CN107937911B - Laser cladding wear-resistant and impact-resistant coating method on cast steel surface - Google Patents
Laser cladding wear-resistant and impact-resistant coating method on cast steel surface Download PDFInfo
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Abstract
本发明公开了一种铸钢表面激光熔覆耐磨耐冲击涂层方法,(1)将熔覆用金属粉末干燥90~120min,干燥温度为80~90℃;(2)将铸钢待处理表面用砂纸打磨进行毛化处理,而后用丙酮清洗油污待用;(3)对铸钢进行400~500℃的预加热处理(4)对预热处理后的铸钢表面进行激光熔凝处理;(5)待激光熔凝处理结束后,在已形成的激光熔凝层上进行同轴送粉激光熔覆金属合金打底层;(6)在已形成的金属合金打底层之上再次进行同轴送粉激光熔覆金属合金耐磨耐冲击层。
The invention discloses a laser cladding wear-resistant and impact-resistant coating method on the surface of cast steel. The surface is polished with sandpaper for roughening treatment, and then the oil stain is cleaned with acetone for use; (3) The cast steel is pre-heated at 400-500 °C (4) The surface of the pre-heated cast steel is laser-melted; (5) After the laser melting treatment is completed, coaxial powder feeding laser cladding metal alloy primer layer is carried out on the formed laser melting layer; (6) Coaxial laser cladding is performed again on the formed metal alloy layer Powder feeding laser cladding metal alloy wear-resistant and impact-resistant layer.
Description
技术领域technical field
本发明属于激光加工领域,涉及一种铸钢表面激光熔覆耐磨耐冲击涂层方法。The invention belongs to the field of laser processing and relates to a method for laser cladding a wear-resistant and impact-resistant coating on the surface of cast steel.
背景技术Background technique
铸钢是在凝固过程中不经历共晶转变的用于生产铸件的铁基合金的总称,其中碳元素为主要元素,含量在0~2%之间。根据在铸钢中的碳含量的不同,可将铸钢分为:低碳钢,中碳钢和高碳钢;根据在铸钢中的合金元素含量的不同,可将铸钢分为:铸造低合金钢、铸造中合金钢和铸造高合金钢。除以上种类外,还包括铸造特殊钢,例如铸造不锈钢、铸造耐磨钢与铸造耐热钢等。目前,铸钢材料因其优良的性能而广泛应用于机械加工、汽车、船舶以及石油化工等重工业领域。但在以上领域的工作环境中,长时间使用的铸钢部件易受到不同程度的冲击与磨损破坏,使用寿命急剧缩短,从而产生大量能耗、污染以及资源浪费。Cast steel is a general term for iron-based alloys used to produce castings that do not undergo eutectic transformation during solidification, in which carbon is the main element, and the content is between 0 and 2%. According to the carbon content in cast steel, cast steel can be divided into: low carbon steel, medium carbon steel and high carbon steel; according to the content of alloy elements in cast steel, cast steel can be divided into: casting Low alloy steel, cast medium alloy steel and cast high alloy steel. In addition to the above types, it also includes cast special steel, such as cast stainless steel, cast wear-resistant steel and cast heat-resistant steel. At present, cast steel materials are widely used in heavy industries such as machining, automobiles, ships, and petrochemicals because of their excellent performance. However, in the working environment of the above fields, the cast steel parts used for a long time are vulnerable to different degrees of impact and wear damage, and the service life is shortened sharply, resulting in a large amount of energy consumption, pollution and waste of resources.
为提高铸钢件耐磨性能,对铸钢件工作表面进行强化处理。目前,普通淬火与感应淬火为主要表面处理方法,部分研究者还采用激光淬火工艺强化铸钢件工作表面性能。但由于淬火工艺无法改变基体材料的本质性能,导致耐磨性能提升有限。采用激光熔覆技术在铸钢件表面制备金属合金涂层可以实现在原始材料表面覆着高性能材料,从而大幅提高铸钢件的耐磨性能。然而,由于铸钢在铸造过程可能存在较多气孔与夹渣,在激光熔覆过程中会在金属合金涂层中产生大量缺陷,使涂层与铸钢基材难以形成良好的冶金结合,降低涂层的耐磨耐冲击性能。In order to improve the wear resistance of steel castings, the working surface of steel castings is strengthened. At present, ordinary quenching and induction quenching are the main surface treatment methods, and some researchers also use laser quenching technology to strengthen the working surface properties of steel castings. However, since the quenching process cannot change the essential properties of the matrix material, the improvement in wear resistance is limited. The use of laser cladding technology to prepare metal alloy coatings on the surface of steel castings can realize the coating of high-performance materials on the surface of original materials, thereby greatly improving the wear resistance of steel castings. However, since cast steel may have many pores and slag inclusions in the casting process, a large number of defects will be generated in the metal alloy coating during the laser cladding process, making it difficult to form a good metallurgical bond between the coating and the cast steel substrate, reducing the The wear and impact resistance of the coating.
