CN108157379A - Containing pyroxsulam He metamifop Herbicidal combinations - Google Patents
Containing pyroxsulam He metamifop Herbicidal combinations Download PDFInfo
- Publication number
- CN108157379A CN108157379A CN201810039386.5A CN201810039386A CN108157379A CN 108157379 A CN108157379 A CN 108157379A CN 201810039386 A CN201810039386 A CN 201810039386A CN 108157379 A CN108157379 A CN 108157379A
- Authority
- CN
- China
- Prior art keywords
- pyroxsulam
- herbicidal combinations
- active ingredient
- composition
- metamifop
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000005607 Pyroxsulam Substances 0.000 title claims abstract description 39
- GLBLPMUBLHYFCW-UHFFFAOYSA-N n-(5,7-dimethoxy-[1,2,4]triazolo[1,5-a]pyrimidin-2-yl)-2-methoxy-4-(trifluoromethyl)pyridine-3-sulfonamide Chemical compound N1=C2N=C(OC)C=C(OC)N2N=C1NS(=O)(=O)C1=C(OC)N=CC=C1C(F)(F)F GLBLPMUBLHYFCW-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 28
- ADDQHLREJDZPMT-AWEZNQCLSA-N (S)-metamifop Chemical compound O=C([C@@H](OC=1C=CC(OC=2OC3=CC(Cl)=CC=C3N=2)=CC=1)C)N(C)C1=CC=CC=C1F ADDQHLREJDZPMT-AWEZNQCLSA-N 0.000 title claims abstract description 19
- 239000000203 mixture Substances 0.000 claims abstract description 44
- 239000004480 active ingredient Substances 0.000 claims abstract description 21
- 230000002195 synergetic effect Effects 0.000 claims abstract description 10
- 239000000575 pesticide Substances 0.000 claims abstract description 4
- 241000196324 Embryophyta Species 0.000 claims description 22
- -1 wettable Pulvis Substances 0.000 claims description 13
- 239000000375 suspending agent Substances 0.000 claims description 8
- 240000003173 Drymaria cordata Species 0.000 claims description 6
- 244000058871 Echinochloa crus-galli Species 0.000 claims description 6
- 239000002552 dosage form Substances 0.000 claims description 6
- 244000025254 Cannabis sativa Species 0.000 claims description 5
- 210000000582 semen Anatomy 0.000 claims description 5
- 239000004562 water dispersible granule Substances 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 4
- 239000002671 adjuvant Substances 0.000 claims description 2
- 239000002917 insecticide Substances 0.000 claims description 2
- 241000981770 Buddleja asiatica Species 0.000 claims 1
- 239000004009 herbicide Substances 0.000 abstract description 9
- 238000012360 testing method Methods 0.000 abstract description 7
- 238000001228 spectrum Methods 0.000 abstract description 4
- 239000003337 fertilizer Substances 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- ATWGHWZRHOJITC-UHFFFAOYSA-N [S].C1=CC=NC=C1 Chemical compound [S].C1=CC=NC=C1 ATWGHWZRHOJITC-UHFFFAOYSA-N 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 231100000419 toxicity Toxicity 0.000 description 7
- 230000001988 toxicity Effects 0.000 description 7
- 239000012752 auxiliary agent Substances 0.000 description 6
- 238000013329 compounding Methods 0.000 description 6
- 239000000470 constituent Substances 0.000 description 6
- 235000019441 ethanol Nutrition 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 240000007594 Oryza sativa Species 0.000 description 5
- 235000007164 Oryza sativa Nutrition 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 235000009566 rice Nutrition 0.000 description 5
- 231100000820 toxicity test Toxicity 0.000 description 5
- 238000009333 weeding Methods 0.000 description 5
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 244000304962 green bristle grass Species 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 239000004563 wettable powder Substances 0.000 description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000000440 bentonite Substances 0.000 description 3
- 229910000278 bentonite Inorganic materials 0.000 description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N dimethyl sulfoxide Natural products CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 229920005610 lignin Polymers 0.000 description 3
- 229920000151 polyglycol Polymers 0.000 description 3
- 239000010695 polyglycol Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 description 3
- 239000008158 vegetable oil Substances 0.000 description 3
