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CN108087851A - A kind of binary channels waste heat boiler for preventing SCR denitration ammonium salt crystallization - Google Patents

A kind of binary channels waste heat boiler for preventing SCR denitration ammonium salt crystallization Download PDF

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Publication number
CN108087851A
CN108087851A CN201810115043.2A CN201810115043A CN108087851A CN 108087851 A CN108087851 A CN 108087851A CN 201810115043 A CN201810115043 A CN 201810115043A CN 108087851 A CN108087851 A CN 108087851A
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CN
China
Prior art keywords
passage
waste heat
heat boiler
boiler
denitration
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Pending
Application number
CN201810115043.2A
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Chinese (zh)
Inventor
石常庆
崔向阳
敖建军
谭少军
吴彪
苏欣新
沃开宇
殷鸿
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Zhejiang Better Thermal Energy Boiler Equipment Co Ltd
SHANGHAI NINGSONG HEAT ENERGY ENVIRONMENT ENGINEERING Co Ltd
Original Assignee
Zhejiang Better Thermal Energy Boiler Equipment Co Ltd
SHANGHAI NINGSONG HEAT ENERGY ENVIRONMENT ENGINEERING Co Ltd
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Application filed by Zhejiang Better Thermal Energy Boiler Equipment Co Ltd, SHANGHAI NINGSONG HEAT ENERGY ENVIRONMENT ENGINEERING Co Ltd filed Critical Zhejiang Better Thermal Energy Boiler Equipment Co Ltd
Priority to CN201810115043.2A priority Critical patent/CN108087851A/en
Publication of CN108087851A publication Critical patent/CN108087851A/en
Pending legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B1/00Methods of steam generation characterised by form of heating method
    • F22B1/02Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
    • F22B1/18Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B31/00Modifications of boiler construction, or of tube systems, dependent on installation of combustion apparatus; Arrangements or dispositions of combustion apparatus
    • F22B31/08Installation of heat-exchange apparatus or of means in boilers for heating air supplied for combustion

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chimneys And Flues (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention discloses a kind of binary channels waste heat boilers for preventing SCR denitration ammonium salt crystallization, including boiler steel structure, boiler inlet passage, denitration exit passageway, boiler export passage, exhanst gas outlet, waste heat boiler high temperature section, waste heat boiler denitration section and two sets of waste heat boiler low-temperature zones, the denitration exit passageway includes passage A, passage B, the first stop valve being arranged on passage A and the second stop valve being arranged on passage B;The boiler export passage includes channel C, passage D, the 3rd stop valve being arranged in channel C and the 4th stop valve being arranged on passage D;Two sets of waste heat boiler low-temperature zones are arranged on correspondingly between the outlet of the passage A and the import of channel C and between the outlet of the passage B and the import of passage D.The binary channels waste heat boiler of the present invention can effectively avoid because ammonium salt crystallization causes waste heat boiler efficiency to decline and stop, it can be ensured that device long-term operation.

