CN107982079A - A kind of haze amino acid is without silicone oil shampoo and preparation method thereof - Google Patents

Abstract

The present invention relates to a kind of haze amino acid without silicone oil shampoo and preparation method thereof, belong to daily chemical product technical field.The present invention is hydrolyzed by sericin and produces amino acid,Bonding introduces lauroyl chloride,Reach hydrophile-lipophile balance,Improve surface-active,Prepare sericin surfactant,Compounded again with Cocoamidopropyl betaine,Both produce cooperative effect,Change the micellar structure of sericin surfactant in shampoo,So that shampoo system viscosity greatly improves,And utilize sericin parcel hair,Fill up hair rough surface defect,Form smooth protective film,Prevent haze particle adhesion,Solve the problems, such as that haze is caused for hair,The amino acid supplementation hair nutrition produced at the same time by sericin hydrolysis,Substantial amounts of hydrophilic group also provides good wetting and moisture retention,Reduce the stimulation and injury to hair,Hair caused by improvement shampoo degreasing power is too strong is dry and astringent,Cardability is poor,The problems such as hair is low and deep unglazed.

Description

A kind of haze amino acid is without silicone oil shampoo and preparation method thereof

Technical field

The present invention relates to a kind of haze amino acid without silicone oil shampoo and preparation method thereof, belong to daily chemical product technology Field.

Background technology

Hair is the attached fibr tissue of human body, is the important component of human body, has Winter protection, prevents head

By physiological functions such as strong solarizations, personal image can also be beautified.Since own human civilization, hair is as appearance The one of the important signs that of bodybuilding, or even the symbol as right, hair style is also one of feature for distinguishing male and female, so head Hair receives the more concern of the mankind.Many cities are all more or less at present is influenced be subject to haze, and haze not only can be to people Health damages, while it is also most noticeable " hair killer ".At present, most of shampoo is all using a large amount of Silicone oil product reach conditioning performance.But excessive conditioner can not only deposit on hair, and mist cannot be solved The problem of haze is caused for hair.Market of Chinese Shampoo is that personal care market development is earliest, one of most fast market.Market is competing Fierceness is striven, production firm faces more pressure, it is necessary to constantly release new product and promotion method to increase market competition energy Power.Because being the faster market of development, consumer is opposite to have more ripe consumption habit, and consumption demand more becomes to segmenting Change.Shampoo on the market generally has that foam performance is poor, degreasing power is too strong and causes that hair is dry and astringent, cardability is poor, head at present Shade the problems such as mute unglazed.

With the improvement of living standards with the fast development of science and technology, people are to chemicals used in everyday particularly table The requirement of the security of face activating agent is also higher and higher.Amino acid surfactant is the gentle surface-active of a protein species Agent, has low irritant, hypotoxicity, mildness, good biodegradability properties and to preferable compatibility of human body etc., meets consumption Every demand of person, increasingly attracts people's attention.At abroad, the research for amino acid type surfactant is very long-pending Pole, many new achievements in research have been carried out commercialization, and amino acid type surfactant, which is widely used in, washes shield class product, including washes Face milk, shampoo, shower cream etc..At home, the research to amino acid type surfactant is started late and is fallen behind relatively, ammonia When base acid type surfactant is applied in cleaning class product, often it can not even be thickened in the presence of thickening difficulty so as to cause difficulty The problem of to apply, therefore, utility ratio is not also very high in hair product, skin care item and soap bath product at home for it. All big enterprises are solved by adding various high molecular polymer type thickeners at present, but are so done and can be asked there are following Topic：High temperature, which is easily led to, there is metachromatism, and the foam characteristic of amino acid type surfactant is suppressed, and skin experiences height during cleaning Molecular raw material influences, and the high price of macromolecule raw material ties up formulation cost space.

The content of the invention

The technical problems to be solved by the invention：It is generally poor, de- with foam performance for shampoo at present on the market Fat power is too strong and causes that hair is dry and astringent, cardability is poor, hair is low and deep unglazed, and amino acid type surfactant is applied to cleaning class When in product, often it can not even be thickened so that the problem of causing to be difficult to application in the presence of thickening is difficult, there is provided a kind of antifog Haze amino acid is without silicone oil shampoo and preparation method thereof.

