CN108373698B - A kind of environment-friendly water-based paint for pool protection and preparation method thereof - Google Patents
A kind of environment-friendly water-based paint for pool protection and preparation method thereof Download PDFInfo
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- CN108373698B CN108373698B CN201810073476.6A CN201810073476A CN108373698B CN 108373698 B CN108373698 B CN 108373698B CN 201810073476 A CN201810073476 A CN 201810073476A CN 108373698 B CN108373698 B CN 108373698B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
- C08F218/08—Vinyl acetate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
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Abstract
本发明公开一种用于水池防护的环保水性涂料及其制备方法，所述用于水池防护的环保水性涂料，按照重量百分比计，包括以下组分：不饱和有机硅5~10%；叔碳酸乙烯酯5~15%；甲基丙烯酸（甲）酯10~25%；醋酸乙烯酯10~35%；苯乙烯10~20%；无机盐粉体30~50%。本发明所述用于水池防护的环保水性涂料是采用多元聚合乳液的方式复配成乳状涂料，使之成为具有防水，防锈，防腐蚀，抗龟裂，耐老化好的新型环保水性涂料。The invention discloses an environment-friendly water-based paint for pool protection and a preparation method thereof. The environment-friendly water-based paint for pool protection comprises the following components in weight percentage: 5-10% of unsaturated organic silicon; tertiary carbonic acid Vinyl ester 5~15%; (methyl) methacrylate 10~25%; vinyl acetate 10~35%; styrene 10~20%; inorganic salt powder 30~50%. The environmentally friendly water-based paint for pool protection of the present invention is formulated into an emulsion paint by means of multi-polymerized emulsion, so that it becomes a new type of environmentally-friendly water-based paint with good waterproof, anti-rust, anti-corrosion, anti-cracking and anti-aging properties.
Description
Technical Field
The invention relates to the field of metal protective coatings, and mainly relates to an environment-friendly water-based coating for pool protection and a preparation method thereof.
Background
Some water pools of factories are formed by welding steel plates, some liquid contained in the water pools is electrolyte solution with very high salinity, and the electrolyte solution is a natural corrosive agent with strong corrosivity, and a metal water pool is in a liquid soaking environment for a long time and is extremely severely corroded, so that water resistance, rust resistance, corrosion resistance and aging resistance are important standards after the metal water pool is formed, and proper protection measures ensure the service life of the metal water pool. The water pool is generally protected by coating a protective coating on the surface of a metal water pool, but the existing protective coating has an unsatisfactory use effect due to unreasonable components.
Accordingly, the prior art is yet to be improved and developed.
Disclosure of Invention
In view of the defects of the prior art, the invention aims to provide an environment-friendly water-based paint for pool protection and a preparation method thereof, and aims to solve the problem that the effect of the existing protective paint is not ideal.
The technical scheme of the invention is as follows:
the environment-friendly water-based paint for pool protection comprises the following components in percentage by weight:
5-10% of unsaturated organic silicon;
5-15% of ethylene versatate;
10-25% of (methyl) methacrylate;
10-35% of vinyl acetate;
10-20% of styrene;
30-50% of inorganic salt powder.
The environment-friendly water-based paint for pool protection comprises water, wherein the water accounts for 45-50% of the total mass of the raw materials.
The environment-friendly water-based paint for pool protection is characterized in that the unsaturated organic silicon is one of acryloyloxymethyl trimethoxysilane, methacryloyloxymethyl triphenoxysilane, 3-acryloyloxypropyl triethoxysilane, chloromethyl tris (2-methoxyethoxy) silane, bromomethyl triisopropoxysilane and the like.
The environment-friendly water-based paint for pool protection is characterized in that the inorganic salt powder is one or more than two of talcum powder, mica powder, barium sulfate, wollastonite, magnesium hydroxide, zinc oxide, feldspar powder, glass powder, silica micropowder and calcium carbonate.
The preparation method of the environment-friendly water-based paint for pool protection comprises the following steps:
unsaturated organosilicon, vinyl versatate, methyl methacrylate, vinyl acetate and styrene are metered according to a formula and are singly mixed and stirred; then water is used as a solvent to polymerize the milky white fluid; finally, inorganic salt powder is added to form the coating.
