CN108003370A - PET bottle for containing pesticide and preparation method thereof - Google Patents
PET bottle for containing pesticide and preparation method thereof Download PDFInfo
- Publication number
- CN108003370A CN108003370A CN201711499598.3A CN201711499598A CN108003370A CN 108003370 A CN108003370 A CN 108003370A CN 201711499598 A CN201711499598 A CN 201711499598A CN 108003370 A CN108003370 A CN 108003370A
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- Prior art keywords
- pet bottle
- pesticide
- bottle
- pet
- preparation
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/06—Coating with compositions not containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides a kind of PET bottle for being used to contain pesticide and preparation method thereof, is related to packing container technical field, and the inner wall of the PET bottle for containing pesticide is provided with silicon dioxide drainage coating.Bottle containing above-mentioned silicon dioxide drainage coating, sticks viscous material even if containing, will not be sticked to inside bottle very much, and once with regard to that can topple over more than 99.5%, remaining part adds a small amount of clear water, jiggle it is several under, then just can thoroughly remove.At the same time, the silica of the hydrophobic coating is inorganic material, chemical reaction will not be produced during pesticide storage with pesticide, with higher safety in utilization, and then effectively alleviate that existing bottled pesticide liquid is not easy outflow and existing coating of organic material is easy to produce reaction with pesticide, security and it is uncertain the problem of.
Description
Technical field
The present invention relates to packing container technical field, more particularly, to a kind of PET bottle and its preparation for being used to contain pesticide
Method.
Background technology
The many biological surfaces of nature all possess special moistened surface behavior.Researcher has found, water droplet is dripped in lotus leaf
Upper surface, rice leaf upper surface, water skipper above can obtain the contact angle more than 150 ° enough.It is this that the anti-profit of excess of export is showed to water droplet
Moist surface is referred to as super hydrophobic surface.Found through further scientific research, these biological surfaces are respectively provided with micro-scale
Coarse structure, when these microstructures make the water droplet be contacted with surface can not complete wetting surface, air retained in microcosmic knot
So as to form air bag inside structure, due to the presence of air bag, water droplet can slip away from surface easily.Due to its special surface
Resist wet behavior, super hydrophobic surface have the characteristics that waterproof, automatically cleaning.
The container containing of Pesticidal products typically uses common PET material and is prepared at present.Used in actual
Cheng Zhong, we have such experience, are exactly difficult to pour out remaining liquid, it is often necessary in after bottle inversion a period of time
The remaining pesticide in face could flow out, and such case frequently can lead to the waste of pesticide, and the recycling of the PET bottle to containing pesticide
Processing brings very big difficulty, and then the pesticide in bottle also can produce serious pollution problem to environment.In recent years, for upper
State problem and also occur some for solving the hydrophobic coating that bottling liquid is not easy to flow out.But these hydrophobic coating majorities are
Coating of organic material, such as fluorine material or organic solvent etc., these coating of organic material are easy to produce reaction, peace with pesticide
Full property is not known simultaneously, so limiting application of these coating of organic material in pesticides packaging field of containers.
Therefore, a kind of PET bottle with inorganic material hydrophobic coating is researched and developed, alleviates existing bottled pesticide liquid not
The problem of easily flowing out, and the security of storage is improved, become very necessary and urgent.
In view of this, it is special to propose the present invention.
The content of the invention
The first object of the present invention is to provide a kind of PET bottle for being used to contain pesticide, the PET bottle for containing pesticide
Inner wall is provided with silicon dioxide drainage coating.Bottle containing above-mentioned silicon dioxide drainage coating, sticks what is glued very much even if containing
Material, will not be sticked to inside bottle, and once with regard to that can topple over more than 99.5%, remaining part adds a small amount of clear water, gently
Under jog rolling is several, then just can thoroughly it remove.Meanwhile the silica of the hydrophobic coating is inorganic material, is stored in pesticide
Chemical reaction will not be produced with pesticide in journey, there is higher safety in utilization, and then effectively alleviate existing bottled pesticide
Liquid is not easy outflow and existing coating of organic material is easy to produce reaction with pesticide, security and it is uncertain the problem of.
