CN108376720A - A kind of photovoltaic cell component and preparation method thereof - Google Patents
A kind of photovoltaic cell component and preparation method thereof Download PDFInfo
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- CN108376720A CN108376720A CN201810368681.5A CN201810368681A CN108376720A CN 108376720 A CN108376720 A CN 108376720A CN 201810368681 A CN201810368681 A CN 201810368681A CN 108376720 A CN108376720 A CN 108376720A
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F19/00—Integrated devices, or assemblies of multiple devices, comprising at least one photovoltaic cell covered by group H10F10/00, e.g. photovoltaic modules
- H10F19/80—Encapsulations or containers for integrated devices, or assemblies of multiple devices, having photovoltaic cells
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F71/00—Manufacture or treatment of devices covered by this subclass
- H10F71/137—Batch treatment of the devices
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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Abstract
Description
技术领域technical field
本发明涉及光伏技术领域,尤其涉及一种光伏电池组件及其制作方法。The invention relates to the field of photovoltaic technology, in particular to a photovoltaic battery module and a manufacturing method thereof.
背景技术Background technique
太阳能电池组件又被称为光伏电池组件,是一种将吸收的太阳光转换成电能的装置。光伏电池组件通常在室外环境具有25年以上的使用寿命;如果光伏电池组件所处环境的湿度较大,则所处环境的水汽容易侵蚀光伏电池组件,导致光伏电池组件内的太阳能电池芯片发电量降低。因此,光伏电池组件都需要进行防潮密封处理,以适应湿度较大的环境要求。A solar cell module, also known as a photovoltaic cell module, is a device that converts absorbed sunlight into electrical energy. Photovoltaic cell components usually have a service life of more than 25 years in the outdoor environment; if the humidity of the environment where the photovoltaic cell components are located is high, the water vapor in the environment is easy to corrode the photovoltaic cell components, resulting in the power generation of the solar cell chips in the photovoltaic cell components reduce. Therefore, all photovoltaic cell modules need to be subjected to moisture-proof sealing treatment to meet the environmental requirements of high humidity.
现有光伏电池组件包括透光基板和背板,以及形成在透光基板和背板之间的太阳能电池层;透光基板和太阳能电池层之间,以及背板与太阳能电池层之间均通过EVA(乙烯-醋酸乙烯共聚物,英文全称为Ethylene-vinyl Acetate Copolymer,缩写为EVA)胶膜或PVB(聚乙烯醇缩丁醛,英文全称为Poly Vinyl Butyral,缩写为PVB)胶膜粘合在一起,以将太阳能电池层夹胶密封。然而由于PVB材料的耐水性不佳,长期潮湿浸泡易脱落开胶,而EVA易渗水并且容易发黄,所以,在透光基板的边缘和太阳能电池层的边缘之间,以及背板的边缘与太阳能电池层的边缘之间均涂覆有丁基热熔胶,以最大可能的实现防水密封的目的。但是,这种密封方式也使得光伏电池组件的重量增加,使得光伏电池组件难以用于对重量要求比较严格的应用环境,导致光伏电池组件的应用范围受限。The existing photovoltaic cell assembly includes a light-transmitting substrate and a back plate, and a solar cell layer formed between the light-transmitting substrate and the back plate; between the light-transmitting substrate and the solar cell layer, and between the back plate and the solar cell layer, pass EVA (ethylene-vinyl acetate copolymer, English full name is Ethylene-vinyl Acetate Copolymer, abbreviated as EVA) film or PVB (polyvinyl butyral, English full name is Poly Vinyl Butyral, abbreviated as PVB) film bonded on together to seal the solar cell layer sandwich. However, due to the poor water resistance of PVB materials, long-term wet immersion is easy to fall off and open the glue, while EVA is easy to seep and yellow, so between the edge of the light-transmitting substrate and the edge of the solar cell layer, as well as the edge of the back sheet and the solar energy The edges of the battery layers are coated with butyl hot melt adhesive to achieve the purpose of waterproof sealing as much as possible. However, this sealing method also increases the weight of the photovoltaic cell assembly, making it difficult for the photovoltaic cell assembly to be used in an application environment with strict weight requirements, which limits the application range of the photovoltaic cell assembly.
发明内容Contents of the invention
本发明的目的在于提供一种光伏电池组件及其制作方法,以在保证光伏电池组件密封性能的基础上,减轻光伏电池组件的重量,从而扩展光伏电池组件的应用范围。The object of the present invention is to provide a photovoltaic cell assembly and its manufacturing method, so as to reduce the weight of the photovoltaic cell assembly on the basis of ensuring the sealing performance of the photovoltaic cell assembly, thereby expanding the application range of the photovoltaic cell assembly.
为了实现上述目的,本发明提供如下技术方案:In order to achieve the above object, the present invention provides the following technical solutions:
一种光伏电池组件,该光伏电池组件包括太阳能电池芯片和背板,所述太阳能电池芯片和所述背板通过封框件连接在一起,所述封框件的外表面设有疏水封装层。A photovoltaic cell assembly, the photovoltaic cell assembly includes a solar cell chip and a back plate, the solar cell chip and the back plate are connected together through a sealing frame, and a hydrophobic encapsulation layer is provided on the outer surface of the sealing frame.
