CN108264973A - It is a kind of using natural plant essential oils as detergent of preservative and preparation method thereof - Google Patents
It is a kind of using natural plant essential oils as detergent of preservative and preparation method thereof Download PDFInfo
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- CN108264973A CN108264973A CN201611251743.1A CN201611251743A CN108264973A CN 108264973 A CN108264973 A CN 108264973A CN 201611251743 A CN201611251743 A CN 201611251743A CN 108264973 A CN108264973 A CN 108264973A
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- essential oil
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- 239000000341 volatile oil Substances 0.000 title claims abstract description 115
- 239000003599 detergent Substances 0.000 title claims abstract description 29
- 239000003755 preservative agent Substances 0.000 title claims abstract description 24
- 230000002335 preservative effect Effects 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 241000196324 Embryophyta Species 0.000 claims abstract description 45
- 239000002994 raw material Substances 0.000 claims abstract description 27
- 239000000203 mixture Substances 0.000 claims abstract description 24
- 230000002421 anti-septic effect Effects 0.000 claims abstract description 16
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 14
- 240000000560 Citrus x paradisi Species 0.000 claims abstract description 12
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 12
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 11
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 11
- 235000009024 Ceanothus sanguineus Nutrition 0.000 claims abstract description 10
- 240000003553 Leptospermum scoparium Species 0.000 claims abstract description 10
- 235000015459 Lycium barbarum Nutrition 0.000 claims abstract description 10
- 235000009051 Ambrosia paniculata var. peruviana Nutrition 0.000 claims abstract description 9
- 235000003097 Artemisia absinthium Nutrition 0.000 claims abstract description 9
- 240000001851 Artemisia dracunculus Species 0.000 claims abstract description 9
- 235000017731 Artemisia dracunculus ssp. dracunculus Nutrition 0.000 claims abstract description 9
- 235000003261 Artemisia vulgaris Nutrition 0.000 claims abstract description 9
- 235000008632 Santalum album Nutrition 0.000 claims abstract description 9
- 239000001138 artemisia absinthium Substances 0.000 claims abstract description 9
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims abstract description 9
- 235000007866 Chamaemelum nobile Nutrition 0.000 claims abstract description 8
- 244000042664 Matricaria chamomilla Species 0.000 claims abstract description 8
- 235000007232 Matricaria chamomilla Nutrition 0.000 claims abstract description 8
- 239000000654 additive Substances 0.000 claims abstract description 4
- 240000000513 Santalum album Species 0.000 claims abstract 3
- -1 alkyl glucoside Chemical class 0.000 claims description 18
- 239000008367 deionised water Substances 0.000 claims description 16
- 229910021641 deionized water Inorganic materials 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 108700004121 sarkosyl Proteins 0.000 claims description 9
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 claims description 9
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical group [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 claims description 9
- MSWZFWKMSRAUBD-IVMDWMLBSA-N 2-amino-2-deoxy-D-glucopyranose Chemical compound N[C@H]1C(O)O[C@H](CO)[C@@H](O)[C@@H]1O MSWZFWKMSRAUBD-IVMDWMLBSA-N 0.000 claims description 6
- MSWZFWKMSRAUBD-UHFFFAOYSA-N beta-D-galactosamine Natural products NC1C(O)OC(CO)C(O)C1O MSWZFWKMSRAUBD-UHFFFAOYSA-N 0.000 claims description 6
- 150000002191 fatty alcohols Chemical class 0.000 claims description 6
- 229960002442 glucosamine Drugs 0.000 claims description 6
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 6
- 239000008820 moutan cortex Substances 0.000 claims description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 5
- ZPFAVCIQZKRBGF-UHFFFAOYSA-N 1,3,2-dioxathiolane 2,2-dioxide Chemical compound O=S1(=O)OCCO1 ZPFAVCIQZKRBGF-UHFFFAOYSA-N 0.000 claims description 4
- 239000012752 auxiliary agent Substances 0.000 claims description 4
- DAZXVJBJRMWXJP-UHFFFAOYSA-N n,n-dimethylethylamine Chemical compound CCN(C)C DAZXVJBJRMWXJP-UHFFFAOYSA-N 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 229920002125 Sokalan® Polymers 0.000 claims description 2
