CN108102373A - A kind of elastomeric environment-friendly silica gel color masterbatch - Google Patents
A kind of elastomeric environment-friendly silica gel color masterbatch Download PDFInfo
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- CN108102373A CN108102373A CN201711222905.3A CN201711222905A CN108102373A CN 108102373 A CN108102373 A CN 108102373A CN 201711222905 A CN201711222905 A CN 201711222905A CN 108102373 A CN108102373 A CN 108102373A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The present invention relates to a kind of elastomeric environment-friendly silica gel color masterbatch, the elastomeric environment-friendly silica gel color masterbatch includes following raw material:84~96 parts of silicon virgin rubber,14~23 parts of rosin,16~22 parts of pigment,40~56 parts of silicone oil,14~18 parts of cellulose acetate,8~16 parts of nano zine oxide,12~18 parts of stearic acid,40~46 parts of water,34~42 parts of butyl rubber,Without 24~28 parts of benzene silicon rubber,14~21 parts of sodium metasilicate,20~25 parts of polymethyl methacrylate,15~23 parts of animal tallow,2~5 parts of 4~6 parts of ultraviolet absorber and fluorescer,The elastomeric environment-friendly silica gel color masterbatch of the present invention carries out scientific and reasonable proportioning using Novel environment-friendlymaterial material,Masterbatch security obtained is good,Uniform coloring,It is easy to use,Good economy performance,It manufactures at low cost,With good potentiality,Environmentally protective few harm,Meet polycyclic aromatic hydrocarbons (PAH) inspection specification,Polycyclic aromatic hydrocarbons (PAH) is not detected,Meet environmental requirement.
Description
Technical field
The present invention relates to silica gel material technical fields, and in particular to a kind of elastomeric environment-friendly silica gel color masterbatch.
Background technology
Silica gel color masterbatch is a kind of novel high polymer material silica gel special colorant, it is by pigment or dyestuff, carrier and addition
Three kinds of fundamentals of agent are formed, and are aggregations obtained from the pigment or dyestuff of super quantity are equably attached among resin
Body can claim condensed pigment so his tinting strength, tinting power is higher than pigment in itself.
Silica gel color masterbatch can be applied to medicine, health and food etc., but general silica gel color masterbatch use contains halogen
Either arene is toxic or low toxicity material, and the toxicity for reducing silica gel color masterbatch will be current urgent problem.
The content of the invention
To solve the above problems, a kind of the present invention is intended to provide elastomeric environment-friendly silica gel color masterbatch.
Purpose to realize the present invention, the technical solution adopted is that:A kind of elastomeric environment-friendly silica gel color masterbatch, the high resiliency
Environment-friendly silica gel color masterbatch include following raw material:84~96 parts of silicon virgin rubber, 14~23 parts of rosin, 16~22 parts of pigment, silicone oil
40~56 parts, 14~18 parts of cellulose acetate, 8~16 parts of nano zine oxide, 12~18 parts of stearic acid, 40~46 parts of water, butyl
34~42 parts of rubber, without 14~21 parts of 24~28 parts of benzene silicon rubber and sodium metasilicate.
Preferably, the elastomeric environment-friendly silica gel color masterbatch is also added with 20~25 parts of polymethyl methacrylate.
Preferably, the elastomeric environment-friendly silica gel color masterbatch is also added with 15~23 parts of animal tallow.
Preferably, animal tallow includes lard, tallow, suet and cream in the elastomeric environment-friendly silica gel color masterbatch.
Preferably, the ratio of the lard in the animal tallow, tallow, suet and cream is 2~4:1~2:1~2:2~
3。
Preferably, 4~6 parts of ultraviolet absorber is also added in the elastomeric environment-friendly silica gel color masterbatch.
Preferably, 2~5 parts of fluorescer is also added in the elastomeric environment-friendly silica gel color masterbatch.
