CN108101541A - A kind of ejection forming method of non-bond cemented carbide - Google Patents
A kind of ejection forming method of non-bond cemented carbide Download PDFInfo
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- CN108101541A CN108101541A CN201711388964.8A CN201711388964A CN108101541A CN 108101541 A CN108101541 A CN 108101541A CN 201711388964 A CN201711388964 A CN 201711388964A CN 108101541 A CN108101541 A CN 108101541A
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- 238000000034 method Methods 0.000 title claims abstract description 28
- 238000005245 sintering Methods 0.000 claims abstract description 41
- 239000000843 powder Substances 0.000 claims abstract description 34
- 239000011230 binding agent Substances 0.000 claims abstract description 22
- 238000005238 degreasing Methods 0.000 claims abstract description 14
- 238000002347 injection Methods 0.000 claims abstract description 13
- 239000007924 injection Substances 0.000 claims abstract description 13
- 238000000498 ball milling Methods 0.000 claims abstract description 11
- 238000001746 injection moulding Methods 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 239000002904 solvent Substances 0.000 claims abstract description 9
- 238000000280 densification Methods 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 8
- 238000001513 hot isostatic pressing Methods 0.000 claims abstract description 6
- 238000001125 extrusion Methods 0.000 claims abstract description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical group CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- 238000002791 soaking Methods 0.000 claims description 8
- 238000000227 grinding Methods 0.000 claims description 6
- 239000012188 paraffin wax Substances 0.000 claims description 6
- -1 polyethylene Polymers 0.000 claims description 6
- 238000005469 granulation Methods 0.000 claims description 5
- 230000003179 granulation Effects 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 4
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 claims description 4
- 235000013871 bee wax Nutrition 0.000 claims description 4
- 239000012166 beeswax Substances 0.000 claims description 4
- 238000004898 kneading Methods 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 238000007873 sieving Methods 0.000 claims description 4
- 229960002415 trichloroethylene Drugs 0.000 claims description 4
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 claims description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 2
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 238000005516 engineering process Methods 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 239000002994 raw material Substances 0.000 abstract description 5
- 238000001035 drying Methods 0.000 abstract 1
- 239000000956 alloy Substances 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 5
- 239000000243 solution Substances 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 238000009770 conventional sintering Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000005495 investment casting Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/56—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
- C04B35/5607—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on refractory metal carbides
- C04B35/5626—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on refractory metal carbides based on tungsten carbides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
- C04B35/645—Pressure sintering
- C04B35/6455—Hot isostatic pressing
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/38—Non-oxide ceramic constituents or additives
- C04B2235/3817—Carbides
- C04B2235/3839—Refractory metal carbides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/38—Non-oxide ceramic constituents or additives
- C04B2235/3817—Carbides
- C04B2235/3839—Refractory metal carbides
- C04B2235/3843—Titanium carbides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/658—Atmosphere during thermal treatment
- C04B2235/6581—Total pressure below 1 atmosphere, e.g. vacuum
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Powder Metallurgy (AREA)
Abstract
The present invention provides a kind of ejection forming methods of non-bond cemented carbide, mainly include the following steps that：Batch mixing：WC powder, TiC powder, TaC powder are weighed according to a certain percentage, carry out ball milling drying；It is kneaded：Mixture powder is kneaded with binding agent, and injection feeding is made；Feeding is extruded by banding, strip using extrusion device, is pelletized by pulverizer；Injection moulding：Feeding is passed through into injector injection moulding；Degreasing：Including solvent degreasing and thermal debinding；Vacuum-sintering：Vacuum-sintering is taken to carry out at a certain temperature pre-sintered；HIP sintering：Green body after pre-sintering, which is put into hot isostatic pressing stove, carries out HIP sintering promotion densification.The technology of the present invention can obtain the non-bond cemented carbide product of various complicated shapes by injection molding process, and for material density up to 99.9%, technological process is simple, and raw material availability is high, is suitble to industrialization production.
Description
Technical field
The present invention relates to hard alloy preparing technical field more particularly to a kind of injection mouldings of non-bond cemented carbide
Method.
Background technology
Hard alloy has high rigidity, high-wearing feature, good chemical stability and thermal stability, is widely used in the modern times
Tool materials, wear-resistant material, heat-resisting material, resistant material etc..General hard alloy be by hard phase (based on WC) and
Binder Phase (iron group metal) is formed.Non-bond cemented carbide is a kind of cemented carbide material without Binder Phase, is had excellent
Mechanical property and corrosion resistance, be mainly used in the application field of requirement highly corrosion resistant and high-wearing feature.
