[go: up one dir, main page]

CN107974619A - Microalloy containing V builds steel bar and its production method - Google Patents

Microalloy containing V builds steel bar and its production method Download PDF

Info

Publication number
CN107974619A
CN107974619A CN201711242341.XA CN201711242341A CN107974619A CN 107974619 A CN107974619 A CN 107974619A CN 201711242341 A CN201711242341 A CN 201711242341A CN 107974619 A CN107974619 A CN 107974619A
Authority
CN
China
Prior art keywords
steel
production method
content
billet
steel bar
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711242341.XA
Other languages
Chinese (zh)
Inventor
邓通武
刘明
郭跃华
冉准
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pangang Group Panzhihua Iron and Steel Research Institute Co Ltd
Original Assignee
Pangang Group Panzhihua Iron and Steel Research Institute Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pangang Group Panzhihua Iron and Steel Research Institute Co Ltd filed Critical Pangang Group Panzhihua Iron and Steel Research Institute Co Ltd
Priority to CN201711242341.XA priority Critical patent/CN107974619A/en
Publication of CN107974619A publication Critical patent/CN107974619A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/0056Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00 using cored wires
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
    • C21D8/065Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
    • C21D8/08Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires for concrete reinforcement
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/04Making ferrous alloys by melting
    • C22C33/06Making ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/009Pearlite
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Abstract

本发明属于钢铁冶金领域,具体涉及一种含V微合金建筑钢棒材及其生产方法。针对现有制备含氮合金钢所选用氮化钒合金氮含量低、种类少等问题,本发明提供了一种含V微合金建筑钢棒材及其生产方法。该棒材的组成成分为:按重量百分比计,C:0.15%~0.30%、Si:0.30%~1.00%、Mn:0.60%~1.30%、N:0.0060%~0.0180%、P≤0.040%、S≤0.040%、V:0.010%~0.160%,余量为Fe和不可避免的杂质。其制备方法的关键在于在炉后小平台喂入含N包芯线,调整N到适宜的水平。本发明方法操作简单,氮收得率高且稳定,还能有效的降低生产成本,值得推广使用。The invention belongs to the field of iron and steel metallurgy, and in particular relates to a V-containing microalloy construction steel bar and a production method thereof. Aiming at the problems of low nitrogen content and few types of vanadium nitride alloys used in the preparation of nitrogen-containing alloy steels, the invention provides a V-containing microalloy building steel bar and a production method thereof. The composition of the bar is: by weight percentage, C: 0.15% to 0.30%, Si: 0.30% to 1.00%, Mn: 0.60% to 1.30%, N: 0.0060% to 0.0180%, P≤0.040%, S≤0.040%, V:0.010%~0.160%, the balance is Fe and unavoidable impurities. The key of its preparation method is to feed the N-containing cored wire on the small platform behind the furnace and adjust the N to a suitable level. The method of the invention has simple operation, high and stable nitrogen yield, and can effectively reduce the production cost, and is worthy of popularization and use.

Description

含V微合金建筑钢棒材及其生产方法Containing V micro-alloyed construction steel bar and production method thereof

技术领域technical field

本发明属于钢铁冶金领域,具体涉及一种含V微合金建筑钢棒材及其生产方法。The invention belongs to the field of iron and steel metallurgy, and in particular relates to a V-containing microalloy construction steel bar and a production method thereof.

背景技术Background technique

微合金钢主要是指在钢中添加很少量或者是微量的某种元素就能明显提高性能的钢,特别是提高钢的强度指标。现有技术条件下微合金钢主要通常添加很少量或者是微量钒、铌和钛而得到。微合金化的作用机制是:作为微量元素的钒、铌和钛加入钢液后,与钢液中的碳和氮结合,形成碳、氮的化合物质点,即V(C、N),Nb(C、N)和Ti(C、N)质点,这些质点具有一定的沉淀强化和晶粒细化的作用,可明显的提高钢的强度。Microalloyed steel mainly refers to the steel whose performance can be obviously improved by adding a small amount or a trace amount of certain elements in the steel, especially the strength index of the steel. Under the existing technical conditions, microalloyed steel is mainly obtained by adding a small amount or a small amount of vanadium, niobium and titanium. The mechanism of microalloying is: after adding vanadium, niobium and titanium as trace elements into molten steel, they combine with carbon and nitrogen in molten steel to form carbon and nitrogen compound particles, namely V(C, N), Nb( C, N) and Ti (C, N) particles, these particles have a certain effect of precipitation strengthening and grain refinement, which can significantly improve the strength of steel.

由此可看出,实际上微合金钢钒、铌和钛的作用均是和氮分不开的,但一般情况下采用转炉冶炼钢,残留氮含量在0.0030%~0.065%范围内,采用电炉冶炼钢,残留氮含量在0.050%~0.085%范围内,大多数情况下。如要充分发挥钒、铌和钛的作用,是必须要额外加入氮元素才能实现的。It can be seen from this that in fact, the role of microalloyed steel vanadium, niobium and titanium is inseparable from nitrogen, but in general, converters are used to smelt steel, and the residual nitrogen content is in the range of 0.0030% to 0.065%. For smelting steel, the residual nitrogen content is in the range of 0.050% to 0.085%, in most cases. In order to give full play to the role of vanadium, niobium and titanium, it is necessary to add nitrogen to achieve it.

早期在微合金钢中增加氮,是通过添加3%~6%的氮化类合金来实现的,但由于氮化类合金含氮很低,造成合金加入量大,且收得率不稳定,逐渐被氮含量较高的氮化钒合金代替。目前微合金钢的生产中几乎很难再使用3%~6%的氮化类合金,几乎全部使用即含钒、且氮含量又高的氮化钒合金。氮化钒合金主要有VN12、VN14和VN16三个牌号。一般情况下该三个牌号氮和钒的比值是基本固定的,分别为12:78(N:V);14:78(N:V);16:78(N:V),即氮和钒的比值最高为VN16的16:78,即合金中含有16%的N,含有78%钒。氮化钒合金虽然既含钒、且氮含量又高,但对于微合金钢中不同的微合金化技术路线,特别是复合微合金钢,例如V-Ti-N,甚至于V-Ti-Nb-N,也是不能满足需求的。In the early days, nitrogen was added to microalloyed steels by adding 3% to 6% of nitrided alloys. However, due to the low nitrogen content of nitrided alloys, the amount of alloy added was large and the yield was unstable. Gradually replaced by vanadium nitride alloys with higher nitrogen content. At present, it is almost difficult to use 3% to 6% nitrided alloys in the production of microalloyed steels, and almost all of them use vanadium-containing and high-nitrogen vanadium nitride alloys. Vanadium nitride alloys mainly have three grades: VN12, VN14 and VN16. In general, the ratios of nitrogen and vanadium of the three grades are basically fixed, respectively 12:78(N:V); 14:78(N:V); 16:78(N:V), namely nitrogen and vanadium The highest ratio of VN16 is 16:78, that is, the alloy contains 16% N and 78% vanadium. Although vanadium nitride alloys contain both vanadium and high nitrogen content, for different microalloying technology routes in microalloyed steels, especially composite microalloyed steels, such as V-Ti-N, or even V-Ti-Nb -N, also cannot meet the demand.

