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CN108033775A - A kind of burned-magnesia brick and its production method that paper pulp is replaced with Dextrose Monohydrate - Google Patents

A kind of burned-magnesia brick and its production method that paper pulp is replaced with Dextrose Monohydrate Download PDF

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Publication number
CN108033775A
CN108033775A CN201711170452.4A CN201711170452A CN108033775A CN 108033775 A CN108033775 A CN 108033775A CN 201711170452 A CN201711170452 A CN 201711170452A CN 108033775 A CN108033775 A CN 108033775A
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Prior art keywords
magnesia
parts
brick
mass percentage
dextrose monohydrate
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Pending
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CN201711170452.4A
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Chinese (zh)
Inventor
赵东辉
王新杰
张义先
金钊
尹斌
王健骁
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Haicheng Lear Meg Materials Co Ltd Sita
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Haicheng Lear Meg Materials Co Ltd Sita
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Priority to CN201711170452.4A priority Critical patent/CN108033775A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/03Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on magnesium oxide, calcium oxide or oxide mixtures derived from dolomite
    • C04B35/04Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on magnesium oxide, calcium oxide or oxide mixtures derived from dolomite based on magnesium oxide
    • C04B35/043Refractories from grain sized mixtures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/62204Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/632Organic additives
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/64Burning or sintering processes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/60Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
    • C04B2235/608Green bodies or pre-forms with well-defined density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The present invention relates to fire resisting material field, more particularly to a kind of burned-magnesia brick and its production method that paper pulp is replaced with Dextrose Monohydrate.Include the raw material of following parts by weight:92 22 41 parts of brickmaking magnesia;92 useless 18 parts of bricks;Calcine Al2O335 parts of micro mist;35 parts of bonding agent Dextrose Monohydrate;Its physical and chemical index:MgO mass percentage >=92%;Al2O3Mass percentage≤0.4%;SiO2Mass percentage≤3%;Fe2O3Mass percentage≤1.10%;CaO mass percentage≤1.05%;Compressive resistance >=100.4MPa;Apparent porosity≤17.0;Bulk density >=2.92g/cm3.Its production method, includes the following steps:1) raw material crush, sieve, fine grinding;2) dispensing;3) it is kneaded;4) it is molded;5) dry, burn till.The present invention will not produce pollution, reach environmental-protection function;Desulfurization device need not be installed, you can reach standard limit of smog release;Can more preferable acceleration of sintering;It is cost-effective, and pollute small.