与现有技术相比,本发明提供的光伏电池组件中,封框件的外表面设有疏水封装层,使得封框件具有良好的疏水能力;当光伏电池组件应用于湿度较高的环境时,空气中含有的水汽只会以水珠的形式凝结到疏水封装层的表面,而无法穿过封框件腐蚀太阳能电池芯片,这样就能够保证光伏电池组件的防水汽性能;另外,由于封框件的外表面设有疏水封装层,使得疏水封装层相当于封框件的保护层,以利用疏水封装层避免水氧对封框件的侵蚀,保证封框件的封框性能持久发挥;而且,本发明提供的光伏电池组件中,只是在封框件的外表面设有疏水封装层,就能够保证光伏电池组件的防水汽性能,因此,无需在背板相对太阳能电池芯片的表面形成防水密封结构,相对于现有技术,本发明提供的光伏电池组件的重量较轻,使得光伏电池组件的应用范围拓宽。Compared with the prior art, in the photovoltaic cell assembly provided by the present invention, the outer surface of the sealing frame is provided with a hydrophobic encapsulation layer, so that the sealing frame has good hydrophobicity; when the photovoltaic cell assembly is used in an environment with high humidity , the water vapor contained in the air will only condense on the surface of the hydrophobic encapsulation layer in the form of water droplets, and cannot pass through the sealing frame to corrode the solar cell chip, so that the waterproof performance of the photovoltaic cell module can be guaranteed; in addition, because the sealing frame The outer surface of the part is provided with a hydrophobic encapsulation layer, so that the hydrophobic encapsulation layer is equivalent to the protective layer of the frame sealing part, so as to avoid the erosion of water and oxygen on the frame sealing part by using the hydrophobic encapsulation layer, and ensure the lasting performance of the frame sealing performance of the frame sealing part; and , in the photovoltaic cell assembly provided by the present invention, only a hydrophobic encapsulation layer is provided on the outer surface of the sealing frame to ensure the water vapor performance of the photovoltaic cell assembly, therefore, there is no need to form a waterproof seal on the surface of the back plate opposite to the solar cell chip Compared with the prior art, the weight of the photovoltaic cell assembly provided by the present invention is lighter, so that the application range of the photovoltaic cell assembly is broadened.
本发明还提供了一种光伏电池组件的制作方法,该光伏电池组件的制作方法包括:The present invention also provides a method for manufacturing a photovoltaic cell assembly. The method for manufacturing the photovoltaic cell assembly includes:
提供太阳能电池芯片、背板和封框件;Provide solar cell chips, backplanes and sealing frames;
利用封框件将所述太阳能电池芯片和所述背板连接在一起,所述封框件的外表面设有疏水封装层。The solar cell chip and the back plate are connected together by a sealing frame, and a hydrophobic encapsulation layer is provided on the outer surface of the sealing frame.
与现有技术相比,本发明提供的光伏电池组件的制作方法的有益效果与上述技术方案提供的光伏电池组件的有益效果相同,在此不做赘述。Compared with the prior art, the beneficial effect of the manufacturing method of the photovoltaic cell assembly provided by the present invention is the same as that of the photovoltaic cell assembly provided by the above technical solution, and will not be repeated here.
附图说明Description of drawings
此处所说明的附图用来提供对本发明的进一步理解,构成本发明的一部分,本发明的示意性实施例及其说明用于解释本发明,并不构成对本发明的不当限定。在附图中:The accompanying drawings described here are used to provide a further understanding of the present invention, and constitute a part of the present invention. The schematic embodiments of the present invention and their descriptions are used to explain the present invention, and do not constitute improper limitations to the present invention. In the attached picture:
图1为本发明实施例提供的光伏电池组件的结构示意图;Fig. 1 is a schematic structural view of a photovoltaic cell assembly provided by an embodiment of the present invention;
图2为本发明实施例中太阳能电池芯片的结构示意图;FIG. 2 is a schematic structural view of a solar cell chip in an embodiment of the present invention;
图3为本发明实施例提供的光伏电池组件的制作方法流程图;Fig. 3 is the flow chart of the manufacturing method of the photovoltaic cell assembly provided by the embodiment of the present invention;
图4为本发明实施例中利用封框件将太阳能电池芯片和背板连接在一起的流程图。FIG. 4 is a flow chart of connecting solar cell chips and backplanes together by using a frame sealing member in an embodiment of the present invention.
附图标记:Reference signs:
1-太阳能电池芯片, 10-透明基板;1-solar cell chip, 10-transparent substrate;
11-太阳能电池单元, 111-第一电极层;11-solar battery unit, 111-first electrode layer;
112-第二电极层, 112a-AZO电极层;112-the second electrode layer, 112a-AZO electrode layer;
112b-Ag/NiCr/Al电极层, 113-电池功能层;112b-Ag/NiCr/Al electrode layer, 113-battery functional layer;
113a-第一PIN结构电池功能层, 113b-第二PIN结构电池功能层;113a-the first PIN structure battery functional layer, 113b-the second PIN structure battery functional layer;
2-背板, 3-封框件;2-back panel, 3-sealing frame;
4-疏水封装层, 40-侧面疏水部;4-hydrophobic encapsulation layer, 40-side hydrophobic part;
401-第一弯折部, 402-第二弯折部;401-the first bending part, 402-the second bending part;
41-第一疏水接触部, 42-第二疏水接触部;41-the first hydrophobic contact part, 42-the second hydrophobic contact part;
51-第一SGP胶膜, 52-第二SGP胶膜。51 - the first SGP adhesive film, 52 - the second SGP adhesive film.
具体实施方式Detailed ways
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The following will clearly and completely describe the technical solutions in the embodiments of the present invention with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only some, not all, embodiments of the present invention. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without creative efforts fall within the protection scope of the present invention.
