CN108003535A - A kind of high tenacity acryl plates and preparation method thereof - Google Patents
A kind of high tenacity acryl plates and preparation method thereof Download PDFInfo
- Publication number
- CN108003535A CN108003535A CN201711420526.5A CN201711420526A CN108003535A CN 108003535 A CN108003535 A CN 108003535A CN 201711420526 A CN201711420526 A CN 201711420526A CN 108003535 A CN108003535 A CN 108003535A
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- Prior art keywords
- glass fibre
- acryl
- butyl acrylate
- acrylate
- resin monomer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
A kind of high tenacity acryl plates, by weight including following components：0.5% cyano methyl formate, 1% chloromethyl acetate, 1.7% dimethacrylate diethanol, 2% modification acrylate, 1.8% ethyl propylene acid esters, 8% epoxy acrylate, 0.5% butyl acrylate, 0.5% trimethoxy silane, 0.5% magnesium stearate, 25% glass fibre, acryl resin monomer to 100%；The acryl resin monomer is made of the mixture of butyl acrylate and polymethyl methacrylate, and wherein the percentage by weight of butyl acrylate and polymethyl methacrylate is 1:5；The mutually random interleaved arrangement of the glass fibre is into honeycomb laminated structure.
Description
Technical field
The present invention is related to more particularly to a kind of high tenacity acryl plates and preparation method thereof.
Background technology
Existing acryl plates have the function of that chemical stability, easy dyeing etc. be excellent and characteristic, but its toughness is but
It is slightly insufficient, it directly affects the use of acrylic to a certain extent.
The content of the invention
To solve the above-mentioned problems, the present invention provides a kind of high tenacity acryl plates：
A kind of high tenacity acryl plates, by weight including following components：
0.5% cyano methyl formate, 1% chloromethyl acetate, 1.7% dimethacrylate diethanol, 2-3% modified propylenes
Acid esters, 1.8% ethyl propylene acid esters, 8% epoxy acrylate, 0.5% butyl acrylate, 0.5% trimethoxy silane,
0.5% magnesium stearate, 25% glass fibre, acryl resin monomer to 100%；
The acryl resin monomer is made of the mixture of butyl acrylate and polymethyl methacrylate, wherein propylene
The percentage by weight of acid butyl ester and polymethyl methacrylate is 1:5；The mutually random interleaved arrangement of the glass fibre is into bee
Nest laminated structure.
Preferably, a kind of high tenacity acryl plates, by weight including following components：
0.5% cyano methyl formate, 1% chloromethyl acetate, 1.7% dimethacrylate diethanol, 2.6% modified propylene
Acid esters, 1.8% ethyl propylene acid esters, 8% epoxy acrylate, 0.5% butyl acrylate, 0.5% trimethoxy silane,
0.5% magnesium stearate, 25% glass fibre, acryl resin monomer to 100%.
A kind of preparation method of high tenacity acryl plates, step are as follows：
S1：Cyano methyl formate, chloromethyl acetate, dimethacrylate diethanol, acryl resin monomer are added anti-
Answer in kettle, it is 120 DEG C that heating, which keeps temperature, adherence pressure to 2MPA, is taken out after stirring 3h and obtains acrylic moulding compound, by its point
For two parts；
S2：First glass fibre is added in cellular mould, adding acrylic moulding compound makes glass fibre mutual
Random interleaved arrangement congeals into the glass fiber sheets of honeycomb laminated structure, then glass fiber sheets are filled into acrylic board mould
In；
S3：By modification acrylate, ethyl propylene acid esters, epoxy acrylate, butyl acrylate, trimethoxy silane,
Magnesium stearate, acrylic moulding compound are put into reaction kettle, in 165 DEG C, the pressure of 35MPa, are poured into after being stirred continuously 2h in mould
With glass fiber sheets adhesive solidification, acryl plates are obtained.
The present invention has the advantages that：Acrylic board is formed by the glass fiber sheets in honeycomb laminated structure
Skeleton, substantially increases its toughness and intensity, and the process made is simple, is particularly suitable for industrialized production.
Embodiment
The present invention is further described with reference to embodiment.