Description

A kind of burned-magnesia brick and its production method that paper pulp is replaced with Dextrose Monohydrate
Technical field
The present invention relates to fire resisting material field, it is more particularly to a kind of with Dextrose Monohydrate replace paper pulp burned-magnesia brick and its Production method.
Background technology
Magnesia brick refers to content of magnesia more than 90%, the basic refractory using periclase as principal crystalline phase.Burned-magnesia brick is adopted It is primary raw material with high-quality magnesite clinker, bonding agent is used as using paper pulp.After mixing and high-pressure molding, the height more than 1550 DEG C Burnt till in warm tunnel oven.Magnesia brick has higher refractoriness, and good alkali resistance slag performance, loading softening start temperature is high, has Good heat endurance, anti-erosion and antistrip performance.It is mainly used for making steel alkaline open-hearth furnace, EAF bottom and furnace wall, oxygen turns The permanent liner of stove, non-ferrous metal smelting furnace, hyperthermia tunnel Kiln calcine magnesia brick and cement rotary kiln liner, the furnace bottom of heating furnace and Furnace wall, regenerator chamber of glass kiln checker brick etc..
The bonding agent of the production and application of present burned-magnesia brick is sulphite secondary stock, the sulphur containing 3%-4% in paper pulp, When burning till, these sulphur can be discharged in the form of sulfur oxide.On the one hand the loss of desulfurization device is added, on the other hand Air can be polluted, causes environmental disruption.
The content of the invention
The technical problems to be solved by the invention be to provide it is a kind of with Dextrose Monohydrate replace paper pulp burned-magnesia brick and its Production method, reduces the generation of sulfur dioxide when magnesia brick produces, so as to reduce the loss and atmosphere pollution of desulfurization device.
To achieve the above object, the present invention is realized using following technical scheme:
A kind of burned-magnesia brick that paper pulp is replaced with Dextrose Monohydrate, its physical and chemical index:MgO >=92%;Al2O3≤ 0.4%; SiO2≤ 3%;Fe2O3≤ 1.10%;CaO≤1.05%;Compressive resistance >=100.4MPa;Apparent porosity≤17.0;Bulk density ≥2.92g/cm3
Its raw material includes following parts by weight of component:22-29 parts of the 92 brickmaking magnesia of 200 mesh, 0-1mm (refers to and is less than more than 0mm Equal to 1mm) 22-29 parts of 92 brickmaking magnesia, 33-41 parts of the 92 brickmaking magnesia of 1-3mm (refer to and be less than or equal to 3mm more than 1mm), Useless 1-8 parts of the brick in the 92 of 200 mesh, 92 useless 1-7 parts of the bricks of 0-1mm (refer to and be less than or equal to 1mm more than 0mm), 1-3mm (refers to small more than 1mm In equal to 3mm) 92 useless 1-7 part of bricks, calcining Al2O33-5 parts of micro mist, 3-5 parts of bonding agent Dextrose Monohydrate.
A kind of production method for the burned-magnesia brick for replacing paper pulp with Dextrose Monohydrate, specifically comprises the following steps:
(1) raw material crush, sieve, fine grinding:92 brickmaking magnesia and 92 useless bricks are crushed respectively, are sieved, fine grinding:By 92 brickmaking Magnesia is slightly broken in jaw crusher, and the particle after slightly breaking enters thin broken in kibbler roll, rolls, finally by vibration Sieved, screen size is 0-200 mesh, 0-1mm, 1-3mm;92 useless bricks are slightly broken in jaw crusher, it is thick broken Particle afterwards enters thin broken in kibbler roll, rolls, and is sieved finally by vibrating screen, screen size is 0-200 mesh, 0- 1mm、1-3mm;
(2) it is formulated:Formula weighs raw material as described in claim 1-4;
(3) it is kneaded:The raw material of 0-1mm, 1-3mm granularity is first added, is kneaded 1-2min, Dextrose Monohydrate is then added and mixes again 2-3min, adds after fine powder is kneaded 8-10min and discharges;
(4) it is molded:630t press-moldings are used after discharging, cloth is uniform, ensures 2-3 tip-tap, and green brick forming volume is close Spend for 2.92-2.94g/cm3
(5) dry, burn till:Adobe is first put into drying kiln for drying 10-12h discharge moisture, then tunnel is entered by kiln car Burnt till in road kiln;Cart system is per car 70-100min, and calcining system burns till 1480 DEG C for highest, 3 high temperature dots, and oil gun is equal For to rifle.
Compared with prior art, the beneficial effects of the invention are as follows:
1. Dextrose Monohydrate not sulfur-bearing, will not produce pollution, reach environmental-protection function.
After 2. bonding agent is changed to Dextrose Monohydrate by paper pulp, pollutant, therefore nothing are all free of in fuel, raw material, bonding agent Desulfurization device need to be installed, you can reach standard limit of smog release.
3. Dextrose Monohydrate bonding agent belongs to low-temperature binder, when alumina powder is used together, can preferably promote Into sintering.
4. it is cost-effective in the case where key index is substantially without influence, and pollute small.
Embodiment
With reference to embodiment, the present invention is further described:
The present invention will be described in detail for following embodiments.These embodiments be only to preferred embodiment of the invention into Row description, does not limit the scope of the present invention.
Embodiment 1-3 is given below, replaces the formula of the burned-magnesia brick of paper pulp as shown in table 1 with Dextrose Monohydrate:
1 embodiment 1-3 of table makes the formula of gunning refractory using 92 brickmaking magnesia as primary raw material
Primary raw material index is shown in Table 2:
2 primary raw material index of table
The production method of the burned-magnesia brick that paper pulp is replaced with Dextrose Monohydrate of above-described embodiment 1-3, comprises the following steps:
1) raw material crush, sieve, fine grinding:
92 brickmaking magnesia are slightly broken in jaw crusher, it is thick broken after particle enter thin broken in kibbler roll, Roll, sieved finally by vibrating screen, it is 200 mesh, 0 < granularities≤1mm, 1mm < granularity≤3mm particle diameters that granularity, which is made, Raw material, 92 useless bricks are slightly broken in jaw crusher, and the particle after slightly breaking enters thin broken in kibbler roll, rolls, most Sieved afterwards by vibrating screen, granularity is made as 200 mesh, the raw material of 0 < granularities≤1mm, 1mm < granularity≤3mm particle diameters;
2) dispensing:
Raw material is weighed by above-mentioned formula;
3) it is kneaded:
The raw material of 0-1,1-3 granularity is first added, is kneaded 2min, Dextrose Monohydrate is then added and mixes 3min again, is added thin Powder discharges after being kneaded 9min.
4) it is molded:
630t press-moldings are used after discharging, cloth is uniform, ensures 3 tip-taps, green brick forming bulk density is 2.94g/ cm3
5) dry, burn till:
Adobe is first put into drying kiln for drying 12 it is small when discharge moisture, then entered by kiln car in tunnel oven and burnt till.Push away Car system is per car 90min, and calcining system burns till 1480 DEG C for highest, and 3 high temperature dots, oil gun is to rifle.
6) check and accept and pack:
1 checks and accepts:
The sampling of 1.1 material, check and accept and press YB 367-75《Refractory product sampling, check and accept, take care of and transport rule》Carry out.
Chemical composition analysis is done in 1.2 grab sample.
2 packagings, transport, storage and quality certificate:
YB 367-75 are pressed in packaging, transport and the storage of 2.1 material《Refractory product sampling, check and accept, take care of and transport rule》Into OK.
2.2 material must be accompanied by the quality certificate that technical supervision department signs and issues when dispatching from the factory, indicate supplier's title or emblem mark, need Square title, Shipping Date, contract number, standard number, name of product, the trade mark, lot number and physical and chemical index, wait result to report.
My company adheres to developing for many years high-new refractory material, services international and domestic metallurgical and building material industry, company The marketability of capacity for technological innovation and new product also obtains the consistent accreditation of user.Produced for existing burned-magnesia brick The loss problem of desulfurization device, and the environmental protection policy that response country implements are added in journey, my company proposes a kind of water Glucose replaces the burned-magnesia brick of paper pulp.Dextrose Monohydrate not sulfur-bearing, will not produce pollution, reach environmental-protection function.Bonding agent by After paper pulp is changed to Dextrose Monohydrate, pollutant is all free of in fuel, raw material, bonding agent, therefore desulfurization device need not be installed, you can Reach standard limit of smog release.Dextrose Monohydrate bonding agent belongs to low-temperature binder, when alumina powder is used together, Ke Yigeng Good acceleration of sintering.It is cost-effective in the case where key index is substantially without influence, and pollute small.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (5)

