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CN108004047A - Closestool cleanser and preparation method thereof - Google Patents

Closestool cleanser and preparation method thereof Download PDF

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Publication number
CN108004047A
CN108004047A CN201711418048.4A CN201711418048A CN108004047A CN 108004047 A CN108004047 A CN 108004047A CN 201711418048 A CN201711418048 A CN 201711418048A CN 108004047 A CN108004047 A CN 108004047A
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CN
China
Prior art keywords
closestool
closestool cleanser
parts
essential oil
raw material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201711418048.4A
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Chinese (zh)
Inventor
不公告发明人
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuhu Wanjiang Intellectual Property Operation Center Co Ltd
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Wuhu Wanjiang Intellectual Property Operation Center Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuhu Wanjiang Intellectual Property Operation Center Co Ltd filed Critical Wuhu Wanjiang Intellectual Property Operation Center Co Ltd
Priority to CN201711418048.4A priority Critical patent/CN108004047A/en
Publication of CN108004047A publication Critical patent/CN108004047A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/046Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/201Monohydric alcohols linear
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2079Monocarboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008Polymeric surface-active agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/75Amino oxides

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention provides Closestool cleanser and preparation method thereof, the Closestool cleanser includes following material:Methyl sodiosul foaliphatate, neopelex, lauramide third class amine oxide, fatty alcohol polyoxyethylene ether, fungicide, citric acid, sodium hypochlorite, light-coloured vinegar, fruits and vegetables zymotic fluid, essential oil, 75% ethanol, distilled water.Detergent of closet agent prescription provided by the invention is gentle, and compared with prior art, it can quickly remove toilet grime and have the function that bacteriostat degerming, and one punching of a spray can purify closestool, and fast and easy is succinct.

