CN108456503A - The adhesive and preparation method thereof used in space key high intensity water - Google Patents
The adhesive and preparation method thereof used in space key high intensity water Download PDFInfo
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- CN108456503A CN108456503A CN201711349211.6A CN201711349211A CN108456503A CN 108456503 A CN108456503 A CN 108456503A CN 201711349211 A CN201711349211 A CN 201711349211A CN 108456503 A CN108456503 A CN 108456503A
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- 239000000853 adhesive Substances 0.000 title claims abstract description 42
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 42
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 22
- 239000011256 inorganic filler Substances 0.000 claims abstract description 15
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 15
- XUBKPYAWPSXPDZ-UHFFFAOYSA-N [Ba].OS(O)(=O)=O Chemical compound [Ba].OS(O)(=O)=O XUBKPYAWPSXPDZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 239000003085 diluting agent Substances 0.000 claims abstract description 12
- 239000003822 epoxy resin Substances 0.000 claims abstract description 10
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 150000001412 amines Chemical class 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 16
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 13
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 12
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 9
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 6
- -1 glycidol ethers Chemical class 0.000 claims description 5
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 claims description 4
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 claims description 3
- DGUJJOYLOCXENZ-UHFFFAOYSA-N 4-[2-[4-(oxiran-2-ylmethoxy)phenyl]propan-2-yl]phenol Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C1=CC=C(O)C=C1 DGUJJOYLOCXENZ-UHFFFAOYSA-N 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 238000010790 dilution Methods 0.000 claims description 3
- 239000012895 dilution Substances 0.000 claims description 3
- UWFRVQVNYNPBEF-UHFFFAOYSA-N 1-(2,4-dimethylphenyl)propan-1-one Chemical compound CCC(=O)C1=CC=C(C)C=C1C UWFRVQVNYNPBEF-UHFFFAOYSA-N 0.000 claims description 2
- KUAUJXBLDYVELT-UHFFFAOYSA-N 2-[[2,2-dimethyl-3-(oxiran-2-ylmethoxy)propoxy]methyl]oxirane Chemical compound C1OC1COCC(C)(C)COCC1CO1 KUAUJXBLDYVELT-UHFFFAOYSA-N 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- 229930185605 Bisphenol Natural products 0.000 claims 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims 1
- 238000002791 soaking Methods 0.000 abstract description 3
- 230000009471 action Effects 0.000 abstract description 2
- 238000010276 construction Methods 0.000 abstract description 2
- 230000007123 defense Effects 0.000 abstract description 2
- 238000009434 installation Methods 0.000 abstract description 2
- 238000007711 solidification Methods 0.000 abstract description 2
- 230000008023 solidification Effects 0.000 abstract description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- KCAMLFCTSSYIFW-UHFFFAOYSA-N 2,4,6-tris(dimethylamino)phenol Chemical group CN(C)C1=CC(N(C)C)=C(O)C(N(C)C)=C1 KCAMLFCTSSYIFW-UHFFFAOYSA-N 0.000 description 2
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical class CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229940117969 neopentyl glycol Drugs 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
- C08G59/4207—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof aliphatic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Epoxy Resins (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to the adhesives and preparation method thereof used in a kind of space key high intensity water, and described adhesive is by component A and B component by weight 1:1 proportioning composition；The component A is made of by weight ratio following raw material：32 40 parts of epoxy resin, 23 parts of diluents, 48 55 parts of inorganic fillers, 10 20 parts of high-purity sulfuric acid barium；The B component is made of by weight ratio following raw material：35 45 parts of special modified fatty amine curing agents, 34 parts of diluents, 30 55 parts of inorganic fillers, 2 2.5 parts of accelerating agents, 10 20 parts of high-purity sulfuric acid barium.The present invention is suitable for dam, water pipe, sink, tunnel, hypogee, civil air defense constructions and installations, wet environment, the bonding of ship broken hole, repairing, leak stopping, this adhesive has certain surface-active action, can replace the hydrone on adherend surface or miscible, can be in water to well being moistened by maxxaedium, adhesive keeps stablizing after meeting water, not by water destruct, condition solidification can be completed under water, and can soaking-resistant.
