CN108467707A - 一种环保玻璃胶 - Google Patents
一种环保玻璃胶 Download PDFInfo
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- CN108467707A CN108467707A CN201810371955.6A CN201810371955A CN108467707A CN 108467707 A CN108467707 A CN 108467707A CN 201810371955 A CN201810371955 A CN 201810371955A CN 108467707 A CN108467707 A CN 108467707A
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- 239000004568 cement Substances 0.000 title claims abstract description 24
- 239000011521 glass Substances 0.000 title claims abstract description 24
- 230000007613 environmental effect Effects 0.000 title claims abstract description 11
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 39
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 26
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 24
- 230000002421 anti-septic effect Effects 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- XGRSAFKZAGGXJV-UHFFFAOYSA-N 3-azaniumyl-3-cyclohexylpropanoate Chemical compound OC(=O)CC(N)C1CCCCC1 XGRSAFKZAGGXJV-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000008367 deionised water Substances 0.000 claims abstract description 13
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 13
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 13
- UIUXUFNYAYAMOE-UHFFFAOYSA-N methylsilane Chemical compound [SiH3]C UIUXUFNYAYAMOE-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004006 olive oil Substances 0.000 claims abstract description 13
- 235000008390 olive oil Nutrition 0.000 claims abstract description 13
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 229960004711 sodium monofluorophosphate Drugs 0.000 claims abstract description 13
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 13
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000908 ammonium hydroxide Substances 0.000 claims abstract description 12
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 12
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 12
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910002012 Aerosil® Inorganic materials 0.000 claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920002125 Sokalan® Polymers 0.000 claims abstract description 10
- 239000004584 polyacrylic acid Substances 0.000 claims abstract description 10
- 241000790917 Dioxys <bee> Species 0.000 claims 3
- 229910003978 SiClx Inorganic materials 0.000 claims 3
- 239000007789 gas Substances 0.000 claims 3
- 238000001035 drying Methods 0.000 abstract description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 240000007817 Olea europaea Species 0.000 description 3
- 239000006210 lotion Substances 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 240000008790 Musa x paradisiaca Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- -1 which is a kind of Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
- C09J183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
本发明公开了一种环保玻璃胶，其特征在于，是由以下重量份数的原料组成：聚丙烯酸脂乳液10‑20份、有机羟基硅酮20‑25份、有机甲基硅酮15‑20份、甲基硅烷2‑5份、气相二氧化硅5‑8份、碳酸钙10‑12份、橄榄油2‑5份、单氟磷酸钠1‑2份、醋酸2‑3份、氨基硅烷0.2‑0.5份、抗菌剂0.1‑1份、双氧水3‑5份、乳化剂3‑6份、氨水5‑8份、水玻璃15‑20份、去离子水50‑60份。本发明提供一种环保玻璃胶，环保能力强、干燥时间短、粘合力强、不易脱落等特点，通过在玻璃胶中加入的抗菌剂，可以防止因霉变而产生的发黑或变色现象。
Description
技术领域
本发明涉及化工技术领域，尤其涉及一种环保玻璃胶。
背景技术
玻璃胶是一种用于黏性物质，是装饰装修中必不可少的用品，玻璃胶通常溶于水，可以用作粘合剂，但是目前的玻璃胶常常存在粘合力不强问题，容易开胶，使用效果不理想，且内含苯类溶剂，乙酸乙酯或者香蕉水等，不但污染环境，对施工人员有害，而且易燃，其在使用一段时间后，往往会发霉致使变黑或者变色，影响美观。因此，需要一种新的配方诞生来满足人们的市场需求。