Description

Closestool cleanser and preparation method thereof
Technical field
The present invention relates to Closestool cleanser and preparation method thereof.
Background technology
Closestool is common daily necessities in people's life, and most easily grows the place of dirt and bacterium, detergent of closet Agent is to switch to the cleaning formulation of toilet designs.Presently commercially available the mostly of toilet bowl cleaning agent use are cheap, poisonous and not degradable Inorganic acid and surfactant be made of bulk composition, except pollute environment, the health of people can also be caused necessarily Influence.
The content of the invention
The deficiency for more than, the present invention provides Closestool cleanser and preparation method thereof, is pressed down by adding Chinese medicinal plant type Microbial inoculum, and gentle formula is used, the Closestool cleanser of antibacterial delicate fragrance type is prepared, its cleaning effect to hand is bright It is aobvious, hand skin will not be stimulated, there is moisturizing moisturizing and antibacterial, and be easy to degrade, it is environmentally protective for environment.
The technical solution that the present invention takes is:
A kind of Closestool cleanser, includes the raw material of following parts by weight:
Further, it is preferable to it is the raw material for including following parts by weight:
The methyl sodiosul foaliphatate is carbochain in C14/16Or C14Following methyl sodiosul foaliphatate, it is relatively more suitable For being used as surfactant in liquid detergent.
The fungicide is by trichlorine is non-, benzalkonium bromide, dimethyl oxazolidine are according to weight ratio 1:(0.3~0.6):(0.8~ 1.2) form.The effect of the fungicide sterilization of such a proportioning is stronger, if proportioning can reduce the effect of sterilization outside this scope Fruit.
The fruits and vegetables zymotic fluid includes the raw material of following parts by weight:5~10 parts of aloe, 10~30 parts of pomelo peel, orange peel 10~30 parts, 15~25 parts of lemon.
The preparation method of the fruits and vegetables zymotic fluid is:Each raw material of formula ratio is crushed, 5~10 times of water is added and carries out anaerobism Fermentation 7~10 days.Each fruits and vegetables produce a variety of organic acids after anaerobic fermentation above, can remove remaining urine on closestool Alkali.
The essential oil includes Rosa Damascana, clove oil, Lavender, refined jasmine oil, chamomile essential oil, lemon extract Oil, in one's early teens orange essential oil, one kind in essential oil.
Present invention also offers the preparation method of the Closestool cleanser, the preparation method comprises the following steps:
(1) distilled water of formula ratio and 75% ethanol are mixed and heated to 45~55 DEG C, added thereto while agitating Enter methyl sodiosul foaliphatate, neopelex, lauramide third class amine oxide, the aliphatic alcohol polyethenoxy of formula ratio Ether, heating stirring is to being completely dissolved, and natural cooling;
(2) citric acid, sodium hypochlorite, light-coloured vinegar, the fruits and vegetables zymotic fluid of formula ratio are added into step (1), is mixed equal It is even;
(3) fungicide and essential oil of formula ratio will be added in step (2), is mixed evenly that to can obtain the closestool clear Clean dose.
In the formula of Closestool cleanser provided by the invention, by the anion, cation, non-ionic surface of low irritant Activating agent compounds, and has fabulous synergistic function, has stronger dirt-removing power, and have certain bacteriostasis.Lemon Lemon acid, sodium hypochlorite, fruits and vegetables zymotic fluid, light-coloured vinegar mating reaction can depth remove closestool in tough stains.
The addition of essential oil improves the delicate fragrance degree of Closestool cleanser, effectively purifies the air of toilet.
The formula of Closestool cleanser provided by the invention is gentle, can be made respectively as solvent using 75% ethanol and distilled water Raw material fully dissolves, and obtained product viscosity is suitable, and each raw material, which cooperates, can effectively play the work of antibacterial decontamination de-sludging With, and it is easy to safety and environmental protection of degrading.
Compared with prior art, Closestool cleanser provided by the invention removes toilet grime and with suppression with quick The degerming effect of bacterium, one punching of a spray can purify closestool, and fast and easy is succinct.
Embodiment
With reference to embodiment, the present invention is described in detail.
Embodiment 1
A kind of Closestool cleanser, includes the raw material of following parts by weight:
The fungicide is by trichlorine is non-, benzalkonium bromide, dimethyl oxazolidine are according to weight ratio 1:0.5:1.0 composition.