Description

A kind of binary channels waste heat boiler for preventing SCR denitration ammonium salt crystallization
Technical field
The present invention relates to a kind of binary channels waste heat boilers for preventing SCR denitration ammonium salt crystallization.
Background technology
Generally, oil refining, the waste heat boiler of chemical metallurgy device are responsible for the waste heat recovery of device, self-produced steam, feedwater The multinomial effects such as preheating, device vapour and power output.At present, due to the needs of environmental requirement, waste heat boiler is often fitted in SCR Warm denitration function, the principle of SCR denitration are to reduce the NOx in flue gas with ammonia so as to achieve the purpose that denitration.Consider anyization Learning reaction can not possibly convert completely, therefore using inevitably there are ammonia in the flue gas after Benitration reactor during SCR denitration Gas remains, and is commonly called as the escaping of ammonia.The escaping of ammonia be facts have proved in more than 3ppm, the ammonia of escape inevitably with the SO3 in flue gas Generate ammonium sulfate or hydrogen sulfate ammonia with water, be commonly called as the crystallization of sulphur ammonia, the sulphur ammonia crystalline melt point of generation is relatively low, often with the catalysis in flue gas Agent and particulate matter, which combine to be attached on boiler heating surface, causes flue gas to block, and so as to influence boiler efficiency, can seriously influence boiler Safe operation causes to be forced blowing out or destructive consequence.
The content of the invention
The defects of the purpose of the present invention is overcoming the prior art, provides a kind of bilateral for preventing SCR denitration ammonium salt crystallization Road waste heat boiler, with it is light-weight, rational in infrastructure, heat-transfer effect is good, modularized design, binary channels design and installation are convenient The advantages of, it is realized on the basis of being removed to flue gas waste heat recovery and to nitrogen oxides in effluent and avoids ammonium salt crystallization so as to ensure Waste heat boiler long-term operation.
Realizing the technical solution of above-mentioned target is:A kind of binary channels waste heat boiler for preventing SCR denitration ammonium salt crystallization, bag Include boiler steel structure, boiler inlet passage, denitration exit passageway, boiler export passage, exhanst gas outlet, waste heat boiler high temperature section, Waste heat boiler denitration section and two sets of waste heat boiler low-temperature zones, wherein:
The boiler steel structure includes steelframe and the platform staircase that is arranged on the steelframe, the boiler inlet passage, Denitration exit passageway and boiler export passage are separately fixed on the steelframe;
The denitration exit passageway includes passage A, passage B, the first stop valve being arranged on passage A and is arranged on passage The second stop valve on B, the port of export of the boiler inlet passage connect respectively with the passage A and passage B;
The boiler export passage includes channel C, passage D, the 3rd stop valve being arranged in channel C and is arranged on passage The 4th stop valve on D, the channel C and passage D are connected respectively with the exhanst gas outlet;
The passage A and channel C are oppositely arranged, and the passage B and passage D are oppositely arranged;
The waste heat boiler high temperature section includes water conservation section, high temperature superheater, low temperature superheater and high-temperature evaporator;
The waste heat boiler denitration section includes dilution wind preheater, spray ammonia module and Benitration reactor;
The water conservation section, high temperature superheater, low temperature superheater, high-temperature evaporator, dilution wind preheater, spray ammonia module and The flow direction of Benitration reactor along flue gas is successively set in the boiler inlet passage;
Two sets of waste heat boiler low-temperature zones be arranged on correspondingly the passage A outlet and channel C import it Between and the outlet of the passage B and the import of passage D between;
It often covers in the waste heat boiler low-temperature zone and is respectively arranged with flue gas waste heat recovery equipment;
Ash cleaner for exhaust-heating boiler is provided in the waste heat boiler low-temperature zone.
A kind of above-mentioned binary channels waste heat boiler for preventing SCR denitration ammonium salt crystallization, wherein, the flue gas waste heat recovery Equipment includes the cryogenic vaporizer, high-temperature economizer and the low-level (stack-gas) economizer that are set gradually along the flow direction of flue gas.
A kind of above-mentioned binary channels waste heat boiler for preventing SCR denitration ammonium salt crystallization, wherein, the water conservation section, height Warm superheater, low temperature superheater, high-temperature evaporator, dilution wind preheater, spray ammonia module, Benitration reactor, cryogenic vaporizer, height Modular structure is respectively adopted in warm economizer and low-level (stack-gas) economizer.
A kind of above-mentioned binary channels waste heat boiler for preventing SCR denitration ammonium salt crystallization, wherein, the waste heat boiler low temperature Duan Caiyong external thermal insulation hot-wall structures.
A kind of above-mentioned binary channels waste heat boiler for preventing SCR denitration ammonium salt crystallization, wherein, the waste heat boiler deashing Device includes the shock wave soot blower of online soot blowing and the water flushing device of excision soot blower, and the shock wave soot blower is arranged on described On the external thermal insulation hot wall of waste heat boiler low-temperature zone.
A kind of above-mentioned binary channels waste heat boiler for preventing SCR denitration ammonium salt crystallization, wherein, the Benitration reactor is adopted With single-layer or multi-layer Benitration reactor, the multilayer Benitration reactor is set gradually along the flow direction of flue gas.
The binary channels waste heat boiler for preventing SCR denitration ammonium salt crystallization of the present invention, with light-weight, structure conjunction Reason, the advantages of heat-transfer effect is good, modularized design, binary channels design and installation facilitate, to flue gas waste heat recovery and to flue gas On the basis of middle removal of nitrogen oxide realize avoid ammonium salt crystallization so as to ensure waste heat boiler long-term operation, can effectively avoid because Ammonium salt crystallization causes waste heat boiler efficiency to decline and stop.
