CN108046433A - A kind of floating stuffing colonization method of Anaerobic wastewater treatment - Google Patents
A kind of floating stuffing colonization method of Anaerobic wastewater treatment Download PDFInfo
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- 238000000034 method Methods 0.000 title claims abstract description 59
- 238000004065 wastewater treatment Methods 0.000 title claims 3
- 239000010802 sludge Substances 0.000 claims abstract description 94
- 239000000945 filler Substances 0.000 claims abstract description 68
- 239000002351 wastewater Substances 0.000 claims abstract description 42
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 103
- 238000005273 aeration Methods 0.000 claims description 19
- 239000012452 mother liquor Substances 0.000 claims description 16
- 238000012856 packing Methods 0.000 claims description 12
- 230000008021 deposition Effects 0.000 claims description 9
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 8
- 235000015097 nutrients Nutrition 0.000 claims description 8
- 235000017281 sodium acetate Nutrition 0.000 claims description 8
- 239000001632 sodium acetate Substances 0.000 claims description 8
- 235000013619 trace mineral Nutrition 0.000 claims description 8
- 239000011573 trace mineral Substances 0.000 claims description 8
- 241000894006 Bacteria Species 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 230000001580 bacterial effect Effects 0.000 claims description 5
- 239000010865 sewage Substances 0.000 claims description 5
- 239000000693 micelle Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- -1 polyethylene Polymers 0.000 claims description 4
- 238000004062 sedimentation Methods 0.000 claims description 4
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 235000013405 beer Nutrition 0.000 claims description 2
- 235000013361 beverage Nutrition 0.000 claims description 2
- 239000003245 coal Substances 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 238000003307 slaughter Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 239000012528 membrane Substances 0.000 abstract description 3
- 238000012546 transfer Methods 0.000 abstract description 2
- 230000000813 microbial effect Effects 0.000 description 4
- 244000005700 microbiome Species 0.000 description 4
- 241001148471 unidentified anaerobic bacterium Species 0.000 description 4
- 238000005086 pumping Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000010842 industrial wastewater Substances 0.000 description 2
- 238000011081 inoculation Methods 0.000 description 2
- 210000004379 membrane Anatomy 0.000 description 2
- 210000004400 mucous membrane Anatomy 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 241000194108 Bacillus licheniformis Species 0.000 description 1
- 241000736131 Sphingomonas Species 0.000 description 1
- 241001148470 aerobic bacillus Species 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- MYSWGUAQZAJSOK-UHFFFAOYSA-N ciprofloxacin Chemical compound C12=CC(N3CCNCC3)=C(F)C=C2C(=O)C(C(=O)O)=CN1C1CC1 MYSWGUAQZAJSOK-UHFFFAOYSA-N 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
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- 230000004060 metabolic process Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 239000010826 pharmaceutical waste Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000010801 sewage sludge Substances 0.000 description 1
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- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/301—Aerobic and anaerobic treatment in the same reactor
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F2003/001—Biological treatment of water, waste water, or sewage using granular carriers or supports for the microorganisms
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/06—Nutrients for stimulating the growth of microorganisms
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Abstract
一种废水厌氧处理的悬浮填料挂膜方法,涉及一种废水厌氧处理的挂膜方法。本发明是要解决现有的厌氧生物膜反应器挂膜困难,启动周期长以及操作较多,不易控制的技术问题。本发明:一、利用好氧污泥对填料做了挂膜处理;二、培养生物膜;三、转入厌氧条件下的填料挂膜;四、连续泵入厌氧工艺进水,培养生物膜。本发明提供了一种快速挂膜的方法,挂膜完成(COD去除率达30%)需要5d~7d,相比传统的排泥挂膜法所需时间缩短2周以上。本发明先利用好氧污泥对填料做了挂膜处理,再转入厌氧条件下的填料挂膜。
The invention relates to a film-hanging method for suspended fillers for anaerobic treatment of wastewater, and relates to a film-hanging method for anaerobic treatment of wastewater. The invention aims to solve the technical problems that the existing anaerobic biofilm reactor is difficult to form a film, has a long start-up period, many operations and is difficult to control. The present invention: 1. Utilize aerobic sludge to carry out film-hanging treatment on the filler; 2. Cultivate biofilm; 3. Transform the filler into film-hanging under anaerobic conditions; membrane. The present invention provides a method for rapid film formation, and it takes 5 days to 7 days to complete the film formation (COD removal rate reaches 30%), which is more than 2 weeks shorter than the time required by the traditional sludge discharge and film formation method. In the present invention, the aerobic sludge is used to carry out film-forming treatment on the filler, and then transfer to the film-forming of the filler under anaerobic conditions.
Description
技术领域technical field
本发明涉及一种废水厌氧处理的挂膜方法。The invention relates to a membrane-hanging method for anaerobic treatment of wastewater.
