CN108130199A - Efficient color protection liquid detergent and preparation method thereof - Google Patents
Efficient color protection liquid detergent and preparation method thereof Download PDFInfo
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- CN108130199A CN108130199A CN201711415619.9A CN201711415619A CN108130199A CN 108130199 A CN108130199 A CN 108130199A CN 201711415619 A CN201711415619 A CN 201711415619A CN 108130199 A CN108130199 A CN 108130199A
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- surfactant
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- liquid detergent
- protection liquid
- polynary
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- 239000003599 detergent Substances 0.000 title claims abstract description 46
- 239000007788 liquid Substances 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title claims abstract description 27
- 239000004094 surface-active agent Substances 0.000 claims abstract description 40
- 239000003381 stabilizer Substances 0.000 claims abstract description 19
- 239000002562 thickening agent Substances 0.000 claims abstract description 17
- 239000003755 preservative agent Substances 0.000 claims abstract description 16
- 230000002335 preservative effect Effects 0.000 claims abstract description 16
- 239000002738 chelating agent Substances 0.000 claims abstract description 8
- 239000006081 fluorescent whitening agent Substances 0.000 claims abstract description 8
- 230000000694 effects Effects 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000470 constituent Substances 0.000 claims abstract description 5
- 239000003945 anionic surfactant Substances 0.000 claims description 34
- 239000002736 nonionic surfactant Substances 0.000 claims description 26
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 24
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 24
- 239000000344 soap Substances 0.000 claims description 22
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 21
- 239000000194 fatty acid Substances 0.000 claims description 21
- 229930195729 fatty acid Natural products 0.000 claims description 21
- 150000004665 fatty acids Chemical class 0.000 claims description 21
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 16
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 14
- 235000011152 sodium sulphate Nutrition 0.000 claims description 14
- 150000002191 fatty alcohols Chemical class 0.000 claims description 13
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 13
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 13
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical compound CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 claims description 12
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 12
- 239000011780 sodium chloride Substances 0.000 claims description 12
- 239000000686 essence Substances 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 10
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 9
- 229960005323 phenoxyethanol Drugs 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 150000005846 sugar alcohols Polymers 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 6
- 230000003213 activating effect Effects 0.000 claims description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 4
- PIGKXHAIBGNREV-UHFFFAOYSA-N C1=CC=CC=C1C1=CC=CC=C1.C=1C=CC=CC=1C=CC1=CC=CC=C1 Chemical group C1=CC=CC=C1C1=CC=CC=C1.C=1C=CC=CC=1C=CC1=CC=CC=C1 PIGKXHAIBGNREV-UHFFFAOYSA-N 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 229920000075 poly(4-vinylpyridine) Polymers 0.000 claims description 3
- -1 polyoxy Polymers 0.000 claims description 3
- 239000001509 sodium citrate Substances 0.000 claims description 3
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 3
- 238000007127 saponification reaction Methods 0.000 claims description 2
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 claims description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 125000000129 anionic group Chemical group 0.000 claims 1
- 238000005282 brightening Methods 0.000 claims 1
- 239000004615 ingredient Substances 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 19
- 238000005406 washing Methods 0.000 abstract description 17
- 238000011109 contamination Methods 0.000 abstract description 6
- 239000000463 material Substances 0.000 abstract description 3
- 238000004140 cleaning Methods 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 description 31
- 239000000126 substance Substances 0.000 description 26
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 8
- 238000010422 painting Methods 0.000 description 8
- 241000322338 Loeseliastrum Species 0.000 description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 235000010290 biphenyl Nutrition 0.000 description 4
- 239000004305 biphenyl Substances 0.000 description 4
- 235000013305 food Nutrition 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000000975 dye Substances 0.000 description 3
- 238000004453 electron probe microanalysis Methods 0.000 description 3
- UFZOPKFMKMAWLU-UHFFFAOYSA-N ethoxy(methyl)phosphinic acid Chemical compound CCOP(C)(O)=O UFZOPKFMKMAWLU-UHFFFAOYSA-N 0.000 description 3
- 244000248349 Citrus limon Species 0.000 description 2
- 235000005979 Citrus limon Nutrition 0.000 description 2
- HDWLUGYOLUHEMN-UHFFFAOYSA-N Dinobuton Chemical compound CCC(C)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1OC(=O)OC(C)C HDWLUGYOLUHEMN-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 241000425573 Talanes Species 0.000 description 2
- 125000005233 alkylalcohol group Chemical group 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 239000012669 liquid formulation Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 150000003839 salts Chemical group 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/187—Hydrocarbons aromatic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to mainly using surface active cpd as the cleaning compositions field of base-material, specially a kind of efficient color protection liquid detergent and preparation method thereof.A kind of efficient color protection liquid detergent, it is characterized in that：It is uniformly mixed by following component：Constituent mass percent concentration (%)：Polynary surfactant 15~30；Color stabilizer 0.1~3；Chelating agent 1~5；Fluorescent whitening agent 0~5；Preservative 0.1~1；Essence 0.1~1；Thickener 0.1~1；Water surplus.Washing effect of the present invention is good, reduces fabric color loss, prevents fabric washing colour contamination.