Description of the drawings
Fig. 1 is the structure diagram of the binary channels waste heat boiler for preventing SCR denitration ammonium salt crystallization of the present invention;
Fig. 2 is the side view of Fig. 1;
Fig. 3 is the process flow chart of the binary channels waste heat boiler for preventing SCR denitration ammonium salt crystallization of the present invention.
Specific embodiment
It is right below in conjunction with the accompanying drawings in order to which those skilled in the art is made to be better understood when technical scheme Its specific embodiment is described in detail:
It please refers to Fig.1, Fig. 2 and Fig. 3, highly preferred embodiment of the present invention, a kind of bilateral for preventing SCR denitration ammonium salt crystallization Road waste heat boiler, including boiler steel structure, boiler inlet passage 10, denitration exit passageway, boiler export passage, exhanst gas outlet 50th, waste heat boiler high temperature section, waste heat boiler denitration section and two sets of waste heat boiler low-temperature zones.
Boiler steel structure includes steelframe 71 and platform staircase 72.Boiler inlet passage 10, denitration exit passageway and boiler go out Mouth passage is separately fixed on steelframe 71.
Denitration exit passageway includes passage A 31, passage B 33, the first stop valve 32 being arranged on passage A 31 and sets The second stop valve 34 on passage B 33 is put, the port of export of boiler inlet passage 10 connects respectively with passage A 31 and passage B 33 It is logical.
Boiler export passage includes channel C 51, passage D 53, the 3rd stop valve 52 being arranged in channel C 51 and sets The 4th stop valve 54 on passage D 53 is put, channel C 51 and passage D 53 are connected respectively with exhanst gas outlet 50.Passage A 31 It is oppositely arranged with channel C 51, passage B 33 and passage D 53 are oppositely arranged;
Waste heat boiler high temperature section includes water conservation section 11, high temperature superheater 12, low temperature superheater 13 and high-temperature evaporator 14; Waste heat boiler denitration section includes dilution wind preheater 21, spray ammonia module 22 and Benitration reactor 23;Water conservation section 11, hyperthermia and superheating Device 12, low temperature superheater 13, high-temperature evaporator 14, dilution wind preheater 21, spray ammonia module 22 and Benitration reactor 23 are along flue gas Flow direction be successively set in boiler inlet passage 10.
Two sets of waste heat boiler low-temperature zones are arranged on correspondingly between the outlet of passage A 31 and the import of channel C 51 And between the outlet of passage B 33 and the import of passage D 53;It often covers in waste heat boiler low-temperature zone and is respectively arranged with fume afterheat Reclaimer, flue gas waste heat recovery equipment can be identical, can also arrange difference;In the present embodiment, flue gas waste heat recovery equipment Include the cryogenic vaporizer 41, high-temperature economizer 42 and the low-level (stack-gas) economizer 43 that are set gradually along the flow direction of flue gas.
Ash cleaner for exhaust-heating boiler is provided in waste heat boiler low-temperature zone.Waste heat boiler low-temperature zone uses external thermal insulation hot wall knot Structure is conducive to set effective soot blowing facility, so as to control ammonium salt crystallization.Ash cleaner for exhaust-heating boiler includes swashing for online soot blowing The water flushing device 62 of ripple soot blower 61 and excision soot blower, shock wave soot blower 61 are arranged on the external thermal insulation of waste heat boiler low-temperature zone On hot wall.
Water conservation section 11, high temperature superheater 12, low temperature superheater 13, high-temperature evaporator 14, dilution wind preheater 21, spray ammonia Modular structure is respectively adopted in module 22, Benitration reactor 23, cryogenic vaporizer 41, high-temperature economizer 42 and low-level (stack-gas) economizer 43. Water conservation section 11, high temperature superheater 12, low temperature superheater 13, high-temperature evaporator 14, dilution wind preheater 21, spray ammonia module 22, Benitration reactor 23, cryogenic vaporizer 41, high-temperature economizer 42 and low-level (stack-gas) economizer 43 form each heating surface of waste heat boiler.I.e. Each heating surface of waste heat boiler is designed as modular structure, has and is replaced using maintenance.
Benitration reactor 23 use single-layer or multi-layer Benitration reactor, multilayer Benitration reactor along the flow direction of flue gas according to Secondary setting.
Again referring to Fig. 3, flue gas enters from the input end of boiler inlet passage 10, successively by water conservation section 11, high temperature At superheater 12, low temperature superheater 13, high-temperature evaporator 14, dilution wind preheater 21, spray ammonia module 22 and Benitration reactor 23 Then reason enters waste heat boiler low-temperature zone by passage A and/or passage B respectively and carries out flue gas waste heat recovery, last flue gas is from logical Road C and/or passage D enters exhanst gas outlet 50, can lead on the passage A, passage B, channel C, passage D before and after waste heat boiler low-temperature zone It crosses corresponding stop valve effectively to cut off, the pipe-line system of two sets of waste heat boiler low-temperature zones also can effectively be cut off and two sets of waste heat boilers Low-temperature zone is spare each other.
In conclusion the binary channels waste heat boiler of the present invention can prevent the binary channels waste heat boiler of SCR denitration ammonium salt crystallization, Have the advantages that with it is light-weight, rational in infrastructure, heat-transfer effect is good, modularized design, binary channels design and installation are convenient, can have Effect avoids because of ammonium salt crystallization waste heat boiler efficiency being caused to decline and stop, it can be ensured that device long-term operation.
Those of ordinary skill in the art it should be appreciated that more than embodiment be intended merely to illustrate the present invention, And be not used as limitation of the invention, as long as in the spirit of the present invention, the change to embodiment described above Change, modification will all fall in the range of claims of the present invention.