背景技术Background technique
厌氧水处理技术主要分为厌氧活性污泥法和厌氧生物膜法两类。厌氧水处理的生物膜法主要是利用生物膜在固液两相的传质作用下与废水接触,通过自身的新陈代谢降解有机污染物,达到净化水质的目的。以此为原理,发展出了多种厌氧生物膜反应器,具有处理效率高,适应能力强,耐冲击负荷等优点,一般可分为厌氧生物滤池、厌氧流化床、厌氧生物膜膨胀床等。生物膜是微生物细胞附着在载体表面生长和繁殖形成的,主要由微生物和其产生的胞外多聚物,以及被吸附和镶嵌于内的溶质和无机颗粒所组成。由于厌氧菌增殖慢,厌氧生物膜反应器普遍存在挂膜困难,启动周期长的情况,制约了其在工业废水和生活污水处理领域的应用。Anaerobic water treatment technology is mainly divided into anaerobic activated sludge method and anaerobic biofilm method. The biofilm method of anaerobic water treatment mainly uses biofilm to contact wastewater under the action of solid-liquid two-phase mass transfer, and degrades organic pollutants through its own metabolism to achieve the purpose of purifying water quality. Based on this principle, a variety of anaerobic biofilm reactors have been developed, which have the advantages of high processing efficiency, strong adaptability, and impact load resistance. They can generally be divided into anaerobic biofilters, anaerobic fluidized beds, anaerobic Biofilm expanded bed, etc. Biofilm is formed by the growth and reproduction of microbial cells attached to the surface of the carrier. It is mainly composed of microorganisms and their extracellular polymers, as well as solutes and inorganic particles that are adsorbed and embedded in them. Due to the slow growth of anaerobic bacteria, it is generally difficult for anaerobic biofilm reactors to form a film, and the start-up period is long, which restricts its application in the field of industrial wastewater and domestic sewage treatment.
中国发明专利《生物接触氧化池中填料的挂膜方法》(专利号ZL200710061583.9),通过污泥循环、曝气和悬浮微生物排放,增加填料上的微生物量,通过控制有机负荷来培养生物膜。该方法适用于悬浮填料好氧挂膜过程。Chinese invention patent "Film Hanging Method for Filling in Biological Contact Oxidation Tank" (Patent No. ZL200710061583.9), through sludge circulation, aeration and suspended microorganism discharge, increase the microbial load on the filler, and cultivate biofilm by controlling the organic load . This method is suitable for the aerobic film-hanging process of suspended fillers.
中国发明专利《一种移动床生物膜反应器中载体填料的挂膜方法》(公开号05565480A)通过对移动床生物膜反应器同时进行排水和补充离交废水,进行动态培养,并回流活性污泥,该方法需要监控污泥浓度,操作不便。该方法适用于悬浮填料好氧挂膜过程。Chinese invention patent "A method of film-hanging carrier filler in moving bed biofilm reactor" (publication number 05565480A) through the moving bed biofilm reactor simultaneously draining water and supplementing the separated waste water, performing dynamic culture, and refluxing the active sewage Sludge, this method needs to monitor the sludge concentration, which is inconvenient to operate. This method is suitable for the aerobic film-hanging process of suspended fillers.
中国发明专利《一种废水生物膜快速挂膜装置及方法》(公开号106430560A)通过在填料上固定红色鞘氨醇单胞菌以加快挂膜,但该方法所固定的菌株在反应器中的适应性受到诸多因素的影响,不易控制。The Chinese invention patent "A Device and Method for Rapid Biofilm Forming of Wastewater" (publication number 106430560A) speeds up film formation by fixing Sphingomonas rubrum on the filler. Adaptability is affected by many factors and is not easy to control.
中国发明专利《一种培养用于抗生素废水厌氧处理的生物膜的方法》(公开号CN105948242A)制备地衣芽胞杆菌微生物菌剂,填料挂膜处理,和厌氧反应器的生物膜培养三个步骤培养组合填料上的生物膜。该方法需预先制备相应生物菌剂,且需要另设装置对填料预处理,操作较多,运行管理不便。Chinese invention patent "A Method for Cultivating Biofilm for Anaerobic Treatment of Antibiotic Wastewater" (publication number CN105948242A) prepares Bacillus licheniformis microbial agent, filler film-hanging treatment, and anaerobic reactor biofilm cultivation in three steps Cultivation of biofilms on combined media. This method needs to prepare the corresponding biological bacteria agent in advance, and needs to set up another device to pretreat the filler, which requires many operations and is inconvenient for operation and management.
发明内容Contents of the invention
本发明是要解决现有的厌氧生物膜反应器挂膜困难,启动周期长以及操作较多,不易控制的技术问题,而提供一种废水厌氧处理的悬浮填料挂膜方法。The present invention aims to solve the technical problems of the existing anaerobic biofilm reactors, such as difficulty in film formation, long start-up period, many operations and difficult control, and provides a film formation method for suspended fillers for anaerobic treatment of wastewater.