The second object of the present invention is to provide a kind of preparation method of the PET bottle for being used to contain pesticide, the preparation
Silicon dioxde solution is injected bottle by method at twice after the injection bottle embryo and drawing and forming link in traditional PET bottle preparation process
In and heating cure, the PET bottle for containing pesticide is made.This method has that procedure of processing is few, easy to operate and preparing
During the advantages of special process equipment is not required, be very suitable for large batch of industrialized production processing.
A kind of PET bottle for being used to contain pesticide provided by the invention, the inner wall of the PET bottle for containing pesticide are provided with two
Silica hydrophobic coating.
Further, the silicon dioxide drainage coating is to be attached to splendid attire pesticide by the heated curing of silicon dioxde solution
PET bottle inner wall.
Further, the silicon dioxde solution is made of nanosized silica particles and solvent.
Further, the particle diameter of the nanosized silica particles is 50~80nm.
Further, the solvent is any one of ethanol, methanol, isopropanol or glycerine.
It is provided by the invention it is a kind of it is above-mentioned be used for contain pesticide PET bottle preparation method, the preparation method include with
Lower step：
(a) first by PET raw materials heat drying 4~8 it is small when, be then molded into bottle embryo；
(b) silicon dioxde solution is injected in bottle embryo, its liquid is evenly affixed to bottle embryo inner wall, then pour out liquid
Dry, bottle embryo is then subjected to heat drying 4~after five minutes, is put into drawing and forming in bottle blowing machine mould, PET bottle body is made；
(c) silicon dioxde solution to be poured into PET bottle body made from step (b), lean-in 45 ° of rotations are enclosed no less than one,
180 ° of handstand are dried for 8~12 minutes still further below, and PET bottle body then is positioned over UV light consolidates in stove, are carried out inside coating curing, are obtained
To the PET bottle for containing pesticide.
Further, the temperature of step (b) heat drying is 100~200 DEG C.
Further, the ultraviolet wavelength that the UV light consolidates stove is 260~400nm.
Further, the solidification temperature that the UV light consolidates stove is 40~50 DEG C.
Further, the preparation method specifically includes following steps：
(a) first by PET raw materials heat drying 4~8 it is small when, be then molded into bottle embryo；
(b) silicon dioxde solution is injected in bottle embryo, its liquid is evenly affixed to bottle embryo inner wall, then pour out liquid
Dry, bottle embryo is then subjected to the heat drying 4~after five minutes at a temperature of 100~200 DEG C, be put into bottle blowing machine mould and draw
Type is stretched into, PET bottle body is made；
(c) silicon dioxde solution to be poured into PET bottle body made from step (b), lean-in 45 ° of rotations are enclosed no less than one,
Stand upside down and dry for 8~12 minutes for 180 ° still further below, PET bottle body then is positioned over UV light consolidate in stove, ultraviolet wavelength be 260~
400nm, under conditions of solidification temperature is 40~50 DEG C, carries out inside coating curing to PET bottle body, obtains for containing pesticide
PET bottle.
Compared with prior art, beneficial effects of the present invention are：
A kind of PET bottle for being used to contain pesticide provided by the invention, the inner wall of the PET bottle for containing pesticide are provided with two
Silica hydrophobic coating.Bottle containing above-mentioned silicon dioxide drainage coating, sticks viscous material even if containing, will not glue very much
Inside bottle, once just can topple over more than 99.5%, remaining part adds a small amount of clear water, jiggle it is several under, so
Just can thoroughly it remove afterwards., will not be with pesticide during pesticide storage meanwhile the silica of the hydrophobic coating is inorganic material
Produce chemical reaction, there is higher safety in utilization, so effectively alleviate existing bottled pesticide liquid be not easy flow out with
And existing coating of organic material is easy to produce reaction with pesticide, security and it is uncertain the problem of.