Claims (6)

1. a kind of binary channels waste heat boiler for preventing SCR denitration ammonium salt crystallization, which is characterized in that including boiler steel structure, pot Stove intake channel, denitration exit passageway, boiler export passage, exhanst gas outlet, waste heat boiler high temperature section, waste heat boiler denitration section and Two sets of waste heat boiler low-temperature zones, wherein:
The boiler steel structure includes steelframe and the platform staircase being arranged on the steelframe, the boiler inlet passage, denitration Exit passageway and boiler export passage are separately fixed on the steelframe;
The denitration exit passageway includes passage A, passage B, the first stop valve being arranged on passage A and is arranged on passage B The second stop valve, the port of export of the boiler inlet passage connects respectively with the passage A and passage B;
The boiler export passage includes channel C, passage D, the 3rd stop valve being arranged in channel C and is arranged on passage D The 4th stop valve, the channel C and passage D are connected respectively with the exhanst gas outlet;
The passage A and channel C are oppositely arranged, and the passage B and passage D are oppositely arranged;
The waste heat boiler high temperature section includes water conservation section, high temperature superheater, low temperature superheater and high-temperature evaporator;
The waste heat boiler denitration section includes dilution wind preheater, spray ammonia module and Benitration reactor;
The water conservation section, high temperature superheater, low temperature superheater, high-temperature evaporator, dilution wind preheater, spray ammonia module and denitration The flow direction of reactor along flue gas is successively set in the boiler inlet passage;
Two sets of waste heat boiler low-temperature zones be arranged on correspondingly between the outlet of the passage A and the import of channel C with And between the outlet of the passage B and the import of passage D;
It often covers in the waste heat boiler low-temperature zone and is respectively arranged with flue gas waste heat recovery equipment;
Ash cleaner for exhaust-heating boiler is provided in the waste heat boiler low-temperature zone.
2. a kind of binary channels waste heat boiler for preventing SCR denitration ammonium salt crystallization according to claim 1, feature exist In, the flue gas waste heat recovery equipment include the cryogenic vaporizer set gradually along the flow direction of flue gas, high-temperature economizer and Low-level (stack-gas) economizer.
3. a kind of binary channels waste heat boiler for preventing SCR denitration ammonium salt crystallization according to claim 2, feature exist In the water conservation section, high temperature superheater, low temperature superheater, high-temperature evaporator, dilution wind preheater, spray ammonia module, denitration are anti- Answer device, cryogenic vaporizer, high-temperature economizer and low-level (stack-gas) economizer that modular structure is respectively adopted.
4. a kind of binary channels waste heat boiler for preventing SCR denitration ammonium salt crystallization according to claim 1, feature exist In the waste heat boiler low-temperature zone uses external thermal insulation hot-wall structure.
5. a kind of binary channels waste heat boiler for preventing SCR denitration ammonium salt crystallization according to claim 4, feature exist In the ash cleaner for exhaust-heating boiler includes the shock wave soot blower of online soot blowing and the water flushing device of excision soot blower, described Shock wave soot blower is arranged on the external thermal insulation hot wall of the waste heat boiler low-temperature zone.
6. a kind of binary channels waste heat boiler for preventing SCR denitration ammonium salt crystallization according to claim 1, feature exist In the Benitration reactor uses single-layer or multi-layer Benitration reactor, flow direction of the multilayer Benitration reactor along flue gas It sets gradually.
CN201810115043.2A 2018-02-06 2018-02-06 A kind of binary channels waste heat boiler for preventing SCR denitration ammonium salt crystallization Pending CN108087851A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810115043.2A CN108087851A (en) 2018-02-06 2018-02-06 A kind of binary channels waste heat boiler for preventing SCR denitration ammonium salt crystallization