Injection molding technology is a kind of near-net-shape technology, can manufacture complex-shaped, dimension precision requirement is high, high-volume
The product of production, even density, respectively identical, similar to hot investment casting to shrinking, and precision and surface roughness are good, without after
Continuous processing.Non-bond cemented carbide is prepared using injection molding technology, the production that can meet various complicated shape structural members will
It asks, raw material availability is high, at low cost, is suitble to industrialization production.
Non-bond cemented carbide sintering densification is relatively difficult, is difficult to obtain densification production using conventional sintering process
Product.It is handled by HIP sintering, most of micro-pore in product can be eliminated, high densification product is obtained, be conducive to
It enhances product performance.
The content of the invention
To solve the above problems, the technical solution adopted is that：
A kind of ejection forming method of non-bond cemented carbide, includes the following steps：
(1) batch mixing：WC powder, TiC powder, TaC powder are weighed according to a certain percentage, are put into ball grinding cylinder, add in mill Jie's ball and
Decentralized medium, ball milling take out and dry sieving afterwards for a period of time；
(2) it is kneaded：Mixture powder and binding agent are weighed according to a certain percentage, is added in kneading machine, is heated and be kneaded
For a period of time；
(3) pelletize：Feeding is extruded by banding, strip using extrusion device, is pelletized by pulverizer；
(4) injection moulding：Feeding after granulation is injected into variously-shaped injection base using injector；
(5) degreasing：Remove portion of binder in a solvent first, then the remaining binding agent of heating removing；
(6) vacuum-sintering：Vacuum-sintering is taken to carry out at a certain temperature pre-sintered；
(7) HIP sintering：Green body after pre-sintering, which is put into hot isostatic pressing stove, carries out HIP sintering promotion cause
Densification.
The object of the invention to solve the technical problems also can be used following technical measures and further realize：
A kind of ejection forming method of foregoing non-bond cemented carbide, wherein, the mass fraction of powder is：WC powder 93
~96%, TiC powder 2~4%, TaC powder 1~3%.
A kind of ejection forming method of foregoing non-bond cemented carbide, wherein, mill Jie ball during ball milling is that hard closes
Gold goal, decentralized medium are acetone；Ball material weight ratio is 3：1, solid-liquid volume ratio is 1：5, Ball-milling Time is 50~80h.
A kind of ejection forming method of foregoing non-bond cemented carbide, wherein, the quality of the mixing binding agent
Fraction is：Paraffin 30~40%, beeswax 30~40%, polyethylene 20~40% and stearic acid 2~10%；Mixture powder
Volume fraction is 50~65%.
A kind of ejection forming method of foregoing non-bond cemented carbide, wherein, melting temperature is 120~180 DEG C, is mixed
The refining time is 2~6h.
A kind of ejection forming method of foregoing non-bond cemented carbide, wherein, injection temperature is 160~180 DEG C, note
Injection pressure is 60~80MPa, and mould temperature is 25-35 DEG C.
A kind of ejection forming method of foregoing non-bond cemented carbide, wherein, solvent degreasing can be selected trichloro ethylene,
One kind in chloroform or normal heptane, skimming temp are 45~70 DEG C, and degreasing time is 5~8h；Thermal debinding temperature for 450~
500℃。
A kind of ejection forming method of foregoing non-bond cemented carbide, wherein, the sintering temperature of vacuum-sintering is
1600~1700 DEG C, soaking time is 40~90min.
A kind of ejection forming method of foregoing non-bond cemented carbide, wherein, the sintering temperature of HIP sintering
For 1400~1500 DEG C, pressure is 80~150MPa, and soaking time is 40~90min.
Compared with prior art, the present invention can be prepared complex-shaped product, be obtained high cause using injection molding technology
Close or even fully dense non-bond cemented carbide product, raw material availability is high, is suitble to produce in enormous quantities.
Above description is only the general introduction of technical solution of the present invention, in order to better understand the technological means of the present invention,
And can be practiced according to the content of specification, and in order to allow the present invention above-mentioned advantage and other purposes, feature and advantage
It can be clearer and more comprehensible, special below to lift preferred embodiment, detailed description are as follows.