- 241000894007 species Species 0.000 claims 2
- 229930182478 glucoside Natural products 0.000 claims 1
- 238000002474 experimental method Methods 0.000 abstract description 8
- 238000011156 evaluation Methods 0.000 abstract description 5
- 230000000813 microbial effect Effects 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 239000002537 cosmetic Substances 0.000 abstract description 3
- 239000003205 fragrance Substances 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 230000014759 maintenance of location Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract 1
- 230000002906 microbiologic effect Effects 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 16
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 14
- 230000000844 anti-bacterial effect Effects 0.000 description 11
- 229930182470 glycoside Natural products 0.000 description 8
- 239000011780 sodium chloride Substances 0.000 description 8
- 241000894006 Bacteria Species 0.000 description 7
- 229960003237 betaine Drugs 0.000 description 7
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 7
- 241000221035 Santalaceae Species 0.000 description 6
- 239000000126 substance Substances 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 3
- 230000036039 immunity Effects 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- WRYLYDPHFGVWKC-UHFFFAOYSA-N 4-terpineol Chemical compound CC(C)C1(O)CCC(C)=CC1 WRYLYDPHFGVWKC-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- UILPJVPSNHJFIK-UHFFFAOYSA-N Paeonol Chemical compound COC1=CC=C(C(C)=O)C(O)=C1 UILPJVPSNHJFIK-UHFFFAOYSA-N 0.000 description 2
- 241000194017 Streptococcus Species 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- WRYLYDPHFGVWKC-SNVBAGLBSA-N 4-Terpineol Natural products CC(C)[C@]1(O)CCC(C)=CC1 WRYLYDPHFGVWKC-SNVBAGLBSA-N 0.000 description 1
- 241000193738 Bacillus anthracis Species 0.000 description 1
- 241000222122 Candida albicans Species 0.000 description 1
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 1
- 241000588769 Proteus <enterobacteria> Species 0.000 description 1
- 241000589517 Pseudomonas aeruginosa Species 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 229930003268 Vitamin C Natural products 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 230000003110 anti-inflammatory effect Effects 0.000 description 1
- 229940065181 bacillus anthracis Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 238000012258 culturing Methods 0.000 description 1
- RHZNQEWFWUODFC-UHFFFAOYSA-N ethyl(dimethyl)azanium;ethyl sulfate Chemical compound CC[NH+](C)C.CCOS([O-])(=O)=O RHZNQEWFWUODFC-UHFFFAOYSA-N 0.000 description 1
- 210000000987 immune system Anatomy 0.000 description 1
- YLTGFGDODHXMFB-UHFFFAOYSA-N isoacetovanillon Natural products COC1=CC=C(C(C)=O)C=C1O YLTGFGDODHXMFB-UHFFFAOYSA-N 0.000 description 1
- 238000012009 microbiological test Methods 0.000 description 1
- 231100000344 non-irritating Toxicity 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- MLIBGOFSXXWRIY-UHFFFAOYSA-N paeonol Natural products COC1=CC=C(O)C(C(C)=O)=C1 MLIBGOFSXXWRIY-UHFFFAOYSA-N 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
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- Agricultural Chemicals And Associated Chemicals (AREA)
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Abstract
本发明提供了一种以天然植物精油为防腐剂的洗涤剂及其制备方法，制备所述洗涤剂的原料包括阴离子表面活性剂、阳离子表面活性剂、非离子表面活性剂、两性表面活性剂、无机盐、助剂、天然植物精油。其中，所述的精油包括艾草精油、牡丹皮精油、洋甘菊精油、茶树精油、檀香精油、葡萄柚精油、罗文莎叶精油中的一种或几种的混合物。本发明所述的洗涤剂中，将天然的植物精油作以防腐剂和留香剂，并按照《微生物挑战实验对化妆品的防腐效果评价》中微生物挑战实验的操作方法进行了防腐测试，证实有很强的防腐效果。The invention provides a detergent with natural plant essential oil as a preservative and a preparation method thereof. The raw materials for preparing the detergent include anionic surfactants, cationic surfactants, nonionic surfactants, amphoteric surfactants, Inorganic salts, additives, natural plant essential oils. Wherein, the essential oil includes one or a mixture of wormwood essential oil, moutan essential oil, chamomile essential oil, tea tree essential oil, sandalwood essential oil, grapefruit essential oil, and Ravensah leaf essential oil. In the detergent of the present invention, the natural plant essential oil is used as preservative and fragrance retention agent, and the antiseptic test is carried out according to the operation method of the microbial challenge experiment in "Evaluation of Antiseptic Effect of Cosmetics by Microbiological Challenge Experiment", and it is confirmed that there is Strong anti-corrosion effect.
