CN108048252A - A kind of preparation method of bathtub cleaning agent - Google Patents
A kind of preparation method of bathtub cleaning agent Download PDFInfo
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- CN108048252A CN108048252A CN201711276713.0A CN201711276713A CN108048252A CN 108048252 A CN108048252 A CN 108048252A CN 201711276713 A CN201711276713 A CN 201711276713A CN 108048252 A CN108048252 A CN 108048252A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
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- C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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Abstract
The invention discloses a kind of preparation methods of bathtub cleaning agent, belong to household chemicals technical field.The present invention will pre-process sepiolite and No. 1 treatment fluid mixes, and after being stirred to react, filter, dry, obtain No. 1 additive；Pretreatment zeolite with No. 2 treatment fluids is mixed, after being stirred, is filtered, it is dry, obtain No. 2 additives；It counts, weighs successively in parts by weight：3~8 parts of hydrochloric acid, 30~45 parts of water, 5~8 parts of No. 1 additives, 5~8 parts of No. 2 additives, 10~13 parts of surfactants, 2~5 parts of auxiliary agents, 2~4 parts of essential oil, 1~3 part of catalyst and 3~5 parts of hydroxymethyl celluloses, after raw material is stirred, bathtub cleaning agent is obtained.Bathtub cleaning agent prepared by the present invention has excellent dirt-removing power, and to washing rear bathtub with protecting effect.
Description
Technical field
The invention discloses a kind of preparation methods of bathtub cleaning agent, belong to household chemicals technical field.
Background technology
With the raising of lives of the people level, used bathtub also tends to be medium-to-high grade day.Sanitary ware is typically all acid
It washes, but the cleaning washing of its safety becomes one than more prominent problem.Bathtub used in family has cast iron enamel bathtub, steel plate to ward off
Porcelain bathtub and acryl bathtub etc., enamel bathtub are deep due tos beautiful and comfortable, sturdy and durable, excellent thermal insulation performance and affordable etc.
It is welcome by consumers in general.The composite wood that enamel is made of inorganic vitreous enamel and metal.Quartz, feldspar, clay and borax
Inorganic matters are waited, mix high-temperature fusion, levigate after cooling is vitreous enamel.So the major defect of enamelware is acid-fast alkali-proof
It is poor to learn stability, enamel porcelain（Glaze）Face is subject to be damaged after being corroded by soda acid to cause scared, and dirt can be more difficult to remove.
Acid solution invades candle to enamel coating, starts from the ion exchange at sour porcelain interface, ion exchange pine, so that the molecule in acid solution
Also enamel coating can be diffused into, directly destroys enamel coating structure.Destruction of the acid to enamel coating, is not only alkali metal oxide and is hydrolyzed
And solution is changed into, and the cinnamic acid salt of the alkaline-earth metal of weak hydrolysis, zinc and trick also can partly be subject to the rotten candle effect of acid.Generally
Think, acid solution is that the king of enamel wants etchant.Corrosion of the alkali to enamel coating, not as good as acid is to noticeable the corrosion of enamel coating.Alkali
Effect of the acid to enamel is different to the effect of enamel, when alkali contacts enamel, alkali metal oxide is mainly leached out, sends out simultaneously
Raw silicic acid be partly dissolved or all dissolvings.Therefore, aqueous slkali is also stronger to the erosion of enamel, and the degree of corrosion is usual
It is proportional to the time of effect.
Bath tub surface dirt is mainly soap scum not soluble in water（Calcium and magnesium soap）, incrustation scale（Calcium carbonate and magnesium carbonate etc.）And people
Body dirt（Sebum and dust of human secretory etc.）.Soap scum forms with other dirts such as incrustation scale combination hair and scurfs and mixes dirt
Dirt is attached on bath tub surface securely, it is difficult to remove.In general, soap scum and incrustation scale are usually washed with acidic cleaning, are allowed to
It is removed as solubility salt, but bronsted lowry acids and bases bronsted lowry has corrosiveness to the enamel layer of bathtub, so preferably in raising, its cleaning is gone
While dirty effect, corrosion of the cleaning agent to bathtub should be reduced.