本发明的一种废水厌氧处理的悬浮填料挂膜方法是按以下步骤进行的:A kind of suspended filler film hanging method of wastewater anaerobic treatment of the present invention is carried out according to the following steps:
一、将好氧污泥接种于生物膜反应器中:将悬浮填料放入生物膜反应器中,用进料泵将好氧污泥通过布置在生物膜反应器内部上方的布水器泵入生物膜反应器中,然后启动循环泵将好氧污泥通过布置在生物膜反应器内部上方的布水器泵入生物膜反应器中循环淋洗悬浮填料6h,然后将好氧污泥排空;所述的悬浮填料的填充率为生物膜反应器容积的30%-80%;所述的好氧污泥的投加量为生物膜反应器容积的1/8~1/3;所述的好氧污泥为城市污水厂二沉池底泥经间歇曝气培养的好氧污泥;1. Inoculate the aerobic sludge into the biofilm reactor: put the suspended filler into the biofilm reactor, and use the feed pump to pump the aerobic sludge through the water distributor arranged above the interior of the biofilm reactor In the biofilm reactor, then start the circulating pump to pump the aerobic sludge into the biofilm reactor through the water distributor arranged above the interior of the biofilm reactor to circulate and wash the suspended filler for 6 hours, and then empty the aerobic sludge The filling rate of the suspended filler is 30%-80% of the volume of the biofilm reactor; the dosage of the aerobic sludge is 1/8 to 1/3 of the volume of the biofilm reactor; The aerobic sludge is the aerobic sludge cultivated by intermittent aeration of the bottom sludge of the secondary sedimentation tank of the urban sewage plant;
二、培养生物膜:用进料泵向生物膜反应器中连续泵入合成废水,在溶解氧浓度为3mg/L~6mg/L的条件下曝气运行至填料表面生长出生物膜;2. Cultivate biofilm: use the feed pump to continuously pump synthetic wastewater into the biofilm reactor, aerate and run under the condition of dissolved oxygen concentration of 3mg/L-6mg/L until the biofilm grows on the surface of the filler;
确定填料表面生长出生物膜的方法为:填料表面在显微镜检下能观察到菌胶团、丝状菌和钟虫,且出水的COD去除率为50%~70%;The method to determine the growth of biofilm on the surface of the filler is as follows: the surface of the filler can be observed under a microscope to observe bacterial micelles, filamentous bacteria and bell worms, and the COD removal rate of the effluent is 50% to 70%;
所述的合成废水是由是由营养元素母液和微量元素母液组成;营养元素母液是由乙酸钠、NH4Cl、KH2PO4、CaCl2·H2O、MgSO4·7H2O和水组成;微量元素母液是由MnCl2·4H2O、FeCl2·4H2O、ZnSO4·7H2O、CoCl2·6H2O、NiCl·6H2O和水组成;The synthetic wastewater is composed of nutrient element mother liquor and trace element mother liquor; the nutrient element mother liquor is composed of sodium acetate, NH 4 Cl, KH 2 PO 4 , CaCl 2 ·H 2 O, MgSO 4 ·7H 2 O and water composition; trace element mother liquor is composed of MnCl 2 4H 2 O, FeCl 2 4H 2 O, ZnSO 4 7H 2 O, CoCl 2 6H 2 O, NiCl 6H 2 O and water;
所述的合成废水中各成分的浓度如下:乙酸钠为250mg/L、NH4Cl为40mg/L、KH2PO4为10mg/L、CaCl2·H2O为20mg/L、MgSO4·7H2O为25mg/L、MnCl2·4H2O为0.075mg/L、FeCl2·4H2O为1mg/L、ZnSO4·7H2O为0.075mg/L、CoCl2·6H2O为0.1mg/L、NiCl·6H2O为0.25mg/L;The concentration of each component in the synthetic wastewater is as follows: sodium acetate is 250 mg/L, NH 4 Cl is 40 mg/L, KH 2 PO 4 is 10 mg/L, CaCl 2 ·H 2 O is 20 mg/L, MgSO 4 · 7H 2 O is 25 mg/L, MnCl 2 4H 2 O is 0.075 mg/L, FeCl 2 4H 2 O is 1 mg/L, ZnSO 4 7H 2 O is 0.075 mg/L, CoCl 2 6H 2 O is 0.1mg/L, NiCl·6H 2 O is 0.25mg/L;
三、将厌氧污泥接种于生物膜反应器中:用进料泵将厌氧污泥通过布置在生物膜反应器内部上方的布水器泵入生物膜反应器中,然后启动循环泵将厌氧污泥通过布置在生物膜反应器内部上方的布水器泵入生物膜反应器中循环淋洗悬浮填料24h,然后将厌氧污泥排空;所述的厌氧污泥的投加量为生物膜反应器容积的1/8~1/3;所述的厌氧污泥为污泥浓缩池的底泥或水厂厌氧反应器内的絮状污泥;3. Inoculate the anaerobic sludge into the biofilm reactor: use the feed pump to pump the anaerobic sludge into the biofilm reactor through the water distributor arranged above the interior of the biofilm reactor, and then start the circulation pump to The anaerobic sludge is pumped into the biofilm reactor through the water distributor arranged above the interior of the biofilm reactor to circulate and wash the suspended filler for 24 hours, and then the anaerobic sludge is emptied; the addition of the anaerobic sludge The amount is 1/8-1/3 of the volume of the biofilm reactor; the anaerobic sludge is the bottom sludge of the sludge concentration tank or the flocculent sludge in the anaerobic reactor of the water plant;
四、连续泵入厌氧工艺进水:在容积负荷为0.5kg/m3·d~1kg/m3·d的条件下用进料泵向生物膜反应器中连续泵入厌氧工艺进水至出水的COD去除率达到30%,挂膜完成。4. Continuous pumping of anaerobic process feed water: under the condition of a volume load of 0.5kg/m 3 ·d~1kg/m 3 ·d, use a feed pump to continuously pump anaerobic process feed water into the biofilm reactor Until the COD removal rate of the effluent reaches 30%, the film formation is completed.