针对现有技术中由于湿汽较重,水汽侵蚀进入光伏电池组件内部后会腐蚀光伏电池组件所包括的太阳能电池芯片,使得光伏电池组件内部的载流子浓度降低、电导率严重衰退,造成电池芯片性能参数中的开路电压Voc以及填充因子FF下降明显,最终导致发电量的降低。请参阅图1和图2,本发明实施例提供的光伏电池组件包括太阳能电池芯片1和背板2,太阳能电池芯片1和背板2通过封框件3连接在一起,封框件3的外表面设有疏水封装层4。In view of the heavy moisture in the prior art, the water vapor will corrode the solar cell chip included in the photovoltaic cell module after the water vapor enters the interior of the photovoltaic cell module, so that the carrier concentration inside the photovoltaic cell module is reduced, and the conductivity is seriously reduced, resulting in battery The open-circuit voltage Voc and fill factor FF in the chip performance parameters drop significantly, which eventually leads to a reduction in power generation. Referring to Fig. 1 and Fig. 2, the photovoltaic cell assembly provided by the embodiment of the present invention includes a solar cell chip 1 and a back plate 2, and the solar cell chip 1 and the back plate 2 are connected together through a sealing frame 3, and the outer surface of the sealing frame 3 A hydrophobic encapsulation layer 4 is provided on the surface.
下面结合图1~图3对本发明实施例提供的光伏电池组件的制作过程进行详细说明。The manufacturing process of the photovoltaic cell module provided by the embodiment of the present invention will be described in detail below with reference to FIGS. 1 to 3 .
第一步:提供太阳能电池芯片1、背板2和封框件3;Step 1: Provide solar cell chip 1, backplane 2 and sealing frame 3;
第二步:利用封框件3将太阳能电池芯片1和所述背板2连接在一起,封框件3的外表面设有疏水封装层4。Step 2: Connect the solar cell chip 1 and the back sheet 2 together by using the sealing frame 3 , and the outer surface of the sealing frame 3 is provided with a hydrophobic encapsulation layer 4 .
基于本发明实施例提供的光伏电池组件中,封框件3的外表面设有疏水封装层4,使得封框件3具有良好的疏水能力;当光伏电池组件应用于湿度较高的环境时,空气中含有的水汽只会以水珠的形式凝结到疏水封装层4的表面,而无法穿过封框件3腐蚀太阳能电池芯片1,例如:光伏电站长期运营时,光伏电池组件边缘凝结的水珠会被风干,即使连续阴雨天气,在光伏电站运营维护时,维护人员只需擦去每块组件边缘疏水膜上凝结的水珠即可,从而提高光伏组件使用寿命,这样就能够保证光伏电池组件的防水汽性能。In the photovoltaic cell assembly provided based on the embodiment of the present invention, the outer surface of the sealing frame 3 is provided with a hydrophobic encapsulation layer 4, so that the sealing frame 3 has good hydrophobicity; when the photovoltaic cell assembly is applied to an environment with high humidity, The water vapor contained in the air will only condense on the surface of the hydrophobic encapsulation layer 4 in the form of water droplets, but cannot pass through the sealing frame 3 to corrode the solar cell chip 1, for example: when the photovoltaic power station is in operation for a long time, the water condensed on the edge of the photovoltaic cell module The beads will be air-dried, even in continuous rainy weather, during the operation and maintenance of the photovoltaic power station, the maintenance personnel only need to wipe off the water droplets condensed on the hydrophobic film on the edge of each module, so as to improve the service life of the photovoltaic modules and ensure the photovoltaic cells Water vapor resistance of components.
另外,由于封框件3的外表面设有疏水封装层4,使得疏水封装层4相当于封框件3的保护层,以利用疏水封装层4避免水氧对封框件3的侵蚀,保证封框件3的封框性能持久发挥;而且,本发明实施例提供的光伏电池组件中,只是在封框件3的外表面设有疏水封装层4,就能够保证光伏电池组件的防水汽性能,因此,无需在背板2相对太阳能电池芯片1的表面形成防水密封结构,相对于现有技术,本发明实施例提供的光伏电池组件的重量较轻,使得光伏电池组件的应用范围拓宽。In addition, since the outer surface of the sealing frame 3 is provided with a hydrophobic encapsulating layer 4, the hydrophobic encapsulating layer 4 is equivalent to the protective layer of the sealing frame 3, so that the hydrophobic encapsulating layer 4 is used to avoid the corrosion of the sealing frame 3 by water and oxygen, ensuring The sealing performance of the sealing frame member 3 can be played for a long time; moreover, in the photovoltaic cell assembly provided by the embodiment of the present invention, only the outer surface of the sealing frame member 3 is provided with a hydrophobic encapsulation layer 4, which can ensure the waterproof performance of the photovoltaic cell assembly Therefore, there is no need to form a waterproof sealing structure on the surface of the back plate 2 opposite to the solar cell chip 1. Compared with the prior art, the photovoltaic cell assembly provided by the embodiment of the present invention is lighter, so that the application range of the photovoltaic cell assembly is broadened.
需要说明的是,本发明实施例中背板2可以透明,也可以不透明,当背板2为透明背板时,能够增加太阳能电池芯片1的载流子吸收量,从而增加其发电量。It should be noted that the backsheet 2 in the embodiment of the present invention can be transparent or opaque, and when the backsheet 2 is transparent, the carrier absorption of the solar cell chip 1 can be increased, thereby increasing its power generation.