A kind of preparation method of PET bottle for being used to contain pesticide provided by the invention, the preparation method is in traditional PET bottle system
Silicon dioxde solution is injected into simultaneously heating cure in bottle at twice after injection bottle embryo and drawing and forming link during standby, is made
For containing the PET bottle of pesticide.This method have procedure of processing it is few, it is easy to operate and be not required in preparation process it is special
The advantages of process equipment, be very suitable for large batch of industrialized production processing.
Embodiment
Technical scheme is clearly and completely described below in conjunction with embodiment, it is clear that described reality
It is part of the embodiment of the present invention to apply example, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this area
Art personnel all other embodiments obtained without making creative work, belong to the model that the present invention protects
Enclose.
According to an aspect of the present invention, it is a kind of to be used to containing the PET bottle of pesticide, the PET bottle for containing pesticide it is interior
Wall is provided with silicon dioxide drainage coating.
The present invention is used for the PET bottle for containing pesticide, and the inner wall of the PET bottle for containing pesticide is provided with silicon dioxide drainage
Coating.The silica of the hydrophobic coating is inorganic material, will not produce chemical reaction, tool with pesticide during pesticide storage
There is higher safety in utilization, and then effectively alleviate existing bottled pesticide liquid and be not easy outflow and existing organic material
Coating is easy to produce reaction with pesticide, security and it is uncertain the problem of.
In the preferred embodiment of the present invention, the silicon dioxide drainage coating is through adding by silicon dioxde solution
Temperature curing is attached to the PET bottle inner wall of splendid attire pesticide.
As a preferred embodiment, the present invention is adhered to silicon dioxide drainage coating using the method for heating cure
In the PET bottle inner wall for containing pesticide, have the advantages that method is simple, process equipment and step that need not be complicated in process
Suddenly.
In the preferred embodiment of the present invention, the silicon dioxde solution by nanosized silica particles with it is molten
Agent forms.
As a preferred embodiment, above-mentioned silicon dioxde solution is by nanosized silica particles and solvent group
Into.The coating that above-mentioned nanosized silica particles are prepared has the advantages that transparency is high.
In above-mentioned preferred embodiment, the particle diameter of the nanosized silica particles is 50~80nm.
In the present invention, the particle diameter of above-mentioned nanosized silica particles it is typical but it is infinite for 50nm, 60nm, 70nm or
80nm。
Preferably, the particle diameter of above-mentioned nanosized silica particles is 60nm.
In above-mentioned preferred embodiment, the solvent is any one of ethanol, methanol, isopropanol or glycerine.
According to an aspect of the present invention, a kind of preparation method of the above-mentioned PET bottle for being used to contain pesticide, the preparation side
Method comprises the following steps：
(a) first by PET raw materials heat drying 4~8 it is small when, be then molded into bottle embryo；
(b) silicon dioxde solution is injected in bottle embryo, its liquid is evenly affixed to bottle embryo inner wall, then pour out liquid
Dry, bottle embryo is then subjected to heat drying 4~after five minutes, is put into drawing and forming in bottle blowing machine mould, PET bottle body is made；
(c) silicon dioxde solution to be poured into PET bottle body made from step (b), lean-in 45 ° of rotations are enclosed no less than one,
180 ° of handstand are dried for 8~12 minutes still further below, and PET bottle body then is positioned over UV light consolidates in stove, are carried out inside coating curing, are obtained
To the PET bottle for containing pesticide.
The preparation method of the above-mentioned PET bottle for being used to contain pesticide of the present invention, the injection moulding bottle in traditional PET bottle preparation process
Silicon dioxde solution is injected into simultaneously heating cure in bottle at twice after embryo and drawing and forming link, is made for containing pesticide
PET bottle.This method has that procedure of processing is few, easy to operate and the excellent of special process equipment is not required in preparation process
Point, is very suitable for large batch of industrialized production processing.
In the preferred embodiment of the present invention, the temperature of step (b) heat drying is 100~200 DEG C.
Preferably, the temperature of above-mentioned steps (b) heat drying is 150 DEG C.
In the preferred embodiment of the present invention, the ultraviolet wavelength that the UV light consolidates stove is 260~400nm.
