CN108251077A - Anhydrous cooling liquid - Google Patents
Anhydrous cooling liquid Download PDFInfo
- Publication number
- CN108251077A CN108251077A CN201611237720.5A CN201611237720A CN108251077A CN 108251077 A CN108251077 A CN 108251077A CN 201611237720 A CN201611237720 A CN 201611237720A CN 108251077 A CN108251077 A CN 108251077A
- Authority
- CN
- China
- Prior art keywords
- water
- free cooling
- cooling liquid
- cooling according
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000110 cooling liquid Substances 0.000 title abstract description 7
- 238000001816 cooling Methods 0.000 claims abstract description 22
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 21
- -1 triazole compounds Chemical class 0.000 claims abstract description 16
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 10
- 239000003086 colorant Substances 0.000 claims abstract description 8
- 150000007529 inorganic bases Chemical class 0.000 claims abstract description 7
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229960004063 propylene glycol Drugs 0.000 claims abstract description 5
- 239000001361 adipic acid Substances 0.000 claims abstract description 3
- 235000011037 adipic acid Nutrition 0.000 claims abstract description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 230000003750 conditioning effect Effects 0.000 claims description 8
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- 159000000000 sodium salts Chemical class 0.000 claims description 6
- 150000003852 triazoles Chemical class 0.000 claims description 6
- XZOYHFBNQHPJRQ-UHFFFAOYSA-N 7-methyloctanoic acid Chemical compound CC(C)CCCCCC(O)=O XZOYHFBNQHPJRQ-UHFFFAOYSA-N 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 3
- 239000012964 benzotriazole Substances 0.000 claims description 3
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical group OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims 3
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims 1
- 238000009835 boiling Methods 0.000 abstract description 11
- 238000005260 corrosion Methods 0.000 abstract description 11
- 238000007710 freezing Methods 0.000 abstract description 10
- 230000008014 freezing Effects 0.000 abstract description 10
- 230000007797 corrosion Effects 0.000 abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 7
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 abstract description 6
- 239000003112 inhibitor Substances 0.000 abstract description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 238000005266 casting Methods 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 238000005476 soldering Methods 0.000 abstract 1
- 150000004867 thiadiazoles Chemical class 0.000 abstract 1
- 239000002826 coolant Substances 0.000 description 17
- 238000003912 environmental pollution Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 2
- 229920000305 Nylon 6,10 Polymers 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 2
- GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 description 2
- 230000017525 heat dissipation Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 230000002528 anti-freeze Effects 0.000 description 1
- 235000019628 coolness Nutrition 0.000 description 1
- AEDZKIACDBYJLQ-UHFFFAOYSA-N ethane-1,2-diol;hydrate Chemical group O.OCCO AEDZKIACDBYJLQ-UHFFFAOYSA-N 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000008450 motivation Effects 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/20—Antifreeze additives therefor, e.g. for radiator liquids
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
An anhydrous cooling liquid, which comprises the following components: according to mass percentage, 60-80% of ethylene glycol, 15-32% of 1, 2-propylene glycol, 0.2-1% of triazole compounds, 0.2-1% of thiadiazole compounds, 0.3-0.9% of adipic acid, 0.1-0.3% of sebacic acid, 0.2-1.5% of organic monocarboxylic acid compounds, 2-4% of viscosity specific heat regulator, 0.3-1% of inorganic base, 0.01-0.1% of defoaming agent and 0.01-0.05% of colorant. The freezing point of the cooling liquid is below 50 ℃ below zero, the boiling point is 160-2In addition, the system adopts organic corrosion inhibitor components with low consumption speed, multifunction and high efficiency, thoroughly eliminates the problems of aluminum casting and soldering tin corrosion caused by using diluent and concentrated solution of the traditional water-containing cooling liquid, ensures that the service life of the cooling liquid reaches 4 years, is a long-service-life product, and is particularly suitable for cooling and corrosion-relieving requirements of high-power and heavy-load engines in harsh environments.
Description
Technical field
The present invention relates to a kind of engine coolant, more particularly to a kind of low viscosity long-life engine water-free cooling.