Description
Technical field
The present invention relates to mainly using surface active cpd as the cleaning compositions field of base-material, specially one kind is efficiently protected
Color liquid detergent and preparation method thereof.
Background technology
With the improvement of living standards, consumer is also more and more diversified to the demand of liquid detergent, in addition to basic washing
Function, also it is desirable to which it has fabric the effects that protection and nursing.Often occur colored fabric in daily washing fade, is white and deep
Yarn dyed fabric shuffles the phenomenon that colour contamination, this with fabric the color fastness in dyeing course it is insufficient, repeatedly washing, high-temperature wash, be exposed to the sun
Factor is related, and clothing color protection solution problem most efficient method is that the shield that can play color-protecting function is added in laundry liquid formulation at present
Toner.Common color stabilizer has non-ionic and two class of cationic, but non-ionic color stabilizer effect of color protection is limited, most of sun
Ionic color stabilizer and anion surfactant, there are compatibility issues for fluorescent whitening agent.
Invention content
The defects of in order to overcome the prior art, provide a kind of washing effect it is good, reduce fabric color loss, prevent fabric washing
The detergent of colour contamination is washed, the invention discloses a kind of efficient color protection liquid detergents and preparation method thereof.
The present invention reaches goal of the invention by following technical solution：
A kind of efficient color protection liquid detergent, it is characterized in that：It is uniformly mixed by following component：
Wherein：Polynary surfactant includes anion surfactant, nonionic surfactant and fatty acid soaps, cloudy
Ionic surface active agent is selected in sulfonate surfactant, sulfuric acid type surfactant and carboxylic acid type surfactant extremely
Few one kind；Nonionic surfactant selects at least one of fatty alcohol polyoxyethylene ether and modified ethoxylate object；Fat
The general structure of sour soap is RCOONa, and R selects C in formula8-C18、C12-C18Or C12、C14、C16、C18；
Color stabilizer selects poly 4 vinyl pyridine nitrogen oxides, and the physicochemical property of color stabilizer is as follows：Degree of oxidation >=
90%, active constituent 33%~37%, Ghana's moral (i.e. Gardn) coloration 6~13, viscosity 40cps~80cps, pH value 4.0~
5.0；
Chelating agent selects sodium citrate；
Fluorescent whitening agent selects stilbene biphenyl type；
Stilbene biphenyl fluorescent brightener is a kind of compound caused by the conjugated system of talan extends, this
The characteristics of class substance is：Containing biphenyl structural unit in its skeleton, the contraposition of biphenyl usually with styrene or other alkene
Double bond is connected, and forms conjugated system.Their structure is similar, and only the substituent group on the phenyl ring of outside is different.It is generally available following formula
It represents：
Preservative selects at least one of Kathon CG, polyalcohols and Phenoxyethanol；
Essence selects commercially available common daily essence, such as food lemon extract or food flowers and fruits essence；
Thickener selects at least one of sodium chloride, sodium sulphate and polyacrylic polymer.
