CN108014543A - A kind of ormolu water process filter wire and preparation method thereof - Google Patents
A kind of ormolu water process filter wire and preparation method thereof Download PDFInfo
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- CN108014543A CN108014543A CN201810002690.2A CN201810002690A CN108014543A CN 108014543 A CN108014543 A CN 108014543A CN 201810002690 A CN201810002690 A CN 201810002690A CN 108014543 A CN108014543 A CN 108014543A
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- Prior art keywords
- ormolu
- wire
- filter wire
- water process
- process filter
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 238000000034 method Methods 0.000 title claims abstract description 30
- 230000008569 process Effects 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 229910045601 alloy Inorganic materials 0.000 claims description 14
- 239000000956 alloy Substances 0.000 claims description 14
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 13
- 238000000137 annealing Methods 0.000 claims description 13
- 229910052725 zinc Inorganic materials 0.000 claims description 13
- 239000011701 zinc Substances 0.000 claims description 13
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 12
- 229910052802 copper Inorganic materials 0.000 claims description 12
- 239000010949 copper Substances 0.000 claims description 12
- 238000005491 wire drawing Methods 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 4
- 239000000706 filtrate Substances 0.000 abstract description 23
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000000746 purification Methods 0.000 abstract description 4
- 239000000243 solution Substances 0.000 description 23
- 239000000463 material Substances 0.000 description 11
- 238000001914 filtration Methods 0.000 description 10
- 239000002245 particle Substances 0.000 description 10
- 238000001556 precipitation Methods 0.000 description 8
- HJTAZXHBEBIQQX-UHFFFAOYSA-N 1,5-bis(chloromethyl)naphthalene Chemical compound C1=CC=C2C(CCl)=CC=CC2=C1CCl HJTAZXHBEBIQQX-UHFFFAOYSA-N 0.000 description 6
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 6
- GOLCXWYRSKYTSP-UHFFFAOYSA-N arsenic trioxide Inorganic materials O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 6
- 239000000047 product Substances 0.000 description 5
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 4
- 238000004448 titration Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 3
- 125000001309 chloro group Chemical group Cl* 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- 238000006479 redox reaction Methods 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 238000002479 acid--base titration Methods 0.000 description 2
- XTEGARKTQYYJKE-UHFFFAOYSA-N chloric acid Chemical compound OCl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-N 0.000 description 2
- 229940005991 chloric acid Drugs 0.000 description 2
- RCTYPNKXASFOBE-UHFFFAOYSA-M chloromercury Chemical compound [Hg]Cl RCTYPNKXASFOBE-UHFFFAOYSA-M 0.000 description 2
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 2
- RLJMLMKIBZAXJO-UHFFFAOYSA-N lead nitrate Chemical compound [O-][N+](=O)O[Pb]O[N+]([O-])=O RLJMLMKIBZAXJO-UHFFFAOYSA-N 0.000 description 2
- RVPVRDXYQKGNMQ-UHFFFAOYSA-N lead(2+) Chemical compound [Pb+2] RVPVRDXYQKGNMQ-UHFFFAOYSA-N 0.000 description 2
- 229960002523 mercuric chloride Drugs 0.000 description 2
- LWJROJCJINYWOX-UHFFFAOYSA-L mercury dichloride Chemical compound Cl[Hg]Cl LWJROJCJINYWOX-UHFFFAOYSA-L 0.000 description 2
- BQPIGGFYSBELGY-UHFFFAOYSA-N mercury(2+) Chemical compound [Hg+2] BQPIGGFYSBELGY-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- -1 catalyst Chemical compound 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/02—Loose filtering material, e.g. loose fibres
- B01D39/06—Inorganic material, e.g. asbestos fibres, glass beads or fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
- B21C37/00—Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
- B21C37/04—Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of bars or wire
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/04—Alloys based on copper with zinc as the next major constituent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/10—Filtering material manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/12—Special parameters characterising the filtering material
- B01D2239/1291—Other parameters
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The present invention provides a kind of ormolu water process filter wire and preparation method thereof, and the ormolu water process filter wire is wire clusters.The filter wire has the specific surface area of higher, adds the purification efficiency of the ormolu filtrate of Unit Weight, reduces the production cost of ormolu filtrate water purifier.
Description
Technical field
The invention belongs to filtering material field, is related to a kind of ormolu water process filter wire and preparation method thereof.