Embodiment 1：A kind of high tenacity acryl plates, by weight including following components：
0.5% cyano methyl formate, 1% chloromethyl acetate, 1.7% dimethacrylate diethanol, 2% modified acroleic acid
Ester, 1.8% ethyl propylene acid esters, 8% epoxy acrylate, 0.5% butyl acrylate, 0.5% trimethoxy silane, 0.5%
Magnesium stearate, 25% glass fibre, acryl resin monomer to 100%；
The acryl resin monomer is made of the mixture of butyl acrylate and polymethyl methacrylate, wherein propylene
The percentage by weight of acid butyl ester and polymethyl methacrylate is 1:5；The mutually random interleaved arrangement of the glass fibre is into bee
Nest laminated structure.
Embodiment 2：A kind of high tenacity acryl plates, by weight including following components：
0.5% cyano methyl formate, 1% chloromethyl acetate, 1.7% dimethacrylate diethanol, 2.6% modified propylene
Acid esters, 1.8% ethyl propylene acid esters, 8% epoxy acrylate, 0.5% butyl acrylate, 0.5% trimethoxy silane,
0.5% magnesium stearate, 25% glass fibre, acryl resin monomer to 100%.
The acryl resin monomer is made of the mixture of butyl acrylate and polymethyl methacrylate, wherein propylene
The percentage by weight of acid butyl ester and polymethyl methacrylate is 1:5；The mutually random interleaved arrangement of the glass fibre is into bee
Nest laminated structure.
Embodiment 3：A kind of high tenacity acryl plates, by weight including following components：
0.5% cyano methyl formate, 1% chloromethyl acetate, 1.7% dimethacrylate diethanol, 3% modified acroleic acid
Ester, 1.8% ethyl propylene acid esters, 8% epoxy acrylate, 0.5% butyl acrylate, 0.5% trimethoxy silane, 0.5%
Magnesium stearate, 25% glass fibre, acryl resin monomer to 100%.
The acryl resin monomer is made of the mixture of butyl acrylate and polymethyl methacrylate, wherein propylene
The percentage by weight of acid butyl ester and polymethyl methacrylate is 1:5；The mutually random interleaved arrangement of the glass fibre is into bee
Nest laminated structure.
A kind of preparation method of high tenacity acryl plates, step are as follows：
S1：Cyano methyl formate, chloromethyl acetate, dimethacrylate diethanol, acryl resin monomer are added anti-
Answer in kettle, it is 120 DEG C that heating, which keeps temperature, adherence pressure to 2MPA, is taken out after stirring 3h and obtains acrylic moulding compound, by its point
For two parts；
S2：First glass fibre is added in cellular mould, adding acrylic moulding compound makes glass fibre mutual
Random interleaved arrangement congeals into the glass fiber sheets of honeycomb laminated structure, then glass fiber sheets are filled into acrylic board mould
In；
S3：By modification acrylate, ethyl propylene acid esters, epoxy acrylate, butyl acrylate, trimethoxy silane,
Magnesium stearate, acrylic moulding compound are put into reaction kettle, in 165 DEG C, the pressure of 35MPa, are poured into after being stirred continuously 2h in mould
With glass fiber sheets adhesive solidification, acryl plates are obtained.
The skeleton of acrylic board is made up of the glass fiber sheets in honeycomb laminated structure, substantially increase its toughness with
Intensity, and the process made is simple, is particularly suitable for industrialized production.
Obviously, the above embodiment of the present invention is intended to be merely illustrative of the present example, and not to the present invention
Embodiment restriction.For those of ordinary skill in the field, can also make on the basis of the above description
Other various forms of changes or variation.There is no need and unable to give poor example to all embodiments.And these belong to this
The connotation changes and variations that derived from of invention still fall within protection scope of the present invention.
Claims (3)
1. a kind of high tenacity acryl plates, it is characterised in that by weight including following components：
0.5% cyano methyl formate, 1% chloromethyl acetate, 1.7% dimethacrylate diethanol, 2-3% modified acroleic acids
Ester, 1.8% ethyl propylene acid esters, 8% epoxy acrylate, 0.5% butyl acrylate, 0.5% trimethoxy silane, 0.5%
Magnesium stearate, 25% glass fibre, acryl resin monomer to 100%；
The acryl resin monomer is made of the mixture of butyl acrylate and polymethyl methacrylate, wherein acrylic acid fourth
The percentage by weight of ester and polymethyl methacrylate is 1:5；The mutually random interleaved arrangement of the glass fibre is into honeycomb piece
Shape structure.