发明内容Contents of the invention
本发明技术解决问题:为了解决铸钢材料在激光熔覆过程中由于铸钢基体存在的气孔与夹渣缺陷而带来的熔覆层质量下降的问题,提供一种钢表面激光熔覆耐磨耐冲击涂层方法,实现无气孔与夹渣高耐磨耐冲击性涂层的制备。The technical solution of the present invention: In order to solve the problem of the degradation of the quality of the cladding layer caused by the pores and slag inclusion defects in the cast steel matrix during the laser cladding process of the cast steel material, a laser cladding wear-resistant laser cladding on the steel surface is provided. The impact-resistant coating method realizes the preparation of a high wear-resistant and impact-resistant coating without pores and slag inclusions.
本发明技术解决方案:一种铸钢表面激光熔覆耐磨耐冲击涂层方法,包括如下步骤:Technical solution of the present invention: a method for laser cladding a wear-resistant and impact-resistant coating on the surface of cast steel, comprising the following steps:
步骤一、将金属合金粉末进行称重并真空干燥,待后续激光熔覆使用;Step 1. Weigh the metal alloy powder and dry it in vacuum for use in subsequent laser cladding;
步骤二、将铸钢表面用砂纸打磨进行毛化处理,而后用丙酮清洗油污待用;Step 2, polishing the cast steel surface with sandpaper for roughening treatment, and then cleaning the oil stain with acetone for later use;
步骤三、对已经除去油污与锈蚀的铸钢进行预热处理,为激光熔凝处理做准备;Step 3. Preheating the cast steel that has been degreased and rusted to prepare for laser melting;
步骤四、对预热处理后的铸钢表面进行高功率激光熔凝处理,形成激光熔凝层,消除铸钢表面的缺陷与孔隙;Step 4. Perform high-power laser melting treatment on the surface of the preheated cast steel to form a laser fused layer to eliminate defects and pores on the cast steel surface;
步骤五、在铸钢所形成的激光熔凝层表面进行激光熔覆处理,氩气作为保护气,熔覆粉末采用韧性好,润湿铺展性强的金属合金粉末,金属合金粉末通过同轴送粉方法并利用氩气作为载粉气而吹送到铸钢激光熔凝层表面,在已形成的激光熔凝层上激光熔覆金属合金打底层,其主要作为铸钢与金属合金耐磨耐冲击层的连接层,使复合涂层与铸钢表面形成无气孔裂纹的良好结合;Step 5. Laser cladding treatment is performed on the surface of the laser fused layer formed by cast steel. Argon is used as the protective gas. The cladding powder is made of metal alloy powder with good toughness and strong wettability. The metal alloy powder is sent through the coaxial powder method and use argon as the powder carrier gas to blow to the surface of the cast steel laser melting layer, and laser cladding metal alloy primer on the formed laser melting layer, which is mainly used as cast steel and metal alloy wear resistance and impact resistance The connecting layer of the layer makes the composite coating and the cast steel surface form a good combination without pores and cracks;
步骤六、在铸钢所形成的金属合金打底层表面进行激光熔覆处理,氩气作为保护气,熔覆粉末采用耐磨耐冲击性能良好的金属合金粉末通过同轴送粉方法并利用氩气作为载粉气而吹送到铸钢金属合金打底层表面,在已形成的金属合金打底层上激光熔覆金属合金耐磨耐冲击层。Step 6: Carry out laser cladding treatment on the surface of the metal alloy base layer formed by cast steel, argon gas is used as the protective gas, and the cladding powder is made of metal alloy powder with good wear resistance and impact resistance through the coaxial powder feeding method and using argon gas As a powder-carrying gas, it is blown to the surface of the cast steel metal alloy primer layer, and the laser cladding metal alloy wear-resistant and impact-resistant layer is formed on the formed metal alloy primer layer.
进一步的,所述步骤一进一步包括:将称重后的粉末在80~90℃的真空干燥箱中干燥90~120min。Further, the step 1 further includes: drying the weighed powder in a vacuum oven at 80-90° C. for 90-120 minutes.