Preferably, the ultraviolet wavelength that above-mentioned UV light consolidates stove is 320nm.
In the preferred embodiment of the present invention, the solidification temperature that the UV light consolidates stove is 40~50 DEG C.
Preferably, the solidification temperature that above-mentioned UV light consolidates stove is 45 DEG C.
In the preferred embodiment of the present invention, the preparation method specifically includes following steps：
(a) first by PET raw materials heat drying 4~8 it is small when, be then molded into bottle embryo；
(b) silicon dioxde solution is injected in bottle embryo, its liquid is evenly affixed to bottle embryo inner wall, then pour out liquid
Dry, bottle embryo is then subjected to the heat drying 4~after five minutes at a temperature of 100~200 DEG C, be put into bottle blowing machine mould and draw
Type is stretched into, PET bottle body is made；
(c) silicon dioxde solution to be poured into PET bottle body made from step (b), lean-in 45 ° of rotations are enclosed no less than one,
Stand upside down and dry for 8~12 minutes for 180 ° still further below, PET bottle body then is positioned over UV light consolidate in stove, ultraviolet wavelength be 260~
400nm, under conditions of solidification temperature is 40~50 DEG C, carries out inside coating curing to PET bottle body, obtains for containing pesticide
PET bottle.
Technical scheme is described further below in conjunction with embodiment.
Embodiment 1
A kind of preparation method for the PET bottle for being used to contain pesticide, the preparation method specifically include following steps：
(a) first by PET raw materials heat drying 4 it is small when, be then molded into bottle embryo；
(b) silicon dioxde solution is injected in bottle embryo, its liquid is evenly affixed to bottle embryo inner wall, then pour out liquid
Dry, after bottle embryo is then carried out at a temperature of 100 DEG C heat drying 4 minutes, be put into drawing and forming in bottle blowing machine mould, make
Obtain PET bottle body；
(c) silicon dioxde solution to be poured into PET bottle body made from step (b), lean-in 45 ° of rotations are enclosed no less than one,
180 ° of handstand are dried for 8 minutes still further below, and PET bottle body then is positioned over UV light consolidates in stove, is 260nm in ultraviolet wavelength, are cured
Under conditions of temperature is 40 DEG C, inside coating curing is carried out to PET bottle body, obtains the PET bottle for containing pesticide.
Embodiment 2
A kind of preparation method for the PET bottle for being used to contain pesticide, the preparation method specifically include following steps：
(a) first by PET raw materials heat drying 8 it is small when, be then molded into bottle embryo；
(b) silicon dioxde solution is injected in bottle embryo, its liquid is evenly affixed to bottle embryo inner wall, then pour out liquid
Dry, bottle embryo then is carried out the heat drying at a temperature of 200 DEG C after five minutes, is put into drawing and forming in bottle blowing machine mould, makes
Obtain PET bottle body；
(c) silicon dioxde solution to be poured into PET bottle body made from step (b), lean-in 45 ° of rotations are enclosed no less than one,
180 ° of handstand are dried for 12 minutes still further below, and PET bottle body then is positioned over UV light consolidates in stove, is 400nm in ultraviolet wavelength, are cured
Under conditions of temperature is 50 DEG C, inside coating curing is carried out to PET bottle body, obtains the PET bottle for containing pesticide.
Embodiment 3
A kind of preparation method for the PET bottle for being used to contain pesticide, the preparation method specifically include following steps：
(a) first by PET raw materials heat drying 5 it is small when, be then molded into bottle embryo；
(b) silicon dioxde solution is injected in bottle embryo, its liquid is evenly affixed to bottle embryo inner wall, then pour out liquid
Dry, after bottle embryo is then carried out at a temperature of 120 DEG C heat drying 4 minutes, be put into drawing and forming in bottle blowing machine mould, make
Obtain PET bottle body；
(c) silicon dioxde solution to be poured into PET bottle body made from step (b), lean-in 45 ° of rotations are enclosed no less than one,
180 ° of handstand are dried for 9 minutes still further below, and PET bottle body then is positioned over UV light consolidates in stove, is 300nm in ultraviolet wavelength, are cured
Under conditions of temperature is 42 DEG C, inside coating curing is carried out to PET bottle body, obtains the PET bottle for containing pesticide.