- 206010059866 Drug resistance Diseases 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 235000010086 Setaria viridis var. viridis Nutrition 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000000274 adsorptive effect Effects 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 230000003111 delayed effect Effects 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 2
- 150000002790 naphthalenes Chemical class 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000009331 sowing Methods 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 229940124530 sulfonamide Drugs 0.000 description 2
- WHOZNOZYMBRCBL-OUKQBFOZSA-N (2E)-2-Tetradecenal Chemical compound CCCCCCCCCCC\C=C\C=O WHOZNOZYMBRCBL-OUKQBFOZSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- NWACCXJCJNDIDK-UHFFFAOYSA-N 1,2,3-tributylbenzene Chemical compound CCCCC1=CC=CC(CCCC)=C1CCCC NWACCXJCJNDIDK-UHFFFAOYSA-N 0.000 description 1
- XXKHDSGLCLCFSC-UHFFFAOYSA-N 2,3-diphenylphenol Chemical compound C=1C=CC=CC=1C=1C(O)=CC=CC=1C1=CC=CC=C1 XXKHDSGLCLCFSC-UHFFFAOYSA-N 0.000 description 1
- NFAOATPOYUWEHM-UHFFFAOYSA-N 2-(6-methylheptyl)phenol Chemical class CC(C)CCCCCC1=CC=CC=C1O NFAOATPOYUWEHM-UHFFFAOYSA-N 0.000 description 1
- SXERGJJQSKIUIC-UHFFFAOYSA-N 2-Phenoxypropionic acid Chemical compound OC(=O)C(C)OC1=CC=CC=C1 SXERGJJQSKIUIC-UHFFFAOYSA-N 0.000 description 1
- WTLNOANVTIKPEE-UHFFFAOYSA-N 2-acetyloxypropanoic acid Chemical compound OC(=O)C(C)OC(C)=O WTLNOANVTIKPEE-UHFFFAOYSA-N 0.000 description 1
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 240000001592 Amaranthus caudatus Species 0.000 description 1
- 235000009328 Amaranthus caudatus Nutrition 0.000 description 1
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 235000007320 Avena fatua Nutrition 0.000 description 1
- 244000075850 Avena orientalis Species 0.000 description 1
- 235000007319 Avena orientalis Nutrition 0.000 description 1
- 235000007558 Avena sp Nutrition 0.000 description 1
- 241001647031 Avena sterilis Species 0.000 description 1
- 235000004535 Avena sterilis Nutrition 0.000 description 1
- IKYJYLYATYADEX-ZAGWXBKKSA-N CC\C(\C1=CC=C(O)C=C1)=C(/C1=CC=C(O)C=C1)\CC.C1=CC=CC=C1 Chemical compound CC\C(\C1=CC=C(O)C=C1)=C(/C1=CC=C(O)C=C1)\CC.C1=CC=CC=C1 IKYJYLYATYADEX-ZAGWXBKKSA-N 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 235000011305 Capsella bursa pastoris Nutrition 0.000 description 1
- 240000008867 Capsella bursa-pastoris Species 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 244000264242 Descurainia sophia Species 0.000 description 1
- 235000017680 Descurainia sophia Nutrition 0.000 description 1
- 244000025670 Eleusine indica Species 0.000 description 1
- 235000014716 Eleusine indica Nutrition 0.000 description 1
- 241001553700 Euphorbia lathyris Species 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- YPWFISCTZQNZAU-UHFFFAOYSA-N Thiane Chemical compound C1CCSCC1 YPWFISCTZQNZAU-UHFFFAOYSA-N 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 150000005693 branched-chain amino acids Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000032823 cell division Effects 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 230000000266 injurious effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 150000002916 oxazoles Chemical class 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 229940044654 phenolsulfonic acid Drugs 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N phthalic anhydride Chemical compound C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- KKDONKAYVYTWGY-UHFFFAOYSA-M sodium;2-(methylamino)ethanesulfonate Chemical compound [Na+].CNCCS([O-])(=O)=O KKDONKAYVYTWGY-UHFFFAOYSA-M 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 150000003456 sulfonamides Chemical group 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 230000005945 translocation Effects 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of Herbicidal combinations with synergistic effect, active ingredient pyroxsulam is contained in the composition He metamifop.The weight ratio of active ingredient pyroxsulam and metamifop can be 5~1：1~30.The test of pesticide effectiveness shows that the composition has the characteristics that with strong complementarity, synergistic effect is apparent, herbicide controlling spectrum expands, amount of application is reduced, the optimum period for applying fertilizer extends, high, environmental pollution reduces, is by force etc. positive with environment compatibility to crop safety.