进一步的,所述步骤三进一步包括:Further, said step three further includes:
对铸钢进行400~500℃的预加热处理;Preheating the cast steel at 400-500°C;
进一步的,所述步骤四进一步包括:Further, said step four further includes:
所形成的熔凝层深0.3~0.5mm,熔凝层均匀无缺陷、无裂纹;The formed fused layer is 0.3-0.5mm deep, and the fused layer is uniform without defects and cracks;
进一步的,所述步骤五进一步包括:Further, said step five further includes:
所形成的金属合金打底层厚度为0.3~0.5mm;The thickness of the formed metal alloy primer layer is 0.3-0.5mm;
进一步的,所述步骤五进一步还包括:Further, said step five further includes:
打底层所采用的金属合金粉末的化学成分(各元素质量百分比)为:C:0.02%~0.03%、Si:0.1%~0.14%、Mn:0.4%~0.46%、Cr:15.5%~16.5%、Co:2.0%~2.8%Mo:15.5%~16.5%、W:3.8%~4.6%、Nb:0.31%~0.37%、Fe:0.7%~0.8%、Ni:余量;The chemical composition (mass percentage of each element) of the metal alloy powder used in the bottom layer is: C: 0.02% ~ 0.03%, Si: 0.1% ~ 0.14%, Mn: 0.4% ~ 0.46%, Cr: 15.5% ~ 16.5% , Co: 2.0% ~ 2.8% Mo: 15.5% ~ 16.5%, W: 3.8% ~ 4.6%, Nb: 0.31% ~ 0.37%, Fe: 0.7% ~ 0.8%, Ni: the balance;
进一步的,所述步骤六进一步包括:Further, said step six further includes:
所形成的金属合金耐磨耐冲击层厚度为0.8~1.0mm;The formed metal alloy wear-resistant and impact-resistant layer has a thickness of 0.8-1.0mm;
进一步的,所述步骤六进一步还包括:Further, said step six further includes:
耐磨耐冲击层所采用的金属合金粉末的化学成分(各元素质量百分比)为:C:0.30%~0.34%、Si:3.5%~4.3%、Cr:10.5%~11.5%、B:2.0%~2.6%、Fe:10.0%~11.0%、Ni:余量;The chemical composition (mass percentage of each element) of the metal alloy powder used in the wear-resistant and impact-resistant layer is: C: 0.30% ~ 0.34%, Si: 3.5% ~ 4.3%, Cr: 10.5% ~ 11.5%, B: 2.0% ~2.6%, Fe: 10.0%~11.0%, Ni: balance;
进一步,步骤四中,激光功率2000~3500W,扫描速率200~350mm/min,光斑直径4~6mm;Further, in step 4, the laser power is 2000-3500W, the scanning rate is 200-350mm/min, and the spot diameter is 4-6mm;
进一步,步骤五中,激光功率1500~2500W,扫描速率200~350mm/min,送粉速率3~5g/min,光斑直径2~4mm,保护气流量6~10l/min;Further, in step five, the laser power is 1500-2500W, the scanning rate is 200-350mm/min, the powder feeding rate is 3-5g/min, the spot diameter is 2-4mm, and the protective gas flow rate is 6-10l/min;
进一步,步骤六中,激光功率1800~2600W,扫描速率250~400mm/min,送粉速率5~8g/min,光斑直径2~4mm,其中保护气流量8~15l/min。Further, in Step 6, the laser power is 1800-2600W, the scanning rate is 250-400mm/min, the powder feeding rate is 5-8g/min, the spot diameter is 2-4mm, and the protective gas flow rate is 8-15l/min.
本发明与现有技术相比的优点在于:The advantage of the present invention compared with prior art is:
(1)在激光熔凝过程中,激光可以将铸钢件表层熔化并再次凝固,在此过程中铸钢表层存在的铸造气孔与夹渣等缺陷会被消除,从而有效减少激光熔覆金属合金涂层与基体结合区的缺陷,使铸钢基体与金属合金打底层之间形成良好的冶金结合;(1) During the laser melting process, the laser can melt and re-solidify the surface of the steel casting. During this process, the defects such as casting pores and slag inclusions on the surface of the cast steel will be eliminated, thereby effectively reducing the laser cladding metal alloy. The defects in the bonding area between the coating and the substrate make a good metallurgical bond between the cast steel substrate and the metal alloy primer;
(2)激光熔覆形成的金属合金打底层主要由韧性好,润湿铺展性强的金属合金粉末制成,其为铸钢与金属合金耐磨耐冲击层的连接层,由于金属合金打底层具有良好的韧性和润湿性,在铸钢与金属合金打底层之间形成无气孔裂纹的冶金结合区,证明铸钢基材与金属合金打底层具有良好的结合效果。(2) The metal alloy base layer formed by laser cladding is mainly made of metal alloy powder with good toughness and strong wettability and spreadability. It is the connecting layer between cast steel and metal alloy wear-resistant and impact-resistant layer. It has good toughness and wettability, and a metallurgical bonding zone without porosity and cracks is formed between the cast steel and the metal alloy primer, which proves that the cast steel substrate and the metal alloy primer have a good bonding effect.
(3)激光熔覆形成的金属合金耐磨耐冲击层主要由具有耐磨耐冲击性能的金属合金粉末制成,因合金粉末良好的减磨与耐磨耐冲击属性,相关实验证明所形成的金属合金层具有较好的耐磨减磨与耐冲击性能。(3) The metal alloy wear-resistant and impact-resistant layer formed by laser cladding is mainly made of metal alloy powder with wear-resistant and impact-resistant properties. Due to the good wear-reducing, wear-resistant and impact-resistant properties of the alloy powder, relevant experiments have proved that the formed The metal alloy layer has good wear-resistance and impact-resistance properties.
