CN107953433A - A kind of method of Calophyllum preservative treatment - Google Patents
A kind of method of Calophyllum preservative treatment Download PDFInfo
- Publication number
- CN107953433A CN107953433A CN201711393448.4A CN201711393448A CN107953433A CN 107953433 A CN107953433 A CN 107953433A CN 201711393448 A CN201711393448 A CN 201711393448A CN 107953433 A CN107953433 A CN 107953433A
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- CN
- China
- Prior art keywords
- calophyllum
- preservative
- preservative treatment
- mentioned steps
- added
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/02—Processes; Apparatus
- B27K3/08—Impregnating by pressure, e.g. vacuum impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/02—Processes; Apparatus
- B27K3/08—Impregnating by pressure, e.g. vacuum impregnation
- B27K3/10—Apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
- B27K5/04—Combined bleaching or impregnating and drying of wood
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/20—Removing fungi, molds or insects
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
The present invention discloses a kind of method of Calophyllum preservative treatment, including following operating procedure：（1）Silver nitrate, sodium tungstate are added in deionized water extremely, then add monocrystalline silica flour thereto, after being heated to 220 250 DEG C, when isothermal holding 23 is small after, centrifugation is precipitated, and Calophyllum preservative will be made after precipitation cleans；（2）By step（1）Obtained Calophyllum preservative is added into 90 95 times of heavy water of its weight, after mixing uniformly, then is added Polyethylenimine thereto, is continued after stirring evenly, and maceration extract is made, and then using vacuum pressure impregnating method, impregnation is carried out to Calophyllum；（3）Step will be passed through（2）After the Calophyllum drying of processing, anti-corrosion Calophyllum is made.The method of Calophyllum preservative treatment provided by the invention, it is easy to operate, it is of low cost, in processing procedure, the excellent properties of of Calophyllum itself are not interfered with, but the antiseptic property of Calophyllum can be greatly lifted, and the anti-corrosion term of validity is grown.
Description
Technical field
The invention belongs to wood preservation technical field, and in particular to a kind of method of Calophyllum preservative treatment.
Background technology
Calophyllum, which becomes a useful person, needs more than 150-200, the expensive hardwood of generic name, is commonly called as the red wingceltis in Southeast Asia, and Calophyllum drying property is good
Good, not easy to crack and warpage, is the sound wood for making solid wood furniture, Calophyllum is high-end furniture woods, due to its texture
Color also referred to as small redwood close with rosewood class color and luster.Therefore the preservative treatment of Calophyllum is particularly important, it is necessary to anti-
Rotten agent meets permanent effective anti-corrosion effect.In the prior art, to the preservation of timber against decay, organic anti-corrosive agent is used mostly, although its
Permeance property in timber is excellent, but the anti-corrosion term of validity is shorter, it is impossible to meets the long-term corrosion-resistant needs of Calophyllum.
The content of the invention
In order to solve the above technical problem, the present invention provides a kind of method of Calophyllum preservative treatment.
The present invention is achieved by the following technical solutions.
A kind of method of Calophyllum preservative treatment, including following operating procedure：
（1）By weight, 15-22 parts of silver nitrates, 28-32 parts of sodium tungstates are added into 150-200 parts of deionized water, so
Afterwards thereto add 17-20 part monocrystalline silica flours, after being heated to 220-250 DEG C, when isothermal holding 2-3 is small after, centrifuge precipitated,
After precipitation is cleaned, Calophyllum preservative is made；
（2）By step（1）Obtained Calophyllum preservative is added into 90-95 times of water weighed of its weight, mix uniformly after, then to its
Middle addition Polyethylenimine, continues after stirring evenly, and maceration extract is made, and then using vacuum pressure impregnating method, Calophyllum is carried out
Impregnation；
（3）Step will be passed through（2）After the Calophyllum drying of processing, anti-corrosion Calophyllum is made.
Specifically, above-mentioned steps（1）In, the Average Particle Diameters of monocrystalline silica flour are 300 mesh.
Specifically, above-mentioned steps（1）In, precipitation cleaning way is：After being cleaned 2 times using deionized water, then using volume
The ethanol solution that fraction is 75% cleans 3 times, is finally cleaned 2 times using deionized water again.
Specifically, above-mentioned steps（2）In, the addition of Polyethylenimine is the 0.5-0.7% of water weight.
Specifically, above-mentioned steps（2）In, in vacuum pressure impregnating method, the vacuum of impregnating autoclave is 0.045MPa, impregnates and adds
The pressure of pressure is 0.74MPa.
Specifically, above-mentioned steps（3）In, the temperature of drying is 65-70 DEG C, when the time of drying is 10-12 small.
