CN108421200A - It is a kind of using waste shell as the preparation method of the fire foam of raw material - Google Patents
It is a kind of using waste shell as the preparation method of the fire foam of raw material Download PDFInfo
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- CN108421200A CN108421200A CN201810496522.3A CN201810496522A CN108421200A CN 108421200 A CN108421200 A CN 108421200A CN 201810496522 A CN201810496522 A CN 201810496522A CN 108421200 A CN108421200 A CN 108421200A
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- 239000006260 foam Substances 0.000 title claims abstract description 37
- 239000002994 raw material Substances 0.000 title claims abstract description 21
- 239000002699 waste material Substances 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000000126 substance Substances 0.000 claims abstract description 34
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 28
- 238000006243 chemical reaction Methods 0.000 claims abstract description 25
- 241000276489 Merlangius merlangus Species 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 239000004094 surface-active agent Substances 0.000 claims abstract description 16
- 239000002904 solvent Substances 0.000 claims abstract description 15
- 239000003381 stabilizer Substances 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims description 25
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 18
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 239000004115 Sodium Silicate Substances 0.000 claims description 6
- 230000003213 activating effect Effects 0.000 claims description 6
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 150000002500 ions Chemical class 0.000 claims description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 6
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 6
- 239000001488 sodium phosphate Substances 0.000 claims description 6
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 6
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 235000019441 ethanol Nutrition 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 2
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims description 2
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims description 2
- 238000007259 addition reaction Methods 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 229960003237 betaine Drugs 0.000 claims description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 2
- 235000013539 calcium stearate Nutrition 0.000 claims description 2
- 239000008116 calcium stearate Substances 0.000 claims description 2
- 238000005285 chemical preparation method Methods 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 239000002563 ionic surfactant Substances 0.000 claims description 2
- 239000000787 lecithin Substances 0.000 claims description 2
- 229940067606 lecithin Drugs 0.000 claims description 2
- 235000010445 lecithin Nutrition 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- 229950008882 polysorbate Drugs 0.000 claims description 2
- 229920000136 polysorbate Polymers 0.000 claims description 2
- HSJXWMZKBLUOLQ-UHFFFAOYSA-M potassium;2-dodecylbenzenesulfonate Chemical group [K+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HSJXWMZKBLUOLQ-UHFFFAOYSA-M 0.000 claims description 2
- 229940079827 sodium hydrogen sulfite Drugs 0.000 claims description 2
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 150000001413 amino acids Chemical class 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims 1
- 159000000000 sodium salts Chemical class 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 abstract description 6
- 229910021502 aluminium hydroxide Inorganic materials 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- 230000007812 deficiency Effects 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 239000002736 nonionic surfactant Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 3
- 210000002700 urine Anatomy 0.000 description 3
- 239000007788 liquid Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 125000003275 alpha amino acid group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0071—Foams
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Detergent Compositions (AREA)
Abstract
It is the present invention relates to a kind of preparation method of environment-friendly type fire foam, more particularly to a kind of using waste shell as the fire foam of raw material.The preparation method of the extinguishing chemical is as follows:It is uniform that progress high-speed stirred in reaction kettle is added in 25 30 parts of fc-surfactant of mass fraction meter, 10 20 parts of stabilizer, 5 10 parts of aluminium hydroxide, 5 15 parts of Nano type oyster shell whiting, 20 50 parts of solvent composition, after carrying out reaction 12 hours, obtained substance is carried out bottled or packed is sealed；It is an object of the invention to be directed to above-mentioned technological deficiency existing for current aqueous film-forming foam extinguishing agent, a kind of environment-friendly type fire foam is provided, feature is the good at bubble effect of the extinguishing chemical, and the attachment time is long, and environmental pollution is small；It is another object of the present invention to provide a kind of using oyster shell whiting as the fire foam of raw material, and especially using oyster shell as the fire foam of raw material, this measure is conducive to the secondary use of waste, and promote sustainable development strategy implementation.
Description
Technical field
It is the present invention relates to a kind of environment-friendly type fire foam, more particularly to a kind of using waste shell as the foam fire-fighting of raw material
The preparation method of agent.
