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CN108428809A - Soft-package battery - Google Patents

Soft-package battery Download PDF

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Publication number
CN108428809A
CN108428809A CN201710080414.3A CN201710080414A CN108428809A CN 108428809 A CN108428809 A CN 108428809A CN 201710080414 A CN201710080414 A CN 201710080414A CN 108428809 A CN108428809 A CN 108428809A
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CN
China
Prior art keywords
packaging film
layer
layers
soft
free end
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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CN201710080414.3A
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Chinese (zh)
Inventor
林森
何平
谢斌
郭培培
张亚杰
殷科
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Ningde Amperex Technology Ltd
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Ningde Amperex Technology Ltd
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Priority to CN201710080414.3A priority Critical patent/CN108428809A/en
Publication of CN108428809A publication Critical patent/CN108428809A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/183Sealing members
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sealing Battery Cases Or Jackets (AREA)

Abstract

The present invention provides a kind of soft-package batteries comprising two layers of packaging film and the battery core being encapsulated between two layers of packaging film.Each layer packaging film includes external protection, interior fused layer and the metal layer between external protection and interior fused layer.Two layers of packaging film forms the main part of receiving battery core at middle part, is tightly connected around main part and forms closedtop portion and side seal portion, wherein side seal portion bends and is bonded on the side of main part.Each layer packaging film is divided into ontology and free end in side seal portion, and free end is folded back on corresponding ontology;Expose metal layer on the end face of each free end, the free end of two layers of packaging film is fixed together and is clamped between the ontology of two layers of packaging film.The soft-package battery of the present invention can utilize inflection structure of each layer packaging film in side seal portion to realize the insulated enclosure of the metal layer exposed on end face, and edge sealing effect is improved to simplify the edge sealing process of soft-package battery without using other edging materials.

Description

软包电池Soft pack battery

技术领域technical field

本发明涉及电池领域,尤其涉及一种软包电池。The invention relates to the field of batteries, in particular to a soft pack battery.

背景技术Background technique

软包锂离子电池目前主要采用铝塑复合膜进行电芯封装,铝塑膜主要分为保护层、金属层及融合层三层结构。包装时经封装、切边后,在封装边的边缘处的金属层无法被包裹而裸露,容易导致短路等问题。Soft-pack lithium-ion batteries currently mainly use aluminum-plastic composite film for cell packaging. The aluminum-plastic film is mainly divided into a three-layer structure of a protective layer, a metal layer and a fusion layer. After packaging and edge trimming during packaging, the metal layer at the edge of the package cannot be wrapped and exposed, which may easily lead to problems such as short circuits.

目前电池边缘封边结构主要有包胶单折边结构和双折边两种结构。包胶单折边结构是在电池封装边的边缘贴上绝缘胶带,然后采用机械方法将封装边折起并粘贴在电芯主体侧边;双折边结构则是将封装边露出金属层的边缘翻折到封装边本体上,再将封装边本体折起并粘接到电芯主体,通过两次翻折使露出金属层的边缘夹持在封装边本体与电芯主体之间。At present, the edge sealing structure of the battery mainly includes two kinds of structure, the single folding edge structure and the double folding edge structure. The single folded edge structure of the rubber wrapping is to paste the insulating tape on the edge of the battery package, and then use the mechanical method to fold up the package edge and paste it on the side of the main body of the cell; the double folded edge structure is to expose the package edge to the edge of the metal layer Fold it onto the package side body, then fold up the package side body and bond it to the battery core body, and clamp the edge of the exposed metal layer between the package side body and the battery core body through two folds.