Description
技术领域technical field
本发明属于洗涤剂组合物领域，特别涉及一种以天然植物精油为防腐剂的洗涤剂及其制备方法。The invention belongs to the field of detergent compositions, in particular to a detergent using natural plant essential oil as a preservative and a preparation method thereof.
背景技术Background technique
目前随着人们文化水平、消费水平的逐渐提升，对自身身体健康，环境保护意识的增强，对产品的要求也越来越高，不仅在产品的使用性能上，更注重产品的安全性，环保性。这就促使生产企业，在源头上要控制产品的安全性、环保性。对日化行业来说，在产品中使用的原料越少、原料越天然，那么产品就越安全、越环保。所有的产品都有一个货架期，在整个货架期内要保证产品不生菌，不腐败，都需要添加一定量的防腐剂，大家都知道防腐剂会对人的有一定的负作用，因此，目前急需一种天然防腐剂。At present, with the gradual improvement of people's cultural level and consumption level, the awareness of their own health and environmental protection is enhanced, and the requirements for products are getting higher and higher. Not only in terms of product performance, but also pay more attention to product safety and environmental protection. sex. This prompts production companies to control the safety and environmental protection of products at the source. For the daily chemical industry, the fewer and more natural raw materials used in products, the safer and more environmentally friendly the products will be. All products have a shelf life. In order to ensure that the product is free from bacteria and corruption throughout the shelf life, it is necessary to add a certain amount of preservatives. Everyone knows that preservatives will have certain negative effects on people. Therefore, There is an urgent need for a natural preservative.
发明内容Contents of the invention
针对上述存在的问题，本发明的提供了一种以天然植物精油为防腐剂的洗涤剂及其制备方法。本发明所述的洗涤剂中，将天然的植物精油作以防腐剂和留香剂，所使用的这些植物精油具有抗菌抑菌、提高免疫力、无刺激性、呵护家人健康。To solve the above problems, the present invention provides a detergent with natural plant essential oil as a preservative and a preparation method thereof. In the detergent of the present invention, natural plant essential oils are used as preservatives and fragrance retention agents, and these plant essential oils used have the functions of antibacterial and antibacterial, improving immunity, non-irritating, and caring for the health of family members.
本发明的目的是通过以下技术方案实现的：The purpose of the present invention is achieved through the following technical solutions:
一种天然植物精油的应用，所述天然植物精油作为防腐剂应用于洗涤产品中；所述天然植物精油包括艾草精油、牡丹皮精油、洋甘菊精油、茶树精油、檀香精油、葡萄柚精油、罗文莎叶精油中的一种或几种的混合物。A kind of application of natural plant essential oil, described natural plant essential oil is used in washing product as preservative; Described natural plant essential oil comprises wormwood essential oil, moutan cortex essential oil, chamomile essential oil, tea tree essential oil, sandalwood essential oil, grapefruit essential oil, One or a mixture of Ravensah leaf essential oils.
一种以天然植物精油为防腐剂的洗涤剂，制备所述洗涤剂的原料包括阴离子表面活性剂、非离子表面活性剂、两性表面活性剂、无机盐、助剂、天然植物精油，各原料的重量份数比为：A kind of detergent that takes natural plant essential oil as antiseptic, the raw material of preparation described detergent comprises anionic surfactant, nonionic surfactant, amphoteric surfactant, inorganic salt, auxiliary agent, natural plant essential oil, each raw material The ratio of parts by weight is:
阴离子表面活性剂 3.0~30Anionic surfactant 3.0~30
非离子表面活性剂 8~25Nonionic surfactant 8~25
两性表面活性剂 3~13Amphoteric surfactant 3~13
无机盐 0.1-3.5Inorganic salt 0.1-3.5
助剂 0.5~5Auxiliary 0.5~5
天然植物精油 0.5~2.5Natural plant essential oil 0.5~2.5
去离子水 21-85。Deionized water 21-85.
进一步的，所述原料还包括阳离子表面活性剂，其重量份数比为：Further, the raw material also includes a cationic surfactant, and its weight and number ratio is:
阳离子表面活性剂 0.3-2。Cationic surfactant 0.3-2.
进一步的，所述的阴离子表面活性剂为月桂酰肌氨酸钠。Further, the anionic surfactant is sodium lauroyl sarcosinate.
