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CN108373888A - A kind of supporter protective film and its production method - Google Patents

A kind of supporter protective film and its production method Download PDF

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Publication number
CN108373888A
CN108373888A CN201611058832.4A CN201611058832A CN108373888A CN 108373888 A CN108373888 A CN 108373888A CN 201611058832 A CN201611058832 A CN 201611058832A CN 108373888 A CN108373888 A CN 108373888A
Authority
CN
China
Prior art keywords
sensitive adhesive
pressure
adhesive layer
protective film
base material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611058832.4A
Other languages
Chinese (zh)
Inventor
孙攀
王玺
王健
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Jingshen New Material Co ltd
Original Assignee
SHANGHAI PLUSCO TECH Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHANGHAI PLUSCO TECH Co Ltd filed Critical SHANGHAI PLUSCO TECH Co Ltd
Priority to CN201611058832.4A priority Critical patent/CN108373888A/en
Publication of CN108373888A publication Critical patent/CN108373888A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/326Applications of adhesives in processes or use of adhesives in the form of films or foils for bonding electronic components such as wafers, chips or semiconductors
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Adhesive Tapes (AREA)

Abstract

The invention discloses a kind of supporter protective film and its production method, which is made of base material, pressure-sensitive adhesive layer and release film, and base material single side passes through sided corona treatment; and fitted by pressure-sensitive adhesive layer with release film, pressure sensitive adhesive includes acrylic resin, lytic agent; curing agent and photoinitiator.The supporter protective film of the present invention has the peeling force of superelevation under normal conditions, and after the irradiation of sufficient UV light, then it can be reduced to ultralow peeling force.