Background technology
Current fire foam product category main on the market includes aqueous film-forming foam extinguishing agent, air foam agent
And chemical fire foam, also occur protein foam extinguishing agent in recent years.The fire-fighting principle of fire foam is to be to pass through
Foaming agent generates foam on comburant surface, and fire-retardant purpose is realized in the further contact to completely cut off combustible and air.Its
Middle aqueous film-forming foam extinguishing agent is due to technology of preparing maturation, and product category is various, and the fire-fighting for being widely used in public place is set
In standby.It is advantageous that the extinguishing chemical can not only put out fire caused by solid combustible, for flammable liquid fuel
Fire behavior control also has good effect.
Due to commercially available aqueous film-forming foam extinguishing agent generally all inorganic salts or organic salt containing higher concentration, corrosivity compared with
Greatly.And in order to avoid the disadvantage big at mobility after bubble, adhesion is poor, stabilizer concentration therein is often improved, this gesture
It must cause secondary pollution.
Invention content
It is an object of the invention to be directed to above-mentioned technological deficiency existing for current aqueous film-forming foam extinguishing agent, a kind of ring is provided
Guarantor's type fire foam, feature are the good at bubble effect of the extinguishing chemical, and the attachment time is long, and environmental pollution is small.The present invention's
Another is designed to provide a kind of using oyster shell whiting as the fire foam of raw material, especially goes out by the foam of raw material of oyster shell
Fiery agent, this measure are conducive to the secondary use of waste, and promote sustainable development strategy implementation.
What the present invention realized by the following technical solutions
It is a kind of using waste shell as the preparation method of the fire foam of raw material, which is characterized in that the extinguishing chemical
Preparation method is as follows:
(1) it after being cleaned up the oyster shell that market is bought, is crushed, it is big to obtain grain size after crushing
It is small in 10-200 mesh powders, then will weigh mass fraction be 100-120 part the powder be added reaction kettle in, then again add
Enter suitable dilute hydrochloric acid solution after powder solvent, 1-2 parts of sodium metasilicate is added, high-speed stirred is then turned on, in the mistake of stirring
80-120 parts of sodium carbonate is slowly added in journey, after carrying out high-speed stirred reaction after being added dropwise completely again 1-2 hours, stops stirring
It mixes, then obtained substance is dried, the substance after drying is exactly Nano type oyster shell whiting；
(2) by the fc-surfactant, 10-20 parts of stabilizer, 5-10 parts of hydrogen-oxygen of 25-30 parts of mass fraction meter
It is uniform to change progress high-speed stirred in aluminium, 5-15 parts of Nano type oyster shell whiting, 20-50 parts of solvent composition addition reaction kettle, progress
After reaction 1-2 hour, by substance carry out it is bottled or it is packed be sealed, this substance is exactly that a kind of environment-friendly type is put out a fire
Agent.
Further, the fc-surfactant be by mass fraction be 10-20 parts ion surface type activating agent, 2-
8 parts of nonionic surfactant, 3-4 parts of sodium hydrogensulfite, 4-6 parts of sodium phosphate is added in reaction kettle and is uniformly mixed
The substance obtained afterwards.
Further, the stabilizer be by quality powder number be 10-20 parts ethylene glycol, 4-8 parts of butyl,
The substance that 3-6 parts of butyl glycol ether, 1-4 parts of urea are obtained after mixing.
Further, the solution that the solvent mixes for 95% water and 5% ethyl alcohol.
Further, the ionic surfactant is odium stearate, Potassium dodecylbenzenesulfonate, betaine type sodium
One or more of salt, calcium stearate, zinc stearate.
Further, the nonionic surface active agent be fatty acid sorbitan, it is amino acid pattern lecithin, quaternized
One or more of object, polysorbate.
