CN108251048A - Dry granular glaze glue, dry granular glaze, dry granular glazed tile and preparation method thereof - Google Patents
Dry granular glaze glue, dry granular glaze, dry granular glazed tile and preparation method thereof Download PDFInfo
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- CN108251048A CN108251048A CN201810052401.XA CN201810052401A CN108251048A CN 108251048 A CN108251048 A CN 108251048A CN 201810052401 A CN201810052401 A CN 201810052401A CN 108251048 A CN108251048 A CN 108251048A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J191/00—Adhesives based on oils, fats or waxes; Adhesives based on derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Organic Chemistry (AREA)
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- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
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- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Dry granular glaze glue, dry granular glaze, the dry granular glazed tile and preparation method thereof of the present invention, emphasis optimizes the formula composition and dry granular glaze glue surface tension of dry granular glaze glue and dry granular glaze, make the dry granular glaze glue of preparation there is preferable suspension and dispersibility and stronger caking property, and then the dry granular glaze of preparation is made to have the characteristics that not precipitate, do not reunite, be uniformly dispersed, bonding force it is strong, it is and adaptable with ink-jet printing ink, have many advantages, such as not repel, parch that the time is short, good permeability；The ceramic brick surface dry granular prepared using dry granular glaze is uniformly dispersed, and finger touch temperature is sliding fine and smooth, and under light-illuminating, dry granular flashing has uniqueness decorative effect；And brick product surface without leakage dry granular, pin-free, glaze bubble, quick-fried glaze the defects of, decorative pattern is clear, well arranged, color development is pure, especially the dry granular of deep printing product surface is uniformly dispersed, and color development is bright-coloured, and product pollution resistance is strong, hardness is high, wearability is good.
Description
Technical field：
The present invention relates to technical fields prepared by ceramic glaze, refer in particular to a kind of dry granular glaze glue, dry granular glaze, do
Grain glazed tile and preparation method thereof.
Background technology：
At present, the application with inkjet printing technology in ceramic tile production makes the decoration technique on ceramic wall and floor bricks surface
Play variation with rapid changepl. never-ending changes and improvements, due to its fidelity is high, the development cycle of pattern pattern is short, variation is fast, easy to operate and by
To the favor of numerous ceramic wall and floor bricks manufacturers, but also the drawbacks of homogeneity is serious is brought, so as to which product be made to lose competition
Power, thus the ceramic tile production producer that some are big, R＆D capability is strong is to break the homogeneous quagmire in ink-jet epoch,
On the product face of general surface printing ornament, then one layer of dry granular glaze is applied, after high-temperature calcination, the dry granular glaze of these product surfaces
Material can occur to flicker radiance under light-illuminating, while make product surface hardness, abrasion resistance, non-skid property etc. than common print
The product of decoration is spent to be largely increased, finger touches the sliding exquisiteness of temperature, pico- concave-convex such as former stone shape, not only visually and tactile
All there is a kind of completely new effect than original common Wall or floor tile product in feel, so as to greatly increase the competitiveness of product.
However when applying dry granular glaze, common glue is since suspension is poor, dispersion is bad, parches the time slowly, gas permeability
The reasons such as difference can cause：
Dry granular precipitation is difficult to glazing, and easily reuniting is unevenly distributed product surface dry granular, influences Integral decoration effect；
It is easily taken away to cause to lack dry granular defect by the wind turbine in kiln；
Easily occur dry granular glaze occur because ink-jet ink does not parch for the moment at dark images when producing deep printing product
It is incompatible with ink and cause not applying dry granular glaze；
Or poor air permeability, closure because of glue is too strong, high temperature firing when gas discharge it is bad easily occur pin hole, bubble or
The defects of quick-fried glaze；
Or because parching overlong time, the wetting ability of glue and pattern is excessive, and dim pattern is caused not have level；
Or because glue high temperature residue is excessive, color development is influenced, the defects of color color development is not pure.