Therefore, it is bad how to improve conventional bath cleaning agent dirt-removing power, is not grown in the bath tub surface residence time, protection effect
The shortcomings that fruit is short of is that it is promoted with applied to broader field, meeting to obtain the tile cleaner of more high combination property
Industrial production demand urgent problem to be solved.
The content of the invention
The present invention solves the technical problem of：It is bad for conventional bath cleaning agent dirt-removing power, in bath tub surface
The shortcomings that residence time is not grown, and protecting effect is short of, provides a kind of preparation method of bathtub cleaning agent.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is：
（1）By sepiolite and water in mass ratio 1：4~1：6 mixing, after constant temperature is stood, concentrated by rotary evaporation obtains pretreatment sepiolite；
（2）Zeolite is crushed, sintering furnace is moved into after sieving, is sintered, obtains pretreatment zeolite；
（3）By nano silicon dioxide and water in mass ratio 1：10~1：15 mixing, and add in nano silicon dioxide quality 0.2~
0.5 times of dispersant after being stirred, obtains No. 1 treatment fluid；
（4）By Gluten and chitosan in mass ratio 1：1~1：2 mixed grindings, obtain mixed-powder, and mixed-powder and water are pressed matter
Measure ratio 1：8~1：15 mixing, after being stirred, obtain No. 2 treatment fluids；
（5）It will pretreatment sepiolite and No. 1 treatment fluid in mass ratio 1：2~1：5 mixing after being stirred to react, are filtered, dry, obtain 1
Number additive；
（6）It will pretreatment zeolite and No. 2 treatment fluids in mass ratio 1：5~1：8 mixing after being stirred, are filtered, dry, obtain No. 2
Additive；
（7）Count in parts by weight, weigh successively 3~8 parts of hydrochloric acid, 30~45 parts of water, 5~8 parts of No. 1 additives, 5~8 parts No. 2 add
Add agent, 10~13 parts of surfactants, 2~5 parts of auxiliary agents, 2~4 parts of essential oil, 1~3 part of catalyst and 3~5 parts of methylol fibres
Dimension element, after raw material is stirred, obtains bathtub cleaning agent.
Step（3）The dispersant is dispersant NNO, any one in Dispersant MF or dispersant 5040.
Step（7）The preparation method of the surfactant is by neopelex and dodecyl dimethyl sweet tea
Dish alkali in mass ratio 1：1~1：2 mixing, and 0.5~0.7 times of part Tween-60 of neopelex quality is added in, stirring is mixed
It closes, obtains surfactant.
Step（7）The auxiliary agent is any one in sodium alginate or Lauryl Alcohol ester.
Step（7）The essential oil is Peppermint essential oil, any one in refined jasmine oil or Salvia japonica essential oil.
Step（7）The catalyst is any one in two ring ethyls, two carbon imines or p-methyl benzenesulfonic acid.
The beneficial effects of the invention are as follows：
（1）The present invention adds in No. 1 additive when preparing bathtub cleaning agent, and first, the sepiolite in No. 1 additive is at process
After reason, adsorption area increase, after adding in detergent system, in use, the dirt of adsorbable bath tub surface deposition,
So that the dirt-removing power of product improves, secondly, sepiolite in No. 1 additive is a certain amount of in adsorption after treatment
Nano silicon dioxide, in use, the pit of bath tub surface can be filled under the effect of the catalyst, so as to
The consistency of bath tub surface is improved, and then makes product that can play a protective role after bathtub is cleaned to bathtub；
（2）The present invention adds in No. 2 additives when preparing bathtub cleaning agent, on the one hand, Gluten and shell are added in No. 2 additives
Glycan after being added in detergent system, can play suction to the metal ion in bath tub surface dirt and oil substances
Attached effect, makes it be fixed on zeolite surface, so that the dirt-removing power of product further improves, on the other hand, the zeolite of addition
After processing, volume becomes smaller, and can be attached to bath tub surface in physical action in use, adsorb bath tub surface
The dirt generated again and extra acid solution, and then prevent bathtub from irreversible breaking occurring in washing process, bathtub is risen
To protective effect.