Preferably, the pigment of the elastomeric environment-friendly silica gel color masterbatch includes organic pigment and inorganic pigment, wherein, it is organic
The proportioning of pigment and inorganic pigment is 1:2~4.
Preferably, the preparation method of the elastomeric environment-friendly silica gel color masterbatch comprises the following steps:
1) is just mixed:At 230~250 DEG C melt to by silicon virgin rubber, butyl rubber and without benzene silicon rubber it is liquid,
It adds nano zine oxide, sodium metasilicate, ultraviolet absorber and fluorescer and is uniformly mixed and be added in molten mass, with 2000~
The rotating speed high-speed stirred of 3000r/min is all melted and is uniformly mixed completely to material;
2) mixes colours:Pigment, animal tallow and silicone oil is soluble in water, pigment is stirred at a temperature of 120~150 DEG C, is moved
Object fat and silicone oil are uniformly mixed in water to thick, add 30~40% stearic acid, then with 1500~2500r/min
Rotating speed moderate-speed mixer to material be uniformly mixed;
3) bis- mixing of:The molten mass mixed in step 1 is cooled to 180~250 DEG C, is stirred to molten mass inner edge
It mixes after side adds in remaining stearic acid, polymethyl methacrylate, rosin and cellulose acetate to molten mass retrogradation and is cooled to 150
The pigment that step 2 mixes up is added in after~180 DEG C, then 3~6h is stirred with the rotating speed of 2500~3000r/min, then is transferred to
In synchronism double screw extruder;
4) extruding pelletizations:By the screw speed control of double screw extruder in 130~150r/min, extrusion temperature control
At 180~240 DEG C, material is squeezed out from extruder, then the material item of extrusion using cutter be cut into the length of 8~12cm
Item is granulated using comminutor at 210~250 DEG C, and elastomeric environment-friendly silica gel color masterbatch is made after Masterbatch cooling.
Beneficial effects of the present invention are:The elastomeric environment-friendly silica gel color masterbatch of the present invention carries out science using Novel environment-friendlymaterial material
Rational proportioning, Masterbatch security obtained is good, and uniform coloring is easy to use, good economy performance, and manufacture is at low cost, has
Potentiality, environmentally protective few harm meets polycyclic aromatic hydrocarbons (PAH) inspection specification, do not detect polycyclic aromatic hydrocarbons (PAH), meet environmental requirement.
Description of the drawings
Fig. 1 is the raw material proportioning table of the elastomeric environment-friendly silica gel color masterbatch of the present invention.
Specific embodiment
Below in conjunction with the attached drawing in the embodiment of the present invention, the technical solution in the embodiment of the present invention is carried out clear, complete
Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, those of ordinary skill in the art are obtained every other without making creative work
Embodiment belongs to the scope of protection of the invention.
Embodiment 1
Refering to Figure 1, the technical solution adopted by the present invention is:A kind of elastomeric environment-friendly silica gel color masterbatch, the height
The environment-friendly silica gel color masterbatch of elasticity includes following raw material:96 parts of silicon virgin rubber, 23 parts of rosin, 22 parts of pigment, 56 parts of silicone oil, acetic acid
18 parts of cellulose, 16 parts of nano zine oxide, 18 parts of stearic acid, 46 parts of water, 42 parts of butyl rubber, without 28 parts of benzene silicon rubber, silicic acid
5 parts of 21 parts of sodium, 25 parts of polymethyl methacrylate, 23 parts of animal tallow, 6 parts of ultraviolet absorber and fluorescer.