进一步的，所述阳离子表面活性剂为亚油酰胺丙基乙基二甲基铵乙基硫酸钠。Further, the cationic surfactant is sodium linoleamidopropyl ethyl dimethyl ammonium ethosulfate.
进一步的，所述的非离子表面活性剂包括烷基糖苷、脂肪醇聚氧乙烯醚和葡糖胺中的一种或几种的混合物。Further, the nonionic surfactant includes one or a mixture of alkyl glycosides, fatty alcohol polyoxyethylene ethers and glucosamine.
进一步的，所述的两性表面活性剂为月桂酰胺丙基二甲基甜菜碱。Further, the amphoteric surfactant is lauryl amidopropyl dimethyl betaine.
进一步的，所述的助剂为丙烯酸聚合物。Further, the auxiliary agent is an acrylic acid polymer.
进一步的，所述的无机盐为氯化钠。Further, the inorganic salt is sodium chloride.
进一步的，所述天然植物精油包括艾草精油、牡丹皮精油、洋甘菊精油、茶树精油、檀香精油、葡萄柚精油、罗文莎叶精油中的一种或几种的混合物。Further, the natural plant essential oils include one or a mixture of wormwood essential oil, moutan essential oil, chamomile essential oil, tea tree essential oil, sandalwood essential oil, grapefruit essential oil, and Ravensah leaf essential oil.
葡萄柚精油：葡萄柚精油含有高浓度的维生素C，双氢黄酮类化合物，因而对免疫系统非常有利用价值，可以提高免疫力，起到抗菌抑菌的作用；Grapefruit essential oil: Grapefruit essential oil contains high concentrations of vitamin C and dihydroflavonoids, so it is very useful for the immune system, can improve immunity, and has antibacterial and antibacterial effects;
茶树精油里的主要成分4-松油醇具有很强的杀菌、消毒、抗菌、抑菌、防腐的功效；The main component of tea tree essential oil, 4-terpineol, has strong sterilization, disinfection, antibacterial, antibacterial and antiseptic effects;
牡丹皮精油：牡丹皮中的丹皮酚是抗菌的主要成分，有实验研究牡丹皮精油对金黄色葡萄球菌、白色念珠菌、绿脓杆菌、炭疽杆菌、变形杆菌、甲型链球菌、乙型链球菌均有很好的抑菌作用；Moutan Cortex Essential Oil: Paeonol in Moutan Cortex is the main antibacterial component. There are experimental studies on the effect of Moutan Cortex Essential Oil on Staphylococcus aureus, Candida albicans, Pseudomonas aeruginosa, Bacillus anthracis, Proteus, Streptococcus type A, and Type B bacteria. Streptococcus has a good antibacterial effect;
檀香精油：檀香精油具有消炎、抑菌的功效。Sandalwood essential oil: Sandalwood essential oil has anti-inflammatory and antibacterial effects.
所述的以天然植物精油为防腐剂的洗涤剂的制备方法，所述制备方法包括以下步骤：Described take natural plant essential oil as the preparation method of the detergent of antiseptic, described preparation method comprises the following steps:
1）预先将天然植物精油与非离子表面活性剂按同等比例进行乳化，得到混合物A；1) Pre-emulsify natural plant essential oils and nonionic surfactants in the same proportion to obtain mixture A;
2）在反应釜中添加40%~50%的50℃～60℃的去离子水，按顺序依次加入阴离子表面活性剂、剩余的非离子表面活性剂、两性表面活性剂和助剂，边加入边搅拌，混合均匀即得到混合物B；2) Add 40%~50% deionized water at 50℃~60℃ to the reaction kettle, add anionic surfactants, remaining nonionic surfactants, amphoteric surfactants and additives in sequence, while adding While stirring, mix evenly to obtain mixture B;
3）待温度降到40℃以下时，将混合物A、阳离子表面活性剂和剩余的去离子水加入混合物B中，搅拌均匀，过滤，静置，即得到所述的以天然植物精油为防腐剂的洗涤剂。3) When the temperature drops below 40°C, add the mixture A, cationic surfactant and the remaining deionized water to the mixture B, stir evenly, filter, and let stand to obtain the natural plant essential oil as preservative detergent.