Description

A kind of supporter protective film and its production method
Technical field
The present invention relates to protective film field, more particularly to a kind of supporter protective film and its production method.
Background technology
The chips such as semiconductor, optical glass need to use supporter protective film in process, to ensure that chip is being ground Mill does not fall off in cutting process, does not disperse, and protecting undressed part, this just needs supporter protective film to have the viscous force of superelevation, It will not fall off in process.And after chip process, which can also should easily be torn, To make chip can be in lower one of production process normal use.And there is not the supporter protective film for having above-mentioned function at present.
Invention content
In view of the deficiencies of the prior art, the present invention provides a kind of supporter protective film and its production methods.Institute of the present invention The supporter protective film of offer, including:Base material, pressure-sensitive adhesive layer and release film, wherein the base material single side passes through sided corona treatment, Coated on one side of the base material Jing Guo sided corona treatment has pressure-sensitive adhesive layer, and release film is covered on the pressure-sensitive adhesive layer, described pressure-sensitive The pressure sensitive adhesive of glue-line is acrylic system class pressure sensitive adhesive, including the acrylic resin that weight percent is 30-60%, weight percent Than the lytic agent for 30-60%, the curing agent that weight percent is 0.4-3% and the light that weight percent is 0.4%-3% draw Send out agent.
It is further preferred that the base material is PET or PO films, thickness is 25-200 μm.
It is further preferred that the coating layer thickness of the pressure-sensitive adhesive layer is 5-35 μm.
It is further preferred that the release film is the PET with release performance, thickness is 25-75 μm.
It is further preferred that the acrylic resin can be polymethyl methacrylate, polyethyl methacrylate, poly- first One or more of mixtures of base butyl acrylate.
A kind of production method of supporter protective film provided by the present invention, includes the following steps:
(a) base material single side is subjected to sided corona treatment;
(b) one layer of pressure sensitive adhesive of the coated on one side in base material Jing Guo sided corona treatment, forms pressure-sensitive adhesive layer, and the pressure sensitive adhesive is third Olefin(e) acid system class pressure sensitive adhesive, including weight percent are the acrylic resin of 30-60%, and weight percent is the molten of 30-60% Solve agent, the curing agent that weight percent is 0.4-3% and the photoinitiator that weight percent is 0.4%-3%;
(c) supporter protective film finished product is made, is used in combination non-in the pressure-sensitive adhesive layer overlying last layer release film after drying Transparent material is kept in dark place.
It is further preferred that in step (a), the base material is PET or PO films, and thickness is 25-200 μm.
It is further preferred that in step (b), the coating layer thickness of the pressure-sensitive adhesive layer is 5-35 μm.
It is further preferred that in step (c), the release film is the PET with release performance, and thickness is 25-75 μm.
It is further preferred that in step (b) and step (c), by uniformly mixed 45-100 μm of spreader of pressure sensitive adhesive In one side coated on PET base material 1 Jing Guo sided corona treatment, pressure-sensitive adhesive layer is formed, is then dried in dryer in 110 DEG C 1min, it is after going out baking oven, the layer upper surface of release film is laminating in pressure-sensitive adhesive layer, supporter protective film finished product is made.
The beneficial effects of the invention are as follows:
Supporter protective film provided by the present invention is UV visbreaking protective films, by PET base material, pressure-sensitive adhesive layer, release The selection of parameter setting and the pressure sensitive adhesive proportioning of film so that the supporter protective film under normal conditions, i.e., is irradiated in no UV In the case of, the viscous force with superelevation, it is ensured that chip does not fall off in grinding, cutting process, do not disperse, and protects undressed Part.As long as and irradiating enough UV light after completion of processing, you can the viscous force for lowering supporter protective film, so as to quilt It tears easily, makes chip in lower one of production process normal use.
Description of the drawings
Fig. 1 is the schematic diagram of supporter protective film provided by the present invention;
Fig. 2 is the flow chart of supporter protection film production method provided by the present invention.
Specific implementation mode
Invention is further described in detail below.
As shown in Figure 1, supporter protective film provided by the present invention includes:Base material 1, pressure-sensitive adhesive layer 2 and release film 3, In, 1 single side of the base material passes through sided corona treatment, and coated on one side of the base material 1 Jing Guo sided corona treatment has pressure-sensitive adhesive layer 2, described Release film 3 is covered on pressure-sensitive adhesive layer 2.
The base material 1 is the films such as PET (polyethylene terephthalate) or PO (polyolefin), and thickness is 25-200 μm. The pressure sensitive adhesive of the pressure-sensitive adhesive layer 2 is acrylic system class pressure sensitive adhesive, including the acrylic acid tree that weight percent is 30-60% Fat, weight percent are the lytic agent of 30-60%, and weight percent is the curing agent of 0.4-3% and weight percent is The photoinitiator of 0.4%-3%.The coating layer thickness of the pressure-sensitive adhesive layer 2 is 5-35 μm.The release film 3 is with release performance PET, thickness be 25-75 μm.