填料挂膜的过程是一个微生物在填料上附着并生长的过程,由于厌氧菌生长繁殖很慢,造成直接使用传统的方法时(比如排泥挂膜法),挂膜完成的用时很长。本发明先使用好氧污泥接种,填料表面生长出好氧条件下的生物膜,这时再转入厌氧条件,以好氧条件下快速产生的生物膜为基础,使厌氧菌群能够在填料表面更容易附着和生长。The process of film-hanging on the filler is a process in which microorganisms attach and grow on the filler. Due to the slow growth and reproduction of anaerobic bacteria, it takes a long time to complete the film-hanging when using traditional methods (such as the sludge-draining film-hanging method). The present invention first uses aerobic sludge to inoculate, and biofilm under aerobic conditions grows on the surface of the filler, and then changes to anaerobic conditions, based on the biofilm rapidly produced under aerobic conditions, so that the anaerobic flora can It is easier to attach and grow on the filler surface.
本发明原理在于好氧菌与部分兼性厌氧菌增殖迅速,其产生的胞外多聚物有利于生成膜结构;好氧条件下微生物生长繁殖形成的胶质粘膜,有效改善了载体表面特性,有利于厌氧生物膜的附着和生长,最终实现厌氧条件下生物膜的形成。The principle of the invention is that aerobic bacteria and some facultative anaerobic bacteria proliferate rapidly, and the extracellular polymers produced by them are conducive to the formation of membrane structures; the colloidal mucous membrane formed by the growth and reproduction of microorganisms under aerobic conditions effectively improves the surface characteristics of the carrier , is conducive to the attachment and growth of anaerobic biofilm, and finally realizes the formation of biofilm under anaerobic conditions.
挂膜是生物膜反应器启动最开始的一个阶段,本发明提供了一种快速挂膜的方法,挂膜完成(COD去除率达30%)需要5d~7d,相比传统的排泥挂膜法所需时间缩短2周以上。Film-hanging is the initial stage of biofilm reactor start-up. The present invention provides a method for rapid film-hanging. It takes 5-7 days to complete film-hanging (COD removal rate reaches 30%). The time required for the method was shortened by more than 2 weeks.
与现有技术相比,本发明具有如下显著效果:Compared with prior art, the present invention has following remarkable effect:
(1)本发明采用厌氧污泥间歇曝气培养的好氧污泥接种,利用厌氧消化微生物种群中的兼性厌氧的菌种进行好氧挂膜,改善载体表面特性,有利于厌氧菌的附着与生长;(1) The present invention adopts the aerobic sludge inoculation of anaerobic sludge intermittent aeration culture, utilizes the facultative anaerobic bacterial classification in the anaerobic digestion microbial population to carry out aerobic film-hanging, improves carrier surface characteristic, is conducive to anaerobic Attachment and growth of oxygen bacteria;
(2)本发明结合利用了厌氧生物膜工艺下厌氧反应器的结构,在同一反应器中完成整个挂膜过程,悬浮填料挂膜阶段所需的动力设备不存在冗余,运行管理方便,实用性强;(2) The present invention combines and utilizes the structure of the anaerobic reactor under the anaerobic biofilm process, and completes the whole film-forming process in the same reactor, and the power equipment required for the suspended filler film-forming stage does not have redundancy, and the operation and management are convenient , strong practicability;
(3)本发明中污泥接种时采用循环泵送污泥,污泥从上部淋洗填料的方式,只需少量的接种污泥,且与常规挂膜方法相比挂膜速度快,有效缩短反应器启动时间。(3) In the present invention, when the sludge is inoculated, the sludge is circulated and pumped, and the sludge is rinsed from the upper part of the filler. Only a small amount of inoculation sludge is needed, and compared with the conventional film-forming method, the film-forming speed is fast, which effectively shortens the time. Reactor startup time.
附图说明Description of drawings
图1为具体实施方式二中生物膜反应器的示意图。Fig. 1 is a schematic diagram of the biofilm reactor in Embodiment 2.
具体实施方式Detailed ways
具体实施方式一:本实施方式为一种废水厌氧处理的悬浮填料挂膜方法是按以下步骤进行的:Specific implementation mode one: this implementation mode is a kind of suspended filler membrane-hanging method of wastewater anaerobic treatment is carried out according to the following steps:
一、将好氧污泥接种于生物膜反应器中:将悬浮填料放入生物膜反应器中,用进料泵将好氧污泥通过布置在生物膜反应器内部上方的布水器泵入生物膜反应器中,然后启动循环泵将好氧污泥通过布置在生物膜反应器内部上方的布水器泵入生物膜反应器中循环淋洗悬浮填料6h,然后将好氧污泥排空;所述的悬浮填料的填充率为生物膜反应器容积的30%-80%;所述的好氧污泥的投加量为生物膜反应器容积的1/8~1/3;所述的好氧污泥为城市污水厂二沉池底泥经间歇曝气培养的好氧污泥;1. Inoculate the aerobic sludge into the biofilm reactor: put the suspended filler into the biofilm reactor, and use the feed pump to pump the aerobic sludge through the water distributor arranged above the interior of the biofilm reactor In the biofilm reactor, then start the circulating pump to pump the aerobic sludge into the biofilm reactor through the water distributor arranged above the interior of the biofilm reactor to circulate and wash the suspended filler for 6 hours, and then empty the aerobic sludge The filling rate of the suspended filler is 30%-80% of the volume of the biofilm reactor; the dosage of the aerobic sludge is 1/8 to 1/3 of the volume of the biofilm reactor; The aerobic sludge is the aerobic sludge cultivated by intermittent aeration of the bottom sludge of the secondary sedimentation tank of the urban sewage plant;
这步使用的是厌氧污泥间歇曝气得到的好氧污泥,这部分污泥有大量兼性厌氧菌的存在,能够较好的适应后续的厌氧条件。This step uses aerobic sludge obtained by intermittent aeration of anaerobic sludge. This part of sludge has a large number of facultative anaerobic bacteria and can better adapt to subsequent anaerobic conditions.