Invention content：
It is an object of the invention to overcome disadvantages mentioned above, a kind of dry granular glaze glue, dry granular glaze, dry granular glazed tile are provided
And preparation method thereof, make weight in the production technology not to existing dry granular glaze glue and the production of dry granular glaze and glazing process
On the basis of big change, emphasis is to the formula composition of dry granular glaze glue, the formula composition of dry granular glaze and dry granular glaze glue
The optimization of surface tension, so as to which the dry granular glaze for making preparation has the characteristics that not precipitate, do not reunite, be uniformly dispersed, bonding force is strong,
And it is adaptable with ink-jet printing ink, have many advantages, such as not repel, parch that the time is short, good permeability, make using dry granular glaze
Ceramic Tiles product surface dry granular prepared by material is uniformly dispersed, and finger touch temperature is sliding fine and smooth, and under light-illuminating, these dry granulars dodge
It is bright to shine, there is unique decorative effect；And product surface without leakage dry granular, pin-free, glaze bubble, quick-fried glaze the defects of, decorative pattern
Clearly, it is well arranged, color development is pure, especially the dry granular of deep printing product surface is uniformly dispersed, and color development is bright-coloured, production
Product pollution resistance is strong, hardness is high, wearability is good；The technology has stronger universality simultaneously, is easy in industry promote.
In order to solve the above technical problems, the invention is realized by the following technical scheme：
The present invention relates to a kind of dry granular glaze glue, are prepared by following parts by weight of component：
Solubility parameters is 27~35 (J/ ㎝3)1/230~60 parts of solvent, 4~20 parts of vegetable oil, 30~50 parts of water, addition
0.3~2.3 part of agent；
Solubility parameters therein is 27~35 (J/ ㎝3)1/2Solvent for methanol, phenol, ethylene glycol, glycerine, diethylene glycol (DEG) class
In one or more mixing；
Vegetable oil therein is tung oil, one or more mixing in castor oil, palm oil, linseed oils；
Additive therein is epoxy resin, polyvinyl butyral, Sodium Polyacrylate, carboxymethyl cellulose, BYKJET-
9131st, one or more mixing in BYKJET-9132, BYKJET-9133 class；
The surface tension of dry granular glaze glue therein is 25mNm-1~35mNm-1。
Additive is first dissolved in solubility parameters as 27~35 (J/ ㎝ respectively3)1/2Solvent in, add vegetable oil and
Water stirs evenly.
The invention further relates to a kind of preparation method of dry granular glaze glue, according to foregoing dry granular glaze glue
Parts by weight of component matches, and additive is dissolved in solubility parameters for 27~35 (J/ ㎝ respectively3)1/2Solvent in, add plant
Oil and water are stirred evenly up to dry granular glaze glue；
Solubility parameters therein is 27~35 (J/ ㎝3)1/2Solvent for methanol, phenol, ethylene glycol, glycerine, diethylene glycol (DEG) class
In one or more mixing；
Vegetable oil therein is tung oil, one or more mixing in castor oil, palm oil, linseed oils；
Additive therein is epoxy resin, polyvinyl butyral, Sodium Polyacrylate, carboxymethyl cellulose, BYKJET-
9131st, one or more mixing in BYKJET-9132, BYKJET-9133 class；
The surface tension of dry granular glaze glue therein is 25mNm-1~35mNm-1。
The invention further relates to a kind of dry granular glaze, wherein：
Dry granular glaze：It is prepared by following parts by weight of component：
100 parts of dry granular glaze glue, 0.5~50 part of dry granular；
Dry granular glaze glue therein is prepared according to the parts by weight of component of foregoing dry granular glaze glue；
Dry granular therein is preferably the frit granules of the mesh of 60 mesh~200.