Description
Technical field
The invention belongs to agriculture plant protection field, more particularly to a kind of Herbicidal combinations for having and improving performance.
Background technology
Active component pyroxsulam is triazolopyrimidine sulfonamides herbicide.Pyroxsulam is sulfonamides Uptake and translocation
Property, selective herbicide after seedling, herbicidal spectrum is wide, activity of weeding is high, drug action is fast.Pass through grass cutting blade, sheath portion, stem or root
Portion absorbs, and is accumulated in growing point, inhibits acetolactate synthestase, can not synthesize branched-chain amino acid, and then influence the conjunction of protein
Into, weeds cell division is influenced, weeds is caused to stop growing, yellow, it is then dead.Pyroxsulam to wheat, barley, oat,
Corn and soybean, rice, cotton, peanut safety, can effectively management of weeds amur foxtail, ox chickweed, Descurainia sophia, wild oat, shepherd's purse
Deng.
Huo Zu Fen metamifops (metamifop) are the fragrant phenoxy propionic acid developed by Chemical Engineering Technology research institute of South Korea
Ester herbicide, can be fabulous prevent and kill off most of annual gramineous weeds, the , oxazoles unlike most of such herbicides
Acyl grass amine can effectively prevent and kill off rice terrace main weeds, such as barnyard grass, moleplant seed, lady's-grass and eleusine indica, be mainly used for rice safety
Transplanting and direct sowing rice field weeding.Metamifop low toxicity, it is environmentally safe, there is extensive miscibilty, and be expected to be used for other works
Object and Kill weeds are a very promising herbicides.
Practical pesticide experience have shown that, repeat and single-minded carry out controlling weeds in many feelings using a kind of reactive compound
The fast selective that will lead to weeds under condition prevents injurious weed usually using the mixture of different activities compound at present.
By the way that the reactive compound with different role mechanism is combined, can delaying drug resistance generate, reduce amount of application, reduce prevention
Cost.
Invention content
The purpose of the present invention is being directed to herbicide resistance and pedo relict problem in practical applications, filter out containing two
The herbicide of the different weeding principles of kind is compounded, and to improve herbicide prevention effect, delaying drug resistance generates, and reduces amount of application,
Reduce cost accounting.
It is a further object of the present invention to provide a kind of application of above-mentioned composition in agriculture field controlling weeds.
The purpose of the present invention can be achieved by the following measures：
The present invention provides a kind of Herbicidal combinations with synergistic effect, contain effective constituents A and B in the composition,
Effective constituents A is pyroxsulam, active ingredient B Wei metamifops.
Inventor is found by experiment that above-mentioned Herbicidal combinations synergy is apparent, it is often more important that amount of application is reduced, and reduction makes
Contain that component A is different from the compound structure type of component B, and mechanism of action is different with cost, the two compounding can expand weeding
Spectrum, and generation and the development speed of Weed Resistance can be delayed to a certain extent, and no interactions between component A and component B
Resistance.
The active ingredient of the present composition can be only comprising A and B, can also be in the base for not influencing composition overall performance
On plinth, other active ingredients are further included.
In a kind of scheme, the active ingredient pyroxsulam of Herbicidal combinations of the present invention is He the weight ratio of metamifop is
5~1：1~30.
Active ingredient pyroxsulam in a kind of preferred embodiment is He the weight ratio of metamifop is 1：1~25, in another kind
In scheme, the active ingredient pyroxsulam of Herbicidal combinations of the present invention is He the weight ratio of metamifop is 1：5~20.
In a kind of preferred scheme, the weight ratio between two component of A and B can be arbitrarily in the range of following proportionings
It is adjusted：5：1、4：1、3：1、2：1、1：1、1：2、1：3、1：4、1：5、1：6、1：7、1：8、1：9、1：10、1：11、1：12、
1：13、1：14、1：15、1：16、1：17、1：18、1：19、1：20、1：21、1：22、1：23、1：24、1：25、1：26、1：27、1：
28、1：29、1：30, it can also be selected in the range of two proportionings of any of the above form.
