CN108048245A - 天然浓缩型泡沫餐具洗涤剂 - Google Patents
天然浓缩型泡沫餐具洗涤剂 Download PDFInfo
- Publication number
- CN108048245A CN108048245A CN201711414885.XA CN201711414885A CN108048245A CN 108048245 A CN108048245 A CN 108048245A CN 201711414885 A CN201711414885 A CN 201711414885A CN 108048245 A CN108048245 A CN 108048245A
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- Prior art keywords
- sodium
- selects
- surfactant
- acid
- concentrated type
- Prior art date
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- 239000003599 detergent Substances 0.000 title claims abstract description 38
- 239000006260 foam Substances 0.000 title claims abstract description 31
- 239000002904 solvent Substances 0.000 claims description 52
- 239000004094 surface-active agent Substances 0.000 claims description 28
- -1 alkyl dimethyl amine oxide Chemical compound 0.000 claims description 26
- 239000002738 chelating agent Substances 0.000 claims description 26
- 239000003755 preservative agent Substances 0.000 claims description 26
- 230000002335 preservative effect Effects 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 19
- 239000008367 deionised water Substances 0.000 claims description 19
- 229910021641 deionized water Inorganic materials 0.000 claims description 19
- 239000000470 constituent Substances 0.000 claims description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- 125000000217 alkyl group Chemical group 0.000 claims description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 14
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 14
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 14
- 150000002191 fatty alcohols Chemical class 0.000 claims description 14
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 14
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 14
- 229910052708 sodium Inorganic materials 0.000 claims description 14
- 239000011734 sodium Substances 0.000 claims description 14
- 235000015424 sodium Nutrition 0.000 claims description 14
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 13
- 239000002280 amphoteric surfactant Substances 0.000 claims description 13
- 239000003945 anionic surfactant Substances 0.000 claims description 13
- 239000002736 nonionic surfactant Substances 0.000 claims description 13
- 229960003237 betaine Drugs 0.000 claims description 11
- 235000019441 ethanol Nutrition 0.000 claims description 9