From the above technical scheme, it can be seen that the beneficial effects of the invention are as follows：
The method of Calophyllum preservative treatment provided by the invention, it is easy to operate, it is of low cost, in processing procedure, do not interfere with sea
The excellent properties of of Chinese bush cherry wood itself, but the antiseptic property of Calophyllum can be greatly lifted, and the anti-corrosion term of validity is grown, and is at least
10 years.The present invention uses inorganic corrosion inhibitor, its anti-corrosion term of validity is significantly higher than organic anti-corrosive agent, but in the prior art,
There is the defects of inorganic corrosion inhibitor poor permeability, therefore the present invention uses carrier of the monocrystalline silica flour as inorganic corrosion inhibitor, into
And the permeability of inorganic corrosion inhibitor is effectively lifted, improve the antiseptic property of Calophyllum；Wherein, the addition of Polyethylenimine, can
Further to lift adhesive rate of the inorganic corrosion inhibitor inside Calophyllum, and then improve corrosion-resistant effect；The present invention is made
Wolframic acid silver preservative, there is extremely excellent bactericidal property, and the phenomenon for being not susceptible to degrade or failing.
Embodiment
Below by specific embodiment, the present invention is described in detail, but the purposes of these illustrative embodiments and
Purpose is only used for enumerating the present invention, not forms any type of any restriction to the real protection scope of the present invention, more non-to incite somebody to action
Protection scope of the present invention is confined to this.
Embodiment 1
A kind of method of Calophyllum preservative treatment, including following operating procedure：
（1）By weight, 15 parts of silver nitrates, 28 parts of sodium tungstates are added into 150 parts of deionized water, then added thereto
Enter 17 parts of monocrystalline silica flours, after being heated to 220 DEG C, when isothermal holding 2 is small after, centrifugation precipitated, will precipitation clean after, be made sea
Chinese bush cherry wood corrosion-proof agent；
（2）By step（1）Obtained Calophyllum preservative is added into 90 times of heavy water of its weight, after mixing uniformly, then thereto
Polyethylenimine is added, is continued after stirring evenly, maceration extract is made, then using vacuum pressure impregnating method, Calophyllum is soaked
Stain processing；
（3）Step will be passed through（2）After the Calophyllum drying of processing, anti-corrosion Calophyllum is made.
Specifically, above-mentioned steps（1）In, the Average Particle Diameters of monocrystalline silica flour are 300 mesh.
Specifically, above-mentioned steps（1）In, precipitation cleaning way is：After being cleaned 2 times using deionized water, then using volume
The ethanol solution that fraction is 75% cleans 3 times, is finally cleaned 2 times using deionized water again.
Specifically, above-mentioned steps（2）In, the addition of Polyethylenimine is the 0.5% of water weight.
Specifically, above-mentioned steps（2）In, in vacuum pressure impregnating method, the vacuum of impregnating autoclave is 0.045MPa, impregnates and adds
The pressure of pressure is 0.74MPa.
Specifically, above-mentioned steps（3）In, the temperature of drying is 65 DEG C, when the time of drying is 10 small.
Embodiment 2
A kind of method of Calophyllum preservative treatment, including following operating procedure：
（1）By weight, 18 parts of silver nitrates, 30 parts of sodium tungstates are added into 180 parts of deionized water, then added thereto
Enter 18 parts of monocrystalline silica flours, after being heated to 230 DEG C, when isothermal holding 2.5 is small after, centrifugation precipitated, will precipitation clean after, be made
Calophyllum preservative；
（2）By step（1）Obtained Calophyllum preservative is added into 93 times of heavy water of its weight, after mixing uniformly, then thereto
Polyethylenimine is added, is continued after stirring evenly, maceration extract is made, then using vacuum pressure impregnating method, Calophyllum is soaked
Stain processing；
（3）Step will be passed through（2）After the Calophyllum drying of processing, anti-corrosion Calophyllum is made.
Specifically, above-mentioned steps（1）In, the Average Particle Diameters of monocrystalline silica flour are 300 mesh.
Specifically, above-mentioned steps（1）In, precipitation cleaning way is：After being cleaned 2 times using deionized water, then using volume
The ethanol solution that fraction is 75% cleans 3 times, is finally cleaned 2 times using deionized water again.
Specifically, above-mentioned steps（2）In, the addition of Polyethylenimine is the 0.6% of water weight.
Specifically, above-mentioned steps（2）In, in vacuum pressure impregnating method, the vacuum of impregnating autoclave is 0.045MPa, impregnates and adds
The pressure of pressure is 0.74MPa.
Specifically, above-mentioned steps（3）In, the temperature of drying is 68 DEG C, when the time of drying is 11 small.
Embodiment 3
A kind of method of Calophyllum preservative treatment, including following operating procedure：
（1）By weight, 22 parts of silver nitrates, 32 parts of sodium tungstates are added into 200 parts of deionized water, then added thereto
Enter 20 parts of monocrystalline silica flours, after being heated to 250 DEG C, when isothermal holding 3 is small after, centrifugation precipitated, will precipitation clean after, be made sea
Chinese bush cherry wood corrosion-proof agent；
（2）By step（1）Obtained Calophyllum preservative is added into 95 times of heavy water of its weight, after mixing uniformly, then thereto
Polyethylenimine is added, is continued after stirring evenly, maceration extract is made, then using vacuum pressure impregnating method, Calophyllum is soaked
Stain processing；
（3）Step will be passed through（2）After the Calophyllum drying of processing, anti-corrosion Calophyllum is made.