The efficient color protection liquid detergent, it is characterized in that：
Anion surfactant in polynary surfactant selects benzene sulfonic acid sodium salt and multi-alcohol polyoxyethylene ether
At least one of sodium sulphate, the general structure of multi-alcohol polyethenoxy ether sodium sulfate is R (OC2H4)nSO3Na, R in formula
For C12-C15Or C12-C14Alkylol, n take 2 or 3；Nonionic surfactant in polynary surfactant selects poly alkyl alcohol
Ethylene oxide ether, the general structure of fatty alcohol polyoxyethylene ether are：R(OC2H4)nOH, R is C in formula12-C15Or C12-C14Alkylol, n
Take the positive integer in the range of 3~11, wherein n take the constituent mass of 5~9 ranges account for nonionic surfactant quality 60%~
70%.
The efficient color protection liquid detergent, it is characterized in that：
The mass percent concentration of anion surfactant in polynary surfactant is 10%~20%, anion
Surfactant selects -70 type of sodium sulfate of polyethenoxy ether of fatty alcohol；Nonionic surfactant in polynary surfactant
Mass percent concentration for 10%~20%, nonionic surfactant selects fatty alcohol polyoxyethylene ether -9, poly alkyl alcohol
At least one of ethylene oxide ether -7 and fatty alcohol polyoxyethylene ether -3；The quality hundred of fatty acid soaps in polynary surfactant
It is 1%~5% to divide specific concentration, during the mixture or carbon chain lengths that fatty acid soaps selection carbon chain lengths are 8~18 are 12~18
Any one or carbon chain lengths be that 12~18 mixture and sodium hydroxide solution match in 50 DEG C~70 DEG C temperature ranges
Product after abundant saponification down；
The mass percent concentration of color stabilizer is 0.3%~1%；
The mass percent concentration of fluorescent whitening agent is 0.05%~1%.
The preparation method of the efficient color protection liquid detergent, it is characterized in that：Implement successively as follows：
Portions of de-ionized water and aqueous alkali are first added in preparation tank, and temperature is risen to 55 DEG C~65 DEG C, adds in fat
Fat acid, is stirred to fully transparent：Add in chelating agent, stirring and dissolving；It is sequentially added into anion surfactant, non-ionic surface
Activating agent is stirred to whole dissolvings；Then excess water is added in, and cools the temperature to 30 DEG C hereinafter, sequentially adding color stabilizer, glimmering
Optical brightener, preservative, essence, thickener, stirring are filtered to being completely dissolved.
The present invention not only has fabric outstanding colour-preserving function, also has with anion surfactant, fluorescent whitening agent good
Good compatibility has preferably washing dirt-removing power, while consumer's scourability is met, can protect the color of fabric
Pool reduces fabric color loss, reduces mutual colour contamination caused by fabric mixing, washing.
Specific embodiment
It is further illustrated the present invention below by way of specific embodiment.
Embodiment 1
A kind of efficient color protection liquid detergent, it is characterized in that：It is uniformly mixed by following component：
Wherein：Polynary surfactant selects anion surfactant and nonionic surfactant with mass fraction 1:
1 mixing, anion surfactant select sulfonate surfactant, sulfuric acid type surfactant and carboxylic acid type table successively
Face activating agent；Nonionic surfactant selects fatty alcohol polyoxyethylene ether and modified ethoxylate species successively；
Color stabilizer selects poly 4 vinyl pyridine nitrogen oxides, and the physicochemical property of color stabilizer is as follows：Degree of oxidation >=
90%, active constituent 33%~37%, Ghana's moral coloration 6~13, viscosity 40cps~80cps, pH value 4.0~5.0；
Chelating agent selects sodium citrate；
Fluorescent whitening agent selects stilbene biphenyl type；
Stilbene biphenyl fluorescent brightener is a kind of compound caused by the conjugated system of talan extends, this
The characteristics of class substance is：Containing biphenyl structural unit in its skeleton, the contraposition of biphenyl usually with styrene or other alkene
Double bond is connected, and forms conjugated system.Their structure is similar, and only the substituent group on the phenyl ring of outside is different.It is generally available following formula
It represents：
Preservative selects Kathon CG, polyalcohols and Phenoxyethanol successively；
Essence selects commercially available common daily essence, such as food lemon extract or food flowers and fruits essence；
Thickener selects sodium chloride, sodium sulphate and polyacrylic polymer successively.