Further, the preparation method of the elastomeric environment-friendly silica gel color masterbatch comprises the following steps:
1) is just mixed:At 250 DEG C melt to by silicon virgin rubber, butyl rubber and without benzene silicon rubber liquid, add
Nano zine oxide, sodium metasilicate, ultraviolet absorber and fluorescer, which are uniformly mixed, to be added in molten mass, with the rotating speed of 3000r/min
High-speed stirred is all melted and is uniformly mixed completely to material;
2) mixes colours:Pigment, animal tallow and silicone oil is soluble in water, pigment, tallow are stirred at a temperature of 150 DEG C
Fat and silicone oil are uniformly mixed in water to thick, add 40% stearic acid, then the rotating speed moderate-speed mixer with 2500r/min
It is uniformly mixed to material;
3) bis- mixing of:The molten mass mixed in step 1 is cooled to 250 DEG C, is added while stirring into molten mass
Enter after being cooled to 180 DEG C after remaining stearic acid, polymethyl methacrylate, rosin and cellulose acetate to molten mass retrogradation plus
Enter the pigment that step 2 mixes up, then 6h is stirred with the rotating speed of 3000r/min, then be transferred in synchronism double screw extruder;
4) extruding pelletizations:By the screw speed control of double screw extruder in 150r/min, extrusion temperature is controlled 240
DEG C, material is squeezed out from extruder, then the material item of extrusion using cutter be cut into the strip of 12cm, uses comminutor
It is granulated at 250 DEG C, elastomeric environment-friendly silica gel color masterbatch is made after Masterbatch cooling.
Embodiment 2
Refering to Figure 1, the technical solution adopted by the present invention is:A kind of elastomeric environment-friendly silica gel color masterbatch, the height
The environment-friendly silica gel color masterbatch of elasticity includes following raw material:84 parts of silicon virgin rubber, 14 parts of rosin, 16 parts of pigment, 40 parts of silicone oil, acetic acid
14 parts of cellulose, 8 parts of nano zine oxide, 12 parts of stearic acid, 40 parts of water, 34 parts of butyl rubber, without 24 parts of benzene silicon rubber, sodium metasilicate
2 parts of 14 parts, 20 parts of polymethyl methacrylate, 15 parts of animal tallow, 4 parts of ultraviolet absorber and fluorescer.
Further, the preparation method of the elastomeric environment-friendly silica gel color masterbatch comprises the following steps:
1) is just mixed:At 230 DEG C melt to by silicon virgin rubber, butyl rubber and without benzene silicon rubber liquid, add
Nano zine oxide, sodium metasilicate, ultraviolet absorber and fluorescer, which are uniformly mixed, to be added in molten mass, with the rotating speed of 2000r/min
High-speed stirred is all melted and is uniformly mixed completely to material;
2) mixes colours:Pigment, animal tallow and silicone oil is soluble in water, pigment, tallow are stirred at a temperature of 120 DEG C
Fat and silicone oil are uniformly mixed in water to thick, add 30% stearic acid, then the rotating speed moderate-speed mixer with 1500r/min
It is uniformly mixed to material;
3) bis- mixing of:The molten mass mixed in step 1 is cooled to 180 DEG C, is added while stirring into molten mass
Enter after being cooled to 150 DEG C after remaining stearic acid, polymethyl methacrylate, rosin and cellulose acetate to molten mass retrogradation plus
Enter the pigment that step 2 mixes up, then 3h is stirred with the rotating speed of 2500r/min, then be transferred in synchronism double screw extruder;
4) extruding pelletizations:By the screw speed control of double screw extruder in 130r/min, extrusion temperature is controlled 180
DEG C, material is squeezed out from extruder, then the material item of extrusion using cutter be cut into the strip of 8cm, uses comminutor
It is granulated at 210 DEG C, elastomeric environment-friendly silica gel color masterbatch is made after Masterbatch cooling.
Embodiment 3
Refering to Figure 1, the technical solution adopted by the present invention is:A kind of elastomeric environment-friendly silica gel color masterbatch, the height
The environment-friendly silica gel color masterbatch of elasticity includes following raw material:96 parts of silicon virgin rubber, 14 parts of rosin, 22 parts of pigment, 40 parts of silicone oil, acetic acid
18 parts of cellulose, 8 parts of nano zine oxide, 18 parts of stearic acid, 40 parts of water, 42 parts of butyl rubber, without 24 parts of benzene silicon rubber, sodium metasilicate
5 parts of 21 parts, 20 parts of polymethyl methacrylate, 23 parts of animal tallow, 4 parts of ultraviolet absorber and fluorescer.
