CN108101424A - A kind of super water-fast super similarity stone-like coating of quick-drying and preparation method thereof - Google Patents
A kind of super water-fast super similarity stone-like coating of quick-drying and preparation method thereof Download PDFInfo
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- CN108101424A CN108101424A CN201711260838.4A CN201711260838A CN108101424A CN 108101424 A CN108101424 A CN 108101424A CN 201711260838 A CN201711260838 A CN 201711260838A CN 108101424 A CN108101424 A CN 108101424A
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- 238000000576 coating method Methods 0.000 title claims abstract description 42
- 239000011248 coating agent Substances 0.000 title claims abstract description 41
- 238000001035 drying Methods 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims description 12
- 239000004576 sand Substances 0.000 claims abstract description 61
- 239000003973 paint Substances 0.000 claims abstract description 44
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000000839 emulsion Substances 0.000 claims abstract description 28
- 239000008367 deionised water Substances 0.000 claims abstract description 20
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 20
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 11
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 11
- 239000000057 synthetic resin Substances 0.000 claims abstract description 11
- 239000000049 pigment Substances 0.000 claims abstract description 7
- 239000000945 filler Substances 0.000 claims abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 83
- 239000006210 lotion Substances 0.000 claims description 46
- 239000002562 thickening agent Substances 0.000 claims description 25
- 239000002518 antifoaming agent Substances 0.000 claims description 23
- 239000006004 Quartz sand Substances 0.000 claims description 21
- 238000002156 mixing Methods 0.000 claims description 21
- 239000003292 glue Substances 0.000 claims description 20
- 238000005469 granulation Methods 0.000 claims description 20
- 230000003179 granulation Effects 0.000 claims description 20
- 239000003755 preservative agent Substances 0.000 claims description 19
- 230000002335 preservative effect Effects 0.000 claims description 19
- 239000000084 colloidal system Substances 0.000 claims description 12
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 12
- 239000002270 dispersing agent Substances 0.000 claims description 11
- 239000002994 raw material Substances 0.000 claims description 10
- 239000005995 Aluminium silicate Substances 0.000 claims description 9
- 235000012211 aluminium silicate Nutrition 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- 229920001296 polysiloxane Polymers 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- 230000002528 anti-freeze Effects 0.000 claims description 5
- -1 part of auxiliary A Substances 0.000 claims description 4
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- PRPAGESBURMWTI-UHFFFAOYSA-N [C].[F] Chemical compound [C].[F] PRPAGESBURMWTI-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 241000872198 Serjania polyphylla Species 0.000 claims description 2
- 239000010456 wollastonite Substances 0.000 claims description 2
- 229910052882 wollastonite Inorganic materials 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims 1
- 238000005034 decoration Methods 0.000 abstract description 6
- 239000004575 stone Substances 0.000 abstract description 4
- 238000003860 storage Methods 0.000 abstract description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 27
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 23
- 239000003086 colorant Substances 0.000 description 16
- 235000010215 titanium dioxide Nutrition 0.000 description 12
- 239000004408 titanium dioxide Substances 0.000 description 10
- 239000000126 substance Substances 0.000 description 8
- 239000004922 lacquer Substances 0.000 description 5
- 239000003002 pH adjusting agent Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000004579 marble Substances 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 229910052622 kaolinite Inorganic materials 0.000 description 3
- 230000000630 rising effect Effects 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000005253 cladding Methods 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- PLXMOAALOJOTIY-FPTXNFDTSA-N Aesculin Natural products OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)[C@H]1Oc2cc3C=CC(=O)Oc3cc2O PLXMOAALOJOTIY-FPTXNFDTSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 102200082943 rs35424040 Human genes 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/30—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds
- C04B26/32—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds containing silicon
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
- C04B2111/82—Coloured materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of decoration of exterior wall art works,More particularly to a kind of super water-fast super similarity stone-like coating of quick-drying,It includes color tablets containing sand and dispersed phase component mixes,Wherein,Base paint component includes 25~40 parts of synthetic resin emulsion,40~56.4 parts of deionized water,10~18 parts of auxiliary agent A,0~10 part of pigment or/and filler,Dispersed phase includes 18~25 parts of deionized water,60~75 parts of synthetic resin emulsion,5.0~7.0 parts of auxiliary agent B,A kind of quick-drying of the present invention,It is super water-fast,Super similarity stone-like coating,Stone material emulation similarity with superelevation,Quick-drying,Super water resistance,Surface drying time only has original 1/4,It can reach that dry 2h is soaked not to whiten,And still can slightly it whiten after conventional counterparts drying for 24 hours,Storage period was up to 1 year,Meet commercial requirements.
