CN108321351B - Device for improving fluidity of lithium ion battery slurry - Google Patents
Device for improving fluidity of lithium ion battery slurry Download PDFInfo
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- CN108321351B CN108321351B CN201711364646.8A CN201711364646A CN108321351B CN 108321351 B CN108321351 B CN 108321351B CN 201711364646 A CN201711364646 A CN 201711364646A CN 108321351 B CN108321351 B CN 108321351B
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- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 24
- 239000002002 slurry Substances 0.000 title claims abstract description 22
- 239000002904 solvent Substances 0.000 claims abstract description 87
- 239000007788 liquid Substances 0.000 claims abstract description 6
- 238000007599 discharging Methods 0.000 claims abstract 3
- 239000000463 material Substances 0.000 claims description 15
- 239000004744 fabric Substances 0.000 claims description 10
- 239000011232 storage material Substances 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 abstract 2
- 239000011344 liquid material Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000010406 cathode material Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000007773 negative electrode material Substances 0.000 description 2
- 239000007774 positive electrode material Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- -1 diaphragm Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000005087 graphitization Methods 0.000 description 1
- GELKBWJHTRAYNV-UHFFFAOYSA-K lithium iron phosphate Chemical compound [Li+].[Fe+2].[O-]P([O-])([O-])=O GELKBWJHTRAYNV-UHFFFAOYSA-K 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 238000009818 secondary granulation Methods 0.000 description 1
- 239000011163 secondary particle Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0404—Methods of deposition of the material by coating on electrode collectors
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Cell Separators (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
技术领域technical field
本发明涉及锂离子电池技术领域,尤其涉及一种改善锂离子电池浆料流动性的装置。The invention relates to the technical field of lithium ion batteries, in particular to a device for improving the fluidity of lithium ion battery slurry.
背景技术Background technique
目前环境友好型的新能源产业正快速蓬勃兴起,锂离子电池因其高安全性、长循环寿命、环境友好等特性被人们越来越多的应用于日常生活中,目前锂离子电池的主要应用领域于3C类电子产品及新能源汽车产业。近几年新能源汽车的产能及出货量数以倍计的增长,对于新能源汽车,人们主要关注的是其续航里程,从而要求单体电池及模组高能量密度以达到长续航里程的目标。At present, the environment-friendly new energy industry is booming rapidly. Lithium-ion batteries are more and more used in daily life due to their high safety, long cycle life, and environmental friendliness. At present, the main application of lithium-ion batteries The field is in 3C electronic products and new energy automobile industry. In recent years, the production capacity and shipments of new energy vehicles have increased by several times. For new energy vehicles, people are mainly concerned about their cruising range, which requires high energy density of single cells and modules to achieve long cruising range. Target.
目前能量密度提升的方式主要通过增加单体能量密度提升以及模组减重方式实现,对于单体能量密度提升的方式从材料体系选择、电芯结构设计等方面,为保证一定的机械与物理强度,对于较轻材质的选择较为慎重,提升单体电芯能量密度的主要核心技术为材料化学体系性能的提升。材料体系主要包括正极材料、负极材料、隔膜、电解液四大主材,其中正负极材料的克容量及压实密度提升是关键项。高容量的正极材料,目前高镍三元材料的逐步应用以及磷酸铁锂材料克容量的逐步提升,随着正极材料克容量的提升其加工性能尤其是吸水性方面对制程环境要求越来越高;高容量高压实负极材料,主要技术是通过二次造粒程度及石墨化度提升,但这种技术提升带来的弊端会因为二次颗粒的粘结性导致浆料流动性变差从而影响涂布均一性,对于这种材料本征特性导致的加工问题,除进行材料本身改进外,对于其合适工艺的开发也是实现材料应用价值的关键点。At present, the energy density improvement method is mainly achieved by increasing the energy density of the monomer and reducing the weight of the module. For the method of improving the energy density of the monomer, from the aspects of material system selection, cell structure design, etc., in order to ensure a certain mechanical and physical strength , The choice of lighter materials is more cautious, and the main core technology to improve the energy density of a single cell is the improvement of the performance of the material chemical system. The material system mainly includes four main materials: positive electrode material, negative electrode material, diaphragm, and electrolyte. Among them, the gram capacity and compaction density improvement of positive and negative electrode materials are the key items. High-capacity cathode materials, the current gradual application of high-nickel ternary materials and the gradual increase in the gram capacity of lithium iron phosphate materials, with the improvement of the gram capacity of cathode materials, their processing performance, especially in terms of water absorption, have higher and higher requirements for the process environment ; High-capacity and high-compression anode materials, the main technology is to improve the degree of secondary granulation and graphitization, but the drawbacks brought by this technical improvement will be due to the adhesion of the secondary particles. Affecting the coating uniformity, for the processing problems caused by the intrinsic characteristics of this material, in addition to improving the material itself, the development of its appropriate process is also a key point to realize the application value of the material.