Further, the preparation method of the elastomeric environment-friendly silica gel color masterbatch comprises the following steps:
1) is just mixed:At 250 DEG C melt to by silicon virgin rubber, butyl rubber and without benzene silicon rubber liquid, add
Nano zine oxide, sodium metasilicate, ultraviolet absorber and fluorescer, which are uniformly mixed, to be added in molten mass, with the rotating speed of 2000r/min
High-speed stirred is all melted and is uniformly mixed completely to material;
2) mixes colours:Pigment, animal tallow and silicone oil is soluble in water, pigment, tallow are stirred at a temperature of 150 DEG C
Fat and silicone oil are uniformly mixed in water to thick, add 40% stearic acid, then the rotating speed moderate-speed mixer with 1500r/min
It is uniformly mixed to material;
3) bis- mixing of:The molten mass mixed in step 1 is cooled to 250 DEG C, is added while stirring into molten mass
Enter after being cooled to 150 DEG C after remaining stearic acid, polymethyl methacrylate, rosin and cellulose acetate to molten mass retrogradation plus
Enter the pigment that step 2 mixes up, then 3h is stirred with the rotating speed of 3000r/min, then be transferred in synchronism double screw extruder;
4) extruding pelletizations:By the screw speed control of double screw extruder in 150r/min, extrusion temperature is controlled 180
DEG C, material is squeezed out from extruder, then the material item of extrusion using cutter be cut into the strip of 12cm, uses comminutor
It is granulated at 210 DEG C, elastomeric environment-friendly silica gel color masterbatch is made after Masterbatch cooling.
Embodiment 4
Refering to Figure 1, the technical solution adopted by the present invention is:A kind of elastomeric environment-friendly silica gel color masterbatch, the height
The environment-friendly silica gel color masterbatch of elasticity includes following raw material:84 parts of silicon virgin rubber, 23 parts of rosin, 16 parts of pigment, 56 parts of silicone oil, acetic acid
14 parts of cellulose, 16 parts of nano zine oxide, 12 parts of stearic acid, 46 parts of water, 34 parts of butyl rubber, without 28 parts of benzene silicon rubber, silicic acid
2 parts of 14 parts of sodium, 25 parts of polymethyl methacrylate, 15 parts of animal tallow, 6 parts of ultraviolet absorber and fluorescer.
Further, the preparation method of the elastomeric environment-friendly silica gel color masterbatch comprises the following steps:
1) is just mixed:At 250 DEG C melt to by silicon virgin rubber, butyl rubber and without benzene silicon rubber liquid, add
Nano zine oxide, sodium metasilicate, ultraviolet absorber and fluorescer, which are uniformly mixed, to be added in molten mass, with the rotating speed of 2000r/min
High-speed stirred is all melted and is uniformly mixed completely to material;
2) mixes colours:Pigment, animal tallow and silicone oil is soluble in water, pigment, tallow are stirred at a temperature of 150 DEG C
Fat and silicone oil are uniformly mixed in water to thick, add 30% stearic acid, then the rotating speed moderate-speed mixer with 2500r/min
It is uniformly mixed to material;
3) bis- mixing of:The molten mass mixed in step 1 is cooled to 180 DEG C, is added while stirring into molten mass
Enter after being cooled to 180 DEG C after remaining stearic acid, polymethyl methacrylate, rosin and cellulose acetate to molten mass retrogradation plus
Enter the pigment that step 2 mixes up, then 6h is stirred with the rotating speed of 2500r/min, then be transferred in synchronism double screw extruder;
4) extruding pelletizations:By the screw speed control of double screw extruder in 130r/min, extrusion temperature is controlled 240
DEG C, material is squeezed out from extruder, then the material item of extrusion using cutter be cut into the strip of 12cm, uses comminutor
It is granulated at 210 DEG C, elastomeric environment-friendly silica gel color masterbatch is made after Masterbatch cooling.
