CN108274774A - The molding preparation process of the co-curing of metal and composite flywheel - Google Patents
The molding preparation process of the co-curing of metal and composite flywheel Download PDFInfo
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- 239000002131 composite material Substances 0.000 title claims abstract description 31
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 30
- 239000002184 metal Substances 0.000 title claims abstract description 22
- 238000000465 moulding Methods 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- 238000000034 method Methods 0.000 claims abstract description 21
- 239000006260 foam Substances 0.000 claims description 18
- 229920002379 silicone rubber Polymers 0.000 claims description 12
- 239000002905 metal composite material Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 238000013461 design Methods 0.000 claims description 3
- 239000003292 glue Substances 0.000 claims description 3
- 239000012943 hotmelt Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 229910000831 Steel Inorganic materials 0.000 claims description 2
- 239000000741 silica gel Substances 0.000 claims description 2
- 229910002027 silica gel Inorganic materials 0.000 claims description 2
- 239000010959 steel Substances 0.000 claims description 2
- 238000007654 immersion Methods 0.000 claims 3
- 238000009833 condensation Methods 0.000 claims 1
- 230000005494 condensation Effects 0.000 claims 1
- 230000008878 coupling Effects 0.000 claims 1
- 238000010168 coupling process Methods 0.000 claims 1
- 238000005859 coupling reaction Methods 0.000 claims 1
- 229910052738 indium Inorganic materials 0.000 claims 1
- 239000007769 metal material Substances 0.000 abstract description 8
- 239000004945 silicone rubber Substances 0.000 description 10
- 239000010410 layer Substances 0.000 description 5
- 238000004146 energy storage Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000010354 integration Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
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- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
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- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
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- 239000002356 single layer Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/30—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/54—Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
- B29L2031/3097—Cosmonautical vehicles; Rockets
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Thermal Sciences (AREA)
- Moulding By Coating Moulds (AREA)
Abstract
一种金属与复合材料飞轮的共固化成型的制备工艺,通过将金属与复合材料共固化飞轮划分为五个区域并在成型模具相应区域分别根据各自铺层方式进行单向预浸料铺层且将环形预制体包裹,铺层完成后与金属轮缘扣合并经固化成型得到金属与复合材料飞轮。本发明能够满足飞轮对转动惯量误差、动平衡质量及高速旋转稳定性的要求。
A preparation process for the co-curing molding of a metal and composite material flywheel, by dividing the metal and composite material co-curing flywheel into five areas and performing unidirectional prepreg layup in the corresponding areas of the molding mold according to their respective layup methods and Wrap the annular prefabricated body, buckle with the metal rim after the layup is completed, and solidify and form to obtain a metal and composite material flywheel. The invention can meet the requirements of the flywheel on the error of the moment of inertia, the quality of dynamic balance and the stability of high-speed rotation.
Description
技术领域technical field
本发明涉及的是一种复合材料处理领域的技术,具体是一种金属与复合材料飞轮的共固化成型的制备工艺。The invention relates to a technique in the field of composite material processing, in particular to a preparation process for co-solidification molding of a metal and composite material flywheel.
背景技术Background technique
近年来,国外对卫星飞轮的研究主要集中在飞轮储能与姿控功能的集成方面,成功开发出了多种储能、姿控一体化飞轮;利用复合材料具有较大拉伸强度的特点,将CFRP材料通过缠绕法制成轮缘,大大提高了轮体的极限转速,使得飞轮的储能密度大为提高;同时,由于实现储能、姿控一体化,节约了大量星体空间和质量。In recent years, foreign research on satellite flywheels has mainly focused on the integration of flywheel energy storage and attitude control functions, and a variety of energy storage and attitude control integrated flywheels have been successfully developed; using composite materials with characteristics of greater tensile strength, The CFRP material is made into the wheel rim by winding method, which greatly increases the limit speed of the wheel body and greatly improves the energy storage density of the flywheel; at the same time, due to the integration of energy storage and attitude control, it saves a lot of star space and mass.