2. a kind of high tenacity acryl plates according to claim 1, it is characterised in that by weight including following groups
Point：
0.5% cyano methyl formate, 1% chloromethyl acetate, 1.7% dimethacrylate diethanol, 2.6% modified acroleic acid
Ester, 1.8% ethyl propylene acid esters, 8% epoxy acrylate, 0.5% butyl acrylate, 0.5% trimethoxy silane, 0.5%
Magnesium stearate, 25% glass fibre, acryl resin monomer to 100%.
A kind of 3. method for the acryl plates for preparing the high tenacity described in claim 1, it is characterised in that step is as follows：
S1：Cyano methyl formate, chloromethyl acetate, dimethacrylate diethanol, acryl resin monomer are added into reaction kettle
In, it is 120 DEG C that heating, which keeps temperature, adherence pressure to 2MPA, is taken out after stirring 3h and obtains acrylic moulding compound, is classified as two
Part；
S2：First glass fibre is added in cellular mould, adding acrylic moulding compound makes glass fibre mutually random
Then interleaved arrangement congeals into the glass fiber sheets of honeycomb laminated structure, then glass fiber sheets are filled into acrylic board mould；
S3：By modification acrylate, ethyl propylene acid esters, epoxy acrylate, butyl acrylate, trimethoxy silane, tristearin
Sour magnesium, acrylic moulding compound are put into reaction kettle, in 165 DEG C, the pressure of 35MPa, be stirred continuously after 2h pour into mould with glass
Glass fibre plate adhesive solidification, obtains acryl plates.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711420526.5A CN108003535A (en) | 2017-12-25 | 2017-12-25 | A kind of high tenacity acryl plates and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711420526.5A CN108003535A (en) | 2017-12-25 | 2017-12-25 | A kind of high tenacity acryl plates and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN108003535A true CN108003535A (en) | 2018-05-08 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711420526.5A Pending CN108003535A (en) | 2017-12-25 | 2017-12-25 | A kind of high tenacity acryl plates and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108997693A (en) * | 2018-06-25 | 2018-12-14 | 安徽源美广告传媒有限公司 | A kind of novel acrylic plate |
| CN112724568A (en) * | 2020-12-28 | 2021-04-30 | 安徽金亮新型材料有限公司 | Acrylic plate with excellent bending performance and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103112203A (en) * | 2013-03-07 | 2013-05-22 | 辽阳艺蒙织毯有限公司 | Honeycomb core board |
| CN106398076A (en) * | 2016-11-09 | 2017-02-15 | 安徽新胜塑料科技有限公司 | Highly tenacious acrylic board |
| CN106543616A (en) * | 2016-11-09 | 2017-03-29 | 安徽新胜塑料科技有限公司 | A kind of high-quality acrylic board of heat-resistant, wear-resistant and preparation method thereof |
| CN107254132A (en) * | 2017-06-06 | 2017-10-17 | 苍南县通普工艺礼品有限公司 | A kind of stable type acrylic diamond and preparation method thereof |
-
2017
- 2017-12-25 CN CN201711420526.5A patent/CN108003535A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103112203A (en) * | 2013-03-07 | 2013-05-22 | 辽阳艺蒙织毯有限公司 | Honeycomb core board |
| CN106398076A (en) * | 2016-11-09 | 2017-02-15 | 安徽新胜塑料科技有限公司 | Highly tenacious acrylic board |
| CN106543616A (en) * | 2016-11-09 | 2017-03-29 | 安徽新胜塑料科技有限公司 | A kind of high-quality acrylic board of heat-resistant, wear-resistant and preparation method thereof |
| CN107254132A (en) * | 2017-06-06 | 2017-10-17 | 苍南县通普工艺礼品有限公司 | A kind of stable type acrylic diamond and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108997693A (en) * | 2018-06-25 | 2018-12-14 | 安徽源美广告传媒有限公司 | A kind of novel acrylic plate |
| CN112724568A (en) * | 2020-12-28 | 2021-04-30 | 安徽金亮新型材料有限公司 | Acrylic plate with excellent bending performance and preparation method thereof |
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Application publication date: 20180508 |