When prepared by the present embodiment, implement successively as follows：
Portions of de-ionized water and aqueous alkali are first added in preparation tank, and temperature is risen to 55 DEG C~65 DEG C, adds in fat
Fat acid, is stirred to fully transparent：Add in chelating agent, stirring and dissolving；It is sequentially added into anion surfactant, non-ionic surface
Activating agent is stirred to whole dissolvings；Then excess water is added in, and cools the temperature to 30 DEG C hereinafter, sequentially adding color stabilizer, glimmering
Optical brightener, preservative, essence, thickener, stirring are filtered to being completely dissolved.
I. color protection performance
Test method：Color protection liquid detergent, ordinary liquid laundry detergent (not plus color stabilizer) and commercially available color protection is weighed respectively to declare to do washing
Each 2g of liquid is placed in the water washing tank of Terg-O-Tometer, is added in the hard water that 1L hardness is 250ppm and is dissolved completely, respectively adds in each tank
Enter 3 EMPA painting cloths (commercially available, size 6cm × 6cm) and 3 calicos (GB/T7568.2-2008, size 6cm × 6cm), 30 DEG C
Mixing, washing 20min.
The value of chromatism of painting cloth and calico is measured before washing as original value, after color protection experiment, is rinsed through 2 times, after drying
Measure the value of chromatism of painting cloth and calico.Dye migration resistant performance, that is, anti-colour contamination is with calico in front and rear its value of chromatism △ E1 tables of washing
Show, calico △ E1 are smaller, and anti-colour contamination performance is better；With painting cloth, its value of chromatism △ E2 before and after washing are represented solid color, painting cloth △
E2 is smaller, and fixing property is better.Test result is shown in Table 1.
The value of chromatism of calico and painting cloth after 1 mixing, washing of table
Table 1 is shown：With ordinary liquid laundry detergent and commercial laundry liquid phase ratio, calico △ E1 numbers after color protection liquid detergent mixing, washing
Value is smaller, illustrates that color stabilizer is notable to four kinds of EMPA painting cloth dyestuff dye migration resistant function and effect, EMPA painting cloth aberration △ E2
It is whole also smaller, illustrate that the present invention has preferable colour-preserving function.
II. detergency ability
Detergency ability test is with reference to GB/T13174-2008《Dress material detergent detergency and the survey for recycling scourability
It is fixed》It carries out, prepares the slurry of 250ppm, tested using carbon black JB-01, albumen JB-02, sebum JB-03, test
It the results are shown in Table 2.
The decontamination data of 2 color protection liquid detergent of table and ordinary liquid laundry detergent
Table 2 is shown：The dirt-removing power of color protection liquid detergent is preferable than ordinary liquid laundry detergent, and the addition of color stabilizer polymer is conducive to
The detergency of liquid detergent is improved, it is a kind of liquid detergent of high-effective cleansing to illustrate the present invention.
III. stability
Use range estimation test evaluation compatibility.- 18 DEG C of liquid detergent can restore after placing for 24 hours under the conditions of 4 DEG C, and 37 DEG C put
The present embodiment appearance is without layering and precipitate, transparency height after putting 1 year.
Embodiment 2
A kind of efficient color protection liquid detergent, it is characterized in that：It is uniformly mixed by following component：
Wherein：Polynary surfactant selects anion surfactant and nonionic surfactant with mass fraction 1:
The selection substance of 3 mixing, anion surfactant and nonionic surfactant is all same with embodiment 1；
The selection substance and preparation method of other components are all same with embodiment 1.
Embodiment 3
A kind of efficient color protection liquid detergent, it is characterized in that：It is uniformly mixed by following component：
Wherein：Polynary surfactant selects anion surfactant and nonionic surfactant with mass fraction 3:
The selection substance of 1 mixing, anion surfactant and nonionic surfactant is all same with embodiment 1；
The selection substance and preparation method of other components are all same with embodiment 1.
