polyol ester meets for a:0.1%≤b/a≤5.0%, when the quality for squeezing antiwear additive is b and the first polyalcohol
When the quality sum of ester and the second polyol ester is that the ratio of a meets this kind of condition, machine oil 3 can be made to have and squeeze wear-resistant spy
Property.
Preferably, the quality of antiwear additive is squeezed as b, and the quality sum of the first polyol ester and the second polyol ester is full for a
Foot:0.5%≤b/a≤3.0%, when the quality that the quality for squeezing antiwear additive is b and the first polyol ester and the second polyol ester
The sum of when meeting this kind of condition for the ratio of a, machine oil 3 can be made to have and preferable squeeze antiwear characteristics.
In some embodiments, further include for the machine oil of compressor 3:Antioxidant, adding antioxidant in machine oil 3 can be with
Increase the high-temperature stability of refrigerator oil 3, it is not easy to deteriorate, antioxidant can be phenolic antioxidant, optionally, phenolic antioxidant
Can be 2,6 di t butyl phenol, 2,6- di-t-butyls Pyrogentisinic Acid, 4,4 '-methylene-bis(2,6-di-t-butyl phenol)s etc.
In one kind, the quality of antioxidant is c, and the quality sum of the first polyol ester and the second polyol ester is a, is met:0.01%
≤ c/a≤3%.
When the ratio that the quality of antioxidant is c and the quality sum of the first polyol ester and the second polyol ester is a meets
It can make machine oil 3 that there is oxidation resistant characteristic when the condition.
Preferably, the quality of antioxidant is c, and the quality sum of the first polyol ester and the second polyol ester is a satisfactions:
0.05%≤c/a≤1.5%.
When the ratio that the quality of antioxidant is c and the quality sum of the first polyol ester and the second polyol ester is a meets
It can make machine oil 3 that there is preferable oxidation resistant characteristic when the condition.
In further embodiments, further include for the machine oil of compressor 3:Antioxidant, antioxidant are amine antioxidants, amine
Kind antioxidant can be selected from dioctyl diphenylamine, dinonyldiphenylamine, butyl, and octyl diphenylamine, N, N '-di-sec-butyls are to benzene
One kind in diamines, phenyl-α-naphthylamine, the quality of antioxidant are c, first polyol ester and second polyol ester
Quality sum is a, is met:0.01%≤c/a≤2%.
When the ratio that the quality of antioxidant is c and the quality sum of the first polyol ester and the second polyol ester is a meets
It can make machine oil 3 that there is oxidation resistant characteristic when the condition.
In some embodiments, the quality of antioxidant is c, and the quality sum of the first polyol ester and the second polyol ester is
A meets:0.05%≤c/a≤1.0%.
When the ratio that the quality of antioxidant is c and the quality sum of the first polyol ester and the second polyol ester is a meets
It can make machine oil 3 that there is preferable oxidation resistant characteristic when the condition.
Antioxidant can be mixed by above-mentioned phenolic antioxidant and above-mentioned amine antioxidants in yet other embodiments,.
In some embodiments, further include for the machine oil of compressor 3:Sour agent for capturing adds sour agent for capturing in machine oil 3
Oil product can be prevented to be acidified, prevent copper facing, optionally, sour agent for capturing can be the compound or carbodiimidization for having epoxide ring
Close object, the quality of sour agent for capturing is d, and the quality sum of the first polyol ester and the second polyol ester is a, is met:0.01%≤
D/a≤2.0%.
When the quality of sour agent for capturing be d and the quality sum of the first polyol ester and the second polyol ester to be that a meets above-mentioned
It can make machine oil 3 that there is the characteristic for reducing acid value when condition.
Preferably, the quality of sour agent for capturing is d, and the quality sum of the first polyol ester and the second polyol ester is a, full
Foot:0.02%≤d/a≤1.0%.
When the quality of sour agent for capturing be d and the quality sum of the first polyol ester and the second polyol ester to be that a meets above-mentioned
It can make machine oil 3 that there is the preferable characteristic for reducing acid value when condition.
In some embodiments, further include for the machine oil of compressor 3:Metal active agent, metal deactivator can be benzene
And triazole derivative and thiadiazoles derivative, the quality of metal active agent is e, the matter of the first polyol ester and the second polyol ester
The sum of amount is a, is met:0.0001%≤e/a≤0.01%.
When the ratio that the quality of metal active agent is e and the quality sum of the first polyol ester and the second polyol ester is a
When meeting above-mentioned condition, it can make machine oil 3 that there is the characteristic for making metal deactivating.
Preferably, the quality of metal active agent is e, and the quality sum of the first polyol ester and the second polyol ester is a, full
Sufficient e/a=0.005%.
When the ratio that the quality of metal active agent is e and the quality sum of the first polyol ester and the second polyol ester is a
When meeting above-mentioned condition, it can make machine oil 3 that there is the characteristic for preferably making metal deactivating.
