CN108432769A - A kind of composition pesticide of humulone containing quinoline and benzene flumetsulam - Google Patents
A kind of composition pesticide of humulone containing quinoline and benzene flumetsulam Download PDFInfo
- Publication number
- CN108432769A CN108432769A CN201810430231.4A CN201810430231A CN108432769A CN 108432769 A CN108432769 A CN 108432769A CN 201810430231 A CN201810430231 A CN 201810430231A CN 108432769 A CN108432769 A CN 108432769A
- Authority
- CN
- China
- Prior art keywords
- benzene flumetsulam
- composition pesticide
- humulone
- quinoline
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 title claims abstract description 139
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 title claims abstract description 94
- RMFGNMMNUZWCRZ-UHFFFAOYSA-N Humulone Natural products CC(C)CC(=O)C1=C(O)C(O)(CC=C(C)C)C(O)=C(CC=C(C)C)C1=O RMFGNMMNUZWCRZ-UHFFFAOYSA-N 0.000 title claims abstract description 48
- VMSLCPKYRPDHLN-NRFANRHFSA-N humulone Chemical compound CC(C)CC(=O)C1=C(O)C(CC=C(C)C)=C(O)[C@@](O)(CC=C(C)C)C1=O VMSLCPKYRPDHLN-NRFANRHFSA-N 0.000 title claims abstract description 48
- 239000000203 mixture Substances 0.000 title claims abstract description 46
- RXCPQSJAVKGONC-UHFFFAOYSA-N Flumetsulam Chemical compound N1=C2N=C(C)C=CN2N=C1S(=O)(=O)NC1=C(F)C=CC=C1F RXCPQSJAVKGONC-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 239000000575 pesticide Substances 0.000 title claims abstract description 33
- 241000196324 Embryophyta Species 0.000 claims abstract description 25
- 240000008042 Zea mays Species 0.000 claims abstract description 11
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims abstract description 11
- 239000000375 suspending agent Substances 0.000 claims abstract description 11
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims abstract description 10
- 235000005822 corn Nutrition 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 239000000470 constituent Substances 0.000 claims abstract description 9
- 239000004562 water dispersible granule Substances 0.000 claims abstract description 7
- 239000007900 aqueous suspension Substances 0.000 claims abstract description 5
- 239000002671 adjuvant Substances 0.000 claims abstract description 4
- 239000002917 insecticide Substances 0.000 claims abstract description 4
- 244000025254 Cannabis sativa Species 0.000 claims description 3
- AHIBWURJLGCHAY-UHFFFAOYSA-N [S].C1=CC=CC=C1 Chemical compound [S].C1=CC=CC=C1 AHIBWURJLGCHAY-UHFFFAOYSA-N 0.000 claims 1
- 125000003277 amino group Chemical group 0.000 claims 1
- 230000002195 synergetic effect Effects 0.000 abstract description 10
- 239000012752 auxiliary agent Substances 0.000 abstract description 4
- 239000002552 dosage form Substances 0.000 abstract description 4
- 125000002943 quinolinyl group Chemical group N1=C(C=CC2=CC=CC=C12)* 0.000 abstract description 2
- 238000009313 farming Methods 0.000 abstract 1
- 244000304962 green bristle grass Species 0.000 description 12
- 230000002363 herbicidal effect Effects 0.000 description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 241001060350 Acalypha Species 0.000 description 8
- 235000010086 Setaria viridis var. viridis Nutrition 0.000 description 8
- 239000004009 herbicide Substances 0.000 description 7
- -1 neopelex Chemical compound 0.000 description 6
- 239000004576 sand Substances 0.000 description 6
- 238000013329 compounding Methods 0.000 description 5
- 230000005764 inhibitory process Effects 0.000 description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 description 5
- 241000448435 Acalypha australis Species 0.000 description 4
- 235000002248 Setaria viridis Nutrition 0.000 description 4
- 240000006394 Sorghum bicolor Species 0.000 description 4
- 235000011684 Sorghum saccharatum Nutrition 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 241000209140 Triticum Species 0.000 description 3
- 235000021307 Triticum Nutrition 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 238000003912 environmental pollution Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- 240000001592 Amaranthus caudatus Species 0.000 description 2