Embodiment 4
A kind of efficient color protection liquid detergent, it is characterized in that：It is uniformly mixed by following component：
Wherein：Polynary surfactant selects anion surfactant and fatty acid soaps with mass fraction 1:1 mixing,
The selection substance of anion surfactant and fatty acid soaps is all same with embodiment 4；
Preservative selects Kathon CG and polyalcohols with mass fraction 1:1 mixing；
Thickener selects sodium chloride and sodium sulphate with mass fraction 1:1 mixing.
The selection substance and preparation method of other components are all same with embodiment 1.
Embodiment 5
A kind of efficient color protection liquid detergent, it is characterized in that：It is uniformly mixed by following component：
Wherein：Polynary surfactant selects anion surfactant and fatty acid soaps with mass fraction 1:3 mixing,
The selection substance of anion surfactant and fatty acid soaps is all same with embodiment 4；
Preservative selects Kathon CG and polyalcohols with mass fraction 1:3 mixing；
Thickener selects sodium chloride and sodium sulphate with mass fraction 1:3 mixing.
The selection substance and preparation method of other components are all same with embodiment 1.
Embodiment 6
A kind of efficient color protection liquid detergent, it is characterized in that：It is uniformly mixed by following component：
Wherein：Polynary surfactant selects anion surfactant and fatty acid soaps with mass fraction 3:1 mixing,
The selection substance of anion surfactant and fatty acid soaps is all same with embodiment 4；
Preservative selects Kathon CG and polyalcohols with mass fraction 3:1 mixing；
Thickener selects sodium chloride and sodium sulphate with mass fraction 3:1 mixing.
The selection substance and preparation method of other components are all same with embodiment 1.
Embodiment 7
A kind of efficient color protection liquid detergent, it is characterized in that：It is uniformly mixed by following component：
Wherein：Polynary surfactant select anion surfactant, nonionic surfactant and fatty acid soaps with
Mass fraction 1:1:1 mixing, anion surfactant select sulfonate surfactant, sulfuric acid type surface-active successively
Agent and carboxylic acid type surfactant；Nonionic surfactant selects fatty alcohol polyoxyethylene ether and modified ethoxylate object successively
Kind；The general structure of fatty acid soaps is RCOONa, and R selects C in formula8-C18、 C12-C18Or C12、C14、C16、C18；
Preservative selects Kathon CG and Phenoxyethanol with mass fraction 1:1 mixing；
Thickener selects sodium chloride and polyacrylic polymer with mass fraction 1:1 mixing.
The selection substance and preparation method of other components are all same with embodiment 1.
Embodiment 8
A kind of efficient color protection liquid detergent, it is characterized in that：It is uniformly mixed by following component：
Wherein：Polynary surfactant select anion surfactant, nonionic surfactant and fatty acid soaps with
Mass fraction 1:3:6 mixing, the selection substance of anion surfactant, nonionic surfactant and fatty acid soaps all and
Embodiment 7 is same；
Preservative selects Kathon CG and Phenoxyethanol with mass fraction 1:3 mixing；
Thickener selects sodium chloride and polyacrylic polymer with mass fraction 1:3 mixing.
The selection substance and preparation method of other components are all same with embodiment 1.
Embodiment 9
A kind of efficient color protection liquid detergent, it is characterized in that：It is uniformly mixed by following component：
Wherein：Polynary surfactant select anion surfactant, nonionic surfactant and fatty acid soaps with
Mass fraction 6:3:1 mixing, the selection substance of anion surfactant, nonionic surfactant and fatty acid soaps all and
Embodiment 7 is same；
Preservative selects Kathon CG and Phenoxyethanol with mass fraction 3:1 mixing；
Thickener selects sodium chloride and polyacrylic polymer with mass fraction 3:1 mixing.
The selection substance and preparation method of other components are all same with embodiment 1.
Embodiment 10
A kind of efficient color protection liquid detergent, it is characterized in that：It is uniformly mixed by following component：
Wherein：Polynary surfactant selects anion surfactant, and anion surfactant selects sulfonic acid successively
Salt form surfactant, sulfuric acid type surfactant and carboxylic acid type surfactant；
Preservative selects Kathon CG, polyalcohols and Phenoxyethanol with mass fraction 1:1:1 mixing；
Thickener selects sodium chloride, sodium sulphate and polyacrylic polymer with mass fraction 1:1:1 mixing.