发明内容Contents of the invention

针对现有制备含氮合金钢所选用氮化钒合金氮含量低、种类少等问题,本发明提供了一种新的制备含氮合金的方法。该方法采用添加含氮包芯线的方式精确控制氮含量,氮收得率高。Aiming at the problems of low nitrogen content and few types of vanadium nitride alloys selected for preparing nitrogen-containing alloy steels, the invention provides a new method for preparing nitrogen-containing alloys. The method adopts the method of adding nitrogen-containing cored wire to precisely control the nitrogen content, and the nitrogen yield is high.

本发明解决上述技术问题的技术方案为:提供一种含V微合金建筑钢棒材及其生产方法。The technical solution of the present invention to solve the above-mentioned technical problems is: to provide a V-containing micro-alloyed construction steel bar and a production method thereof.

本发明提供一种含V微合金建筑钢棒材,其化学成分为:按重量百分比计,C:0.15%~0.30%、Si:0.30%~1.00%、Mn:0.60%~1.30%、N:0.0060%~0.0180%、P≤0.040%、S≤0.040%、V:0.010%~0.160%,余量为Fe和不可避免的杂质。The invention provides a V-containing microalloy building steel bar, the chemical composition of which is: by weight percentage, C: 0.15% to 0.30%, Si: 0.30% to 1.00%, Mn: 0.60% to 1.30%, N: 0.0060%~0.0180%, P≤0.040%, S≤0.040%, V: 0.010%~0.160%, the balance is Fe and unavoidable impurities.

本发明还提供了一种上述含V微合金建筑钢棒材的生产方法,包括以下步骤:The present invention also provides a method for producing the above-mentioned V-containing microalloyed construction steel bar, comprising the following steps:

高炉铁水经转炉冶炼、连铸制得钢坯;钢坯经加热、连续式棒材轧制生产线轧制成材、冷却制成圆棒或带肋钢筋;其中在炉后小平台的钢包内喂入包芯线调整N,钢坯加热温度控制为950~1220℃,均热温度控制为1000~1200℃,加热和均热总时间90~120min;所述钢坯成分为:按重量百分比计,C:0.15%~0.30%、Si:0.30%~1.00%、Mn:0.60%~1.30%、N:0.0060%~0.0180%、P≤0.040%、S≤0.040%、V:0.010%~0.160%,余量为Fe和不可避免的杂质。The molten iron in the blast furnace is smelted in a converter and continuously cast to produce a billet; the billet is heated, rolled into a continuous bar rolling production line, and cooled to form a round bar or ribbed steel bar; the core is fed into the ladle on the small platform behind the furnace Line adjustment N, billet heating temperature controlled to 950-1220°C, soaking temperature controlled to 1000-1200°C, total heating and soaking time 90-120min; the composition of the billet is: by weight percentage, C: 0.15%~ 0.30%, Si: 0.30% ~ 1.00%, Mn: 0.60% ~ 1.30%, N: 0.0060% ~ 0.0180%, P≤0.040%, S≤0.040%, V: 0.010% ~ 0.160%, the balance is Fe and unavoidable impurities.

进一步的,上述含V微合金建筑钢棒材的生产方法,包括以下步骤:Further, the production method of the above-mentioned V-containing microalloyed construction steel bar comprises the following steps:

a、转炉冶炼a. Converter smelting

在转炉内加入铁水和废钢,利用转炉吹氧脱C,进行冶炼,待钢水C含量为0.05%~0.15%,P含量≤0.025%、S含量≤0.035%,钢水温度≥1650℃时出钢;Add molten iron and scrap steel into the converter, use the converter to blow oxygen to remove C, and carry out smelting. When the C content of the molten steel is 0.05% to 0.15%, the P content is ≤0.025%, the S content is ≤0.035%, and the molten steel temperature is ≥1650°C, the steel is tapped;

出钢1/3-2/3时,加入FeSi、FeMn合金和增碳剂,FeV或VN合金,控制C为0.15%~0.30%、Si为0.30%~1.00%,Mn为0.60%~1.30%,V为0.010%~0.160%;When tapping 1/3-2/3, add FeSi, FeMn alloy and recarburizer, FeV or VN alloy, control C at 0.15%-0.30%, Si at 0.30%-1.00%, and Mn at 0.60%-1.30% , V is 0.010% to 0.160%;

b、喂包芯线b. Feed cored wire

出钢后转入钢包,钢包到达炉后小平台后,向钢包内吹入惰性气体,加入含N包芯线,控制钢液中N含量为0.0060%~0.0180%;After the steel is tapped, it is transferred to the ladle. After the ladle reaches the small platform behind the furnace, an inert gas is blown into the ladle, and a cored wire containing N is added to control the N content in the molten steel to 0.0060% to 0.0180%;

c、连铸c. Continuous casting

控制连铸机中包的过热度为20~50℃,将钢液连铸成的钢坯断面为150mm×150mm~200mm×200mm的方坯,空冷至室温;Control the superheat degree of the tundish in the continuous casting machine to 20-50°C, continuously cast the molten steel billet into a billet with a cross-section of 150mm×150mm-200mm×200mm, and air-cool it to room temperature;

d、钢坯加热和轧制d. Billet heating and rolling

钢坯加热温度控制为950~1220℃,均热温度控制为1000~1200℃,加热和均热总时间为90~120min,采用连续式棒材轧制生产线轧制成圆棒或带肋钢筋。The billet heating temperature is controlled at 950-1220°C, the soaking temperature is controlled at 1000-1200°C, the total heating and soaking time is 90-120 minutes, and the continuous bar rolling production line is used to roll into round bars or ribbed steel bars.