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 9
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 9
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 7
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 claims description 7
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 7
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 7
- 239000005711 Benzoic acid Substances 0.000 claims description 7
- 239000004287 Dehydroacetic acid Substances 0.000 claims description 7
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 claims description 7
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 7
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 7
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 7
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims description 7
- 239000004288 Sodium dehydroacetate Substances 0.000 claims description 7
- WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical compound CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 claims description 7
- 235000010233 benzoic acid Nutrition 0.000 claims description 7
- 229960004365 benzoic acid Drugs 0.000 claims description 7
- NSFKBZXCXCJZDQ-UHFFFAOYSA-N cumene;sodium Chemical compound [Na].CC(C)C1=CC=CC=C1 NSFKBZXCXCJZDQ-UHFFFAOYSA-N 0.000 claims description 7
- 235000019258 dehydroacetic acid Nutrition 0.000 claims description 7
- 229940061632 dehydroacetic acid Drugs 0.000 claims description 7
- JEQRBTDTEKWZBW-UHFFFAOYSA-N dehydroacetic acid Chemical compound CC(=O)C1=C(O)OC(C)=CC1=O JEQRBTDTEKWZBW-UHFFFAOYSA-N 0.000 claims description 7
- PGRHXDWITVMQBC-UHFFFAOYSA-N dehydroacetic acid Natural products CC(=O)C1C(=O)OC(C)=CC1=O PGRHXDWITVMQBC-UHFFFAOYSA-N 0.000 claims description 7
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 7
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims description 7
- 235000013922 glutamic acid Nutrition 0.000 claims description 7
- 239000004220 glutamic acid Substances 0.000 claims description 7
- 235000011187 glycerol Nutrition 0.000 claims description 7
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims description 7
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 claims description 7
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 7
- 229960005323 phenoxyethanol Drugs 0.000 claims description 7
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 claims description 7