Background technology
Automobile engine cooling liquid is the circulating heat transfer medium of car water engine-cooling system, it can take away hair
The big calorimetric that motivation generates at work, in addition, it also has the function of antifreeze, anti-boiling, anticorrosion etc..
The coolant of mainstream is water-ethylene glycol coolant currently on the market, and this coolant has the following disadvantages:1) boiling point
Low (be less than 108.5 DEG C) can only meet conventional engines and work at a lower temperature, but high power can not be met, heavy load is started
The requirement that machine could be worked normally in higher boiling;2) since the coolant contains water, a large amount of vapor are in the metal of cylinder periphery
Surface forms steam thermal insulation layer, and engine interior is caused to overheat, makes the hydraulic performance decline of engine;3) service life is short, in the market
Mainstream cooling liquid system consumes fast inorganic type corrosion inhibiter using component mostly, and service life is mostly 1-2;4) it is used for a long time
Aqueous coolant can form incrustation scale, and coolant heat conduction and exchange capability of heat is caused to decline;5) ethylene glycol is larger and difficult there are toxicity
The shortcomings that degrade.
Invention content
The purpose of the present invention is to provide a kind of water-free coolings.
To achieve the above object, the present invention provides a kind of water-free cooling, including following components:By mass percentage,
Ethylene glycol 60-80%, 1,2- propylene glycol 15-32%, triazole class compounds 0.2-1%, thiadiazole compound 0.2-1%, oneself
Diacid 0.3-0.9%, decanedioic acid 0.1-0.3%, organic mono carboxylic acid compound 0.2-1.5%, ratio of viscosities thermal conditioning agent 2-
4%th, inorganic base 0.3-1%, antifoaming agent 0.01-0.1% and colorant 0.01-0.05%.
Further, the triazole class compounds are one or both of benzotriazole and methyl benzotriazazole.
Further, the thiadiazole compound is one kind in dimercaptothiodiazole sodium salt and dimercaptothiodiazole sodium salt
Or two kinds.
Further, the organic mono carboxylic acid compound is one or both of isooctyl acid and isononanoic acid.
Further, the ratio of viscosities thermal conditioning agent is one kind or two in diethylene glycol monobutyl ether and ethyl carbitol
Kind.
Further, the inorganic base is sodium hydroxide or potassium hydroxide.
Further, the antifoaming agent is modified organic silicon antifoaming agent.
The colorant is row colorant commonly used in the trade, does not do particular determination, can be water soluble fluorescence Huang, fluorescence green
And fluorescein.
The beneficial effects of the invention are as follows:
1) it is not aqueous, completely eliminate containing boil caused by water coolant, fouling, corrosion the shortcomings of;
2) system boiling point is more than 150 DEG C, and freezing point is less than 20mm less than -50 DEG C, kinematic viscosity2/ s (20 DEG C), can meet height
Power, the cooling of heavy-duty engine, anti-corrosion and heat conduction demand;
3) generation for the steam vapour lock layer for seriously affecting heat dissipation is avoided, the high temperature of engine interior is controlled, effectively carries
The power of engine is risen;
4) the slow organic acid inhibitor of depletion rate is employed, substantially prolongs the service life of coolant;
5) after adding ratio of viscosities thermal conditioning agent, the heat exchange efficiency of system is effectively improved;
6) using the method for propylene glycol substitution part ethylene glycol, environmental pollution is on the one hand reduced, is on the other hand had adjusted
The viscosity and freezing point of system.
7) without organic amine, borate, phosphate, nitrite, molybdate, the silicate being harmful to human body and environment
Deng completely eliminating the environmental pollution that inorganic salts corrosion inhibiter is brought.
Specific embodiment
With reference to embodiment, the present invention is described further.
A kind of water-free cooling, including following components:By mass percentage, ethylene glycol 60-80%, 1,2-PD
15-32%, triazole class compounds 0.2-1%, thiadiazole compound 0.2-1%, adipic acid 0.3-0.9%, decanedioic acid 0.1-
0.3%th, organic mono carboxylic acid compound 0.2-1.5%, ratio of viscosities thermal conditioning agent 2-4%, inorganic base 0.3-1%, antifoaming agent
0.01-0.1% and colorant 0.01-0.05%.