附图说明Description of drawings
图1为本发明方法工艺流程图;Fig. 1 is a process flow diagram of the method of the present invention;
图2为实施例1中42CrMo铸钢表面激光熔覆耐磨耐冲击涂层金相图片;Fig. 2 is the metallographic picture of the laser cladding wear-resistant and impact-resistant coating on the surface of 42CrMo cast steel in embodiment 1;
图3为实施例1中42CrMo铸钢不同表面处理方式条件下的磨损率对比图;Fig. 3 is the comparison chart of wear rate under the different surface treatment mode conditions of 42CrMo cast steel in embodiment 1;
图4为实施例1中42CrMo铸钢不同表面处理方式条件下的摩擦系数对比图;Fig. 4 is the friction coefficient contrast chart under the different surface treatment mode conditions of 42CrMo cast steel in embodiment 1;
图5为实施例1中42CrMo铸钢不同表面处理方式条件下的平均冲击功对比图;Fig. 5 is the average impact energy contrast figure under the different surface treatment mode conditions of 42CrMo cast steel in embodiment 1;
图6为实施例1中42CrMo铸钢激光熔覆耐磨耐冲击涂层在室温时与500℃高温回火后的显微硬度曲线图。Fig. 6 is a graph showing microhardness curves of the laser cladding wear-resistant and impact-resistant coating on 42CrMo cast steel in Example 1 at room temperature and after tempering at a high temperature of 500°C.
具体实施方式Detailed ways
下面结合附图及具体实施例详细介绍本发明。但以下的实施例仅限于解释本发明,本发明的保护范围应包括权利要求的全部内容,不仅仅限于本实施例。The present invention will be described in detail below in conjunction with the accompanying drawings and specific embodiments. But the following embodiments are only limited to explain the present invention, and the protection scope of the present invention should include the entire content of the claims, not only limited to the present embodiment.
如图1所示,本发明一种铸钢表面激光熔覆耐磨耐冲击涂层方法的具体实施步骤如下:As shown in Figure 1, the specific implementation steps of a laser cladding wear-resistant and impact-resistant coating method on the surface of cast steel of the present invention are as follows:
步骤一、将金属合金粉末进行称重后在80~90℃的真空干燥箱中干燥90~120min;Step 1, weighing the metal alloy powder and drying it in a vacuum oven at 80-90°C for 90-120 minutes;
步骤二、将铸钢部件待处理表面用砂纸打磨进行毛化处理,而后用丙酮清洗油污待用;Step 2, polishing the surface of the cast steel part to be treated with sandpaper for roughening treatment, and then cleaning the oil stain with acetone for use;
步骤三、对已经除去油污与锈蚀的铸钢进行400~500℃预热处理,为激光熔凝处理做准备;Step 3: Preheat the cast steel that has been degreased and rusted at 400-500°C to prepare for laser melting;
步骤四、对预热处理后的铸钢表面进行高功率激光熔凝处理,形成激光熔凝层,消除铸钢表面的缺陷与孔隙;Step 4. Perform high-power laser melting treatment on the surface of the preheated cast steel to form a laser fused layer to eliminate defects and pores on the cast steel surface;
所采用工艺参数为:激光功率2000~3500W,扫描速率200~350mm/min,光斑直径4~6mm,所形成的熔凝层深0.3~0.5mm,熔凝层均匀无缺陷、无裂纹;The process parameters used are: laser power 2000-3500W, scanning speed 200-350mm/min, spot diameter 4-6mm, the depth of the formed fused layer is 0.3-0.5mm, and the fused layer is uniform without defects and cracks;
步骤五、在铸钢所形成的激光熔凝层表面进行激光熔覆处理,氩气作为保护气,熔覆粉末采用韧性好,润湿铺展性强的金属合金粉末,粉末通过同轴送粉方法并利用氩气作为载粉气而吹送到铸钢激光熔凝层表面,在已形成的激光熔凝层上激光熔覆金属合金打底层,其主要作为铸钢与金属合金耐磨耐冲击层的连接层,使复合涂层与铸钢表面形成无气孔裂纹的良好结合;Step 5. Laser cladding treatment is performed on the surface of the laser fused layer formed by cast steel. Argon gas is used as a protective gas. The cladding powder is made of metal alloy powder with good toughness and strong wettability and spreadability. The powder is fed through the coaxial powder method. And use argon as the carrier gas to blow it to the surface of the cast steel laser melting layer, and laser cladding the metal alloy primer layer on the formed laser melting layer, which is mainly used as the wear-resistant and impact-resistant layer of cast steel and metal alloy Connecting layer, so that the composite coating and the cast steel surface form a good combination without pores and cracks;
所采用工艺参数为:激光熔覆工艺参数为:激光功率1500~2500W,扫描速率200~350mm/min,送粉速率3~5g/min,光斑直径2~4mm,保护气流量6~10l/min,所形成的金属合金打底层厚度为0.3~0.5mm;打底层所采用的金属合金粉末的化学成分(各元素质量百分比)为:C:0.02%~0.03%、Si:0.1%~0.14%、Mn:0.4%~0.46%、Cr:15.5%~16.5%、Co:2.0%~2.8%、Mo:15.5%~16.5%、W:3.8%~4.6%、Nb:0.31%~0.37%、Fe:0.7%~0.8%、Ni:余量;The process parameters used are: laser cladding process parameters are: laser power 1500~2500W, scanning speed 200~350mm/min, powder feeding rate 3~5g/min, spot diameter 2~4mm, protective gas flow 6~10l/min , the thickness of the formed metal alloy primer layer is 0.3-0.5mm; the chemical composition (mass percentage of each element) of the metal alloy powder used in the primer layer is: C: 0.02%-0.03%, Si: 0.1%-0.14%, Mn: 0.4% to 0.46%, Cr: 15.5% to 16.5%, Co: 2.0% to 2.8%, Mo: 15.5% to 16.5%, W: 3.8% to 4.6%, Nb: 0.31% to 0.37%, Fe: 0.7%~0.8%, Ni: balance;
步骤六、在铸钢所形成的金属合金打底层表面进行激光熔覆处理,氩气作为保护气,熔覆粉末采用耐磨耐冲击性能良好的金属合金粉末,粉末通过同轴送粉方法并利用氩气作为载粉气而吹送到铸钢金属合金打底层表面,在已形成的金属合金打底层上激光熔覆金属合金耐磨耐冲击层。Step 6. Laser cladding treatment is performed on the surface of the metal alloy base layer formed by cast steel. Argon gas is used as the protective gas. The cladding powder is made of metal alloy powder with good wear resistance and impact resistance. The powder is fed through the coaxial powder method and used The argon gas is blown to the surface of the cast steel metal alloy primer layer as a carrier gas, and the metal alloy wear-resistant and impact-resistant layer is laser cladding on the formed metal alloy primer layer.