In order to solve the above technical problems, the technical solution adopted by the present invention is：

A kind of haze amino acid is made of without silicone oil shampoo following component and its parts by weight：

18~25 parts of sericin surfactants, 8~12 parts of Cocoamidopropyl betaines, 10~15 parts of sweet ammonia of trimethyl Acid, 3~5 parts of sorbierites, 5~8 parts of glycerine, 2~3 parts of jojoba oils, 1~2 part of lanolin alcohol polyethers, 5~8 parts of decyl glucose Glycosides, 0.5~1.0 part of butanediol laurate, 0.5~1.0 part of sorbitan monostearate, 0.2~0.3 part of cellulose acetate, 0.2~0.3 part of niacinamide, 0.2~0.3 part of panthenol, 0.1~0.2 portion of preservative, 0.1~0.2 part of essence, 40~50 parts go from Sub- water.

Dialysis concentration is made after the sericin surfactant synthesizes for sericin with lauroyl chloride, reaction condition For pH be 8~9 times stirring 3~4h.

The dialysis concentration process is to be fitted into the bag filter that molecular weight is 1000~5000 to dialyse 6~8 days, every 4~8h Deionized water is replaced, it is 30% to take retention solution decompression to be concentrated by evaporation to solid content after dialysis.

The sericin merges supernatant after repeating boiling 3~5 times in sodium carbonate liquor for Silk Soaking, and concentration is saturating It is freeze-dried and is made after analysis.

The mass fraction of the sodium carbonate liquor is 5%, and the mass ratio with silk is 10：1.

It is described concentration dialysis procedure for be evaporated under reduced pressure be concentrated into merge after supernatant volume 10~20%, reenter molecular weight To dialyse 6~8 days in 1000~5000 bag filter, every 4~8h replaces deionized water, and trapped fluid is taken after dialysis.

A kind of preparation method of the haze amino acid without silicone oil shampoo, concretely comprises the following steps：

（1）It will be immersed in after silk washing and drying in sodium carbonate liquor, and be heated to 95~100 DEG C of 30~40min of boiling, centrifuged Separating must precipitate and supernatant, will precipitation repeat boiling 3~5 times after merge supernatant, be concentrated by evaporation to obtain concentrate；

（2）Trapped fluid is taken after concentrate is dialysed, trapped fluid is freeze-dried 10~20h, obtains sericin；

（3）Take sericin, lauroyl chloride to add in deionized water and be uniformly mixed, pH to 8~9 adjusted with sodium hydroxide solution, Dialyse after 3~4h of stirring, take retention solution decompression to be concentrated by evaporation, obtain sericin surfactant；

（4）Sericin surfactant, Cocoamidopropyl betaine, trimethylglycine, sorbierite, glycerine are taken, is added It is uniformly mixed in deionized water, obtains water phase；

（5）Jojoba oil, lanolin alcohol polyethers, Plantacare 818, butanediol laurate, sorbitan monostearate are taken, is put Heating stirring to solid is completely dissolved in 70~80 DEG C of water-baths, obtains oil phase；

（6）Water phase is added dropwise into oil phase with 1~2mL/min, is continued stirring until and is added dropwise with 200~300r/min, is cooled to 40~50 DEG C, cellulose acetate, niacinamide, panthenol, preservative, essence are added, continues 20~30min of stirring, obtains haze Amino acid is without silicone oil shampoo.

Compared with other methods, advantageous effects are the present invention：

（1）The present invention is hydrolyzed by sericin and produces amino acid, exposes more-NH₂,-COOH ,-OH isoreactivity bases Group, using these abundant reaction bonded points, bonding introduces lauroyl chloride, reaches hydrophile-lipophile balance, improves surface-active, system It is standby go out sericin surfactant, reaction condition is gently easily-controllable, the easily separated purifying of product, of low cost, then with coconut oleoyl amine Propyl betaine compounds, both produce cooperative effect, change the micellar structure of sericin surfactant in shampoo, So that shampoo system viscosity greatly improves, preferable washing force and foaming power are shown, foam stability energy also greatly enhances, Stablize in hard water, it is low to skin irritation close to neutrality, abundant and fine and smooth foam is produced, and there is splendid calcium soap Dispersiveness；

（2）Oil phase of the present invention is used with excellent blistering, emulsification, scattered and dirt-removing power, and nontoxic, metabolic is good, to skin Irritation is small, biodegradable rapid and thoroughly, there is a Plantacare 818 of the laudatory title of green surfactant, stronger compatibility, Cooperative effect is obvious, stronger broad spectrum antibiotic activity, and collaboration jojoba oil is configured to a kind of non-greasy, salubrious oil phase, it has Play the role of easily sprawling, lubricate, soft but non-greasy salubrious sensation is given while water loss is prevented, and make hair It is more smooth flexible；

（3）The present invention is filled up hair rough surface defect, is formed smooth protective film, prevented using sericin parcel hair Haze particle adhesion, solves the problems, such as that haze is caused for hair, while the amino acid supplementation produced by sericin hydrolysis Hair nutrition, substantial amounts of hydrophilic group also provide good wetting and moisture retention, reduce stimulation and injury to hair, improve hair washing The problems such as hair caused by shampoo degreasing power is too strong is dry and astringent, cardability is poor, hair is low and deep unglazed.