The fruits and vegetables zymotic fluid includes the raw material of following parts by weight:8 parts of aloe, 15 parts of pomelo peel, 15 parts of orange peel, lemon 20 parts of lemon;Each raw material of formula ratio is crushed, 8 times of water progress anaerobic fermentations is added and can obtain the fruits and vegetables zymotic fluid in 10 days.
The preparation method of the Closestool cleanser is:
(1) distilled water of formula ratio and 75% ethanol are mixed and heated to 50 DEG C, add match somebody with somebody thereto while agitating The methyl sodiosul foaliphatate just measured, neopelex, lauramide third class amine oxide, fatty alcohol polyoxyethylene ether, Heating stirring is to being completely dissolved, and natural cooling;
(2) citric acid, sodium hypochlorite, light-coloured vinegar, the fruits and vegetables zymotic fluid of formula ratio are added into step (1), is mixed equal It is even;
(3) fungicide and essential oil of formula ratio will be added in step (2), is mixed evenly that to can obtain the closestool clear Clean dose.
Embodiment 2
A kind of Closestool cleanser, includes the raw material of following parts by weight:
The fungicide is by trichlorine is non-, benzalkonium bromide, dimethyl oxazolidine are according to weight ratio 1:0.3:1.2 composition.
The fruits and vegetables zymotic fluid includes the raw material of following parts by weight:5 parts of aloe, 10 parts of pomelo peel, 10 parts of orange peel, lemon 15 parts of lemon;Each raw material of formula ratio is crushed, 5 times of water progress anaerobic fermentations is added and can obtain the fruits and vegetables zymotic fluid in 10 days.
The preparation method of the Closestool cleanser is:
(1) distilled water of formula ratio and 75% ethanol are mixed and heated to 55 DEG C, add match somebody with somebody thereto while agitating The methyl sodiosul foaliphatate just measured, neopelex, lauramide third class amine oxide, fatty alcohol polyoxyethylene ether, Heating stirring is to being completely dissolved, and natural cooling;
(2) citric acid, sodium hypochlorite, light-coloured vinegar, the fruits and vegetables zymotic fluid of formula ratio are added into step (1), is mixed equal It is even;
(3) fungicide and essential oil of formula ratio will be added in step (2), is mixed evenly that to can obtain the closestool clear Clean dose.
Embodiment 3
A kind of Closestool cleanser, includes the raw material of following parts by weight:
The fungicide is by trichlorine is non-, benzalkonium bromide, dimethyl oxazolidine are according to weight ratio 1:0.6:0.8 composition.
The fruits and vegetables zymotic fluid includes the raw material of following parts by weight:10 parts of aloe, 30 parts of pomelo peel, 30 parts of orange peel, lemon 25 parts of lemon;Each raw material of formula ratio is crushed, 10 times of water progress anaerobic fermentations is added and can obtain the fruits and vegetables zymotic fluid in 7 days.
The preparation method of the Closestool cleanser is:
(1) distilled water of formula ratio and 75% ethanol are mixed and heated to 45 DEG C, add match somebody with somebody thereto while agitating The methyl sodiosul foaliphatate just measured, neopelex, lauramide third class amine oxide, fatty alcohol polyoxyethylene ether, Heating stirring is to being completely dissolved, and natural cooling;
(2) citric acid, sodium hypochlorite, light-coloured vinegar, the fruits and vegetables zymotic fluid of formula ratio are added into step (1), is mixed equal It is even;
(3) fungicide and essential oil of formula ratio will be added in step (2), is mixed evenly that to can obtain the closestool clear Clean dose.
Comparative example 1
Other simply wherein eliminate lauramide third class amine oxide, fatty alcohol polyoxyethylene ether component with embodiment 1.
Comparative example 2
Other simply wherein eliminate fruits and vegetables zymotic fluid with embodiment 1.
Comparative example 3
Other are with embodiment 1, and simply the proportioning of fungicide therein is that trichlorine is non-:Benzalkonium bromide:Dimethyl dislikes=1: 0.1:1.4.
After the Closestool cleanser cleaning closestool obtained using embodiment 1~3, comparative example 1~3, quickly surveyed using bacterium Test paper detects toilet bowl interior, finds embodiment 1~3 and the toilet bowl interior noresidue bacterium that comparative example 1~2 cleans, and compares The toilet bowl interior cleaned compared with example 3 has slightly remaining bacteria.
Choose the stain removal and scale removal for the Closestool cleanser that 120 volunteers obtain various embodiments of the present invention and comparative example Property is evaluated, and 10 points are best result, and evaluation result is as shown in table 1:
Table 1
The above-mentioned detailed description carried out to Closestool cleanser and preparation method thereof with reference to embodiment, be it is illustrative rather than Limited, several embodiments, therefore the change in the case where not departing from present general inventive concept can be included according to limited scope Change and change, should belong within protection scope of the present invention.