所采用工艺参数为:激光熔覆工艺参数为:激光功率1800~2600W,扫描速率250~400mm/min,送粉速率5~8g/min,光斑直径2~4mm,保护气流量8~15l/min,所形成的金属合金耐磨耐冲击层厚度为0.8~1.0mm;The process parameters used are: laser cladding process parameters are: laser power 1800~2600W, scanning speed 250~400mm/min, powder feeding rate 5~8g/min, spot diameter 2~4mm, protective gas flow 8~15l/min , the thickness of the formed metal alloy wear-resistant and impact-resistant layer is 0.8-1.0mm;
耐磨耐冲击层所采用的金属合金粉末的化学成分(各元素质量百分比)为:C:0.30%~0.34%、Si:3.5%~4.3%、Cr:10.5%~11.5%、B:2.0%~2.6%、Fe:10.0%~11.0%、Ni:余量;The chemical composition (mass percentage of each element) of the metal alloy powder used in the wear-resistant and impact-resistant layer is: C: 0.30% ~ 0.34%, Si: 3.5% ~ 4.3%, Cr: 10.5% ~ 11.5%, B: 2.0% ~2.6%, Fe: 10.0%~11.0%, Ni: balance;
实施例1Example 1
本实施例以铸钢ZG 42CrMo为基体,打底层材料为镍基合金粉末,化学成分(各元素质量百分比)为:C:0.02%、Si:0.1%、Mn:0.4%、Cr:15.5%、Co:2.0%、Mo:15.5%、W:3.8%、Nb:0.31%、Fe:0.7%、Ni:余量;耐磨耐冲击层材料为铁基合金粉末,化学成分(各元素质量百分比)为:C:0.30%、Si:3.5%、Cr:10.5%、B:2.0%、Fe:10.0%、Ni:余量;In this embodiment, cast steel ZG 42CrMo is used as the matrix, and the base layer material is nickel-based alloy powder. The chemical composition (mass percentage of each element) is: C:0.02%, Si:0.1%, Mn:0.4%, Cr:15.5%, Co: 2.0%, Mo: 15.5%, W: 3.8%, Nb: 0.31%, Fe: 0.7%, Ni: balance; the wear-resistant and impact-resistant layer material is iron-based alloy powder, chemical composition (mass percentage of each element) For: C: 0.30%, Si: 3.5%, Cr: 10.5%, B: 2.0%, Fe: 10.0%, Ni: balance;
具体实施步骤如下:The specific implementation steps are as follows:
(1)将镍基合金粉末与铁基合金粉末进行称重后在80℃的真空干燥箱中干燥90min;(1) After weighing the nickel-based alloy powder and the iron-based alloy powder, dry them in a vacuum oven at 80°C for 90 minutes;
(2)将ZG 42CrMo待处理表面用砂纸打磨进行毛化处理,而后用丙酮清洗油污待用;(2) Grinding the ZG 42CrMo surface to be treated with sandpaper for roughening treatment, and then cleaning the oil stain with acetone for later use;
(3)将ZG 42CrMo进行400℃预热处理,加热1h;(3) Preheat ZG 42CrMo at 400°C for 1 hour;
(4)对预热后的ZG 42CrMo进行激光熔凝处理,其中激光熔凝采用工艺参数为:激光功率2000W,扫描速率200mm/min,光斑直径5mm,所形成的激光熔凝层厚度为0.4mm,熔凝层均匀无缺陷、无裂纹;(4) Perform laser melting treatment on the preheated ZG 42CrMo, wherein the laser melting process parameters are: laser power 2000W, scanning rate 200mm/min, spot diameter 5mm, and the thickness of the formed laser melting layer is 0.4mm , the fused layer is uniform without defects and cracks;
(5)待激光熔凝处理结束后,在已形成的激光熔凝层上进行同轴送粉激光熔覆镍基合金打底层,激光熔覆工艺参数为:激光功率1500W,扫描速率200mm/min,送粉速率4g/min,光斑直径2mm,保护气与载粉气均为氩气,其中保护气流量6l/min,所形成的镍基合金打底层厚度为0.4mm;(5) After the laser melting treatment is completed, the coaxial powder feeding laser cladding nickel-based alloy primer layer is carried out on the formed laser melting layer. The laser cladding process parameters are: laser power 1500W, scanning speed 200mm/min , the powder feeding rate is 4g/min, the spot diameter is 2mm, the protective gas and powder carrier gas are both argon, and the protective gas flow rate is 6l/min, and the thickness of the formed nickel-based alloy primer layer is 0.4mm;
(6)在已形成的镍基合金打底层之上再次进行同轴送粉激光熔覆铁基合金耐磨耐冲击层,激光熔覆工艺参数为:激光功率2600W,扫描速率400mm/min,送粉速率7g/min,光斑直径4mm,保护气与载粉气均为氩气,其中保护气流量15l/min,所形成的金属合金耐磨耐冲击层厚度为0.9mm,最后形成的激光熔覆涂层无气孔裂纹,与铸钢ZG42CrMo表面结合良好,无缺陷产生,耐磨性测试证明:激光熔覆处理后的铸钢ZG42CrMo的磨损率比单独激光淬火和未处理的铸钢ZG 42CrMo显著减少,摩擦系数显著减小,冲击功增大,其耐磨减磨与耐冲击性能显著提高。