Embodiment 4
A kind of preparation method for the PET bottle for being used to contain pesticide, the preparation method specifically include following steps：
(a) first by PET raw materials heat drying 7 it is small when, be then molded into bottle embryo；
(b) silicon dioxde solution is injected in bottle embryo, its liquid is evenly affixed to bottle embryo inner wall, then pour out liquid
Dry, bottle embryo then is carried out the heat drying at a temperature of 180 DEG C after five minutes, is put into drawing and forming in bottle blowing machine mould, makes
Obtain PET bottle body；
(c) silicon dioxde solution to be poured into PET bottle body made from step (b), lean-in 45 ° of rotations are enclosed no less than one,
180 ° of handstand are dried for 11 minutes still further below, and PET bottle body then is positioned over UV light consolidates in stove, is 350nm in ultraviolet wavelength, are cured
Under conditions of temperature is 48 DEG C, inside coating curing is carried out to PET bottle body, obtains the PET bottle for containing pesticide.
Embodiment 5
A kind of preparation method for the PET bottle for being used to contain pesticide, the preparation method specifically include following steps：
(a) first by PET raw materials heat drying 6 it is small when, be then molded into bottle embryo；
(b) silicon dioxde solution is injected in bottle embryo, its liquid is evenly affixed to bottle embryo inner wall, then pour out liquid
Dry, bottle embryo then is carried out the heat drying at a temperature of 150 DEG C after five minutes, is put into drawing and forming in bottle blowing machine mould, makes
Obtain PET bottle body；
(c) silicon dioxde solution to be poured into PET bottle body made from step (b), lean-in 45 ° of rotations are enclosed no less than one,
180 ° of handstand are dried for 10 minutes still further below, and PET bottle body then is positioned over UV light consolidates in stove, is 320nm in ultraviolet wavelength, are cured
Under conditions of temperature is 45 DEG C, inside coating curing is carried out to PET bottle body, obtains the PET bottle for containing pesticide.
In conclusion the present invention is used for the PET bottle for containing pesticide, the inner wall of the PET bottle for containing pesticide is provided with two
Silica hydrophobic coating.Bottle containing above-mentioned silicon dioxide drainage coating, sticks viscous material even if containing, will not glue very much
Inside bottle, once just can topple over more than 99.5%, remaining part adds a small amount of clear water, jiggle it is several under, so
Just can thoroughly it remove afterwards., will not be with pesticide during pesticide storage meanwhile the silica of the hydrophobic coating is inorganic material
Produce chemical reaction, there is higher safety in utilization, so effectively alleviate existing bottled pesticide liquid be not easy flow out with
And existing coating of organic material is easy to produce reaction with pesticide, security and it is uncertain the problem of.
Finally it should be noted that：The above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations；To the greatest extent
Pipe is described in detail the present invention with reference to foregoing embodiments, it will be understood by those of ordinary skill in the art that：Its according to
Can so modify to the technical solution described in foregoing embodiments, either to which part or all technical characteristic into
Row equivalent substitution；And these modifications or replacement, the essence of appropriate technical solution is departed from various embodiments of the present invention technology
The scope of scheme.
Claims (10)
1. a kind of PET bottle for being used to contain pesticide, it is characterised in that the inner wall of the PET bottle for containing pesticide is provided with dioxy
SiClx hydrophobic coating.
2. the PET bottle according to claim 1 for being used to contain pesticide, it is characterised in that the silicon dioxide drainage coating
It is that the PET bottle inner wall for containing pesticide is attached to by the heated curing of silicon dioxde solution.
3. the PET bottle according to claim 1 for being used to contain pesticide, it is characterised in that the silicon dioxde solution is by receiving
Meter level silica dioxide granule is formed with solvent.