Claims (8)

1. a kind of Closestool cleanser, it is characterised in that include the raw material of following parts by weight:
2. Closestool cleanser according to claim 1, it is characterised in that include the raw material of following parts by weight:
3. Closestool cleanser according to claim 1 or 2, it is characterised in that the methyl sodiosul foaliphatate is carbochain In C14/16Or C14Following methyl sodiosul foaliphatate.
4. Closestool cleanser according to claim 1 or 2, it is characterised in that the fungicide is by trichlorine is non-, benzene pricks bromine Ammonium, dimethyl oxazolidine are according to weight ratio 1:(0.3~0.6):(0.8~1.2) form.
5. Closestool cleanser according to claim 1 or 2, it is characterised in that the fruits and vegetables zymotic fluid includes following heavy Measure the raw material of part:5~10 parts of aloe, 10~30 parts of pomelo peel, 10~30 parts of orange peel, 15~25 parts of lemon.
6. Closestool cleanser according to claim 4, it is characterised in that the preparation method of the fruits and vegetables zymotic fluid is:Will Each raw material of formula ratio crushes, and adds 5~10 times of water and carries out anaerobic fermentation 7~10 days.
7. Closestool cleanser according to claim 1 or 2, it is characterised in that the essential oil includes Rosa Damascana, cloves essence Oil, Lavender, refined jasmine oil, chamomile essential oil, lemon, in one's early teens orange essential oil, one kind in essential oil.
8. the preparation method of Closestool cleanser according to claim 1 or 2, it is characterised in that the preparation method includes Following steps:
(1) distilled water of formula ratio and 75% ethanol are mixed and heated to 45~55 DEG C, add match somebody with somebody thereto while agitating The methyl sodiosul foaliphatate just measured, neopelex, lauramide third class amine oxide, fatty alcohol polyoxyethylene ether, Heating stirring is to being completely dissolved, and natural cooling;
(2) citric acid, sodium hypochlorite, light-coloured vinegar, the fruits and vegetables zymotic fluid of formula ratio are added into step (1), is mixed evenly;
(3) fungicide and essential oil of formula ratio will be added in step (2), is mixed evenly and can obtain the detergent of closet Agent.
CN201711418048.4A 2017-12-25 2017-12-25 Closestool cleanser and preparation method thereof Withdrawn CN108004047A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711418048.4A CN108004047A (en) 2017-12-25 2017-12-25 Closestool cleanser and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711418048.4A CN108004047A (en) 2017-12-25 2017-12-25 Closestool cleanser and preparation method thereof

Publications (1)

Publication Number Publication Date
CN108004047A true CN108004047A (en) 2018-05-08

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110484375A (en) * 2019-09-07 2019-11-22 阜阳洁平日化有限公司 One kind is high performance to be quantitatively sustained bottled detergent for toilet and preparation method thereof
CN110934151A (en) * 2019-10-28 2020-03-31 许伟健 Novel disinfectant fluid
CN114736742A (en) * 2022-05-10 2022-07-12 珠海市合顺兴日化股份有限公司 A novel toilet cleaner and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102296004A (en) * 2011-07-26 2011-12-28 山东丽波日化股份有限公司 Paste washing agent for cleaning hard surfaces in kitchen and preparation method thereof
CN106635560A (en) * 2016-12-24 2017-05-10 叶宗瑞 Environment-friendly antibacterial toilet detergent and preparation method thereof
CN106753907A (en) * 2016-11-23 2017-05-31 温州兴南环保科技有限公司 A kind of environment-friendly type detergent and preparation method thereof
CN107312633A (en) * 2017-06-24 2017-11-03 张强 A kind of detergent for toilet

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102296004A (en) * 2011-07-26 2011-12-28 山东丽波日化股份有限公司 Paste washing agent for cleaning hard surfaces in kitchen and preparation method thereof
CN106753907A (en) * 2016-11-23 2017-05-31 温州兴南环保科技有限公司 A kind of environment-friendly type detergent and preparation method thereof
CN106635560A (en) * 2016-12-24 2017-05-10 叶宗瑞 Environment-friendly antibacterial toilet detergent and preparation method thereof
CN107312633A (en) * 2017-06-24 2017-11-03 张强 A kind of detergent for toilet

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王磊: "《化学与生活(选修)教师用书》", 30 April 2005, 山东科学技术出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110484375A (en) * 2019-09-07 2019-11-22 阜阳洁平日化有限公司 One kind is high performance to be quantitatively sustained bottled detergent for toilet and preparation method thereof
CN110934151A (en) * 2019-10-28 2020-03-31 许伟健 Novel disinfectant fluid
CN114736742A (en) * 2022-05-10 2022-07-12 珠海市合顺兴日化股份有限公司 A novel toilet cleaner and preparation method thereof

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Application publication date: 20180508