Description
Technical field
The present invention relates to a kind of decoration of exterior wall art work, more particularly to a kind of super water-fast super similarity stone-like coating of quick-drying
And preparation method thereof, belong to decorating outer wall of building paint field.
Background technology
It is higher and higher to the finishing requirements of building with the raising of people's material and cultural life, to meet high dress
Decorations requirement, past, high-grade decoration was cladding frequently with marble, but itself is heavy, security risk is big, complicated construction technique, expensive
Etc. restricting its application scope；And its substitute lacquer coating, texture coating decoration texture are strong, have higher emulation
Degree, it is moderate, but there are still film from great, dust, single color the shortcomings that；There is also working procedures to answer for polychrome lacquer
Miscellaneous, the shortcomings that cycle is long, difficulty is big, color is not abundant enough；Though plain edition water-soluble colorful coating has marble decoration effect true to nature
Fruit, but texture is not strong enough, becomes its shortcoming；On the basis of the excellent dicoration of water-based colorful imitation marble paint is retained, people
Aqueous multicolor finish containing sand is accordingly developed to make up its texture difference shortcoming, but since its drying is too slow, easy quilt of rainy season
Rainwater washes out, and constrains its use.
The content of the invention
The first technical problem to be solved by the present invention is that providing one kind not only has rich colors, but also with strong Dali
The super water-fast super similarity stone-like coating of quick-drying of stone decorative effect true to nature, with substitute existing marble it is cladding and its substitute quality sense
Coating, lacquer, sliver paint, even existing water-soluble colorful coating and conventional water-soluble colorful coating containing sand；The present invention is ingenious
The color for enriching water-soluble colorful coating combine with lacquer, the strong texture of texture coating, and using raw material
Between controllable reaction improve system viscosity, greatly reduce thickener dosage, reach quick-drying, super water resistance.
The second technical problem to be solved by the present invention is to provide the super water-fast super similarity stone-like coating of above-mentioned quick-drying
Preparation method.
Technical problems to be solved needed for the present invention can be achieved through the following technical solutions：
A kind of super water-fast super similarity stone-like coating of quick-drying is combined application with coloring floating coating and finish, wherein
It is described to colour in floating coating at least containing lotion, color stuffing, functional material composition in the super water-fast super similarity stone-like coating of quick-drying
It is at least formed containing lotion, pigment or titanium dioxide, filler, lotion is included at least in the finish.
In the present invention, the super water-fast super similarity stone-like coating of the quick-drying is formed including at least quartz sand and base paint
The component of color tablets containing sand and dispersed phase component, the weight ratio of the component of color tablets containing sand and dispersed phase component is 3.5~4.5：1；
The component of color tablets containing sand is 1 according to weight ratio by containing sand base paint with granulation pregel component：0.4~0.7 ratio is made
Grain forms, and the base paint containing sand presses 30~60 by base paint and quartz sand component：40~70 ratio mixes；
Wherein, base paint component is made of the raw material for including following parts by weight：
The raw material that dispersed phase component includes following parts by weight is formed：
18~25 parts of deionized water；
60~75 parts of synthetic resin emulsion；
5.0~7.0 parts of auxiliary agent B；
The raw material that the quartz sand component includes following parts by weight is formed：
80-120 mesh (containing 120 mesh) 50~70 parts of quartz sand；
50~30 parts of 120-180 mesh quartz sand；
Wherein, the grain size of quartz sand, ratio can be adjusted flexibly according to stone material roughness, texture effect；
The raw material that granulation pregel component includes following parts by weight is formed：
It is granulated 1 part of lotion；
2.5~4.0 parts of Protection glue；
Appropriate amount of water.
In a preferred embodiment of the invention, the granulation lotion is good 9301 lotion of Poly, is that kind carries
The extraordinary lotion for the functional group that can be reacted with Protection glue, by adjusting its reaction interval with the ratio control system of Protection glue
Degree, to reach the viscosity needed for system, so as to reduce or not add influence system rate of drying and the thickener of water resistance.
In a preferred embodiment of the invention, the Protection glue is handled by grafting, including Shanghai
It can cause the Q2550 Protection glues of functional material Co., Ltd.
In a preferred embodiment of the invention, the weight ratio of the component of color tablets containing sand and dispersed phase component is preferred
4：1.
In a preferred embodiment of the invention, the component of color tablets containing sand is by containing sand base paint and granulation pregel
Component is 1 according to weight ratio：0.6 ratio is granulated.