本发明所述的以天然植物精油为防腐剂的洗涤剂相比现有技术的有益效果为：Compared with the beneficial effects of the prior art, the detergent with natural plant essential oil as preservative of the present invention is:
1、本发明首次公开了将天然植物精油作为防腐剂使用，添加到洗涤产品中，代替了目前使用的化学防腐剂，对消费者来说，避免了化学防腐剂的侵害，保护身体健康，对生产企业来说可以降低成本，保护环境，同时天然植物精油具有留香作用，同时可以起到消除异味的作用，并留下淡淡的清香味；1. The present invention discloses for the first time that natural plant essential oils are used as preservatives and added to washing products to replace the currently used chemical preservatives. For consumers, it avoids the damage of chemical preservatives and protects their health. For production enterprises, it can reduce costs and protect the environment. At the same time, natural plant essential oils have a fragrance-retaining effect, and can also eliminate odors and leave a light fragrance;
2、本发明所述的以天然植物精油为防腐剂的洗涤剂，所使用的天然植物精油艾草精油、牡丹皮精油、洋甘菊精油、茶树精油、檀香精油、葡萄柚精油、罗文莎叶精油，这些植物精油具有抗菌抑菌、提高免疫力、呵护家人健康。2, the detergent of the present invention with natural plant essential oil as preservative, used natural plant essential oil Wormwood essential oil, moutan cortex essential oil, chamomile essential oil, tea tree essential oil, sandalwood essential oil, grapefruit essential oil, Ravensah leaf essential oil, These plant essential oils have antibacterial and antibacterial properties, improve immunity, and care for family health.
具体实施方式Detailed ways
实施例1Example 1
本实施例提供了一种以天然植物精油为防腐剂的洗涤剂，所用各原料的重量份数比如下：The present embodiment provides a kind of detergent with natural plant essential oil as preservative, and the parts by weight ratio of each raw material used is as follows:
阴离子表面活性剂 3.0~30Anionic surfactant 3.0~30
非离子表面活性剂 8~25Nonionic surfactant 8~25
两性表面活性剂 3~13Amphoteric surfactant 3~13
无机盐 0.1-3.5Inorganic salt 0.1-3.5
助剂 0.5~5Auxiliary 0.5~5
天然植物精油 0.5~2.5Natural plant essential oil 0.5~2.5
去离子水 21-85。Deionized water 21-85.
进一步的，所述原料还包括阳离子表面活性剂，其重量份数比为：Further, the raw material also includes a cationic surfactant, and its weight and number ratio is:
阳离子表面活性剂 0.3-2。Cationic surfactant 0.3-2.
进一步的，所述天然植物精油包括艾草精油、牡丹皮精油、洋甘菊精油、茶树精油、檀香精油、葡萄柚精油、罗文莎叶精油中的一种或几种的混合物。Further, the natural plant essential oils include one or a mixture of wormwood essential oil, moutan essential oil, chamomile essential oil, tea tree essential oil, sandalwood essential oil, grapefruit essential oil, and Ravensah leaf essential oil.
所述的以天然植物精油为防腐剂的洗涤剂的制备方法，所述制备方法包括以下步骤：Described take natural plant essential oil as the preparation method of the detergent of antiseptic, described preparation method comprises the following steps:
1）预先将天然植物精油与非离子表面活性剂按同等比例进行乳化，得到混合物A；1) Pre-emulsify natural plant essential oils and nonionic surfactants in the same proportion to obtain mixture A;
2）在反应釜中添加40%的50℃～60℃的去离子水，按顺序依次加入阴离子表面活性剂、剩余的非离子表面活性剂、两性表面活性剂和助剂，边加入边搅拌，混合均匀即得到混合物B；2) Add 40% deionized water at 50°C to 60°C in the reaction kettle, add anionic surfactants, remaining nonionic surfactants, amphoteric surfactants and additives in sequence, and stir while adding, Mix evenly to obtain mixture B;
3）待温度降到40℃以下时，将混合物A、阳离子表面活性剂和剩余的去离子水加入混合物B中，搅拌均匀，过滤，静置，即得到所述的以天然植物精油为防腐剂的洗涤剂。3) When the temperature drops below 40°C, add the mixture A, cationic surfactant and the remaining deionized water to the mixture B, stir evenly, filter, and let stand to obtain the natural plant essential oil as preservative detergent.