其中,上述含V微合金建筑钢棒材的生产方法中,步骤a中所述铁水要求S含量≤0.060%。Wherein, in the production method of the above-mentioned V-containing microalloyed construction steel bar, the molten iron in step a requires that the S content is ≤0.060%.

其中,上述含V微合金建筑钢棒材的生产方法中,步骤a中所述FeSi和FeMn合金用FeSiMn合金替代。Wherein, in the above-mentioned production method of V-containing microalloyed construction steel rods, the FeSi and FeMn alloys in step a are replaced by FeSiMn alloys.

其中,上述含V微合金建筑钢棒材的生产方法中,步骤b中所述的惰性气体为氩气或氮气中的一种。Wherein, in the production method of the above-mentioned V-containing microalloyed construction steel bar, the inert gas described in step b is one of argon or nitrogen.

其中,上述含V微合金建筑钢棒材的生产方法中,步骤b中所述吹入惰性气体的时间≥2min。Wherein, in the production method of the above-mentioned V-containing micro-alloyed construction steel rod, the time for injecting the inert gas in step b is ≥ 2 minutes.

其中,上述含V微合金建筑钢棒材的生产方法中,步骤b出站温度高于钢的液相线温度60~90℃。Wherein, in the production method of the above-mentioned V-containing micro-alloyed construction steel bar, the exit temperature of step b is 60-90° C. higher than the liquidus temperature of the steel.

其中,上述含V微合金建筑钢棒材的生产方法中,步骤d中所述圆棒或带肋钢筋的规格为 Wherein, in the production method of the above-mentioned V-containing microalloyed construction steel bar, the specification of the round bar or ribbed steel bar described in step d is

本发明的有益效果为:The beneficial effects of the present invention are:

本发明通过设计一种含V的微合金建筑钢棒材,在钢中添加合金成分V:0.010%~0.160%,再配合采用在转炉冶炼后喂入含N包芯线的方式调整钢种N含量、采用棒材轧制生产线轧制,最终可制备得到一种强度高、氮收得率高的微合金建筑钢棒材。本发明方法操作简单,氮收得率高且稳定,还能有效的降低生产成本,值得推广使用。The present invention designs a V-containing micro-alloy building steel bar, adds alloy composition V: 0.010% to 0.160% in the steel, and then adjusts the steel type N by feeding the N-containing cored wire after converter smelting. content, rolled by a bar rolling production line, and finally a micro-alloyed construction steel bar with high strength and high nitrogen yield can be prepared. The method of the invention has simple operation, high and stable nitrogen yield, and can effectively reduce the production cost, and is worthy of popularization and use.

具体实施方式Detailed ways

本发明提供了一种含V微合金建筑钢棒材,其化学成分为:按重量百分比计,C:0.15%~0.30%、Si:0.30%~1.0%、Mn:0.60%~1.30%、N:0.0060%~0.0180%、P≤0.040%、S≤0.040%、V:0.010%~0.160%,余量为Fe和不可避免的杂质。The invention provides a V-containing microalloy building steel bar, the chemical composition of which is: by weight percentage, C: 0.15% to 0.30%, Si: 0.30% to 1.0%, Mn: 0.60% to 1.30%, N : 0.0060%~0.0180%, P≤0.040%, S≤0.040%, V: 0.010%~0.160%, the balance is Fe and unavoidable impurities.

本发明加入0.010%~0.160%的V是为了保证钢材的时效性能。一般情况下采用转炉冶炼钢时,最终成品钢中的残留氮含量在0.0030%~0.0065%范围内,采用电炉冶炼钢,残留氮含量则在0.0050%~0.0085%范围内。随着钢中N含量升高,时效性随之变差,本发明则采用加入0.010%~0.160%的V的方式,以保证钢材的时效性,同时还能充分发挥氮的固溶强化作用,从而提高钢的强度,降低钢的合金成本。The purpose of adding 0.010%-0.160% V in the present invention is to ensure the aging performance of the steel. Generally, when steel is smelted by converter, the residual nitrogen content in the final finished steel is in the range of 0.0030% to 0.0065%, and when steel is smelted by electric furnace, the residual nitrogen content is in the range of 0.0050% to 0.0085%. As the N content in the steel increases, the timeliness becomes worse. The present invention adopts the method of adding 0.010% to 0.160% V to ensure the timeliness of the steel, and at the same time give full play to the solid solution strengthening effect of nitrogen. Thereby increasing the strength of the steel and reducing the cost of the alloy of the steel.

另外,上述化学成分中,因钢水中的氮含量比通常钢中残留氮含量高,钛的加入也更加容易形成V(C、N)质点,从而促进了V的析出,能够更加充分的发挥钒的沉淀强化和晶粒细化作用,以提高钢的综合力学性能,在同等力学性能的前提下,可减少钒的使用量。In addition, in the above chemical composition, because the nitrogen content in molten steel is higher than the residual nitrogen content in ordinary steel, the addition of titanium is also easier to form V (C, N) particles, thereby promoting the precipitation of V, and can more fully exert vanadium. Precipitation strengthening and grain refinement to improve the comprehensive mechanical properties of steel, and reduce the amount of vanadium used under the premise of the same mechanical properties.

本发明还提供了一种含V微合金建筑钢棒材的生产方法,包括以下步骤:The present invention also provides a production method of V-containing micro-alloyed construction steel bars, comprising the following steps:

a、转炉冶炼a. Converter smelting

首先在转炉内加入铁水和废钢,要求加入的铁水S含量不大于0.060%,铁水和废钢加入转炉后,利用转炉吹氧脱C的功能,将铁水和废钢初炼成钢水,当钢水成分初炼到0.05%~0.15%的C,P不大于0.025%、S不大于0.035%,且出钢温度不低于1650℃时出钢到钢包中;First, add molten iron and steel scrap into the converter. It is required that the S content of the added molten iron is not more than 0.060%. To 0.05% ~ 0.15% of C, P is not more than 0.025%, S is not more than 0.035%, and the steel is tapped into the ladle when the tapping temperature is not lower than 1650°C;

出钢过程中加入含有Si元素的FeSi合金,含有Mn元素的FeMn合金,以及含有V元素的合金和增碳剂,所述增碳剂为C粉或无烟煤,控制C在0.15%~0.30%范围内、控制Si在0.30%~1.00%范围内,控制Mn在0.60%~1.30%范围内,控制V在0.010%~0.160%范围内;在出钢1/3时开始加入FeSi、FeMn和FeV或者VN合金,出钢至2/3时必须加完;Add FeSi alloy containing Si element, FeMn alloy containing Mn element, and alloy containing V element and recarburizing agent during the tapping process. The recarburizing agent is C powder or anthracite, and the C is controlled in the range of 0.15% to 0.30%. Inside, control Si in the range of 0.30% to 1.00%, control Mn in the range of 0.60% to 1.30%, control V in the range of 0.010% to 0.160%; start adding FeSi, FeMn and FeV or For VN alloy, it must be added when the steel is tapped to 2/3;

上述合金的加入中,也可采用含有Si和Mn的FeSiMn合金代替FeSi和FeMn合金;In the addition of the above alloys, FeSiMn alloys containing Si and Mn can also be used instead of FeSi and FeMn alloys;

b、转炉炉后吹入惰性气体并喂入包芯线b. Inert gas is blown into the converter and the cored wire is fed

当出钢完成后,钢水包立即接入管道,向钢包中的钢液吹入惰性气体,吹入的惰性气体可以是氩气,也可以是氮气,吹入惰性气体的时间应不低于2min;规定惰性气体的吹入时间不低于2min是为了保证钢液有足够的循环时间,可以使加入的各类合金充分熔化和均匀;When tapping is completed, the ladle is immediately connected to the pipeline, and inert gas is blown into the molten steel in the ladle. The inert gas blown in can be argon or nitrogen, and the time for blowing inert gas should not be less than 2 minutes. ; The inert gas blowing time is specified to be not less than 2 minutes to ensure that the molten steel has sufficient circulation time to fully melt and homogenize the various alloys added;

吹入惰性气体时间大于2min后,取样进行N含量检测,根据检验结果采用喂线的方法加入含N包芯线,所述含N包芯线主要为含N合金,如SiN等,控制钢液中N含量在0.0060%~0.0180%范围内;如果炉后钢水中N含量控制较为稳定可不取样进行N含量检测,直接喂入包芯线;After blowing inert gas for more than 2 minutes, take samples for N content detection, and add N-containing cored wire by feeding the wire according to the test results. The N-containing cored wire is mainly N-containing alloys, such as SiN, etc., and control the molten steel The N content in the medium is in the range of 0.0060% to 0.0180%. If the N content control in the molten steel after the furnace is relatively stable, it is not necessary to take a sample for N content detection, and directly feed the cored wire;

喂入包芯线前,钢水包需再次接上吹入惰性气体的管道,并吹入的惰性气体后才能喂入含N的包芯线,惰性气体可以是氩气,也可以是氮气,当喂线完成后吹入惰性气体的时间还需延长2min以上,以保证钢液中N元素的均匀性,并控制出站钢水温度;Before feeding the cored wire, the ladle needs to be connected to the pipe for blowing inert gas again, and the inert gas can only be fed into the cored wire containing N. The inert gas can be argon or nitrogen. After the line feeding is completed, the time for blowing inert gas needs to be extended by more than 2 minutes to ensure the uniformity of N elements in the molten steel and to control the temperature of the molten steel out of the station;

出站前进行测温,确保出站温度高于钢的液相线温度60~90℃;Measure the temperature before exiting the station to ensure that the exiting temperature is 60-90°C higher than the liquidus temperature of the steel;

c、连铸成钢坯c. Continuous casting into billets

控制连铸机中包的过热度为20~50℃,该温度是通过上述转炉出钢和炉后出站温度的控制来实现的;Control the superheat degree of the tundish of the continuous casting machine to 20-50°C, which is achieved through the control of the above-mentioned converter tapping and post-station temperature control;

钢液连铸成的钢坯断面为150mm×150mm~200mm×200mm的方坯,低于150mm×150mm的方坯断面小不利于转炉流程的连续作业,大于200mm×200mm的方坯断面则会延长后续轧制钢坯时的加热时间;The cross-section of the steel billet made by molten steel continuous casting is 150mm×150mm~200mm×200mm. The small cross-section of the billet below 150mm×150mm is not conducive to the continuous operation of the converter process, and the cross-section of the billet larger than 200mm×200mm will prolong the subsequent Heating time when rolling billets;

钢液连铸成的钢坯,在空气中自然冷却到室温;The steel billet made by continuous casting of molten steel is naturally cooled to room temperature in the air;

d、钢坯加热和轧制d. Billet heating and rolling

钢坯的加热要求总加热时间为90~120min,加热炉最高加热温度为1220℃,最高均热温度为1200℃,钢坯出加热炉的温度控制在1000~1200℃范围内;The heating of the billet requires a total heating time of 90-120 minutes, the maximum heating temperature of the heating furnace is 1220°C, the maximum soaking temperature is 1200°C, and the temperature of the billet out of the heating furnace is controlled within the range of 1000-1200°C;

最终成品规格是的圆棒,或者是具有与GB 1499.2中所规定的带肋钢筋外型的用建筑用带肋钢筋,均可采用连续式棒材轧制生产线进行轧制。The final product specification is The round bar, or the shape of the ribbed steel bar specified in GB 1499.2 Ribbed steel bars for construction can be rolled by a continuous bar rolling production line.

下面将通过实施例对本发明的具体实施方式做进一步的解释说明,但不表示将本发明的保护范围限制在实施例所述范围内。The following will further explain the specific implementation of the present invention through examples, but it does not mean that the protection scope of the present invention is limited to the scope described in the examples.

实施例1用本发明方法制备含V微合金建筑钢棒材Embodiment 1 uses the inventive method to prepare containing V microalloy building steel bars

某钢铁厂在公称容量120吨(实际出钢量在120~140吨范围内)转炉流程上采用本发明技术生产建筑用带肋钢筋,生产工艺为转炉冶炼→炉后吹入惰性气体+喂入包芯线→6机6流方坯连铸机浇铸成150mm×150mm钢坯→钢坯加热→连续式棒材轧制生产线轧制成带肋钢筋。A steel plant adopts the technology of the present invention to produce ribbed steel bars for construction in the converter process with a nominal capacity of 120 tons (the actual steel output is in the range of 120 to 140 tons). The production process is converter smelting → blowing inert gas after the furnace + feeding Core-spun wire → 6-machine 6-strand billet continuous casting machine casting into 150mm×150mm billet → billet heating → rolling into continuous bar rolling production line Ribbed steel bars.

首先在转炉内加入120吨铁水和20吨废钢,加入的铁水S含量为0.047%。铁水和废钢加入转炉后,利用转炉吹氧脱C的功能,将铁水和废钢初炼成钢水,当钢水成分初炼到0.09%的C、0.020%的P、0.025%的S,温度为1676℃时出钢到钢包中,此时实际出钢量为136吨(转炉冶炼过程中约5%的原料被烧损)。出钢过程中向钢液中加入FeSi、FeMn、FeV合金和无烟煤进行Si、Mn、V和C元素合金化,其中加入的FeSi合金中Si含量为74%,FeMn合金中Mn含量为82%,FeV合金中V含量为78%,无烟煤中固定C为92%,控制钢水中Si含量为0.30%、Mn含量为0.60%、V含量为0.011%、C含量为0.15%。。Firstly, 120 tons of molten iron and 20 tons of scrap steel are added into the converter, and the S content of the added molten iron is 0.047%. After the molten iron and steel scrap are added to the converter, the molten iron and steel scrap are initially smelted into molten steel by using the function of the converter to remove C by blowing oxygen. When the composition of the molten steel is initially smelted to 0.09% C, 0.020% P, and 0.025% S, the temperature is 1676°C When tapping into the ladle, the actual tapping amount is 136 tons (about 5% of the raw material is burned in the converter smelting process). Add FeSi, FeMn, FeV alloy and anthracite to the molten steel during the tapping process to carry out alloying of Si, Mn, V and C elements, wherein the content of Si in the added FeSi alloy is 74%, and the content of Mn in the FeMn alloy is 82%. The V content in the FeV alloy is 78%, the fixed C in the anthracite is 92%, the Si content in the molten steel is controlled to be 0.30%, the Mn content is 0.60%, the V content is 0.011%, and the C content is 0.15%. .

钢水到达炉后小平台后,钢水包立即接入管道,向钢包中的钢液吹入氮气,吹入氮气4min后采用喂线的方法加入含N包芯线,控制钢液中N含量为0.0064%。After the molten steel reaches the small platform behind the furnace, the ladle is immediately connected to the pipeline, and nitrogen gas is blown into the molten steel in the ladle. After blowing nitrogen gas for 4 minutes, the N-containing cored wire is added by feeding the wire, and the N content in the molten steel is controlled to 0.0064 %.

喂完包芯线后继续吹入氮气2min后进行测温,根据测温结果确定继续吹氮时间以调整钢水温度,出站前再次进行测温,待钢水温度为1671℃时出站,并将钢液送到连铸机进行浇铸。After feeding the cored wire, continue to blow in nitrogen for 2 minutes before measuring the temperature. Determine the time to continue blowing nitrogen according to the temperature measurement results to adjust the temperature of the molten steel. Measure the temperature again before leaving the station. When the temperature of the molten steel is 1671°C, leave the station and The molten steel is sent to the continuous casting machine for casting.

在6机6流方坯连铸机上浇铸成150mm×150mm铸坯,连铸时中间包温度为1549℃,钢的液相线温度为1515℃,在连铸机中包取样分析钢水化学组分为0.15%的C、0.30%的Si、0.63%的Mn、0.03%的Cr、0.010%的V、0.038%的P、0.028%的S、0.0061%的N,其余为Fe和不可避免的其它杂质。铸坯堆垛自然冷却至室温。Cast billets of 150mm×150mm on a 6-machine, 6-strand billet continuous casting machine. During continuous casting, the temperature of the tundish is 1549°C, and the liquidus temperature of the steel is 1515°C. Sampling and analysis of the chemical composition of molten steel in the continuous casting machine 0.15% C, 0.30% Si, 0.63% Mn, 0.03% Cr, 0.010% V, 0.038% P, 0.028% S, 0.0061% N, the rest is Fe and other unavoidable impurities . The slab stack is naturally cooled to room temperature.

铸坯冷却后送至连续式棒材生产线进行加热、轧制,轧制规格为的带肋钢筋。铸坯加热温度为1213℃,均热温度为1182℃,总加热时间达到95min后出炉进行轧制,终轧温度为955℃,上冷床后进行自然空冷,最后收集、打捆。After the slab is cooled, it is sent to the continuous bar production line for heating and rolling. The rolling specification is ribbed steel bars. The billet heating temperature is 1213°C, the soaking temperature is 1182°C, the total heating time reaches 95 minutes, and then it is rolled out of the furnace. The final rolling temperature is 955°C, and it is naturally air-cooled after being placed on the cooling bed, and finally collected and bundled.

钢的力学性能检验结果为:ReL(Rp0.2)为ReL(Rp0.2)为346MPa、抗拉强度为452MPa、伸长率为37.1%、最大力总伸长率为17.4%,180℃冷弯合格。钢的组织均为铁素体+珠光体。The test results of the mechanical properties of the steel are: ReL (Rp0.2) is 346MPa, the tensile strength is 452MPa, the elongation is 37.1%, and the total elongation of the maximum force is 17.4%. Bend qualified. The structure of steel is ferrite + pearlite.

实施例2用本发明方法制备含V微合金建筑钢棒材Example 2 Preparation of V-containing microalloyed building steel bars by the method of the present invention

某钢铁厂在公称容量120吨(实际出钢量在120~140吨范围内)转炉流程上采用本发明技术生产建筑用带肋钢筋,生产工艺为转炉冶炼→炉后吹入惰性气体+喂入包芯线→6机6流方坯连铸机浇铸成150mm×150mm钢坯→钢坯加热→连续式棒材轧制生产线轧制成带肋钢筋。A steel plant adopts the technology of the present invention to produce ribbed steel bars for construction in the converter process with a nominal capacity of 120 tons (the actual steel output is in the range of 120 to 140 tons). The production process is converter smelting → blowing inert gas after the furnace + feeding Core-spun wire → 6-machine 6-strand billet continuous casting machine casting into 150mm×150mm billet → billet heating → rolling into continuous bar rolling production line Ribbed steel bars.

首先在转炉内加入120吨铁水和20吨废钢,加入的铁水S含量为0.042%。铁水和废钢加入转炉后,利用转炉吹氧脱C的功能,将铁水和废钢初炼成钢水,当钢水成分初炼到0.06%的C、0.020%的P、0.025%的S,温度为1683℃时出钢到钢包中,此时实际出钢量为131吨(转炉冶炼过程中约5%的原料被烧损)。出钢过程中向钢液中加入FeSi、FeMn、FeV合金和无烟煤进行Si、Mn、V和C元素合金化,其中加入的FeSi合金中Si含量为74%,FeMn合金中Mn含量为82%,FeV合金中V含量为78%,无烟煤中固定C为92%,控制钢水中Si含量为0.95%、Mn含量为1.29%、V含量为0.156%、C含量为0.29%。Firstly, 120 tons of molten iron and 20 tons of scrap steel are added into the converter, and the S content of the added molten iron is 0.042%. After the molten iron and steel scrap are added to the converter, the molten iron and steel scrap are initially smelted into molten steel by using the function of the converter to remove C by blowing oxygen. When the composition of the molten steel is initially smelted to 0.06% C, 0.020% P, and 0.025% S, the temperature is 1683°C When tapping into the ladle, the actual tapping amount is 131 tons (about 5% of the raw material is burned in the converter smelting process). Add FeSi, FeMn, FeV alloy and anthracite to the molten steel during the tapping process to carry out alloying of Si, Mn, V and C elements, wherein the content of Si in the added FeSi alloy is 74%, and the content of Mn in the FeMn alloy is 82%. The V content in the FeV alloy is 78%, the fixed C in the anthracite is 92%, the Si content in the controlled molten steel is 0.95%, the Mn content is 1.29%, the V content is 0.156%, and the C content is 0.29%.

钢水到达炉后小平台后,钢水包立即接入管道,向钢包中的钢液吹入氮气,吹入氮气4min后采用喂线的方法加入含N包芯线,控制钢液中N含量在0.0164%范围内。After the molten steel reaches the small platform behind the furnace, the ladle is immediately connected to the pipeline, and nitrogen gas is blown into the molten steel in the ladle. After blowing nitrogen gas for 4 minutes, the N-containing cored wire is added by wire feeding method, and the N content in the molten steel is controlled at 0.0164 % range.

喂完包芯线后继续吹入氮气2min后进行测温,根据测温结果确定继续吹氮时间以调整钢水温度,出站前再次进行测温,待钢水温度为1677℃时出站,并将钢液送到连铸机进行浇铸。After feeding the cored wire, continue to blow nitrogen for 2 minutes before measuring the temperature. Determine the time to continue blowing nitrogen according to the temperature measurement results to adjust the temperature of the molten steel. Measure the temperature again before leaving the station. When the temperature of the molten steel reaches 1677°C, leave the station and The molten steel is sent to the continuous casting machine for casting.

在6机6流方坯连铸机上浇铸成200mm×200mm铸坯,连铸时中间包温度为1530℃,钢的液相线温度为1495℃,在连铸机中包取样分析钢水化学组分为0.30%的C、0.98%的Si、1.29%的Mn、0.03%的Cr、0.156%的V、0.034%的P、0.022%的S、0.0162%的N,其余为Fe和不可避免的其它杂质。铸坯堆垛自然冷却至室温。Cast billets of 200mm×200mm on a 6-machine, 6-strand billet continuous casting machine. During continuous casting, the temperature of the tundish is 1530 ° C, and the liquidus temperature of the steel is 1495 ° C. Sampling and analysis of the chemical composition of molten steel in the continuous casting machine 0.30% C, 0.98% Si, 1.29% Mn, 0.03% Cr, 0.156% V, 0.034% P, 0.022% S, 0.0162% N, the rest is Fe and other unavoidable impurities . The slab stack is naturally cooled to room temperature.

铸坯冷却后送至连续式棒材生产线进行加热、轧制,轧制规格为的带肋钢筋。铸坯加热温度为1032℃,均热温度为1005℃,总加热时间达到95min后出炉进行轧制,终轧温度为881℃,上冷床后进行自然空冷,最后收集、打捆。After the slab is cooled, it is sent to the continuous bar production line for heating and rolling. The rolling specification is ribbed steel bars. The billet heating temperature is 1032°C, the soaking temperature is 1005°C, the total heating time reaches 95 minutes, and then it is rolled out of the furnace. The final rolling temperature is 881°C, and it is naturally air-cooled after being placed on the cooling bed, and finally collected and bundled.

钢的力学性能检验结果为:ReL(Rp0.2)为536MPa、抗拉强度为702MPa、伸长率为17.3%、最大力总伸长率为12.3%,180℃冷弯合格。钢的组织均为铁素体+珠光体。The test results of the mechanical properties of the steel are: ReL (Rp0.2) is 536MPa, the tensile strength is 702MPa, the elongation is 17.3%, the maximum total elongation is 12.3%, and the cold bending at 180°C is qualified. The structure of steel is ferrite + pearlite.

实施例3用本发明方法制备含V微合金建筑钢棒材Example 3 Preparation of V-containing microalloyed building steel bar by the method of the present invention

某钢铁厂在公称容量120吨(实际出钢量在120~140吨范围内)转炉流程上采用本发明技术生产建筑用带肋钢筋,生产工艺为转炉冶炼→炉后吹入惰性气体+喂入包芯线→6机6流方坯连铸机浇铸成150mm×150mm钢坯→钢坯加热→连续式棒材轧制生产线轧制成带肋钢筋。A steel plant adopts the technology of the present invention to produce ribbed steel bars for construction in the converter process with a nominal capacity of 120 tons (the actual steel output is in the range of 120 to 140 tons). The production process is converter smelting → blowing inert gas after the furnace + feeding Core-spun wire→6-machine 6-strand billet continuous casting machine casting into 150mm×150mm steel billet→steel billet heating→rolling into continuous bar rolling production line Ribbed steel bars.

首先在转炉内加入120吨铁水和20吨废钢,加入的铁水S含量为0.051%。铁水和废钢加入转炉后,利用转炉吹氧脱C的功能,将铁水和废钢初炼成钢水,当钢水成分初炼到0.06%的C、0.020%的P、0.025%的S,温度为1681℃时出钢到钢包中,此时实际出钢量为134吨(转炉冶炼过程中约5%的原料被烧损)。出钢过程中向钢液中加入FeSi、FeMn、FeV合金和无烟煤进行Si、Mn、V和C元素合金化,其中加入的FeSi合金中Si含量为74%,FeMn合金中Mn含量为82%,FeV合金中V含量为78%,无烟煤中固定C为92%,控制钢水中Si含量为0.64%、Mn含量为0.96%、V含量为0.080%、C含量为0.21%。Firstly, 120 tons of molten iron and 20 tons of scrap steel are added into the converter, and the S content of the added molten iron is 0.051%. After the molten iron and steel scrap are added to the converter, the molten iron and steel scrap are initially smelted into molten steel by using the function of the converter to remove C by blowing oxygen. When the composition of the molten steel is initially smelted to 0.06% C, 0.020% P, and 0.025% S, the temperature is 1681°C When tapping into the ladle, the actual tapping amount is 134 tons (about 5% of the raw material is burned in the converter smelting process). Add FeSi, FeMn, FeV alloy and anthracite to the molten steel during the tapping process to carry out alloying of Si, Mn, V and C elements, wherein the content of Si in the added FeSi alloy is 74%, and the content of Mn in the FeMn alloy is 82%. The V content in the FeV alloy is 78%, the fixed C in the anthracite is 92%, and the Si content in the controlled molten steel is 0.64%, the Mn content is 0.96%, the V content is 0.080%, and the C content is 0.21%.