Compressor 100 according to a second aspect of the present invention, including:Shell 1 and compression mechanism 2, shell 1 is interior to be equipped with according to this
The machine oil 3 of invention first aspect, compression mechanism 2 are installed in shell 1.
In some embodiments, motor is accommodated in shell 1, motor is for driving compression mechanism 2, compression mechanism
2 for compressing refrigerant, and the machine oil 3 in shell 1 is used to ensure the lubrication of each component in compression mechanism 2.
As depicted in figs. 1 and 2, compressor 100 can also include condenser 4, expansion valve 5 and evaporator 6, compressor 100
Refrigerant compression is discharged at high temperature and high pressure gas in condenser 4, condenser 4 makes system by carrying out heat exchange with heat exchange object
Cryogen condenses, and condensed refrigerant is depressurized by expansion valve 5, then into evaporator 6, freezed in evaporator 6
Agent carries out heat exchange with heat exchange object, to flash to gas, is finally drawn into compressor 100 and completes a cycle.
Compressor 100 according to the ... of the embodiment of the present invention is by using machine oil 3 according to the present invention, to make compressor 100
It is more stable in the performance of system in the case of less refrigerant enclosed volume and the reliability of compressor 100.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " illustrative examples ",
The description of " example ", " specific example " or " some examples " etc. means specific features described in conjunction with this embodiment or example, knot
Structure, material or feature are included at least one embodiment or example of the invention.In the present specification, to above-mentioned term
Schematic representation may not refer to the same embodiment or example.Moreover, specific features, structure, material or the spy of description
Point can be combined in any suitable manner in any one or more of the embodiments or examples.
Although an embodiment of the present invention has been shown and described, it will be understood by those skilled in the art that:Not
In the case of being detached from the principle of the present invention and objective a variety of change, modification, replacement and modification can be carried out to these embodiments, this
The range of invention is limited by claim and its equivalent.
Claims (13)
1. a kind of machine oil for compressor, which is characterized in that including:
First polyol ester, first polyol ester are synthesized by pentaerythrite with the polyhydric aliphatic acid of carbon number 6~12;
Second polyol ester, second polyol ester is by neopentyl glycol, trimethylolpropane and dipentaerythritol at least one
Kind polyalcohol and oleic acid synthesis;
The mass ratio of first polyol ester and second polyol ester is w, is met:5/95≤w≤95/5.
2. the machine oil according to claim 1 for compressor, which is characterized in that further include:Squeeze antiwear additive, antioxygen
At least one of agent, sour agent for capturing, metal active agent.
3. the machine oil according to claim 1 for compressor, which is characterized in that including:Squeeze antiwear additive, the extruding
The quality of antiwear additive is b, and the quality sum of first polyol ester and second polyol ester is a, is met:0.05%≤
B/a≤10%.
4. the machine oil according to claim 3 for compressor, which is characterized in that meet:0.1%≤b/a≤5.0%.
5. the machine oil according to claim 3 for compressor, which is characterized in that meet:0.5%≤b/a≤3.0%.
6. the machine oil according to claim 1 for compressor, which is characterized in that including:Antioxidant, the antioxidant are
Phenolic antioxidant, the quality of the antioxidant are c, and the quality sum of first polyol ester and second polyol ester is
A meets:0.01%≤c/a≤3%.
7. the machine oil according to claim 6 for compressor, which is characterized in that meet:0.05%≤c/a≤1.5%.
8. the machine oil according to claim 1 for compressor, which is characterized in that including:Antioxidant, the antioxidant are
Amine antioxidants, the quality of the antioxidant are c, and the quality sum of first polyol ester and second polyol ester is
A meets:0.01%≤c/a≤2%.
9. the machine oil according to claim 8 for compressor, which is characterized in that meet:0.05%≤c/a≤1.0%.
10. the machine oil according to claim 1 for compressor, which is characterized in that including:Sour agent for capturing, the acid are caught
The quality of agent is caught as d, the quality sum of first polyol ester and second polyol ester is a, is met:0.01%≤d/
A≤2.0%.
11. the machine oil according to claim 10 for compressor, which is characterized in that meet:0.02%≤d/a≤
1.0%.
12. the machine oil according to claim 1 for compressor, which is characterized in that including:Metal active agent, the gold
Belong to the quality of activating agent for e, the quality sum of first polyol ester and second polyol ester is a, is met:
0.0001%≤e/a≤0.01%.