Beneficial to benefit
1, technology of the invention is on the basis of the formula of traditional aqueous film-forming foam extinguishing agent, use particle oyster shell whiting and
Aluminium hydroxide increases duration of the fire foam in combustible surface of liquid due to the adhesion of solid particle,
To improve extinguishing property；
2, the main component for the oyster shell whiting that the present invention uses is calcium carbonate, and with fine and close cavernous structure, specific surface
Product is big, and moisturizing power is high.The particle is fast at bubble after being sprayed in fire extinguisher, and coverage effect is good.And the oyster shell whiting under wet face state can
To go deep into combustible gap, long-acting moisture film is contributed to form, avoids the secondary resume combustion after putting out；
3, it is raw material present invention utilizes waste shell powder, has the characteristics that environmental protection.
Specific implementation mode
In order to keep the purpose of the present invention, technical solution and advantageous effect clearer, below in conjunction with experimental data, to this
The preferred embodiment of invention is described in detail, to facilitate the technical staff to understand.
Embodiment 1
It is a kind of as follows using waste shell as the preparation method of the fire foam of raw material:
(1) it after being cleaned up the oyster shell that market is bought, is crushed, it is big to obtain grain size after crushing
It is small in 120 mesh powders, then will weigh the powder that mass fraction is 100 parts and be added in reaction kettle, then add appropriate
Dilute hydrochloric acid solution after powder solvent, 1 part of sodium metasilicate is added, is then turned on high-speed stirred, during stirring slowly
80 parts of addition sodium carbonate, again carry out after high-speed stirred reacts 1 hour, stopping stirring, then obtaining after being added dropwise completely
Substance is dried, and obtains Nano type oyster shell whiting；
(2) the ion surface type activating agent, 2 parts of nonionic surfactant, 3 parts of sulfurous for being 10 parts by mass fraction
Sour hydrogen sodium, 4 parts of sodium phosphate are added in reaction kettle and carry out after mixing, obtaining fc-surfactant；
(3) it is 10 parts of ethylene glycol, 4 parts of butyl, 3 parts of butyl glycol ether, 1 part of urine by quality powder number
Element carries out after mixing, obtaining stabilizer；
(4) by 25 parts of fc-surfactant of mass fraction meter, 10 parts of stabilizer, 5 parts of aluminium hydroxide, 5 parts
Nano type oyster shell whiting, 20 parts solvent composition be added reaction kettle in carry out high-speed stirred it is uniform, carry out reaction 1 hour after, will
Substance carry out it is bottled or it is packed be sealed, this substance is exactly a kind of environment-friendly type extinguishing chemical.
Embodiment 2
It is a kind of as follows using waste shell as the preparation method of the fire foam of raw material:
(1) it after being cleaned up the oyster shell that market is bought, is crushed, it is big to obtain grain size after crushing
It is small in 100 mesh powders, then will weigh the powder that mass fraction is 110 parts and be added in reaction kettle, then add appropriate
Dilute hydrochloric acid solution after powder solvent, 1 part of sodium metasilicate is added, is then turned on high-speed stirred, during stirring slowly
82 parts of addition sodium carbonate, again carry out after high-speed stirred reacts 1 hour, stopping stirring, then obtaining after being added dropwise completely
Substance is dried, and obtains Nano type oyster shell whiting；
(2) the ion surface type activating agent, 2 parts of nonionic surfactant, 3 parts of sulfurous for being 12 parts by mass fraction
Sour hydrogen sodium, 4 parts of sodium phosphate are added in reaction kettle and carry out after mixing, obtaining fc-surfactant；
(3) by quality powder number be 12 parts of ethylene glycol, 4 parts of butyl, 3 parts of butyl glycol ether, 1-4 parts
Urea carries out after mixing, obtaining stabilizer；
(4) by 30 parts of fc-surfactant of mass fraction meter, 12 parts of stabilizer, 5 parts of aluminium hydroxide, 15 parts
Nano type oyster shell whiting, 25 parts solvent composition be added reaction kettle in carry out high-speed stirred it is uniform, carry out reaction 1-2 hours after,
By substance carry out it is bottled or it is packed be sealed, this substance is exactly a kind of environment-friendly type extinguishing chemical.