The selection substance and preparation method of other components are all same with embodiment 1.
Embodiment 11
A kind of efficient color protection liquid detergent, it is characterized in that：It is uniformly mixed by following component：
Wherein：Polynary surfactant selects nonionic surfactant, and nonionic surfactant selects fat successively
Alcohol polyoxyethylene ether and modified ethoxylate species；
Preservative selects Kathon CG, polyalcohols and Phenoxyethanol with mass fraction 1:3:6 mixing；
Thickener selects sodium chloride, sodium sulphate and polyacrylic polymer with mass fraction 1:3:6 mixing.
The selection substance and preparation method of other components are all same with embodiment 1.
Embodiment 12
A kind of efficient color protection liquid detergent, it is characterized in that：It is uniformly mixed by following component：
Wherein：Polynary surfactant selected fatty acid soap, the general structures of fatty acid soaps are RCOONa, and R is selected in formula
C8-C18、C12-C18Or C12、C14、C16、C18；
Preservative selects Kathon CG, polyalcohols and Phenoxyethanol with mass fraction 6:3:1 mixing；
Thickener selects sodium chloride, sodium sulphate and polyacrylic polymer with mass fraction 6:3:1 mixing.
The selection substance and preparation method of other components are all same with embodiment 1.
Embodiment 13
A kind of efficient color protection liquid detergent, it is characterized in that：It is uniformly mixed by following component：
The selection substance of component is all same with embodiment 1；
When prepared by the present embodiment, implement successively as follows：
Portions of de-ionized water and aqueous alkali are first added in preparation tank, and temperature is risen to 55 DEG C~65 DEG C, adds in fat
Fat acid, is stirred to fully transparent：Add in chelating agent, stirring and dissolving；It is sequentially added into anion surfactant, non-ionic surface
Activating agent is stirred to whole dissolvings；Then excess water is added in, and cools the temperature to 30 DEG C hereinafter, sequentially adding color stabilizer, preventing
Rotten agent, essence, thickener, stirring are filtered to being completely dissolved.
Embodiment 14
A kind of efficient color protection liquid detergent, it is characterized in that：It is uniformly mixed by following component：
The selection substance of component is all same with embodiment 2；
Preparation method and embodiment 13 are same.
Embodiment 15
A kind of efficient color protection liquid detergent, it is characterized in that：It is uniformly mixed by following component：
The selection substance of component is all same with embodiment 3；
Preparation method and embodiment 13 are same.
Embodiment 16
A kind of efficient color protection liquid detergent, it is characterized in that：It is uniformly mixed by following component：
The selection substance of component is all same with embodiment 4；
Preparation method and embodiment 13 are same.
Embodiment 17
A kind of efficient color protection liquid detergent, it is characterized in that：It is uniformly mixed by following component：
The selection substance of component is all same with embodiment 5；
Preparation method and embodiment 13 are same.
Embodiment 18
A kind of efficient color protection liquid detergent, it is characterized in that：It is uniformly mixed by following component：
The selection substance of component is all same with embodiment 6；
Preparation method and embodiment 13 are same.
Claims (4)
1. a kind of efficient color protection liquid detergent, it is characterized in that：It is uniformly mixed by following component：
Wherein：Polynary surfactant includes anion surfactant, nonionic surfactant and fatty acid soaps, anion
Surfactant selects at least one in sulfonate surfactant, sulfuric acid type surfactant and carboxylic acid type surfactant
Kind；Nonionic surfactant selects at least one of fatty alcohol polyoxyethylene ether and modified ethoxylate object；Fatty acid soaps
General structure for RCOONa, R selects C in formula8-C18、C12-C18Or C12、C14、C16、C18；
Color stabilizer selects poly 4 vinyl pyridine nitrogen oxides, and the physicochemical property of color stabilizer is as follows：Degree of oxidation >=90%, activity
Ingredient 33%~37%, Ghana's moral coloration 6~13, viscosity 40cps~80cps, pH value 4.0~5.0；
Chelating agent selects sodium citrate；
Fluorescent whitening agent selects stilbene biphenyl type；
Preservative selects at least one of Kathon CG, polyalcohols and Phenoxyethanol；
Essence selects commercially available common daily essence；
Thickener selects at least one of sodium chloride, sodium sulphate and polyacrylic polymer.