In a preferred embodiment of the invention, the synthetic resin emulsion in the base paint and dispersed phase component is bag
It includes more than one or both of pure third resin emulsion, organosilicon acrylic resin lotion, fluorine carbon emulsion, elastic emulsion or elastic silicone acrylic emulsion
Combination, take into account stain resistance and volatile organic content.The base paint of the present invention preferably selects to include silicone acrylic emulsion or flexible silicon
The tool low temperature self-contained film properties lotion for being not required to add or help coalescents demand small including acrylic emulsion, such as Shanghai person of outstanding talent's hat trade
The HR-181 of company, KD99,9388A of the good company of Shanghai Poly, the 4765 of Shanghai Zhao companies.The dispersed phase component of the present invention
It preferably selects to include combination more than one or both of pure third resin emulsion, organosilicon acrylic resin lotion, fluorine carbon emulsion, such as Shanghai day
Go out the 661B of company, the KD99 etc. of the good company of Shanghai Poly.
In a preferred embodiment of the invention, the pigment includes one or both of white, red, yellow, blue, black
With the mixing of paint or the mixing of corresponding mill base.The white pigment includes titanium dioxide, using high refractive index, easily disperses
Rutile type titanium white, such as the CR-828 of R-902+, Ke Meiji of Dupont.
In a preferred embodiment of the invention, the filler includes one kind in ultrafine kaolin, wollastonite in powder
Or two or more mixing, the ultrafine kaolin of common 1250 mesh.
In a preferred embodiment of the invention, the auxiliary agent A is helped including dispersant, antifoaming agent, preservative, film forming
One kind or arbitrary two or more mixing in agent, antifreeze, thickener.The wherein preferred ammonium polyacrylate salt of dispersant, such as moral
The 5027 of state's Henkel, the 1124 of Dow Chemical, dosage is the 2%~5% of pigment weight；Antifoaming agent has Henkel KGaA
The B199 of NXZ, rising sun electrification paint the 0.1%-0.3% of total amount based on dosage；Preservative Ke Yi Wei Tuo Luoyi company K9N, Germany
The A26 of Shu Mei companies, LX150, R640 of Dow Chemical paint the 0.1%-0.4% of total amount based on dosage；Antifreeze can
Think propylene glycol or polypropylene glycol.The 0-2.5% of total amount is painted based on dosage；Coalescents can be selected this suitable graceful environmental protection and help
The 1-3% of total amount is painted in agent based on dosage；Thickener has the HS100000YP and HS30000YP of section's Lay anthracene, Asia across dragon
250HBR, the TT-935 of DOW Chemical, the 030 of Shanghai grid paint the 0.5-2% of total amount based on dosage.
In the related embodiment of the present invention, the auxiliary agent B includes antifoaming agent, preservative, coalescents, freeze proof
One kind or arbitrary two or more mixing in agent, thickener.The antifoaming agent has SN8034, Bi Ke company of Henkel KGaA
Byk024, B556, B199 of rising sun electrification, dosage be dispersed phase component total amount 0.1%-0.2%；Preservative can be Germany
Shu Mei companies K40, A28S, LX150, R640 of Dow Chemical, dosage are the 0.1%-0.4% of dispersed phase component total amount；
Antifreeze can be propylene glycol or polypropylene glycol, and dosage is the 0-2.5% of dispersed phase component total amount；Coalescents can be advisable this
Graceful environmentally friendly auxiliary agent, dosage are the 1-3% of dispersed phase component total amount；Thickener can be TT-935, the Shanghai net of DOW Chemical
The 030 of lattice, the B4000 clay class thickeners of strength brightness, dosage are the 0.2-2% of dispersed phase component total amount.
Implement for ease of those skilled in the art, the present invention also provides a kind of super water-fast super similarity stone-like coatings of quick-drying
Preparation method, this method includes：
(1) component of color tablets containing sand is produced：
(1.1) deionized water, part of auxiliary A, pigment or/and filler are weighed by weight under 2000-3000rpm/min
Scattered 30-50min, in uniform state, then adds in synthetic resin emulsion, residue helps to slurry under 1000-2000rpm/min
Agent A adjusts viscous, addition formula ratio after toning quartz sand component, obtains base paint containing sand, for use；
(1.2) pregel is prepared：
Protection glue, water are weighed by formula ratio, disperses 30min in 1000-1500rpm/min, is dissolved into the pre- of homogeneous transparent
Gel, obtains protecting colloid, is then slowly added into and is granulated in lotion, is uniformly mixing to obtain granulation pregel component, for use；
(1.3) it is granulated and is handled with surface cure：
It will be pressed by step (1.1) obtained base paint containing sand and the obtained protecting colloid material of step (1.2) with square gauge
Fixed weight ratio, which is put into prilling granulator, to be granulated to obtain required size specification and the component of color tablets containing sand of hardness, stand,
Surface cure processing；
(2) prepared by dispersed phase component
Deionized water, synthetic resin emulsion, auxiliary agent B are weighed by formula ratio, is stirred evenly under 800-1000rpm/min,
It is configured to dispersed phase components；
(3) preparation of the super water-fast super similarity stone-like coating of quick-drying
The component of color tablets containing sand prepared by step (1) is proportionally added into the dispersed phase component of step (2) preparation, disperseed
It is mixed to get the super water-fast super similarity stone-like coating of quick-drying.