Specific embodiment
By sepiolite and water in mass ratio 1：4~1：6 are mixed in beaker, and by beaker under room temperature, constant temperature is stood
After 30~50min, material in beaker is moved into Rotary Evaporators, is 70~80 DEG C in temperature, rotating speed is 160~180r/min,
Under conditions of pressure is 500~800kPa, 25~35min of concentrated by rotary evaporation obtains pretreatment sepiolite；Zeolite is moved into pulverizer
It crushes, crosses 100~160 mesh sieves, obtain zeolite powder, zeolite powder is moved into sintering furnace, in the item that temperature is 300~400 DEG C
Under part after 45~60min of calcining at constant temperature, pretreatment zeolite is obtained；By nano silicon dioxide and water in mass ratio 1：10~1：15 mixing
In flask, and the dispersant of 0.2~0.5 times of nano silicon dioxide quality is added in into flask, flask immigration digital display is tested the speed
Constant temperature blender with magnetic force, in 45~55 DEG C of temperature, under conditions of rotating speed is 240~280r/min, constant temperature stirs 45~55min
Afterwards, No. 1 treatment fluid is obtained；By Gluten and chitosan in mass ratio 1：1~1：2 mixed grindings, obtain mixed-powder, by mixed-powder
With water in mass ratio 1：8~1：15 are mixed in beaker, and beaker immigration digital display is tested the speed constant temperature blender with magnetic force, in temperature be 40
~50 DEG C, under conditions of rotating speed is 200~250r/min, after being stirred 30~50min, obtain No. 2 treatment fluids；It will pretreatment sea
Afrodite and No. 1 treatment fluid in mass ratio 1：2~1：5 mixing are 35~45 DEG C in temperature, and rotating speed is the item of 200~240r/min
Under part, after being stirred 45~55min, filtering obtains filter cake, filter cake is moved into drying box, in the condition that temperature is 70~90 DEG C
Under, 25~40min of freeze-day with constant temperature obtains No. 1 additive；It will pretreatment zeolite and No. 2 treatment fluids in mass ratio 1：5~1：8 mixing,
It is 40~55 DEG C in temperature, under conditions of rotating speed is 180~220r/min, after being stirred 30~50min, filtering obtains filter residue,
Filter residue is moved into drying box, under conditions of temperature is 70~85 DEG C, 20~35min of freeze-day with constant temperature obtains No. 2 additives；By weight
Number meter is measured, is weighed successively：3~8 parts of hydrochloric acid, 30~45 parts of water, 5~8 parts of No. 1 additives, 5~8 parts of No. 2 additives, 10~
13 parts of surfactants, 2~5 parts of auxiliary agents, 2~4 parts of essential oil, 1~3 part of catalyst and 3~5 parts of hydroxymethyl celluloses, by original
Material is moved into mixer, is 35~50 DEG C in temperature, under conditions of rotating speed is 200~220r/min, it is stirred 30~
40min obtains bathtub cleaning agent.The dispersant is dispersant NNO, any one in Dispersant MF or dispersant 5040.It is described
The preparation method of surfactant is by neopelex and dodecyldimethylammonium hydroxide inner salt in mass ratio 1：1~1：
2 mixing, and 0.5~0.7 times of part Tween-60 of neopelex quality is added in, it is stirred, obtains surfactant.Institute
Auxiliary agent is stated as any one in sodium alginate or Lauryl Alcohol ester.The essential oil is Peppermint essential oil, refined jasmine oil or Salvia japonica
Any one in essential oil.The catalyst is any one in two ring ethyls, two carbon imines or p-methyl benzenesulfonic acid.