- 235000009328 Amaranthus caudatus Nutrition 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 206010059866 Drug resistance Diseases 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 239000005578 Mesotrione Substances 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 239000004178 amaranth Substances 0.000 description 2
- 235000012735 amaranth Nutrition 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000007884 disintegrant Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- KPUREKXXPHOJQT-UHFFFAOYSA-N mesotrione Chemical compound [O-][N+](=O)C1=CC(S(=O)(=O)C)=CC=C1C(=O)C1C(=O)CCCC1=O KPUREKXXPHOJQT-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
- 239000000661 sodium alginate Substances 0.000 description 2
- 229940005550 sodium alginate Drugs 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- 229920002785 Croscarmellose sodium Polymers 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 241001272567 Hominoidea Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 102000004316 Oxidoreductases Human genes 0.000 description 1
- 108090000854 Oxidoreductases Proteins 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 208000005374 Poisoning Diseases 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 101100339555 Zymoseptoria tritici HPPD gene Proteins 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000003042 antagnostic effect Effects 0.000 description 1
- MXWJVTOOROXGIU-UHFFFAOYSA-N atrazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)C)=N1 MXWJVTOOROXGIU-UHFFFAOYSA-N 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- BEHLMOQXOSLGHN-UHFFFAOYSA-N benzenamine sulfate Chemical compound OS(=O)(=O)NC1=CC=CC=C1 BEHLMOQXOSLGHN-UHFFFAOYSA-N 0.000 description 1
- UDHMTPILEWBIQI-UHFFFAOYSA-N butyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(=O)OCCCC)=CC=CC2=C1 UDHMTPILEWBIQI-UHFFFAOYSA-N 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 229960001681 croscarmellose sodium Drugs 0.000 description 1
- 229960000913 crospovidone Drugs 0.000 description 1
- 235000010947 crosslinked sodium carboxy methyl cellulose Nutrition 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 150000002190 fatty acyls Chemical group 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229940031703 low substituted hydroxypropyl cellulose Drugs 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 235000011147 magnesium chloride Nutrition 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 230000005226 mechanical processes and functions Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 description 1
- 229940073769 methyl oleate Drugs 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000002420 orchard Substances 0.000 description 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 235000013809 polyvinylpolypyrrolidone Nutrition 0.000 description 1
- 229920000523 polyvinylpolypyrrolidone Polymers 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of humulone containing quinoline and benzene flumetsulam composition pesticide, active constituent is quinoline humulone and benzene flumetsulam, and the wherein mass fraction ratio of quinoline humulone and benzene flumetsulam is 1:0.5~5, composition has synergistic effect to target weeds in proportional region, is preferably in a proportion of 1:1~3.Composition can also contain auxiliary agent in addition to containing active constituent, and the weight of active component is the 0.1%~60% of composition total weight, remaining is insecticides adjuvant.Composition can be processed into aqueous suspension agent, dispersible oil-suspending agent, water dispersible granules etc. agriculturally common dosage form in order to farming operations.The composition is suitable for preventing and kill off corn field annual grassy weeds.
Description
Technical field
The invention belongs to chemical pesticide fields, are specifically related to a kind of Synergistic fertilizer group of humulone containing quinoline and benzene flumetsulam
Close object.
Background technology
Quinoline humulone is the special selective superelevation effective herbicide of sorghum, and tight security is shown to sorghum, to corn and small
Wheat is also very safe, belongs to HPPD inhibitor, can be used for preventing and kill off sorghum field, corn field, wheat paddock annual grassy weeds.
