CN108300949B - A method of distributing bundled bainite orientation in steel - Google Patents
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 59
- 239000010959 steel Substances 0.000 title claims abstract description 59
- 229910001563 bainite Inorganic materials 0.000 title claims abstract description 25
- 238000000034 method Methods 0.000 title claims abstract description 8
- 238000009826 distribution Methods 0.000 claims abstract description 13
- 238000001816 cooling Methods 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 230000006698 induction Effects 0.000 claims abstract description 6
- 239000000126 substance Substances 0.000 claims description 6
- 238000005520 cutting process Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 238000010276 construction Methods 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 230000009466 transformation Effects 0.000 description 3
- HMDDXIMCDZRSNE-UHFFFAOYSA-N [C].[Si] Chemical compound [C].[Si] HMDDXIMCDZRSNE-UHFFFAOYSA-N 0.000 description 2
- 230000006911 nucleation Effects 0.000 description 2
- 238000010899 nucleation Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/002—Heat treatment of ferrous alloys containing Cr
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/008—Heat treatment of ferrous alloys containing Si
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/002—Bainite
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Abstract
一种使钢中束状贝氏体取向分布的方法。本发明通过中频真空感应炉熔炼出的钢坯铸成钢锭,然后再高温锻造成板材。将该钢加热到1000‑1050℃,保温20‑30min,油冷至240‑260℃保温20‑30min后水冷至室温,通过在冷却时钢材内部形成的温度梯度场制得使束状贝氏体取向分布的钢,其成分及含量:C为0.84wt.%‑0.90wt.%;Si为1.34wt.%‑1.45wt.%;Mn为0.35wt.%‑0.40wt.%;Cr为0.95wt.%‑1.10wt.%;P<0.02wt.%;S<0.02wt.%;其余为Fe。本发明具有成本低廉、周期短、工艺简单及生产效率高等特点。所制备的束状贝氏体钢抗拉强度达1700‑2100MPa,可应用于工程机械、公路、桥梁等领域。
A method of orienting the distribution of bundled bainite in steel. In the present invention, the steel billet smelted by the intermediate frequency vacuum induction furnace is cast into a steel ingot, and then forged into a plate at a high temperature. The steel is heated to 1000-1050°C, kept for 20-30min, oil-cooled to 240-260°C, kept for 20-30min, and then water-cooled to room temperature, through the temperature gradient field formed inside the steel during cooling to obtain bundled bainite Orientation distribution steel, its composition and content: C is 0.84wt.%-0.90wt.%; Si is 1.34wt.%-1.45wt.%; Mn is 0.35wt.%-0.40wt.%; Cr is 0.95wt.% .%-1.10wt.%; P<0.02wt.%;S<0.02wt.%; the rest is Fe. The invention has the characteristics of low cost, short cycle, simple process and high production efficiency. The prepared bundled bainitic steel has a tensile strength of 1700-2100 MPa, and can be used in construction machinery, highways, bridges and other fields.
Description
技术领域technical field
本发明属于金属材料技术领域,特别涉及一种贝氏体钢及其制备方法。The invention belongs to the technical field of metal materials, and particularly relates to a bainitic steel and a preparation method thereof.
背景技术Background technique
上世纪30年代,Bain和Davenprot通过中温等温转变获得了贝氏体组织。从此以后,多种形貌的贝氏体组织被各国学者所发现。大大推动了贝氏体钢在工程中的实际应用。2002年,Bhadeshia等人通过改变钢的化学成分获得束状贝氏体,使钢铁材料获得了出色的强度、韧性和延展的组合,而更加掀起了人们对低温贝氏体研究的热情。但是由于中温等温时间过长并且生产效率过低从而导致束状贝氏体钢难以在工业上大规模的应用。In the 1930s, Bain and Davenprot obtained the bainite structure through mesothermal transformation. Since then, bainite structures with various morphologies have been discovered by scholars from all over the world. It has greatly promoted the practical application of bainitic steel in engineering. In 2002, Bhadeshia et al. obtained bundled bainite by changing the chemical composition of steel, so that the steel material obtained an excellent combination of strength, toughness and ductility, which further aroused people's enthusiasm for low-temperature bainite research. However, due to the long isothermal time at medium temperature and the low production efficiency, it is difficult for bundled bainitic steel to be applied on a large scale in industry.