Description
Technical field
The present invention relates to the adhesive used in technical field of adhesive more particularly to a kind of space key high intensity water and
Preparation method.
Background technology
Under water in bonding application, since the adhesive of the prior art can only can just be put into water after the completion of the external world bonds
In, if bonded in water, bonding effect can be substantially reduced, moreover, the usage time of the adhesive of the prior art in water
Use duration, adhesive strength also wretched insufficiency that cannot fully meet people to underwater or damp significantly shorter than in airspace
The demand bonded in wet environment.
Invention content
It is an object of the invention to solve problem of the prior art and provide it is a kind of have can under water condition complete it is solid
Change, and the adhesive of energy soaking-resistant, it is another object of the present invention to propose a kind of method making the adhesive.
To achieve the purpose of the present invention, the adhesive used in a kind of space key high intensity water provided by the invention, it is described
Adhesive is by component A and B component by weight 1:1 proportioning composition；
The component A is made of by weight ratio following raw material：32-40 parts of epoxy resin, 2-3 parts of diluents, 48-
55 parts of inorganic fillers, 10-20 parts of high-purity sulfuric acid barium；
The B component is made of by weight ratio following raw material：35-45 parts of special modified fatty amine curing agents, 3-4
Part diluent, 30-55 parts of inorganic fillers, 2-2.5 parts of accelerating agents, 10-20 parts of high-purity sulfuric acid barium；
Usually, the component A and B component individually store, and when in use, are uniformly mixed by component A and B component.
In another embodiment of the adhesive used in space key high intensity water based on the present invention, the asphalt mixtures modified by epoxy resin
Fat is one or more in bis-phenol A glycidyl ether, Bisphenol F glycidol ether, polyglycidyl ether.
It is described inorganic to fill out in another embodiment of adhesive used in space key high intensity water based on the present invention
Material is one or more in calcium carbonate, nano-calcium carbonate.
In another embodiment of the adhesive used in space key high intensity water based on the present invention, the barium sulfate
For nano barium sulfate.
In another embodiment of the adhesive used in space key high intensity water based on the present invention, the diluent
It shrinks for carbon 12-14 alkyl glycidyl ethers, allyl glycidyl ether, ethylene glycol diglycidylether, neopentyl glycol two sweet
It is one or more in oily ether.
In another embodiment of the adhesive used in space key high intensity water based on the present invention, the accelerating agent
It is 2,4,6- tri- (dimethylamino) phenol, N, it is one or more in N- dimethyl benzylamines, n,N-Dimethylaniline.
Other side based on the embodiment of the present invention discloses the adhesive used in a kind of space key high intensity water
Preparation method includes the following steps：
The method for preparing component A；
The method for preparing B component；
Component A and B component are mixed, described adhesive is obtained.
In another embodiment of the preparation method of the adhesive used in space key high intensity water based on the present invention,
It is described prepare component A method include：
It under conditions of 25-35 DEG C of normal pressure, is formed by proportion by weight, epoxy resin and dilution is added into reaction kettle
Agent, being stirred makes said mixture be uniformly mixed, and wherein mixing speed is 33-50 revs/min, and mixing time is 10-20 points
Clock；
Inorganic filler and high-purity sulfuric acid barium are sequentially added by proportion by weight composition, continues to stir, wherein stirring
Speed is 33-50 revs/min, and mixing time is 20-30 minutes；
Component A is made, component A is individually preserved.
In another embodiment of the preparation method of the adhesive used in space key high intensity water based on the present invention,
It is described prepare B component method include：
At normal temperatures and pressures, it is formed by proportion by weight, phenol-modified fatty amine curing agent, dilute is added into reaction kettle
Agent and accelerating agent are released, being stirred makes said mixture be uniformly mixed, and wherein mixing speed is 33-50 revs/min, when stirring
Between be 15-25 minutes；
It is formed by proportion by weight, sequentially adds inorganic filler and high-purity sulfuric acid barium, continue to stir, wherein stirring
It is 33-50 revs/min to mix speed, and mixing time is 25-35 minutes；
B component is made, B component is individually preserved.