发明内容SUMMARY OF THE INVENTION
为解决背景技术中存在的技术问题,本发明提出一种改善锂离子电池浆料流动性的装置。In order to solve the technical problems existing in the background art, the present invention proposes a device for improving the fluidity of lithium ion battery slurry.
本发明提出的一种改善锂离子电池浆料流动性的装置,包括:安装架、布料组件;A device for improving the fluidity of lithium ion battery slurry proposed by the present invention includes: a mounting frame and a cloth assembly;
布料组件安装在安装架上,布料组件包括溶剂进料管、微凹管、溶剂擦拭管,溶剂进料管水平设置,微凹管可转动套设在溶剂进料管外部且微凹管内壁与溶剂进料管外壁间隔预设距离,微凹管外壁设有多个凸起,多个凸起在微凹管表面形成多个凹槽结构,溶剂擦拭管套设在微凹管外部,溶剂擦拭管采用多孔存液材料制成;The cloth component is installed on the mounting frame, and the cloth component includes a solvent feeding tube, a micro-concave tube, and a solvent wiping tube. The solvent feeding tube is set horizontally. The outer wall of the solvent feed pipe is spaced by a preset distance, the outer wall of the micro-concave pipe is provided with a plurality of protrusions, and the plurality of protrusions form a plurality of groove structures on the surface of the micro-concave pipe. The tube is made of porous liquid storage material;
溶剂进料管一端设有进料口,溶剂进料管表面设有第一出料孔,微凹管与溶剂进料管通过所述第一出料孔连通,微凹管侧壁设有第二出料孔,溶剂擦拭管通过所述第二出料孔与微凹管内部连通。One end of the solvent feed pipe is provided with a feed port, the surface of the solvent feed pipe is provided with a first discharge hole, the micro-concave pipe is communicated with the solvent feed pipe through the first discharge hole, and the side wall of the micro-concave pipe is provided with a first discharge hole. Two discharge holes, the solvent wiping tube communicates with the inside of the micro-concave tube through the second discharge hole.
优选地,溶剂进料管的进料口设有流量控制阀。Preferably, the feed port of the solvent feed pipe is provided with a flow control valve.
优选地,微凹管两端分别设有挡板,挡板与微凹管固定连接。Preferably, baffles are respectively provided at both ends of the microconcave tube, and the baffles are fixedly connected to the microconcave tube.
优选地,溶剂进料管表面设有多个第一出料孔,多个第一出料孔在溶剂进料管表面均匀分布。Preferably, a plurality of first discharge holes are provided on the surface of the solvent feed pipe, and the plurality of first discharge holes are evenly distributed on the surface of the solvent feed pipe.
优选地,微凹管表面设有多个第二出料孔,多个第二出料孔在微凹管表面均匀分布。Preferably, the surface of the micro-concave tube is provided with a plurality of second discharge holes, and the plurality of second discharge holes are evenly distributed on the surface of the micro-concave tube.
优选地,第二出料孔位于所述凹槽内。Preferably, the second discharge hole is located in the groove.
优选地,所述凸起远离溶剂进料管一端抵靠溶剂擦拭管内壁。Preferably, one end of the protrusion away from the solvent feeding pipe abuts against the inner wall of the solvent wiping pipe.