Benzene flumetsulam is proporphyrinogen oxidase (PPO) inhibitor, can effectively prevent and kill off wheat paddock, corn field, sorghum field
Etc. the broad leaved weed in a variety of gramineous crop fields, it can also be used to prevent and kill off bare place and orchard broad leaved weed.
Farmland weed grass is mutually complicated, and type is various, is to prevent and kill off the most effective chemical means of agricultural weed using chemical agent
One of；With the novel pesticide of not cross resistance come to prevent and kill off agricultural weed be a good solution；But one is developed at present
A novel pesticide needs to screen a compounds up to ten thousand, and hundred million dollars of cost 1.2-1.5, the development cycle is 5-10, it is difficult to which that catches up with is upper miscellaneous
The speed that grass develops immunity to drugs；Other methods such as crop structure adjustment, different pesticide rotations etc., in actual mechanical process,
It is difficult to play apparent effect.
Rational chemical herbicide compounding or mixture, which have, expands herbicide controlling spectrum, improves control effect, extends dispenser period, subtracts
Few dosage reduces poisoning risk, reduces residual, delays the advantages that generation and development of weeds drug resistance and drug resistance, so
It is maximally efficient and economic one of the method to solve the above problems to select suitable mixture of herbicides or mixture；However because agriculture
The mechanism of action is complicated between medicine mixture, and whether synergy is affected by various factors after combination, only relies on experimental result and is subject to
Verification, can not be expected.
Develop new product herbicide is expensive, the period is long, and in contrast, exploitation is efficient, less toxic, low-residual with research
Compounding have with mixture invest small, lead time it is short and by attention both domestic and external, it is numerous and confused to increase development dynamics.
It is had not been reported as the binary composition pesticide of active constituent using quinoline humulone and benzene flumetsulam.
Invention content
The present invention is directed to by provide a kind of active constituent for the synergetic pesticide composition of quinoline humulone and benzene flumetsulam come
Pesticide use amount is reduced, is reduced environmental pollution, is reduced grower's Pesticide use cost, weeds is delayed to generate speed to the resistance of single dose
Degree.
The invention is realized by the following technical scheme：
The composition pesticide of the humulone containing quinoline and benzene flumetsulam, active constituent is by quinoline humulone and benzene flumetsulam group
At the mass fraction ratio of quinoline humulone and benzene flumetsulam is 1:0.5~5, quinoline humulone and benzene flumetsulam in the proportional region
There is unexpected synergistic effect to target weeds.
The mass fraction ratio of preferred quinoline humulone and benzene flumetsulam is 1:1~3.
The mass fraction ratio of further preferred quinoline humulone and benzene flumetsulam is 1:1.
The mass fraction ratio of further preferred quinoline humulone and benzene flumetsulam is 1:1.5.
The mass fraction ratio of further preferred quinoline humulone and benzene flumetsulam is 1:2.
The mass fraction ratio of further preferred quinoline humulone and benzene flumetsulam is 1:3.
The weight of the composition pesticide active constituent is the 0.1%~60% of composition total weight, remaining is helped for pesticide
Agent；The weight of preferred active constituent is the 5%~40% of composition total weight, remaining is insecticides adjuvant.
The composition pesticide by certain technological means can excipient be aqueous suspension agent, dispersible oil-suspending agent, water
Dispersible granule etc..
The aqueous suspension agent dosage form weight percent group becomes：Quinoline humulone 0.1~20%, benzene flumetsulam 0.1~
30%, dispersant 0.1~20%, wetting agent 0.1-10%, thickener 0.1~3%, antifreezing agent 1~5%, deionized water carrier
Complement to 100%.Specifically production stage is：Active ingredient and other auxiliary agents are mixed, through sand in high speed shear dispersion, sand mill
After mill, high dispersive, the suspension system of stabilization are formed in water-medium, and the suspending agent of corresponding weight percentage is made.