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Application Number Priority Date Filing Date Title
CN201810115043.2A CN108087851A (en) 2018-02-06 2018-02-06 A kind of binary channels waste heat boiler for preventing SCR denitration ammonium salt crystallization

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5943865A (en) * 1998-12-03 1999-08-31 Cohen; Mitchell B. Reheating flue gas for selective catalytic systems
CN204345682U (en) * 2014-12-22 2015-05-20 山东恒涛节能环保有限公司 A kind of boiler flue gas treatment system with SCR denitration function
CN105833695A (en) * 2016-05-03 2016-08-10 浙江天蓝环保技术股份有限公司 Device and technology for wet desulfurization and denitrification of flue gas of coal-fired boiler and treatment of wastewater
CN206198975U (en) * 2016-10-31 2017-05-31 中钢集团鞍山热能研究院有限公司 A kind of desulphurization denitration energy saving integral cleaning system of flue gases of cock oven
US20170197180A1 (en) * 2014-06-05 2017-07-13 Meihua ZOU Process and device for desulphurization and denitration of flue gas
CN107174927A (en) * 2017-07-13 2017-09-19 北京建筑材料科学研究总院有限公司 The method of denitration and system of a kind of cement rotary kiln
CN207849329U (en) * 2018-02-06 2018-09-11 上海宁松热能环境工程有限公司 A kind of binary channels waste heat boiler preventing SCR denitration ammonium salt crystallization

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5943865A (en) * 1998-12-03 1999-08-31 Cohen; Mitchell B. Reheating flue gas for selective catalytic systems
US20170197180A1 (en) * 2014-06-05 2017-07-13 Meihua ZOU Process and device for desulphurization and denitration of flue gas
CN204345682U (en) * 2014-12-22 2015-05-20 山东恒涛节能环保有限公司 A kind of boiler flue gas treatment system with SCR denitration function
CN105833695A (en) * 2016-05-03 2016-08-10 浙江天蓝环保技术股份有限公司 Device and technology for wet desulfurization and denitrification of flue gas of coal-fired boiler and treatment of wastewater
CN206198975U (en) * 2016-10-31 2017-05-31 中钢集团鞍山热能研究院有限公司 A kind of desulphurization denitration energy saving integral cleaning system of flue gases of cock oven
CN107174927A (en) * 2017-07-13 2017-09-19 北京建筑材料科学研究总院有限公司 The method of denitration and system of a kind of cement rotary kiln
CN207849329U (en) * 2018-02-06 2018-09-11 上海宁松热能环境工程有限公司 A kind of binary channels waste heat boiler preventing SCR denitration ammonium salt crystallization

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Address after: Jinhui town Fengxian District Shanghai city 201403 North Village four group B -28

Applicant after: SHANGHAI NINGSONG THERMAL & ENVIRONMENTAL ENGINEERING CO.,LTD.

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Address before: Jinhui town Fengxian District Shanghai city 201403 North Village four group B -28

Applicant before: SHANGHAI NINGSONG THERMAL & ENVIRONMENTAL ENGINEERING CO.,LTD.

Applicant before: ZHEJIANG NINGSONG HEAT ENERGY BOILER EQUIPMENT CO.,LTD.

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Application publication date: 20180529