- 239000004302 potassium sorbate Substances 0.000 claims description 7
- 235000010241 potassium sorbate Nutrition 0.000 claims description 7
- 229940069338 potassium sorbate Drugs 0.000 claims description 7
- 229960004063 propylene glycol Drugs 0.000 claims description 7
- 229960004889 salicylic acid Drugs 0.000 claims description 7
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 7
- 239000004299 sodium benzoate Substances 0.000 claims description 7
- 235000010234 sodium benzoate Nutrition 0.000 claims description 7
- 229960003885 sodium benzoate Drugs 0.000 claims description 7
- 235000019259 sodium dehydroacetate Nutrition 0.000 claims description 7
- 229940079839 sodium dehydroacetate Drugs 0.000 claims description 7
- 229940048842 sodium xylenesulfonate Drugs 0.000 claims description 7
- DSOWAKKSGYUMTF-GZOLSCHFSA-M sodium;(1e)-1-(6-methyl-2,4-dioxopyran-3-ylidene)ethanolate Chemical compound [Na+].C\C([O-])=C1/C(=O)OC(C)=CC1=O DSOWAKKSGYUMTF-GZOLSCHFSA-M 0.000 claims description 7
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 7
- 239000004334 sorbic acid Substances 0.000 claims description 7
- 235000010199 sorbic acid Nutrition 0.000 claims description 7
- 229940075582 sorbic acid Drugs 0.000 claims description 7
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 7
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims description 7
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 claims description 7
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 6
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 6
- LBFQNVUVSTWKGG-UHFFFAOYSA-N chloromethane 4,5-dihydro-1,2-thiazole Chemical compound S1N=CCC1.CCl LBFQNVUVSTWKGG-UHFFFAOYSA-N 0.000 claims description 6
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 claims description 6
- 150000002576 ketones Chemical class 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- 239000001632 sodium acetate Substances 0.000 claims description 6
- 235000017281 sodium acetate Nutrition 0.000 claims description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 6
- 235000011152 sodium sulphate Nutrition 0.000 claims description 6
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 5
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 1
- 235000016068 Berberis vulgaris Nutrition 0.000 claims 1