The invention further relates to a kind of preparation methods of dry granular glaze, include the following steps：
A, the preparation of dry granular glaze glue：It is prepared according to the parts by weight of component of foregoing dry granular glaze glue, respectively
Additive is dissolved in solubility parameters as 27~35 (J/ ㎝3)1/2Solvent in, add vegetable oil and water stir evenly to obtain the final product
Dry granular glaze glue；
B, the preparation of dry granular glaze：It is prepared according to the parts by weight of component of foregoing dry granular glaze, by dry granular glaze glue
Water and dry granular, which are mixed together, to stir evenly to get dry granular glaze；
Dry granular therein is preferably the frit granules of the mesh of 60 mesh~200.
The invention further relates to a kind of preparation methods of dry granular glaze Ceramic Tiles, according to the design needs of product, use respectively
Spray gun, bell jar or the mode of silk-screen printing, the dry granular glaze that will be prepared according to the preparation method of foregoing dry granular glaze
Material is applied on the ceramic adobe for normally having applied bottom, overglaze and printing ornament, high temperature firing is carried out subsequently into roller kilns, through overground
The processes such as side, classification, that is, be made finished product.
The invention further relates to a kind of dry granular glaze Ceramic Tiles, according to the preparation side of foregoing dry granular glaze Ceramic Tiles
Method is prepared.
A kind of dry granular glaze glue, dry granular glaze, the dry granular glazed tile and preparation method thereof of the present invention, by optimizing dry granular
The formula composition of glaze glue, so as to make the dry granular glaze glue of preparation on the one hand have preferable suspension and dispersibility and
Stronger adhesive property so as to ensure that the suspension of dry granular glaze, will not generate split-phase and precipitation due to the ratio of dry granular is great,
The glazing for influencing the later stage is difficult；On the other hand, dry granular glaze glue also has stronger penetrating power, so as to ensure that Shi Yin
The glue in dry granular glaze in flower decoration adobe can inside the capillary percolation to glaze quickly through glaze adobe surface,
Shorten while dry granular glaze parches the time and dry granular is quickly adhesively fixed；Furthermore in being formed because of dry granular glaze glue formula
The volatilization temperature of these materials of solvent and vegetable oil is relatively low, is fully able to ensure to volatilize before 350 DEG C complete, so as to not influence
Gas discharge of the adobe body in high temperature, otherwise can make ceramic brick product due to poor air permeability adobe high-temperature gas discharges difficult
There is the defects of pin hole, glaze bubble, quick-fried glaze or even influences the stain resistance of ceramic brick product in surface.
In addition, the dispersion performance and mobile performance of these substances such as vegetable oil and ethylene glycol, diethylene glycol (DEG), methanol, water, glycerine
It is good, so as to ensure that the uniformity of dry granular distribution dispersion, it ensure that the dry granular shape of ceramic brick surface and the reflection to light and folding
Effect is penetrated, so as to send out the radiance of flicker and the sliding fine and smooth feel of temperature under light-illuminating.
Additive types preferably with the optimization of proportioning, on the one hand ensure that the suspension of dry granular glaze glue；The opposing party
Face also assures the adhesive property of dry granular glaze glue, will not make dry granular because adhesive property is bad, easily by the wind turbine in kiln and
External force is blown away, so as to cause leakage dry granular phenomenon；The polyvinyl butyral in additive, Sodium Polyacrylate, carboxymethyl are fine simultaneously
Plain sodium of dimension etc., they are all a kind of high molecular polymers, and fixation can also be played while ensure that stronger adhesive property
The effect of agent, so as to ensure that the clarity of printed patterns, so as to will not make the pattern of printing by glue wetting action and mould
Paste；And the substance in additive does not stay residue after 600 DEG C of high-temperature calcinations, so as to not interfere with the color development of printed patterns, makes
Printed patterns are bright-colored, pure；Furthermore BYKJET-9131, BYKJET-9132, BYKJET-9133, these substances or one
The oil-soluble dispersant of kind, it is ensured that vegetable oil miscible with water is not in split-phase.