The dispersible oil-suspending agent dosage form weight percent group becomes：Quinoline humulone 0.1~20%, benzene flumetsulam
0.1~30%, dispersant 0.1~15%, emulsifier 0.1~8%, thickener 0.1~5%, antifreezing agent 1~5%, liquid carry
Body complements to 100%.Specifically production stage is：Active ingredient and other auxiliary agents are mixed, through in high speed shear dispersion, sand mill
After sand milling, high dispersive, the suspension system of stabilization are formed in oil is medium, and the oil-suspending agent of corresponding weight percentage is made.
The dosage form of water dispersible granule weight percent group becomes：Quinoline humulone 0.1~20%, benzene flumetsulam 0.1~
40%, dispersant 0.1~10%, wetting agent 0.1~10%, disintegrant 0.1~6%, solid carrier complements to 100%.Specifically
Production stage is：Active ingredient and other auxiliary agents are uniformly mixed, crushed with micro jet, through mediating, is then added
It is granulated, dried, sieved in fluidized-bed granulation dryer, the water dispersible granules of corresponding weight percentage are made.
The antifreezing agent can be one or more of in glycerine, propylene glycol, diethylene glycol (DEG), urea etc..
The emulsifier is castor oil polyoxyethylene ether, neopelex, calcium dodecyl benzene sulfonate, fatty alcohol
One or more of polyoxyethylene ether, phenethyl phenol polyethenoxy ether etc..
The wetting agent can be lauryl sodium sulfate, neopelex, sodium butylnaphthalenesulfonate, alkyl sulphur
One or more of sour sodium, tea seed cake powder, spaonin powder, spaonin powder etc..
The dispersant can be APES formaldehyde condensation product, naphthalenesulfonate formaldehyde condensation compound, to first
Oxygroup fatty acyl anilinesulfonic acid, lignosulfonates, polycarboxylate, alkyl phenol polyoxyethylene ether sulfate, alkyl benzene sulphonate
One in calcium salt, aliphatic ester sulfate, EO-PO block polymers, alkyl phenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether etc.
Kind is several.
The disintegrant can be sodium carboxymethyl starch, low-substituted hydroxypropyl cellulose, croscarmellose sodium,
Crospovidone, chitosan, sodium alginate, sodium bicarbonate, magnesium chloride, aluminium chloride, sodium chloride, urea, ammonium sulfate, bentonite etc.
One or more of.
The thickener can be polyvinyl acetate, xanthans, gelatin, gum arabic, aluminium-magnesium silicate, phenolic aldehyde tree
One or more of fat, hydroxymethyl cellulose, sodium alginate etc..
The solid carrier can be precipitated calcium carbonate, clay, kaolin, diatomite, bentonite, white carbon, clay,
One or more of attapulgite, talcum powder, quartz sand, precipitated calcium carbonate etc..
The liquid-carrier can be exquisite soybean oil, corn oil, rapeseed oil, turpentine oil, methyl oleate, coconut oil,
One or more of palm oil etc..
The deionized water is industrialization deionized water.
The composition pesticide can be used for preventing and kill off rice year annual grassy weeds.
The present invention has the advantages that：
1, quinoline humulone and benzene flumetsulam have synergistic effect, such as green bristlegrass within the scope of certain proportion to target weeds
(Setaria viridis), acalypha copperleaf (Acalypha australis) etc..
2, quinoline humulone and benzene flumetsulam are mixed within the scope of certain proportion can reduce Pesticide use amount, reduce grower
Using pesticide cost and mitigate environmental pollution.
Specific implementation mode
In order to keep the objectives, technical solutions, and advantages of the present invention more concise, present invention following specific examples
It illustrates, but the present invention is by no means limited to these examples.It is as described below to be only the preferred embodiment of the present invention, it is used only for retouching
The present invention is stated, limiting the scope of the present invention is should not be understood as.It should be pointed out that it is all the spirit and principles in the present invention it
Interior done all any modification, equivalent and improvement etc., should all be included in the protection scope of the present invention.