Background technology
Currently there is a kind of ormolu water treatment filter material of high-purity (99.99%), it is by power series classification method
It is manufactured.At present, Kai get Fei KDF filtrates have two kinds of major products：KDF055, the alloy of the zinc of 50% copper 50%, color gold
Huang, is in granular form, and size is 0.145~2.0mm, and apparent density is 2.4~2.9g/cm3；Kai get Fei KDF085,85% copper
With the alloy of 15% zinc, color is bronzing, is in granular form, and size is 0.149~2.0mm, apparent density for 2.2~
2.9g/cm3。
Ormolu is many, such as electrochemical redox reaction, zinc ion, catalytic action in water purifying principle.
Electrochemical redox reaction：As being based primarily upon electrification to chlorine residue and heavy metal in Kai get Fei KDF filtrate purified waters
Learn redox.The normal potential of zinc is -0.76V, and copper is+0.34V, both net potential differences are 1.1V, in electrolyte solution
In (raw water), copper, the zinc of alloy surface form numerous small electrode and form micro cell, and current potential becomes cathode for positive copper
Generation reduction reaction, current potential become anode for negative zinc and oxidation reaction occur.Zinc, which loses, in anode is electronically generated zinc ion entrance
In raw water, in raw water chlorine residue receive electronics and be reduced to become chlorion.Heavy metal ion is then reduced into be insoluble in water
Metallic atom, plating are overlying on the surface of Kai get Fei KDF alloys.Electrochemical redox reaction make hydrogen peroxide in water, hydroxyl from
Sub- concentration rise, so that pH value increases in water, destroys the living environment of some bacteriums, plays bactericidal bacteriostasis.Zinc ion
It can play the role of preventing the synthesis of microbial enzyme in water, so as to influence the normal growth of organism, reach and suppress microorganism
The purpose of breeding.Copper, zinc can be used as the organic matters such as oxidant Pyrogentisinic Acid, the benzene such as catalyst, catalysis oxygen in water to be aoxidized
Degraded.Kai get Fei KDF have outstanding advantages as water purification filtrate compared with traditional filtrate：Such as service life length, at least can be used
More than 10 years；It can recover filter capacity with 100%；It is easy to maintain；Processing cost is low；High comprehensive performance etc..
But Kai get Fei KDF exist in granular form in the prior art, specific surface area is limited, the filter that when filtering needs
Expect more, improve the cost of Kai get Fei KDF filters.
The content of the invention
For technical problem existing in the prior art, the present invention provides a kind of ormolu water process filter wire and its preparation
Method, the ormolu water process filter wire are linear bulk, and the filter wire has the specific surface area of higher, adds unit weight
The purification efficiency of the filtrate of amount, reduces the production cost of Kai get Fei KDF filters.
To reach above-mentioned purpose, the present invention uses following technical scheme：
It is an object of the present invention to provide a kind of ormolu water process filter wire, the ormolu water process filter wire is
Wire clusters.
As currently preferred technical solution, the size of the KDF filtrates is 0.05mm* (0.10~0.15) mm, such as
0.05mm*0.10mm, 0.05mm*0.11mm, 0.05mm*0.12mm, 0.05mm*0.13mm, 0.05mm*0.14mm or
0.05mm*0.15mm, it is not limited to cited numerical value, other interior unrequited numerical value of the number range are equally applicable.
Size of the present invention is the cross-sectional area of the ormolu water process filter wire, its length can be according to production need
Free adjusting is carried out, therefore its length is not defined in specification.
As currently preferred technical solution, the water process filter wire is ormolu, and the mass fraction of wherein copper is
50~85%, such as 50%, 55%, 60%, 65%, 70%, 75%, 80% or 85%, it is not limited to cited number
Value, other interior unrequited numerical value of the number range are equally applicable, and surplus is zinc.
The second purpose of the present invention is to provide a kind of preparation method of above-mentioned water process filter wire, the preparation method include with
Lower step：
(1) elemental copper and simple substance zinc are melted and mixed, pour to obtain alloy bar；
(2) alloy bar obtained to step (1) makes annealing treatment, after annealing wire drawing obtain the ormolu filter wire.
In the present invention, the filter wire of suitable stiffness, can continue the ormolu filter wire that step (2) obtain in order to obtain
Repeatedly annealing.