这步只要求挂膜到一定阶段,填料表面生成了胶质黏膜即可,因此这步用时很短,但能够缩短厌氧挂膜所需的时间。This step only requires that the film hangs to a certain stage, and the colloidal mucous membrane is formed on the surface of the filler. Therefore, this step takes a short time, but it can shorten the time required for anaerobic film hanging.
二、培养生物膜:用进料泵向生物膜反应器中连续泵入合成废水,在溶解氧浓度为3mg/L~6mg/L的条件下曝气运行至填料表面生长出生物膜;2. Cultivate biofilm: use the feed pump to continuously pump synthetic wastewater into the biofilm reactor, aerate and run under the condition of dissolved oxygen concentration of 3mg/L-6mg/L until the biofilm grows on the surface of the filler;
确定填料表面生长出生物膜的方法为:填料表面在显微镜检下能观察到菌胶团、丝状菌和钟虫,且出水的COD去除率为50%~70%;The method to determine the growth of biofilm on the surface of the filler is as follows: the surface of the filler can be observed under a microscope to observe bacterial micelles, filamentous bacteria and bell worms, and the COD removal rate of the effluent is 50% to 70%;
所述的合成废水是由是由营养元素母液和微量元素母液组成;营养元素母液是由乙酸钠、NH4Cl、KH2PO4、CaCl2·H2O、MgSO4·7H2O和水组成;微量元素母液是由MnCl2·4H2O、FeCl2·4H2O、ZnSO4·7H2O、CoCl2·6H2O、NiCl·6H2O和水组成;The synthetic wastewater is composed of nutrient element mother liquor and trace element mother liquor; the nutrient element mother liquor is composed of sodium acetate, NH 4 Cl, KH 2 PO 4 , CaCl 2 ·H 2 O, MgSO 4 ·7H 2 O and water composition; trace element mother liquor is composed of MnCl 2 4H 2 O, FeCl 2 4H 2 O, ZnSO 4 7H 2 O, CoCl 2 6H 2 O, NiCl 6H 2 O and water;
所述的合成废水中各成分的浓度如下:乙酸钠为250mg/L、NH4Cl为40mg/L、KH2PO4为10mg/L、CaCl2·H2O为20mg/L、MgSO4·7H2O为25mg/L、MnCl2·4H2O为0.075mg/L、FeCl2·4H2O为1mg/L、ZnSO4·7H2O为0.075mg/L、CoCl2·6H2O为0.1mg/L、NiCl·6H2O为0.25mg/L;The concentration of each component in the synthetic wastewater is as follows: sodium acetate is 250 mg/L, NH 4 Cl is 40 mg/L, KH 2 PO 4 is 10 mg/L, CaCl 2 ·H 2 O is 20 mg/L, MgSO 4 · 7H 2 O is 25 mg/L, MnCl 2 4H 2 O is 0.075 mg/L, FeCl 2 4H 2 O is 1 mg/L, ZnSO 4 7H 2 O is 0.075 mg/L, CoCl 2 6H 2 O is 0.1mg/L, NiCl·6H 2 O is 0.25mg/L;
三、将厌氧污泥接种于生物膜反应器中:用进料泵将厌氧污泥通过布置在生物膜反应器内部上方的布水器泵入生物膜反应器中,然后启动循环泵将厌氧污泥通过布置在生物膜反应器内部上方的布水器泵入生物膜反应器中循环淋洗悬浮填料24h,然后将厌氧污泥排空;所述的厌氧污泥的投加量为生物膜反应器容积的1/8~1/3;所述的厌氧污泥为污泥浓缩池的底泥或水厂厌氧反应器内的絮状污泥;3. Inoculate the anaerobic sludge into the biofilm reactor: use the feed pump to pump the anaerobic sludge into the biofilm reactor through the water distributor arranged above the interior of the biofilm reactor, and then start the circulation pump to The anaerobic sludge is pumped into the biofilm reactor through the water distributor arranged above the interior of the biofilm reactor to circulate and wash the suspended filler for 24 hours, and then the anaerobic sludge is emptied; the addition of the anaerobic sludge The amount is 1/8-1/3 of the volume of the biofilm reactor; the anaerobic sludge is the bottom sludge of the sludge concentration tank or the flocculent sludge in the anaerobic reactor of the water plant;
四、连续泵入厌氧工艺进水:在容积负荷为0.5kg/m3·d~1kg/m3·d的条件下用进料泵向生物膜反应器中连续泵入厌氧工艺进水至出水的COD去除率达到30%,挂膜完成。4. Continuous pumping of anaerobic process feed water: under the condition of a volume load of 0.5kg/m 3 ·d~1kg/m 3 ·d, use a feed pump to continuously pump anaerobic process feed water into the biofilm reactor Until the COD removal rate of the effluent reaches 30%, the film formation is completed.