The optimization of dry granular glaze glue surface tension, it is ensured that dry granular glaze and ink-jet ink adaptability, because of ink-jet
The surface tension requirements of ink are stringent, are 25mNm-1~35mNm-1, otherwise the product of some dark printed patterns can be because of two
The difference of person's surface tension is big and repels, and the dry granular glaze at printed patterns is caused to shrink outward, dry granular glaze does not adhere to
In patterned surfaces, the defects of causing leakage dry granular glaze.
A kind of dry granular glaze glue, dry granular glaze, the dry granular glazed tile and preparation method thereof of the present invention has the following advantages：
1st, due to optimizing the formula composition of dry granular glaze glue, the formula composition of dry granular glaze and dry granular glaze glue
The adjustment of processing method and surface tension and optimization etc., so as to make the dry granular glaze glue of preparation that there is preferable suspension and divide
Dissipate property and stronger adhesive property.
There is dry granular glaze glue preferable suspension to make the dry granular glaze suspension of preparation good, will not be because of the proportion of dry granular
Glazing that is excessive and generating the split-phase precipitation influence later stage is difficult, while dry granular is made to be uniformly dispersed, and is not in reunion, lumps now
As.
The dry granular glaze prepared by dry granular glaze glue has that adhesive property is strong, it is excellent to parch that the time is short, permeability is good
Point, so as to make the dry granular dispersed distribution of the dry granular glaze Ceramic Tiles product surface of preparation is uniform, finger touch is warm to slide exquisiteness, in lamp
Under light irradiation, twinkLing stars light is sent out, and printed patterns are clear, well arranged, bright-colored, pure, antifouling property is strong, needleless
The defects of hole, glaze bubble, quick-fried glaze.The product of especially some dark inkjet print images will not be because of ink-jet ink and dry granular glaze glue
The difference of water surface both tension is big and repels, and the dry granular glaze at printed patterns is caused to shrink outward, dry granular glaze is not
The defects of being adhered to patterned surfaces, causing leakage dry granular glaze.
2nd, the product clean environment firendly, volatility be weak, volatile organic content (VOC), benzene, toluene, ethylbenzene, dimethylbenzene are total
Reach the requirement of GB18582-2008 standards, the Ceramic Tiles prepared using the dry granular glaze with free formaldehyde, soluble heavy metal
Surface quality, radioactivity, pollution resistance, lead-indium alloy reach GB/T4100-2015, GB6566-2010 and HT/T297-
The requirement of 2006 standards.
3rd, the product uses the production technology of existing dry granular glaze glue and production and the glazing process of dry granular glaze, easily
In realization industrialized scale.
Description of the drawings：
Fig. 1 is the technological process of the dry granular glaze glue, dry granular glaze, dry granular glazed tile of the present invention and preparation method thereof
Figure.
Specific embodiment：
The present invention is described in further detail with reference to embodiment.
Embodiment 1
A kind of preparation method of dry granular glazed tile of the present invention, includes the following steps：
A, the preparation of dry granular glaze glue：
Additive is weighed by the formula composition of table 1, is then dissolved separately in solubility parameters as 27~35 (J/ ㎝3)1/2It is molten
It is stirred evenly in agent, then is mixed together to stir evenly with vegetable oil and water and obtains dry granular glaze glue, dry granular glaze glue
Surface tension is 25mNm-1~35mNm-1.Preparing for dry granular glaze glue can also the conventional feasible configuration of other uses
Step.
Table 1, dry granular glaze glue constituent table (parts by weight)
Solubility parameters therein is 27~35 (J/ ㎝3)1/2Solvent for methanol, phenol, ethylene glycol, glycerine, diethylene glycol (DEG) class
In one or more mixing.Solubility parameters is 27~35 (J/ ㎝3)1/2Solvent can also select it is each in this ceramic field
The common solubility parameters of kind is 27~35 (J/ ㎝3)1/2Solvent.
Vegetable oil therein is tung oil, one or more mixing in castor oil, palm oil, linseed oils.