现有的复合材料和金属组合结构的飞轮中的复合材料作为轮辐起减重作用,外侧金属轮缘为机装可更换式。但由于不锈钢轮缘与碳纤维复合材料轮辐之间采用螺钉连接,连接可靠性差,动平衡性不足,特别是在高低温循环试验之后动平衡出现较大偏离。The composite material in the flywheel of the existing composite material and metal composite structure acts as a wheel spoke to reduce weight, and the outer metal wheel rim is machine-installed and replaceable. However, due to the screw connection between the stainless steel rim and the carbon fiber composite spoke, the connection reliability is poor and the dynamic balance is insufficient, especially after the high and low temperature cycle test, the dynamic balance deviates greatly.
现有的铝合金轮毂+碳纤维复合材料轮辐+不锈钢轮缘的改进结构中采用金属-复合材料全包式构型。虽然其轮缘与轮辐采用热紧配-胶接的混合连接模式,没有任何连接螺钉。但金属-复合材料胶接质量较差,肉眼可见的结构和表面质量不高,高低温试验之后动平衡发生了一定程度的漂移。The improved structure of the existing aluminum alloy wheel hub+carbon fiber composite material spoke+stainless steel rim adopts a metal-composite all-inclusive configuration. Although the rim and the spokes are connected in a heat-fitting-adhesive hybrid connection mode, there are no connecting screws. However, the bonding quality of the metal-composite material is poor, the structure and surface quality visible to the naked eye are not high, and the dynamic balance has drifted to a certain extent after the high and low temperature test.
发明内容Contents of the invention
本发明针对现有技术存在的上述不足,提出一种金属与复合材料飞轮的共固化成型的制备工艺,能够满足飞轮对转动惯量误差、动平衡质量及高速旋转稳定性的要求。Aiming at the above-mentioned deficiencies in the prior art, the present invention proposes a co-curing and molding preparation process of metal and composite material flywheels, which can meet the requirements of flywheels for moment of inertia error, dynamic balance quality and high-speed rotation stability.
本发明是通过以下技术方案实现的:The present invention is achieved through the following technical solutions:
本发明通过将金属与复合材料共固化飞轮划分为五个区域并在成型模具相应区域分别根据各自铺层方式进行单向预浸料铺层且将环形预制体包裹,铺层完成后与金属轮缘扣合并经固化成型得到金属与复合材料飞轮。In the present invention, the metal and composite material co-cured flywheel is divided into five areas, and the unidirectional prepreg is laid up in the corresponding areas of the molding mold according to the respective layup methods, and the annular prefabricated body is wrapped. After the layup is completed, it is combined with the metal wheel The metal and composite material flywheel is obtained by fastening the flange and curing and forming.
所述的成型模具是指金属-复合材料共固化飞轮成型模具方案,具体采用硅胶软模辅助+ 金属组合模具的结构形式,其中的金属模具包含:作为阴模的上瓣成型模具、作为阳模的下瓣成型模具。The forming mold refers to the metal-composite material co-curing flywheel forming mold scheme, which specifically adopts the structural form of a silicone soft mold auxiliary + metal combined mold, wherein the metal mold includes: an upper lobe forming mold as a female mold, and a male mold as a The lower flap forming mold.
所述的成型模具优选采用45号钢制成。The forming die is preferably made of No. 45 steel.
所述的五个区域是指:飞轮辐条泡沫区域、飞轮轮毂区域、飞轮辐条下蒙皮区域、飞轮辐条上蒙皮区域和飞轮轮缘区域。The five regions mentioned refer to: the foam region of the flywheel spoke, the hub region of the flywheel, the lower skin region of the flywheel spoke, the upper skin region of the flywheel spoke and the rim region of the flywheel.