As currently preferred technical solution, the temperature of step (2) described annealing is 200~400 DEG C, such as 200
DEG C, 220 DEG C, 250 DEG C, 280 DEG C, 300 DEG C, 320 DEG C, 350 DEG C, 380 DEG C or 400 DEG C etc., it is not limited to cited number
Value, other interior unrequited numerical value of the number range are equally applicable.
Preferably, the time of step (2) described annealing is 1~3h, as 1h, 1.2h, 1.5h, 1.8h, 2h, 2.2h,
2.5h, 2.8h or 3h etc., it is not limited to cited numerical value, other interior unrequited numerical value of the number range are equally suitable
With.
The present invention obtains wire clusters water process filter wire using wire-drawing equipment, its size can be worked by change wire-drawing equipment joins
Number obtains, and the size of the wire drawing material obtained due to changing wire-drawing equipment technological parameter is the common knowledge of this area, is said
Do not repeated in bright book.
Compared with prior art, the present invention at least has the advantages that：
The present invention provides a kind of ormolu water process filter wire, and the ormolu filter wire is line style clusters, specific surface area
Up to 0.458m2/ g, granular Kai get Fei KDF filtrates compared with the prior art, specific surface area are 10~30 purposes of particle diameter
20 times of the specific surface area of Kai get Fei KDF filtrates, are 7 times of the specific surface area of 30~70 Mu Kai get Fei KDF filtrates of particle diameter.
Brief description of the drawings
Fig. 1 is the product figure for the wire ormolu filter wire that the size that the present invention is prepared is 0.05mm*0.10mm；
Fig. 2 is the product figure for the wire ormolu filter wire that the size that the present invention is prepared is 0.05mm*0.15mm；
Fig. 3 is for the product figure of the 30-70 mesh Kai get Fei KDF filtering material particles of in the market purchase；
Fig. 4 is for the product figure of the 10-30 mesh Kai get Fei KDF filtering material particles of in the market purchase.
Embodiment
For the present invention is better described, technical scheme is readily appreciated, of the invention is typical but non-limiting
Embodiment is as follows：
Embodiment 1
The present invention provides a kind of preparation method of ormolu water process filter wire, and the preparation method comprises the following steps：
(1) elemental copper and simple substance zinc are melted and according to mass ratio 1:1 mixing (or other ratios), pours to obtain alloy
Rod；
(2) to the alloy bar that step (1) obtains 300 DEG C make annealing treatment 2h, after annealing wire drawing obtain the ormolu
Water process filter wire.
The method provided by embodiment 1, be prepared size be respectively 0.05mm*0.10mm, 0.05mm*0.12mm with
And the wire ormolu filter wire of 0.05mm*0.15mm.
Embodiment 2
The present invention provides a kind of preparation method of ormolu filter wire, and the preparation method comprises the following steps：
(1) elemental copper and simple substance zinc are melted and according to mass ratio 8:2 mixing, pour to obtain alloy bar；
(2) to the alloy bar that step (1) obtains 200 DEG C make annealing treatment 3h, after annealing wire drawing obtain the ormolu
Filter wire.
The method provided by embodiment 2, be prepared size be respectively 0.05mm*0.10mm, 0.05mm*0.12mm with
And the wire ormolu filter wire of 0.05mm*0.15mm.
Embodiment 3
In the present embodiment, the hypochlorite solution of 3 parts of 500mL 0.05mol/L is configured first, is respectively prepared into embodiment 1
To size be respectively 0.05mm*0.10mm, 0.05mm*0.12mm and 0.05mm*0.15mm wire clusters ormolu
Filter wire 5g is put into the liquor natrii hypochloritis of configuration, and filtrate is taken out after 5min, using oxidimetry to time in solution
The concentration of chloric acid is tested, calculate hypochlorous acid it is clear remove rate.
Embodiment 4
In the present embodiment, the hydrogen sulfide solution of 3 parts of 500mL 0.05mol/L is configured first, is respectively prepared into embodiment 1
To size be respectively 0.05mm*0.10mm, 0.05mm*0.12mm and 0.05mm*0.15mm wire clusters ormolu
Filter wire 5g is put into the liquor natrii hypochloritis of configuration, and filtrate is taken out after 5min, using acid-base titration to the hydrogen sulfide in solution
Concentration tested, calculate the clearance rate of hydrogen sulfide.