Has the advantages that: the environment-friendly water-based paint for pool protection is a novel environment-friendly water-based paint which is prepared by compounding a multi-component polymerization emulsion into an emulsion paint, and has the advantages of water resistance, rust prevention, corrosion prevention, cracking resistance and good aging resistance. The environment-friendly water-based paint for protecting the water pool disclosed by the invention can well solve the problems of water resistance, rust prevention and corrosion prevention of a metal water pool, and can have a good effect on application and protection of various steel products widely.
Detailed Description
The invention provides an environment-friendly water-based paint for pool protection and a preparation method thereof, and the invention is further described in detail below in order to make the purpose, technical scheme and effect of the invention clearer and clearer. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
The invention provides an environment-friendly water-based paint for pool protection, which is prepared by selecting a multi-polymerization mode, creating a formula of using water to replace an organic solvent, using a plurality of multipolymers of silicon, carbon, acrylic, vinegar and benzene resin as base materials, using inorganic substances as aggregate, adding an anti-aging agent, a culture medium, an adhesive and the like, and can be used for producing a novel waterproof, antirust, anticorrosion and aging-resistant environment-friendly water-based paint which has strong adhesive force and insulativity, is fast in curing and molding, fast in high and low variable speed resistance, free of cracking, good in weather resistance, non-toxic, tasteless and free of discoloration.
Specifically, the environment-friendly water-based paint for pool protection comprises the following components in percentage by weight:
5-10% of unsaturated organic silicon;
5-15% of ethylene versatate;
10-25% of (methyl) methacrylate;
10-35% of vinyl acetate;
10-20% of styrene;
30-50% of inorganic salt powder.
The adding proportion of the water accounts for 45-50% of the total mass of the raw materials.
Wherein, the unsaturated organosilicon has high temperature resistance and strong hydrophobicity, and can be one of acryloyloxymethyl trimethoxysilane, methacryloyloxymethyl triphenoxysilane, 3-acryloyloxypropyl triethoxysilane, chloromethyl tris (2-methoxyethoxy) silane, bromomethyl triisopropoxysilane and the like.
Vinyl versatate, ultra-soft and low temperature resistant. (methyl) methacrylate, a strong binding soft monomer. Vinyl acetate, a hard monomer with strong binding action. Styrene, a hard monomer that enhances adhesion. The inorganic salt powder can be one or more than two of talcum powder, mica powder, barium sulfate, wollastonite, magnesium hydroxide, zinc oxide, feldspar powder, glass powder, silica micropowder, calcium carbonate and the like.
The invention also provides a preparation method of the environment-friendly water-based paint for pool protection, which comprises the following steps:
unsaturated organosilicon, vinyl versatate, methyl methacrylate, vinyl acetate and styrene are metered according to a formula and are singly mixed and stirred; then water is used as a solvent to polymerize the milky white fluid; finally, inorganic salt powder is added to form the coating.
The environment-friendly water-based paint for pool protection is a novel environment-friendly water-based paint which is prepared by compounding a multi-component polymerization emulsion into an emulsion paint, and has the advantages of water resistance, rust prevention, corrosion prevention, cracking resistance and good aging resistance. The method has the following advantages:
1. sealing property: the water-based paint produced by the invention has strong adhesive force to steel, can completely block the corrosion of water and air to the steel after being coated, and well plays roles of water resistance, rust resistance, corrosion resistance and aging resistance.
2. Environmental protection property: most of the raw materials selected by the invention are inorganic materials, no waste water, waste residue and waste gas are discharged in the process of manufacturing finished products, no heavy metal residue harmful to human bodies exists, and no formaldehyde exists in market application. The production mode and the production process are environment-friendly, and the product is also environment-friendly when applied to the market.
3. Stability: most of the materials selected by the invention are inorganic materials, and no organic adhesive is adopted, so that the defects of natural aging, peeling and shedding existing in the traditional anti-rust oil paint are avoided; meanwhile, the coating has good high and low temperature resistance, good aging resistance and good stability, is not influenced by thermal expansion and cold contraction, fully shows excellent functions of fire prevention, water prevention, rust prevention and corrosion resistance, and can well protect steel products from corrosion by being coated on the surface of steel, thereby prolonging the service life of the steel products.
4. Strong adhesive force: the invention can tightly gather a plurality of auxiliary materials together, has super strong adhesive force when being coated on steel, is not easy to be peeled off and fall off, and can effectively protect the steel.