所述的飞轮辐条泡沫区域、飞轮轮毂区域、飞轮辐条下蒙皮区域和飞轮轮缘区域采用各自对应的铺层方式进行单向预浸料铺层,不同区域之间需要进行交叉铺层以保证连接刚度与强度。The flywheel spoke foam area, the flywheel hub area, the flywheel spoke lower skin area and the flywheel rim area adopt their respective layup methods for unidirectional prepreg layup, and cross layup is required between different areas to ensure Connection stiffness and strength.
所述的飞轮辐条上蒙皮区域采用预制体单向预浸料包裹,当铺至接近泡沫的时候,贴近泡沫的层采用±45°铺层,然后将泡沫填入飞轮辐条泡沫区域中,然后再对飞轮辐条上蒙皮区域进行单向预浸料的铺覆,铺层延续至飞轮轮缘区域上。The upper skin area of the spokes of the flywheel is wrapped with a prefabricated unidirectional prepreg. When it is laid close to the foam, the layer close to the foam is laid at ±45°, and then the foam is filled into the foam area of the flywheel spokes, and then The unidirectional prepreg is applied to the skin area on the spokes of the flywheel, and the layup continues to the rim area of the flywheel.
所述的硅橡胶模,根据设计飞轮的数模要求选用R10301硅橡胶制备得到。The silicone rubber mold is prepared by selecting R10301 silicone rubber according to the digital model requirements of the designed flywheel.
所述的硅橡胶模,通过以下方式制备得到:首先将硅胶和固化剂组分混合后,室温下固化24h;固化完成后将硅橡胶模坯放入烘箱中进行热处理,热处理温度为150℃,保温6h。要求制完成的硅橡胶模的邵氏硬度为30~40,线膨胀系数为2.5~2.8×10-4/K。The silicone rubber mold is prepared in the following way: firstly, after mixing the silica gel and the curing agent component, curing at room temperature for 24 hours; Keep warm for 6 hours. The Shore hardness of the finished silicone rubber mold is required to be 30-40, and the coefficient of linear expansion is 2.5-2.8×10 -4 /K.
所述的轮毂预制体,通过以下方式制备得到:预先制备轮毂处环形预制体,铺层厚度 20mm,铺制完成后包覆吸胶并预压实,然后对预制体表面进行清理、修边,并测量厚度,对局部厚度偏差较大的区域进行修补得到。The wheel hub prefabricated body is prepared in the following manner: pre-preparing the annular prefabricated body at the wheel hub with a layer thickness of 20mm, after the paving is completed, it is coated with glue and pre-compacted, and then the surface of the prefabricated body is cleaned and trimmed. And measure the thickness, and repair the area with large local thickness deviation.
所述的固化成型是指:通过压力罐施加0.2MPa压力,温度保持在160℃,保温4小时。The curing molding refers to: apply a pressure of 0.2 MPa through a pressure tank, keep the temperature at 160° C., and keep the temperature for 4 hours.
所述的复合材料为M40JB/602热熔法预浸料。The composite material is M40JB/602 hot-melt prepreg.
本发明涉及一种通过上述方法制备得到的金属与复合材料飞轮,为金属与复合材料为整体共固化一体成型,可避免飞轮的动平衡漂移,成型面精度高,主要指标飞轮动不平衡质量<1gcm2;轮体转动惯量0.078±0.0015kg·m2;转速在±1500r/min范围内不发生颤振和失效。The invention relates to a metal and composite material flywheel prepared by the above method, which is integrally formed by co-curing the metal and the composite material, which can avoid the dynamic balance drift of the flywheel, has high precision of the forming surface, and the main index flywheel dynamic unbalance quality < 1gcm 2 ; moment of inertia of the wheel body 0.078±0.0015kg·m 2 ; chatter and failure will not occur within the range of ±1500r/min.