Example 1
By sepiolite and water in mass ratio 1：6 are mixed in beaker, by beaker under room temperature, after constant temperature stands 50min, incite somebody to action
Material moves into Rotary Evaporators in beaker, is 80 DEG C, rotating speed 180r/min in temperature, under conditions of pressure is 800kPa, revolves
Inspissation contracting 35min, obtains pretreatment sepiolite；Zeolite is moved into pulverizer and is crushed, 160 mesh sieves is crossed, zeolite powder is obtained, by zeolite
Powder is moved into sintering furnace, under conditions of temperature is 400 DEG C after calcining at constant temperature 60min, obtains pretreatment zeolite；By nano-silica
SiClx and water in mass ratio 1：15 are mixed in flask, and the dispersant of 0.5 times of nano silicon dioxide quality is added in into flask,
Flask immigration digital display is tested the speed constant temperature blender with magnetic force, in 55 DEG C of temperature, under conditions of rotating speed is 280r/min, constant temperature stirring
After 55min, No. 1 treatment fluid is obtained；By Gluten and chitosan in mass ratio 1：2 mixed grindings, obtain mixed-powder, by mixed-powder
With water in mass ratio 1：15 are mixed in beaker, and beaker immigration digital display is tested the speed constant temperature blender with magnetic force, are 50 DEG C in temperature, turn
Under conditions of speed is 250r/min, after being stirred 50min, No. 2 treatment fluids are obtained；Pretreatment sepiolite and No. 1 treatment fluid are pressed
Mass ratio 1：5 mixing are 45 DEG C in temperature, and under conditions of rotating speed is 240r/min, after being stirred 55min, filtering must filter
Filter cake is moved into drying box by cake, and under the conditions of at a temperature of 90 °C, freeze-day with constant temperature 40min obtains No. 1 additive；Pretreatment is boiled
Stone and No. 2 treatment fluids in mass ratio 1：8 mixing are 55 DEG C in temperature, under conditions of rotating speed is 220r/min, are stirred
After 50min, filtering obtains filter residue, filter residue is moved into drying box, and under conditions of temperature is 85 DEG C, freeze-day with constant temperature 35min obtains No. 2
Additive；It counts, weighs successively in parts by weight：8 parts of hydrochloric acid, 45 parts of water, 8 parts of No. 1 additives, 8 parts of No. 2 additives, 13 parts of tables
Face activating agent, 5 parts of auxiliary agents, 4 parts of essential oil, 3 parts of catalyst and 5 parts of hydroxymethyl celluloses move into raw material in mixer, Yu Wen
It spends for 50 DEG C, under conditions of rotating speed is 220r/min, is stirred 40min, obtains bathtub cleaning agent.The dispersant is dispersant
NNO.The preparation method of the surfactant is that neopelex and dodecyldimethylammonium hydroxide inner salt are pressed quality
Than 1：2 mixing, and 0.7 times of part Tween-60 of neopelex quality is added in, it is stirred, obtains surfactant.It is described
Auxiliary agent is sodium alginate.The essential oil is Peppermint essential oil.The catalyst is two ring ethyls, two carbon imines.
Example 2
Zeolite is moved into pulverizer and is crushed, 160 mesh sieves is crossed, obtains zeolite powder, zeolite powder is moved into sintering furnace, in temperature
After calcining at constant temperature 60min under conditions of 400 DEG C, pretreatment zeolite is obtained；By Gluten and chitosan in mass ratio 1：2 mixing are ground
Mill, obtains mixed-powder, by mixed-powder and water in mass ratio 1：15 are mixed in beaker, and beaker immigration digital display is tested the speed constant temperature magnetic
Power blender is 50 DEG C in temperature, under conditions of rotating speed is 250r/min, after being stirred 50min, obtains No. 2 treatment fluids；It will be pre-
Handle zeolite and No. 2 treatment fluids in mass ratio 1：8 mixing are 55 DEG C in temperature, and under conditions of rotating speed is 220r/min, stirring is mixed
After closing 50min, filtering obtains filter residue, filter residue is moved into drying box, and under conditions of temperature is 85 DEG C, freeze-day with constant temperature 35min obtains 2
Number additive；It counts, weighs successively in parts by weight：8 parts of hydrochloric acid, 45 parts of water, 8 parts of No. 2 additives, 13 parts of surfactants, 5 parts
Auxiliary agent, 4 parts of essential oil, 3 parts of catalyst and 5 parts of hydroxymethyl celluloses move into raw material in mixer, are 50 DEG C in temperature, turn
Under conditions of speed is 220r/min, 40min is stirred, obtains bathtub cleaning agent.The dispersant is dispersant NNO.The table
The preparation method of face activating agent is by neopelex and dodecyldimethylammonium hydroxide inner salt in mass ratio 1：2 mixing,
And 0.7 times of part Tween-60 of neopelex quality is added in, it is stirred, obtains surfactant.The auxiliary agent is seaweed
Sour sodium.The essential oil is Peppermint essential oil.The catalyst is two ring ethyls, two carbon imines.