One, raw to survey embodiment
According to the Colby formula (predictive role of evaluation particular composition, referring to S.R.Colby, " Calculating
Synergistic and Antagonistic Responses of Herbicide combinations”Weeds 1967,
15,20-22) as follows, formula is as follows：
In formula：
X is the fresh weight inhibition rate to target weeds when quinoline humulone is applied alone with certain dosage；
Y is the fresh weight inhibition rate to target weeds when benzene flumetsulam is applied alone with certain dosage；
E0For two kinds of quinoline humulone, benzene flumetsulam pharmacy mix when theoretical value to target weeds fresh weight inhibition rate or expectation
Value；
It is the measured value compareed to target weeds fresh weight inhibition rate when E is two kinds of quinoline humulone, benzene flumetsulam pharmacy mix
Or observation.
Evaluation criterion：The observation of fresh weight inhibition rate has synergistic effect (synergistic effect) when being more than desired value.
1 quinoline humulone of table, benzene flumetsulam and its compounding are to green bristlegrass (Setaria viridis), acalypha copperleaf (Acalypha
Australis) interior toxicity test, green bristlegrass, acalypha copperleaf are 3 leaf phase weeds (m2Expression square metre).
The inhibiting rate of 1 quinoline humulone of table, benzene flumetsulam and its compounding to green bristlegrass, acalypha copperleaf
The synergy of mixture is evaluated according to Colby equatioies, 1 data of table are shown, quinoline humulone, two tuple of benzene flumetsulam
Close (1g+0.5g)/1500m2To (1g+5g)/1500m2To green bristlegrass (Setaria viridis), acalypha copperleaf (Acalypha
Australis) toxicity observation is more than desired value, has synergistic effect；And (1g+7g)/1500m2To (1g+10g)/
1500m2To green bristlegrass (Setaria viridis), acalypha copperleaf (Acalypha australis) toxicity observation is less than
Desired value, without synergistic effect.
Two, example of formulations
One quinoline humulone benzene flumetsulam water dispersible granules of example of formulations
Above-mentioned material is added together in cone-type mixer and is uniformly mixed, is crushed by airslide disintegrating mill, the object after crushing
Material is mixed through cone-type mixer again, and mixed fineness of materials 98% is added in kneader that be kneaded into can by 600 mesh standard sieves
This material is finally put into extruder grain in Squeezinggranulator by plastic material, obtains corresponding weight after granulation after drying, screening
Measure the quinoline humulone benzene flumetsulam water dispersible granules of percentage.
Two quinoline humulone benzene flumetsulam aqueous suspension agent of example of formulations
Above-mentioned formula is crushed in advance in proportion, adds in sand mill and grinds, system is allocated after high shear mixing
Obtain the quinoline humulone benzene flumetsulam suspending agent of corresponding weight percent.
The three dispersible oil-suspending agent of quinoline humulone benzene flumetsulam of example of formulations
Above-mentioned material (except organobentonite) is added to together in reaction kettle mixing machine, is stirred 2 hours, bottom is opened
Material is injected in multistage sand mill and is ground by pan feeding valve, and the fineness of materials 98% after grinding after 1-5um by discharging, and material is again
It is put into togerther in high-shear emulsifying kettle with the organobentonite dissolved in advance, it is good corresponding that flowing to property is can be made into after emulsification
The quinoline humulone benzene flumetsulam oil-suspending agent of weight percent.
Three, Application Example
Quinoline humulone, benzene flumetsulam herbicidal composition prevent and kill off corn field annual grassy weeds field control effectiveness test.