In a preferred embodiment of the invention, in step (1.3), required size specification refers to the mark provided by client
Particle size on quasi- model needed for different color dots
In a preferred embodiment of the invention, in step (1.3), the hardness is the standard jig provided by client
The texture intensity of upper difference color dot determines that texture then requires the toughness strong point of the component of color tablets containing sand strongly；Toughness is strong, then grain
Sub hard, three-dimensional sense is strong after spraying, is not easy to shakeout, and keeps initial particle size；Toughness is low, then particle is soft, can be shakeout after spraying, shape
Into particle diameter it is more slightly larger than initial particle, it is more smooth with respect to decorative pattern.
In a preferred embodiment of the invention, it is described to stand to put after the completion of the granulation of color tablets containing sand in step (1.3)
Next procedure is entered back into after putting 2h or so：Ensure that the surface of color tablets containing sand fully cures and be granulated the reaction of lotion and Protection glue, have
Beneficial to further improving for product bin stability and promotion system viscosity is improved, thickener additive amount is substantially reduced, greatly
Improve the water resistance of film.
In a preferred embodiment of the invention, in step (1.3), the surface cure processing is granulated for color tablets containing sand
2h or so is placed after finishing, it is ensured that the reactive group in the lotion of color tablets surface layer carries out instead with being granulated the functional group of Protection glue in glue
Should, the surface strength of color tablets containing sand is improved, so as to improve the bin stability of product.
Beneficial effects of the present invention：
The super water-fast super similarity stone-like coating of a kind of quick-drying of the present invention, the color for cleverly enriching water-soluble colorful coating
Coloured silk combines with lacquer, the strong texture of texture coating, has the stone material emulation similarity of superelevation, and utilizes raw material
Between controllable reaction improve system viscosity, greatly reduce thickener dosage, reach quick-drying, super water resistance, surface drying time only has
Originally 1/4, it can reach that dry 2h is soaked not to whiten, and still can slightly whiten after conventional counterparts drying for 24 hours, storage period can
Up to 1 year, meet commercial requirements.
Specific embodiment
In order to which the technical means, creative features, achievable purpose and effectiveness for making the present invention are easy to understand, with reference to tool
Body embodiment, the present invention is further explained.
Unless expressly stated otherwise, it is Shanghai Poly to prepare the synthetic resin emulsion in the component of color tablets containing sand to following embodiment
The 9388A lotions of good Chemical Co., Ltd. or the complex emulsions mixed with KD99 lotions, preservative are Tuo Luoyi companies K9N
With the A26 of German Shu Mei companies, antifoaming agent is the B199 of Japanese rising sun electrification, and titanium dioxide is the limited R-902 of Dupont chemical industry
+, ultrafine kaolin is that Shanghai is double up to the kaolin that Chemical Co., Ltd.'s grain size is 1250 mesh, and coalescents are advisable this graceful alcohol ester
12 coalescents, Protection glue can cause the Q2550 Protection glues of functional material Co., Ltd for Shanghai, and quartz sand is Shijiazhuang Jin Yuan
The mixture of Chemical Co., Ltd.'s 120-180 mesh and 80-120 mesh quartz sands, thickener for section's Lay anthracene HS100000YP, it is sub- across
250HBR, the TT-935 of DOW Chemical of dragon are granulated 9301 lotions that lotion is the good Chemical Co., Ltd. of Shanghai Poly, the third breast of silicon
Liquid for the good Chemical Co., Ltd. of Shanghai Poly KD99 lotions or Shanghai sunrise Chemical Co., Ltd. 661B lotions, pH adjusting agent
For the AMP-95 of Dow Chemical.
Embodiment 1
1. produce the component of color tablets containing sand：
49.3 parts of deionized water, 0.5 part of preservative, 0.2 part of dispersant, 0.4 part of antifoaming agent, thickener 250HBR 1.25
Part, 0.15 part of HS100000YP, 1 part of titanium dioxide, 5 parts of ultrafine kaolin, 20 parts of 9388A lotions, 10 parts of KD99 lotions, the third two
1 part of alcohol, 1 part of coalescents.