- 241000335053 Beta vulgaris Species 0.000 claims 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims 1
- 239000003513 alkali Substances 0.000 claims 1
- 239000002585 base Substances 0.000 claims 1
- 229930182478 glucoside Natural products 0.000 claims 1
- 150000008131 glucosides Chemical class 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 7
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 2
- 238000002360 preparation method Methods 0.000 description 14
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- 238000003756 stirring Methods 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 235000019197 fats Nutrition 0.000 description 4
- 235000013305 food Nutrition 0.000 description 4
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- 238000004851 dishwashing Methods 0.000 description 3
- 235000005979 Citrus limon Nutrition 0.000 description 2
- 244000131522 Citrus pyriformis Species 0.000 description 2
- 206010040880 Skin irritation Diseases 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 239000000686 essence Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- PXFBZOLANLWPMH-UHFFFAOYSA-N 16-Epiaffinine Natural products C1C(C2=CC=CC=C2N2)=C2C(=O)CC2C(=CC)CN(C)C1C2CO PXFBZOLANLWPMH-UHFFFAOYSA-N 0.000 description 1
- ZKWJQNCOTNUNMF-QXMHVHEDSA-N 2-[dimethyl-[3-[[(z)-octadec-9-enoyl]amino]propyl]azaniumyl]acetate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O ZKWJQNCOTNUNMF-QXMHVHEDSA-N 0.000 description 1
- FQANRCWINZEGNW-UHFFFAOYSA-N 3-chloro-4-methyl-1,2-thiazole Chemical compound CC1=CSN=C1Cl FQANRCWINZEGNW-UHFFFAOYSA-N 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 240000003183 Manihot esculenta Species 0.000 description 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 125000005257 alkyl acyl group Chemical group 0.000 description 1
- SMWDFEZZVXVKRB-UHFFFAOYSA-N anhydrous quinoline Natural products N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
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- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 235000001727 glucose Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- WGYKZJWCGVVSQN-UHFFFAOYSA-N mono-n-propyl amine Natural products CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/16—Organic compounds
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- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2027—Monohydric alcohols unsaturated
