CN108059916A - A kind of brilliant material of metallic paint surface plating and preparation method thereof - Google Patents
A kind of brilliant material of metallic paint surface plating and preparation method thereof Download PDFInfo
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- CN108059916A CN108059916A CN201711499487.2A CN201711499487A CN108059916A CN 108059916 A CN108059916 A CN 108059916A CN 201711499487 A CN201711499487 A CN 201711499487A CN 108059916 A CN108059916 A CN 108059916A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
- Chemically Coating (AREA)
Abstract
The invention discloses a kind of metallic paint surfaces to plate brilliant material, includes the ingredient of following parts by weight：35 45 parts of organic siliconresin, 0.1 0.2 parts of amino silane, 53 63 parts of organic solvent, 0.3 0.5 parts of fluorine-containing surfactant, 0.2 0.3 parts of ultra-violet absorber, 0.2 0.3 parts of dimethyl silicone polymer, 0.001 0.005 parts of catalyst, 0.1 0.2 parts of isocyanates.Plating brilliant material in metallic paint surface of the present invention is a kind of using the Si O keys repeated as main chain, the polymer of organic group is directly connected on silicon atom, need not in barn hot setting, as long as in air moisture occur chemical reaction crystallization, with regard to that can be cured as with silica (SiO2) crystal glass plating crystal layer as main component, there are splendid yellowing resistance, hardness, hydrophobicity, resistance to acid and alkali etc..Meanwhile the present invention also provides a kind of preparation methods of the brilliant material of metallic paint surface plating.
Description
Technical field
The present invention relates to a kind of surfaces to plate brilliant material and preparation method thereof, the brilliant material of especially a kind of metallic paint surface plating and
Its preparation method.
Background technology
It is clear that metallic paint sealer above market today is substantially the acrylic acid using normal temperature cure, polyurethane
Paint, high temperature baking vanish and UV coating varnishes etc., their usual hardness only have 1H to 3H, so metallic paint surface is very easy to be scraped
Wound, hydrophobic angle are generally smaller than 90 degree, easily contaminated outdoors, it is not easy to clean, yellowing resistance is poor, in 400 degree of high temperature
Under environment, phenomena such as lacquer painting can be scorched, blister, coming off.
The content of the invention
Based on this, a kind of metallic paint surface is provided it is an object of the invention to overcome above-mentioned the deficiencies in the prior art part
The brilliant material of plating.
To achieve the above object, the technical solution used in the present invention is：A kind of brilliant material of metallic paint surface plating, comprising with
The ingredient of lower parts by weight：35-45 parts of organic siliconresin, 0.1-0.2 parts of amino silane, 53-63 parts of organic solvent, fluorochemical surface are lived
0.3-0.5 parts of agent of property, 0.2-0.3 parts of ultra-violet absorber, 0.2-0.3 parts of dimethyl silicone polymer, catalyst 0.001-0.005
Part, 0.1-0.2 parts of isocyanates.
Plating brilliant material in metallic paint surface of the present invention is a kind of using the Si-O keys repeated as main chain, has been directly connected on silicon atom
The polymer of machine group.Need not in barn hot setting, as long as in air moisture occur chemical reaction crystallization, with regard to energy
It is cured as with silica (SiO2) crystal glass plating crystal layer as main component, there is splendid yellowing resistance, hydrophobic angle reaches
To 115 degree, in 25 degree of normal temperature cures, hardness can reach 5H, and in the case where 400 degree of high temperature are roasted, hardness can reach 7H, so can solve
The common metal paint surface protection layer material institute problem.
Preferably, the brilliant material of metallic paint surface plating also includes the ingredient of following parts by weight：Levelling agent 0.2-0.3
Part, 0.1-0.2 parts of antifoaming agent.
Preferably, the organic solvent for ethyl acetate, butyl acetate, n-butyl ether, toluene, hexamethylene, hexahydrotoluene,
At least one of dimethylbenzene, tetrahydrofuran, dioxane.It is described to select to peomote the dissolubility of a variety of materials, reduce
Viscosity is easy to construct.