1. a kind of burned-magnesia brick that paper pulp is replaced with Dextrose Monohydrate, it is characterised in that include the raw material of following parts by weight:
Its physical and chemical index:MgO mass percentage >=92%;Al2O3Mass percentage≤0.4%;SiO2Mass percentage ≤ 3%;Fe2O3Mass percentage≤1.10%;CaO mass percentage≤1.05%;Compressive resistance >=100.4MPa;It is aobvious The porosity≤17.0;Bulk density >=2.92g/cm3
2. a kind of burned-magnesia brick that paper pulp is replaced with Dextrose Monohydrate according to claim 1, it is characterised in that described 92 Brickmaking magnesia is mixed by the 92 brickmaking magnesia of different-grain diameter of following parts by weight:22-29 parts of the 92 brickmaking magnesia of 200 mesh;0 < 22-29 parts of the 92 brickmaking magnesia of particle diameter≤1mm;33-41 parts of the 92 brickmaking magnesia of 1 < particle diameters≤3mm.
3. a kind of burned-magnesia brick that paper pulp is replaced with Dextrose Monohydrate according to claim 1, it is characterised in that described 92 Useless brick is mixed by the different-grain diameter 92 of the following parts by weight brick that gives up:Useless 1-8 parts of the brick in the 92 of 200 mesh;The 92 of 0 < particle diameters≤1mm Useless 1-7 parts of brick;Useless 1-7 parts of the brick in the 92 of 1 < particle diameters≤3mm.
4. a kind of burned-magnesia brick that paper pulp is replaced with Dextrose Monohydrate according to claim 1, it is characterised in that described 92 CaO mass percentage≤1.5% in brickmaking magnesia.
5. a kind of a kind of production method for the burned-magnesia brick for replacing paper pulp with Dextrose Monohydrate according to claim 1, its It is characterized in that, specifically comprises the following steps:
(1) raw material crush, sieve, fine grinding:92 brickmaking magnesia and 92 useless bricks are crushed respectively, are sieved, fine grinding:By 92 brickmaking magnesia Slightly broken in jaw crusher, it is thick broken after particle enter thin broken in kibbler roll, roll, finally by vibrating screen into Row screening, screen size is 0-200 mesh, 0-1mm, 1-3mm;92 useless bricks are slightly broken in jaw crusher, after slightly breaking Particle enter kibbler roll in thin broken, roll, sieved finally by vibrating screen, screen size for 0-200 mesh, 0-1mm, 1-3mm;
(2) it is formulated:Formula weighs raw material as described in claim 1-4;
(3) it is kneaded:The raw material of 0-1mm, 1-3mm granularity is first added, is kneaded 1-2min, Dextrose Monohydrate is then added and mixes 2- again 3min, adds after fine powder is kneaded 8-10min and discharges;
(4) it is molded:500-630t press-moldings are used after discharging, cloth is uniform, ensures 2-3 tip-tap, and green brick forming volume is close Spend for 2.92-2.94g/cm3
(5) dry, burn till:Adobe is first put into drying kiln for drying 10-12h discharge moisture, then tunnel oven is entered by kiln car In burn till;Cart system is per car 70-100min, and calcining system burns till 1480 DEG C for highest, and 3 high temperature dots, oil gun is pair Rifle.
CN201711170452.4A 2017-11-22 2017-11-22 A kind of burned-magnesia brick and its production method that paper pulp is replaced with Dextrose Monohydrate Pending CN108033775A (en)

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CN109020602A (en) * 2018-08-27 2018-12-18 海城利尔麦格西塔材料有限公司 A kind of hydration-resisting magnesia brick and its production method
CN109020504A (en) * 2018-08-27 2018-12-18 海城利尔麦格西塔材料有限公司 A kind of magnesium silicon carbide brick and its production method

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109020602A (en) * 2018-08-27 2018-12-18 海城利尔麦格西塔材料有限公司 A kind of hydration-resisting magnesia brick and its production method
CN109020504A (en) * 2018-08-27 2018-12-18 海城利尔麦格西塔材料有限公司 A kind of magnesium silicon carbide brick and its production method

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Application publication date: 20180515