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
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- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
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Abstract
本发明涉及主要以表面活性化合物为基料的洗涤组合物领域，具体为一种天然浓缩型泡沫餐具洗涤剂。一种天然浓缩型泡沫餐具洗涤剂，其特征是：按如下组分混合均匀而成：
Description
技术领域
本发明涉及主要以表面活性化合物为基料的洗涤组合物领域，具体为一种天然浓缩型泡沫餐具洗涤剂。
背景技术
洗洁精作为日常清洁用品，在生活中几乎每天都会使用到。其主要成分为表面活性剂，以去除油污为主要用途。传统餐具洗涤剂外观一般为淡黄色透明液体，粘度一般较高，呈粘稠状，给人一种产品有效成分很高的感觉，但从技术角度分析，洗涤剂产品的粘稠度与产品本身的有效活性物含量并无直接联系，特别是现在的餐具洗涤剂一般都添加无机盐来增加产品稠度，而无机盐的加入对产品的去污力并不会有所提高，粘稠状的洗洁精反而需要更多时间才能让其完全溶解于水中并产生泡沫；而且，目前的餐具洗涤剂较多使用的表面活性剂原料为烷基苯磺酸钠，该原料来源于石油，对皮肤刺激性大。从环保角度来说，随着社会生活水平的提高。消费者越来越倾向于使用节能环保以及天然绿色的产品，对于洗涤剂行业来说浓缩型产品、成分天然来源也成为行业发展的方向。
发明内容
为了克服现有技术的缺陷，提供一种环保性好、去污力高的洗涤剂，本发明公开了一种天然浓缩型泡沫餐具洗涤剂。
本发明通过如下技术方案达到发明目的：
一种天然浓缩型泡沫餐具洗涤剂，其特征是：按如下组分混合均匀而成：
组分 质量百分比浓度(%)
表面活性剂 20～50
增溶剂 0.1～10
溶剂 0.1～10
防腐剂 0.001～1.0
螯合剂 0.001～1.0
香精 0.001～5
去离子水 余量。
其中：表面活性剂选用阴离子表面活性剂、非离子表面活性剂或两性表面活性剂中的至少一种；阴离子表面剂选用十二烷基硫酸钠、脂肪醇聚氧乙烯醚硫酸钠、脂肪醇聚氧乙烯醚羧酸钠、脂肪酸甲酯磺酸钠和磺基琥珀酸酯钠中的至少一种；非离子表面活性剂选用烷基葡萄糖苷、脂肪醇聚氧乙烯醚、烷基二甲基氧化胺和烷基酰胺基丙基氧化胺中的至少一种；两性表面活性剂选用烷基二甲基甜菜碱、椰油酰胺基丙基甜菜碱、烷基羟磺基丙基甜菜碱和烷基两性醋酸钠中的至少一种；
增溶剂选用二甲苯磺酸钠、对甲苯磺酸钠和异丙苯磺酸钠中的至少一种；
溶剂选用乙醇、1,2-丙二醇、1,3-丙二醇和丙三醇中的至少一种；
防腐剂选用山梨酸、山梨酸钾、苯氧乙醇、水杨酸、甲基异噻唑啉酮、甲基氯异噻唑啉酮、尼泊金甲酯、尼泊金丙酯、苯甲醇、苯甲酸、苯甲酸钠、脱氢醋酸和脱氢醋酸钠中的至少一种；
螯合剂选用乙二胺四乙酸二钠、乙二胺四乙酸四钠、谷氨酸二乙酸二钠、亚氨基二琥珀酸四钠和甲基甘氨酸二乙酸三钠中的至少一种；
香精选用食品用柠檬香精或食品用花果香香精。
将上述组分按如下所述制备：
1. 称重：根据要求对各种原料进行检验，按配方比例和生产量称取各种组分备用；
2. 检查设备，确保搅拌容器洁净无菌，将生产所需去离子水全部加入容器中，加入增溶剂、螯合剂、阴离子表面活性剂、非离子表面活性剂和两性表面活性剂中的任选两种，开启搅拌器，转速设置40转/分钟，搅拌30分钟，使各组分充分溶解；
3. 继续搅拌，边搅拌边依次加入其余表面活性剂、防腐剂、香精、溶剂，搅拌20分钟，使各组分充分溶解。
4. 补充生产过程中损失的水分，搅拌10分钟，使各组分充分溶解，静置10分钟，制得天然浓缩型泡沫餐具洗涤剂。
本发明采用天然来源的表面活性剂原料，如棕榈油、椰子油、葡萄糖、甘蔗、木薯等，原料来源更加绿色环保，刺激性更低，对手部肌肤更为温和，可减少洗涤产品对肌肤的刺激性，降低长期使用后皮肤变粗糙的风险。本发明为浓缩型洗涤剂，泡沫丰富、去污力更强劲，在延长购买时间，减少资源浪费、降低运输成本、节约包装材料等方面都完全符合环保的概念。本发明为泡沫型洗涤剂，料液具有极低的粘度以及很好的流动性，粘度<100mpa.s，远小于现有普通餐具洗涤剂1500 mpa.s的粘度，更适合于压泵使用，使用时用压泵将料液以泡沫形式直接泵出，产品在清洗餐具时更为便捷，且生产过程中也不再需要额外添加增稠剂。
本发明通过调整配方配比，克服高表面活性剂含量下产品的凝胶现象，使产品在浓缩条件下仍具有优秀的流动性和极低的粘度，使得浓缩型产品可以通过泡沫泵头直接压出泡沫进行餐具清洗，无需像传统餐具洗涤剂那般先将洗涤剂溶解于水中搅出泡沫后进行洗涤。
本发明具有如下有益效果：使用简单便捷快速，泡沫丰富，去污力强，亲和肌肤不伤手。
具体实施方式
以下通过具体实施例进一步说明本发明。
实施例1
一种天然浓缩型泡沫餐具洗涤剂，按如下组分混合均匀而成：
组分 质量百分比浓度(%)
表面活性剂 20
增溶剂 0.1
溶剂 0.1
防腐剂 0.001
螯合剂 0.001
香精 0.001
去离子水 余量；
其中：表面活性剂依次选用阴离子表面活性剂、非离子表面活性剂和两性表面活性剂；阴离子表面剂依次选用十二烷基硫酸钠、脂肪醇聚氧乙烯醚硫酸钠、脂肪醇聚氧乙烯醚羧酸钠、脂肪酸甲酯磺酸钠和磺基琥珀酸酯钠；非离子表面活性剂依次选用烷基葡萄糖苷、脂肪醇聚氧乙烯醚、烷基二甲基氧化胺和烷基酰胺基丙基氧化胺；两性表面活性剂依次选用烷基二甲基甜菜碱、椰油酰胺基丙基甜菜碱、烷基羟磺基丙基甜菜碱和烷基两性醋酸钠；