两种封边结构均可以解决目前常规电池的露铝问题,但是也存在较大的自身局限性,尤其是在对非矩形电池的非直线边作封边处理时局限性更加明显,一方面,对于非直线边,绝缘胶带无法完整的包覆封装边的边缘,存在露铝风险,对于圆角等弧形边,存在胶带起皱、重叠等问题,引起外观缺陷,并且在使用一定时间后,胶带在起始处和终止处可能翘起或翻角,引起外观缺陷和露铝风险;另一方面,对于包胶单折边结构,需要增加胶带等耗材,同时需要增加贴胶工序;对于双折边结构,两次折边工序繁琐,同时增加了电池的宽度,容易导致尺寸超规格。Both edge-sealing structures can solve the problem of exposed aluminum in conventional batteries, but they also have their own limitations, especially when the edge-sealing treatment of non-rectangular batteries is performed on non-linear edges. On the one hand, For non-straight edges, the insulating tape cannot completely cover the edge of the packaging edge, and there is a risk of aluminum exposure. For curved edges such as rounded corners, there are problems such as tape wrinkling and overlapping, causing appearance defects, and after a certain period of use, The tape may be warped or turned at the beginning and end, causing appearance defects and the risk of aluminum exposure; For the folded edge structure, the double folded edge process is cumbersome, and at the same time increases the width of the battery, which may easily cause the size to exceed the specification.

发明内容Contents of the invention

鉴于背景技术中存在的问题,本发明的目的在于提供一种软包电池,其能简化封边工艺,提高封边效果。In view of the problems existing in the background technology, the object of the present invention is to provide a pouch battery, which can simplify the edge-sealing process and improve the edge-sealing effect.

为了实现上述目的,本发明提供了一种软包电池,其包括两层包装膜以及封装在两层包装膜之间的电芯。各层包装膜包括外保护层、内融合层以及位于外保护层与内融合层之间的金属层。两层包装膜在中部形成收容电芯的主体部,在主体部的周围密封连接并形成顶封部和侧封部,其中,侧封部弯折并粘接在主体部的侧面上。各层包装膜在侧封部上分为本体和自由端,而自由端回折到对应的本体上;各自由端的端面上露出金属层,两层包装膜的自由端固定在一起并夹持在两层包装膜的本体之间。In order to achieve the above object, the present invention provides a soft pack battery, which includes two layers of packaging films and an electric core packaged between the two layers of packaging films. Each layer of packaging film includes an outer protection layer, an inner fusion layer and a metal layer between the outer protection layer and the inner fusion layer. The two-layer packaging film forms a main body for storing batteries in the middle, and seals and connects around the main body to form a top seal and a side seal, wherein the side seal is bent and bonded to the side of the main body. Each layer of packaging film is divided into a body and a free end on the side seal, and the free end is folded back to the corresponding body; the metal layer is exposed on the end surface of each free end, and the free ends of the two layers of packaging film are fixed together and clamped between the two Between the body of the layer wrapping film.

本发明的有益效果如下:The beneficial effects of the present invention are as follows:

在根据本发明的软包电池中,各层包装膜在侧封部上的自由端并夹持在两层包装膜的本体之间,从而使得端面上露出金属层直接由两层包装膜的本体绝缘密封,因此,本发明的软包电池可以利用各层包装膜在侧封部上的回折结构实现端面上露出的金属层的绝缘密封,无需使用其它的封边材料,从而简化软包电池的封边工艺,提高封边效果。In the pouch battery according to the present invention, the free ends of each layer of packaging film on the side seal are clamped between the bodies of the two layers of packaging films, so that the exposed metal layer on the end surface is directly exposed by the bodies of the two layers of packaging films. Insulation and sealing, therefore, the pouch battery of the present invention can utilize the folding structure of each layer of packaging film on the side sealing part to realize the insulation and sealing of the metal layer exposed on the end surface, without using other edge sealing materials, thereby simplifying the pouch battery. Edge banding process improves the effect of edge banding.