Quinoline humulone, benzene flumetsulam herbicidal composition are to the field control effectiveness test result (product of corn field annual grassy weeds
Kind：Zheng Dan 958；Dispenser period, 4 leaf phase of corn, weeds 3-4 leaf phases are watered 30 kilograms of cauline leaf sprayings, field dominant weed per acre
For green bristlegrass, lady's-grass, thorn amaranth, acalypha copperleaf；Comparison medicament is 6% mesotrione of corn field herbicide of Ministry of Agriculture's approval registration
The dispersible oil-suspending agent of 24% atrazine (PD20160733)
2 quinoline humulone of table, benzene flumetsulam herbicidal composition Control Weeds in Maize Field field control effectiveness test
From the herbicidal composition that 2 test result of table can be seen that quinoline humulone, benzene flumetsulam compounds to corn field 1 year
15 days control effects after green bristlegrass, lady's-grass, thorn amaranth, acalypha copperleaf medicine in raw weeds, in the case where dosage is small, control effect
It is also significantly better than the dispersible oil-suspending agent of mesotrione atrazines, shows that there is synergy to make for quinoline humulone, benzene flumetsulam compounding
With can reduce Pesticide use amount, reduce grower using pesticide cost and mitigate environmental pollution.
Claims (10)
1. the composition pesticide of a kind of humulone containing quinoline and benzene flumetsulam, it is characterised in that：Active constituent is phonetic by quinoline humulone and benzene
Sulphur grass amine forms, and wherein the mass fraction ratio of quinoline humulone and benzene flumetsulam is 1:0.5~5.
2. composition pesticide according to claim 1, it is characterised in that：The mass parts of the quinoline humulone and benzene flumetsulam
Number ratio is 1:1~3.
3. composition pesticide according to claim 2, it is characterised in that：The mass parts of the quinoline humulone and benzene flumetsulam
Number ratio is 1:1.
4. composition pesticide according to claim 2, it is characterised in that：The mass parts of the quinoline humulone and benzene flumetsulam
Number ratio is 1:1.5.
5. composition pesticide according to claim 2, it is characterised in that：The mass parts of the quinoline humulone and benzene flumetsulam
Number ratio is 1:2.
6. composition pesticide according to claim 2, it is characterised in that：The mass parts of the quinoline humulone and benzene flumetsulam
Number ratio is 1:3.
7. the weight of composition pesticide according to claim 1, the active constituent is composition pesticide total weight
0.1%~60%, remaining is insecticides adjuvant.
8. composition pesticide according to claim 7, the weight of the active component is the 5% of composition pesticide total weight
~40%, remaining is insecticides adjuvant.
9. according to the composition pesticide described in claim 1~8 any one, the composition pesticide can be prepared as aqueous suspension
Agent, dispersible oil-suspending agent, water dispersible granules.
10. the composition pesticide described in claim 1~8 any one is used to prevent and kill off the purposes of corn field annual grassy weeds.
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| CN109006829A (en) * | 2018-11-01 | 2018-12-18 | 山东省农业科学院植物保护研究所 | One kind humulone containing quinoline and sethoxydim binary herbicidal composition and its preparation and application |
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| CN109122694A (en) * | 2018-11-01 | 2019-01-04 | 山东省农业科学院植物保护研究所 | A kind of binary herbicidal composition and its preparation and the application of humulone containing quinoline and sulfentrazone |
| CN109221142A (en) * | 2018-11-01 | 2019-01-18 | 山东省农业科学院植物保护研究所 | A kind of binary herbicidal composition and its preparation and the application of humulone containing quinoline and tribenuron-methyl |
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| CN109221144A (en) * | 2018-11-01 | 2019-01-18 | 山东省农业科学院植物保护研究所 | A kind of binary herbicidal composition and its preparation and the application of humulone containing quinoline and isoproturon |
| CN109258660A (en) * | 2018-11-01 | 2019-01-25 | 山东省农业科学院植物保护研究所 | A kind of binary herbicidal composition and its preparation and the application of humulone containing quinoline and flufenacet |
| CN109258655A (en) * | 2018-11-01 | 2019-01-25 | 山东省农业科学院植物保护研究所 | One kind humulone containing quinoline and Quizalotop-ethyl binary herbicidal composition and its preparation and application |
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Application publication date: 20180824 |