Deionized water, preservative, dispersant, part antifoaming agent, thickener, titanium dioxide, ultra-fine kaolinite are weighed by weight
Soil disperses 30-50min to slurry in uniform state, then under 1000-2000rpm/min under 2000-3000rpm/min
9388A lotions, KD99 lotions, remaining antifoaming agent, 0.1 part of adjustment viscosity of thickener TT-935 to 110KU are added in, then basis
Different color dot demands are separately added into corresponding color paste toning in client's model, and the base paint that a variety of colors is obtained after toning is spare；
According to the base paint of each color：Quartz sand=55：The quartz sand component mixing that 45 ratio adds in formula ratio is equal
After even, the base paint containing sand of a variety of colors is respectively obtained, for use；
2. prepare granulation pregel component
Protection glue, water are weighed by formula ratio, disperses 30min in 1000-1500rpm/min, is dissolved into the pre- of homogeneous transparent
Gel obtains the protecting colloid of 7% concentration, then according to the protecting colloid of 7% concentration：Good 9301 lotion=3.5 of Poly：1
Ratio is slowly added into good 9301 lotion of Poly, is uniformly mixing to obtain granulation pregel component, for use；
It is handled 3. being granulated with surface cure：
It will separately or concurrently be used by the base paint containing sand of the obtained different colours of step 1 with obtained be granulated of step 2
Pregel presses 1：0.6 weight ratio, which is put into prilling granulator, to be granulated, and obtains the required component of color tablets containing sand.
4. dispersed phase is prepared, mixed, lacquering：
20.7 parts of deionized water, 0.2 part of preservative, 0.1 part of antifoaming agent, 73.2 parts of silicone acrylic emulsion, 2 parts of propylene glycol, film forming
3 parts of auxiliary agent, 0.6 part of thickener, 0.2 part of pH adjusting agent.
Above-mentioned material is weighed by formula ratio, is stirred evenly under 800-1000rpm/min, is configured to dispersed phase, by colors
The component of color tablets containing sand：Dispersed phase=4：1 ratio adds in the above-mentioned assorted component of color tablets containing sand, is mixed to get finished product.
Embodiment 2
1. produce the component of color tablets containing sand：
56.4 parts of deionized water, 0.2 part of preservative, 0.2 part of dispersant, 0.4 part of antifoaming agent, 1 part of titanium dioxide, ultra-fine kaolinite
5 parts of soil, 15 parts of 9388A lotions, 10 parts of KD99 lotions, 1 part of propylene glycol, 1 part of coalescents.
Deionized water, preservative, dispersant, part antifoaming agent, 1.4 parts of thickener 250HBR, titanium white are weighed by weight
Powder, ultrafine kaolin disperse 30-50min to slurry in uniform state, then in 1000- under 2000-3000rpm/min
9388A lotions, KD99 lotions are added under 2000rpm/min, 0.15 part of remaining antifoaming agent, thickener TT-935 adjustment viscosity are extremely
Then 110KU is separately added into corresponding color paste toning according to different color dot demands in client's model, a variety of colors is obtained after toning
Base paint it is spare；
According to the base paint of each color：Quartz sand=60：The quartz sand component mixing that 40 ratio adds in formula ratio is equal
After even, the base paint containing sand of a variety of colors is respectively obtained, for use；
2. prepare granulation pregel
Protection glue, water are weighed by formula ratio, disperses 30min in 1000-1500rpm/min, is dissolved into the pre- of homogeneous transparent
Gel obtains the protecting colloid of 7% concentration, then according to the protecting colloid of 7% concentration：Good 9301 lotion=3.0 of Poly：1
Ratio is slowly added into good 9301 lotion of Poly, is uniformly mixing to obtain granulation pregel component, for use；
It is handled 3. being granulated with surface cure
It will separately or concurrently be used by the base paint containing sand of the obtained different colours of step 1 with obtained be granulated of step 2
Pregel presses 1：0.7 weight ratio, which is put into prilling granulator, to be granulated, and obtains the required component of color tablets containing sand.
4. dispersed phase is prepared, mixed, lacquering：
20.7 parts of deionized water, 0.2 part of preservative, 0.1 part of antifoaming agent, 73.2 parts of silicone acrylic emulsion, 2 parts of propylene glycol, film forming
3 parts of auxiliary agent, 0.6 part of thickener, 0.2 part of pH adjusting agent.