The advantage of the invention is that：
The adhesive used in space key high intensity water provided by the invention uses underwater new special material and water imbibition
Filler, is suitable for dam, water pipe, sink, tunnel, hypogee, civil air defense constructions and installations, wet environment, and the bonding of ship broken hole is repaiied
It mends, leak stopping, this adhesive has certain surface-active action, can replace the hydrone on adherend surface or miscible, can be
To well being moistened by maxxaedium in water, adhesive keeps stablizing after meeting water, not by water destruct, condition can complete solidification under water,
And it can soaking-resistant.
Specific implementation mode
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, to the technology in the embodiment of the present invention
Scheme is clearly and completely described, it is clear that described embodiments are only a part of the embodiments of the present invention, rather than complete
The embodiment in portion.
Based on the embodiments of the present invention, those of ordinary skill in the art institute without making creative work
The every other embodiment obtained, shall fall within the protection scope of the present invention.
The adhesive used in a kind of space key high intensity water provided by the invention, to achieve the purpose of the present invention, this hair
The adhesive used in a kind of space key high intensity water of bright offer, described adhesive is by component A and B component by weight 1:1
Proportioning composition；
The component A is made of by weight ratio following raw material：32-40 parts of epoxy resin, 2-3 parts of diluents, 48-
55 parts of inorganic fillers, 10-20 parts of high-purity sulfuric acid barium；
The B component is made of by weight ratio following raw material：35-45 parts of special modified fatty amine curing agents, 3-4
Part diluent, 30-55 parts of inorganic fillers, 2-2.5 parts of accelerating agents, 10-20 parts of high-purity sulfuric acid barium；
Usually, the component A and B component individually store, and when in use, are uniformly mixed by component A and B component.
The epoxy resin be bis-phenol A glycidyl ether, Bisphenol F glycidol ether, one kind in polyglycidyl ether or
It is a variety of.
The inorganic filler is one or more in calcium carbonate, nano-calcium carbonate.
The barium sulfate is nano barium sulfate.
The diluent is carbon 12-14 alkyl glycidyl ethers, allyl glycidyl ether, ethylene glycol diglycidyl
It is one or more in ether, neopentylglycol diglycidyl ether.
The accelerating agent is 2,4,6- tri- (dimethylamino) phenol, N, N- dimethyl benzylamines, N, in N- dimethylanilines
It is one or more.
A kind of preparation method of the adhesive used in space key high intensity water, includes the following steps：
The method for preparing component A；
The method for preparing B component；
Component A and B component are mixed, described adhesive is obtained.
It is described prepare component A method include：
It under conditions of 25-35 DEG C of normal pressure, is formed by proportion by weight, epoxy resin and dilution is added into reaction kettle
Agent, being stirred makes said mixture be uniformly mixed, and wherein mixing speed is 33-50 revs/min, and mixing time is 10-20 points
Clock；
Inorganic filler and high-purity sulfuric acid barium are sequentially added by proportion by weight composition, continues to stir, wherein stirring
Speed is 33-50 revs/min, and mixing time is 20-30 minutes；
Component A is made, component A is individually preserved.
It is described prepare B component method include：
At normal temperatures and pressures, it is formed by proportion by weight, phenol-modified fatty amine curing agent, dilute is added into reaction kettle
Agent and accelerating agent are released, being stirred makes said mixture be uniformly mixed, and wherein mixing speed is 33-50 revs/min, when stirring
Between be 15-25 minutes；
It is formed by proportion by weight, sequentially adds inorganic filler and high-purity sulfuric acid barium, continue to stir, wherein stirring
It is 33-50 revs/min to mix speed, and mixing time is 25-35 minutes；
B component is made, B component is individually preserved.
The adhesive and preparation method thereof used in a kind of space key high intensity water provided by the present invention is carried out above
It is discussed in detail, principle and implementation of the present invention are described for specific case used herein, above example
Explanation be merely used to help understand the present invention method and its core concept；Meanwhile for the general technology people of this field
Member, according to the thought of the present invention, there will be changes in the specific implementation manner and application range, in conclusion this explanation
Book content should not be construed as limiting the invention.