钢水到达炉后小平台后,钢水包立即接入管道,向钢包中的钢液吹入氮气,吹入氮气4min后采用喂线的方法加入含N包芯线,控制钢液中N含量在0.0132%。After the molten steel reaches the small platform behind the furnace, the ladle is immediately connected to the pipeline, and nitrogen gas is blown into the molten steel in the ladle. After blowing nitrogen gas for 4 minutes, the N-containing cored wire is added by feeding the wire, and the N content in the molten steel is controlled at 0.0132 %.

喂完包芯线后继续吹入氮气2min后进行测温,根据测温结果确定继续吹氮时间以调整钢水温度,出站前再次进行测温,待钢水温度为1665℃时出站,并将钢液送到连铸机进行浇铸。After feeding the cored wire, continue to blow nitrogen for 2 minutes before measuring the temperature. Determine the time to continue blowing nitrogen according to the temperature measurement results to adjust the temperature of the molten steel. Measure the temperature again before leaving the station. When the temperature of the molten steel is 1665°C, leave the station and put The molten steel is sent to the continuous casting machine for casting.

在6机6流方坯连铸机上浇铸成150mm×150mm铸坯,连铸时中间包温度为1532℃,钢的液相线温度为1510℃,在连铸机中包取样分析钢水化学组分为0.21%的C、0.67%的Si、0.97%的Mn、0.03%的Cr、0.080%的V、0.033%的P、0.022%的S、0.0131%的N,其余为Fe和不可避免的其它杂质。铸坯堆垛自然冷却至室温。Cast billets of 150mm×150mm on a 6-machine 6-strand billet continuous casting machine. During continuous casting, the temperature of the tundish is 1532°C, and the liquidus temperature of the steel is 1510°C. Sampling and analysis of the chemical composition of molten steel in the continuous casting machine 0.21% C, 0.67% Si, 0.97% Mn, 0.03% Cr, 0.080% V, 0.033% P, 0.022% S, 0.0131% N, the rest is Fe and other unavoidable impurities . The slab stack is naturally cooled to room temperature.

铸坯冷却后送至连续式棒材生产线进行加热、轧制,轧制规格为的带肋钢筋。铸坯加热温度为1137℃,均热温度为1115℃,总加热时间达到95min后出炉进行轧制,终轧温度为919℃,上冷床后进行自然空冷,最后收集、打捆。After the slab is cooled, it is sent to the continuous bar production line for heating and rolling. The rolling specification is ribbed steel bars. The billet heating temperature is 1137°C, the soaking temperature is 1115°C, the total heating time reaches 95 minutes, and then it is rolled out of the furnace. The final rolling temperature is 919°C, and it is naturally air-cooled after being placed on the cooling bed, and finally collected and bundled.

钢的力学性能检验结果为:ReL(Rp0.2)为433MPa、抗拉强度为581MPa、伸长率为22.9%、最大力总伸长率为15.4%,180℃冷弯合格。钢的组织均为铁素体+珠光体。The test results of the mechanical properties of the steel are: ReL (Rp0.2) is 433MPa, tensile strength is 581MPa, elongation is 22.9%, the maximum total elongation is 15.4%, and the cold bending at 180°C is qualified. The structure of steel is ferrite + pearlite.

Claims (9)

1. microalloy containing V builds steel bar, it is characterised in that chemical composition is:By weight percentage, C:0.15%~ 0.30%th, Si:0.30%~1.00%, Mn:0.60%~1.30%, N:0.0060%~0.0180%, P≤0.040%, S ≤ 0.040%, V:0.010%~0.160%, surplus is Fe and inevitable impurity.
2. the production method of the building steel bar of microalloy containing V described in claim 1, it is characterised in that comprise the following steps:
It is blast-melted that steel billet is made through converter smelting, continuous casting;Steel billet is heated, the rolling of continous way rolling bar production line is become a useful person, Pole or Ribbed Bar is made in cooling;Core-spun yarn adjustment N, billet heating temperature control are fed in the ladle of chain-wales wherein after stove 950~1220 DEG C are made as, soaking temperature control is 1000~1200 DEG C, heating and 90~120min of soaking total time;The steel Base component is:By weight percentage, C:0.15%~0.30%, Si:0.30%~1.00%, Mn:0.60%~1.30%, N:0.0060%~0.0180%, P≤0.040%, S≤0.040%, V:0.010%~0.160%, surplus is Fe and can not The impurity avoided.
3. the production method of the building of microalloy containing V steel bar according to claim 2, it is characterised in that including following step Suddenly:
A, converter smelting
Molten iron and steel scrap are added in converter, C is taken off using Converter Oxigen Blowing, is smelted, treat molten steel C content for 0.05%~ 0.15%, P content≤0.025%, S content≤0.035%, when liquid steel temperature >=1650 DEG C, tap;
Tap 1/3-2/3 when, add FeSi, FeMn alloy and carburant, FeV or VN alloys, control C be 0.15%~ 0.30%th, Si is that 0.30%~1.00%, Mn is that 0.60%~1.30%, V is 0.010%~0.160%;
B, core-spun yarn is fed
It is transferred to ladle after tapping, ladle is reached after stove after chain-wales, and inert gas is blown into ladle, adds core-spun yarn containing N, is controlled N content is 0.0060%~0.0180% in molten steel processed;
C, continuous casting
It is 20~50 DEG C to control the degree of superheat wrapped in conticaster, the steel billet section that molten steel is casting continuously to form for 150mm × 150mm~ The square billet of 200mm × 200mm, is air-cooled to room temperature;
D, heating steel billet and rolling
Billet heating temperature control is 950~1220 DEG C, and soaking temperature control is 1000~1200 DEG C, heating and soaking total time For 90~120min, pole or Ribbed Bar are rolled into using continous way rolling bar production line.
4. the production method of the building of microalloy containing V steel bar according to claim 3, it is characterised in that:Described in step a Molten iron requires S content≤0.060%.
5. the production method of the building of microalloy containing V steel bar according to claim 3, it is characterised in that:Described in step a FeSi and FeMn alloys FeSiMn alloy replacings.
6. the production method of the building of microalloy containing V steel bar according to claim 3, it is characterised in that:Described in step b Inert gas be one kind in argon gas or nitrogen.
7. the production method of the building of microalloy containing V steel bar according to claim 3, it is characterised in that:Described in step b It is blown into time >=2min of inert gas.
8. the production method of the building of microalloy containing V steel bar according to claim 3, it is characterised in that:The outbound temperature of step b Liquidus temperature 60~90 DEG C of the degree higher than steel.
9. the production method of the building of microalloy containing V steel bar according to claim 3, it is characterised in that:Described in step d The specification of pole or Ribbed Bar is
CN201711242341.XA 2017-11-30 2017-11-30 Microalloy containing V builds steel bar and its production method Pending CN107974619A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711242341.XA CN107974619A (en) 2017-11-30 2017-11-30 Microalloy containing V builds steel bar and its production method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711242341.XA CN107974619A (en) 2017-11-30 2017-11-30 Microalloy containing V builds steel bar and its production method