Above-mentioned material is weighed by formula ratio, is stirred evenly under 800-1000rpm/min, is configured to dispersed phase, by colors
The component of color tablets containing sand：Dispersed phase=4.5：1 ratio adds in the above-mentioned assorted component of color tablets containing sand, is mixed to get finished product.
Embodiment 3
1., produce the component of color tablets containing sand：
42.3 parts of deionized water, 0.35 part of preservative, 0.2 part of dispersant, 0.4 part of antifoaming agent, 1 part of titanium dioxide, ultra-fine height
5 parts of ridge soil, 20 parts of 9388A lotions, 15 parts of KD99 lotions, 1 part of propylene glycol, 1 part of coalescents.
Weigh by weight deionized water, preservative, dispersant, part antifoaming agent, 1.0 parts of thickener 250HBR,
0.4 part of HS100000YP, titanium dioxide, ultrafine kaolin disperse 30-50min to slurry in equal under 2000-3000rpm/min
Even state, then adds in 9388A lotions, KD99 lotions under 1000-2000rpm/min, and 0 part of remaining antifoaming agent, thickener glue
Then degree is separately added into corresponding color paste toning according to different color dot demands in client's model, is obtained after toning various to 120KU
The base paint of color is spare；According to the base paint of each color：Quartz sand=40：60 ratio adds in the quartz sand group of formula ratio
Divide after mixing, respectively obtain the base paint containing sand of a variety of colors, for use；
2. prepare granulation pregel
Protection glue, water are weighed by formula ratio, disperses 30min in 1000-1500rpm/min, is dissolved into the pre- of homogeneous transparent
Gel obtains the protecting colloid of 7% concentration, then according to the protecting colloid of 7% concentration：Good 9301 lotion=4.0 of Poly：1
Ratio is slowly added into good 9301 lotion of Poly, is uniformly mixing to obtain granulation pregel component, for use；
It is handled 3. being granulated with surface cure：
It will separately or concurrently be used by the base paint containing sand of the obtained different colours of step 1 with obtained be granulated of step 2
Pregel presses 1：0.4 weight ratio, which is put into prilling granulator, to be granulated, and obtains the required component of color tablets containing sand.
4. dispersed phase is prepared, mixed, lacquering：
20.7 parts of deionized water, 0.2 part of preservative, 0.1 part of antifoaming agent, 73.2 parts of silicone acrylic emulsion, 2 parts of propylene glycol, film forming
3 parts of auxiliary agent, 0.6 part of thickener, 0.2 part of pH adjusting agent.
Above-mentioned material is weighed by formula ratio, is stirred evenly under 800-1000rpm/min, is configured to dispersed phase, by colors
The component of color tablets containing sand：Dispersed phase=3.5：1 ratio adds in the above-mentioned assorted component of color tablets containing sand, is mixed to get finished product.
Embodiment 4
1. produce the component of color tablets containing sand：
53.0 parts of deionized water, 0.5 part of preservative, 0.5 part of dispersant, 0.4 part of antifoaming agent, 1 part of titanium dioxide, ultra-fine kaolinite
5 parts of soil, 30 parts of 661B lotions, 1 part of propylene glycol, 1 part of coalescents.
Weigh by weight deionized water, preservative, dispersant, part antifoaming agent, 1.25 parts of thickener 250HBR,
0.15 part of HS100000YP, titanium dioxide, ultrafine kaolin, under 2000-3000rpm/min disperse 30-50min is in slurry
Then uniform state adds in 661B lotions, 0.05 part of remaining antifoaming agent, thickener TT-935 under 1000-2000rpm/min
Whole viscosity is adjusted to 106KU, corresponding color paste toning is then separately added into according to different color dot demands in client's model, after toning
The base paint for obtaining a variety of colors is spare；
According to the base paint of each color：Quartz sand==33.3：66.7 ratio adds in the quartz sand component of formula ratio
After mixing, the base paint containing sand of a variety of colors is respectively obtained, for use；
2. prepare granulation pregel
Protection glue, water are weighed by formula ratio, disperses 30min in 1000-1500rpm/min, is dissolved into the pre- of homogeneous transparent
Gel obtains the protecting colloid of 7% concentration, then according to the protecting colloid of 7% concentration：Good 9301 lotion=3.5 of Poly：1
Ratio is slowly added into good 9301 lotion of Poly, is uniformly mixing to obtain granulation pregel component, for use；
It is handled 3. being granulated with surface cure
It will separately or concurrently be used by the base paint containing sand of the obtained different colours of step 1 with obtained be granulated of step 2
Pregel presses 1：0.5 weight ratio, which is put into prilling granulator, to be granulated, and obtains the required component of color tablets containing sand.