发明内容
本发明的目的在于，提供一种环保玻璃胶，环保能力强、干燥时间短、粘合力强、不易脱落等特点，通过在玻璃胶中加入的抗菌剂，可以防止因霉变而产生的发黑或变色现象。
本发明的技术方案：一种环保玻璃胶，其特征在于，是由以下重量份数的原料组成：聚丙烯酸脂乳液10-20份、有机羟基硅酮20-25份、有机甲基硅酮15-20份、甲基硅烷2-5份、气相二氧化硅5-8份、碳酸钙 10-12份、橄榄油2-5份、单氟磷酸钠1-2份、醋酸2-3份、氨基硅烷0.2-0.5份、抗菌剂0.1-1份、双氧水3-5份、乳化剂3-6份、氨水5-8份、水玻璃15-20份、去离子水50-60份。
前述的一种环保玻璃胶，其特征在于，是由以下重量份数的原料组成：聚丙烯酸脂乳液10份、有机羟基硅酮20份、有机甲基硅酮15份、甲基硅烷2份、气相二氧化硅5份、碳酸钙10份、橄榄油2份、单氟磷酸钠1份、醋酸2份、氨基硅烷0.2份、抗菌剂0.1份、双氧水3份、乳化剂3份、氨水5份、水玻璃15份、去离子水50份。
前述的一种环保玻璃胶，其特征在于，是由以下重量份数的原料组成：聚丙烯酸脂乳液20份、有机羟基硅酮25份、有机甲基硅酮20份、甲基硅烷5份、气相二氧化硅8份、碳酸钙12份、橄榄油5份、单氟磷酸钠2份、醋酸3份、氨基硅烷0.5份、抗菌剂1份、双氧水5份、乳化剂6份、氨水8份、水玻璃20份、去离子水60份。
前述的一种环保玻璃胶，其特征在于，是由以下重量份数的原料组成：聚丙烯酸脂乳液15份、有机羟基硅酮22份、有机甲基硅酮18份、甲基硅烷4份、气相二氧化硅6份、碳酸钙11份、橄榄油3份、单氟磷酸钠1.5份、醋酸2.5份、氨基硅烷0.3份、抗菌剂0.5份、双氧水4份、乳化剂5份、氨水6份、水玻璃18份、去离子水55份。
本发明的有益效果：环保能力强、干燥时间短、粘合力强、不易脱落等特点，通过在玻璃胶中加入的抗菌剂，可以防止因霉变而产生的发黑或变色现象。
具体实施方式
下面实施例对本发明作进一步的说明，但并不作为对本发明限制的依据。
实施例1：一种环保玻璃胶，是由以下重量份数的原料组成：聚丙烯酸脂乳液10-20份、有机羟基硅酮20-25份、有机甲基硅酮15-20份、甲基硅烷2-5份、气相二氧化硅5-8份、碳酸钙 10-12份、橄榄油2-5份、单氟磷酸钠1-2份、醋酸2-3份、氨基硅烷0.2-0.5份、抗菌剂0.1-1份、双氧水3-5份、乳化剂3-6份、氨水5-8份、水玻璃15-20份、去离子水50-60份。
实施例2：一种环保玻璃胶，是由以下重量份数的原料组成：聚丙烯酸脂乳液10份、有机羟基硅酮20份、有机甲基硅酮15份、甲基硅烷2份、气相二氧化硅5份、碳酸钙 10份、橄榄油2份、单氟磷酸钠1份、醋酸2份、氨基硅烷0.2份、抗菌剂0.1份、双氧水3份、乳化剂3份、氨水5份、水玻璃15份、去离子水50份。
实施例3：一种环保玻璃胶，是由以下重量份数的原料组成：聚丙烯酸脂乳液20份、有机羟基硅酮25份、有机甲基硅酮20份、甲基硅烷5份、气相二氧化硅8份、碳酸钙 12份、橄榄油5份、单氟磷酸钠2份、醋酸3份、氨基硅烷0.5份、抗菌剂1份、双氧水5份、乳化剂6份、氨水8份、水玻璃20份、去离子水60份。
实施例4：一种环保玻璃胶，是由以下重量份数的原料组成：聚丙烯酸脂乳液15份、有机羟基硅酮22份、有机甲基硅酮18份、甲基硅烷4份、气相二氧化硅6份、碳酸钙 11份、橄榄油3份、单氟磷酸钠1.5份、醋酸2.5份、氨基硅烷0.3份、抗菌剂0.5份、双氧水4份、乳化剂5份、氨水6份、水玻璃18份、去离子水55份。
Claims (4)
1.一种环保玻璃胶，其特征在于，是由以下重量份数的原料组成：聚丙烯酸脂乳液10-20份、有机羟基硅酮20-25份、有机甲基硅酮15-20份、甲基硅烷2-5份、气相二氧化硅5-8份、碳酸钙 10-12份、橄榄油2-5份、单氟磷酸钠1-2份、醋酸2-3份、氨基硅烷0.2-0.5份、抗菌剂0.1-1份、双氧水3-5份、乳化剂3-6份、氨水5-8份、水玻璃15-20份、去离子水50-60份。
2.根据权利要求1所述的一种环保玻璃胶，其特征在于，是由以下重量份数的原料组成：聚丙烯酸脂乳液10份、有机羟基硅酮20份、有机甲基硅酮15份、甲基硅烷2份、气相二氧化硅5份、碳酸钙 10份、橄榄油2份、单氟磷酸钠1份、醋酸2份、氨基硅烷0.2份、抗菌剂0.1份、双氧水3份、乳化剂3份、氨水5份、水玻璃15份、去离子水50份。
3.根据权利要求1所述的一种环保玻璃胶，其特征在于，是由以下重量份数的原料组成：聚丙烯酸脂乳液20份、有机羟基硅酮25份、有机甲基硅酮20份、甲基硅烷5份、气相二氧化硅8份、碳酸钙 12份、橄榄油5份、单氟磷酸钠2份、醋酸3份、氨基硅烷0.5份、抗菌剂1份、双氧水5份、乳化剂6份、氨水8份、水玻璃20份、去离子水60份。
4.根据权利要求1所述的一种环保玻璃胶，其特征在于，是由以下重量份数的原料组成：聚丙烯酸脂乳液15份、有机羟基硅酮22份、有机甲基硅酮18份、甲基硅烷4份、气相二氧化硅6份、碳酸钙 11份、橄榄油3份、单氟磷酸钠1.5份、醋酸2.5份、氨基硅烷0.3份、抗菌剂0.5份、双氧水4份、乳化剂5份、氨水6份、水玻璃18份、去离子水55份。
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2021531359A (ja) * | 2018-06-12 | 2021-11-18 | ダウ シリコーンズ コーポレーション | 水性ハイブリッド感圧粘着剤組成物およびその製造方法 |
| US11685854B1 (en) | 2022-09-20 | 2023-06-27 | King Fahd University Of Petroleum And Minerals | Carbonation-resistant cementitious blend containing olive waste |
-
2018
- 2018-04-24 CN CN201810371955.6A patent/CN108467707A/zh not_active Withdrawn
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2021531359A (ja) * | 2018-06-12 | 2021-11-18 | ダウ シリコーンズ コーポレーション | 水性ハイブリッド感圧粘着剤組成物およびその製造方法 |
| JP7193553B2 (ja) | 2018-06-12 | 2022-12-20 | ダウ シリコーンズ コーポレーション | 水性ハイブリッド感圧粘着剤組成物およびその製造方法 |
| US12024658B2 (en) | 2018-06-12 | 2024-07-02 | Dow Silicones Corporation | Water-based hybrid pressure sensitive adhesive composition and method of producing the same |
| US11685854B1 (en) | 2022-09-20 | 2023-06-27 | King Fahd University Of Petroleum And Minerals | Carbonation-resistant cementitious blend containing olive waste |
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