附图说明Description of drawings

图1为根据本发明的软包电池的包装膜的一示意图;Fig. 1 is a schematic diagram of the packaging film of the pouch battery according to the present invention;

图2为图1沿中心线C作出的剖视图;Fig. 2 is a sectional view taken along the centerline C of Fig. 1;

图3为根据本发明的软包电池成型前的一示意图;Fig. 3 is a schematic diagram of the pouch battery according to the present invention before molding;

图4为根据本发明的软包电池成型前的另一示意图;Fig. 4 is another schematic diagram of the pouch battery according to the present invention before molding;

图5为图4沿线A-A作出的剖视图;Fig. 5 is a sectional view taken along line A-A of Fig. 4;

图6为图5虚线框部分的放大图;Fig. 6 is an enlarged view of the dotted frame in Fig. 5;

图7为据本发明的软包电池成型后的一示意图。FIG. 7 is a schematic view of the formed pouch battery according to the present invention.

其中,附图标记说明如下:Wherein, the reference signs are explained as follows:

1 顶封部 P3 金属层1 Top seal P3 metal layer

2 侧封部 G 胶水2 Side seal G glue

21 本体 S 凹腔21 Body S Recess

22 自由端 B 电芯22 Free end B Cell

221 端面 B1 极耳221 End face B1 tab

3 主体部 W 宽度方向3 Main body W width direction

31 侧面 L 长度方向31 Side L Length direction

P 包装膜 T 厚度方向P Packaging film T Thickness direction

P1 外保护层 C 中心线P1 Outer protective layer C Centerline

P2 内融合层P2 inner fusion layer

具体实施方式Detailed ways

下面参照附图来详细说明本发明的软包电池。The pouch battery of the present invention will be described in detail below with reference to the accompanying drawings.

参照图1至图7,根据本发明的软包电池包括两层包装膜P以及封装在两层包装膜P之间的电芯B。各层包装膜P包括外保护层P1、内融合层P2以及位于外保护层P1与内融合层P2之间的金属层P3。两层包装膜P在中部形成收容电芯B的主体部3,在主体部3的周围密封连接并形成顶封部1和侧封部2,其中,侧封部2弯折并粘接在主体部3的侧面31上。各层包装膜P在侧封部2上分为本体21和自由端22,而自由端22回折到对应的本体21上;各自由端22的端面211上露出金属层P3,两层包装膜P的自由端22固定在一起并夹持在两层包装膜P的本体21之间。Referring to FIG. 1 to FIG. 7 , the pouch battery according to the present invention includes two layers of packaging film P and a battery cell B packaged between the two layers of packaging film P. Each layer of packaging film P includes an outer protective layer P1, an inner fusion layer P2, and a metal layer P3 located between the outer protection layer P1 and the inner fusion layer P2. The two-layer packaging film P forms the main body part 3 in the middle to accommodate the battery B, and is sealed and connected around the main body part 3 to form a top seal part 1 and a side seal part 2, wherein the side seal part 2 is bent and bonded to the main body On the side 31 of the part 3. Each layer of packaging film P is divided into a body 21 and a free end 22 on the side sealing part 2, and the free end 22 is folded back to the corresponding body 21; the metal layer P3 is exposed on the end surface 211 of each free end 22, and the two layers of packaging film P The free ends 22 are fixed together and clamped between the bodies 21 of the two packaging films P.

在根据本发明的软包电池中,各层包装膜P在侧封部2上的自由端22并夹持在两层包装膜P的本体21之间,从而使得端面211上露出金属层P3直接由两层包装膜P的本体21绝缘密封,因此,本发明的软包电池可以利用各层包装膜P在侧封部2上的回折结构实现端面211上露出的金属层P3的绝缘密封,无需使用其它的封边材料(例如绝缘胶带),从而简化软包电池的封边工艺(即将包装膜P露出的金属层P3绝缘密封的工艺),提高封边效果。In the pouch battery according to the present invention, the free end 22 of each layer of packaging film P on the side sealing part 2 is clamped between the bodies 21 of the two layers of packaging film P, so that the metal layer P3 is exposed directly on the end surface 211. The body 21 of the two-layer packaging film P is insulated and sealed. Therefore, the pouch battery of the present invention can utilize the folding structure of each layer of packaging film P on the side sealing part 2 to realize the insulation and sealing of the metal layer P3 exposed on the end surface 211 without Use other edge-sealing materials (such as insulating tape) to simplify the edge-sealing process of the pouch battery (that is, the process of insulating and sealing the metal layer P3 exposed from the packaging film P) and improve the edge-sealing effect.