Specifically, above-mentioned steps（1）In, the Average Particle Diameters of monocrystalline silica flour are 300 mesh.
Specifically, above-mentioned steps（1）In, precipitation cleaning way is：After being cleaned 2 times using deionized water, then using volume
The ethanol solution that fraction is 75% cleans 3 times, is finally cleaned 2 times using deionized water again.
Specifically, above-mentioned steps（2）In, the addition of Polyethylenimine is the 0.7% of water weight.
Specifically, above-mentioned steps（2）In, in vacuum pressure impregnating method, the vacuum of impregnating autoclave is 0.045MPa, impregnates and adds
The pressure of pressure is 0.74MPa.
Specifically, above-mentioned steps（3）In, the temperature of drying is 70 DEG C, when the time of drying is 12 small.
With reference to GB/T18621《Mould inhibitor prevents the test method of timber mould and Stain fungi》In method test Calophyllum
Preventing efficiency, test result is as shown in table 1：
The bacteriostasis property of 1 Calophyllum of table
| Project | Botryodiplodia theo-bromae | Pinecone shell spore | Trichoderma asperellum |
| Embodiment 1 | 100% | 99 | 97 |
| Embodiment 2 | 100% | 98 | 99 |
| Embodiment 3 | 100% | 100 | 100 |
As shown in Table 1, Calophyllum produced by the present invention, has extremely effective prevention effect to the fungi for causing Wood staining.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to compared with
The present invention is described in detail in good embodiment, it will be understood by those of ordinary skill in the art that, can be to the skill of the present invention
Art scheme technical scheme is modified or replaced equivalently, without departing from the objective and scope of technical solution of the present invention, it should all cover at this
Among the right of invention.
Claims (6)
- A kind of 1. method of Calophyllum preservative treatment, it is characterised in that including following operating procedure：（1）By weight, 15-22 parts of silver nitrates, 28-32 parts of sodium tungstates are added into 150-200 parts of deionized water, so Afterwards thereto add 17-20 part monocrystalline silica flours, after being heated to 220-250 DEG C, when isothermal holding 2-3 is small after, centrifuge precipitated, After precipitation is cleaned, Calophyllum preservative is made；（2）By step（1）Obtained Calophyllum preservative is added into 90-95 times of water weighed of its weight, mix uniformly after, then to its Middle addition Polyethylenimine, continues after stirring evenly, and maceration extract is made, and then using vacuum pressure impregnating method, Calophyllum is carried out Impregnation；（3）Step will be passed through（2）After the Calophyllum drying of processing, anti-corrosion Calophyllum is made.
- A kind of 2. method of Calophyllum preservative treatment according to claim 1, it is characterised in that above-mentioned steps（1）In, it is single The Average Particle Diameters of crystal silicon powder are 300 mesh.
- A kind of 3. method of Calophyllum preservative treatment according to claim 1, it is characterised in that above-mentioned steps（1）In, sink Shallow lake cleaning way is：Using deionized water clean 2 times after, then use volume fraction be 75% ethanol solution cleaning 3 times, finally Cleaned 2 times using deionized water again.
- A kind of 4. method of Calophyllum preservative treatment according to claim 1, it is characterised in that above-mentioned steps（2）In, gather The addition of monoethanolamine is the 0.5-0.7% of water weight.
- A kind of 5. method of Calophyllum preservative treatment according to claim 1, it is characterised in that above-mentioned steps（2）In, very In empty pressure impregnating method, the vacuum of impregnating autoclave is 0.045MPa, and the pressure for impregnating pressurization is 0.74MPa.
- A kind of 6. method of Calophyllum preservative treatment according to claim 1, it is characterised in that above-mentioned steps（3）In, dry Dry temperature is 65-70 DEG C, when the time of drying is 10-12 small.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711393448.4A CN107953433A (en) | 2017-12-21 | 2017-12-21 | A kind of method of Calophyllum preservative treatment |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711393448.4A CN107953433A (en) | 2017-12-21 | 2017-12-21 | A kind of method of Calophyllum preservative treatment |
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| CN107953433A true CN107953433A (en) | 2018-04-24 |
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| CN201711393448.4A Pending CN107953433A (en) | 2017-12-21 | 2017-12-21 | A kind of method of Calophyllum preservative treatment |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108789713A (en) * | 2018-06-26 | 2018-11-13 | 阜南县腾博工艺品有限公司 | A kind of Calophyllum anticorrosion treatment technology |
| CN116872316A (en) * | 2023-07-14 | 2023-10-13 | 贵州省林业科学研究院 | A kind of flame retardant preservative containing silver hybrid nanomaterial and flame retardant antiseptic bamboo wood and its preparation method |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108789713A (en) * | 2018-06-26 | 2018-11-13 | 阜南县腾博工艺品有限公司 | A kind of Calophyllum anticorrosion treatment technology |
| CN116872316A (en) * | 2023-07-14 | 2023-10-13 | 贵州省林业科学研究院 | A kind of flame retardant preservative containing silver hybrid nanomaterial and flame retardant antiseptic bamboo wood and its preparation method |
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