Preferably, the isocyanates is toluene di-isocyanate(TDI) (TDI), '-diphenylmethane diisocyanate (MDI), different fluorine
Your ketone diisocyanate (IPDI), trimethyl hexamethylene diisocyanate (TMDI), in hexamethylene diisocyanate (HDI) at least
It is a kind of.The selection can improve crosslink density, the hardness for promoting paint film, improve water resistance.
Preferably, the catalyst is at least one of dibutyl tin laurate (DBTDL), triethylamine (TEA).
Preferably, the hydroxyl value of the dimethyl silicone polymer is 28~105mg KOH/g.The poly dimethyl silicon of the hydroxyl value
The reaction of oxygen alkane mitigates, levelability and hydrophobicity are good.
Preferably, the organic siliconresin is methylsiloxane resin.
Preferably, the amino silane for 3- aminopropyl triethoxysilanes, in 3- aminopropyl trimethoxysilanes extremely
Few one kind.To further improve the flexibility of paint film, adhesive force and water resistance.
The commercially available gained of levelling agent of the present invention, for example, buy in for Di Gao companies Tego Glide 410,
Tego Glide 420, Tego Glide 432 or TegoGlide440；The antifoaming agent is BYK065, moral modest 5300；It is described
Fluorine-containing surfactant is Du Pont fluorocarbon surfactant Capstone FS-3100；The ultra-violet absorber is BASF
1130。
Meanwhile the present invention also provides a kind of preparation method of the brilliant material of metallic paint surface plating, include the following steps：
(1) isocyanates, dimethyl silicone polymer, catalyst are uniformly mixed in reaction vessel, then at 60 DEG C
React 4h；
(2) organic siliconresin, organic solvent are added in reaction kettle and be uniformly dispersed；
(3) the completely reacted material of step (1) is added in the reaction kettle in step (2), be further uniformly dispersed；
(4) by the reaction kettle in amino silane injection step (3), then fluorine-containing surfactants are gradually added into reaction kettle
Then agent, levelling agent, antifoaming agent, ultra-violet absorber react 4h at 45 DEG C；
(5) the completely reacted material room temperature of step (4) is stood into curing 12h and plates crystalline substance to get metallic paint surface of the present invention
Material.
In addition, the construction usage technique of plating brilliant material in metallic paint surface of the present invention is as follows：
(1) metallic paint surface first takes off ester with de- ester agent and handles, and by the lacquer painting of lacquer painting inorganic agent spray after a polish, can reach
Degreasing and the effect of sealing lacquer painting.It is erased oil stain with clean superfine fibre cloth later, applied metallic paint surface is until surface is clean
Only；
(2) brilliant sprays materials are plated on special-purpose polishing sponge in appropriate metallic paint surface of the present invention；
(3) and then on lacquer painting linearly wipe in length and breadth, until covering very thin one layer, (about 2um).Place every time
A fritter lacquer painting is managed, maximum is no more than 0.5 square metre；
(4) wait 30 seconds, gently wipe lacquer painting with other one piece of superfine fibre cloth immediately, dried until brilliant agent will be plated, it is no
Then plating brilliant agent can volatilize crystallization；
(5) or so 1 hour that needs to dry in the air again after lacquer painting is finished according to more than flow waits its air-set, in this phase
Between lacquer painting can not get wet.Also note that it cannot be washed with water within 7 days.
Compared with the prior art, beneficial effects of the present invention are：
(1) there is anti-oxidant, age inhibiting effect after the plating of metallic paint surface is brilliant, is formed after construction in surface of vehicle paint hard
Inorganic (silica glass crystal) film plating layer, combine closely with metallic paint, improve lacquer painting hardness and smoothness, by lacquer painting with
Air completely cuts off completely, and without external force factor never drop-off；
(2) glossiness of metallic paint surface varnish can be greatly improved, metallic paint seems more bright-coloured, honorable and takes by force
Mesh；
(3) it is corrosion-resistant.Hard non-organic (glass crystal) film layer itself is also prevented from extraneous acid while will not aoxidizing
The fine and close glass crystal film of the corrosion to metallic paint such as rain, winged insect, birds droppings has superpower corrosion resistance, and plating epitaxial can effectively prevent
Damage caused by the corrosive goodses confrontation metallic paint such as acid rain, while prevent the colour fading of metallic paint；
(4) high temperature resistant.Glass crystal has heat safe speciality in itself, can effectively reflect sunlight by external heat radiation into
Row effectively reflection, prevents injury of the high temperature to metallic paint.