Embodiment

Silk is washed with deionized 2~3 times and is fitted into drying box, dry 1~2h, takes 200 at 55~60 DEG C ~300g silks, adding 2~3kg mass fractions is in 5% sodium carbonate liquor, and is heated to 95~100 DEG C of 30~40min of boiling, Centrifuging must precipitate and supernatant, precipitation be washed with deionized 2~3 times, then will precipitation repeat boiling 3~5 times after merge Supernatant, and reduction vaporization is concentrated into 10~20% of supernatant volume after merging, obtains concentrate, concentrate is loaded molecular weight To dialyse 6~8 days in 1000~5000 bag filter, every 4~8h replaces deionized water, and trapped fluid is taken after dialysis, will cut Stay liquid to be placed in 10~20h of freeze-drying in freeze drying box, obtain sericin, take 10~20g sericins, 30~50g bays Acyl chlorides, adds in 300~500mL deionized waters, stirs 20~30min with 300~400r/min, then with mass fraction be 5% hydrogen Sodium hydroxide solution adjusts pH to 8~9, continue to be fitted into after 3~4h of stirring in the bag filter that molecular weight is 1000~5000 dialyse 6~ 8 days, every 4~8h replaced deionized water, and it is 30% to take retention solution decompression to be concentrated by evaporation to solid content after dialysis, obtains silk gum Protein surface activating agent, takes 18~25g sericin surfactants, 8~12g Cocoamidopropyl betaines, 10~15g tri- Methylglycine, 3~5g sorbierites, 5~8g glycerine, adds in 40~50mL deionized waters, and 20 are stirred with 300~400r/min ~30min, obtains water phase, takes 2~3g jojoba oils, 1~2g lanolin alcohol polyethers, 5~8g Plantacare 818s, 0.5~1.0g fourths Glycol laurate, 0.5~1.0g sorbitan monostearates, it is complete to solid to be placed in heating stirring in 70~80 DEG C of water-baths Dissolving, obtains oil phase, then water phase is added dropwise into oil phase with 1~2mL/min, is continued stirring until and is added dropwise with 200~300r/min, 40~50 DEG C are cooled to, adds 0.2~0.3g cellulose acetates, 0.2~0.3g niacinamide, 0.2~0.3g panthenols, 0.1~ 0.2g preservatives, 0.1~0.2g essence, continues 20~30min of stirring, obtains haze amino acid without silicone oil shampoo.

Example 1

Silk is washed with deionized 2 times and is fitted into drying box, dry 1h, takes 200g silks at 55 DEG C, adds 2kg matter It is in 5% sodium carbonate liquor to measure fraction, and is heated to 95 DEG C of boiling 30min, and centrifuging must precipitate and supernatant, use deionization Water washing precipitates 2 times, then will precipitation repeat boiling 3 times after merge supernatant, and be evaporated under reduced pressure and be concentrated into supernatant fluid after merging Long-pending 10%, obtains concentrate, and concentrate is fitted into the bag filter that molecular weight is 1000 and is dialysed 6 days, deionized water is replaced per 4h, Trapped fluid is taken after dialysis, trapped fluid is placed in freeze drying box and is freeze-dried 10h, obtains sericin, takes 10g silk gum eggs In vain, 30g lauroyl chlorides, add in 300mL deionized waters, stir 20min with 300r/min, then with mass fraction be 5% hydroxide Sodium solution adjusts pH to 8, continues to be fitted into molecular weight after stirring 3h to dialyse 6 days in 1000 bag filter, deionization is replaced per 4h Water, it is 30% to take retention solution decompression to be concentrated by evaporation to solid content after dialysis, obtains sericin surfactant, takes 18g Glue protein surfactant, 8g Cocoamidopropyl betaines, 10g trimethylglycines, 3g sorbierites, 5g glycerine, adds In 40mL deionized waters, 20min is stirred with 300r/min, water phase is obtained, takes 2g jojoba oils, 1g lanolin alcohol polyethers, 5g decyls Glucoside, 0.5g butanediol laurates, 0.5g sorbitan monostearates, are placed in 70 DEG C of water-baths heating stirring to solid It is completely dissolved, obtains oil phase, then water phase is added dropwise into oil phase with 1mL/min, continued stirring until and be added dropwise with 200r/min, cools down To 40 DEG C, 0.2g cellulose acetates are added, 0.2g niacinamide, 0.2g panthenols, 0.1g preservatives, 0.1g essence, continues to stir 20min, obtains haze amino acid without silicone oil shampoo.