In the present invention, the elastomeric environment-friendly silica gel color masterbatch of the present invention carries out scientific and reasonable match somebody with somebody using Novel environment-friendlymaterial material
Than Masterbatch security obtained is good, and uniform coloring is easy to use, good economy performance, manufactures at low cost, the potentiality having had, green
Colour circle protects few harm, meets polycyclic aromatic hydrocarbons (PAH) inspection specification, does not detect polycyclic aromatic hydrocarbons (PAH), meets environmental requirement.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of variations, modification, replace
And modification, the scope of the present invention is defined by the appended.
Claims (9)
1. a kind of elastomeric environment-friendly silica gel color masterbatch, it is characterised in that:The elastomeric environment-friendly silica gel color masterbatch includes following
Raw material:84~96 parts of silicon virgin rubber, 14~23 parts of rosin, 16~22 parts of pigment, 40~56 parts of silicone oil, cellulose acetate 14~18
Part, 8~16 parts of nano zine oxide, 12~18 parts of stearic acid, 40~46 parts of water, 34~42 parts of butyl rubber, without benzene silicon rubber 24
~28 parts and 14~21 parts of sodium metasilicate.
2. a kind of elastomeric environment-friendly silica gel color masterbatch according to claim 1, it is characterised in that:The elastomeric environmental protection
Silica gel color masterbatch is also added with 20~25 parts of polymethyl methacrylate.
3. a kind of elastomeric environment-friendly silica gel color masterbatch according to claim 1, it is characterised in that:The elastomeric environmental protection
Silica gel color masterbatch is also added with 15~23 parts of animal tallow.
4. a kind of elastomeric environment-friendly silica gel color masterbatch according to claim 3, it is characterised in that:The elastomeric environmental protection
Animal tallow includes lard, tallow, suet and cream in silica gel color masterbatch.
5. a kind of elastomeric environment-friendly silica gel color masterbatch according to claim 3 or 4, it is characterised in that:The animal tallow
In lard, tallow, the ratio of suet and cream be 2~4:1~2:1~2:2~3.
6. a kind of elastomeric environment-friendly silica gel color masterbatch according to claim 1, it is characterised in that:The elastomeric environmental protection
4~6 parts of ultraviolet absorber is also added in silica gel color masterbatch.
7. a kind of elastomeric environment-friendly silica gel color masterbatch according to claim 1, it is characterised in that:The elastomeric environmental protection
2~5 parts of fluorescer is also added in silica gel color masterbatch.
8. a kind of elastomeric environment-friendly silica gel color masterbatch according to claim 1, it is characterised in that:The elastomeric environmental protection
The pigment of silica gel color masterbatch includes organic pigment and inorganic pigment, wherein, the proportioning of organic pigment and inorganic pigment is 1:2~4.
9. a kind of elastomeric environment-friendly silica gel color masterbatch according to claim 1, it is characterised in that:The elastomeric environmental protection
The preparation method of silica gel color masterbatch comprises the following steps:
1) is just mixed:At 230~250 DEG C melt to by silicon virgin rubber, butyl rubber and without benzene silicon rubber liquid, then add
Enter nano zine oxide, sodium metasilicate, ultraviolet absorber and fluorescer and be uniformly mixed to be added in molten mass, with 2000~3000r/
The rotating speed high-speed stirred of min is all melted and is uniformly mixed completely to material;
2) mixes colours:Pigment, animal tallow and silicone oil is soluble in water, pigment, tallow are stirred at a temperature of 120~150 DEG C
Fat and silicone oil are uniformly mixed in water to thick, are added 30~40% stearic acid, then are turned with 1500~2500r/min
Fast moderate-speed mixer to material is uniformly mixed;
3) bis- mixing of:The molten mass mixed in step 1 is cooled to 180~250 DEG C, into molten mass while stirring
Add in after remaining stearic acid, polymethyl methacrylate, rosin and cellulose acetate to molten mass retrogradation and be cooled to 150~
The pigment that step 2 mixes up is added in after 180 DEG C, then 3~6h is stirred with the rotating speed of 2500~3000r/min, then is transferred to same
In step property double screw extruder;
4) extruding pelletizations:By the screw speed control of double screw extruder in 130~150r/min, extrusion temperature is controlled 180
~240 DEG C, material is squeezed out from extruder, then the material item of extrusion using cutter be cut into the strip of 8~12cm, is made
It is granulated with comminutor at 210~250 DEG C, elastomeric environment-friendly silica gel color masterbatch is made after Masterbatch cooling.
