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CN108281556A - OLED device and its manufacturing method and display device - Google Patents

OLED device and its manufacturing method and display device Download PDF

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Publication number
CN108281556A
CN108281556A CN201710007623.5A CN201710007623A CN108281556A CN 108281556 A CN108281556 A CN 108281556A CN 201710007623 A CN201710007623 A CN 201710007623A CN 108281556 A CN108281556 A CN 108281556A
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CN
China
Prior art keywords
electron injecting
injecting layer
oled device
layer
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710007623.5A
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Chinese (zh)
Inventor
李梦真
刘嵩
葛泳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kunshan New Flat Panel Display Technology Center Co Ltd
Kunshan Govisionox Optoelectronics Co Ltd
Kunshan Guoxian Photoelectric Co Ltd
Original Assignee
Kunshan New Flat Panel Display Technology Center Co Ltd
Kunshan Guoxian Photoelectric Co Ltd
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Filing date
Publication date
Application filed by Kunshan New Flat Panel Display Technology Center Co Ltd, Kunshan Guoxian Photoelectric Co Ltd filed Critical Kunshan New Flat Panel Display Technology Center Co Ltd
Priority to CN201710007623.5A priority Critical patent/CN108281556A/en
Publication of CN108281556A publication Critical patent/CN108281556A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/10OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/17Carrier injection layers
    • H10K50/171Electron injection layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00Manufacture or treatment specially adapted for the organic devices covered by this subclass
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K2102/00Constructional details relating to the organic devices covered by this subclass

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Nanotechnology (AREA)
  • Manufacturing & Machinery (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Optics & Photonics (AREA)
  • Electroluminescent Light Sources (AREA)

Abstract

The present invention provides a kind of OLED device and its manufacturing method and display device, the OLED device includes:Substrate and anode, organic layer and cathode on the substrate are set gradually, further includes electron injecting layer, between the organic layer and cathode;The anode is made with cathode of ITO, the electron injecting layer is made of metal material, the metal material is the alloy of active metal or active metal and inert metal, while improving light transmittance, avoid ITO work content it is higher caused by high voltage so that OLED device meets the needs of voltage and light transmittance simultaneously.