Additive therein is epoxy resin, polyvinyl butyral, Sodium Polyacrylate, carboxymethyl cellulose, BYKJET-
9131st, one or more mixing in BYKJET-9132, BYKJET-9133 class；BYKJET-9131, BYKJET-9132 and
BYKJET-9133 is ink-jet used additives.
B, the preparation of dry granular glaze：
It is formed by 2 dry granular glaze formula of table and dry granular glaze glue and dry granular is claimed to be mixed together and stir evenly up to dry granular glaze
Material.
Table 2, dry granular glaze formula composition table (parts by weight)
| Component | Dry granular glaze glue | Dry granular |
| 1# | 100 | 0.5 |
| 2# | 100 | 24.75 |
| 3# | 100 | 50 |
| 4# | 100 | 15 |
| 5# | 100 | 35 |
Dry granular therein can be the frit granules of common mesh number, can also be preferably the frit granules of the mesh of 60 mesh~200,
Such as dragon dollar dry granular of Sihui, Guangdong dragon dollar ceramic raw material Co., Ltd production；
C, the preparation of dry granular glazed tile：
Finally according to the needs of design, with spray gun, bell jar or the mode of silk-screen printing prepared by above-mentioned steps respectively
Obtained dry granular glaze is applied on the ceramic adobe for normally having applied bottom, overglaze and printing ornament, then according to common dry granular glaze
Ceramic adobe is sent into roller kilns and carries out high temperature firing by the firing mode of face brick, by processes such as edging, classifications, that is, is made into
Product.
Through examining dry granular glaze glue and Ceramic Tiles finished product, leading indicator such as the following table 3, table 4：
Table 3, dry granular glaze glue quality test results
Table 4：Dry granular glaze Ceramic Tiles inspection result
In conclusion aforementioned embodiment is only presently preferred embodiments of the present invention, not make any shape to the present invention
Limitation in formula；The those of ordinary skill of all industry can swimmingly implement the present invention by described above；It is but all familiar
Professional and technical personnel without departing from the scope of the present invention, makes using disclosed above technology contents
A little change, modification with develop equivalent variations, be the present invention equivalent embodiment；Meanwhile all realities according to the present invention
The change of any equivalent variations, modification and the differentiation that matter technology makees above example still fall within the technical side of the present invention
Within the protection domain of case.
Claims (6)
1. a kind of dry granular glaze glue, it is characterised in that：
It is prepared by following parts by weight of component：
Solubility parameters is 27~35 (J/ ㎝3)1/230~60 parts of solvent, 4~20 parts of vegetable oil, 30~50 parts of water, additive 0.3
~2.3 parts；
Solubility parameters therein is 27~35 (J/ ㎝3)1/2Solvent be methanol, phenol, ethylene glycol, glycerine, in diethylene glycol (DEG) class
One or more mixing；
Vegetable oil therein is tung oil, one or more mixing in castor oil, palm oil, linseed oils；
Additive therein is epoxy resin, polyvinyl butyral, Sodium Polyacrylate, carboxymethyl cellulose, BYKJET-
9131st, one or more mixing in BYKJET-9132, BYKJET-9133 class；
The surface tension of dry granular glaze glue therein is 25mNm-1~35mNm-1。
2. a kind of preparation method of dry granular glaze glue, it is characterised in that：
It is matched according to the parts by weight of component of the dry granular glaze glue described in claim 1, additive is dissolved in solubility respectively
Parameter is 27~35 (J/ ㎝3)1/2Solvent in, add vegetable oil and water stirred evenly up to dry granular glaze glue.
3. a kind of dry granular glaze, it is characterised in that：
Dry granular glaze：It is prepared by following parts by weight of component：
100 parts of dry granular glaze glue, 0.5~50 part of dry granular；
Dry granular glaze glue therein is prepared according to the parts by weight of component of the dry granular glaze glue described in claim 1.
4. a kind of preparation method of dry granular glaze, it is characterised in that：
It includes the following steps：
A, the preparation of dry granular glaze glue：It is prepared according to the parts by weight of component of the dry granular glaze glue described in claim 3, point
Additive solubility parameters is not dissolved in as 27~35 (J/ ㎝3)1/2Solvent in, add vegetable oil and water stir evenly i.e.