The composition of the present invention acceptable dosage form on pesticide can be made jointly by active ingredient and insecticides adjuvant.
The weight percentage of active ingredient can be 2~95%, preferably 5~85% in the composition of the present invention.
Carrier, auxiliary agent and/or surfactant can be included in the present composition.It can be mixed during application
Common auxiliary agent.
Suitable auxiliary agent can be solid or liquid, they are typically common substance during formulation, such as day
Right or regenerated minerals, solvent, dispersant, wetting agent, adhesive, thickener, adhesive or fertilizer.
The method of administration of the present composition includes for the composition of the present invention being used for the aerial part of plant growth, especially
It is leaf portion or blade face.The frequency and amount of application of application depend on the biology of weeds and weather life condition.It can be by plant
Place is grown, such as rice field is soaked with the liquid preparation of composition or is applied to composition in soil in solid form, such as
(soil application) in granular form, composition can be entered in plant (systemic action) by soil through plant root.
These compositions can only include active constituent (also known as active ingredient) and be administered, can also with additive or
Auxiliary agent mixes together, therefore the composition of the present invention can be prepared into various dosage forms, for example, wettable powder, suspending agent,
Dispersible oil-suspending agent, aqueous emulsion, missible oil, microemulsion, water dispersible granules etc..According to the property and administration group of these compositions
Object institute's purpose to be achieved and ambient conditions are closed, can be selected composition to spray, atomizing, be dusted, broadcast sowing or sprinkle and pour etc. it
The method application of class.
The composition of the present invention can be prepared into various dosage forms by known method, it such as can be by active ingredient with helping
Agent such as solvent, solid carrier, can uniformly mix together with surfactant when needing, grind, be prepared into required dose
Type.
Above-mentioned solvent may be selected from aromatic hydrocarbon, preferably containing 8-12 carbon atom, such as xylene mixture or substituted benzene, phthalein
Esters of gallic acid, such as Dibutyl phthalate or the octanoic acid of phthalandione two, fat hydrocarbon, such as thiacyclohexane or paraffin, alcohol and ethylene glycol and their ether
And ester, such as ethyl alcohol, ethylene glycol, ethylene glycol monomethyl；Ketone, such as cyclohexanone, highly polar solvent, such as N- methyl -2- pyrrolidines
Ketone, dimethyl sulfoxide (DMSO) or dimethylformamide and vegetable oil or vegetable oil, such as soybean oil.
Above-mentioned solid carrier, such as pulvis and dispersible dose of typically natural mineral fillers, such as talcum, kaolinite
Soil, montmorillonite or atlapulgite.In order to manage the physical property of composition, polymolecularity silicic acid or polymolecularity can also be added in
Adsorpting polymerization object carrier, such as granulated adsorptive carriers or non-adsorbed carrier, suitable granulated adsorptive carriers are porous types, it is such as floating
Stone, bentonite or bentonite；Suitable non-adsorbed carrier such as calcite or sand.Further, it is possible to use a large amount of inorganic in nature or having
The prefabricated material to granulate of machine property is as carrier, particularly dolomite.
The chemical property of active ingredient in composition according to the present invention, suitable surfactant are sulfomethylated lignin
Acid, naphthalene sulfonic acids, phenolsulfonic acid, alkali salt or amine salt, alkylaryl sulfonates, alkyl sulfate, alkylsulfonate, fat
Alcohol sulfate, aliphatic acid and sulphated fatty alcohol glycol ether, the also condensation product of sulfonated naphthalene and naphthalene derivatives and formaldehyde, naphthalene or
Naphthalene sulfonic acids and phenol and the condensation product of formaldehyde, NONIN HS 240, ethoxylated isooctyl-phenol, octyl phenol, nonyl phenol,
Alkylaryl polyglycol ether, tributyl benzene polyglycol ether, three stearyl phenyl polyglycol ethers, alkyl aryl polyether alcohol,
Ethoxylated castor oil, polyoxyethylene alkyl ether, ethylene oxide condensation product, ethoxylation polyoxypropylene, bay acid polyethylene glycol
Ether acetal, sorbitol ester, lignin sulfite waste liquor and methylcellulose.