Description

OLED device and its manufacturing method and display device
Technical field
The present invention relates to flat display fields, and in particular to a kind of OLED device and its manufacturing method and display device.
Background technology
Organic electroluminescent LED (organic light emitting diode, OLED) is divided into according to light extraction mode Bottom emitting OLED and top emitting OLED and transparent OLED.The light sent out inside bottom emitting OLED in succession pass through transparent anode, thoroughly Bright substrate projects.The display screen made in this way will be produced on transparent substrate simultaneously due to driving circuit and display area On, cause display area area is opposite to reduce, the aperture opening ratio of display screen reduces.
Compared with bottom emitting OLED, top emitting OLED since the design feature of itself, light can be projected from top electrodes, by It is produced on the lower section of display area in pixel-driving circuit, bus etc. so that the aperture opening ratio of device greatly improves, and then realizes aobvious The high-resolution of display screen.It, can also be to OLED display screen simultaneously by using microcavity effect present in top emitting OLED structure Display colour gamut improved, improve display effect.
There are larger difference, the light generated in transparent OLED can be respectively from substrate lower section and substrate with both above OLED Top is launched, and external ambient light can also penetrate transparent OLED, therefore transparent OLED can have many special applications.
The Major Difficulties of top emitting OLED and transparent OLED are to need to select suitable cathode material, should be had lower Work function obtains preferable light transmittance, and have lower resistance again to ensure that effective charge injects.Common cathode material Material such as aluminium (Al), magnesium silver alloy (Mg-Ag), silver-colored (Ag) just there is good light to penetrate only under very thin thickness Property, but when metal layer is very thin, the problem of breaking or metal is easy oxidation is usually had, effective ohm cannot be formed and connect It touches, being easy to be formed defect on interface causes the loss of charge injection process to increase.
Transparent conductive material is selected in the prior art, if tin indium oxide (indium tin oxides, ITO) etc. is as cloudy Light transmittance is improved to prepare transparent OLED or top emitting OLED in pole with this, but as cathode, the work content of transparent conductive material compared with Height, very high voltage can be led to by directly being contacted with organic layer, therefore how to be reduced the type device voltage and do not reduced light transmission Rate becomes a technical barrier.
Invention content
The purpose of the present invention is to provide a kind of OLED device and its manufacturing methods and display device, reduce cathode voltage While do not reduce light transmittance.
To achieve the above object, the present invention provides a kind of OLED device, including substrate and is successively set on the substrate On anode, organic layer and cathode, further include electron injecting layer, between the organic layer and cathode;The cathode is by saturating Bright conductive material is made, and the electron injecting layer is made of metal material, and the metal material is active metal or active metal With the alloy of inert metal.
Optionally, the transparent conductive material is ITO, and the electron injecting layer is the alloy of magnesium and silver.
Optionally, the thickness of the electron injecting layer is 1nm~5nm;The mass ratio of magnesium and silver in the electron injecting layer It is 1:1~10:1.
Optionally, the thickness of the electron injecting layer is 2nm;The mass ratio of magnesium and silver is 4 in the electron injecting layer:1.
Correspondingly, the present invention also provides a kind of organic light-emitting display device, including above-mentioned OLED device.
Correspondingly, the present invention also provides a kind of manufacturing methods of OLED device, including:
One substrate is provided, forms anode and organic layer on the substrate;
Electron injecting layer is formed on the organic layer, the electron injecting layer is made of metal material, the metal material Material is the alloy of active metal or active metal and inert metal;
Transparent cathode is formed on the electron injecting layer.
Optionally, the transparent cathode is ITO, and the electron injecting layer is the alloy of magnesium and silver.
Optionally, the electron injecting layer is formed on the organic layer by the method for vapor deposition;Pass through the method for sputtering Form the transparent cathode.
Optionally, the thickness of the electron injecting layer is 1nm~5nm;The mass ratio of magnesium and silver in the electron injecting layer It is 1:1~10:1.
Optionally, the thickness of the electron injecting layer is 2nm;The mass ratio of magnesium and silver is 4 in the electron injecting layer:1
Compared with prior art, the advantageous effect of OLED device and its manufacturing method and display device provided by the invention It is as follows:
Using ITO as cathode, electron injecting layer is set between organic layer and cathode layer, is made of metal material electricity Sub- implanted layer, the metal material is the alloy of active metal or active metal and inert metal, while improving light transmittance, Avoid transparent conductive material work content it is higher caused by high voltage so that OLED device meets the need of voltage and light transmittance simultaneously It asks.