As shown in Fig. 2, the production method of supporter protective film provided by the present invention, includes the following steps:
(a) 1 single side of base material is subjected to sided corona treatment;
(b) one layer of pressure sensitive adhesive of the coated on one side in base material 1 Jing Guo sided corona treatment, forms pressure-sensitive adhesive layer 2, and the pressure sensitive adhesive is Acrylic system class pressure sensitive adhesive, including weight percent are the acrylic resin of 30-60%, and weight percent is 30-60%'s Lytic agent, the curing agent that weight percent is 0.4-3% and the photoinitiator that weight percent is 0.4%-3%;
(c) supporter protective film is made in 2 overlying last layer release film 3 of the pressure-sensitive adhesive layer after drying machine drying Finished product is used in combination non-transparent material to be kept in dark place.
Further, in step (a), the base material 1 is the films such as PET or PO, and thickness is 25-200 μm.
In step (b), 2 coating layer thickness of the pressure-sensitive adhesive layer is 5-35 μm.
In step (c), the release film 3 is the PET with release performance, and thickness is 25-75 μm.
In step (c), the non-transparent material is tinfoil.
Further, in step (b) and step (c), uniformly mixed 45 μm of -100 μm of spreaders of pressure sensitive adhesive are applied It is overlying in one side of the PET base material 1 Jing Guo sided corona treatment, forms pressure-sensitive adhesive layer 2, then dry 1min in dryer in 110 DEG C, It is after going out baking oven, the layer upper surface of release film 3 is laminating in pressure-sensitive adhesive layer 2, supporter protective film finished product is made.
The acrylic resin can be polymethyl methacrylate, polyethyl methacrylate, polybutyl methacrylate One or more of mixtures.
The lytic agent is the one or several kinds of ethyl acetate, butyl acetate, toluene, acetone, butanone.
The curing agent is fatty kind isocyanate or fragrant kind isocyanate one or more of which mixture.
The photoinitiator is alpha-hydroxyalkyl benzophenone, dialkylacetophenones, benzoin and derivative, benzil derivatives One or more of mixtures.
Example one
20g acrylic resins are added in 20g ethyl acetate and are diluted, sequentially add 2g curing agent, 2g photoinitiators, fully It stirs and is uniformly mixed to obtain pressure sensitive adhesive;Said mixture is passed through coated on 50 μm of PET film base materials 1 with 45 μm of bar spreaders It crosses in the one side of sided corona treatment, forms pressure-sensitive adhesive layer 2, then dry 1min in dryer in 110 DEG C, it, will be from after going out baking oven The layer upper surface of type film 3 is laminating to be made supporter protective film finished product in pressure-sensitive adhesive layer 2, is used in combination tinfoil cladding to be kept in dark place spare.
Example two
20g acrylic resins are added in 20g ethyl acetate and are diluted, sequentially add 2g curing agent, 2g photoinitiators, fully It stirs and is uniformly mixed to obtain pressure sensitive adhesive;Said mixture is passed through coated on 100 μm of P0 film substrates 1 with 100 μm of dimple rollers In the one side of sided corona treatment, pressure-sensitive adhesive layer 2 is formed, then dries 1min in dryer in 110 DEG C, it, will be release after going out baking oven The layer upper surface of film 3 is laminating to be made supporter protective film finished product in pressure-sensitive adhesive layer 2, is used in combination tinfoil cladding to be kept in dark place spare.
Example three
30g acrylic resins are added in 40g ethyl acetate and are diluted, 3.5g curing agent, 3.5g photoinitiators are sequentially added, It is sufficiently stirred and is uniformly mixed to obtain pressure sensitive adhesive;Said mixture is coated on 100 μm of PET films with 100 μm of bar spreaders In one side of the base material 1 Jing Guo sided corona treatment, pressure-sensitive adhesive layer 2 is formed, then 1min is dried in dryer in 110 DEG C, goes out baking oven Afterwards, the layer upper surface of release film 3 is laminating in pressure-sensitive adhesive layer 2, obtained supporter protective film finished product is used in combination tinfoil cladding to be kept in dark place It is spare.
Supporter protective film provided by the present invention has the peeling force of superelevation under normal conditions, and passes through sufficient UV After light irradiation, then it can be reduced to ultralow peeling force, be suitable for wafer grinding, cutting and the carrying of electronic component processing etc..The branch Support body protective film is in normal use, i.e., in the case where no UV irradiates, the viscous force with superelevation, it is ensured that chip is being ground It does not fall off, disperse in mill, cutting process, and protect undressed part.As long as and irradiating enough UV light after completion of processing Line, you can lower the viscous force of supporter protective film makes chip normally make in lower one of production process so as to be torn easily With.
It is of the art it will be recognized by the skilled artisan that above example of the present invention be only the present invention it is preferred One of embodiment limits for length, cannot enumerate all embodiments one by one here, any to embody the claims in the present invention The implementation of technical solution, all within the scope of the present invention.
It should be noted that the above content is combine specific embodiment made for the present invention further specifically It is bright, and it cannot be said that specific implementation mode of the invention is only limitted to this, under the above-mentioned guidance of the present invention, those skilled in the art can To carry out various improvement and deformations on the basis of the above embodiments, and these are improved or deformation falls the protection model in the present invention In enclosing.