The environment-friendly water-based paint for pool protection is suitable for the protection of all steel materials against water, rust and corrosion, and specifically comprises the following components: a metal pool, a culture frame and a metal transport case; protecting industrial factory buildings, logistics warehouses, agricultural breeding and breeding barns; protecting the vehicle on the railway, the bolt on the rail, the steel structure on the station and the like; protecting various steel products and steel structures on roads and bridges; protecting steel structure supports in tunnels such as railways, highways, subways and the like; protecting a steel structure for building a house; all the protection of steel on the automobile is provided; protecting a bracket for supporting a high-low voltage electric transmission cable and an iron tower; protection of a street lamp post for public lighting at night; the protection of steel products, decks, fences and ship bodies of ships and the protection of steel materials which cannot be specifically listed in various industries need to be protected by novel waterproof, antirust and anticorrosive coatings, so that the service life of the steel materials can be well prolonged. The environment-friendly water-based paint for protecting the water pool is particularly suitable for protecting a metal water pool, a culture frame, a metal transport case and the like, well solves the problems of water resistance, rust resistance and corrosion resistance of a factory shed, and can have a good effect on the application and protection of various steel products widely.
The present invention is further illustrated by the following specific examples.
Example 1
The environment-friendly water-based paint for pool protection comprises the following components in percentage by weight:
10% of unsaturated organic silicon;
15% of ethylene versatate;
10% of (methyl) methacrylate;
25% of vinyl acetate;
10% of styrene;
30 percent of calcium carbonate.
The adding proportion of water is 45 percent of the total mass of the raw materials.
Unsaturated organosilicon, vinyl versatate, methyl methacrylate, vinyl acetate and styrene are metered according to a formula and are singly mixed and stirred; then water is used as a solvent to polymerize the milky white fluid; finally, inorganic salt powder is added to form the coating.
The environment-friendly water-based paint for pool protection obtained in the embodiment is coated on the surface of steel, and the acid resistance and alkali resistance of the coating are tested, wherein the acid resistance (96 h) is tested according to GB/T1763-; alkali resistance (96 h) is detected according to GB/T1763-1989, and the appearance of the coating is unchanged. The aging performance of the coating is detected, according to GB/T9277, after the coating is subjected to a 600-hour artificial accelerated aging test experiment, the gloss retention rate is greater than 90%, and the coating does not blister, peel off or crack. The salt spray resistance is detected according to GB/T1771 standard, the thickness of the coating film is about 40 mu m, and the salt spray resistance can reach 500 hours without foaming and rusting.
Example 2
The environment-friendly water-based paint for pool protection comprises the following components in percentage by weight:
5% of unsaturated organic silicon;
5% of ethylene versatate;
15% of (methyl) methacrylate;
30% of vinyl acetate;
10% of styrene;
15% of mica powder;
25% of barium sulfate.
The adding proportion of water is 50 percent of the total mass of the raw materials.
Unsaturated organosilicon, vinyl versatate, methyl methacrylate, vinyl acetate and styrene are metered according to a formula and are singly mixed and stirred; then water is used as a solvent to polymerize the milky white fluid; finally, inorganic salt powder is added to form the coating.
The environment-friendly water-based paint for pool protection obtained in the embodiment is coated on the surface of steel, and the acid resistance and alkali resistance of the coating are tested, wherein the acid resistance (96 h) is tested according to GB/T1763-; alkali resistance (96 h) is detected according to GB/T1763-1989, and the appearance of the coating is unchanged. The aging performance of the coating is detected, according to GB/T9277, after the coating is subjected to a 600-hour artificial accelerated aging test experiment, the gloss retention rate is greater than 90%, and the coating does not blister, peel off or crack. The salt spray resistance is detected according to GB/T1771 standard, the thickness of the coating film is about 40 mu m, and the salt spray resistance can reach 500 hours without foaming and rusting.
Example 3
The environment-friendly water-based paint for pool protection comprises the following components in percentage by weight:
8% of unsaturated organic silicon;
6% of ethylene versatate;
20% of (methyl) methacrylate;
10% of vinyl acetate;
16% of styrene;
20% of calcium carbonate;
20 percent of talcum powder.
The adding proportion of water is 40 percent of the total mass of the raw materials.
Unsaturated organosilicon, vinyl versatate, methyl methacrylate, vinyl acetate and styrene are metered according to a formula and are singly mixed and stirred; then water is used as a solvent to polymerize the milky white fluid; finally, inorganic salt powder is added to form the coating.