考虑到现有技术中封框件3接触外界的侧面最容易接触到水汽,基于此,如图1和图2所示,本发明实施例中疏水封装层4至少包括侧面疏水部40,侧面疏水部40设在封框件3远离太阳能电池芯片1的一侧(即侧面疏水部40的外立面),以对封框件3的外立面进行防水防氧保护,以减少水汽对于封框件3的腐蚀。Considering that in the prior art, the side of the sealing frame 3 exposed to the outside world is most likely to be exposed to water vapor, based on this, as shown in Figure 1 and Figure 2, the hydrophobic encapsulation layer 4 in the embodiment of the present invention includes at least a side hydrophobic part 40, and the side hydrophobic The portion 40 is arranged on the side of the frame sealing member 3 away from the solar cell chip 1 (i.e., the outer surface of the side hydrophobic portion 40), so as to protect the outer surface of the sealing frame member 3 from water and oxygen, so as to reduce the influence of water vapor on the sealing frame. Corrosion of piece 3.
具体的,如图1和图2所示,本发明实施例中疏水封装层4还包括第一疏水接触部41和/或第二疏水接触部42;第一疏水接触部41位于太阳能电池芯片1相对背板2的表面和封框件3之间,第二疏水接触部42位于背板2与封框件3之间,这相当于在太阳能电池芯片1相对背板2的表面和封框件3之间的缝隙内增设了第一疏水接触部41,以利用第一疏水接触部41位防止水汽进入太阳能电池芯片1相对背板2的表面和封框件3之间的缝隙,从而进一步增加疏水封装层4的防水汽能力和对封框件3的保护作用;同理,第二疏水接触部42可防止水汽进入背板2与封框件3之间的缝隙,从而进一步增加疏水封装层4的防水汽能力和对封框件3的保护作用。Specifically, as shown in Figures 1 and 2, the hydrophobic encapsulation layer 4 in the embodiment of the present invention also includes a first hydrophobic contact part 41 and/or a second hydrophobic contact part 42; the first hydrophobic contact part 41 is located on the solar cell chip 1 Between the surface opposite to the back plate 2 and the sealing frame member 3, the second hydrophobic contact portion 42 is located between the back plate 2 and the sealing frame member 3, which is equivalent to the surface of the solar cell chip 1 opposite to the back plate 2 and the sealing frame member The first hydrophobic contact part 41 is added in the gap between 3 to prevent water vapor from entering the gap between the surface of the solar cell chip 1 opposite to the back plate 2 and the sealing frame 3 by using the first hydrophobic contact part 41, thereby further increasing The waterproof ability of the hydrophobic encapsulation layer 4 and the protective effect on the sealing frame 3; similarly, the second hydrophobic contact part 42 can prevent water vapor from entering the gap between the backplane 2 and the sealing frame 3, thereby further increasing the hydrophobic encapsulation layer 4's waterproof ability and the protective effect on the sealing frame 3.
为了方便制作,如图1和图2所示,本发明实施例中侧面疏水部40与第一疏水接触部41和/或第二疏水接触部42连接,并以一体式结构为最佳连接方式。而考虑到侧面疏水部40设在所述封框件3靠近外界的侧面,第一疏水接触部41位于太阳能电池芯片1相对背板2的表面和封框件3之间,第二疏水接触部42位于背板2与封框件3之间,使得第一疏水接触部41、第二疏水接触部42和侧面疏水部40为一体式结构时,第一疏水接触部41与侧面疏水部40之间需要有弯折部连接,第二疏水接触部42与侧面疏水部40需要有弯折部连接。基于此,第一疏水接触部41与侧面疏水部40通过第一弯折部401连接,相对疏水封装层4的其他部分,第一弯折部401所受到的应力比较大,第二疏水接触部42与侧面疏水部40之间通过第二弯折部402连接,相对疏水封装层4的其他部分,第二弯折部402所述受到的应力比较大;基于此,第一弯折部401的抗折弯性能至少大于第一疏水接触部41的抗折弯性能、第二疏水接触部42的抗折弯性能和侧面疏水部40的抗折弯性能,第二弯折部402的抗折弯性能至少大于第一疏水接触部41的抗折弯性能、第二疏水接触部42的抗折弯性能和侧面疏水部40的抗折弯性能。具体的,第一弯折部401和第二弯折部402为经过等离子轰击处理的弯折部,经过等离子轰击处理的弯折部结构强度增大,因此,当第一疏水接触部41、第二疏水接触部42和侧面疏水部40为一体式结构时,只需要在最后对第一弯折部401和第二弯折部402进行等离子轰击处理,以提高第一弯折部401和第二弯折部402的强度,防止因为长时间遭受过大应力所导致的第一弯折部401和第二弯折部402断裂的问题,从而增加疏水封装层4的使用寿命。For the convenience of manufacture, as shown in Figure 1 and Figure 2, in the embodiment of the present invention, the side hydrophobic part 40 is connected with the first hydrophobic contact part 41 and/or the second hydrophobic contact part 42, and an integral structure is the best connection method . Considering that the side hydrophobic portion 40 is arranged on the side of the sealing frame member 3 close to the outside world, the first hydrophobic contact portion 41 is located between the surface of the solar cell chip 1 opposite to the back plate 2 and the sealing frame member 3, and the second hydrophobic contact portion 42 is located between the back plate 2 and the sealing frame 3, so that when the first hydrophobic contact part 41, the second hydrophobic contact part 42 and the side hydrophobic part 40 are integrated, the first hydrophobic contact part 41 and the side hydrophobic part 40 The second hydrophobic contact portion 42 and the side hydrophobic portion 40 need to be connected by a bending portion. Based on this, the first hydrophobic contact part 41 is connected to the side hydrophobic part 40 through the first bent part 401. Compared with other parts of the hydrophobic encapsulation layer 4, the stress on the first bent part 401 is relatively large, and the second hydrophobic contact part 42 and the side hydrophobic part 40 are connected by the second bending part 402, compared with other