4. dispersed phase is prepared, mixed, lacquering：
20.7 parts of deionized water, 0.2 part of preservative, 0.1 part of antifoaming agent, 73.2 parts of silicone acrylic emulsion, 2 parts of propylene glycol, film forming
3 parts of auxiliary agent, 0.6 part of thickener, 0.2 part of pH adjusting agent.
Above-mentioned material is weighed by formula ratio, is stirred evenly under 800-1000rpm/min, is configured to dispersed phase, by colors
The component of color tablets containing sand：Dispersed phase=4：1 ratio adds in the above-mentioned assorted component of color tablets containing sand, is mixed to get finished product.
Table 1 is embodiment products obtained therefrom key project index
1 product key project index of table
It is examined by a kind of obtained super water-fast super similarity stone-like coating of quick-drying of above-mentioned 4 embodiments through application and performance
It surveys, performance fully meets the requirement of technical indicator, and fast drying, water resistance is fabulous, and texture is strong, and fidelity is high；Comprehensive analysis：
1 comprehensive performance of embodiment is moderate, is preferred embodiment.
It should be appreciated that after instruction the above of the present invention has been read, those skilled in the art can be to the present invention
It makes various changes or modifications, these equivalent forms also fall within the scope of the appended claims of the present application.
Claims (13)
1. the super water-fast super similarity stone-like coating of quick-drying, which is characterized in that the color tablets containing sand including quartz sand and base paint composition
The weight ratio of component and dispersed phase component, the component of color tablets containing sand and dispersed phase component is 3.5~4.5：1；The color containing sand
Grain component is 1 according to weight ratio by containing sand base paint with granulation pregel component：0.4~0.7 ratio is granulated, described
Base paint containing sand press 30~60 by base paint and quartz sand component：40~70 ratio mixes；
Wherein, base paint component is made of the raw material for including following parts by weight：
The raw material that dispersed phase component includes following parts by weight is formed：
18~25 parts of deionized water；
60~75 parts of synthetic resin emulsion；
5.0~7.0 parts of auxiliary agent B；
The raw material that the quartz sand component includes following parts by weight is formed：
80-120 mesh (contains without 120 mesh) 50~70 parts of quartz sand；
50~30 parts of 120-180 mesh quartz sand；
The raw material that granulation pregel component includes following parts by weight is formed：
It is granulated 1 part of lotion；
2.5~4.0 parts of Protection glue；
Appropriate amount of water.
2. the super water-fast super similarity stone-like coating of quick-drying as described in claim 1, which is characterized in that the granulation lotion is
Good 9301 lotion of Poly.
3. the super water-fast super similarity stone-like coating of quick-drying as described in claim 1, which is characterized in that the Protection glue is upper
Sea can cause the Q2550 Protection glues of functional material Co., Ltd.
4. the super water-fast super similarity stone-like coating of quick-drying as described in claim 1, which is characterized in that the component of color tablets containing sand
Weight ratio with dispersed phase component is 4：1.
5. the super water-fast super similarity stone-like coating of quick-drying as described in claim 1, which is characterized in that the component of color tablets containing sand
It is 1 according to weight ratio by containing sand base paint with granulation pregel component：0.6 ratio is granulated.
6. the super water-fast super similarity stone-like coating of quick-drying as described in claim 1, which is characterized in that the base paint and scattered
Synthetic resin emulsion in phase component is to include pure third resin emulsion, organosilicon acrylic resin lotion, fluorine carbon emulsion, elastic emulsion or elasticity
Combination more than one or both of silicone acrylic emulsion.
7. the super water-fast super similarity stone-like coating of quick-drying as described in claim 1, which is characterized in that the pigment includes
In vain, it is one or both of red, yellow, blue, black with the mixing of paint or the mixing of corresponding mill base.
8. the super water-fast super similarity stone-like coating of quick-drying as described in claim 1, which is characterized in that the filler includes super
Mixing more than one or both of thin kaolin, wollastonite in powder.
9. the super water-fast super similarity stone-like coating of quick-drying as described in claim 1, which is characterized in that the auxiliary agent A includes
One kind or arbitrary two or more mixing in dispersant, antifoaming agent, preservative, coalescents, antifreeze, thickener.
10. the super water-fast super similarity stone-like coating of quick-drying as described in claim 1, which is characterized in that the auxiliary agent B includes
One kind or arbitrary two or more mixing in antifoaming agent, preservative, coalescents, antifreeze, thickener.