Embodiment 3
It is a kind of as follows using waste shell as the preparation method of the fire foam of raw material:
(1) it after being cleaned up the oyster shell that market is bought, is crushed, it is big to obtain grain size after crushing
It is small in 200 mesh powders, then will weigh the powder that mass fraction is 120 parts and be added in reaction kettle, then add appropriate
Dilute hydrochloric acid solution after powder solvent, 2 parts of sodium metasilicate is added, is then turned on high-speed stirred, during stirring slowly
120 parts of addition sodium carbonate, again carry out after high-speed stirred reacts 2 hours, stopping stirring, then obtaining after being added dropwise completely
Substance is dried, and obtains Nano type oyster shell whiting；
(2) the ion surface type activating agent, 2 parts of nonionic surfactant, 4 parts of sulfurous for being 20 parts by mass fraction
Sour hydrogen sodium, 6 parts of sodium phosphate are added in reaction kettle and carry out after mixing, obtaining fc-surfactant；
(3) it is 15 parts of ethylene glycol, 6 parts of butyl, 5 parts of butyl glycol ether, 2 parts of urine by quality powder number
Element carries out after mixing, obtaining stabilizer；
(4) by 28 parts of fc-surfactant of mass fraction meter, 15 parts of stabilizer, 8 parts of aluminium hydroxide, 8 parts
Nano type oyster shell whiting, 40 parts solvent composition be added reaction kettle in carry out high-speed stirred it is uniform, carry out reaction 2 hours after, will
Substance carry out it is bottled or it is packed be sealed, this substance is exactly a kind of environment-friendly type extinguishing chemical.
Embodiment 4
It is a kind of as follows using waste shell as the preparation method of the fire foam of raw material:
(1) it after being cleaned up the oyster shell that market is bought, is crushed, it is big to obtain grain size after crushing
It is small in 130 mesh powders, then will weigh the powder that mass fraction is 120 parts and be added in reaction kettle, then add appropriate
Dilute hydrochloric acid solution after powder solvent, 2 parts of sodium metasilicate is added, is then turned on high-speed stirred, during stirring slowly
100 parts of addition sodium carbonate, again carry out after high-speed stirred reacts 2 hours, stopping stirring, then obtaining after being added dropwise completely
Substance is dried, and obtains Nano type oyster shell whiting；
(2) the ion surface type activating agent, 6 parts of nonionic surfactant, 3 parts of sulfurous for being 16 parts by mass fraction
Sour hydrogen sodium, 5 parts of sodium phosphate are added in reaction kettle and carry out after mixing, obtaining fc-surfactant；
(3) it is 14 parts of ethylene glycol, 5 parts of butyl, 5 parts of butyl glycol ether, 2 parts of urine by quality powder number
Element carries out after mixing, obtaining stabilizer；
(4) by 28 parts of fc-surfactant of mass fraction meter, 18 parts of stabilizer, 8 parts of aluminium hydroxide, 15 parts
Nano type oyster shell whiting, 50 parts solvent composition be added reaction kettle in carry out high-speed stirred it is uniform, carry out reaction 2 hours after, will
Substance carry out it is bottled or it is packed be sealed, this substance is exactly a kind of environment-friendly type extinguishing chemical.
Experimental analysis：
1, attack time detects
The embodiment 1-4 products prepared and water are subjected to extinguishing property contrast test, testing result is as follows：
Finally illustrate, preferred embodiment above is only used to illustrate the technical scheme of the present invention and unrestricted, although logical
It crosses above preferred embodiment the present invention is described in detail, however, those skilled in the art should understand that, can be
Various changes are made to it in form and in details, defined by claims of the present invention.
Claims (7)
1. a kind of using waste shell as the preparation method of the fire foam of raw material, which is characterized in that the system of the extinguishing chemical
Preparation Method is as follows:
(1) it after being cleaned up the oyster shell that market is bought, is crushed, particle size will be obtained after crushing and is existed
Then 10-200 mesh powders will weigh the powder that mass fraction is 100-120 parts and be added in reaction kettle, then add suitable
The dilute hydrochloric acid solution of amount is added 1-2 parts of sodium metasilicate, high-speed stirred is then turned on, during stirring after powder solvent
80-120 parts of sodium carbonate is slowly added, after carrying out high-speed stirred reaction after being added dropwise completely again 1-2 hours, stops stirring, so
Obtained substance is dried afterwards, the substance after drying is exactly Nano type oyster shell whiting；
(2) by the fc-surfactant, 10-20 parts of stabilizer, 5-10 parts of hydroxide of 25-30 parts of mass fraction meter
It is uniform that high-speed stirred is carried out in aluminium, 5-15 parts of Nano type oyster shell whiting, 20-50 parts of solvent composition addition reaction kettle, is carried out anti-
After answering 1-2 hours, by substance carry out it is bottled or it is packed be sealed, this substance is exactly a kind of environment-friendly type extinguishing chemical.