Description of the drawings
Fig. 1 is the structural schematic diagram for the OLED device that one embodiment of the invention provides.
Fig. 2 is the flow diagram of the manufacturing method for the OLED device that one embodiment of the invention provides.
Specific implementation mode
To keep present disclosure more clear and easy to understand, below in conjunction with Figure of description, present disclosure is done into one Walk explanation.Certainly the invention is not limited to the specific embodiment, and general replacement well known to the skilled artisan in the art is also contained Lid is within the scope of the present invention.
Secondly, the present invention has carried out detailed statement using schematic diagram, when present example is described in detail, for the ease of saying Bright, schematic diagram is not partially enlarged in proportion to the general scale, should not be to this restriction as the present invention.
Core of the invention thought is, using ITO as cathode, electron injection is arranged between organic layer and cathode layer Layer, is made of metal material electron injecting layer, and the metal material is the conjunction of active metal or active metal and inert metal Gold, while improving light transmittance, avoid ITO work content it is higher caused by high voltage so that OLED device meets electricity simultaneously The demand of pressure and light transmittance.
Referring to FIG. 1, the structural schematic diagram of its OLED device provided for one embodiment of the invention.As shown in Figure 1, described OLED device includes substrate 10 and sets gradually anode 11, organic layer 12 and cathode 13 on the substrate.The OLED Device further includes electron injecting layer 14, between the organic layer 12 and cathode 13;The cathode 13 is by transparent conductive material It is made, 11 material of the anode can also be made of transparent conductive material, and the electron injecting layer 14 is made of metal material, institute State the alloy that metal material is active metal or active metal and inert metal.
The transparent conductive material is to have 80% or more light transmittance in visible-range, and electric conductivity is high, than Resistance value is less than 1 × 10-3The material of Ω cm.
The active metal judges that the metal activity i.e. metal is in chemistry with inert metal according to the activity of metal The arrangement foundation of active degree in reaction, metal activity mainly has at 4 points:The severe degree reacted with oxygen;It is reacted with acid Severe degree;Whether the metal can cement out other metals from the solution of its compound;Whether can displace hydrochloric acid, Hydrogen in dilute sulfuric acid.Metal is ranked up according to above 4 points, because hydrogen ion can embody metallic element in displacement is reacted The characteristics of, so being also discharged into metal activity table, using hydrogen as standard, the metal come before hydrogen is active metal, comes hydrogen Subsequent metal is inert metal.In the present invention, the metal material for making the electron injecting layer 14 is active metal or active The alloy of metal and inert metal, such as can be the alloy or ytterbium and silver-colored alloy of magnesium and silver, in the present embodiment, the metal Material is the alloy of magnesium and silver.
In the present embodiment, the thickness of the electron injecting layer 14 is 1nm~5nm;Such as 1nm, 2nm, 3nm, 4nm or 5nm, Preferably, the thickness of the electron injecting layer 14 is 2nm.Magnesium (Mg) and the mass ratio of silver-colored (Ag) are in the electron injecting layer 14 1:1~10:1, such as 2:1、4:1、6:1、8:1 or 10:1, it is preferred that magnesium (Mg) and silver-colored (Ag) in the electron injecting layer 14 Mass ratio is 4:1.
When the mass ratio that the thickness of the electron injecting layer 14 is 2nm, Mg and Ag is 4:When 1, the conjunction with no magnesium and silver The device that electron injecting layer is made in golden material is compared, and voltage drops to 4.63V, light transmittance 74.82% from 10V.When adjusting institute When stating the thickness of electron injecting layer 14 to 3nm, voltage 4.52V, light transmittance 64.95%;When the adjusting electron injecting layer When 14 thickness is to 4nm, voltage 4.39V, light transmittance 64.80%.
For OLED display screen, driving voltage is usually required that in 5V or less.For one piece 5 inches of OLED display screen, work Input current is about 200mA when making, and the voltage difference of 0.24V is away from the power consumption that can only cause 48mW, therefore voltage is 4.63V when 2nm It can ignore with the power consumption difference of voltage 4.39V when 4nm.But for light transmittance, some OLED application field industries have higher It is required that《Motor vehicle safe and technical specification》Wherein Sub_clause 11 provides:Automobile driving cabin must assure that field of front vision and side Glass does not allow to be less than for the visible transmission ratio at driver's vision area position other than the square visual field, windscreen and air regulator 70%.When replacing simple glass using transparent OLED device, light transmittance otherwise be less than 70%, 2nm and 4nm thickness pair at this time The influence of light transmittance be can not ignore.Therefore the thickness range of the electron injecting layer 14 requires between 1nm~5nm, preferably 2nm。
Correspondingly, the present invention also provides a kind of organic light-emitting display device, including above-mentioned OLED device.