(5) scratch.The hardness on metallic paint surface can be increased to 5-7H by hard non-organic (glass crystal) film layer,
Far above the hardness of the other materials such as acrylic acid, polyurethane 1H-2H, metallic paint surface can preferably be protected not to be scratched, scratch；
(6) it is easy to clean.Electron ion plated film has superpower self-cleaning and water-repellancy, is not easy to attach dust, dirty pool, during cleaning
It is only the effect that can reach cleaning with clear water, metallic paint is made to keep high cleanliness, metallic luster and brightness；
(7) superpower water-repellancy.Hard non-organic (glass crystal) film surface has superpower water-repellancy, falls water
Moment on metallic paint surface layer is shrunk to the formation that droplet landing is effectively prevented incrustation scale.
Specific embodiment
To better illustrate the object, technical solutions and advantages of the present invention, below in conjunction with specific embodiment to the present invention
It is described further.
Embodiment 1
A kind of embodiment of plating brilliant material in metallic paint surface of the present invention, plating brilliant material in metallic paint surface described in the present embodiment
Material includes the ingredient of following parts by weight：
35 parts of methylsiloxane resin, 0.1 part of 3- aminopropyl triethoxysilanes, 63 parts of organic solvent (butyl acetate),
0.2 part of levelling agent (Tego Glide 410), fluorine-containing surfactant (Du Pont fluorocarbon surfactant Capstone FS-
3100) 0.3 part, 0.2 part of ultra-violet absorber (BASF 1130), 0.1 part of antifoaming agent (BYK065), dimethyl silicone polymer
0.2 part of (hydroxyl value 28mg KOH/g), 0.001 part of catalyst (DBTDL), 0.1 part of isocyanates (MDI).
The preparation method of the brilliant material of metallic paint surface plating described in the present embodiment, includes the following steps：
(1) isocyanates, dimethyl silicone polymer, catalyst are uniformly mixed in reaction vessel, then at 60 DEG C
React 4h；
(2) organic siliconresin, organic solvent are added in reaction kettle and be uniformly dispersed；
(3) the completely reacted material of step (1) is added in the reaction kettle in step (2), be further uniformly dispersed；
(4) by the reaction kettle in amino silane injection step (3), then fluorine-containing surfactants are gradually added into reaction kettle
Then agent, levelling agent, antifoaming agent, ultra-violet absorber react 4h at 45 DEG C；
(5) the completely reacted material room temperature of step (4) is stood into curing 12h and plates crystalline substance to get metallic paint surface of the present invention
Material.
Embodiment 2
A kind of embodiment of plating brilliant material in metallic paint surface of the present invention, plating brilliant material in metallic paint surface described in the present embodiment
Material includes the ingredient of following parts by weight：
40 parts of methylsiloxane resin, 0.15 part of 3- aminopropyl trimethoxysilanes, 59 parts of organic solvent (toluene), levelling
0.25 part of agent (Tego Glide 420), fluorine-containing surfactant (Du Pont fluorocarbon surfactant Capstone FS-3100)
0.4 part, 0.25 part of ultra-violet absorber (BASF 1130), 0.15 part of antifoaming agent (BYK065), dimethyl silicone polymer (hydroxyl value
58mg KOH/g) 0.25 part, 0.003 part of catalyst (TEA), 0.15 part of isocyanates (TDI).