2. efficiently color protection liquid detergent as described in claim 1, it is characterized in that：
Anion surfactant in polynary surfactant selects benzene sulfonic acid sodium salt and multi-alcohol polyoxyethylene ether sulfuric acid
At least one of sodium, the general structure of multi-alcohol polyethenoxy ether sodium sulfate is R (OC2H4)nSO3Na, R is C in formula12-
C15Or C12-C14Alkylol, n take 2 or 3；Nonionic surfactant in polynary surfactant selects aliphatic alcohol polyethenoxy
Ether, the general structure of fatty alcohol polyoxyethylene ether are：R(OC2H4)nOH, R is C in formula12-C15Or C12-C14Alkylol, n takes 3~
Positive integer in the range of 11, wherein n take the constituent mass of 5~9 ranges to account for the 60%~70% of nonionic surfactant quality.
3. efficiently color protection liquid detergent as claimed in claim 2, it is characterized in that：
The mass percent concentration of anion surfactant in polynary surfactant is 10%~20%, anionic surface
Activating agent selects -70 type of sodium sulfate of polyethenoxy ether of fatty alcohol；The matter of nonionic surfactant in polynary surfactant
It is 10%~20% to measure percent concentration, and nonionic surfactant selects fatty alcohol polyoxyethylene ether -9, fatty alcohol polyoxy second
At least one of alkene ether -7 and fatty alcohol polyoxyethylene ether -3；The mass percent of fatty acid soaps in polynary surfactant
A concentration of 1%~5%, fatty acid soaps select carbon chain lengths be 8~18 mixture or carbon chain lengths be 12~18 in it is arbitrary
One kind or mixture and sodium hydroxide solution that carbon chain lengths are 12~18 are abundant under being matched in 50 DEG C~70 DEG C temperature ranges
Product after saponification；
The mass percent concentration of color stabilizer is 0.3%~1%；
The mass percent concentration of fluorescent whitening agent is 0.05%~1%.
4. the preparation method of the efficient color protection liquid detergent as described in any one in claims 1 to 3, it is characterized in that：By as follows
Step is implemented successively：
Portions of de-ionized water and aqueous alkali are first added in preparation tank, and temperature is risen to 55 DEG C~65 DEG C, adds in aliphatic acid,
It stirs to fully transparent：Add in chelating agent, stirring and dissolving；It is sequentially added into anion surfactant, non-ionic surface active
Agent is stirred to whole dissolvings；Then excess water is added in, and cools the temperature to 30 DEG C hereinafter, sequentially adding color stabilizer, fluorescent brightening
Agent, preservative, essence, thickener, stirring are filtered to being completely dissolved.
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| CN109679791A (en) * | 2018-11-06 | 2019-04-26 | 枞阳县毛巾有限责任公司 | A kind of builder and preparation method thereof improving towel color protection ability |
| CN110964612A (en) * | 2019-11-29 | 2020-04-07 | 张启田 | Efficient laundry detergent and preparation method thereof |
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| CN113604294A (en) * | 2021-09-16 | 2021-11-05 | 廊坊佰美生物科技有限公司 | Commercial laundry detergent and preparation method thereof |
| CN115368981A (en) * | 2022-09-21 | 2022-11-22 | 云南水星生物科技有限公司 | Biological color fixative and preparation method and application thereof |
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| CN108641832A (en) * | 2018-07-01 | 2018-10-12 | 田波 | A kind of enzyme color protection liquid detergent |
| CN108659980A (en) * | 2018-07-01 | 2018-10-16 | 田波 | A kind of without phosphorus color protection liquid detergent |
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| CN110964612A (en) * | 2019-11-29 | 2020-04-07 | 张启田 | Efficient laundry detergent and preparation method thereof |
| CN113604294A (en) * | 2021-09-16 | 2021-11-05 | 廊坊佰美生物科技有限公司 | Commercial laundry detergent and preparation method thereof |
| CN115368981A (en) * | 2022-09-21 | 2022-11-22 | 云南水星生物科技有限公司 | Biological color fixative and preparation method and application thereof |
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