Obtain dry granular glaze glue；
B, the preparation of dry granular glaze：It is prepared according to the parts by weight of component of the dry granular glaze described in claim 3, by dry granular glaze
Glue and dry granular, which are mixed together, to stir evenly to get dry granular glaze.
5. a kind of preparation method of dry granular glaze Ceramic Tiles, it is characterised in that：
It, will be according to the system in claim 4 respectively with spray gun, bell jar or the mode of silk-screen printing according to the design needs of product
The dry granular glaze that Preparation Method is prepared is applied on the ceramic adobe for normally having applied bottom, overglaze and printing ornament, subsequently into roller
Road kiln carries out high temperature firing, by processes such as edging, classifications, that is, finished product is made.
6. a kind of dry granular glaze Ceramic Tiles, it is characterised in that：
Preparation method according to claim 5 is prepared.
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| CN201810052401.XA CN108251048B (en) | 2018-01-19 | 2018-01-19 | Dry granular glaze glue, dry granular glaze, dry granular glazed tile and preparation method thereof |
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| CN109809836A (en) * | 2018-12-13 | 2019-05-28 | 江苏新嘉理生态环境材料股份有限公司 | A kind of production method of special-shaped cube of pottery curtain wall terra-cotta |
| CN110128172A (en) * | 2019-04-28 | 2019-08-16 | 东莞市唯美陶瓷工业园有限公司 | A kind of method improving Ceramic Tiles green surface performance of keeping humidity and the Ceramic Tiles using this method preparation |
| CN110862231A (en) * | 2019-11-26 | 2020-03-06 | 蒙娜丽莎集团股份有限公司 | Dry particle glaze for soft polished brick and application thereof |
| CN112094526A (en) * | 2020-09-22 | 2020-12-18 | 贾佳 | Water-based glue for producing ceramic printing color ink and application |
| CN113045340A (en) * | 2021-03-09 | 2021-06-29 | 江西金唯冠建材有限公司 | Dry-particle ink-jet stone-like brick and preparation method thereof |
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| CN109809836A (en) * | 2018-12-13 | 2019-05-28 | 江苏新嘉理生态环境材料股份有限公司 | A kind of production method of special-shaped cube of pottery curtain wall terra-cotta |
| CN109761649A (en) * | 2019-03-26 | 2019-05-17 | 东莞市唯美装饰材料有限公司 | A kind of slate Ceramic Tiles and preparation method thereof with diamond luster effect |
| CN109761649B (en) * | 2019-03-26 | 2022-07-12 | 东莞市唯美陶瓷工业园有限公司 | Slate ceramic tile with diamond luster effect and preparation method thereof |
| CN110128172A (en) * | 2019-04-28 | 2019-08-16 | 东莞市唯美陶瓷工业园有限公司 | A kind of method improving Ceramic Tiles green surface performance of keeping humidity and the Ceramic Tiles using this method preparation |
| CN110862231A (en) * | 2019-11-26 | 2020-03-06 | 蒙娜丽莎集团股份有限公司 | Dry particle glaze for soft polished brick and application thereof |
| CN110862231B (en) * | 2019-11-26 | 2021-12-03 | 蒙娜丽莎集团股份有限公司 | Dry particle glaze for soft polished brick and application thereof |
| CN112094526A (en) * | 2020-09-22 | 2020-12-18 | 贾佳 | Water-based glue for producing ceramic printing color ink and application |
| CN113045340A (en) * | 2021-03-09 | 2021-06-29 | 江西金唯冠建材有限公司 | Dry-particle ink-jet stone-like brick and preparation method thereof |
| CN113388344A (en) * | 2021-06-08 | 2021-09-14 | 佛山市三水区康立泰无机合成材料有限公司 | Dry-particle glaze glue and preparation method thereof |
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