Two kinds of active ingredients show as synergistic effect in the composition of the present invention, and the activity of the composition is than using individualized
The expected summation of activity of conjunction object and the independent activity of single compound are more notable.Synergistic effect shows as allowing amount of application
Reduction, broader weeding control spectrum, quick, more longlasting control effect, by only once or a small number of several times using more preferable
Control weeds and broaden the possible administration interval time.These characteristics are to prevent and kill off in control weeds practice process especially
It needs.
The Herbicidal combinations of the present invention can be applicable to significant effect in terms of agriculture field prevention crop weeds, particularly anti-
Control Semen Cuscutae, green bristlegrass, barnyard grass and ox chickweed.
The other features shown of the Herbicidal combinations of the present invention are mainly shown as：1st, due to two lists of this composition
Agent chemical constitution is widely different, and the mechanism of action is entirely different, and there is no cross resistances, and two single dose exclusive uses can be delayed to be produced
Raw resistance problem；2nd, composition of the invention is good to crop safety, preventive effect.Tests prove that herbicidal composition of the present invention
Chemical property is stablized, and synergy is notable, and apparent synergy and complementation are shown to controlling object.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that specific embodiment described herein is not used to limit only to explain the present invention
The fixed present invention, any modifications, equivalent replacements and improvementsmade within the spirit and principles of the invention, etc., should be included in
Within protection scope of the present invention.
Percentage is weight percentage in all formulas of following embodiment.The processing work of the various preparations of the present composition
Skill is the prior art, can be varied from according to different situations.
First, dosage form prepares embodiment
(1) processing of missible oil and embodiment
Active constituent pyroxsulam Yu metamifop, emulsifier and solvent etc. are sufficiently mixed in proportion, you can.
Embodiment 1:33% pyridine sulphur Cao An metamifop missible oil
3% , metamifops 30% of pyroxsulam, benzene diethylstilbestrol polyoxyethylene ether 15%, polyoxyethylene alcohol 12%, soybean oil
Complement to 100%.
Embodiment 2：62% pyridine sulphur Cao An metamifop missible oil
2% , metamifops 60% of pyroxsulam, alkylbenzene naphthalene sulfonate 10%, castor oil ethylene oxide adduct
15%, mineral oil complements to 100%.
(2) processing of dispersible oil-suspending agent and embodiment
Active constituent pyroxsulam Yu metamifop and suspending agent, surfactant, oil phase component etc. are filled in proportion
Divide mixing, you can dispersible oil-suspending agent is made.
Embodiment 3：The 12% dispersible oil-suspending agent of pyridine sulphur Cao An metamifops
10% , metamifops 2% of pyroxsulam, diphenyl phenol polyethenoxy polyethenoxy ether 10%, xanthans
1.6%, fatty acid amide N methyl taurine sodium salt 8%, vegetable oil complements to 100%.
Embodiment 4：The 21% dispersible oil-suspending agent of pyridine sulphur Cao An metamifops
1% , metamifops 20% of pyroxsulam, hydroxymethyl cellulose 3%, fatty alcohol polyoxyethylene ether 8%, polyethylene
Alcohol 16%, mineral oil complements to 100%.
(3) processing of wettable powder and embodiment
Active component pyroxsulam Yu metamifop and various auxiliary agents and filler etc. are sufficiently mixed in proportion, through ultra-fine
Wettable powder is made after crushing in pulverizer.
Embodiment 5：6% pyridine sulphur Cao An metamifop wettable powders
1% , metamifops 5% of pyroxsulam, ammonium sulfate 8%, NONIN HS 240 10%, lignin sulfonic acid
Salt 12%, attapulgite complements to 100%.
Embodiment 6：78% pyridine sulphur Cao An metamifop wettable powders
3% , metamifops 75% of pyroxsulam, aluminium chloride 5%, alkyl sulfate 5%, precipitated calcium carbonate complements to
100%.
(4) processing of water dispersible granules and embodiment
By active constituent pyroxsulam and Huo Cheng Fen metamifops, mixed in the ratio of formula with auxiliary agent and filler
It is even, through air-flow crushing into wettable powder, a certain amount of water mixing extruder grain is added, moisture, which is made, after dry sieve dissipates
Granula product.