Example 2

Silk is washed with deionized 2 times and is fitted into drying box, dry 1h, takes 250g silks at 57 DEG C, adds 2kg matter It is in 5% sodium carbonate liquor to measure fraction, and is heated to 97 DEG C of boiling 35min, and centrifuging must precipitate and supernatant, use deionization Water washing precipitates 2 times, then will precipitation repeat boiling 4 times after merge supernatant, and be evaporated under reduced pressure and be concentrated into supernatant fluid after merging Long-pending 15%, obtains concentrate, and concentrate is fitted into the bag filter that molecular weight is 1250 and is dialysed 7 days, deionized water is replaced per 6h, Trapped fluid is taken after dialysis, trapped fluid is placed in freeze drying box and is freeze-dried 15h, obtains sericin, takes 15g silk gum eggs In vain, 40g lauroyl chlorides, add in 400mL deionized waters, stir 25min with 350r/min, then with mass fraction be 5% hydroxide Sodium solution adjusts pH to 8, continues to be fitted into molecular weight after stirring 3h to dialyse 7 days in 2500 bag filter, deionization is replaced per 6h Water, it is 30% to take retention solution decompression to be concentrated by evaporation to solid content after dialysis, obtains sericin surfactant, takes 21g Glue protein surfactant, 10g Cocoamidopropyl betaines, 12g trimethylglycines, 4g sorbierites, 6g glycerine, adds In 45mL deionized waters, 25min is stirred with 350r/min, water phase is obtained, takes 2g jojoba oils, 1g lanolin alcohol polyethers, 7g decyls Glucoside, 0.75g butanediol laurates, 0.75g sorbitan monostearates, are placed in 75 DEG C of water-baths heating stirring to solid Body is completely dissolved, and obtains oil phase, then water phase is added dropwise into oil phase with 1mL/min, is continued stirring until and is added dropwise with 250r/min, drop Temperature adds 0.25g cellulose acetates to 45 DEG C, 0.25g niacinamide, 0.25g panthenols, 0.15g preservatives, 0.15g essence, after Continuous stirring 25min, obtains haze amino acid without silicone oil shampoo.

Example 3

Silk is washed with deionized 3 times and is fitted into drying box, dry 2h, takes 300g silks at 60 DEG C, adds 3kg matter It is in 5% sodium carbonate liquor to measure fraction, and is heated to 100 DEG C of boiling 40min, and centrifuging must precipitate and supernatant, use deionization Water washing precipitates 3 times, then will precipitation repeat boiling 5 times after merge supernatant, and be evaporated under reduced pressure and be concentrated into supernatant fluid after merging Long-pending 10~20%, obtain concentrate, and concentrate is fitted into the bag filter that molecular weight is 5000 and is dialysed 8 days, deionization is replaced per 8h Water, takes trapped fluid after dialysis, trapped fluid is placed in freeze drying box and is freeze-dried 20h, obtain sericin, takes 20g Glue protein, 50g lauroyl chlorides, add in 500mL deionized waters, stir 30min with 400r/min, then with mass fraction be 5% hydrogen Sodium hydroxide solution adjusts pH to 9, continues to be fitted into molecular weight after stirring 4h to dialyse 8 days in 5000 bag filter, replaces and goes per 8h Ionized water, it is 30% to take retention solution decompression to be concentrated by evaporation to solid content after dialysis, obtains sericin surfactant, takes 25g sericin surfactants, 12g Cocoamidopropyl betaines, 15g trimethylglycines, 5g sorbierites, 8g glycerine, Add in 50mL deionized waters, 30min is stirred with 400r/min, water phase is obtained, takes 3g jojoba oils, 2g lanolin alcohol polyethers, 8g Plantacare 818,1.0g butanediol laurates, 1.0g sorbitan monostearates, are placed in 80 DEG C of water-baths heating stirring extremely Solid is completely dissolved, and obtains oil phase, then water phase is added dropwise into oil phase with 2mL/min, is continued stirring until and is added dropwise with 300r/min, 50 DEG C are cooled to, adds 0.3g cellulose acetates, 0.3g niacinamide, 0.3g panthenols, 0.2g preservatives, 0.2g essence, continues 30min is stirred, obtains haze amino acid without silicone oil shampoo.