增溶剂依次选用二甲苯磺酸钠、对甲苯磺酸钠和异丙苯磺酸钠；
溶剂依次选用乙醇、1,2-丙二醇、1,3-丙二醇和丙三醇；
防腐剂依次选用山梨酸、山梨酸钾、苯氧乙醇、水杨酸、甲基异噻唑啉酮、甲基氯异噻唑啉酮、尼泊金甲酯、尼泊金丙酯、苯甲醇、苯甲酸、苯甲酸钠、脱氢醋酸和脱氢醋酸钠；
螯合剂依次选用乙二胺四乙酸二钠、乙二胺四乙酸四钠、谷氨酸二乙酸二钠、亚氨基二琥珀酸四钠和甲基甘氨酸二乙酸三钠；
香精选用食品用柠檬香精或食品用花果香香精。
将上述组分按如下所述制备：
1. 称重：根据要求对各种原料进行检验，按配方比例和生产量称取各种组分备用；
2. 检查设备，确保搅拌容器洁净无菌，将生产所需去离子水全部加入容器中，加入增溶剂、螯合剂、阴离子表面活性剂、非离子表面活性剂和两性表面活性剂中的任选两种，开启搅拌器，转速设置40转/分钟，搅拌30分钟，使各组分充分溶解；
3. 继续搅拌，边搅拌边依次加入其余表面活性剂、防腐剂、香精、溶剂，搅拌20分钟，使各组分充分溶解。
4. 补充生产过程中损失的水分，搅拌10分钟，使各组分充分溶解，静置10分钟，制得天然浓缩型泡沫餐具洗涤剂。
实施例2
一种天然浓缩型泡沫餐具洗涤剂，按如下组分混合均匀而成：
组分 质量百分比浓度(%)
表面活性剂 23
增溶剂 1.1
溶剂 1.1
防腐剂 0.1
螯合剂 0.1
香精 0.5
去离子水 余量；
组分的选用物质和制备方法都和实施例1同。
实施例3
一种天然浓缩型泡沫餐具洗涤剂，按如下组分混合均匀而成：
组分 质量百分比浓度(%)
表面活性剂 26
增溶剂 2.1
溶剂 2.1
防腐剂 0.2
螯合剂 0.2
香精 1
去离子水 余量；
组分的选用物质和制备方法都和实施例1同。
实施例4
一种天然浓缩型泡沫餐具洗涤剂，按如下组分混合均匀而成：
组分 质量百分比浓度(%)
表面活性剂 29
增溶剂 3.1
溶剂 3.1
防腐剂 0.3
螯合剂 0.3
香精 1.5
去离子水 余量；
组分的选用物质和制备方法都和实施例1同。
实施例5
一种天然浓缩型泡沫餐具洗涤剂，按如下组分混合均匀而成：
组分 质量百分比浓度(%)
表面活性剂 32
增溶剂 4.1
溶剂 4.1
防腐剂 0.4
螯合剂 0.4
香精 2
去离子水 余量；
组分的选用物质和制备方法都和实施例1同。
实施例6
一种天然浓缩型泡沫餐具洗涤剂，按如下组分混合均匀而成：
组分 质量百分比浓度(%)
表面活性剂 35
增溶剂 5.1
溶剂 5.1
防腐剂 0.5
螯合剂 0.5
香精 2.5
去离子水 余量；
组分的选用物质和制备方法都和实施例1同。
实施例7
一种天然浓缩型泡沫餐具洗涤剂，按如下组分混合均匀而成：
组分 质量百分比浓度(%)
表面活性剂 38
增溶剂 6.1
溶剂 6.1
防腐剂 0.6
螯合剂 0.6
香精 3
去离子水 余量；
组分的选用物质和制备方法都和实施例1同。
实施例8
一种天然浓缩型泡沫餐具洗涤剂，按如下组分混合均匀而成：
组分 质量百分比浓度(%)
表面活性剂 41
增溶剂 7.1
溶剂 7.1
防腐剂 0.7
螯合剂 0.7
香精 3.5
去离子水 余量；
组分的选用物质和制备方法都和实施例1同。
实施例9
一种天然浓缩型泡沫餐具洗涤剂，按如下组分混合均匀而成：
组分 质量百分比浓度(%)
表面活性剂 44
增溶剂 8.1
溶剂 8.1
防腐剂 0.8
螯合剂 0.8
香精 4
去离子水 余量；
组分的选用物质和制备方法都和实施例1同。
实施例10
一种天然浓缩型泡沫餐具洗涤剂，按如下组分混合均匀而成：
组分 质量百分比浓度(%)
表面活性剂 47
增溶剂 9.1
溶剂 9.1
防腐剂 0.9
螯合剂 0.9
香精 4.5
去离子水 余量；
组分的选用物质和制备方法都和实施例1同。
实施例11
一种天然浓缩型泡沫餐具洗涤剂，按如下组分混合均匀而成：
组分 质量百分比浓度(%)
表面活性剂 50
增溶剂 10
溶剂 10
防腐剂 1
螯合剂 1
香精 5
去离子水 余量；
组分的选用物质和制备方法都和实施例1同。
实施例12
一种天然浓缩型泡沫餐具洗涤剂，按如下组分混合均匀而成：
组分 质量百分比浓度(%)
表面活性剂 20
增溶剂 0.1
溶剂 0.1
防腐剂 0.001
螯合剂 0.001
香精 0.001
去离子水 余量；
其中：表面活性剂选用阴离子表面活性剂和非离子表面活性剂以质量比为1:1的混合；阴离子表面剂依次选用十二烷基硫酸钠、脂肪醇聚氧乙烯醚硫酸钠、脂肪醇聚氧乙烯醚羧酸钠、脂肪酸甲酯磺酸钠和磺基琥珀酸酯钠；非离子表面活性剂依次选用烷基葡萄糖苷、脂肪醇聚氧乙烯醚、烷基二甲基氧化胺和烷基酰胺基丙基氧化胺；
增溶剂选用二甲苯磺酸钠、对甲苯磺酸钠和异丙苯磺酸钠中的任意两种以质量比为1:1的混合；
溶剂选用乙醇、1,2-丙二醇、1,3-丙二醇和丙三醇中的任意两种以质量比为1:1的混合；
防腐剂选用山梨酸、山梨酸钾、苯氧乙醇、水杨酸、甲基异噻唑啉酮、甲基氯异噻唑啉酮、尼泊金甲酯、尼泊金丙酯、苯甲醇、苯甲酸、苯甲酸钠、脱氢醋酸和脱氢醋酸钠中的任意两种以质量比为1:1的混合；
螯合剂选用乙二胺四乙酸二钠、乙二胺四乙酸四钠、谷氨酸二乙酸二钠、亚氨基二琥珀酸四钠和甲基甘氨酸二乙酸三钠中的任意两种以质量比为1:1的混合。
制备方法和实施例1同。
实施例13
一种天然浓缩型泡沫餐具洗涤剂，按如下组分混合均匀而成：
组分 质量百分比浓度(%)
表面活性剂 29
增溶剂 3.1
溶剂 3.1
防腐剂 0.3
螯合剂 0.3
香精 1.5
去离子水 余量；