本实施例所用重量单位为千克，也可以为克；The weight unit used in this embodiment is kilogram, also can be gram;
本实施例中所述各个原料均为工业级；Each raw material described in the present embodiment is industrial grade;
本实施例中所述的各原料均为市场上出售的常规产品；Each raw material described in the present embodiment is the conventional product sold on the market;
本实施例中，所述的各个原料可以在给出的配比范围内灵活组合，在此不一一枚举。In this embodiment, the various raw materials mentioned above can be combined flexibly within the given proportioning range, which will not be enumerated here.
实施例2Example 2
本实施例是在实施例1基础上的优选方案，所用原料的品质与实施例1相同，所用各原料的重量份数比如下：This embodiment is a preferred scheme based on Example 1, the quality of the raw materials used is the same as that of Example 1, and the parts by weight of each raw material used are as follows:
月桂酰肌氨酸钠 8Sodium Lauroyl Sarcosinate 8
烷基糖苷 12Alkyl glycosides 12
亚油酰胺丙基乙基二甲基铵乙基硫酸钠 0.5Sodium Linoleamidopropyl Ethyl Dimethyl Ammonium Ethyl Sulfate 0.5
月桂酰胺丙基二甲基甜菜碱 9Lauramidopropyl Dimethyl Betaine 9
丙烯酸聚合物 1Acrylic polymer 1
葡萄柚精油 0.8Grapefruit essential oil 0.8
氯化钠 3.5Sodium chloride 3.5
去离子水 65.2。Deionized water 65.2.
实施例3Example 3
本实施例是在实施例1基础上的优选方案，所用原料的品质与实施例1相同，所用各原料的重量份数比如下：This embodiment is a preferred scheme based on Example 1, the quality of the raw materials used is the same as that of Example 1, and the parts by weight of each raw material used are as follows:
月桂酰肌氨酸钠 10Sodium Lauroyl Sarcosinate 10
烷基糖苷 6Alkyl glycoside 6
脂肪醇聚氧乙烯醚 5Fatty alcohol polyoxyethylene ether 5
亚油酰胺丙基乙基二甲基铵乙基硫酸盐 1.5Linoleamidopropyl ethyl dimethyl ammonium ethosulfate 1.5
月桂酰胺丙基二甲基甜菜碱 12Lauramidopropyl Dimethyl Betaine 12
丙烯酸聚合物 1.0Acrylic Polymer 1.0
艾草精油 0.5Wormwood essential oil 0.5
牡丹皮精油 0.5Moutan Bark Essential Oil 0.5
氯化钠 2.0Sodium chloride 2.0
去离子水 61.5。Deionized water 61.5.
实施例4Example 4
本实施例是在实施例1基础上的优选方案，所用原料的品质与实施例1相同，所用各原料的重量份数比如下：This embodiment is a preferred scheme based on Example 1, the quality of the raw materials used is the same as that of Example 1, and the parts by weight of each raw material used are as follows:
月桂酰肌氨酸钠 15Sodium Lauroyl Sarcosinate 15
烷基糖苷 5Alkyl glycoside 5
脂肪醇聚氧乙烯醚 4Fatty alcohol polyoxyethylene ether 4
亚油酰胺丙基乙基二甲基铵乙基硫酸盐 2Linoleamidopropyl ethyl dimethyl ammonium ethosulfate 2
月桂酰胺丙基二甲基甜菜碱 8Lauramidopropyl Dimethyl Betaine 8
丙烯酸聚合物 3Acrylic polymer 3
茶树精油 0.8Tea tree essential oil 0.8
氯化钠 2.5Sodium chloride 2.5
去离子水 59.7。Deionized water 59.7.
实施例5Example 5
本实施例是在实施例1基础上的优选方案，所用原料的品质与实施例1相同，所用各原料的重量份数比如下：This embodiment is a preferred scheme based on Example 1, the quality of the raw materials used is the same as that of Example 1, and the parts by weight of each raw material used are as follows:
月桂酰肌氨酸钠 9Sodium Lauroyl Sarcosinate 9
烷基糖苷 6Alkyl glycoside 6
脂肪醇聚氧乙烯醚 5Fatty alcohol polyoxyethylene ether 5
月桂酰胺丙基二甲基甜菜碱 8Lauramidopropyl Dimethyl Betaine 8
葡萄胺 6Glucosamine 6
葡萄柚精油 0.8Grapefruit essential oil 0.8
氯化钠 3.0Sodium chloride 3.0
去离子水 62.2。Deionized water 62.2.