4. the PET bottle according to claim 3 for being used to contain pesticide, it is characterised in that the nanometer grade silica
The particle diameter of grain is 50~80nm.
5. according to claim 3 be used to contain the PET bottle of pesticide, it is characterised in that the solvent is ethanol, methanol,
Any one of isopropanol or glycerine.
6. a kind of preparation method for the PET bottle for being used to contain pesticide according to Claims 1 to 5 any one of them, its feature exist
In the preparation method comprises the following steps：
(a) first by PET raw materials heat drying 4~8 it is small when, be then molded into bottle embryo；
(b) silicon dioxde solution is injected in bottle embryo, its liquid is evenly affixed to bottle embryo inner wall, then liquid is poured out and is dried in the air
It is dry, bottle embryo is then subjected to heat drying 4~after five minutes, drawing and forming in bottle blowing machine mould is put into, PET bottle body is made；
(c) silicon dioxde solution to be poured into PET bottle body made from step (b), lean-in 45 ° of rotations are enclosed no less than one, then to
Lower 180 ° of handstand is dried for 8~12 minutes, and PET bottle body then is positioned over UV light consolidates in stove, carries out inside coating curing, is used
In the PET bottle for containing pesticide.
7. the preparation method of the PET bottle according to claim 6 for being used to contain pesticide, it is characterised in that the step (b)
The temperature of heat drying is 100~200 DEG C.
8. the preparation method of the PET bottle according to claim 6 for being used to contain pesticide, it is characterised in that the UV light is consolidated
The ultraviolet wavelength of stove is 260~400nm.
9. the preparation method of the PET bottle according to claim 6 for being used to contain pesticide, it is characterised in that the UV light is consolidated
The solidification temperature of stove is 40~50 DEG C.
10. the preparation method of the PET bottle according to claim 6 for being used to contain pesticide, it is characterised in that the preparation side
Method specifically includes following steps：
(a) first by PET raw materials heat drying 4~8 it is small when, be then molded into bottle embryo；
(b) silicon dioxde solution is injected in bottle embryo, its liquid is evenly affixed to bottle embryo inner wall, then liquid is poured out and is dried in the air
It is dry, bottle embryo is then subjected at a temperature of 100~200 DEG C heat drying 4~after five minutes, is put into stretching in bottle blowing machine mould
Shaping, is made PET bottle body；
(c) silicon dioxde solution to be poured into PET bottle body made from step (b), lean-in 45 ° of rotations are enclosed no less than one, then to
Lower 180 ° of handstand is dried for 8~12 minutes, and PET bottle body then is positioned over UV light consolidates in stove, is 260~400nm in ultraviolet wavelength,
Under conditions of solidification temperature is 40~50 DEG C, inside coating curing is carried out to PET bottle body, obtains the PET bottle for containing pesticide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711499598.3A CN108003370A (en) | 2017-12-29 | 2017-12-29 | PET bottle for containing pesticide and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711499598.3A CN108003370A (en) | 2017-12-29 | 2017-12-29 | PET bottle for containing pesticide and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108003370A true CN108003370A (en) | 2018-05-08 |
Family
ID=62049844
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711499598.3A Pending CN108003370A (en) | 2017-12-29 | 2017-12-29 | PET bottle for containing pesticide and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108003370A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101434709A (en) * | 2008-12-09 | 2009-05-20 | 西安交通大学 | Preparation of silastic surface hydrophobic coating |
| CN106479359A (en) * | 2016-09-28 | 2017-03-08 | 惠州市道科包装材料有限公司 | A kind of organosilicon super hydrophobic coating and its preparation method and application |
-
2017
- 2017-12-29 CN CN201711499598.3A patent/CN108003370A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101434709A (en) * | 2008-12-09 | 2009-05-20 | 西安交通大学 | Preparation of silastic surface hydrophobic coating |
| CN106479359A (en) * | 2016-09-28 | 2017-03-08 | 惠州市道科包装材料有限公司 | A kind of organosilicon super hydrophobic coating and its preparation method and application |
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Application publication date: 20180508 |