对于非矩形的软包电池,也可以采用上述的结构实现封边。例如,对于有弧形边的软包电池,由于这种方式无需绝缘胶带,从而可以避免使用绝缘胶带导致的起皱、重叠等问题。For non-rectangular pouch batteries, the above structure can also be used to achieve edge sealing. For example, for pouch batteries with curved edges, since this method does not require insulating tape, problems such as wrinkling and overlapping caused by the use of insulating tape can be avoided.

在根据本发明的软包电池中,内融合层P2为聚丙烯,外保护层P1为尼龙,金属层P3为铝箔或钢箔。In the pouch battery according to the present invention, the inner fusion layer P2 is polypropylene, the outer protective layer P1 is nylon, and the metal layer P3 is aluminum foil or steel foil.

在根据本发明的软包电池中,参照图7,侧封部2通过粘接剂G粘接到主体部3的侧面31上。粘接剂G可为胶水、胶纸等材料。In the pouch battery according to the present invention, referring to FIG. 7 , the side seal portion 2 is adhered to the side surface 31 of the main body portion 3 by an adhesive G. Referring to FIG. Adhesive G can be materials such as glue, gummed paper.

在根据本发明的软包电池中,参照图7,一层包装膜P上形成有收容电芯B的凹腔S,且该层包装膜P在侧封部2上的本体21粘接在主体部3的侧面31上。在所述一层包装膜P进行冲压以形成凹腔S。主体部3的侧面31也就是所述一层包装膜P冲出的凹腔S的对应外壁。In the pouch battery according to the present invention, referring to FIG. 7 , a cavity S for accommodating the cell B is formed on a layer of packaging film P, and the body 21 of the layer of packaging film P on the side seal portion 2 is bonded to the main body. On the side 31 of the part 3. Stamping is performed on the one layer of packaging film P to form a concave cavity S. The side 31 of the main body 3 is also the corresponding outer wall of the concave cavity S punched out by the layer of packaging film P.

在根据本发明的软包电池中,参照图5至图7,包装膜P在自由端22处的内融合层P2与在本体21处的内融合层P2融合在一起。内融合层P2一般为热熔性塑胶材料(聚丙烯),所以在包装膜P的自由端22回折后自由端22处的内融合层P2与在本体21处的内融合层P2直接相对,通过热压可以将自由端22与对应的本体21固定连接。In the pouch battery according to the present invention, referring to FIGS. 5 to 7 , the inner fusion layer P2 at the free end 22 of the packaging film P is fused with the inner fusion layer P2 at the body 21 . The inner fusion layer P2 is generally a hot-melt plastic material (polypropylene), so after the free end 22 of the packaging film P is folded back, the inner fusion layer P2 at the free end 22 is directly opposite to the inner fusion layer P2 at the body 21. Hot pressing can fixedly connect the free end 22 with the corresponding body 21 .

在根据本发明的软包电池中,两层包装膜P的自由端22通过胶水粘接在一起。由于两层包装膜P上下相对,因此两层包装膜P在自由端22处的外保护层P1直接相对,而外保护层P1(尼龙)一般不具备热熔性,因此需要通过胶水来实现两层包装膜P的自由端22的固定连接。In the pouch battery according to the present invention, the free ends 22 of the two packaging films P are bonded together by glue. Since the two layers of packaging film P are facing each other up and down, the outer protective layer P1 of the two layers of packaging film P at the free end 22 is directly opposite, and the outer protective layer P1 (nylon) generally does not have heat-meltability, so it is necessary to realize the two layers by glue. The fixed connection of the free end 22 of the layer packaging film P.