parts of the hydrophobic encapsulation layer 4, the stress received by the second bending part 402 is relatively large; based on this, the first bending part 401 The bending resistance is at least greater than the bending resistance of the first hydrophobic contact portion 41, the bending resistance of the second hydrophobic contact portion 42 and the bending resistance of the side hydrophobic portion 40, and the bending resistance of the second bending portion 402 The performance is at least greater than the bending resistance of the first hydrophobic contact portion 41 , the bending resistance of the second hydrophobic contact portion 42 and the bending resistance of the side hydrophobic portion 40 . Specifically, the first bent part 401 and the second bent part 402 are bent parts treated by plasma bombardment, and the structural strength of the bent part after plasma bombardment treatment increases. Therefore, when the first hydrophobic contact part 41, the second When the two hydrophobic contact parts 42 and the side hydrophobic part 40 are of an integrated structure, only the first bending part 401 and the second bending part 402 need to be subjected to plasma bombardment treatment at the end to improve the first bending part 401 and the second bending part 401. The strength of the bent portion 402 prevents the first bent portion 401 and the second bent portion 402 from breaking due to excessive stress for a long time, thereby increasing the service life of the hydrophobic encapsulation layer 4 .
可以理解的是,本发明实施例中疏水封装层4为接触角大于90°的疏水封装层4。进一步,疏水封装层4为接触角是120°~160°的疏水封装层,此时疏水封装层4能够较好的发挥其疏水能力,使得靠近疏水封装层4空气所含有的水汽能够最大化的凝结在疏水封装层4表面。It can be understood that the hydrophobic encapsulation layer 4 in the embodiment of the present invention is a hydrophobic encapsulation layer 4 with a contact angle greater than 90°. Further, the hydrophobic encapsulation layer 4 is a hydrophobic encapsulation layer with a contact angle of 120° to 160°. At this time, the hydrophobic encapsulation layer 4 can better exert its hydrophobic ability, so that the water vapor contained in the air close to the hydrophobic encapsulation layer 4 can be maximized. condensation on the surface of the hydrophobic encapsulation layer 4.
可选的,本发明实施例中疏水封装层4可以为有机疏水薄膜,也可以为无机疏水薄膜。其中,有机疏水薄膜为聚酰胺疏水薄膜、PMMA-SiO2复合疏水薄膜或聚四氟乙烯薄膜,但不仅限于此;无机疏水薄膜为二氧化硅薄膜、三氧化二铝薄膜或绝缘陶瓷膜,但不仅限于此。Optionally, the hydrophobic encapsulation layer 4 in the embodiment of the present invention may be an organic hydrophobic film or an inorganic hydrophobic film. Wherein, the organic hydrophobic film is a polyamide hydrophobic film, PMMA- SiO Composite hydrophobic film or polytetrafluoroethylene film, but not limited to this; the inorganic hydrophobic film is a silicon dioxide film, aluminum oxide film or insulating ceramic film, but It doesn't stop there.
例如:PMMA-SiO2复合疏水薄膜是用亲水性的工程塑料聚甲基丙烯酸甲酯(PMMA)和环氧树脂作为基体,通过引入疏水性SiO2纳米颗粒,制备PMMA-SiO2复合超疏水薄膜,该PMMA-SiO2复合超疏水薄膜表面与水接触角甚至超过150°,具备很强的疏水性能。For example: PMMA-SiO 2 composite hydrophobic film uses hydrophilic engineering plastics polymethyl methacrylate (PMMA) and epoxy resin as the matrix, and prepares PMMA-SiO 2 composite superhydrophobic film by introducing hydrophobic SiO 2 nanoparticles. film, the surface of the PMMA-SiO 2 composite superhydrophobic film has a contact angle with water even exceeding 150°, and has strong hydrophobic properties.
考虑到操作便利性,本发明实施例中封框件3为热熔性封框层,疏水封装层4为有机疏水薄膜,这种情况下,由于热熔性封框层和有机疏水薄膜均能够在加热条件下融化,冷却后凝固,基于这一特征,可先在太阳能电池芯片1相对背板2的表面形成作为疏水封装层4的疏水基材,然后在疏水基材背离太阳能电池芯片1的表面形成封框件3,接着将封框件3包裹,并将背板2与太阳能电池芯片1形成封框件3的表面相对,最后反复热层压太阳能电池芯片1和背板2,使得背板2与太阳能电池芯片1紧密结合在一起。Considering the convenience of operation, the sealing frame member 3 in the embodiment of the present invention is a hot-melt sealing layer, and the hydrophobic sealing layer 4 is an organic hydrophobic film. In this case, since both the hot-melt sealing layer and the organic hydrophobic film can It melts under heating conditions and solidifies after cooling. Based on this feature, a hydrophobic substrate as a hydrophobic encapsulation layer 4 can be formed on the surface of the solar cell chip 1 opposite to the back plate 2, and then the hydrophobic substrate is away from the solar cell chip 1. The surface of the sealing frame 3 is formed, and then the sealing frame 3 is wrapped, and the back sheet 2 is opposite to the surface of the solar cell chip 1 forming the sealing frame 3, and finally the solar cell chip 1 and the back sheet 2 are thermally laminated repeatedly, so that the back sheet The plate 2 and the solar cell chip 1 are closely combined.