具体实施方式二:本实施方式与具体实施方式一不同的是:如图1所示,所述的生物膜反应器是由反应器本体(1)、布水器(8)、进料泵(9)、循环泵(10)、出水管(11)、曝气管(15)和空气源(16)组成;Specific embodiment two: the difference between this embodiment and specific embodiment one is: as shown in Figure 1, the described biofilm reactor is composed of a reactor body (1), a water distributor (8), a feed pump ( 9), circulation pump (10), outlet pipe (11), aeration pipe (15) and air source (16);
在反应器本体(1)的内部从上至下分别为布水区(3)、悬浮填料区(4)、出水区(5)和污泥沉积区(6);Inside the reactor body (1) from top to bottom are the water distribution area (3), the suspended packing area (4), the water outlet area (5) and the sludge deposition area (6);
在反应器本体(1)的顶部设置进水口(7)和出气口(2),曝气管(15)通过反应器本体(1)的顶部进入到反应器本体(1)中至悬浮填料区(4)的底部,且曝气管(15)与反应器本体(1)密封,空气源(16)的出气口与曝气管(15)的进气口连通;Water inlet (7) and air outlet (2) are set on the top of the reactor body (1), and the aeration pipe (15) enters the reactor body (1) to the suspended packing area through the top of the reactor body (1) (4), and the aeration pipe (15) is sealed with the reactor body (1), and the air outlet of the air source (16) is communicated with the air inlet of the aeration pipe (15);
在布水区(3)中设置布水器(8),布水器(8)的进水端与进水口(7)的出水端连通;A water distributor (8) is arranged in the water distribution area (3), and the water inlet end of the water distributor (8) communicates with the water outlet end of the water inlet (7);
悬浮填料区(4)装有悬浮填料;The suspended packing area (4) is equipped with suspended packing;
在反应器本体(1)位于出水区(5)的侧壁上分别设置有出水口(13)和回流口(12);出水口(13)与出水管(11)连通,出水管末端(11-1)的高度高于出水口(13)且低于进水口(7)的高度;回流口(12)与循环泵(10)的进料口连通,进水口(7)的进水端分别与循环泵(10)的出料口和进料泵(9)的出料口连通;A water outlet (13) and a return port (12) are respectively arranged on the side wall of the reactor body (1) located at the water outlet area (5); the water outlet (13) communicates with the water outlet pipe (11), and the water outlet pipe end (11 -1) is higher than the height of the water outlet (13) and lower than the height of the water inlet (7); It is communicated with the discharge port of circulation pump (10) and the discharge port of feed pump (9);
污泥沉积区(6)呈向下收缩的锥形,污泥沉淀区(6)的底部设有排泥口(14)。The sludge deposition area (6) is in the shape of a downward contracting cone, and a sludge discharge outlet (14) is provided at the bottom of the sludge deposition area (6).
所述的生物膜反应器为应用于市政污水、工业废水、微污染水源水等污废水处理的连续流生物膜法处理单元,其类型为厌氧。其他与具体实施方式一相同。The biofilm reactor is a continuous flow biofilm treatment unit applied to the treatment of municipal sewage, industrial wastewater, slightly polluted source water, etc., and its type is anaerobic. Others are the same as the first embodiment.
具体实施方式三:本实施方式与具体实施方式一或二不同的是:步骤一中所述的悬浮填料的密度小于或等于水的密度。其他与具体实施方式一或二相同。Embodiment 3: The difference between this embodiment and Embodiment 1 or 2 is that the density of the suspended filler in step 1 is less than or equal to the density of water. Others are the same as those in Embodiment 1 or 2.
具体实施方式四:本实施方式与具体实施方式一不同的是:步骤一中所述的悬浮填料为聚乙烯、聚丙烯或聚氨酯。其他与具体实施方式三相同。Embodiment 4: This embodiment is different from Embodiment 1 in that the suspended filler in step 1 is polyethylene, polypropylene or polyurethane. Others are the same as in the third embodiment.
具体实施方式五:本实施方式与具体实施方式四不同的是:步骤一中所述的悬浮填料为圆柱体、球状体或海绵网状。其他与具体实施方式三相同。Embodiment 5: This embodiment is different from Embodiment 4 in that the suspension filler described in step 1 is a cylinder, a sphere or a sponge net. Others are the same as in the third embodiment.
具体实施方式六:本实施方式与具体实施方式一不同的是:步骤四中所述的厌氧工艺进水为饮料废水、啤酒废水、甲醇废水、屠宰废水、制药废水或煤化工废水,具体选择与步骤三的厌氧污泥来源相同的水厂。其他与具体实施方式一相同。Embodiment 6: The difference between this embodiment and Embodiment 1 is that the influent of the anaerobic process described in step 4 is beverage waste water, beer waste water, methanol waste water, slaughter waste water, pharmaceutical waste water or coal chemical industry waste water, and the specific selection The same water plant as the source of the anaerobic sludge in step 3. Others are the same as the first embodiment.