The environment-friendly water-based paint for pool protection obtained in the embodiment is coated on the surface of steel, and the acid resistance and alkali resistance of the coating are tested, wherein the acid resistance (96 h) is tested according to GB/T1763-; alkali resistance (96 h) is detected according to GB/T1763-1989, and the appearance of the coating is unchanged. The aging performance of the coating is detected, according to GB/T9277, after the coating is subjected to a 600-hour artificial accelerated aging test experiment, the gloss retention rate is greater than 90%, and the coating does not blister, peel off or crack. The salt spray resistance is detected according to GB/T1771 standard, the thickness of the coating film is about 40 mu m, and the salt spray resistance can reach 500 hours without foaming and rusting.
It is to be understood that the invention is not limited to the examples described above, but that modifications and variations may be effected thereto by those of ordinary skill in the art in light of the foregoing description, and that all such modifications and variations are intended to be within the scope of the invention as defined by the appended claims.
Claims (3)
1. The environment-friendly water-based paint for pool protection is characterized by comprising the following raw material components in percentage by weight:
5-10% of unsaturated organic silicon;
5-15% of ethylene versatate;
10-25% of methyl methacrylate;
10-35% of vinyl acetate;
10-20% of styrene;
30 to 50 percent of inorganic salt powder,
the components are 100 percent,
the coating also comprises water, the adding proportion of the water accounts for 45-50% of the total mass of the raw materials,
the unsaturated organic silicon is one of acryloyloxymethyl trimetoxysilane, methacryloyloxymethyl triphenoxysilane and 3-acryloyloxypropyl triethoxysilane,
unsaturated organic silicon, vinyl versatate, methyl methacrylate, vinyl acetate and styrene are metered according to a formula, singly mixed and stirred; then water is used as a solvent to polymerize the milky white fluid; finally, inorganic salt powder is added to form the coating.
2. The environment-friendly water-based paint for pool protection as claimed in claim 1, wherein the inorganic salt powder is one or more of talc powder, mica powder, barium sulfate, wollastonite, magnesium hydroxide, zinc oxide, feldspar powder, glass powder, silica micropowder and calcium carbonate.
3. The preparation method of the environment-friendly water-based paint for pool protection as claimed in any one of claims 1 to 2, characterized by comprising the following steps:
unsaturated organic silicon, vinyl versatate, methyl methacrylate, vinyl acetate and styrene are metered according to a formula, singly mixed and stirred; then water is used as a solvent to polymerize the milky white fluid; finally, inorganic salt powder is added to form the coating.
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| CN201810073476.6A CN108373698B (en) | 2018-01-25 | 2018-01-25 | A kind of environment-friendly water-based paint for pool protection and preparation method thereof |
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| CN108373698B true CN108373698B (en) | 2020-05-12 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1344770A (en) * | 2000-09-28 | 2002-04-17 | 罗姆和哈斯公司 | Binding agent composition for coating direct contacting metal |
| CN1814663A (en) * | 2005-02-05 | 2006-08-09 | 广州慧谷化学有限公司 | Thermo-setting acrylic-acid emulsion, its preparing method and paint containing same |
| CN1821323A (en) * | 2006-03-14 | 2006-08-23 | 无锡市奥尔化工有限公司 | Water dispersion chromium-free single component silicon steel insulation paint and its preparing method |
| CN105219203A (en) * | 2015-10-21 | 2016-01-06 | 湖南晟通纳米新材料有限公司 | Smokeless coating |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012082141A1 (en) * | 2010-12-17 | 2012-06-21 | Celanese International Corporation | Aqueous latex coating compositions |
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- 2018-01-25 CN CN201810073476.6A patent/CN108373698B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1344770A (en) * | 2000-09-28 | 2002-04-17 | 罗姆和哈斯公司 | Binding agent composition for coating direct contacting metal |
| CN1814663A (en) * | 2005-02-05 | 2006-08-09 | 广州慧谷化学有限公司 | Thermo-setting acrylic-acid emulsion, its preparing method and paint containing same |
| CN1821323A (en) * | 2006-03-14 | 2006-08-23 | 无锡市奥尔化工有限公司 | Water dispersion chromium-free single component silicon steel insulation paint and its preparing method |
| CN105219203A (en) * | 2015-10-21 | 2016-01-06 | 湖南晟通纳米新材料有限公司 | Smokeless coating |
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