13. a kind of compressor, which is characterized in that including:
Shell, the interior machine oil being equipped with as described in any one of claim 1-12 of the shell;
Compression mechanism, the compression mechanism are installed in the shell.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810383039.4A CN108467761B (en) | 2018-04-26 | 2018-04-26 | Engine oil for compressor and compressor with engine oil |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810383039.4A CN108467761B (en) | 2018-04-26 | 2018-04-26 | Engine oil for compressor and compressor with engine oil |
Publications (2)
Publication Number | Publication Date |
---|---|
CN108467761A true CN108467761A (en) | 2018-08-31 |
CN108467761B CN108467761B (en) | 2021-04-06 |
Family
ID=63263869
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201810383039.4A Active CN108467761B (en) | 2018-04-26 | 2018-04-26 | Engine oil for compressor and compressor with engine oil |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN108467761B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111057611A (en) * | 2019-12-24 | 2020-04-24 | 珠海格力绿色再生资源有限公司 | Mixed refrigerator oil and preparation method thereof |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1993010206A1 (en) * | 1991-11-13 | 1993-05-27 | Imperial Chemical Industries Plc | Lubricants for heat transfer devices |
JPH0625682A (en) * | 1992-07-08 | 1994-02-01 | Kao Corp | Composition for refrigerator working fluid |
JPH09504824A (en) * | 1993-11-09 | 1997-05-13 | ヘンケル・コーポレイション | Polyol ester lubricating oil compatible with mineral oils, especially for compressors for high temperature operating refrigerators |
CN102216438A (en) * | 2008-11-13 | 2011-10-12 | 科聚亚公司 | Lubricants for refrigeration systems |
CN103089570A (en) * | 2011-10-27 | 2013-05-08 | 广东美芝制冷设备有限公司 | Compressor |
CN104087390A (en) * | 2014-07-25 | 2014-10-08 | 中国石油化工股份有限公司 | Refrigerating machine oil |
CN104837966A (en) * | 2012-12-05 | 2015-08-12 | 吉坤日矿日石能源株式会社 | Cooling-equipment working-fluid composition |
-
2018
- 2018-04-26 CN CN201810383039.4A patent/CN108467761B/en active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1993010206A1 (en) * | 1991-11-13 | 1993-05-27 | Imperial Chemical Industries Plc | Lubricants for heat transfer devices |
JPH0625682A (en) * | 1992-07-08 | 1994-02-01 | Kao Corp | Composition for refrigerator working fluid |
JPH09504824A (en) * | 1993-11-09 | 1997-05-13 | ヘンケル・コーポレイション | Polyol ester lubricating oil compatible with mineral oils, especially for compressors for high temperature operating refrigerators |
CN102216438A (en) * | 2008-11-13 | 2011-10-12 | 科聚亚公司 | Lubricants for refrigeration systems |
CN103089570A (en) * | 2011-10-27 | 2013-05-08 | 广东美芝制冷设备有限公司 | Compressor |
CN104837966A (en) * | 2012-12-05 | 2015-08-12 | 吉坤日矿日石能源株式会社 | Cooling-equipment working-fluid composition |
CN104087390A (en) * | 2014-07-25 | 2014-10-08 | 中国石油化工股份有限公司 | Refrigerating machine oil |
Non-Patent Citations (1)
Title |
---|
古丽米热·吐尔地等: ""脂肪酸组成对多元醇酯性能的影响"", 《润滑油》 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111057611A (en) * | 2019-12-24 | 2020-04-24 | 珠海格力绿色再生资源有限公司 | Mixed refrigerator oil and preparation method thereof |
CN111057611B (en) * | 2019-12-24 | 2022-04-22 | 珠海格力绿色再生资源有限公司 | Mixed refrigerator oil and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
CN108467761B (en) | 2021-04-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR100856629B1 (en) | Closed-type compressor | |
KR0145952B1 (en) | Ammonia refrigeration apparatus | |
KR102164106B1 (en) | Electric compressor and refrigeration air conditioning system | |
CA2111196C (en) | Ammonia refrigerating machine, working fluid composition for use in refrigerating machine, and method for lubricating ammonia refrigerating machine | |
JP5260168B2 (en) | Refrigerant compressor | |
WO2007026647A1 (en) | Refrigerator oil composition | |
WO2007058082A1 (en) | Refrigerator oil composition | |
CN100424441C (en) | Transcritical refrigerating device | |
KR20040075914A (en) | Operating medium for carbon dioxide-cooling systems and air-conditioning systems | |
CN108467761A (en) | Machine oil for compressor and the compressor with it | |
JP2015014395A (en) | Air conditioner | |
CN116761873A (en) | Working fluid, refrigerator and refrigerator oil | |
JP6522345B2 (en) | Refrigerating apparatus and sealed electric compressor | |
JP2774307B2 (en) | Refrigeration oil for fluorinated alkane refrigerant | |
JPH05125374A (en) | Refrigerator oil composition | |
JPS60123577A (en) | Refrigerating machine oil composition | |
JP3437177B2 (en) | refrigerator | |
JPS59117590A (en) | High-viscosity refrigerator oil composition | |
JP2016023902A (en) | Air conditioner | |
JP5667362B2 (en) | Reciprocating compressor and refrigerator using the same | |
CA2314130C (en) | Ammonia refrigerating machine, working fluid composition for use in refrigerating machine, and method for lubricating ammonia refrigerating machine | |
JP3241694B2 (en) | Ammonia refrigeration equipment | |
JPH1129766A (en) | Refrigeration equipment and refrigerant compressor | |
JPH08240362A (en) | Refrigeration equipment | |
WO2023136068A1 (en) | Heat source machine, operation method therefor, and refrigeration oil for heat source machine |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |