CN107974825A - A kind of preparation method of polyester fiber antistatic resistant to hydrolysis finishing agent - Google Patents
A kind of preparation method of polyester fiber antistatic resistant to hydrolysis finishing agent Download PDFInfo
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- CN107974825A CN107974825A CN201711239415.4A CN201711239415A CN107974825A CN 107974825 A CN107974825 A CN 107974825A CN 201711239415 A CN201711239415 A CN 201711239415A CN 107974825 A CN107974825 A CN 107974825A
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- parts
- antistatic
- preparation
- finishing agent
- polyester fiber
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 24
- 229920000728 polyester Polymers 0.000 title claims abstract description 24
- 239000000835 fiber Substances 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 230000007062 hydrolysis Effects 0.000 title claims abstract description 20
- 238000006460 hydrolysis reaction Methods 0.000 title claims abstract description 20
- -1 organosilicon Chemical compound 0.000 claims abstract description 43
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 30
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 30
- 238000010438 heat treatment Methods 0.000 claims abstract description 18
- 239000007788 liquid Substances 0.000 claims abstract description 18
- 239000000178 monomer Substances 0.000 claims abstract description 18
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 18
- 150000003973 alkyl amines Chemical class 0.000 claims abstract description 17
- 239000006185 dispersion Substances 0.000 claims abstract description 17
- 239000004088 foaming agent Substances 0.000 claims abstract description 17
- 125000001453 quaternary ammonium group Chemical group 0.000 claims abstract description 17
- 239000000463 material Substances 0.000 claims abstract description 16
- HGWAKQDTQVDVRP-OKULMJQMSA-N butyl (z,12r)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(=O)OCCCC HGWAKQDTQVDVRP-OKULMJQMSA-N 0.000 claims abstract description 15
- 239000003822 epoxy resin Substances 0.000 claims abstract description 15
- 235000011187 glycerol Nutrition 0.000 claims abstract description 15
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims abstract description 15
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 15
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims abstract description 15
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 15
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000005187 foaming Methods 0.000 claims abstract description 14
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 12
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 11
- 239000012467 final product Substances 0.000 claims abstract description 9
- 238000010992 reflux Methods 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims abstract description 8
- 230000001804 emulsifying effect Effects 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 238000010008 shearing Methods 0.000 claims abstract description 7
- 238000010792 warming Methods 0.000 claims description 8
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 6
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 claims description 5
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 claims 1
- 150000004702 methyl esters Chemical class 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 6
- 239000004744 fabric Substances 0.000 abstract description 6
- 239000000675 fabric finishing Substances 0.000 abstract description 3
- 238000009962 finishing (textile) Methods 0.000 abstract description 3
- 238000006243 chemical reaction Methods 0.000 abstract 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 6
- 239000000706 filtrate Substances 0.000 description 6
- 239000005020 polyethylene terephthalate Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000008280 blood Substances 0.000 description 3
- 210000004369 blood Anatomy 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 229920004934 Dacron® Polymers 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 229930003268 Vitamin C Natural products 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004887 air purification Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/272—Unsaturated compounds containing sulfur atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/262—Sulfated compounds thiosulfates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/55—Epoxy resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
A kind of preparation method of polyester fiber antistatic resistant to hydrolysis finishing agent, belongs to fabric finishing agent technical field.Comprise the following steps：It is uniformly mixed alkylamine derivative dispersion liquid foaming agent, neopelex and dimethyl suflfate are added in blender；Said mixture is delivered to the mixing and emulsifying head of foaming machine by screw pump, shearing foaming is carried out to mixed material；Glycerine, butyl ricinoleate sodium sulphate, organosilicon, triethanolamine and Sodium Polyacrylate are heated to reflux, reaction is heated after then addition polysiloxane quaternary ammonium and acrylic ester monomer stir evenly；Added into the mixed material after heating after antistatic epoxide resin and water after heating heating postcooling to room temperature, obtain final product.Finishing agent prepared by the present invention can effectively improve the antistatic effect of fabric, further ensure that the antistatic property of fabric, reduce people in use because of the various inconvenience that electrostatic belt comes, have very strong practical value.
Description
Technical field
The invention belongs to fabric finishing agent technical field, and in particular to a kind of polyester fiber antistatic resistant to hydrolysis finishing agent
Preparation method.
Background technology
Terylene is an important kind in synthetic fibers, is the trade name of China's polyester fiber.It is to benzene two with essence
Formic acid (PTA) or dimethyl terephthalate (DMT) (DMT) and ethylene glycol (EG) for raw material through esterification or ester exchange and polycondensation reaction and
Obtained fiber-forming polymer --- polyethylene terephthalate (PET), through fiber made of spinning and post processing.Production adds
Easily because rubbing and sensing generation electrostatic in work and use, the charge buildup phenomenon of the universal low synthetic fibers product of regain is more
Significantly.The accumulation of electrostatic charge easily causes dust to adhere to, and clothes tangle limbs and produce sense of discomfort, and can cause on pH value of blood
Rise, calcium content reduces in blood, calcium content increases in urine, and blood glucose rise, Vitamin C content decline, and higher electrostatic pressure can be right
Human body produces electric shock, and causes electronic component to damage, and even results on fire and explosion.
Existing most polyester fabric antistatic effect difference and hydrolysis resistance are poor, can not use more than the combustible
In particular surroundings.Polyester fiber filtrate is widely used in metallurgical, change since it has good tension failure strength and wear-resisting property
Technique application, material recycle, air purification, smoke and dust treatment and liquid filtering of a variety of industries such as work, building materials, machinery, oil etc.
Field.But the basic weakness of polyester fiber filtrate is easily to be hydrolyzed, it is easier to be etched under the conditions of acid, alkali.It is if common
Polyester fiber filtrate is used in the work condition environment that low temperature has chemical attack and humidity, can be subject to moist and chemical erosion, is gathered
Ester molecular structure can be hydrolyzed and is broken, and filtrate is lost its intensity, and then influence the service life and filter effect of filter bag.Pass through
The anti-hydrolytic performance of polyester fiber filtrate is improved, can effectively slow down the decline of polyester fiber filtrate ultimate strength in operating mode,
Improve its service life.In currently available technology also not can antistatic again can be with the polyester fabric finishing agent of resistant to hydrolysis.
The content of the invention
The technical problem of solution：For above-mentioned technical problem, the present invention provides a kind of polyester fiber antistatic resistant to hydrolysis
The preparation method of finishing agent, possesses and effectively improves the advantages that antistatic effect of fabric is provided simultaneously with hydrolysis resistance.
Technical solution：A kind of preparation method of polyester fiber antistatic resistant to hydrolysis finishing agent, the preparation method include
Following steps：
Step 1 in parts by mass, takes 3~8 parts of glycerine, 15~25 parts of butyl ricinoleate sodium sulphate, organosilicon 10~18
Part, 1~3 part of triethanolamine, 0.8~5 part of polysiloxane quaternary ammonium, 2~16 parts of acrylic ester monomer, Sodium Polyacrylate 3~7
Part, 12~20 parts of dimethyl suflfate, 9~20 parts of neopelex, 2~6 parts of antistatic epoxide resin, alkylamine derive
200~250 parts of 0.5~1.5 part of thing dispersion liquid foaming agent and water；
Step 2 at a temperature of 60~78 DEG C by alkylamine derivative dispersion liquid foaming agent, neopelex and
Dimethyl suflfate is added in blender and is uniformly mixed；
Mixture prepared by step 2 is delivered to the mixing and emulsifying head of foaming machine by screw pump by step 3, to mixing
Material carries out shearing foaming, and rotating speed is 5000~7000rpm；
Step 4 is by glycerine, butyl ricinoleate sodium sulphate, organosilicon, triethanolamine and Sodium Polyacrylate 200~220
1~2h is heated to reflux at a temperature of DEG C, then add after polysiloxane quaternary ammonium and acrylic ester monomer stir evenly 230~
2~3h is heated at a temperature of 250 DEG C；
It is warming up to after adding antistatic epoxide resin and water in mixed material after the heating that step 5 is prepared to step 4
280~300 DEG C are continued to obtain final product after heating 1h postcoolings to room temperature.
Preferably, in the step 1 in parts by mass, take 6 parts of glycerine, 20 parts of butyl ricinoleate sodium sulphate, organosilicon
14 parts, 2 parts of triethanolamine, 3 parts of polysiloxane quaternary ammonium, 8 parts of acrylic ester monomer, 5 parts of Sodium Polyacrylate, dimethyl suflfate
16 parts, 14 parts of neopelex, 4 parts of antistatic epoxide resin, 1 part of alkylamine derivative dispersion liquid foaming agent and water
225 parts.
Preferably, by alkylamine derivative dispersion liquid foaming agent, dodecyl at a temperature of 65 DEG C in the step 2
Benzene sulfonic acid sodium salt and dimethyl suflfate, which are added in blender, to be uniformly mixed.
Preferably, rotating speed is 6000r/min in the step 3.
Preferably, being heated to reflux 1.5h at a temperature of 210 DEG C in the step 4, polysiloxane quaternary ammonium is then added
After being stirred evenly with acrylic ester monomer 2.5h is heated at a temperature of 240 DEG C.
Continue to obtain final product after heating 1h postcoolings to room temperature preferably, being warming up to 300 DEG C in the step 5.
Beneficial effect：A kind of polyester fiber preparation method of antistatic resistant to hydrolysis finishing agent provided by the present invention, is adopted
Be raw material with materials such as alcohols, carboxylic acids, nitriles, reacted using interim heating, more with the addition of polysiloxane quaternary ammonium and
Acrylic ester monomer, can effectively improve the antistatic effect of fabric, further ensure that the antistatic property of fabric
Can, reduce people in use because of the various inconvenience that electrostatic belt comes, there is very strong practical value.
Embodiment
Embodiment 1
A kind of preparation method of polyester fiber antistatic resistant to hydrolysis finishing agent, the preparation method comprise the following steps：
Step 1 in parts by mass, takes 3 parts of glycerine, 15 parts of butyl ricinoleate sodium sulphate, 10 parts of organosilicon, triethanolamine 1
Part, 0.8 part of polysiloxane quaternary ammonium, 2 parts of acrylic ester monomer, 3 parts of Sodium Polyacrylate, 12 parts of dimethyl suflfate, dodecane
200 parts of 9 parts of base benzene sulfonic acid sodium salt, 2 parts of antistatic epoxide resin, 0.5 part of alkylamine derivative dispersion liquid foaming agent and water；
Step 2 is at a temperature of 60 DEG C by alkylamine derivative dispersion liquid foaming agent, neopelex and sulfuric acid
Dimethyl ester is added in blender and is uniformly mixed；
Mixture prepared by step 2 is delivered to the mixing and emulsifying head of foaming machine by screw pump by step 3, to mixing
Material carries out shearing foaming, rotating speed 5000r/min；
Step 4 is by glycerine, butyl ricinoleate sodium sulphate, organosilicon, triethanolamine and Sodium Polyacrylate in 200 DEG C of temperature
Under be heated to reflux 1h, then add after polysiloxane quaternary ammonium and acrylic ester monomer stir evenly at a temperature of 230 DEG C plus
Hot 2h；
It is warming up to after adding antistatic epoxide resin and water in mixed material after the heating that step 5 is prepared to step 4
280 DEG C are continued to obtain final product after heating 1h postcoolings to room temperature.
Embodiment 2
A kind of preparation method of polyester fiber antistatic resistant to hydrolysis finishing agent, the preparation method comprise the following steps：
Step 1 in parts by mass, takes 8 parts of glycerine, 25 parts of butyl ricinoleate sodium sulphate, 18 parts of organosilicon, triethanolamine 3
Part, 5 parts of polysiloxane quaternary ammonium, 16 parts of acrylic ester monomer, 7 parts of Sodium Polyacrylate, 20 parts of dimethyl suflfate, dodecyl
250 parts of 20 parts of benzene sulfonic acid sodium salt, 6 parts of antistatic epoxide resin, 1.5 parts of alkylamine derivative dispersion liquid foaming agent and water；
Step 2 is at a temperature of 78 DEG C by alkylamine derivative dispersion liquid foaming agent, neopelex and sulfuric acid
Dimethyl ester is added in blender and is uniformly mixed；
Mixture prepared by step 2 is delivered to the mixing and emulsifying head of foaming machine by screw pump by step 3, to mixing
Material carries out shearing foaming, rotating speed 7000r/min；
Step 4 is by glycerine, butyl ricinoleate sodium sulphate, organosilicon, triethanolamine and Sodium Polyacrylate in 220 DEG C of temperature
Under be heated to reflux 2h, then add after polysiloxane quaternary ammonium and acrylic ester monomer stir evenly at a temperature of 250 DEG C plus
Hot 3h；
It is warming up to after adding antistatic epoxide resin and water in mixed material after the heating that step 5 is prepared to step 4
300 DEG C are continued to obtain final product after heating 1h postcoolings to room temperature.
Embodiment 3
A kind of preparation method of polyester fiber antistatic resistant to hydrolysis finishing agent, the preparation method comprise the following steps：
Step 1 in parts by mass, takes 6 parts of glycerine, 20 parts of butyl ricinoleate sodium sulphate, 14 parts of organosilicon, triethanolamine 2
Part, 3 parts of polysiloxane quaternary ammonium, 8 parts of acrylic ester monomer, 5 parts of Sodium Polyacrylate, 16 parts of dimethyl suflfate, dodecyl
225 parts of 14 parts of benzene sulfonic acid sodium salt, 4 parts of antistatic epoxide resin, 1 part of alkylamine derivative dispersion liquid foaming agent and water；
Step 2 is at a temperature of 65 DEG C by alkylamine derivative dispersion liquid foaming agent, neopelex and sulfuric acid
Dimethyl ester is added in blender and is uniformly mixed；
Mixture prepared by step 2 is delivered to the mixing and emulsifying head of foaming machine by screw pump by step 3, to mixing
Material carries out shearing foaming, rotating speed 6000r/min；
Step 4 is by glycerine, butyl ricinoleate sodium sulphate, organosilicon, triethanolamine and Sodium Polyacrylate in 210 DEG C of temperature
Under be heated to reflux 1.5h, then add after polysiloxane quaternary ammonium and acrylic ester monomer stir evenly at a temperature of 240 DEG C
Heat 2.5h；
It is warming up to after adding antistatic epoxide resin and water in mixed material after the heating that step 5 is prepared to step 4
300 DEG C are continued to obtain final product after heating 1h postcoolings to room temperature.
Comparative example 1
With embodiment 3, difference lies in triethanolamine is not added, specific preparation process is as follows：
Step 1 in parts by mass, takes 6 parts of glycerine, 20 parts of butyl ricinoleate sodium sulphate, 14 parts of organosilicon, polysiloxanes
3 parts of quaternary ammonium salt, 8 parts of acrylic ester monomer, 5 parts of Sodium Polyacrylate, 16 parts of dimethyl suflfate, neopelex 14
Part, 4 parts of antistatic epoxide resin, 1 part of alkylamine derivative dispersion liquid foaming agent and 225 parts of water；
Step 2 is at a temperature of 65 DEG C by alkylamine derivative dispersion liquid foaming agent, neopelex and sulfuric acid
Dimethyl ester is added in blender and is uniformly mixed；
Mixture prepared by step 2 is delivered to the mixing and emulsifying head of foaming machine by screw pump by step 3, to mixing
Material carries out shearing foaming, rotating speed 6000r/min；
Step 4 heats back glycerine, butyl ricinoleate sodium sulphate, organosilicon and Sodium Polyacrylate at a temperature of 210 DEG C
1.5h is flowed, then addition polysiloxane quaternary ammonium and acrylic ester monomer heat 2.5h after stirring evenly at a temperature of 240 DEG C；
It is warming up to after adding antistatic epoxide resin and water in mixed material after the heating that step 5 is prepared to step 4
300 DEG C are continued to obtain final product after heating 1h postcoolings to room temperature.
Embodiment 1-3 and comparative example 1 finishing agent prepared are tested into its antistatic property using following methods：
Dacron is immersed to 8g/L embodiments 1-3 respectively and biodegradable antistatic finishing agent prepared by comparative example 1
In, using two two roll process of leaching, pick-up 80% is controlled, is put into baking oven 100 DEG C of preliminary dryings 10 minutes, then in 160 DEG C of conditions
Under bake 1 minute.Before arrangement the electrostatic half-life of dacron for 10 seconds, electrostatic pressure be up to 2946V.It is anti-prepared by the present invention
Electrostatic resistant to hydrolysis finishing agent antistatic property test result such as following table.
| Electrostatic pressure/V | Half degradation period/s | |
| Embodiment 1 | 135 | 0.6 |
| Embodiment 2 | 132 | 0.9 |
| Embodiment 3 | 129 | 0.7 |
| Comparative example 1 | 160 | 0.5 |
Prepared finishing agent anti-static effect is fabulous it can be seen from table.
Claims (6)
1. a kind of polyester fiber preparation method of antistatic resistant to hydrolysis finishing agent, it is characterised in that the preparation method includes
Following steps：
Step 1 in parts by mass, takes 3~8 parts of glycerine, 15~25 parts of butyl ricinoleate sodium sulphate, 10~18 parts of organosilicon, three
1~3 part of monoethanolamine, 0.8~5 part of polysiloxane quaternary ammonium, 2~16 parts of acrylic ester monomer, 3~7 parts of Sodium Polyacrylate,
12~20 parts of dimethyl suflfate, 9~20 parts of neopelex, 2~6 parts of antistatic epoxide resin, alkylamine derivative
200 ~ 250 parts of 0.5 ~ 1.5 part of dispersion liquid foaming agent and water；
Step 2 is at a temperature of 60 ~ 78 DEG C by alkylamine derivative dispersion liquid foaming agent, neopelex and sulfuric acid two
Methyl esters is added in blender and is uniformly mixed；
Mixture prepared by step 2 is delivered to the mixing and emulsifying head of foaming machine by screw pump by step 3, to mixed material
Shearing foaming is carried out, rotating speed is 5000 ~ 7000rpm；
Step 4 is by glycerine, butyl ricinoleate sodium sulphate, organosilicon, triethanolamine and Sodium Polyacrylate in 200 ~ 220 DEG C of temperature
Under be heated to reflux 1 ~ 2h, then add after polysiloxane quaternary ammonium and acrylic ester monomer stir evenly in 230 ~ 250 DEG C of temperature
2 ~ 3h of the lower heating of degree；
Added in mixed material after the heating that step 5 is prepared to step 4 after antistatic epoxide resin and water and be warming up to 280 ~
300 DEG C are continued to obtain final product after heating 1h postcoolings to room temperature.
2. a kind of preparation method of polyester fiber antistatic resistant to hydrolysis finishing agent according to claim 1, its feature exist
In in the step 1 in parts by mass, taking 6 parts of glycerine, 20 parts of butyl ricinoleate sodium sulphate, 14 parts of organosilicon, triethanolamine 2
Part, 3 parts of polysiloxane quaternary ammonium, 8 parts of acrylic ester monomer, 5 parts of Sodium Polyacrylate, 16 parts of dimethyl suflfate, dodecyl
225 parts of 14 parts of benzene sulfonic acid sodium salt, 4 parts of antistatic epoxide resin, 1 part of alkylamine derivative dispersion liquid foaming agent and water.
3. a kind of preparation method of polyester fiber antistatic resistant to hydrolysis finishing agent according to claim 1, its feature exist
In by alkylamine derivative dispersion liquid foaming agent, neopelex and sulfuric acid at a temperature of 65 DEG C in the step 2
Dimethyl ester is added in blender and is uniformly mixed.
4. a kind of preparation method of polyester fiber antistatic resistant to hydrolysis finishing agent according to claim 1, its feature exist
In rotating speed is 6000rpm in the step 3.
5. a kind of preparation method of polyester fiber antistatic resistant to hydrolysis finishing agent according to claim 1, its feature exist
In 1.5 h are heated to reflux in the step 4 at a temperature of 210 DEG C, then add polysiloxane quaternary ammonium and esters of acrylic acid
Monomer heats 2.5 h after stirring evenly at a temperature of 240 DEG C.
6. a kind of preparation method of polyester fiber antistatic resistant to hydrolysis finishing agent according to claim 1, its feature exist
In, be warming up in the step 5 300 DEG C continue heat 1h postcoolings to room temperature after obtain final product.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN119391258A (en) * | 2024-11-23 | 2025-02-07 | 东莞市汨乳粘合剂有限公司 | A water-based acrylic varnish and its preparation method and application in cardboard |
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| EP0962583A2 (en) * | 1991-05-28 | 1999-12-08 | Hercules Incorporated | Cardable hydrophobic polyolefin fiber |
| CN103643517A (en) * | 2013-11-22 | 2014-03-19 | 江苏波波熊纺织品有限公司 | Fiber fabric antistatic finishing agent and preparation method thereof |
| CN104372616A (en) * | 2014-11-03 | 2015-02-25 | 厦门三维丝环保股份有限公司 | Finishing agent for improving hydrolysis resistance of polyester fiber filter material and finishing method of finishing agent |
| CN105506964A (en) * | 2016-01-08 | 2016-04-20 | 湖州市千金丝织厂 | Novel antibacterial anti-static finishing agent |
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| US3730892A (en) * | 1971-03-22 | 1973-05-01 | Allied Chem | Production of polyesters |
| EP0962583A2 (en) * | 1991-05-28 | 1999-12-08 | Hercules Incorporated | Cardable hydrophobic polyolefin fiber |
| CN103643517A (en) * | 2013-11-22 | 2014-03-19 | 江苏波波熊纺织品有限公司 | Fiber fabric antistatic finishing agent and preparation method thereof |
| CN104372616A (en) * | 2014-11-03 | 2015-02-25 | 厦门三维丝环保股份有限公司 | Finishing agent for improving hydrolysis resistance of polyester fiber filter material and finishing method of finishing agent |
| CN105506964A (en) * | 2016-01-08 | 2016-04-20 | 湖州市千金丝织厂 | Novel antibacterial anti-static finishing agent |
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| CN119391258A (en) * | 2024-11-23 | 2025-02-07 | 东莞市汨乳粘合剂有限公司 | A water-based acrylic varnish and its preparation method and application in cardboard |
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