11. a kind of system of the super water-fast super similarity stone-like coating of quick-drying as described in any one of claims 1 to 10 claim
Preparation Method, which is characterized in that include the following steps：
(1) component of color tablets containing sand is produced：
(1.1) deionized water, part of auxiliary A, pigment or/and filler is weighed by weight under 2000-3000rpm/min to disperse
30-50min in uniform state, then adds in synthetic resin emulsion to slurry under 1000-2000rpm/min, remaining auxiliary agent A,
Viscous, addition formula ratio after toning quartz sand component is adjusted, obtains base paint containing sand, for use；
(1.2) pregel is prepared：
Protection glue, water are weighed by formula ratio, disperses 30min in 1000-1500rpm/min, is dissolved into the pregel of homogeneous transparent,
Protecting colloid is obtained, is then slowly added into and is granulated in lotion, be uniformly mixing to obtain granulation pregel component, for use；
(1.3) it is granulated and is handled with surface cure：
It will be as step (1.1) obtained base paint containing sand and the obtained protecting colloid material of step (1.2) as defined in formula
Weight ratio, which is put into prilling granulator, to be granulated to obtain required size specification and the component of color tablets containing sand of hardness, is stood, surface
Curing process；
(2) prepared by dispersed phase component
Deionized water, synthetic resin emulsion, auxiliary agent B are weighed by formula ratio, is stirred evenly under 800-1000rpm/min, is prepared
Into dispersed phase components；
(3) preparation of the super water-fast super similarity stone-like coating of quick-drying
The component of color tablets containing sand prepared by step (1) is proportionally added into the dispersed phase component of step (2) preparation, dispersion mixing
Obtain the super water-fast super similarity stone-like coating of quick-drying.
12. the preparation method of the super water-fast super similarity stone-like coating of quick-drying as claimed in claim 11, which is characterized in that step
(1.3) it is described to stand to enter back into next procedure after placing 2h or so after the completion of the granulation of color tablets containing sand in.
13. the preparation method of the super water-fast super similarity stone-like coating of quick-drying as claimed in claim 11, which is characterized in that step
(1.3) in, the surface cure processing places 2h after the completion of being granulated for color tablets containing sand.
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| CN201711260838.4A CN108101424A (en) | 2017-12-04 | 2017-12-04 | A kind of super water-fast super similarity stone-like coating of quick-drying and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111039593A (en) * | 2019-12-26 | 2020-04-21 | 上海贝塔建筑科技有限公司 | As-cast finish concrete imitation coating and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102925022A (en) * | 2012-11-26 | 2013-02-13 | 常熟市蓝都弹性涂料有限公司 | Energy-saving, environment-friendly and water-soluble artificial marble multi-colour paint and preparation method thereof |
| CN104046189A (en) * | 2014-06-27 | 2014-09-17 | 浙江吴越人家新材料有限公司 | Water-based multicolor granite-like paint and preparation method thereof |
| CN104293056A (en) * | 2014-10-08 | 2015-01-21 | 杭州潮头建材有限公司 | Water-based colorful real stone-type stone-like coating and production process thereof |
| CN104745035A (en) * | 2015-03-19 | 2015-07-01 | 东莞大宝化工制品有限公司 | A kind of simulated sand-containing colorful paint and its preparation method and application method |
| WO2017028471A1 (en) * | 2015-08-16 | 2017-02-23 | 上海大通涂料化工有限公司 | Water-based reflective heat-insulating faux stone texture coating system for construction and preparation method thereof |
-
2017
- 2017-12-04 CN CN201711260838.4A patent/CN108101424A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102925022A (en) * | 2012-11-26 | 2013-02-13 | 常熟市蓝都弹性涂料有限公司 | Energy-saving, environment-friendly and water-soluble artificial marble multi-colour paint and preparation method thereof |
| CN104046189A (en) * | 2014-06-27 | 2014-09-17 | 浙江吴越人家新材料有限公司 | Water-based multicolor granite-like paint and preparation method thereof |
| CN104293056A (en) * | 2014-10-08 | 2015-01-21 | 杭州潮头建材有限公司 | Water-based colorful real stone-type stone-like coating and production process thereof |
| CN104745035A (en) * | 2015-03-19 | 2015-07-01 | 东莞大宝化工制品有限公司 | A kind of simulated sand-containing colorful paint and its preparation method and application method |
| WO2017028471A1 (en) * | 2015-08-16 | 2017-02-23 | 上海大通涂料化工有限公司 | Water-based reflective heat-insulating faux stone texture coating system for construction and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111039593A (en) * | 2019-12-26 | 2020-04-21 | 上海贝塔建筑科技有限公司 | As-cast finish concrete imitation coating and preparation method thereof |
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Application publication date: 20180601 |