Embodiment 5
In the present embodiment, the lead nitrate solution of 3 parts of 500mL 0.05mol/L is configured first, is respectively prepared into embodiment 1
To size be respectively 0.05mm*0.10mm, 0.05mm*0.12mm and 0.05mm*0.15mm wire clusters ormolu
Filter wire 5g is put into the liquor natrii hypochloritis of configuration, and filtrate is taken out after 5min, using precipitation titration to the plumbi nitras in solution
Concentration tested, calculate the clearance rate of lead ion.
Embodiment 6
In the present embodiment, the mercuric chloride solution of 3 parts of 500mL 0.05mol/L is configured first, is respectively prepared into embodiment 1
To size be respectively 0.05mm*0.10mm, 0.05mm*0.12mm and 0.05mm*0.15mm wire clusters ormolu
Filter wire 5g is put into the liquor natrii hypochloritis of configuration, and filtrate is taken out after 5min, using precipitation titration to the mercury chloride in solution
Concentration tested, calculate the clearance rate of mercury ion.
Embodiment 7
In the present embodiment, the arsenic trioxide solution of 3 parts of 500mL 0.05mol/L is configured first, respectively makes embodiment 1
It is respectively the wire clusters copper zinc of 0.05mm*0.10mm, 0.05mm*0.12mm and 0.05mm*0.15mm for obtained size
Alloy filter wire 5g is put into the liquor natrii hypochloritis of configuration, and the precipitation of filtrate and generation is filtered out after 5min, is dripped using precipitation
Determine method to test the concentration of the arsenic trioxide in solution, calculate the clearance rate of arsenic trioxide.
Embodiment 8
In the present embodiment, the hypochlorite solution of 3 parts of 500mL 0.05mol/L is configured first, is respectively prepared into embodiment 2
To size be respectively 0.05mm*0.10mm, 0.05mm*0.12mm and 0.05mm*0.15mm wire clusters ormolu
Filter wire 10g is put into the liquor natrii hypochloritis of configuration, and filtrate is taken out after 5min, using oxidimetry to time in solution
The concentration of chloric acid is tested, and calculates the clear clearance rate of hypochlorous acid.
Embodiment 9
In the present embodiment, the hydrogen sulfide solution of 3 parts of 500mL 0.05mol/L is configured first, is respectively prepared into embodiment 2
To size be respectively 0.05mm*0.10mm, 0.05mm*0.12mm and 0.05mm*0.15mm wire clusters ormolu
Filter wire 10g is put into the liquor natrii hypochloritis of configuration, and filtrate is taken out after 5min, using acid-base titration to the hydrogen sulfide in solution
Concentration tested, calculate the clearance rate of hydrogen sulfide.
Embodiment 10
In the present embodiment, the lead nitrate solution of 3 parts of 500mL 0.05mol/L is configured first, is respectively prepared into embodiment 2
To size be respectively 0.05mm*0.10mm, 0.05mm*0.12mm and 0.05mm*0.15mm wire clusters ormolu
Filter wire 10g is put into the liquor natrii hypochloritis of configuration, and filtrate is taken out after 5min, using precipitation titration to the plumbi nitras in solution
Concentration tested, calculate the clearance rate of lead ion.
Embodiment 11
In the present embodiment, the mercuric chloride solution of 3 parts of 500mL 0.05mol/L is configured first, is respectively prepared into embodiment 2
To size be respectively 0.05mm*0.10mm, 0.05mm*0.12mm and 0.05mm*0.15mm wire clusters ormolu
Filter wire 10g is put into the liquor natrii hypochloritis of configuration, and filtrate is taken out after 5min, using precipitation titration to the mercury chloride in solution
Concentration tested, calculate the clearance rate of mercury ion.
Embodiment 12
In the present embodiment, the arsenic trioxide solution of 3 parts of 500mL 0.05mol/L is configured first, respectively makes embodiment 2
It is respectively the wire clusters copper zinc of 0.05mm*0.10mm, 0.05mm*0.12mm and 0.05mm*0.15mm for obtained size
Alloy filter wire 10g is put into the liquor natrii hypochloritis of configuration, and the precipitation of filtrate and generation is filtered out after 5min, is dripped using precipitation
Determine method to test the concentration of the arsenic trioxide in solution, calculate the clearance rate of arsenic trioxide.
Comparative example 1
In this comparative example, except the ormolu filter wire that embodiment 1 is prepared replaces with the 30-70 of in the market purchase
Outside purpose Kai get Fei KDF055 filtering material particles, other conditions are identical with embodiment 3-7.