Example 3
By sepiolite and water in mass ratio 1：6 are mixed in beaker, by beaker under room temperature, after constant temperature stands 50min, incite somebody to action
Material moves into Rotary Evaporators in beaker, is 80 DEG C, rotating speed 180r/min in temperature, under conditions of pressure is 800kPa, revolves
Inspissation contracting 35min, obtains pretreatment sepiolite；By nano silicon dioxide and water in mass ratio 1：15 are mixed in flask, and to burning
The dispersant of 0.5 times of nano silicon dioxide quality is added in bottle, flask immigration digital display is tested the speed constant temperature blender with magnetic force, in temperature
55 DEG C, under conditions of rotating speed is 280r/min, after constant temperature stirring 55min, obtain No. 1 treatment fluid；It will pre-process at sepiolite and No. 1
Manage liquid in mass ratio 1：5 mix, and are 45 DEG C in temperature, under conditions of rotating speed is 240r/min, after being stirred 55min, filter,
Filter cake is obtained, filter cake is moved into drying box, under the conditions of at a temperature of 90 °C, freeze-day with constant temperature 40min obtains No. 1 additive；By weight
Number meter, weighs successively：8 parts of hydrochloric acid, 45 parts of water, 8 parts of No. 1 additives, 13 parts of surfactants, 5 parts of auxiliary agents, 4 parts of essential oil,
3 parts of catalyst and 5 parts of hydroxymethyl celluloses move into raw material in mixer, are 50 DEG C in temperature, rotating speed is the item of 220r/min
Under part, 40min is stirred, obtains bathtub cleaning agent.The dispersant is dispersant NNO.The preparation side of the surfactant
Method is by neopelex and dodecyldimethylammonium hydroxide inner salt in mass ratio 1：2 mixing, and add in detergent alkylate
0.7 times of part Tween-60 of sodium sulfonate quality, is stirred, obtains surfactant.The auxiliary agent is sodium alginate.The essential oil
For Peppermint essential oil.The catalyst is two ring ethyls, two carbon imines.
Comparative example：The bathtub cleaning agent of Foshan Science and Technology Ltd. production.
The bathtub cleaning agent of 1 to 3 gained of example and comparative example product are subjected to performance detection, specific detection method is as follows：
1. clean effect：It is several to choose 8cm × 4cm stainless steel iron plates, surface applies imitative enamel paint；According to dirt formula（Calcium and magnesium soap
45%（Calcium soap 80%, magnesium soap 20%）；Miscella 50%（Castor oil 35%, lanolin 60%, atoleine 5%）；Ash content 5%（Carbon black
50%, iron oxide 50%））Heat mixed configuration dirt；Dirt is uniformly applied to stainless steel iron plate surface, constant temperature is placed at 40 DEG C
Aging is for 24 hours；It is put into the washing lotion containing test specimen 5% and impregnates 5min, then wash 2min with BXJ-III types pendulum washing machine pendulum（Wobble frequency is 40
Secondary/min, wash temperature are 42 DEG C）；Test specimen soil removal efficiency is detected, according to（1）Formula calculates；
Soil removal efficiency=（m1-m2）/（m1-m0）×100%
In formula：m0For clean test piece quality before defiling（g）；m1For test piece after painting and the gross mass of dirt（g）；m2It washes and dries for pendulum
Test piece residue dirt gross mass afterwards（g）；
2. wall built-up is tested：（l）Take one piece of toilet tile（30cm×20cm×0.8cm）It is divided into several areas vertically, as survey
Test plate (panel)；（2）Tile is cleaned up, vertical naturally dry 1 minute keeps flat tile, is respectively dropped into same amount made of different test specimens
After sample is at the most top in each area of tile, tile is holded up with the horizontal 90 degree, institute is recorded when sample naturally flows to bottom
It takes time；（3）With same tile repeat above step, continuous 3 times.