在根据本发明的软包电池中,参照图7,两个本体21直接相对的部分内融合层P2融合在一起。由于两层包装膜P上下相对,所以两层包装膜P在侧封部2上的两个本体21的内融合层P2上下相对(除去本体21被对应自由端22覆盖的部分),通过热压可将两个本体21直接相对的部分内融合层P2融合在一起。In the pouch battery according to the present invention, referring to FIG. 7 , the inner fusion layers P2 of the directly opposite parts of the two bodies 21 are fused together. Since the two-layer packaging film P is facing up and down, the inner fusion layers P2 of the two main bodies 21 on the side seal part 2 of the two-layer packaging film P are facing up and down (except the part where the main body 21 is covered by the corresponding free end 22), by hot pressing The inner fusion layer P2 in the directly opposite parts of the two main bodies 21 may be fused together.

在根据本发明的软包电池中,参照图7,侧封部2沿厚度方向T的高度小于侧面31的高度。避免侧封部2占用软包电池在厚度方向T上的空间,防止侧封部2过高导致软包电池的能量密度降低。In the pouch battery according to the present invention, referring to FIG. 7 , the height of the side sealing portion 2 along the thickness direction T is smaller than the height of the side surface 31 . Avoid the side seal portion 2 occupying the space of the pouch battery in the thickness direction T, and prevent the energy density of the pouch battery from being reduced due to the side seal portion 2 being too high.

在根据本发明的软包电池中,所述两层包装膜P为独立的两张包装膜。其中,一张包装膜上冲压出凹腔S,另一张包装膜与所述一张包装膜在凹腔S的周围密封连接并形成顶封部1和侧封部2。In the pouch battery according to the present invention, the two-layer packaging film P is two independent packaging films. Wherein, a concave cavity S is punched out on one packaging film, and the other packaging film is sealed and connected with the one packaging film around the concave cavity S to form a top sealing part 1 and a side sealing part 2 .

在根据本发明的软包电池中,参照图1至图4,所述两层包装膜P为一张包装膜,所述一张包装膜对折后形成两层相连的包装膜P。在所述一张包装膜上冲压出凹腔S,然后对折以将凹腔S密封,同时形成相连的两层包装膜P。In the pouch battery according to the present invention, referring to FIG. 1 to FIG. 4 , the two-layer packaging film P is one packaging film, and the one packaging film P is folded in half to form two connected packaging films P. A concave cavity S is punched out on the one packaging film, and then folded in half to seal the concave cavity S, and at the same time, two layers of packaging films P are connected.

在根据本发明的软包电池中,参照图4,电芯B的极耳B1从顶封部1伸出。In the pouch battery according to the present invention, referring to FIG. 4 , the tab B1 of the cell B protrudes from the top seal portion 1 .

以下为本发明一实施例的软包电池的成型过程:The following is the molding process of the pouch battery according to an embodiment of the present invention:

1)参照图1和图2,将一张包装膜P沿宽度方向W两端的露出金属层P3的自由端22回折,以使自由端22的内融合层P2与包装膜P基体的内融合层P2贴合,然后通过热压将自由端22与包装膜P的基体融合在一起;1) With reference to Fig. 1 and Fig. 2, fold back the free end 22 of a piece of packaging film P along the two ends of the width direction W that exposes the metal layer P3, so that the inner fusion layer P2 of the free end 22 and the inner fusion layer of the packaging film P substrate P2 bonding, and then the free end 22 is fused with the substrate of the packaging film P by hot pressing;

2)参照图3,在包装膜P在中心线C的一侧的部分冲坑以形成凹腔S,并将电芯B放置到凹腔S内;2) Referring to Figure 3, punch a hole in the part of the packaging film P on the side of the center line C to form a cavity S, and place the battery B in the cavity S;