本发明中,所提出的改善锂离子电池浆料流动性的装置,溶剂进料管水平设置,微凹管可转动套设在溶剂进料管外部且微凹管内壁与溶剂进料管外壁间隔预设距离,微凹管外壁设有多个凸起,多个凸起在微凹管表面形成多个凹槽结构,溶剂擦拭管套设在微凹管外部,微凹管与溶剂进料管通过第一出料孔连通,溶剂擦拭管通过所述第二出料孔与微凹管内部连通。通过上述优化设计的改善锂离子电池浆料流动性的装置,充分考虑溶剂擦拭的均匀性,溶剂进料管保证对微凹管的溶剂供给量平稳均匀,微凹管外壁的凸起设计保证溶剂的均匀分散,溶剂擦拭管采用存液材料,保证溶剂的均匀擦拭,同时节省溶剂用量。In the present invention, in the proposed device for improving the fluidity of lithium-ion battery slurry, the solvent feeding pipe is horizontally arranged, the micro-concave pipe is rotatably sleeved outside the solvent feeding pipe, and the inner wall of the micro-concave pipe is spaced from the outer wall of the solvent feeding pipe With a preset distance, the outer wall of the micro-concave tube is provided with a plurality of protrusions, and the plurality of protrusions form a plurality of groove structures on the surface of the micro-concave tube. The solvent wiping tube communicates with the inside of the micro concave tube through the second discharge hole. Through the above-mentioned optimized design of the device for improving the fluidity of lithium-ion battery slurry, the uniformity of solvent wiping is fully considered. The solvent feeding pipe ensures a stable and uniform supply of solvent to the micro-concave tube, and the convex design of the outer wall of the micro-concave tube ensures that the solvent is supplied. The solvent wiper tube adopts the liquid storage material to ensure the uniform wipe of the solvent and save the solvent consumption at the same time.
附图说明Description of drawings
图1为本发明提出的一种改善锂离子电池浆料流动性的装置的结构示意图。FIG. 1 is a schematic structural diagram of a device for improving the fluidity of a lithium-ion battery slurry proposed by the present invention.
具体实施方式Detailed ways
如图1所示,图1为本发明提出的一种改善锂离子电池浆料流动性的装置的结构示意图。As shown in FIG. 1 , FIG. 1 is a schematic structural diagram of a device for improving the fluidity of a lithium ion battery slurry proposed by the present invention.
参照图1,本发明提出的一种改善锂离子电池浆料流动性的装置,包括:安装架6、布料组件;Referring to FIG. 1 , a device for improving the fluidity of lithium-ion battery slurry proposed by the present invention includes: a mounting frame 6 and a cloth assembly;
布料组件安装在安装架6上,布料组件包括溶剂进料管1、微凹管2、溶剂擦拭管3,溶剂进料管1水平设置,微凹管2可转动套设在溶剂进料管1外部且微凹管2内壁与溶剂进料管1外壁间隔预设距离,微凹管2外壁设有多个凸起,多个凸起在微凹管2表面形成多个凹槽结构,溶剂擦拭管3套设在微凹管2外部,溶剂擦拭管3采用多孔存液材料制成;The cloth assembly is installed on the mounting frame 6. The cloth assembly includes a solvent feeding pipe 1, a
溶剂进料管1一端设有进料口,溶剂进料管1表面设有第一出料孔,微凹管2与溶剂进料管1通过所述第一出料孔连通,微凹管2侧壁设有第二出料孔,溶剂擦拭管3通过所述第二出料孔与微凹管2内部连通。One end of the solvent feed pipe 1 is provided with a feed port, the surface of the solvent feed pipe 1 is provided with a first discharge hole, the
本实施例的改善锂离子电池浆料流动性的装置的具体工作过程中,首先根据浆料状态及涂布速度向溶剂进料管进料,溶剂进料管可承受溶剂较大压力,溶剂进料管内的溶剂通过第一出料孔进入微凹管内,驱动微凹管转动,通过第二出料口流到微凹管外部,在凸起的作用下实现溶剂均匀分布,均匀的物料流至溶剂擦拭管上,实现溶剂于箔材表面的定量匀速涂覆。In the specific working process of the device for improving the fluidity of the lithium-ion battery slurry in this embodiment, firstly, the material is fed to the solvent feeding pipe according to the slurry state and coating speed. The solvent in the material pipe enters the micro-concave pipe through the first discharge hole, drives the micro-concave pipe to rotate, and flows to the outside of the micro-concave pipe through the second discharge port. The solvent is wiped on the tube to achieve quantitative and uniform coating of the solvent on the surface of the foil.