(6) Carry out coaxial powder-feeding laser cladding on the formed nickel-based alloy primer layer again. The wear-resistant and impact-resistant layer of iron-based alloy is carried out. The powder rate is 7g/min, the spot diameter is 4mm, the protective gas and powder carrier gas are both argon, and the protective gas flow rate is 15l/min, the thickness of the wear-resistant and impact-resistant layer of the metal alloy formed is 0.9mm, and the final laser cladding The coating has no pores and cracks, is well combined with the surface of cast steel ZG42CrMo, and has no defects. The wear resistance test proves that the wear rate of cast steel ZG42CrMo after laser cladding treatment is significantly lower than that of laser quenched and untreated cast steel ZG 42CrMo , the friction coefficient is significantly reduced, the impact energy is increased, and its wear resistance and impact resistance are significantly improved.
实施例2Example 2
本实施例以铸钢ZG 40Cr为基体,打底层材料为镍基合金粉末,化学成分(各元素质量百分比)为:C:0.025%、Si:0.12%、Mn:0.43%、Cr:16%、Co:2.4%、Mo:16%、W:4.2%、Nb:0.34%、Fe:0.75%、Ni:余量;耐磨耐冲击层材料为镍基合金粉末,化学成分(各元素质量百分比)为:C:0.32%、Si:3.9%、Cr:11、B:2.3%、Fe:10.5%、Ni:余量;具体实施步骤如下:In this embodiment, cast steel ZG 40Cr is used as the substrate, and the base layer material is nickel-based alloy powder. The chemical composition (mass percentage of each element) is: C:0.025%, Si:0.12%, Mn:0.43%, Cr:16%, Co: 2.4%, Mo: 16%, W: 4.2%, Nb: 0.34%, Fe: 0.75%, Ni: balance; the wear-resistant and impact-resistant layer material is nickel-based alloy powder, chemical composition (mass percentage of each element) For: C: 0.32%, Si: 3.9%, Cr: 11, B: 2.3%, Fe: 10.5%, Ni: balance; the specific implementation steps are as follows:
(1)将镍基合金粉末与铁基合金粉末进行称重后在85℃的真空干燥箱中干燥100min;(1) After weighing the nickel-based alloy powder and the iron-based alloy powder, dry them in a vacuum oven at 85°C for 100 minutes;
(2)将ZG 40Cr待处理表面用砂纸打磨进行毛化处理,而后用丙酮清洗油污待用;(2) Grinding the surface of ZG 40Cr to be treated with sandpaper for roughening treatment, and then cleaning the oil stain with acetone for later use;
(3)将ZG 40Cr进行450℃预热处理,加热1h;(3) Preheat ZG 40Cr at 450°C for 1 hour;
(4)对预热后的ZG 35SiMn进行激光熔凝处理,其中激光熔凝采用工艺参数为:激光功率2500W,扫描速率250mm/min,光斑直径4mm,所形成的激光熔凝层厚度为0.5mm,熔凝层均匀无缺陷、无裂纹;(4) Perform laser melting treatment on the preheated ZG 35SiMn, wherein the laser melting process parameters are: laser power 2500W, scanning speed 250mm/min, spot diameter 4mm, and the thickness of the formed laser melting layer is 0.5mm , the fused layer is uniform without defects and cracks;
(5)待激光熔凝处理结束后,在已形成的激光熔凝层上进行同轴送粉激光熔覆镍基合金打底层,激光熔覆工艺参数为:激光功率2500W,扫描速率350mm/min,送粉速率5g/min,光斑直径3mm,保护气与载粉气均为氩气,其中保护气流量8l/min,所形成的镍基合金打底层厚度为0.5mm;(5) After the laser melting treatment is completed, the coaxial powder feeding laser cladding nickel-based alloy primer layer is carried out on the formed laser melting layer. The laser cladding process parameters are: laser power 2500W, scanning speed 350mm/min , the powder feeding rate is 5g/min, the spot diameter is 3mm, the protective gas and the carrier gas are both argon, and the flow rate of the protective gas is 8l/min, and the thickness of the formed nickel-based alloy primer layer is 0.5mm;
(6)在已形成的镍基合金打底层之上再次进行同轴送粉激光熔覆铁基合金耐磨耐冲击层,激光熔覆工艺参数为:激光功率2200W,扫描速率350mm/min,送粉速率5g/min,光斑直径2mm,保护气与载粉气均为氩气,其中保护气流量10l/min,所形成的金属合金耐磨耐冲击层厚度为0.8mm,最后形成的激光熔覆涂层无气孔裂纹,与铸钢ZG 40Cr表面结合良好,无缺陷产生,耐磨性与耐冲击性测试结果与实施例1相似,耐磨减磨与耐冲击性能显著提高。(6) Carry out coaxial powder-feeding laser cladding on the formed nickel-based alloy primer layer again, the wear-resistant and impact-resistant layer of iron-based alloy, the laser cladding process parameters are: laser power 2200W, scanning speed 350mm/min, send The powder rate is 5g/min, the spot diameter is 2mm, the protective gas and powder carrier gas are both argon, and the protective gas flow rate is 10l/min, the thickness of the formed metal alloy wear-resistant and impact-resistant layer is 0.8mm, and the final laser cladding The coating has no pores and cracks, is well combined with the surface of cast steel ZG 40Cr, and has no defects. The test results of wear resistance and impact resistance are similar to those of Example 1, and the wear resistance and impact resistance properties are significantly improved.
实施例3Example 3
本实施例以铸钢ZG 35SiMn为基体,打底层材料为镍基合金粉末,化学成分(各元素质量百分比)为:C:0.03%、Si:0.14%、Mn:0.46%、Cr:16.5%、Co:2.8%、Mo:16.5%、W:4.6%、Nb:0.37%、Fe:0.8%、Ni:余量;耐磨耐冲击层材料为镍基合金粉末,化学成分(各元素质量百分比)为:C:0.34%、Si:4.3%、Cr:11.5%、B:2.6%、Fe:11.0%、Ni:余量;具体实施步骤如下:In this embodiment, cast steel ZG 35SiMn is used as the substrate, and the base layer material is nickel-based alloy powder. The chemical composition (mass percentage of each element) is: C:0.03%, Si:0.14%, Mn:0.46%, Cr:16.5%, Co: 2.8%, Mo: 16.5%, W: 4.6%, Nb: 0.37%, Fe: 0.8%, Ni: balance; the wear-resistant and impact-resistant layer material is nickel-based alloy powder, chemical composition (mass percentage of each element) For: C: 0.34%, Si: 4.3%, Cr: 11.5%, B: 2.6%, Fe: 11.0%, Ni: balance; concrete implementation steps are as follows:
(1)将镍基合金粉末与铁基合金粉末进行称重后在90℃的真空干燥箱中干燥120min;(1) Dry the nickel-based alloy powder and the iron-based alloy powder in a vacuum oven at 90°C for 120 minutes after weighing;
(2)将ZG 35SiMn待处理表面用砂纸打磨进行毛化处理,而后用丙酮清洗油污待用;(2) Grinding the surface of ZG 35SiMn to be treated with sandpaper for roughening treatment, and then cleaning the oil stain with acetone for later use;
(3)将ZG 35SiMn进行500℃预热处理,加热1h;(3) Preheat ZG 35SiMn at 500°C for 1 hour;
(4)对预热后的ZG 35SiMn进行激光熔凝处理,其中激光熔凝采用工艺参数为:激光功率3500W,扫描速率350mm/min,光斑直径6mm,所形成的激光熔凝层厚度为0.3mm,熔凝层均匀无缺陷、无裂纹;(4) Perform laser melting treatment on the preheated ZG 35SiMn, wherein the laser melting process parameters are: laser power 3500W, scanning speed 350mm/min, spot diameter 6mm, and the thickness of the formed laser melting layer is 0.3mm , the fused layer is uniform without defects and cracks;
(5)待激光熔凝处理结束后,在已形成的激光熔凝层上进行同轴送粉激光熔覆镍基合金打底层,激光熔覆工艺参数为:激光功率1700W,扫描速率300mm/min,送粉速率3g/min,光斑直径2mm,保护气与载粉气均为氩气,其中保护气流量6l/min,所形成的镍基合金打底层厚度为0.3mm;(5) After the laser melting treatment is completed, the coaxial powder feeding laser cladding nickel-based alloy primer layer is carried out on the formed laser melting layer. The laser cladding process parameters are: laser power 1700W, scanning speed 300mm/min , the powder feeding rate is 3g/min, the spot diameter is 2mm, the shielding gas and the carrier gas are both argon, and the flow rate of the shielding gas is 6l/min, and the thickness of the formed nickel-based alloy primer layer is 0.3mm;
(6)在已形成的镍基合金打底层之上再次进行同轴送粉激光熔覆铁基合金耐磨耐冲击层,激光功率1800W,扫描速率250mm/min,送粉速率8g/min,光斑直径2mm,保护气与载粉气均为氩气,其中保护气流量8l/min,所形成的金属合金耐磨耐冲击层厚度为1.0mm,最后形成的激光熔覆涂层无气孔裂纹,与铸钢ZG 35SiMn表面结合良好,无缺陷产生,耐磨性与耐冲击性测试结果与实施例1相似,耐磨减磨与耐冲击性能显著提高。(6) Coaxial powder feeding laser cladding of iron-based alloy wear-resistant and impact-resistant layer is carried out again on the formed nickel-based alloy primer layer. The laser power is 1800W, the scanning rate is 250mm/min, the powder feeding rate is 8g/min, and the spot The diameter is 2mm, the protective gas and powder carrier gas are both argon, and the protective gas flow rate is 8l/min. The thickness of the wear-resistant and impact-resistant layer of the metal alloy formed is 1.0mm. The final laser cladding coating has no pores and cracks. The surface of the cast steel ZG 35SiMn is well bonded and no defects are generated. The test results of wear resistance and impact resistance are similar to those of Example 1, and the wear resistance and impact resistance properties are significantly improved.