技术效果technical effect
与现有技术相比,本发明采用组合模具设计方案,并利用内腔软模辅助加压,从而提高飞轮复合材料相关型面的成型精度,避免后续对飞轮复合材料部分的机加工步骤;另外飞轮采用整体共固化一体成型,采用内腔软模辅助加压,在高温的状态下使复合材料与金属一体成型,可以保证粘接面的性能,可避免飞轮的动平衡漂移。同时本发明可使复合材料固化完全,保证在真空条件下无挥发物,满足其适应太空工作环境要求。Compared with the prior art, the present invention adopts the combined mold design scheme, and utilizes the inner cavity soft mold to assist pressurization, thereby improving the forming accuracy of the relevant profiles of the flywheel composite material and avoiding subsequent machining steps for the flywheel composite material part; in addition The flywheel adopts integral co-curing and integral molding, and the inner cavity soft mold is used to assist pressurization. The composite material and metal are integrally formed at high temperature, which can ensure the performance of the bonding surface and avoid the dynamic balance drift of the flywheel. Simultaneously, the invention can completely solidify the composite material, ensure that there is no volatile matter under the vacuum condition, and meet the requirement of adapting to the space working environment.
附图说明Description of drawings
图1为本发明金属-复合材料共固化飞轮结构示意图;Fig. 1 is the structure schematic diagram of metal-composite co-cured flywheel of the present invention;
图中:101复合材料辐条、102金属轮毂、103金属轮缘;In the picture: 101 composite material spokes, 102 metal hubs, 103 metal rims;
图2A和图2B为本发明复合材料铺层示意图;Fig. 2A and Fig. 2B are the schematic diagrams of composite material layup of the present invention;
图中:201飞轮辐条泡沫区域、202飞轮轮毂区域、203飞轮辐条下蒙皮区域、204飞轮辐条上蒙皮区域、205飞轮轮缘区域;In the picture: 201 flywheel spoke foam area, 202 flywheel hub area, 203 flywheel spoke lower skin area, 204 flywheel spoke upper skin area, 205 flywheel rim area;
图3A为辐条铺层方式,图3B为蒙皮和轮辐接触处铺层方式,图3C为轮辐与轮缘接触面处铺层方式示意图。Fig. 3A is the layering method of the spokes, Fig. 3B is the layering method of the contact between the skin and the spokes, and Fig. 3C is a schematic diagram of the layering method at the contact surface of the spokes and the rim.
具体实施方式Detailed ways
本实施例包括以下步骤:This embodiment includes the following steps:
步骤1)原材料采用M40JB/602热熔法预浸料,单层厚度0.1mm。按铺层设计进行下料排版,排版要求尺寸准确,保证预浸料具有较高的利用率。Step 1) The raw material is M40JB/602 hot-melt prepreg with a single layer thickness of 0.1mm. According to the design of the layup, the blanking and layout are carried out, and the layout requires accurate dimensions to ensure a high utilization rate of the prepreg.
步骤2)硅橡胶选用R10301硅橡胶。硅橡胶软膜制备过程中,首先将硅橡胶A、B组分混合后,室温下固化24h;固化完成后将硅橡胶模坯放入烘箱中进行热处理,热处理温度为150℃,保温6h。要求制完成的硅橡胶模的邵氏硬度为30~40,线膨胀系数为2.5~2.8×10-4/K。Step 2) The silicone rubber is R10301 silicone rubber. In the preparation process of the silicone rubber soft film, first mix the silicone rubber components A and B, and then cure at room temperature for 24 hours; after curing, put the silicone rubber mold blank in an oven for heat treatment at 150°C and keep it warm for 6 hours. The Shore hardness of the completed silicone rubber mold is required to be 30-40, and the coefficient of linear expansion is 2.5-2.8×10-4/K.
步骤3)预先制备轮毂处环形预制体,铺层厚度20mm,铺制完成后包覆吸胶并预压实。而后,对预制体表面进行清理、修边,并测量厚度,对局部厚度偏差较大的区域进行修补,完成后将预制体放置待用。Step 3) Pre-preparing the annular prefabricated body at the hub, with a layer thickness of 20mm. After the laying is completed, it is coated with glue and pre-compacted. Then, the surface of the prefabricated body is cleaned, trimmed, and the thickness is measured, and the area with a large local thickness deviation is repaired. After completion, the prefabricated body is placed for use.