2. according to claim 1 a kind of using waste shell as the preparation method of the fire foam of raw material, feature exists
In, the fc-surfactant be by mass fraction be 10-20 parts ion surface type activating agent, 2-8 parts of nonionic
The object obtained after mixing in reaction kettle is added in surfactant, 3-4 parts of sodium hydrogensulfite, 4-6 parts of sodium phosphate
Matter.
3. according to claim 1 a kind of using waste shell as the preparation method of the fire foam of raw material, feature exists
In, the stabilizer be by quality powder number be 10-20 parts ethylene glycol, 4-8 parts of butyl, 3-6 parts of second two
The substance that alcohol butyl ether, 1-4 parts of urea is obtained after mixing.
4. according to claim 1 a kind of using waste shell as the preparation method of the fire foam of raw material, feature exists
In the solution that the solvent mixes for 95% water and 5% ethyl alcohol.
5. according to claim 2 a kind of using waste shell as the preparation method of the fire foam of raw material, feature exists
In, the ionic surfactant be odium stearate, it is Potassium dodecylbenzenesulfonate, betaine type sodium salt, calcium stearate, hard
One or more of resin acid zinc.
6. according to claim 2 a kind of using waste shell as the preparation method of the fire foam of raw material, feature exists
In the nonionic surface active agent is in fatty acid sorbitan, amino acid pattern lecithin, quaternary ammonium compound, polysorbate
One or more.
7. the product obtained described in claim 1 is a kind of using waste shell as the fire foam of raw material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810496522.3A CN108421200A (en) | 2018-05-22 | 2018-05-22 | It is a kind of using waste shell as the preparation method of the fire foam of raw material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810496522.3A CN108421200A (en) | 2018-05-22 | 2018-05-22 | It is a kind of using waste shell as the preparation method of the fire foam of raw material |
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| Publication Number | Publication Date |
|---|---|
| CN108421200A true CN108421200A (en) | 2018-08-21 |
Family
ID=63163843
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|---|---|---|---|
| CN201810496522.3A Pending CN108421200A (en) | 2018-05-22 | 2018-05-22 | It is a kind of using waste shell as the preparation method of the fire foam of raw material |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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| CN104056395A (en) * | 2014-06-22 | 2014-09-24 | 许盛英 | Calcium carbonate mesh gel foam mud fire prevention and extinguishing agent |
| CN105396254A (en) * | 2015-11-26 | 2016-03-16 | 襄阳市沧海科技有限公司 | Fluorine-containing complex function extinguishing material |
| CN106457013A (en) * | 2014-02-18 | 2017-02-22 | 消防栓国际贸易有限公司 | fire extinguishing composition |
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| CN1931396A (en) * | 2005-09-15 | 2007-03-21 | 泉耀新材料科技（上海）有限公司 | High efficiency hydroxide/oxide aerosol gel extinguishant and its application |
| CN101426557A (en) * | 2005-09-28 | 2009-05-06 | 塞默斯股份公司 | Fire extinguishant, method for its manufacture and method for fire extinguishing |
| CN106457013A (en) * | 2014-02-18 | 2017-02-22 | 消防栓国际贸易有限公司 | fire extinguishing composition |
| CN104056395A (en) * | 2014-06-22 | 2014-09-24 | 许盛英 | Calcium carbonate mesh gel foam mud fire prevention and extinguishing agent |
| CN105396254A (en) * | 2015-11-26 | 2016-03-16 | 襄阳市沧海科技有限公司 | Fluorine-containing complex function extinguishing material |
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Application publication date: 20180821 |