Correspondingly, the present invention also provides a kind of manufacturing methods of OLED device, for manufacturing above-mentioned OLED device.It please join Fig. 2 is examined, is the flow diagram of the manufacturing method for the OLED device that one embodiment of the invention provides.As shown in Fig. 2, described The manufacturing method of OLED device includes:
Step S01:One substrate is provided, forms anode and organic layer on the substrate;
Step S02:Electron injecting layer is formed on the organic layer, the electron injecting layer is made of metal material, institute State the alloy that metal material is active metal or active metal and inert metal;
Step S03:Transparent cathode is formed on the electron injecting layer.
Shown in please referring to Fig.2, and Fig. 1 is combined, the manufacturing method for the OLED device that the present invention will be described in detail:
In step S01, a substrate 10 is provided, the substrate 10 is transparent substrate, for example, the substrate 10 can be glass Glass substrate.In other embodiments, the substrate 10 is not limited to glass substrate, can also be known to those skilled in the art Other materials.
Then anode 11 is formed on the substrate 10, and in the present embodiment, the method for sputtering may be used in the substrate Anode is formed on 10, in other embodiments, can also form the sun using other methods well known by persons skilled in the art Pole 11.Then organic layer 12 is formed on the anode 11.
In step S02, electron injecting layer 14 is formed on the organic layer 12, the electron injecting layer 14 is by magnesium and silver Alloy material be made.In the present embodiment, the electron injection is formed on the organic layer 12 by using the method for vapor deposition Layer 14, such as magnesium is carried out at the same time with silver and is vaporized on the alloy for forming magnesium and silver on the organic layer 12.
In the present embodiment, the thickness of the electron injecting layer 14 is 1nm~5nm;Such as 1nm, 2nm, 3nm, 4nm or 5nm, Preferably, the thickness of the electron injecting layer 14 is 2nm.Magnesium (Mg) and the mass ratio of silver-colored (Ag) are in the electron injecting layer 14 1:1~10:1, such as 2:1、4:1、6:1、8:1 or 10:1, it is preferred that magnesium (Mg) and silver-colored (Ag) in the electron injecting layer 14 Mass ratio is 4:1.
When the mass ratio that the thickness of the electron injecting layer 14 is 2nm, Mg and Ag is 4:When 1, compared to no magnesium and silver The device of electron injecting layer is made in alloy material, and voltage drops to 4.63V, light transmittance 74.82% from 10V.Described in adjusting When the thickness of electron injecting layer 14 is to 3nm, voltage 4.52V, light transmittance 64.95%;When adjusting the electron injecting layer 14 Thickness to 4nm when, voltage 4.39V, light transmittance 64.80%.
For OLED display screen, driving voltage is usually required that in 5V or less.For one piece 5 inches of OLED display screen, work Input current is about 200mA when making, and the voltage difference of 0.24V is away from the power consumption that can only cause 48mW, therefore voltage is 4.63V when 2nm It can ignore with the power consumption difference of voltage 4.39V when 4nm.But for light transmittance, some OLED application field industries have higher It is required that《Motor vehicle safe and technical specification》Wherein Sub_clause 11 provides:Automobile driving cabin must assure that field of front vision and side Glass does not allow to be less than for the visible transmission ratio at driver's vision area position other than the square visual field, windscreen and air regulator 70%.When replacing simple glass using transparent OLED device, light transmittance otherwise be less than 70%, 2nm and 4nm thickness pair at this time The influence of light transmittance be can not ignore.Therefore the thickness range of the electron injecting layer 14 requires between 1nm~5nm, preferably 2nm。
In step S03, transparent cathode 13 is formed on the electron injecting layer 14.In the present embodiment, transparent cathode 13 materials are transparent conductive material, such as can be ITO, ICO, SnO2Deng the method for sputtering may be used in the electron injection The transparent cathode 13 is formed on layer 14, in other embodiments, its other party well known by persons skilled in the art can also be used Method forms the ITO cathodes 13.
It is understood that further including in the present invention:Further include on the substrate 10 before forming the anode Back plane circuitry is formed, and is formed after the transparent cathode 13, passes through envelope on one side by what substrate 10 was formed with transparent cathode 13 Package material and a glass cover-plate fit, and due to belonging to the prior art, details are not described herein.
In conclusion transparent OLED device provided by the invention and its manufacturing method and display device, may be used ITO As anode and cathode, electron injecting layer is set between organic layer and cathode layer, is made of metal material electron injecting layer, The metal material avoids for the alloy of active metal or active metal and inert metal while improving light transmittance High voltage caused by the work content of bright conductive material is higher so that OLED device meets the needs of voltage and light transmittance simultaneously.
Foregoing description is only the description to present pre-ferred embodiments, not to any restriction of the scope of the invention, this hair Any change, the modification that the those of ordinary skill in bright field does according to the disclosure above content, belong to the protection of claims Range.