Embodiment 7:50% pyridine sulphur Cao An metamifop water dispersible granules
25% , metamifops 25% of pyroxsulam, lauryl sodium sulfate 12%, bentonite 3%, aluminium-magnesium silicate 3%,
White carbon supply is to 100%.
Embodiment 8:40% pyridine sulphur Cao An metamifop water dispersible granules
2.5% , metamifops 37.5% of pyroxsulam, aliphatic alcohol sulfate 15%, aluminium-magnesium silicate 2.4%, spaonin powder
8%, kaolin complements to 100%.
2nd, drug effect verification test
(1) Assays Example
Using pyroxsulam as standard agent, disease index and control effect are calculated.Control effect is converted into niqueMin
(y), liquor strength (μ g/ml) is converted into logarithm (x), concentration EC50 in being calculated virulence equation with least square method and inhibited,
The toxicity index of medicament and co-toxicity coefficient (CTC) are calculated according to the abundant methods of Sun Yun.Toxicity test the results are shown in Table 1.
Survey toxicity index (ATI)=(standard agent EC50/ reagent agent EC50) * 100
Percentage composition+B medicament toxicity index * the mixtures of A in theoretical toxicity index (TTI)=A medicament toxicity index * mixtures
The percentage composition of middle B
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theoretical toxicity index (TTI)] * 100
CTC≤80, composition show as antagonism, 80 ＜ CTC ＜ 120, and composition shows as summation action, and CTC >=
120, composition shows as synergistic effect.
1st, pyroxsulam Yu metamifops compounding tests (one) to the toxicity test of barnyard grass
1 pyroxsulam Yu metamifops different ratio of table, which compounds, analyzes the toxicity test of barnyard grass
As a result (table 1) shows pyroxsulam Yu metamifops in proportioning 5~1：Between 1~30, co-toxicity coefficient exists
More than 120, illustrate that pyroxsulam Yu metamifops compound preventing and kill off with significant synergistic function to barnyard grass.
2nd, pyroxsulam Yu metamifops compounding tests (two) to the toxicity test of Semen Cuscutae grass
The Semen Cuscutae grass toxicity test interpretation of result of 2 pyroxsulam Yu metamifops of table compounding pair
As a result (table 2) shows pyroxsulam Yu metamifops in proportioning 5~1：Between 1~30, co-toxicity coefficient exists
More than 120, illustrate that pyroxsulam Yu metamifops compound preventing and kill off with significant synergistic function to Semen Cuscutae weeds.
(2) field control effectiveness test
1st, the field control effect of pyroxsulam Yu metamifops is verified using embodiment produced by the present invention.
It is expected that preventive effect (%)=X+Y-XY/100 (wherein, X, Y are single dose preventive effect)
3. pyroxsulam Yu metamifops of table compound the field efficiency test result to green bristlegrass and ox chickweed
Measurement result (table 3) shows pyroxsulam Yu metamifops compounding to controlling weeds green bristlegrass and ox chickweed
Preventive effect significantly improves, and illustrates that the two compounding has significant synergistic function to weeds green bristlegrass and ox chickweed.
Claims (10)
1. a kind of Herbicidal combinations with synergistic effect, it is characterised in that in the composition containing active ingredient pyroxsulam and
Metamifop.
2. Herbicidal combinations according to claim 1, it is characterised in that the active ingredient pyroxsulam is He oxazole acyl is careless
The weight ratio of amine is 5~1：1~30.
3. Herbicidal combinations according to claim 2, it is characterised in that the active ingredient pyroxsulam is He oxazole acyl is careless
The weight ratio of amine is 1：1~25.
4. Herbicidal combinations according to claim 3, it is characterised in that the active ingredient pyroxsulam is He oxazole acyl is careless
The weight ratio of amine is 1：5~20.
5. Herbicidal combinations according to claim 1, it is characterised in that the composition is total to by active ingredient and insecticides adjuvant
It is same that acceptable dosage form on pesticide is made.
6. Herbicidal combinations according to claim 5, it is characterised in that the weight percent of active ingredient contains in the composition
Measure is 2~95%.