发明内容SUMMARY OF THE INVENTION
本发明目的是克服现有技术存在的上述不足,通过利用温度梯度场生产一种具有取向分布特征的束状贝氏体钢。该方法生产工艺简单、周期短、生产成本低,制备的束状贝氏体钢机械性能优良。The purpose of the present invention is to overcome the above-mentioned shortcomings of the prior art, and to produce a bundled bainitic steel with orientation distribution characteristics by utilizing the temperature gradient field. The method has the advantages of simple production process, short period and low production cost, and the prepared bundled bainitic steel has excellent mechanical properties.
本发明的技术方案Technical solution of the present invention
一种通过温度梯度场获得具有取向分布的束状贝氏体钢,其化学成分的质量百分比为:C为0.84wt.%-0.90wt.%;Si为1.34wt.%-1.45wt.%;Mn为0.35wt.%-0.40wt.%;Cr为0.95wt.%-1.10wt.%;P<0.02wt.%;S<0.02wt.%;其余为Fe及不可避免的杂质。A beam-shaped bainitic steel with orientation distribution obtained through a temperature gradient field, the mass percentage of its chemical composition is: C is 0.84wt.%-0.90wt.%; Si is 1.34wt.%-1.45wt.%; Mn is 0.35wt.%-0.40wt.%; Cr is 0.95wt.%-1.10wt.%; P<0.02wt.%; S<0.02wt.%; the rest are Fe and inevitable impurities.
本发明提供的使钢中束状贝氏体取向分布的方法,包括以下步骤:The method for making bundled bainite orientation distribution in steel provided by the present invention comprises the following steps:
(1)将中频真空感应炉熔炼出的含有以上所述成分的钢坯铸成钢锭,然后在1050-1100℃高温锻造成板材;将板材切割成厚度为5-10mm而长和宽均为50mm的钢。(1) Cast the steel billet containing the above-mentioned components smelted in the intermediate frequency vacuum induction furnace into a steel ingot, and then forge it into a plate at a high temperature of 1050-1100 ° C; cut the plate into a thickness of 5-10mm and a length and width of 50mm. steel.
(2)将该钢加热到1000℃-1050℃,保温20-30min,油冷至240-260℃保温20-30min后水冷至室温,通过在冷却时钢材内部形成的温度梯度场制得具有取向分布特征的束状贝氏体的钢。(2) Heating the steel to 1000°C-1050°C, holding the temperature for 20-30min, cooling the oil to 240-260°C, holding the temperature for 20-30min, cooling to room temperature with water, and obtaining the oriented steel through the temperature gradient field formed inside the steel during cooling. Distribution characteristic of bundled bainitic steels.
本发明通过较薄的试样,在试样厚度方向上形成大的温度梯度,从而使在厚度方向上具有较大的相比驱动力,能够增加束状贝氏体的形核率从而增加束状贝氏体的数量,并且使得束状贝氏体具有取向分布的特征。这就大大增大了束状贝氏体钢的机械性能。In the present invention, a large temperature gradient is formed in the thickness direction of the sample through a thinner sample, so as to have a relatively large driving force in the thickness direction, and can increase the nucleation rate of bundled bainite, thereby increasing the number of bundles. The number of bainite and the fascicle bainite have the characteristics of orientation distribution. This greatly increases the mechanical properties of bundled bainitic steels.
本发明的优点和有益效果:Advantages and beneficial effects of the present invention:
1.通过较薄的厚度,在钢材进行中温等温时在厚度方向上形成较大的温度梯度。在较大的温度梯度场的作用下束状贝氏体组织在进行中温转变时能够得到大的相变驱动力,从而使得束状贝氏体组织具有大的形核率,具有取向分布的特征。大大增加了束状贝氏体钢的机械性能,提高束状贝氏体钢的生产率。1. Through the thinner thickness, a larger temperature gradient is formed in the thickness direction when the steel is subjected to medium temperature isothermal. Under the action of a large temperature gradient field, the bundled bainite structure can obtain a large phase transformation driving force during the medium temperature transformation, so that the bundled bainite structure has a large nucleation rate and has the characteristics of orientation distribution. . The mechanical properties of the bundled bainite steel are greatly increased, and the productivity of the bundled bainite steel is improved.
2.在大的温度梯度场作用下形成的束状贝氏体钢,具有好的机械性能,抗拉强度可达到1700-2100MPa。2. The bundled bainitic steel formed under the action of a large temperature gradient field has good mechanical properties, and the tensile strength can reach 1700-2100MPa.