Claims (10)

1. a kind of OLED device, including substrate and anode, organic layer and cathode on the substrate are set gradually, feature It is, further includes electron injecting layer, between the organic layer and cathode;The cathode is made of transparent conductive material, institute It states electron injecting layer to be made of metal material, the metal material is the alloy of active metal or active metal and inert metal.
2. OLED device as described in claim 1, which is characterized in that the transparent conductive material is ITO, the electron injection Layer is the alloy of magnesium and silver.
3. OLED device as claimed in claim 1 or 2, which is characterized in that the thickness of the electron injecting layer is 1nm~5nm; The mass ratio of magnesium and silver is 1 in the electron injecting layer:1~10:1.
4. OLED device as claimed in claim 3, which is characterized in that the thickness of the electron injecting layer is 2nm;The electronics The mass ratio of magnesium and silver is 4 in implanted layer:1.
5. a kind of includes the organic light-emitting display device of Claims 1 to 4 any one of them OLED device.
6. a kind of manufacturing method of OLED device, which is characterized in that including:
One substrate is provided, forms anode and organic layer on the substrate;
Electron injecting layer is formed on the organic layer, the electron injecting layer is made of metal material, and the metal material is The alloy of active metal or active metal and inert metal;
Transparent cathode is formed on the electron injecting layer.
7. the manufacturing method of OLED device as claimed in claim 6, which is characterized in that the transparent cathode is ITO, the electricity Sub- implanted layer is the alloy of magnesium and silver.
8. the manufacturing method of OLED device as claimed in claims 6 or 7, which is characterized in that by the method for vapor deposition described The electron injecting layer is formed on organic layer;The transparent cathode is formed by the method for sputtering.
9. the manufacturing method of OLED device as claimed in claims 6 or 7, which is characterized in that the thickness of the electron injecting layer For 1nm~5nm;The mass ratio of magnesium and silver is 1 in the electron injecting layer:1~10:1.
10. the manufacturing method of OLED device as claimed in claim 9, which is characterized in that the thickness of the electron injecting layer is 2nm;The mass ratio of magnesium and silver is 4 in the electron injecting layer:1.
CN201710007623.5A 2017-01-05 2017-01-05 OLED device and its manufacturing method and display device Pending CN108281556A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11910691B2 (en) 2018-12-28 2024-02-20 Yungu (Gu'an) Technology Co., Ltd. Display panel, manufacturing method thereof, and display device

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1918948A (en) * 2004-02-16 2007-02-21 独立行政法人科学技术振兴机构 Light emitting transistor
CN102324463A (en) * 2011-09-09 2012-01-18 昆山维信诺显示技术有限公司 Preparation method of organic electroluminescence device
CN103794731A (en) * 2013-12-31 2014-05-14 北京维信诺科技有限公司 Organic light-emitting display device and organic light-emitting display thereof
CN104993068A (en) * 2014-12-18 2015-10-21 四川虹视显示技术有限公司 Manufacture method of semi-transparent OLED display device

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1918948A (en) * 2004-02-16 2007-02-21 独立行政法人科学技术振兴机构 Light emitting transistor
CN102324463A (en) * 2011-09-09 2012-01-18 昆山维信诺显示技术有限公司 Preparation method of organic electroluminescence device
CN103794731A (en) * 2013-12-31 2014-05-14 北京维信诺科技有限公司 Organic light-emitting display device and organic light-emitting display thereof
CN104993068A (en) * 2014-12-18 2015-10-21 四川虹视显示技术有限公司 Manufacture method of semi-transparent OLED display device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11910691B2 (en) 2018-12-28 2024-02-20 Yungu (Gu'an) Technology Co., Ltd. Display panel, manufacturing method thereof, and display device

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Application publication date: 20180713

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