步骤4)如图3A~图3C所示,首先在成型阳模上对飞轮辐条泡沫区域201、飞轮轮毂区域202、飞轮辐条下蒙皮区域203、飞轮轮缘区域205根据各自铺层方式进行单向预浸料铺层,不同区域之间需要进行交叉铺层以保证连接刚度与强度,轮毂区域需要将预制体用单向预浸料包裹;当铺至接近泡沫的时候,贴近泡沫的层采用±45°铺层,然后将泡沫填入模具的飞轮辐条泡沫区域201中。之后对飞轮辐条上蒙皮区域204、进行单向预浸料的铺覆,铺层延续至飞轮轮缘区域205上。Step 4) As shown in Figures 3A to 3C, first, on the forming male mold, the flywheel spoke foam area 201, the flywheel hub area 202, the flywheel spoke lower skin area 203, and the flywheel rim area 205 are individually layered according to their respective laying methods. When laying layers to the prepreg, different areas need to be cross-laminated to ensure the stiffness and strength of the connection. The hub area needs to wrap the prefabricated body with unidirectional prepreg; when laying close to the foam, the layer close to the foam should be ± 45° layup and then foam fill in the flywheel spoke foam area 201 of the mold. Afterwards, the upper skin area 204 of the flywheel spoke is covered with unidirectional prepreg, and the layup continues to the flywheel rim area 205 .
步骤5)将机加工完成的金属轮缘扣在下瓣成型模具上,保证金属轮缘与轮缘内侧的复合材料接触面有一定的压力以使金属和复合材料充分接触,排出气泡。而后,扣上阴模,完成模具工装。Step 5) Buckle the machined metal rim on the lower lobe forming mold to ensure that the contact surface between the metal rim and the composite material inside the rim has a certain pressure so that the metal and the composite material are in full contact and air bubbles are discharged. Then, buckle the female mold to complete the mold tooling.
步骤6)将共固化飞轮整体置于压力罐中,施加0.2MPa压力,温度保持在160℃,保温 4小时。Step 6) Place the co-cured flywheel as a whole in a pressure tank, apply a pressure of 0.2MPa, keep the temperature at 160°C, and keep it warm for 4 hours.
步骤7)产品脱模后,打磨产品边缘飞边,测量产品基本尺寸,送探伤。Step 7) After the product is demoulded, polish the edge flash of the product, measure the basic size of the product, and send it for flaw detection.
本实施例通过上述方法制备得到的产品的实验参数、技术指标、功能效果为:飞轮动不平衡质量<1gcm2;轮体转动惯量0.078±0.0015kg·m2;转速在±1500r/min范围内不发生颤振和失效。轮体的一阶固有频率不小于180Hz。金属与复合材料为整体共固化一体成型,可避免飞轮的动平衡漂移,成型面精度高。The experimental parameters, technical indicators and functional effects of the product prepared by the above method in this embodiment are: flywheel dynamic unbalanced mass<1gcm2; wheel body moment of inertia 0.078±0.0015kg· m2 ; Flutter and failure occurs. The first-order natural frequency of the wheel body is not less than 180Hz. The metal and the composite material are integrally co-cured and integrally formed, which can avoid the dynamic balance drift of the flywheel, and the precision of the forming surface is high.
上述具体实施可由本领域技术人员在不背离本发明原理和宗旨的前提下以不同的方式对其进行局部调整,本发明的保护范围以权利要求书为准且不由上述具体实施所限,在其范围内的各个实现方案均受本发明之约束。The above specific implementation can be partially adjusted in different ways by those skilled in the art without departing from the principle and purpose of the present invention. The scope of protection of the present invention is subject to the claims and is not limited by the above specific implementation. Each implementation within the scope is bound by the invention.
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