Further, the triazole class compounds are one or both of benzotriazole and methyl benzotriazazole.
Further, the thiadiazole compound is one kind in dimercaptothiodiazole sodium salt and dimercaptothiodiazole sodium salt
Or two kinds.
Further, the organic mono carboxylic acid compound is one or both of isooctyl acid and isononanoic acid.
Further, the ratio of viscosities thermal conditioning agent is one kind or two in diethylene glycol monobutyl ether and ethyl carbitol
Kind.
Further, the inorganic base is sodium hydroxide or potassium hydroxide.
Further, the antifoaming agent is modified organic silicon antifoaming agent.
The colorant is row colorant commonly used in the trade, does not do particular determination, can be water soluble fluorescence Huang, fluorescence green
And fluorescein.
Embodiment 1
A kind of low viscosity long-life water-free cooling, each component and weight percent:
Preparation process:It is stirred evenly after this component is mixed, coolant as of the present invention, boiling point is glued at 160 DEG C or more
It spends for 18.70mm2/ s (20 DEG C), freezing point are less than -50 DEG C, and pH is 8.52.
Embodiment 2
A kind of low viscosity long-life water-free cooling, each component and weight percent:
Preparation process:It is stirred evenly after this component is mixed, coolant as of the present invention, boiling point is glued at 160 DEG C or more
It spends for 18.5mm2/ s (20 DEG C), freezing point are less than -50 DEG C, and pH is 8.40.
Embodiment 3
A kind of low viscosity long-life water-free cooling, each component and weight percent:
Preparation process:It is stirred evenly after this component is mixed, coolant as of the present invention, boiling point is glued at 160 DEG C or more
It spends for 17.70mm2/ s (20 DEG C), freezing point are less than -50 DEG C, and pH is 8.66.
Embodiment 4
A kind of low viscosity long-life water-free cooling, each component and weight percent:
Preparation process:It is stirred evenly after this component is mixed, coolant as of the present invention, boiling point is glued at 160 DEG C or more
It spends for 18.25mm2/ s (20 DEG C), freezing point are less than -50 DEG C, and pH is 8.25.
The main performance test data of the water-free cooling of 1 Examples 1 to 3 of table
What table 1 provided is the main performance test data of present invention shampoo coolant, as can be seen from the table, of the invention
All there is water-free cooling higher boiling (being not less than 150 DEG C), low freezing point (being not higher than -50 DEG C), low viscosity (to be not more than 20mm2/s、
20 DEG C) etc. features, glassware corrosion statistics indicate that, the coolant to various metals all have excellent corrosion inhibition.
The beneficial effects of the invention are as follows:
1) it is not aqueous, completely eliminate containing boil caused by water coolant, fouling, corrosion the shortcomings of;
2) system boiling point is more than 150 DEG C, and freezing point is less than 20mm less than -50 DEG C, kinematic viscosity2/ s (20 DEG C), can meet height
Power, the cooling of heavy-duty engine, anti-corrosion and heat conduction demand;
3) generation for the steam vapour lock layer for seriously affecting heat dissipation is avoided, the high temperature of engine interior is controlled, effectively carries
The power of engine is risen;
4) the slow organic acid inhibitor of depletion rate is employed, substantially prolongs the service life of coolant;
5) after adding ratio of viscosities thermal conditioning agent, the heat exchange efficiency of system is effectively improved;
6) using the method for propylene glycol substitution part ethylene glycol, environmental pollution is on the one hand reduced, is on the other hand had adjusted
The viscosity and freezing point of system.
7) without organic amine, borate, phosphate, nitrite, molybdate, the silicate being harmful to human body and environment
Deng completely eliminating the environmental pollution that inorganic salts corrosion inhibiter is brought.
Certainly, the present invention can also have other various embodiments, without deviating from the spirit and substance of the present invention, ripe
Various corresponding changes and deformation, but these corresponding changes and deformation can be made according to the present invention by knowing those skilled in the art
The protection domain of the claims in the present invention should all be belonged to.