Publications (1)

Publication Number Publication Date
CN107974619A true CN107974619A (en) 2018-05-01

Family

ID=62008804

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711242341.XA Pending CN107974619A (en) 2017-11-30 2017-11-30 Microalloy containing V builds steel bar and its production method

Country Status (1)

Country Link
CN (1) CN107974619A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107955905A (en) * 2017-11-30 2018-04-24 攀钢集团攀枝花钢铁研究院有限公司 Microalloy containing V builds steel bar and its LF stove production methods
CN109252105A (en) * 2018-11-23 2019-01-22 攀钢集团攀枝花钢铁研究院有限公司 The 500MPa grades of high yield ratio anti-seismic steel bar bars of microalloy containing V and its production method
CN109338248A (en) * 2018-10-24 2019-02-15 河钢股份有限公司承德分公司 A kind of Australia mark 300E reinforcing bar and its production method
CN111286674A (en) * 2020-03-31 2020-06-16 湖南华菱湘潭钢铁有限公司 Production method of high-strength anchor rod reinforcing steel bar

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014034683A (en) * 2012-08-07 2014-02-24 Nippon Steel & Sumitomo Metal Bar steel or wire for case hardening
CN105908091A (en) * 2016-04-29 2016-08-31 河北钢铁股份有限公司承德分公司 Hot rolled reinforced bar for high-impact-toughness 500-MPa anchor rod and production method
CN106636917A (en) * 2016-12-05 2017-05-10 河钢股份有限公司承德分公司 HRB600E vanadium-containing high-strength hot-rolled earthquake-resistant reinforced bar and production method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014034683A (en) * 2012-08-07 2014-02-24 Nippon Steel & Sumitomo Metal Bar steel or wire for case hardening
CN105908091A (en) * 2016-04-29 2016-08-31 河北钢铁股份有限公司承德分公司 Hot rolled reinforced bar for high-impact-toughness 500-MPa anchor rod and production method
CN106636917A (en) * 2016-12-05 2017-05-10 河钢股份有限公司承德分公司 HRB600E vanadium-containing high-strength hot-rolled earthquake-resistant reinforced bar and production method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
许后昌等: "HRB400E抗震钢筋研制与开发", 《四川冶金》 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107955905A (en) * 2017-11-30 2018-04-24 攀钢集团攀枝花钢铁研究院有限公司 Microalloy containing V builds steel bar and its LF stove production methods
CN109338248A (en) * 2018-10-24 2019-02-15 河钢股份有限公司承德分公司 A kind of Australia mark 300E reinforcing bar and its production method
CN109252105A (en) * 2018-11-23 2019-01-22 攀钢集团攀枝花钢铁研究院有限公司 The 500MPa grades of high yield ratio anti-seismic steel bar bars of microalloy containing V and its production method
CN111286674A (en) * 2020-03-31 2020-06-16 湖南华菱湘潭钢铁有限公司 Production method of high-strength anchor rod reinforcing steel bar

Similar Documents

Publication Publication Date Title
CN107955906A (en) Steel bar and its production method are built containing V, Nb microalloy
CN107955919A (en) Steel bar and its LF stove production methods are built containing V, Nb microalloy
CN107747053A (en) Steel wire rod and its LF stove production methods are built containing V, Nb microalloy
CN107747047A (en) Steel Bar and its production method are built containing Nb, Cr microalloy
CN107955911A (en) Microalloy containing Nb builds steel bar and its LF stove production methods
CN107815603A (en) Steel Bar and its LF stove production methods are built containing V, Nb, Cr microalloy
CN107974619A (en) Microalloy containing V builds steel bar and its production method
CN107964630A (en) Microalloy containing Ti builds steel bar and its production method
CN107747046A (en) Steel Bar and its production method are built containing V, Ti microalloy
CN107955905A (en) Microalloy containing V builds steel bar and its LF stove production methods
CN107815608A (en) Microalloy containing Ti builds Steel Bar and its LF stove production methods
CN107815525A (en) Microalloy containing Nb builds steel wire rod and its production method
CN107955904A (en) Steel bar and its production method are built containing V, Nb, Ti microalloy
CN107955901A (en) Steel bar and its production method are built containing V, Ti, Cr microalloy
CN107815526A (en) Microalloy containing Nb builds Steel Bar and its production method
CN107723605A (en) Steel Bar and its LF stove production methods are built containing Ti, Cr microalloy
CN107815601B (en) Microalloy construction steel wire rod containing Nb and Cr and LF furnace production method thereof
CN107955918A (en) Steel bar and its LF stove production methods are built containing V, Cr microalloy
CN107815609A (en) Steel Bar and its LF stove production methods are built containing Nb, Cr microalloy
CN107955899A (en) Steel wire rod and its production method are built containing V, Nb microalloy
CN107815604A (en) Steel wire rod and its LF stove production methods are built containing V, Nb, Ti microalloy
CN107747059A (en) Steel wire rod and its production method are built containing V, Ti, Cr microalloy
CN107955913A (en) Steel wire rod and its LF stove production methods are built containing V, Nb, Cr microalloy
CN107955903A (en) Steel bar and its production method are built containing V, Cr microalloy
CN107747058A (en) Steel Bar and its production method are built containing Ti, Cr microalloy

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20180501

RJ01 Rejection of invention patent application after publication