需要说明的是,本发明实施例中的封框件3可以为丁基胶,或其他可实现封框的胶体或树脂,在此不在一一列举。It should be noted that the frame sealing member 3 in the embodiment of the present invention may be butyl rubber, or other glues or resins capable of sealing the frame, which will not be listed here.
可选的,如图1和图2所示,本发明实施例中太阳能电池芯片1分为边框区域和感光区域,该太阳能电池芯片1包括透光基板,透光基板对应感光区域的表面设有太阳能电池单元11,封框件3设在透明基板10对应边框区域的部分。Optionally, as shown in Figure 1 and Figure 2, the solar cell chip 1 in the embodiment of the present invention is divided into a frame area and a photosensitive area, the solar cell chip 1 includes a light-transmitting substrate, and the surface of the light-transmitting substrate corresponding to the photosensitive area is provided with For the solar battery unit 11 , the sealing frame member 3 is disposed on the part of the transparent substrate 10 corresponding to the frame area.
进一步,如图1和图2所示,本发明实施例中太阳能电池单元11包括依次叠置在透光基板的第一电极层111、电池功能层113和第二电极层112,第一电极层111与透光基板的感光区域表面相对,第二电极层112背离电池功能层113的表面与背板2相对。Further, as shown in Fig. 1 and Fig. 2, the solar battery unit 11 in the embodiment of the present invention includes a first electrode layer 111, a battery function layer 113 and a second electrode layer 112 stacked on the light-transmitting substrate in sequence, the first electrode layer 111 is opposite to the surface of the photosensitive area of the transparent substrate, and the surface of the second electrode layer 112 facing away from the battery functional layer 113 is opposite to the back plate 2 .
具体制作太阳能电池芯片1时,采用成膜工艺在透明基板10的表面形成层叠的第一电极层111、电池功能层113和第二电极层112,成膜工艺为化学气相沉积工艺或磁控溅射工艺等;然后采用激光(波长1064nm)将透明基板10边缘的部分膜层清除,这样就使得所制作的太阳能电池芯片1分为边框区域和感光区域,边框区域的膜层被激光去除,而感光区域的膜层保留,将感光区域所保留的膜层称为太阳能电池单元11,且边框区域为电绝缘区域,其宽度为7mm-10mm,此处电绝缘区域的宽度是指:从太阳能电池单元11的侧边到透明基板10的侧边的最短距离d。When specifically making the solar cell chip 1, a film-forming process is used to form a laminated first electrode layer 111, a battery function layer 113, and a second electrode layer 112 on the surface of the transparent substrate 10. The film-forming process is a chemical vapor deposition process or magnetron sputtering. Then use laser (wavelength 1064nm) to remove part of the film layer on the edge of the transparent substrate 10, so that the manufactured solar cell chip 1 is divided into a frame area and a photosensitive area, and the film layer in the frame area is removed by the laser, and The film layer in the photosensitive area is retained, and the film layer retained in the photosensitive area is called a solar cell unit 11, and the frame area is an electrically insulating area with a width of 7mm-10mm, where the width of the electrically insulating area refers to: from the solar cell The shortest distance d from the side of the unit 11 to the side of the transparent substrate 10 .
示例性的,如图2所示,第一电极层111为TCO电极层,第二电极层112为叠置在一起的AZO电极层112A和Ag/NiCr/Al电极层112b,AZO电极层112A位于Ag/NiCr/Al电极层112b和电池功能层113之间,电池功能层113为双层的PIN结构电池功能层,具体包括第一PIN结构电池功能层113a和第二PIN结构电池功能层113b,且第一PIN结构电池功能层113a位于第一电极层111和第二PIN结构电池功能层113b之间。Exemplarily, as shown in FIG. 2, the first electrode layer 111 is a TCO electrode layer, the second electrode layer 112 is an AZO electrode layer 112A and an Ag/NiCr/Al electrode layer 112b stacked together, and the AZO electrode layer 112A is located Between the Ag/NiCr/Al electrode layer 112b and the battery function layer 113, the battery function layer 113 is a double-layer PIN structure battery function layer, specifically including a first PIN structure battery function layer 113a and a second PIN structure battery function layer 113b, And the first PIN structure battery function layer 113a is located between the first electrode layer 111 and the second PIN structure battery function layer 113b.