7. Herbicidal combinations according to claim 6, it is characterised in that the weight percent of active ingredient contains in the composition
Measure is 5~85%.
8. Herbicidal combinations according to claim 5, it is characterised in that the dosage form is dispersible oil-suspending agent, wettable
Pulvis, water dispersible granules or missible oil.
9. purposes of the Herbicidal combinations described in claim 1 in terms of agriculture field prevents crop weeds.
10. purposes according to claim 9, it is characterised in that the weeds are selected from Semen Cuscutae, barnyard grass, ox chickweed, dog tail
Grass.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810039386.5A CN108157379A (en) | 2018-01-16 | 2018-01-16 | Containing pyroxsulam He metamifop Herbicidal combinations |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810039386.5A CN108157379A (en) | 2018-01-16 | 2018-01-16 | Containing pyroxsulam He metamifop Herbicidal combinations |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108157379A true CN108157379A (en) | 2018-06-15 |
Family
ID=62514843
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810039386.5A Pending CN108157379A (en) | 2018-01-16 | 2018-01-16 | Containing pyroxsulam He metamifop Herbicidal combinations |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108157379A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105766899A (en) * | 2010-07-15 | 2016-07-20 | 陶氏益农公司 | Solid Herbicide Compositions With Built-in Adjuvant |
| CN107372543A (en) * | 2017-08-10 | 2017-11-24 | 江苏辉丰农化股份有限公司 | The Herbicidal combinations of Han You metamifops and Flumetsulam |
-
2018
- 2018-01-16 CN CN201810039386.5A patent/CN108157379A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105766899A (en) * | 2010-07-15 | 2016-07-20 | 陶氏益农公司 | Solid Herbicide Compositions With Built-in Adjuvant |
| CN107372543A (en) * | 2017-08-10 | 2017-11-24 | 江苏辉丰农化股份有限公司 | The Herbicidal combinations of Han You metamifops and Flumetsulam |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106305757B (en) | A kind of Synergistic herbicide compositions grand comprising diflufenican and thiophene ketone sulphur | |
| CN103392732A (en) | Herbicidal composition containing glufosinate-ammonium and saflufenacil | |
| CN106561659B (en) | A kind of effective component is the Herbicidal combinations of diflufenican and pretilachlor | |
| CN106259349B (en) | Herbicidal combinations with synergistic effect | |
| CN106259356B (en) | Herbicidal combinations with synergistic effect | |
| CN102812961B (en) | Weeding composition with synergistic effect | |
| CN106259344B (en) | Herbicidal combinations with synergistic effect | |
| CN106386817B (en) | Herbicidal combinations with synergistic effect | |
| CN105248433A (en) | Weeding compound containing 2-methyl-4-chloro-phenoxyacetic acid and oxaziclomefone | |
| CN106259357A (en) | There is the Herbicidal combinations of potentiation | |
| CN106332885B (en) | Herbicidal combinations with synergistic effect | |
| CN107616183A (en) | Herbicidal combinations containing flufenacet Yu clomazones | |
| CN107396932A (en) | A kind of Han You metamifops and the Herbicidal combinations of the chlorine of 2 first 4 | |
| CN106472513B (en) | A kind of Synergistic herbicide compositions comprising diflufenican and pyriftalid | |
| CN108077282A (en) | Herbicidal combinations containing ring sulphur Tong Yu oxaziclomefones | |
| CN106472518B (en) | A kind of Synergistic herbicide compositions comprising amicarbazone and AC 263222 | |
| CN107372543A (en) | The Herbicidal combinations of Han You metamifops and Flumetsulam | |
| CN108157379A (en) | Containing pyroxsulam He metamifop Herbicidal combinations | |
| CN108338179A (en) | Containing flucarbazone He the Herbicidal combinations of metamifop | |
| CN106359407B (en) | Herbicidal combinations with synergistic effect | |
| CN107156137A (en) | Herbicidal combinations containing Quizalotop-ethyl and ethoxysulfuron | |
| CN106912487A (en) | Herbicidal combinations with synergistic effect | |
| CN107616182A (en) | Herbicidal combinations containing flufenacet and haloxyfop-r-methyl | |
| CN102613181B (en) | Weeding combination | |
| CN102613180A (en) | Weeding composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180615 |