实施例6Example 6
本实施例是在实施例1基础上的优选方案，所用原料的品质与实施例1相同，所用各原料的重量份数比如下：This embodiment is a preferred scheme based on Example 1, the quality of the raw materials used is the same as that of Example 1, and the parts by weight of each raw material used are as follows:
月桂酰肌氨酸钠 10Sodium Lauroyl Sarcosinate 10
烷基糖苷 4Alkyl Glycoside 4
脂肪醇聚氧乙烯醚 5Fatty alcohol polyoxyethylene ether 5
月桂酰胺丙基二甲基甜菜碱 6Lauramidopropyl Dimethyl Betaine 6
葡糖胺 8Glucosamine 8
牡丹皮精油 0.8Moutan Bark Essential Oil 0.8
茶树精油 0.3Tea tree essential oil 0.3
氯化钠 1.8Sodium chloride 1.8
去离子水 64.1。Deionized water 64.1.
实施例7Example 7
本实施例是在实施例1基础上的优选方案，所用原料的品质与实施例1相同，所用各原料的重量份数比如下：This embodiment is a preferred scheme based on Example 1, the quality of the raw materials used is the same as that of Example 1, and the parts by weight of each raw material used are as follows:
月桂酰肌氨酸钠 30Sodium Lauroyl Sarcosinate 30
烷基糖苷 22Alkyl glycosides 22
月桂酰胺丙基二甲基甜菜碱 10Lauramidopropyl Dimethyl Betaine 10
葡糖胺 8Glucosamine 8
洋甘菊精油 0.8Chamomile essential oil 0.8
葡萄柚精油 0.3Grapefruit essential oil 0.3
氯化钠 2.2Sodium chloride 2.2
去离子水 26.7。Deionized water 26.7.
实施例8Example 8
本实施例是在实施例1基础上的优选方案，所用原料的品质与实施例1相同，所用各原料的重量份数比如下：This embodiment is a preferred scheme based on Example 1, the quality of the raw materials used is the same as that of Example 1, and the parts by weight of each raw material used are as follows:
月桂酰肌氨酸钠 25Sodium Lauroyl Sarcosinate 25
烷基糖苷 20Alkyl glycoside 20
月桂酰胺丙基二甲基甜菜碱 18Lauramidopropyl Dimethyl Betaine 18
葡糖胺 8Glucosamine 8
牡丹皮精油 0.8Moutan Bark Essential Oil 0.8
艾草精油 0.3Wormwood essential oil 0.3
氯化钠 1.5Sodium chloride 1.5
去离子水 26.4。Deionized water 26.4.
为检测上述实施例所提供的以天然植物精油为防腐剂的洗涤剂的防腐性能，对以上具体实施例按照消毒技术规范和微生物挑战实验对日化产品的防腐效果评价的实验方法进行了微生物测试。In order to detect the antiseptic properties of the detergents provided by the above-mentioned examples with natural plant essential oils as preservatives, microbiological tests were carried out on the experimental methods for the antiseptic effect evaluation of daily chemical products in accordance with the disinfection technical specifications and microbial challenge experiments in the above specific examples .
实验结果如下：The experimental results are as follows:
对以上实施例按照《微生物挑战实验对化妆品的防腐效果评价》中微生物挑战实验的操作方法进行了防腐测试。For the above examples, the antiseptic test was carried out according to the operation method of the microbial challenge experiment in "Evaluation of Antiseptic Effect of Cosmetics by Microbial Challenge Experiment".
此实验方法是按照重复加菌，然后7d后进行培养，共加3次菌，每次加菌量为1～5×106。以上实施例在三次加菌7d后进行培养的结果如下表。This experimental method is to add bacteria repeatedly, and then culture after 7 days, and add bacteria for 3 times in total, and the amount of bacteria added each time is 1-5×10 6 . The results of culturing in the above examples three times after adding bacteria for 7 days are shown in the table below.