Specific testing result is as shown in table 1：
Table 1
| Detection project | Example 1 | Example 2 | Example 3 | Comparative example |
| Soil removal efficiency/% | 98.3 | 87.6 | 83.2 | 52.4 |
| The wall built-up time/s | 376 | 258 | 215 | 112 |
From 1 testing result of table, bathtub cleaning agent prepared by technical solution of the present invention has excellent dirt-removing power, decontamination
The characteristics of significant effect, meanwhile, cleaning performance can enhanced in cleaned material superficial residence longer time, reducing waste,
And it with good protecting effect, has broad prospects in the development of daily bathtub cleaning industry.
Claims (6)
1. a kind of preparation method of bathtub cleaning agent, it is characterised in that specifically preparation method is：
（1）By sepiolite and water in mass ratio 1：4~1：6 mixing, after constant temperature is stood, concentrated by rotary evaporation obtains pretreatment sepiolite；
（2）Zeolite is crushed, sintering furnace is moved into after sieving, is sintered, obtains pretreatment zeolite；
（3）By nano silicon dioxide and water in mass ratio 1：10~1：15 mixing, and add in nano silicon dioxide quality 0.2~
0.5 times of dispersant after being stirred, obtains No. 1 treatment fluid；
（4）By Gluten and chitosan in mass ratio 1：1~1：2 mixed grindings, obtain mixed-powder, and mixed-powder and water are pressed matter
Measure ratio 1：8~1：15 mixing, after being stirred, obtain No. 2 treatment fluids；
（5）It will pretreatment sepiolite and No. 1 treatment fluid in mass ratio 1：2~1：5 mixing after being stirred to react, are filtered, dry, obtain 1
Number additive；
（6）It will pretreatment zeolite and No. 2 treatment fluids in mass ratio 1：5~1：8 mixing after being stirred, are filtered, dry, obtain No. 2
Additive；
（7）Count in parts by weight, weigh successively 3~8 parts of hydrochloric acid, 30~45 parts of water, 5~8 parts of No. 1 additives, 5~8 parts No. 2 add
Add agent, 10~13 parts of surfactants, 2~5 parts of auxiliary agents, 2~4 parts of essential oil, 1~3 part of catalyst and 3~5 parts of methylol fibres
Dimension element, after raw material is stirred, obtains bathtub cleaning agent.
2. a kind of preparation method of bathtub cleaning agent according to claim 1, it is characterised in that：Step（3）It is described scattered
Agent is dispersant NNO, any one in Dispersant MF or dispersant 5040.
3. a kind of preparation method of bathtub cleaning agent according to claim 1, it is characterised in that：Step（7）The surface
The preparation method of activating agent is by neopelex and dodecyldimethylammonium hydroxide inner salt in mass ratio 1：1~1：2 is mixed
It closes, and adds in 0.5~0.7 times of part Tween-60 of neopelex quality, be stirred, obtain surfactant.
4. a kind of preparation method of bathtub cleaning agent according to claim 1, it is characterised in that：Step（7）The auxiliary agent
For any one in sodium alginate or Lauryl Alcohol ester.
5. a kind of preparation method of bathtub cleaning agent according to claim 1, it is characterised in that：Step（7）The essence
Oil is Peppermint essential oil, any one in refined jasmine oil or Salvia japonica essential oil.
6. a kind of preparation method of bathtub cleaning agent according to claim 1, it is characterised in that：Step（7）The catalysis
Agent is any one in two ring ethyls, two carbon imines or p-methyl benzenesulfonic acid.
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Application publication date: 20180518 |