3.在温度梯度场的作用下束状贝氏体中温等温时间短,能够提高生产效率,降低成本。3. Under the action of the temperature gradient field, the mesothermal isothermal time of the bundled bainite is short, which can improve the production efficiency and reduce the cost.
4.生产工艺简单,应用前景广泛。可广泛应用于公路、桥梁、海洋设施造船等领域。4. The production process is simple and the application prospect is wide. Can be widely used in highways, bridges, marine facilities shipbuilding and other fields.
附图说明Description of drawings
图1是本发明实施例1所得试样的金相照片,可观察到束状贝氏体取向排布的特征。Fig. 1 is a metallographic photograph of the sample obtained in Example 1 of the present invention, and the characteristics of the orientation arrangement of bundled bainite can be observed.
图2是本发明实施例2所得试样的金相照片,可观察到可观察到束状贝氏体取向排布的特征。FIG. 2 is a metallographic photograph of the sample obtained in Example 2 of the present invention, and it can be observed that the characteristics of the orientation arrangement of bundled bainite can be observed.
具体实施方式Detailed ways
实施例1:Example 1:
用真空感应炉对高碳含硅钢进行熔炼,该高碳含硅钢的化学成分质量百分比为:C为0.88wt.%;Si为1.36wt.%;Mn为0.38wt.%;Cr为1.01wt.%;P<0.02wt.%;S<0.02wt.%;其余为Fe。The high-carbon silicon-containing steel is smelted in a vacuum induction furnace, and the chemical composition mass percentage of the high-carbon silicon-containing steel is: C is 0.88wt.%; Si is 1.36wt.%; Mn is 0.38wt.%; Cr is 1.01wt.% %; P<0.02wt.%; S<0.02wt.%; the rest is Fe.
对熔炼出的具有上述成分含量的钢锭在1050℃高温锻造成板材。用线切割将板材加工成厚度为5mm而长和宽均为50mm的钢。将该钢加热到1000℃,保温20min,油冷至240℃保温20min后水冷至室温。制备出的钢的抗拉强度为2100MPa。图1是本发明的高碳含硅钢经上述实验条件后所获得的取向性排列的束状贝氏体的金相组织照片。The smelted steel ingot with the above-mentioned component content is forged into a plate at a high temperature of 1050°C. The sheet was machined into steel with a thickness of 5 mm and a length and width of 50 mm by wire cutting. The steel was heated to 1000°C, kept for 20 minutes, oil-cooled to 240°C for 20 minutes, and then water-cooled to room temperature. The tensile strength of the prepared steel was 2100 MPa. FIG. 1 is a photo of the metallographic structure of the oriented bundled bainite obtained after the high carbon silicon-containing steel of the present invention is subjected to the above-mentioned experimental conditions.
实施例2:Example 2:
用真空感应炉对高碳含硅钢进行熔炼,该高碳含硅钢的化学成分质量百分比为:C为0.89wt.%;Si为1.39wt.%;Mn为0.36wt.%;Cr为0.96wt.%;P<0.02wt.%;S<0.02wt.%;其余为Fe。The high-carbon silicon-containing steel is smelted in a vacuum induction furnace, and the chemical composition mass percentage of the high-carbon silicon-containing steel is: C is 0.89wt.%; Si is 1.39wt.%; Mn is 0.36wt.%; Cr is 0.96wt.%. %; P<0.02wt.%; S<0.02wt.%; the rest is Fe.
对熔炼出的具有上述成分含量的钢锭在1080℃高温锻造成板材。用线切割将板材加工成厚度为7mm而长和宽均为50mm的钢。将该钢加热到1020℃,保温30min,油冷至260℃保温30min后水冷至室温。制备出的钢的抗拉强度为1950MPa。图2是本发明的高碳含硅钢经上述实验条件后所获得的取向性排列的束状贝氏体的金相组织照片。The smelted steel ingot with the above-mentioned component content is forged into a plate at a high temperature of 1080°C. The sheet was machined by wire cutting into steel with a thickness of 7 mm and a length and width of 50 mm. The steel was heated to 1020°C, kept for 30 minutes, oil-cooled to 260°C for 30 minutes, and then water-cooled to room temperature. The tensile strength of the prepared steel was 1950 MPa. FIG. 2 is a photograph of the metallographic structure of the oriented bundled bainite obtained after the high carbon silicon-containing steel of the present invention is subjected to the above-mentioned experimental conditions.
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