针对现有技术中EVA胶膜或PVB胶膜的缺陷,本发明实施例中将原有的EVA胶膜或PVB胶膜替换为SGP胶膜,以增加粘结性能。具体的,如图1和图2所示,本发明实施例中背板2相对太阳能电池单元11的表面形成有用于粘合背板2与太阳能电池单元11的第一SGP胶膜51,封框件3还与第一SGP胶膜51的侧边接触;和/或,透光基板与太阳能电池单元11之间形成有用于粘合所述透光基板与太阳能电池单元11的第二SGP胶膜52,封框件3还与所述第二SGP胶膜52的侧边接触。由于SGP胶膜的吸湿性比较小,且具有较好的胶黏性能,因此,本发明实施例提供的光伏发电组件中,虽然在背板2与太阳能电池单元11之间通过第一SGP胶膜51粘合,和/或在透光基板与太阳能电池单元11之间通过第二SGP胶膜52粘合,但通过测试发现,采用第一SGP胶膜51和/或第二SGP胶膜52能够减轻所使用的背板2和/或透明基板10的厚度,使得光伏发电组件的重量降低。In view of the defects of the EVA adhesive film or PVB adhesive film in the prior art, the original EVA adhesive film or PVB adhesive film is replaced by the SGP adhesive film in the embodiment of the present invention to increase the bonding performance. Specifically, as shown in Fig. 1 and Fig. 2, in the embodiment of the present invention, the surface of the back sheet 2 opposite to the solar cell unit 11 is formed with a first SGP adhesive film 51 for bonding the back sheet 2 and the solar cell unit 11, sealing the frame Part 3 is also in contact with the side of the first SGP adhesive film 51; and/or, a second SGP adhesive film for bonding the transparent substrate and solar cell unit 11 is formed between the transparent substrate and the solar cell unit 11 52 , the sealing frame component 3 is also in contact with the side of the second SGP adhesive film 52 . Since the hygroscopicity of the SGP adhesive film is relatively small and has good adhesive properties, therefore, in the photovoltaic power generation module provided by the embodiment of the present invention, although the first SGP adhesive film is passed between the back plate 2 and the solar cell unit 11 51 bonding, and/or between the light-transmitting substrate and the solar cell unit 11 through the second SGP adhesive film 52, but it is found through testing that the first SGP adhesive film 51 and/or the second SGP adhesive film 52 can Reducing the thickness of the back plate 2 and/or the transparent substrate 10 used reduces the weight of the photovoltaic power generation assembly.
具体的,当背板2为普通玻璃或钢化玻璃,图1和图2示出的结构中,通过应用SGP胶膜,使得3.2mm的背板2和透明基板10的厚度减小至2.5mm,4mm的背板2和透明基板10的厚度减小至2mm。同时,采用本发明实施例提供的光伏电池组件制作的光伏大棚用的BIPV(光伏建筑一体化,英文全称为Building Integrated PV,缩写为BIPV)组件的重量从14.4kg降低到9kg,从而降低了光伏大棚建筑的承重要求。Specifically, when the backplane 2 is ordinary glass or tempered glass, in the structures shown in Figures 1 and 2, the thickness of the 3.2mm backplane 2 and the transparent substrate 10 is reduced to 2.5mm by applying the SGP adhesive film, The thickness of the back plate 2 and the transparent substrate 10 of 4 mm is reduced to 2 mm. Simultaneously, the weight of the BIPV (Building Integrated Photovoltaic, English full name Building Integrated PV, abbreviated as BIPV) assembly for photovoltaic greenhouses made of the photovoltaic cell assembly provided by the embodiment of the present invention is reduced from 14.4kg to 9kg, thereby reducing the photovoltaic power consumption. Load-bearing requirements of greenhouse buildings.
可见,经试验表明背板2和/或透光基板均为透光玻璃时,本发明实施例中透光玻璃的厚度均小于3mm,能够极大的降低光伏电池组件的重量。It can be seen that the test shows that when the back plate 2 and/or the light-transmitting substrate are all light-transmitting glass, the thickness of the light-transmitting glass in the embodiment of the present invention is less than 3 mm, which can greatly reduce the weight of the photovoltaic cell module.
如图1~图3所示,本发明实施例提供了一种光伏电池组件的制作方法,该光伏电池组件的制作方法包括:As shown in Figures 1 to 3, an embodiment of the present invention provides a method for manufacturing a photovoltaic cell assembly, the method for manufacturing a photovoltaic cell assembly includes:
步骤S100:第一步:提供太阳能电池芯片1、背板2和封框件3;Step S100: the first step: providing solar cell chips 1, backplane 2 and sealing frame 3;
步骤S300:利用封框件3将太阳能电池芯片1和背板2连接在一起,封框件3的外表面设有疏水封装层4。Step S300 : Connect the solar cell chip 1 and the backsheet 2 together by using the sealing frame 3 , and the outer surface of the sealing frame 3 is provided with a hydrophobic encapsulation layer 4 .
与现有技术相比,本发明实施例提供的光伏电池组件的制作方法的有益效果与上述实施例提供的光伏电池组件的有益效果相同,在此不做赘述。Compared with the prior art, the beneficial effect of the manufacturing method of the photovoltaic cell assembly provided by the embodiment of the present invention is the same as the beneficial effect of the photovoltaic cell assembly provided by the above embodiment, and will not be repeated here.
作为一种可实现的实施例,如图1、图2和图4所示,本发明实施例中利用封框件3将太阳能电池芯片1和背板2连接在一起包括:As a realizable embodiment, as shown in Fig. 1, Fig. 2 and Fig. 4, using the sealing frame 3 to connect the solar cell chip 1 and the back plate 2 together in the embodiment of the present invention includes:
步骤S310:在太阳能电池芯片1的表面形成第一疏水接触部41,第一疏水接触部41通过侧面疏水部40与第二疏水接触部42连接;Step S310: forming a first hydrophobic contact portion 41 on the surface of the solar cell chip 1, the first hydrophobic contact portion 41 is connected to the second hydrophobic contact portion 42 through the side hydrophobic portion 40;
步骤S320:在第一疏水接触部41背离太阳能电池芯片1的表面形成封框件3;Step S320: forming the sealing frame 3 on the surface of the first hydrophobic contact portion 41 facing away from the solar cell chip 1;
步骤S330:将侧面疏水部40与封框件3的侧面连接,将第二疏水接触部42与封框件3背离第一疏水接触部41的表面连接。具体操作时,采用折弯的方式将侧面疏水部40与封框件3的侧面接触(以实现连接),将第二疏水接触部42翻转至与封框件3背离第一疏水接触部41的表面,以使得第二疏水接触部42与封框件3背离第一疏水接触部41的表面接触(以实现连接)。Step S330 : Connect the side hydrophobic portion 40 to the side surface of the sealing frame member 3 , and connect the second hydrophobic contact portion 42 to the surface of the sealing frame member 3 away from the first hydrophobic contact portion 41 . During the specific operation, the side hydrophobic part 40 is brought into contact with the side surface of the sealing frame part 3 (to realize the connection) by bending, and the second hydrophobic contact part 42 is turned over to the position away from the first hydrophobic contact part 41 of the sealing frame part 3. surface, so that the second hydrophobic contact portion 42 is in contact with the surface of the sealing frame member 3 away from the first hydrophobic contact portion 41 (to realize connection).