3)参照图4至图6,在自由端22上涂覆胶水,然后将包装膜P在中心线C的另一侧的部分翻折以封闭凹腔S,翻折后一整张包装膜P分为上下两层,且两层包装膜P的相对的自由端22粘接在一起,其中两层包装膜P的包围电芯B的部分为主体部3;3) Referring to Figures 4 to 6, apply glue on the free end 22, then fold the part of the packaging film P on the other side of the centerline C to close the cavity S, and after folding the entire packaging film P It is divided into upper and lower layers, and the opposite free ends 22 of the two-layer packaging film P are bonded together, wherein the part of the two-layer packaging film P surrounding the battery cell B is the main part 3;

4)参照图7,对主体部3周围的两层包装膜P直接接触的部分进行热压,在主体部3沿宽度方向W两侧形成侧封部2,在主体部3沿长度方向L的一侧形成顶封部1,电芯B的极耳B1经由顶封部1伸出;然后在侧封部2涂粘接剂G,然后弯折侧封部2以将侧封部2粘接在主体部3的侧面31上。4) With reference to Fig. 7, the part of the two-layer packaging film P around the main body 3 that is in direct contact is hot-pressed, and side seals 2 are formed on both sides of the main body 3 along the width direction W, and on the sides of the main body 3 along the length direction L One side forms the top seal part 1, and the tab B1 of the cell B protrudes through the top seal part 1; then apply adhesive G on the side seal part 2, and then bend the side seal part 2 to bond the side seal part 2 On the side surface 31 of the main body part 3 .

Claims (10)

1. a kind of soft-package battery, including two layers of packaging film (P) and the battery core (B) that is encapsulated between two layers of packaging film (P);
Each layer packaging film (P) includes external protection (P1), interior fused layer (P2) and positioned at external protection (P1) and interior fused layer (P2) metal layer (P3) between;
Two layers of packaging film (P) forms the main part (3) of receiving battery core (B) at middle part, is tightly connected simultaneously around main part (3) It is formed closedtop portion (1) and side seal portion (2), wherein side seal portion (2) bend and are bonded on the side (31) of main part (3);
It is characterized in that,
Each layer packaging film (P) is divided into ontology (21) and free end (22) on side seal portion (2), and free end (22) are folded back to correspondence Ontology (21) on;Expose metal layer (P3), the free end of two layers of packaging film (P) on the end face (211) of each free end (22) (22) it is fixed together and is clamped between the ontology (21) of two layers of packaging film (P).
2. soft-package battery according to claim 1, which is characterized in that interior fused layer (P2) is polypropylene, external protection (P1) it is nylon, metal layer (P3) is aluminium foil or steel foil.
3. soft-package battery according to claim 1, which is characterized in that side seal portion (2) are adhered to main body by bonding agent (G) On the side (31) in portion (3).
4. soft-package battery according to claim 1, which is characterized in that be formed with receiving battery core (B) on one layer of packaging film (P) Cavity (S), and ontology (21) of this layer of packaging film (P) on side seal portion (2) is bonded on the side (31) of main part (3).
5. soft-package battery according to claim 1, which is characterized in that interior fusion of the packaging film (P) at free end (22) Layer (P2) is merged with the interior fused layer (P2) at ontology (21).
6. soft-package battery according to claim 1, which is characterized in that the free end (22) of two layers of packaging film (P) passes through glue Water bonds together.
7. soft-package battery according to claim 1, which is characterized in that two ontologies (21) are merged in directly opposite part Layer (P2) is merged.
8. soft-package battery according to claim 1, which is characterized in that the height of side seal portion (2) through-thickness (T) is less than The height of side (31).
9. soft-package battery according to claim 1, which is characterized in that two layers of packaging film (P) is independent Liang Zhangbao Fill film.
10. soft-package battery according to claim 1, which is characterized in that two layers of packaging film (P) is a packaging film, Two layers of connected packaging film (P) is formed after one packaging film doubling.
CN201710080414.3A 2017-02-15 2017-02-15 Soft-package battery Pending CN108428809A (en)

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JP2005116278A (en) * 2003-10-06 2005-04-28 Nec Lamilion Energy Ltd Laminated battery, protection member and battery unit for the laminated battery
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Application publication date: 20180821