Finally it should be noted that：The foregoing is only a preferred embodiment of the present invention, is not limited to this hair
It is bright, although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, according to
So can be with technical scheme described in the above embodiments is modified, or which part technical characteristic is equal
It replaces, all within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in this
Within the protection domain of invention.
Claims (9)
1. the adhesive used in a kind of space key high intensity water, which is characterized in that described adhesive is pressed by component A and B component
Parts by weight 1:1 proportioning composition；
The component A is made of by weight ratio following raw material：32-40 parts of epoxy resin, 2-3 parts of diluents, 48-55 parts of nothings
Machine filler, 10-20 parts of high-purity sulfuric acid barium；
The B component is made of by weight ratio following raw material：35-45 parts of special modified fatty amine curing agents, 3-4 parts of dilutions
Agent, 30-55 parts of inorganic fillers, 2-2.5 parts of accelerating agents, 10-20 parts of high-purity sulfuric acid barium；
Usually, the component A and B component individually store, and when in use, are uniformly mixed by component A and B component.
2. adhesive according to claim 1, which is characterized in that the epoxy resin is bis-phenol A glycidyl ether, bis-phenol
It is one or more in F glycidol ethers, polyglycidyl ether.
3. adhesive according to claim 1, which is characterized in that the inorganic filler is in calcium carbonate, nano-calcium carbonate
It is one or more.
4. adhesive according to claim 1, which is characterized in that the barium sulfate is nano barium sulfate.
5. adhesive according to claim 1, which is characterized in that the diluent be carbon 12-14 alkyl glycidyl ethers,
It is one or more in allyl glycidyl ether, ethylene glycol diglycidylether, neopentylglycol diglycidyl ether.
6. adhesive according to claim 1, which is characterized in that the accelerating agent is 2,4,6- tri- (dimethylamino) benzene
Phenol, N, it is one or more in N- dimethyl benzylamines, n,N-Dimethylaniline.
7. a kind of preparation method of the adhesive used in space key high intensity water, which is characterized in that include the following steps：
The method for preparing component A；
The method for preparing B component；
Component A and B component are mixed, described adhesive is obtained.
8. according to the method described in right 7, which is characterized in that it is described prepare component A method include：
It under conditions of 25-35 DEG C of normal pressure, is formed by proportion by weight, epoxy resin and diluent is added into reaction kettle, into
Row stirring makes said mixture be uniformly mixed, and wherein mixing speed is 33-50 revs/min, and mixing time is 10-20 minutes；
Inorganic filler and high-purity sulfuric acid barium are sequentially added by proportion by weight composition, continues to stir, wherein mixing speed
It it is 33-50 revs/min, mixing time is 20-30 minutes；
Component A is made, component A is individually preserved.
9. according to the method described in right 7, which is characterized in that it is described prepare B component method include：
At normal temperatures and pressures, by proportion by weight form, be added into reaction kettle phenol-modified fatty amine curing agent, diluent and
Accelerating agent, being stirred makes said mixture be uniformly mixed, and wherein mixing speed is 33-50 revs/min, mixing time 15-
25 minutes；
It is formed by proportion by weight, sequentially adds inorganic filler and high-purity sulfuric acid barium, continue to stir, wherein mixing speed
It it is 33-50 revs/min, mixing time is 25-35 minutes；
B component is made, B component is individually preserved.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201711349211.6A CN108456503A (en) | 2017-12-15 | 2017-12-15 | The adhesive and preparation method thereof used in space key high intensity water |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711349211.6A CN108456503A (en) | 2017-12-15 | 2017-12-15 | The adhesive and preparation method thereof used in space key high intensity water |
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| CN108456503A true CN108456503A (en) | 2018-08-28 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111073573A (en) * | 2018-10-19 | 2020-04-28 | 北京航天试验技术研究所 | A kind of composite plugging agent for space station |
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|---|---|---|---|---|
| US4055533A (en) * | 1976-03-30 | 1977-10-25 | Malone Laurence A | Pottery-like coating composition |
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Application publication date: 20180828 |