The preparation method of the brilliant material of metallic paint surface plating described in the present embodiment, includes the following steps：
(1) isocyanates, dimethyl silicone polymer, catalyst are uniformly mixed in reaction vessel, then at 60 DEG C
React 4h；
(2) organic siliconresin, organic solvent are added in reaction kettle and be uniformly dispersed；
(3) the completely reacted material of step (1) is added in the reaction kettle in step (2), be further uniformly dispersed；
(4) by the reaction kettle in amino silane injection step (3), then fluorine-containing surfactants are gradually added into reaction kettle
Then agent, levelling agent, antifoaming agent, ultra-violet absorber react 4h at 45 DEG C；
(5) the completely reacted material room temperature of step (4) is stood into curing 12h and plates crystalline substance to get metallic paint surface of the present invention
Material.
Embodiment 3
A kind of embodiment of plating brilliant material in metallic paint surface of the present invention, plating brilliant material in metallic paint surface described in the present embodiment
Material includes the ingredient of following parts by weight：
45 parts of methylsiloxane resin, 0.2 part of 3- aminopropyl triethoxysilanes, 53 parts of organic solvent (tetrahydrofuran),
0.3 part of levelling agent (Tego Glide 432), fluorine-containing surfactant (Du Pont fluorocarbon surfactant Capstone FS-
3100) 0.5 part, 0.3 part of ultra-violet absorber (BASF 1130), antifoaming agent (0.2 part of modest 5300) of moral, polysiloxanes (hydroxyl value
105mg KOH/g) 0.3 part, 0.005 part of catalyst (DBTDL), 0.2 part of isocyanates (TMDI).
The preparation method of the brilliant material of metallic paint surface plating described in the present embodiment, includes the following steps：
(1) isocyanates, dimethyl silicone polymer, catalyst are uniformly mixed in reaction vessel, then at 60 DEG C
React 4h；
(2) organic siliconresin, organic solvent are added in reaction kettle and be uniformly dispersed；
(3) the completely reacted material of step (1) is added in the reaction kettle in step (2), be further uniformly dispersed；
(4) by the reaction kettle in amino silane injection step (3), then fluorine-containing surfactants are gradually added into reaction kettle
Then agent, levelling agent, antifoaming agent, ultra-violet absorber react 4h at 45 DEG C；
(5) the completely reacted material room temperature of step (4) is stood into curing 12h and plates crystalline substance to get metallic paint surface of the present invention
Material.
Embodiment 4
Brilliant material is plated on the metallic paint surface being prepared in Examples 1 to 3 and carries out construction usage, the construction usage work
Skill is as follows：
(1) metallic paint surface first takes off ester with de- ester agent and handles, and by the lacquer painting of lacquer painting inorganic agent spray after a polish, can reach
Degreasing and the effect of sealing lacquer painting.It is erased oil stain with clean superfine fibre cloth later, applied metallic paint surface is until surface is clean
Only；
(2) brilliant sprays materials are plated on special-purpose polishing sponge in appropriate metallic paint surface of the present invention；
(3) and then on lacquer painting linearly wipe in length and breadth, until covering very thin one layer, (about 2um).Place every time
A fritter lacquer painting is managed, maximum is no more than 0.5 square metre；
(4) wait 30 seconds, gently wipe lacquer painting with other one piece of superfine fibre cloth immediately, dried until brilliant agent will be plated, it is no
Then plating brilliant agent can volatilize crystallization；
(5) or so 1 hour that needs to dry in the air again after lacquer painting is finished according to more than flow waits its air-set, in this phase
Between lacquer painting can not get wet.Also note that it cannot be washed with water within 7 days.
Gained lacquer painting of constructing to it carries out performance evaluation, and the test method of performance is carried out with reference to this field relevant criterion,
Specific performance analysis result is as shown in table 1：
Table 1 plates brilliant material property detection and analysis table
As it can be seen from table 1 the metallic paint surface brilliant material of plating in the embodiment of the present invention 1~3 has, adhesive force is good, hardness
High, corrosion-resistant, acid and alkali-resistance, Gao Zedu be good, superpower pulls out the advantages such as aqueous.
Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than the present invention is protected
The limitation of scope is protected, although being explained in detail with reference to preferred embodiment to the present invention, those of ordinary skill in the art should
Understand, technical scheme can be modified or replaced equivalently, without departing from the essence of technical solution of the present invention
And scope.
Claims (9)
1. a kind of brilliant material of metallic paint surface plating, which is characterized in that include the ingredient of following parts by weight：Organic siliconresin 35-45
Part, 0.1-0.2 parts of amino silane, 53-63 parts of organic solvent, 0.3-0.5 parts of fluorine-containing surfactant, ultra-violet absorber 0.2-
0.3 part, 0.2-0.3 parts of dimethyl silicone polymer, 0.001-0.005 parts of catalyst, 0.1-0.2 parts of isocyanates.
2. plating brilliant material in metallic paint surface as described in claim 1, which is characterized in that also include the ingredient of following parts by weight：
0.2-0.3 parts of levelling agent, 0.1-0.2 parts of antifoaming agent.
3. plating brilliant material in metallic paint surface as claimed in claim 1 or 2, which is characterized in that the organic solvent is acetic acid second
At least one in ester, butyl acetate, n-butyl ether, toluene, hexamethylene, hexahydrotoluene, dimethylbenzene, tetrahydrofuran, dioxane
Kind.
4. plating brilliant material in metallic paint surface as claimed in claim 1 or 2, which is characterized in that the isocyanates is toluene two
Isocyanates, '-diphenylmethane diisocyanate, isoflurane chalcone diisocyanate, trimethyl hexamethylene diisocyanate, hexa-methylene two
At least one of isocyanates.
5. plating brilliant material in metallic paint surface as claimed in claim 1 or 2, which is characterized in that the catalyst is tin dilaurate
At least one of dibutyl tin, triethylamine.
6. plating brilliant material in metallic paint surface as claimed in claim 1 or 2, which is characterized in that the dimethyl silicone polymer
Hydroxyl value is 28~105mg KOH/g.
7. plating brilliant material in metallic paint surface as claimed in claim 1 or 2, which is characterized in that the organic siliconresin is methyl
Organic siliconresin.
8. plating brilliant material in metallic paint surface as claimed in claim 1 or 2, which is characterized in that the amino silane is 3- ammonia third
At least one of ethyl triethoxy silicane alkane, 3- aminopropyl trimethoxysilanes.
9. a kind of preparation method that brilliant material is plated such as claim 1~8 any one of them metallic paint surface, which is characterized in that
Include the following steps：
(1) isocyanates, dimethyl silicone polymer, catalyst in reaction vessel are uniformly mixed, are then reacted at 60 DEG C
4h；
(2) organic siliconresin, organic solvent are added in reaction kettle and be uniformly dispersed；
(3) the completely reacted material of step (1) is added in the reaction kettle in step (2), be further uniformly dispersed；
(4) by the reaction kettle in amino silane injection step (3), then be gradually added into reaction kettle fluorine-containing surfactant,
Then levelling agent, antifoaming agent, ultra-violet absorber react 4h at 45 DEG C；
(5) the completely reacted material room temperature of step (4) is stood into curing 12h and plates brilliant material to get metallic paint surface of the present invention.
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| CN201711499487.2A CN108059916B (en) | 2017-12-29 | 2017-12-29 | Metal paint surface crystal plating material and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109762464A (en) * | 2019-01-28 | 2019-05-17 | 新辉（中国）新材料有限公司 | Hydrophobic coating material of high-hardness high-light pool degree of room temperature curing and preparation method thereof |
| CN109762464B (en) * | 2019-01-28 | 2021-04-30 | 新辉（中国）新材料有限公司 | Room-temperature-cured high-hardness high-glossiness hydrophobic coating material and preparation method thereof |
| CN111647350A (en) * | 2020-04-28 | 2020-09-11 | 江苏龙蟠科技股份有限公司 | Hydrophobic scratch-resistant long-life paint surface coating and preparation method thereof |
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