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CN201711222905.3A CN108102373A (en) | 2017-11-29 | 2017-11-29 | A kind of elastomeric environment-friendly silica gel color masterbatch |
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CN201711222905.3A CN108102373A (en) | 2017-11-29 | 2017-11-29 | A kind of elastomeric environment-friendly silica gel color masterbatch |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN114231146A (en) * | 2021-12-22 | 2022-03-25 | 广东溢达纺织有限公司 | Impregnation slurry, impregnation rope end and preparation method thereof |
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CN104387773A (en) * | 2014-12-04 | 2015-03-04 | 成都锦汇科技有限公司 | Silicone rubber coloring master batch |
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CN104927274A (en) * | 2015-05-20 | 2015-09-23 | 范文杰 | Pre-dispersed masterbatch particle carrier, pre-dispersed masterbatch particles applied to pre-dispersed masterbatch particle carrier, and preparation method and application of pre-dispersed masterbatch particles |
CN105238067A (en) * | 2015-11-09 | 2016-01-13 | 沈阳化工大学 | High-temperature resistance silicone rubber coloring master batch and preparation method thereof |
CN106867183A (en) * | 2017-03-10 | 2017-06-20 | 广州润锋化工有限公司 | A kind of direct use in injection molding bloom black agglomerate of resin and preparation method thereof |
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CN1110975A (en) * | 1994-03-15 | 1995-11-01 | 赫彻斯特股份公司 | Coloring agent adapted for preparation master agent of color |
JPWO2009063940A1 (en) * | 2007-11-16 | 2011-03-31 | 東レ・ダウコーニング株式会社 | Silica masterbatch |
JPWO2009063941A1 (en) * | 2007-11-16 | 2011-03-31 | 東レ・ダウコーニング株式会社 | Silica masterbatch |
CN103360670A (en) * | 2013-06-03 | 2013-10-23 | 广东波斯科技股份有限公司 | Universal high-gloss black masterbatch |
CN104387773A (en) * | 2014-12-04 | 2015-03-04 | 成都锦汇科技有限公司 | Silicone rubber coloring master batch |
CN104476693A (en) * | 2014-12-04 | 2015-04-01 | 成都锦汇科技有限公司 | Preparation method of silicone rubber coloring master batch |
CN104927274A (en) * | 2015-05-20 | 2015-09-23 | 范文杰 | Pre-dispersed masterbatch particle carrier, pre-dispersed masterbatch particles applied to pre-dispersed masterbatch particle carrier, and preparation method and application of pre-dispersed masterbatch particles |
CN105238067A (en) * | 2015-11-09 | 2016-01-13 | 沈阳化工大学 | High-temperature resistance silicone rubber coloring master batch and preparation method thereof |
CN106867183A (en) * | 2017-03-10 | 2017-06-20 | 广州润锋化工有限公司 | A kind of direct use in injection molding bloom black agglomerate of resin and preparation method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN114231146A (en) * | 2021-12-22 | 2022-03-25 | 广东溢达纺织有限公司 | Impregnation slurry, impregnation rope end and preparation method thereof |
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Application publication date: 20180601 |