其中：表面活性剂选用阴离子表面活性剂和两性表面活性剂以质量比为1:3的混合；阴离子表面剂依次选用十二烷基硫酸钠、脂肪醇聚氧乙烯醚硫酸钠、脂肪醇聚氧乙烯醚羧酸钠、脂肪酸甲酯磺酸钠和磺基琥珀酸酯钠；两性表面活性剂依次选用烷基二甲基甜菜碱、椰油酰胺基丙基甜菜碱、烷基羟磺基丙基甜菜碱和烷基两性醋酸钠；
增溶剂选用二甲苯磺酸钠、对甲苯磺酸钠和异丙苯磺酸钠中的任意两种以质量比为1:3的混合；
溶剂选用乙醇、1,2-丙二醇、1,3-丙二醇和丙三醇中的任意两种以质量比为1:3的混合；
防腐剂选用山梨酸、山梨酸钾、苯氧乙醇、水杨酸、甲基异噻唑啉酮、甲基氯异噻唑啉酮、尼泊金甲酯、尼泊金丙酯、苯甲醇、苯甲酸、苯甲酸钠、脱氢醋酸和脱氢醋酸钠中的任意两种以质量比为1:3的混合；
螯合剂选用乙二胺四乙酸二钠、乙二胺四乙酸四钠、谷氨酸二乙酸二钠、亚氨基二琥珀酸四钠和甲基甘氨酸二乙酸三钠中的任意两种以质量比为1:3的混合。
制备方法和实施例1同。
实施例14
一种天然浓缩型泡沫餐具洗涤剂，按如下组分混合均匀而成：
组分 质量百分比浓度(%)
表面活性剂 38
增溶剂 6.1
溶剂 6.1
防腐剂 0.6
螯合剂 0.6
香精 3
去离子水 余量；
其中：表面活性剂选用非离子表面活性剂和两性表面活性剂以质量比为3:1的混合；非离子表面活性剂依次选用烷基葡萄糖苷、脂肪醇聚氧乙烯醚、烷基二甲基氧化胺和烷基酰胺基丙基氧化胺；两性表面活性剂依次选用烷基二甲基甜菜碱、椰油酰胺基丙基甜菜碱、烷基羟磺基丙基甜菜碱和烷基两性醋酸钠；
增溶剂选用二甲苯磺酸钠、对甲苯磺酸钠和异丙苯磺酸钠中的任意两种以质量比为3:1的混合；
溶剂选用乙醇、1,2-丙二醇、1,3-丙二醇和丙三醇中的任意两种以质量比为3:1的混合；
防腐剂选用山梨酸、山梨酸钾、苯氧乙醇、水杨酸、甲基异噻唑啉酮、甲基氯异噻唑啉酮、尼泊金甲酯、尼泊金丙酯、苯甲醇、苯甲酸、苯甲酸钠、脱氢醋酸和脱氢醋酸钠中的任意两种以质量比为3:1的混合；
螯合剂选用乙二胺四乙酸二钠、乙二胺四乙酸四钠、谷氨酸二乙酸二钠、亚氨基二琥珀酸四钠和甲基甘氨酸二乙酸三钠中的任意两种以质量比为3:1的混合。
制备方法和实施例1同。
实施例15
一种天然浓缩型泡沫餐具洗涤剂，按如下组分混合均匀而成：
组分 质量百分比浓度(%)
表面活性剂 50
增溶剂 10
溶剂 10
防腐剂 1
螯合剂 1
香精 5
去离子水 余量；
其中：表面活性剂选用阴离子表面活性剂、非离子表面活性剂和两性表面活性剂以质量比为1:1:1的混合；阴离子表面剂依次选用十二烷基硫酸钠、脂肪醇聚氧乙烯醚硫酸钠、脂肪醇聚氧乙烯醚羧酸钠、脂肪酸甲酯磺酸钠和磺基琥珀酸酯钠；非离子表面活性剂依次选用烷基葡萄糖苷、脂肪醇聚氧乙烯醚、烷基二甲基氧化胺和烷基酰胺基丙基氧化胺；两性表面活性剂依次选用烷基二甲基甜菜碱、椰油酰胺基丙基甜菜碱、烷基羟磺基丙基甜菜碱和烷基两性醋酸钠；
增溶剂选用二甲苯磺酸钠、对甲苯磺酸钠和异丙苯磺酸钠中的任意两种以质量比为2:5的混合；
溶剂选用乙醇、1,2-丙二醇、1,3-丙二醇和丙三醇中的任意两种以质量比为2:5的混合；
防腐剂选用山梨酸、山梨酸钾、苯氧乙醇、水杨酸、甲基异噻唑啉酮、甲基氯异噻唑啉酮、尼泊金甲酯、尼泊金丙酯、苯甲醇、苯甲酸、苯甲酸钠、脱氢醋酸和脱氢醋酸钠中的任意两种以质量比为2:5的混合；
螯合剂选用乙二胺四乙酸二钠、乙二胺四乙酸四钠、谷氨酸二乙酸二钠、亚氨基二琥珀酸四钠和甲基甘氨酸二乙酸三钠中的任意两种以质量比为2:5的混合。
制备方法和实施例1同。
Claims (1)
1.一种天然浓缩型泡沫餐具洗涤剂，其特征是：按如下组分混合均匀而成：
组分 质量百分比浓度(%)
表面活性剂 20～50
增溶剂 0.1～10
溶剂 0.1～10
防腐剂 0.001～1.0
螯合剂 0.001～1.0
香精 0.001～5
去离子水 余量；
其中：表面活性剂选用阴离子表面活性剂、非离子表面活性剂或两性表面活性剂中的至少一种；阴离子表面剂选用十二烷基硫酸钠、脂肪醇聚氧乙烯醚硫酸钠、脂肪醇聚氧乙烯醚羧酸钠、脂肪酸甲酯磺酸钠和磺基琥珀酸酯钠中的至少一种；非离子表面活性剂选用烷基葡萄糖苷、脂肪醇聚氧乙烯醚、烷基二甲基氧化胺和烷基酰胺基丙基氧化胺中的至少一种；两性表面活性剂选用烷基二甲基甜菜碱、椰油酰胺基丙基甜菜碱、烷基羟磺基丙基甜菜碱和烷基两性醋酸钠中的至少一种；
增溶剂选用二甲苯磺酸钠、对甲苯磺酸钠和异丙苯磺酸钠中的至少一种；
溶剂选用乙醇、1,2-丙二醇、1,3-丙二醇和丙三醇中的至少一种；
防腐剂选用山梨酸、山梨酸钾、苯氧乙醇、水杨酸、甲基异噻唑啉酮、甲基氯异噻唑啉酮、尼泊金甲酯、尼泊金丙酯、苯甲醇、苯甲酸、苯甲酸钠、脱氢醋酸和脱氢醋酸钠中的至少一种；
螯合剂选用乙二胺四乙酸二钠、乙二胺四乙酸四钠、谷氨酸二乙酸二钠、亚氨基二琥珀酸四钠和甲基甘氨酸二乙酸三钠中的至少一种。
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| CN110157554A (zh) * | 2019-04-19 | 2019-08-23 | 上海和黄白猫有限公司 | 一种泡沫型去渍餐具洗涤剂及其制备方法 |
| CN110935393A (zh) * | 2019-12-12 | 2020-03-31 | 陕西速源节能科技有限公司 | 一种环保泡沫制剂及其制备方法 |
| CN111718804A (zh) * | 2020-07-24 | 2020-09-29 | 上海绿瑞生物科技有限公司 | 一种泡沫型清洗剂组合物及其应用 |
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