具体实施方式七:本实施方式与具体实施方式一不同的是:步骤四中控制生物膜反应器中的水温为35℃。其他与具体实施方式一相同。Embodiment 7: This embodiment is different from Embodiment 1 in that: in step 4, the water temperature in the biofilm reactor is controlled to 35°C. Others are the same as the first embodiment.
具体实施方式八:本实施方式与具体实施方式一不同的是:步骤四中控制生物膜反应器中的水温为18℃~22℃。其他与具体实施方式一相同。Embodiment 8: This embodiment is different from Embodiment 1 in that: in step 4, the water temperature in the biofilm reactor is controlled to be 18°C to 22°C. Others are the same as the first embodiment.
具体实施方式九:本实施方式与具体实施方式一不同的是:步骤四中控制生物膜反应器中的水温为55℃。其他与具体实施方式一相同。Embodiment 9: This embodiment is different from Embodiment 1 in that: in step 4, the water temperature in the biofilm reactor is controlled to 55°C. Others are the same as the first embodiment.
用以下试验对本发明进行验证:The present invention is verified with following test:
试验一:本试验为一种废水厌氧处理的悬浮填料挂膜方法是按以下步骤进行的:Test 1: This test is a suspended filler film-hanging method for anaerobic treatment of wastewater, which is carried out according to the following steps:
一、将好氧污泥接种于生物膜反应器中:将悬浮填料放入生物膜反应器中,用进料泵将好氧污泥通过布置在生物膜反应器内部上方的布水器泵入生物膜反应器中,然后启动循环泵将好氧污泥通过布置在生物膜反应器内部上方的布水器泵入生物膜反应器中循环淋洗悬浮填料6h,然后将好氧污泥排空;所述的悬浮填料的填充率为生物膜反应器容积的50%;所述的好氧污泥的投加量为生物膜反应器容积的1/4;所述的好氧污泥为二沉池底泥经间歇曝气培养的好氧污泥;1. Inoculate the aerobic sludge into the biofilm reactor: put the suspended filler into the biofilm reactor, and use the feed pump to pump the aerobic sludge through the water distributor arranged above the interior of the biofilm reactor In the biofilm reactor, then start the circulating pump to pump the aerobic sludge into the biofilm reactor through the water distributor arranged above the interior of the biofilm reactor to circulate and wash the suspended filler for 6 hours, and then empty the aerobic sludge The filling rate of the suspended filler is 50% of the volume of the biofilm reactor; the dosage of the aerobic sludge is 1/4 of the volume of the biofilm reactor; the amount of the aerobic sludge is two The aerobic sludge cultivated by intermittent aeration of sedimentation tank bottom sludge;
二、培养生物膜:用进料泵向生物膜反应器中连续泵入合成废水,在溶解氧浓度为3mg/L的条件下曝气运行至填料表面生长出生物膜;2. Cultivate biofilm: use a feed pump to continuously pump synthetic wastewater into the biofilm reactor, aerate and run under the condition of a dissolved oxygen concentration of 3mg/L until the biofilm grows on the surface of the filler;
确定填料表面生长出生物膜的方法为:填料表面在显微镜检下能观察到菌胶团、丝状菌和钟虫,且出水的COD去除率为70%;The method to determine the growth of biofilm on the surface of the filler is as follows: the surface of the filler can be observed under a microscope to observe bacterial micelles, filamentous bacteria and bell worms, and the COD removal rate of the effluent is 70%;
所述的合成废水是由是由营养元素母液和微量元素母液组成;营养元素母液是由乙酸钠、NH4Cl、KH2PO4、CaCl2·H2O、MgSO4·7H2O和水组成;微量元素母液是由MnCl2·4H2O、FeCl2·4H2O、ZnSO4·7H2O、CoCl2·6H2O、NiCl·6H2O和水组成;The synthetic wastewater is composed of nutrient element mother liquor and trace element mother liquor; the nutrient element mother liquor is composed of sodium acetate, NH 4 Cl, KH 2 PO 4 , CaCl 2 ·H 2 O, MgSO 4 ·7H 2 O and water composition; trace element mother liquor is composed of MnCl 2 4H 2 O, FeCl 2 4H 2 O, ZnSO 4 7H 2 O, CoCl 2 6H 2 O, NiCl 6H 2 O and water;
所述的合成废水中各成分的浓度如下:乙酸钠为250mg/L、NH4Cl为40mg/L、KH2PO4为10mg/L、CaCl2·H2O为20mg/L、MgSO4·7H2O为25mg/L、MnCl2·4H2O为0.075mg/L、FeCl2·4H2O为1mg/L、ZnSO4·7H2O为0.075mg/L、CoCl2·6H2O为0.1mg/L、NiCl·6H2O为0.25mg/L;The concentration of each component in the synthetic wastewater is as follows: sodium acetate is 250 mg/L, NH 4 Cl is 40 mg/L, KH 2 PO 4 is 10 mg/L, CaCl 2 ·H 2 O is 20 mg/L, MgSO 4 · 7H 2 O is 25 mg/L, MnCl 2 4H 2 O is 0.075 mg/L, FeCl 2 4H 2 O is 1 mg/L, ZnSO 4 7H 2 O is 0.075 mg/L, CoCl 2 6H 2 O is 0.1mg/L, NiCl·6H 2 O is 0.25mg/L;
三、将厌氧污泥接种于生物膜反应器中:用进料泵将厌氧污泥通过布置在生物膜反应器内部上方的布水器泵入生物膜反应器中,然后启动循环泵将厌氧污泥通过布置在生物膜反应器内部上方的布水器泵入生物膜反应器中循环淋洗悬浮填料24h,然后将厌氧污泥排空;所述的厌氧污泥的投加量为生物膜反应器容积的1/4;3. Inoculate the anaerobic sludge into the biofilm reactor: use the feed pump to pump the anaerobic sludge into the biofilm reactor through the water distributor arranged above the interior of the biofilm reactor, and then start the circulation pump to The anaerobic sludge is pumped into the biofilm reactor through the water distributor arranged above the interior of the biofilm reactor to circulate and wash the suspended filler for 24 hours, and then the anaerobic sludge is emptied; the addition of the anaerobic sludge The volume is 1/4 of the biofilm reactor volume;
四、连续泵入厌氧工艺进水:在容积负荷为0.5kg/m3·d~1kg/m3·d的条件下用进料泵向生物膜反应器中连续泵入厌氧工艺进水至出水的COD去除率达到30%,挂膜完成。4. Continuous pumping of anaerobic process feed water: under the condition of a volume load of 0.5kg/m 3 ·d~1kg/m 3 ·d, use a feed pump to continuously pump anaerobic process feed water into the biofilm reactor Until the COD removal rate of the effluent reaches 30%, the film formation is completed.