在本实施例中,所提出的改善锂离子电池浆料流动性的装置,溶剂进料管水平设置,微凹管可转动套设在溶剂进料管外部且微凹管内壁与溶剂进料管外壁间隔预设距离,微凹管外壁设有多个凸起,多个凸起在微凹管表面形成多个凹槽结构,溶剂擦拭管套设在微凹管外部,微凹管与溶剂进料管通过第一出料孔连通,溶剂擦拭管通过所述第二出料孔与微凹管内部连通。通过上述优化设计的改善锂离子电池浆料流动性的装置,充分考虑溶剂擦拭的均匀性,溶剂进料管保证对微凹管的溶剂供给量平稳均匀,微凹管外壁的凸起设计保证溶剂的均匀分散,溶剂擦拭管采用存液材料,保证溶剂的均匀擦拭,同时节省溶剂用量。In this embodiment, in the proposed device for improving the fluidity of lithium-ion battery slurry, the solvent feeding pipe is set horizontally, the micro-concave pipe is rotatably sleeved outside the solvent feeding pipe, and the inner wall of the micro-concave pipe is connected to the solvent feeding pipe. The outer wall is separated by a preset distance, the outer wall of the micro-concave tube is provided with a plurality of protrusions, and the plurality of protrusions form a plurality of groove structures on the surface of the micro-concave tube. The material pipe is communicated with the first discharge hole, and the solvent wiping pipe is communicated with the inside of the micro concave pipe through the second discharge hole. Through the above-mentioned optimized design of the device for improving the fluidity of lithium-ion battery slurry, the uniformity of solvent wiping is fully considered. The solvent feeding pipe ensures a stable and uniform supply of solvent to the micro-concave tube, and the convex design of the outer wall of the micro-concave tube ensures that the solvent is supplied. The solvent wiper tube adopts the liquid storage material to ensure the uniform wipe of the solvent and save the solvent consumption at the same time.
在具体实施方式中,溶剂进料管1的进料口设有流量控制阀4,根据浆料状态及涂布速度,调节进料流速和流量。In a specific embodiment, the feed port of the solvent feed pipe 1 is provided with a flow control valve 4, and the feed flow rate and flow rate are adjusted according to the slurry state and coating speed.
在其他具体实施方式中,微凹管2两端分别设有挡板5,挡板5与微凹管2固定连接,管道内溶剂流动时,一部分通过挡板作用可回流,节约溶剂用量。In other specific embodiments,
在出料孔的具体设计方式中,溶剂进料管1表面设有多个第一出料孔,多个第一出料孔在溶剂进料管1表面均匀分布,微凹管2表面设有多个第二出料孔,多个第二出料孔在微凹管2表面均匀分布。In the specific design of the discharge hole, the surface of the solvent feed pipe 1 is provided with a plurality of first discharge holes, the plurality of first discharge holes are evenly distributed on the surface of the solvent feed pipe 1, and the surface of the
在进一步具体实施方式中,第二出料孔位于所述凹槽内,使得通过第二出料孔出料的。In a further specific embodiment, the second discharge hole is located in the groove, so that the material is discharged through the second discharge hole.
为了保证在各个方向上布料均匀,在其他具体实施方式中,所述凸起远离溶剂进料管1一端抵靠溶剂擦拭管3内壁。In order to ensure that the cloth is uniform in all directions, in other specific implementations, one end of the protrusion away from the solvent feeding pipe 1 abuts against the inner wall of the
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,根据本发明的技术方案及其发明构思加以等同替换或改变,都应涵盖在本发明的保护范围之内。The above description is only a preferred embodiment of the present invention, but the protection scope of the present invention is not limited to this. The equivalent replacement or change of the inventive concept thereof shall be included within the protection scope of the present invention.
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