Claims (10)

1. a kind of supporter protective film, including:Base material, pressure-sensitive adhesive layer and release film, wherein the base material single side is by corona Reason, coated on one side of the base material Jing Guo sided corona treatment have pressure-sensitive adhesive layer, release film, the pressure are covered on the pressure-sensitive adhesive layer The pressure sensitive adhesive of quick glue-line is acrylic system class pressure sensitive adhesive, including the acrylic resin that weight percent is 30-60%, weight hundred Divide the lytic agent than being 30-60%, the curing agent that weight percent is 0.4-3% and the light that weight percent is 0.4%-3% Initiator.
2. supporter protective film according to claim 1, it is characterised in that:The base material is PET or PO films, and thickness is 25-200μm。
3. supporter protective film according to claim 2, it is characterised in that:The coating layer thickness of the pressure-sensitive adhesive layer is 5-35 μm。
4. supporter protective film according to claim 3, it is characterised in that:The release film is with release performance PET, thickness are 25-75 μm.
5. supporter protective film according to claim 4, it is characterised in that:The acrylic resin can be polymethyl One or more of mixtures of sour methyl esters, polyethyl methacrylate, polybutyl methacrylate.
6. a kind of production method of supporter protective film, includes the following steps:
(a) base material single side is subjected to sided corona treatment;
(b) one layer of pressure sensitive adhesive of the coated on one side in base material Jing Guo sided corona treatment, forms pressure-sensitive adhesive layer, and the pressure sensitive adhesive is acrylic acid System class pressure sensitive adhesive, including weight percent are the acrylic resin of 30-60%, and weight percent is the lytic agent of 30-60%, The curing agent that weight percent is 0.4-3% and the photoinitiator that weight percent is 0.4%-3%;
(c) supporter protective film finished product is made, is used in combination nontransparent in the pressure-sensitive adhesive layer overlying last layer release film after drying Material is kept in dark place.
7. according to the method described in claim 6, it is characterized in that:In step (a), the base material is PET or PO films, thick Degree is 25-200 μm.
8. according to the method described in claim 7, it is characterized in that:In step (b), the coating layer thickness of the pressure-sensitive adhesive layer is 5-35μm。
9. according to the method described in claim 8, it is characterized in that:In step (c), the release film is with release performance PET, thickness be 25-75 μm.
10. according to the method described in claim 9, it is characterized in that:In step (b) and step (c), by uniformly mixed pressure Quick glue is coated on 45-100 μm of spreader in one side of the PET base material 1 Jing Guo sided corona treatment, pressure-sensitive adhesive layer is formed, then in 110 DEG C 1min is dried in dryer, it is after going out dryer, the layer upper surface of release film is laminating in pressure-sensitive adhesive layer, supporter protection is made Film finished product.
CN201611058832.4A 2016-11-25 2016-11-25 A kind of supporter protective film and its production method Pending CN108373888A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611058832.4A CN108373888A (en) 2016-11-25 2016-11-25 A kind of supporter protective film and its production method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611058832.4A CN108373888A (en) 2016-11-25 2016-11-25 A kind of supporter protective film and its production method

Publications (1)

Publication Number Publication Date
CN108373888A true CN108373888A (en) 2018-08-07

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Country Status (1)

Country Link
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110105888A (en) * 2019-05-30 2019-08-09 惠州市科域新材料科技有限公司 Glass cover-plate shipment protective film with low dyestripping power
CN110183981A (en) * 2019-05-30 2019-08-30 惠州市科域新材料科技有限公司 Glass plate processing procedure protective film after tearing without residue glue
CN110564330A (en) * 2019-09-18 2019-12-13 上海精珅新材料有限公司 Acrylic protective film glue capable of achieving high-speed delivery and protective film production method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015074611A1 (en) * 2013-11-22 2015-05-28 东莞市纳利光学材料有限公司 Protective film having high transparency and impact resistance, preparation method therefor
CN105778806A (en) * 2016-03-18 2016-07-20 张家港康得新光电材料有限公司 Heat-resistant UV visbreaking glue composition and UV visbreaking protective film
CN106147636A (en) * 2015-04-01 2016-11-23 上海精涂新材料技术有限公司 A kind of hardening protecting film and production method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015074611A1 (en) * 2013-11-22 2015-05-28 东莞市纳利光学材料有限公司 Protective film having high transparency and impact resistance, preparation method therefor
CN106147636A (en) * 2015-04-01 2016-11-23 上海精涂新材料技术有限公司 A kind of hardening protecting film and production method thereof
CN105778806A (en) * 2016-03-18 2016-07-20 张家港康得新光电材料有限公司 Heat-resistant UV visbreaking glue composition and UV visbreaking protective film

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110105888A (en) * 2019-05-30 2019-08-09 惠州市科域新材料科技有限公司 Glass cover-plate shipment protective film with low dyestripping power
CN110183981A (en) * 2019-05-30 2019-08-30 惠州市科域新材料科技有限公司 Glass plate processing procedure protective film after tearing without residue glue
CN110564330A (en) * 2019-09-18 2019-12-13 上海精珅新材料有限公司 Acrylic protective film glue capable of achieving high-speed delivery and protective film production method thereof

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Effective date of registration: 20190527

Address after: 201507 No. 288, Jinhe Road, Jinshan Industrial Zone, Jinshan District, Shanghai

Applicant after: SHANGHAI JINGSHEN NEW MATERIAL Co.,Ltd.

Address before: 201316 Three Blocks 118 Hangtou Road, Hangtou Town, Pudong New Area, Shanghai

Applicant before: SHANGHAI PLUSCO TECH Co.,Ltd.

WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20180807