Claims (7)
1. a kind of water-free cooling, which is characterized in that including following components:By mass percentage, ethylene glycol 60-80%, 1,
2- propylene glycol 15-32%, triazole class compounds 0.2-1%, thiadiazole compound 0.2-1%, adipic acid 0.3-0.9%, the last of the ten Heavenly stems
Diacid 0.1-0.3%, organic mono carboxylic acid compound 0.2-1.5%, ratio of viscosities thermal conditioning agent 2-4%, inorganic base 0.3-
1%th, antifoaming agent 0.01-0.1% and colorant 0.01-0.05%.
2. water-free cooling according to claim 1, which is characterized in that the triazole class compounds for benzotriazole and
One or both of methyl benzotriazazole.
3. water-free cooling according to claim 1, which is characterized in that the thiadiazole compound is dimercaptothiodiazole
One or both of sodium salt and dimercaptothiodiazole sodium salt.
4. water-free cooling according to claim 1, which is characterized in that the organic mono carboxylic acid compound is different pungent
One or both of acid and isononanoic acid.
5. water-free cooling according to claim 1, which is characterized in that the ratio of viscosities thermal conditioning agent is diethylene glycol list
One or both of butyl ether and ethyl carbitol.
6. water-free cooling according to claim 1, which is characterized in that the inorganic base is sodium hydroxide or hydroxide
Potassium.
7. water-free cooling according to claim 1, which is characterized in that the antifoaming agent is modified organic silicon antifoaming agent.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611237720.5A CN108251077A (en) | 2016-12-28 | 2016-12-28 | Anhydrous cooling liquid |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611237720.5A CN108251077A (en) | 2016-12-28 | 2016-12-28 | Anhydrous cooling liquid |
Publications (1)
Publication Number | Publication Date |
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CN108251077A true CN108251077A (en) | 2018-07-06 |
Family
ID=62719617
Family Applications (1)
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CN201611237720.5A Pending CN108251077A (en) | 2016-12-28 | 2016-12-28 | Anhydrous cooling liquid |
Country Status (1)
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CN (1) | CN108251077A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109181656A (en) * | 2018-08-31 | 2019-01-11 | 江苏凯瑞德润滑技术有限公司 | A kind of high temperature Condition of Engine Coolant for Heavy Duty Engines |
CN110776878A (en) * | 2019-11-28 | 2020-02-11 | 济南鼎隆化工科技有限公司 | A kind of environment-friendly high-boiling point energy exchange medium and preparation method thereof |
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CN1346396A (en) * | 1999-02-26 | 2002-04-24 | 爱什股份有限公司 | Monocarboxylic acid based antifreeze composition for diesel engines |
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CN102559152A (en) * | 2012-01-10 | 2012-07-11 | 广州市标榜汽车用品实业有限公司 | All-organic waterless engine coolant |
CN102977862A (en) * | 2012-12-21 | 2013-03-20 | 中国人民解放军空军油料研究所 | Cooling liquid composition |
CN105419734A (en) * | 2015-11-16 | 2016-03-23 | 惠州市沃斯润滑科技有限公司 | Engine coolant |
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2016
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CN1346396A (en) * | 1999-02-26 | 2002-04-24 | 爱什股份有限公司 | Monocarboxylic acid based antifreeze composition for diesel engines |
CN1982406A (en) * | 2005-12-12 | 2007-06-20 | 现代自动车株式会社 | Antifreezing composition |
CN101812287A (en) * | 2009-02-25 | 2010-08-25 | 北京合创同盛科技有限公司 | Automotive antifreezing coolant |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109181656A (en) * | 2018-08-31 | 2019-01-11 | 江苏凯瑞德润滑技术有限公司 | A kind of high temperature Condition of Engine Coolant for Heavy Duty Engines |
CN110776878A (en) * | 2019-11-28 | 2020-02-11 | 济南鼎隆化工科技有限公司 | A kind of environment-friendly high-boiling point energy exchange medium and preparation method thereof |
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Application publication date: 20180706 |