通过以上实验结果，可知，在三次加菌7d 后进行培养，菌落数都小于10，按照《微生物挑战实验对化妆品的防腐效果评价》中的评价来看，均有很强的防腐效果。From the above experimental results, it can be seen that the number of colonies is less than 10 after three additions of bacteria for 7 days. According to the evaluation in "Evaluation of Antiseptic Effect of Cosmetics by Microbial Challenge Experiment", they all have strong antiseptic effects.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110742827A (en) * | 2019-09-27 | 2020-02-04 | 华南师范大学 | Anticorrosive composition and application thereof |
| CN111718805A (en) * | 2020-06-17 | 2020-09-29 | 南风化工集团股份有限公司 | Tableware detergent with caraway extract as fishy smell removing component and preparation method thereof |
| CN112080353A (en) * | 2020-09-02 | 2020-12-15 | 广东丽臣奥威实业有限公司 | Mild and efficient surfactant composition for cleaning |
| CN112136837A (en) * | 2020-09-25 | 2020-12-29 | 上海和黄白猫有限公司 | Antibacterial mite-killing composition, antibacterial mite-killing laundry detergent and preparation method thereof |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003113013A (en) * | 2001-09-28 | 2003-04-18 | Lion Corp | Vegetable antimicrobial preservative |
| CN1585607A (en) * | 2001-11-28 | 2005-02-23 | 约翰逊迪瓦西公司 | Food washing composition |
| DE102004039722A1 (en) * | 2004-08-17 | 2006-03-02 | Henkel Kgaa | Perfume, useful in the application of washing- or cleaning agents, comprises soda-containing particles |
| CN102296004A (en) * | 2011-07-26 | 2011-12-28 | 山东丽波日化股份有限公司 | Paste washing agent for cleaning hard surfaces in kitchen and preparation method thereof |
| CN102559406A (en) * | 2011-08-06 | 2012-07-11 | 威莱(广州)日用品有限公司 | Compound type cleaning solution |
| CN105400617A (en) * | 2015-12-17 | 2016-03-16 | 宁波工程学院 | Preparation method of cold-formed soap |
| CN105419966A (en) * | 2014-09-17 | 2016-03-23 | 范暄民 | Natural botanic antibacterial detergent |
| KR20160061771A (en) * | 2014-11-24 | 2016-06-01 | 이기혁 | Dishwashing detergent composition comprising spinach extract and manufacturing method thereof |
| JP2016528164A (en) * | 2013-04-10 | 2016-09-15 | ユーエックスエヌ シーオー．，エルティーディー． | Soap composition or cosmetic composition containing gold beads, and soap manufacturing method or cosmetic manufacturing method using the same |
-
2016
- 2016-12-30 CN CN201611251743.1A patent/CN108264973A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003113013A (en) * | 2001-09-28 | 2003-04-18 | Lion Corp | Vegetable antimicrobial preservative |
| CN1585607A (en) * | 2001-11-28 | 2005-02-23 | 约翰逊迪瓦西公司 | Food washing composition |
| DE102004039722A1 (en) * | 2004-08-17 | 2006-03-02 | Henkel Kgaa | Perfume, useful in the application of washing- or cleaning agents, comprises soda-containing particles |
| CN102296004A (en) * | 2011-07-26 | 2011-12-28 | 山东丽波日化股份有限公司 | Paste washing agent for cleaning hard surfaces in kitchen and preparation method thereof |
| CN102559406A (en) * | 2011-08-06 | 2012-07-11 | 威莱(广州)日用品有限公司 | Compound type cleaning solution |
| JP2016528164A (en) * | 2013-04-10 | 2016-09-15 | ユーエックスエヌ シーオー．，エルティーディー． | Soap composition or cosmetic composition containing gold beads, and soap manufacturing method or cosmetic manufacturing method using the same |
| CN105419966A (en) * | 2014-09-17 | 2016-03-23 | 范暄民 | Natural botanic antibacterial detergent |
| KR20160061771A (en) * | 2014-11-24 | 2016-06-01 | 이기혁 | Dishwashing detergent composition comprising spinach extract and manufacturing method thereof |
| CN105400617A (en) * | 2015-12-17 | 2016-03-16 | 宁波工程学院 | Preparation method of cold-formed soap |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110742827A (en) * | 2019-09-27 | 2020-02-04 | 华南师范大学 | Anticorrosive composition and application thereof |
| CN111718805A (en) * | 2020-06-17 | 2020-09-29 | 南风化工集团股份有限公司 | Tableware detergent with caraway extract as fishy smell removing component and preparation method thereof |
| CN112080353A (en) * | 2020-09-02 | 2020-12-15 | 广东丽臣奥威实业有限公司 | Mild and efficient surfactant composition for cleaning |
| CN112136837A (en) * | 2020-09-25 | 2020-12-29 | 上海和黄白猫有限公司 | Antibacterial mite-killing composition, antibacterial mite-killing laundry detergent and preparation method thereof |
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Application publication date: 20180710 |