By the haze amino acid for preparing of the present invention without the shampoo that silicone oil shampoo and Dongguan company produce into Row detection, specific testing result such as following table table 1：

1 haze amino acid of table is without silicone oil shampoo performance characterization

The haze amino acid that as shown in Table 1 prepared by the present invention is greatly lowered without silicone oil shampoo, dry comb performance, bending storage Storage is greatly lowered, and illustrates the softness increase of hair, the moist degree increase of shampoo, reduces the stimulation to hair and wound Evil, allows hair to moisten, cardability is good, glossy.

Claims (7)

1. a kind of haze amino acid is without silicone oil shampoo, it is characterised in that is made of following component and its parts by weight：

18~25 parts of sericin surfactants, 8~12 parts of Cocoamidopropyl betaines, 10~15 parts of sweet ammonia of trimethyl Acid, 3~5 parts of sorbierites, 5~8 parts of glycerine, 2~3 parts of jojoba oils, 1~2 part of lanolin alcohol polyethers, 5~8 parts of decyl glucose Glycosides, 0.5~1.0 part of butanediol laurate, 0.5~1.0 part of sorbitan monostearate, 0.2~0.3 part of cellulose acetate, 0.2~0.3 part of niacinamide, 0.2~0.3 part of panthenol, 0.1~0.2 portion of preservative, 0.1~0.2 part of essence, 40~50 parts go from Sub- water.

2. a kind of haze amino acid as claimed in claim 1 is without silicone oil shampoo, it is characterised in that the sericin Surfactant for sericin synthesize with lauroyl chloride after dialysis concentration be made, reaction condition for pH be 8~9 times stir 3 ~4h.

3. a kind of haze amino acid as claimed in claim 2 is without silicone oil shampoo, it is characterised in that the dialysis concentration Process is to be fitted into the bag filter that molecular weight is 1000~5000 to dialyse 6~8 days, and every 4~8h replaces deionized water, and dialysis terminates After take retention solution decompression be concentrated by evaporation to solid content be 30%.

4. a kind of haze amino acid as claimed in claim 1 is without silicone oil shampoo, it is characterised in that the sericin Merge supernatant after repeating boiling 3~5 times in sodium carbonate liquor for Silk Soaking, be freeze-dried and be made after concentration dialysis.

5. a kind of haze amino acid as claimed in claim 4 is without silicone oil shampoo, it is characterised in that the sodium carbonate is molten The mass fraction of liquid is 5%, and the mass ratio with silk is 10：1.

6. a kind of haze amino acid as claimed in claim 4 is without silicone oil shampoo, it is characterised in that the concentration dialysis Process for be evaporated under reduced pressure be concentrated into the 10~20% of stoste volume, reenter molecular weight be 1000~5000 bag filter in dialysis 6~ 8 days, every 4~8h replaced deionized water, and trapped fluid is taken after dialysis.

7. a kind of preparation method of the haze amino acid without silicone oil shampoo as described in claim 1~6 any one, its It is characterized in that, concretely comprises the following steps：

（1）It will be immersed in after silk washing and drying in sodium carbonate liquor, and be heated to 95~100 DEG C of 30~40min of boiling, centrifuged Separating must precipitate and supernatant, will precipitation repeat boiling 3~5 times after merge supernatant, be concentrated by evaporation to obtain concentrate；

（2）Trapped fluid is taken after concentrate is dialysed, trapped fluid is freeze-dried 10~20h, obtains sericin；

（3）Take sericin, lauroyl chloride to add in deionized water and be uniformly mixed, pH to 8~9 adjusted with sodium hydroxide solution, Dialyse after 3~4h of stirring, take retention solution decompression to be concentrated by evaporation, obtain sericin surfactant；

（4）Sericin surfactant, Cocoamidopropyl betaine, trimethylglycine, sorbierite, glycerine are taken, is added It is uniformly mixed in deionized water, obtains water phase；

（5）Jojoba oil, lanolin alcohol polyethers, Plantacare 818, butanediol laurate, sorbitan monostearate are taken, is put Heating stirring to solid is completely dissolved in 70~80 DEG C of water-baths, obtains oil phase；

（6）Water phase is added dropwise into oil phase with 1~2mL/min, is continued stirring until and is added dropwise with 200~300r/min, is cooled to 40~50 DEG C, cellulose acetate, niacinamide, panthenol, preservative, essence are added, continues 20~30min of stirring, obtains haze Amino acid is without silicone oil shampoo.