Description of the drawings
Nothing
Specific embodiment
Embodiment 1：
A kind of ejection forming method of non-bond cemented carbide, includes the following steps：
(1) batch mixing：It weighs 93%WC powder, 3%TiC powder, 3%TaC powder to be put into ball grinding cylinder, adds in hard alloy mill Jie's ball
With acetone decentralized medium.Add in 3% paraffin binder of powder raw material, ratio of grinding media to material 3：1 (weight ratio), solid-to-liquid ratio 1：5
(volume ratio), Ball-milling Time 72h take out after ball milling and dry sieving；
(2) it is kneaded：Mixture powder and binding agent are weighed according to a certain percentage, the volume fraction of mixture powder is
55%, it adds in kneading machine.33% paraffin of Binder Composition, 33% beeswax, 30% polyethylene and 4% stearic acid form compound
Binding agent.Melting temperature is 150 DEG C, is kneaded 4h；
(3) pelletize：Feeding is extruded into respectively three times by banding, strip using extrusion device, is pelletized by pulverizer；
(4) injection moulding：Feeding after granulation is injected into variously-shaped injection base using injector.Injection temperature is
160 DEG C, injection pressure 75MPa, mould temperature is 30 DEG C or so；
(5) degreasing：Using two step degreasing methods of solvent degreasing+thermal debinding.Part is removed in trichloroethylene solvent first
Binding agent, temperature are 50 DEG C, time 6h.Then the thermal debinding in dewaxing furnace, thermal debinding temperature are 500 DEG C, and heating removing is surplus
Remaining binding agent；
(6) vacuum-sintering：Vacuum sintering method is taken to carry out pre-sintered, vacuum-sintering temperature is 1650 DEG C, soaking time
For 60min；
(7) HIP sintering：Green body after pre-sintering, which is put into hot isostatic pressing stove, carries out HIP sintering promotion cause
Densification, the sintering temperature of HIP sintering is 1450 DEG C, pressure 100MPa, soaking time 40min.
Embodiment 2：
A kind of ejection forming method of non-bond cemented carbide, includes the following steps：
(1) batch mixing：It weighs 94.5%WC powder, 3%TiC powder, 2.5%TaC powder to be put into ball grinding cylinder, adds in hard alloy mill
Jie's ball and acetone decentralized medium.Add in 3% paraffin binder of powder raw material, ratio of grinding media to material 3：1 (weight ratio), solid-to-liquid ratio are
1：5 (volume ratios), Ball-milling Time 72h take out after ball milling and dry sieving；
(2) it is kneaded：Mixture powder and binding agent are weighed according to a certain percentage, the volume fraction of mixture powder is
60%, it adds in kneading machine.41% paraffin of Binder Composition, 32% beeswax, 22% polyethylene and 5% stearic acid form compound
Binding agent.Melting temperature is 150 DEG C, is kneaded 6h；
(3) pelletize：Feeding is extruded into respectively three times by banding, strip using extrusion device, is pelletized by pulverizer；
(4) injection moulding：Feeding after granulation is injected into variously-shaped injection base using injector.Injection temperature is
160 DEG C, injection pressure 75MPa, mould temperature is 30 DEG C or so；
(5) degreasing：Using two step degreasing methods of solvent degreasing+thermal debinding.Part is removed in trichloroethylene solvent first
Binding agent, temperature are 50 DEG C, time 6h.Then the thermal debinding in dewaxing furnace, thermal debinding temperature are 500 DEG C, and heating removing is surplus
Remaining binding agent；
(6) vacuum-sintering：Vacuum sintering method is taken to carry out pre-sintered, vacuum-sintering temperature is 1650 DEG C, soaking time
For 60min；
(7) HIP sintering：Green body after pre-sintering, which is put into hot isostatic pressing stove, carries out HIP sintering promotion cause
Densification, the sintering temperature of HIP sintering is 1430 DEG C, pressure 120MPa, soaking time 60min.
The above described is only a preferred embodiment of the present invention, not doing limitation in any form to the present invention, appoint
What those skilled in the art, without departing from the scope of the present invention, is made a little using above-mentioned technology contents
It changes or the embodiment of modification, in the range of still falling within technical solution of the present invention.