步骤S340:将太阳能电池芯片1形成第一疏水接触部41的表面与背板2相对;Step S340: facing the surface of the solar cell chip 1 on which the first hydrophobic contact portion 41 is formed and the back plate 2;
步骤S350:反复热层压所述太阳能电池芯片1和背板2,使得封框件3将太阳能电池芯片1和背板2连接在一起;封框件3连接侧面疏水部40的侧面位于封框件3远离太阳能电池芯片1的一侧。Step S350: heat-laminate the solar cell chip 1 and the back sheet 2 repeatedly, so that the frame sealing member 3 connects the solar cell chip 1 and the back sheet 2 together; The part 3 is away from the side of the solar cell chip 1 .
进一步,如图1~图3所示,在太阳能电池芯片1的表面形成第一疏水接触部41前,利用封框件3将太阳能电池芯片1和背板2连接在一起还包括:Further, as shown in FIGS. 1 to 3 , before forming the first hydrophobic contact portion 41 on the surface of the solar cell chip 1, connecting the solar cell chip 1 and the back plate 2 together by using the sealing frame member 3 further includes:
步骤S200:将太阳能电池芯片1划分为感光区域以及设在感光区域周向的非感光区域;去除太阳能电池芯片1的非感光区域所包含的功能膜层,使得太阳能电池芯片1的非感光区域形成绝缘的边框区域;Step S200: Divide the solar cell chip 1 into a photosensitive area and a non-photosensitive area arranged around the photosensitive area; remove the functional film layer contained in the non-photosensitive area of the solar cell chip 1, so that the non-photosensitive area of the solar cell chip 1 is formed Insulated border area;
步骤S310具体包括:在太阳能电池芯片1的表面形成第一疏水接触部41包括:在边框区域形成第一疏水接触部41。Step S310 specifically includes: forming the first hydrophobic contact portion 41 on the surface of the solar cell chip 1 includes: forming the first hydrophobic contact portion 41 in the frame region.
如图1、图2和图4所示,如果第一疏水接触部41与侧面疏水部40通过第一弯折部401连接,第二疏水接触部42与侧面疏水部40之间通过第二弯折部402连接;上述利用封框件3将太阳能电池芯片1和背板2连接在一起后,本发明实施例提供的光伏电池组件的制作方法还包括:As shown in Figure 1, Figure 2 and Figure 4, if the first hydrophobic contact part 41 and the side hydrophobic part 40 are connected through the first bending part 401, the second hydrophobic contact part 42 and the side hydrophobic part 40 are connected through the second bend The folding part 402 is connected; after the solar cell chip 1 and the back plate 2 are connected together by the above-mentioned sealing frame member 3, the method for manufacturing the photovoltaic cell module provided by the embodiment of the present invention further includes:
步骤S400:采用等离子轰击工艺分别对第一弯折部401和第二弯折部402进行处理,使得第一弯折部401的抗折弯性能至少大于第一疏水接触部41的抗折弯性能、第二疏水接触部42的抗折弯性能和侧面疏水部40的抗折弯性能,第二弯折部402的抗折弯性能至少大于第一疏水接触部41的抗折弯性能、第二疏水接触部42的抗折弯性能和侧面疏水部的抗折弯性能。Step S400: Using a plasma bombardment process to treat the first bent part 401 and the second bent part 402 respectively, so that the bending resistance of the first bent part 401 is at least greater than that of the first hydrophobic contact part 41 , the bending resistance of the second hydrophobic contact portion 42 and the bending resistance of the side hydrophobic portion 40, the bending resistance of the second bending portion 402 is at least greater than the bending resistance of the first hydrophobic contact portion 41, the second The bending resistance of the hydrophobic contact portion 42 and the bending resistance of the side hydrophobic portion.
在上述实施方式的描述中,具体特征、结构、材料或者特点可以在任何的一个或多个实施例或示例中以合适的方式结合。In the description of the above embodiments, specific features, structures, materials or characteristics may be combined in any one or more embodiments or examples in an appropriate manner.
以上所述,仅为本发明的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,可轻易想到变化或替换,都应涵盖在本发明的保护范围之内。因此,本发明的保护范围应以所述权利要求的保护范围为准。The above is only a specific embodiment of the present invention, but the scope of protection of the present invention is not limited thereto. Anyone skilled in the art can easily think of changes or substitutions within the technical scope disclosed in the present invention. Should be covered within the protection scope of the present invention. Therefore, the protection scope of the present invention should be determined by the protection scope of the claims.
Claims (16)
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