如图2所示,耐磨复合涂层与42CrMo铸钢表面形成良好的冶金结合,结合部位基本无气孔、缺陷,涂层无裂纹。As shown in Figure 2, the wear-resistant composite coating forms a good metallurgical bond with the surface of the 42CrMo cast steel, and the bonding part is basically free of pores and defects, and the coating has no cracks.
如图3所示,42CrMo铸钢在表面未处理、激光熔凝处理以及激光熔覆处理的条件下磨损率逐渐减小,说明激光熔覆处理可以有效提高蠕墨铸钢表面的耐磨性。As shown in Figure 3, the wear rate of 42CrMo cast steel gradually decreases under the conditions of untreated surface, laser melting treatment and laser cladding treatment, indicating that laser cladding treatment can effectively improve the wear resistance of the surface of vermicular graphite cast steel.
如图4所示,42CrMo铸钢在表面未处理、激光熔凝处理以及激光熔覆处理的条件下摩擦系数逐渐减小,说明激光熔覆处理可以有效提高蠕墨铸钢表面的减磨性。As shown in Figure 4, the friction coefficient of 42CrMo cast steel gradually decreases under the conditions of untreated surface, laser melting treatment and laser cladding treatment, indicating that laser cladding treatment can effectively improve the wear reduction of the surface of vermicular graphite cast steel.
如图5所示,实施例1中42CrMo铸钢在激光熔凝处理、表面未处理以及激光熔覆处理的条件下平均冲击功依次增大,并且冲击功越大则耐冲击性能越好,说明激光熔覆处理可以有效提高蠕墨铸钢表面的耐冲击性能。As shown in Figure 5, the average impact energy of the 42CrMo cast steel in Example 1 increases sequentially under the conditions of laser melting treatment, untreated surface and laser cladding treatment, and the greater the impact energy, the better the impact resistance, indicating that Laser cladding treatment can effectively improve the impact resistance of the surface of compacted graphite cast steel.
如图6所示,实施例1中42CrMo铸钢激光熔覆制备的耐磨耐冲击涂层在常温下与500℃高温回火后耐磨层硬度基本无变化,激光熔凝层硬度则显著下降,说明激光熔覆处理可以有效提高蠕墨铸钢表面的耐高温回火性能。As shown in Figure 6, the wear-resistant and impact-resistant coating prepared by laser cladding of 42CrMo cast steel in Example 1 has basically no change in the hardness of the wear-resistant layer after tempering at room temperature and at a high temperature of 500 °C, while the hardness of the laser-melted layer decreases significantly , indicating that laser cladding treatment can effectively improve the high temperature tempering performance of the surface of vermicular graphite cast steel.
需要说明的是,按照本发明上述各实施例,本领域技术人员是完全可以实现本发明独立权利要求及从属权利的全部范围的,实现过程及方法同上述各实施例;且本发明未详细阐述部分属于本领域公知技术。It should be noted that, according to the above-mentioned embodiments of the present invention, those skilled in the art can fully realize the full scope of the independent claims and dependent rights of the present invention, and the implementation process and method are the same as the above-mentioned embodiments; and the present invention is not elaborated Some of them belong to well-known technologies in the art.
提供以上实施例仅仅是为了描述本发明的目的,而并非要限制本发明的范围,实验结果与实施例1接近。本发明的范围由所附权利要求限定。不脱离本发明的精神和原理而做出的各种等同替换和修改,均应涵盖在本发明的范围之内。The above examples are provided only for the purpose of describing the present invention, not to limit the scope of the present invention, and the experimental results are close to those of Example 1. The scope of the invention is defined by the appended claims. Various equivalent replacements and modifications made without departing from the spirit and principle of the present invention shall fall within the scope of the present invention.
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