Comparative example 2
In this comparative example, except the ormolu filter wire that embodiment 2 is prepared replaces with the 30-70 of in the market purchase
Outside purpose Kai get Fei KDF085 filtering material particles, other conditions are identical with embodiment 8-12.
The Kai get Fei KDF that the ormolu filter wire specific surface area and comparative example 1 and 2 that Examples 1 and 2 are prepared use
The data of the specific surface area of filtering material particle are as shown in table 1；To in embodiment 3-12 and comparative example 1 and 2 to different material in water
Clearance rate test result as shown in tables 2 and 3.
Table 1
Table 2
Table 3
Wire clusters ormolu filter wire and the Kai get Fei KDF that embodiment 1-2 is prepared are can be seen that from table 1-3
The specific surface area of filtrate, 6~7 times of the 30-70 Mu Kai get Fei KDF filtering material particle specific surface areas bought in the market, though
Kai get Fei KDF055 and Kai get Fei the KDF085 particles of right in the market to the removal rate of chlorine residue in water up to 99%, to heavy metal
Removal rate up to 98%, but the removal efficiency higher of wire clusters ormolu filter wire provided by the invention, and clearance rate
The slightly above Kai get Fei KDF filtering material particles of in the market, improve the purification efficiency of Kai get Fei KDF filtrates, reduce water purifier
Production cost.
Applicant states that the present invention illustrates the detailed construction feature of the present invention by above-described embodiment, but the present invention is simultaneously
Above-mentioned detailed construction feature is not limited to, that is, does not mean that the present invention has to rely on above-mentioned detailed construction feature and could implement.Institute
Belong to those skilled in the art it will be clearly understood that any improvement in the present invention, to the equivalence replacement of component selected by the present invention
And the increase of accessory, selection of concrete mode etc., all fall within protection scope of the present invention and the open scope.
The preferred embodiment of the present invention described in detail above, still, during present invention is not limited to the embodiments described above
Detail, in the range of the technology design of the present invention, a variety of simple variants, example can be carried out to technical scheme
Such as Filamentous filter wire, bulk filter wire, foaming filter wire, netted filtering silk etc..These simple variants belong to the guarantor of the present invention
Protect scope.
It is further to note that each particular technique feature described in above-mentioned embodiment, in not lance
In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to it is various can
The combination of energy no longer separately illustrates.
In addition, various embodiments of the present invention can be combined randomly, as long as it is without prejudice to originally
The thought of invention, it should equally be considered as content disclosed in this invention.
Claims (5)
1. a kind of ormolu water process filter wire, it is characterised in that the ormolu water process filter wire rolls into a ball silk for wire.
2. ormolu water process filter wire according to claim 1, it is characterised in that the ormolu water process filter wire
Size be 0.05mm* (0.10~0.15) mm.
3. ormolu water process filter wire according to claim 1 or 2, it is characterised in that the ormolu water process
The mass fraction of filter wire, wherein copper is 50~85%, and surplus is zinc.
A kind of 4. preparation method of any one of claim 1-3 ormolu water process filter wires, it is characterised in that the system
Preparation Method comprises the following steps：
(1) elemental copper and simple substance zinc are melted and mixed, pour to obtain alloy bar；
(2) alloy bar obtained to step (1) makes annealing treatment, after annealing wire drawing obtain ormolu water process filter
Silk.
5. preparation method according to claim 4, it is characterised in that the temperature of step (2) described annealing for 200~
400℃；
Preferably, the time of step (2) described annealing is 1~3h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810002690.2A CN108014543A (en) | 2018-01-02 | 2018-01-02 | A kind of ormolu water process filter wire and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810002690.2A CN108014543A (en) | 2018-01-02 | 2018-01-02 | A kind of ormolu water process filter wire and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108014543A true CN108014543A (en) | 2018-05-11 |
Family
ID=62071140
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810002690.2A Pending CN108014543A (en) | 2018-01-02 | 2018-01-02 | A kind of ormolu water process filter wire and preparation method thereof |
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| JP2000129376A (en) * | 1998-10-28 | 2000-05-09 | Mitsui Mining & Smelting Co Ltd | Reinforced brass and its manufacture |
| JP2006150379A (en) * | 2004-11-26 | 2006-06-15 | San-Etsu Metals Co Ltd | Brass material and manufacturing method therefor |
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| CN208465388U (en) * | 2018-01-02 | 2019-02-05 | 关险峰 | A kind of water-treated filter wire of ormolu |
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