如图1所示,所述的生物膜反应器是由反应器本体(1)、布水器(8)、进料泵(9)、循环泵(10)、出水管(11)、曝气管(15)和空气源(16)组成;As shown in Figure 1, the described biofilm reactor is composed of a reactor body (1), a water distributor (8), a feed pump (9), a circulation pump (10), an outlet pipe (11), an aeration Tube (15) and air source (16);
在反应器本体(1)的内部从上至下分别为布水区(3)、悬浮填料区(4)、出水区(5)和污泥沉积区(6);Inside the reactor body (1) from top to bottom are the water distribution area (3), the suspended packing area (4), the water outlet area (5) and the sludge deposition area (6);
在反应器本体(1)的顶部设置进水口(7)和出气口(2),曝气管(15)通过反应器本体(1)的顶部进入到反应器本体(1)中至悬浮填料区(4)的底部,且曝气管(15)与反应器本体(1)密封,空气源(16)的出气口与曝气管(15)的进气口连通;Water inlet (7) and air outlet (2) are set on the top of the reactor body (1), and the aeration pipe (15) enters the reactor body (1) to the suspended packing area through the top of the reactor body (1) (4), and the aeration pipe (15) is sealed with the reactor body (1), and the air outlet of the air source (16) is communicated with the air inlet of the aeration pipe (15);
在布水区(3)中设置布水器(8),布水器(8)的进水端与进水口(7)的出水端连通;A water distributor (8) is arranged in the water distribution area (3), and the water inlet end of the water distributor (8) communicates with the water outlet end of the water inlet (7);
悬浮填料区(4)装有悬浮填料;The suspended packing area (4) is equipped with suspended packing;
在反应器本体(1)位于出水区(5)的侧壁上分别设置有出水口(13)和回流口(12);出水口(13)与出水管(11)连通,出水管末端(11-1)的高度高于出水口(13)且低于进水口(7)的高度;回流口(12)与循环泵(10)的进料口连通,进水口(7)的进水端分别与循环泵(10)的出料口和进料泵(9)的出料口连通;A water outlet (13) and a return port (12) are respectively arranged on the side wall of the reactor body (1) located at the water outlet area (5); the water outlet (13) communicates with the water outlet pipe (11), and the water outlet pipe end (11 -1) is higher than the height of the water outlet (13) and lower than the height of the water inlet (7); It is communicated with the discharge port of circulation pump (10) and the discharge port of feed pump (9);
污泥沉积区(6)呈向下收缩的锥形,污泥沉淀区(6)的底部设有排泥口(14)。The sludge deposition area (6) is in the shape of a downward contracting cone, and a sludge discharge outlet (14) is provided at the bottom of the sludge deposition area (6).
步骤一中所述的悬浮填料为聚氨酯,密度小于水的密度;步骤一中所述的悬浮填料为海绵网状;步骤四中所述的厌氧工艺进水为饮料废水;步骤四中控制生物膜反应器中的水温为35℃。The suspension filler described in step 1 is polyurethane, and the density is less than the density of water; The water temperature in the membrane reactor was 35°C.
本试验提供了一种快速挂膜的方法,挂膜完成(COD去除率达30%)需要5d~7d,相比传统的排泥挂膜法所需时间缩短2周以上。This experiment provides a method of rapid film formation, and it takes 5-7 days to complete the film formation (COD removal rate reaches 30%), which is more than 2 weeks shorter than the traditional method of sludge discharge and film formation.
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CN110981094A (en) * | 2019-12-12 | 2020-04-10 | 芜湖市科邦新能源科技有限公司 | A complete set of equipment for biologically reacting sewage into clean energy |
CN115536134A (en) * | 2021-06-29 | 2022-12-30 | 中国石油化工股份有限公司 | Method and device for treating oily sewage |
CN115536134B (en) * | 2021-06-29 | 2024-04-05 | 中国石油化工股份有限公司 | Treatment method and device for oily sewage |
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