Claims (9)
1. a kind of ejection forming method of non-bond cemented carbide, it is characterised in that:Include the following steps：
Batch mixing：WC powder, TiC powder, TaC powder are weighed according to a certain percentage, are put into ball grinding cylinder, adds in mill Jie's ball and scattered Jie
Matter, ball milling take out and dry sieving afterwards for a period of time；
It is kneaded：Mixture powder and binding agent are weighed according to a certain percentage, added in kneading machine, when heating and being kneaded one section
Between；
Granulation：Feeding is extruded by banding, strip using extrusion device, is pelletized by pulverizer；
Injection moulding：Feeding after granulation is injected into variously-shaped injection base using injector；
Degreasing：Remove portion of binder in a solvent first, then the remaining binding agent of heating removing；
Vacuum-sintering：Vacuum-sintering is taken to carry out at a certain temperature pre-sintered；
HIP sintering：Green body after pre-sintering, which is put into hot isostatic pressing stove, carries out HIP sintering promotion densification.
2. a kind of ejection forming method of non-bond cemented carbide as described in claim 1, it is characterised in that:The matter of powder
Measuring fraction is：WC powder 93~96%, TiC powder 2~4%, TaC powder 1~3%.
3. a kind of ejection forming method of non-bond cemented carbide as described in claim 1, it is characterised in that:During ball milling
It is sintered carbide ball to grind Jie's ball, and decentralized medium is acetone；Ball material weight ratio is 3：1, solid-liquid volume ratio is 1：5, Ball-milling Time is
50~80h.
4. a kind of preparation method of non-bond cemented carbide as described in claim 1, which is characterized in that the mixing is glued
Knot agent mass fraction be：Paraffin 30~40%, beeswax 30~40%, polyethylene 20~40% and stearic acid 2~10%；It is mixed
The volume fraction for closing feed powder end is 50~65%.
5. a kind of ejection forming method of non-bond cemented carbide as described in claim 1, it is characterised in that:Melting temperature
For 120~180 DEG C, mixing time is 2~6h.
6. a kind of ejection forming method of non-bond cemented carbide as described in claim 1, it is characterised in that：Injection temperature
For 160~180 DEG C, injection pressure is 60~80MPa, and mould temperature is 25-35 DEG C.
7. a kind of ejection forming method of non-bond cemented carbide as described in claim 1, it is characterised in that：Solvent degreasing
One kind in trichloro ethylene, chloroform or normal heptane can be selected, skimming temp is 45~70 DEG C, and degreasing time is 5~8h；Heat
Skimming temp is 450~500 DEG C.
A kind of 8. ejection forming method of non-bond cemented carbide as described in claim 1, which is characterized in that vacuum-sintering
Sintering temperature for 1600~1700 DEG C, soaking time is 40~90min.
9. a kind of ejection forming method of non-bond cemented carbide as described in claim 1, it is characterised in that：Hot isostatic pressing
The sintering temperature of sintering is 1400~1500 DEG C, and pressure is 80~150MPa, and soaking time is 40~90min.
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| CN201711388964.8A CN108101541A (en) | 2017-12-21 | 2017-12-21 | A kind of ejection forming method of non-bond cemented carbide |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711388964.8A CN108101541A (en) | 2017-12-21 | 2017-12-21 | A kind of ejection forming method of non-bond cemented carbide |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110181059A (en) * | 2018-12-13 | 2019-08-30 | 苏州赛特锐精密机械配件有限公司 | A kind of method of co-injection near-net-shape ultra-fine cemented carbide cutter green body |
| CN111673089A (en) * | 2020-05-18 | 2020-09-18 | 株洲天成金属激光高科有限公司 | Hard alloy vertical needle injection molding process for microwave chip packaging |
| CN117020204A (en) * | 2023-08-22 | 2023-11-10 | 钢研昊普科技有限公司 | 20CrNiMo bearing piece and preparation method and application thereof |
| CN118637918A (en) * | 2024-07-22 | 2024-09-13 | 苏州铠欣半导体科技有限公司 | Tantalum carbide feed material, tantalum carbide product and preparation method thereof |
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| CN107459353A (en) * | 2017-07-04 | 2017-12-12 | 江苏大学 | A kind of method of VC, TiC enhancing soap-free emulsion polymeization phase WC base cemented carbide performances |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111673089A (en) * | 2020-05-18 | 2020-09-18 | 株洲天成金属激光高科有限公司 | Hard alloy vertical needle injection molding process for microwave chip packaging |
| CN117020204A (en) * | 2023-08-22 | 2023-11-10 | 钢研昊普科技有限公司 | 20CrNiMo bearing piece and preparation method and application thereof |
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