CN107916183A - A kind of novel environment friendly chemical industry equipment detergent - Google Patents
A kind of novel environment friendly chemical industry equipment detergent Download PDFInfo
- Publication number
- CN107916183A CN107916183A CN201711298797.8A CN201711298797A CN107916183A CN 107916183 A CN107916183 A CN 107916183A CN 201711298797 A CN201711298797 A CN 201711298797A CN 107916183 A CN107916183 A CN 107916183A
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- CN
- China
- Prior art keywords
- parts
- chemical industry
- environment friendly
- novel environment
- industry equipment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000003599 detergent Substances 0.000 title claims abstract description 39
- 239000000126 substance Substances 0.000 title claims abstract description 36
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 39
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 36
- -1 sorbitan fatty acid ester Chemical class 0.000 claims abstract description 36
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims abstract description 34
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000004094 surface-active agent Substances 0.000 claims abstract description 22
- 239000000341 volatile oil Substances 0.000 claims abstract description 22
- 239000001509 sodium citrate Substances 0.000 claims abstract description 19
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims abstract description 19
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 18
- 235000017550 sodium carbonate Nutrition 0.000 claims abstract description 18
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 18
- 235000010265 sodium sulphite Nutrition 0.000 claims abstract description 17
- 239000002562 thickening agent Substances 0.000 claims abstract description 17
- 239000002738 chelating agent Substances 0.000 claims abstract description 16
- 239000008367 deionised water Substances 0.000 claims abstract description 15
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 15
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 13
- 239000000194 fatty acid Substances 0.000 claims abstract description 13
- 229930195729 fatty acid Natural products 0.000 claims abstract description 13
- 239000002480 mineral oil Substances 0.000 claims abstract description 12
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 12
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 12
- 230000007797 corrosion Effects 0.000 claims abstract description 10
- 238000005260 corrosion Methods 0.000 claims abstract description 10
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 10
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 10
- 238000005202 decontamination Methods 0.000 claims abstract description 4
- 230000003588 decontaminative effect Effects 0.000 claims abstract description 3
- 241000196324 Embryophyta Species 0.000 claims description 16
- 238000005282 brightening Methods 0.000 claims description 13
- 229930003944 flavone Natural products 0.000 claims description 12
- 235000011949 flavones Nutrition 0.000 claims description 12
- 235000011083 sodium citrates Nutrition 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 9
- 239000000654 additive Substances 0.000 claims description 9
- 230000000996 additive effect Effects 0.000 claims description 9
- 239000000872 buffer Substances 0.000 claims description 9
- GAMYVSCDDLXAQW-AOIWZFSPSA-N Thermopsosid Natural products O(C)c1c(O)ccc(C=2Oc3c(c(O)cc(O[C@H]4[C@H](O)[C@@H](O)[C@H](O)[C@H](CO)O4)c3)C(=O)C=2)c1 GAMYVSCDDLXAQW-AOIWZFSPSA-N 0.000 claims description 8
- VHBFFQKBGNRLFZ-UHFFFAOYSA-N vitamin p Natural products O1C2=CC=CC=C2C(=O)C=C1C1=CC=CC=C1 VHBFFQKBGNRLFZ-UHFFFAOYSA-N 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 239000003513 alkali Substances 0.000 claims description 6
- 241000723347 Cinnamomum Species 0.000 claims description 5
- 239000004115 Sodium Silicate Substances 0.000 claims description 5
- 235000017803 cinnamon Nutrition 0.000 claims description 5
- HVQAJTFOCKOKIN-UHFFFAOYSA-N flavonol Natural products O1C2=CC=CC=C2C(=O)C(O)=C1C1=CC=CC=C1 HVQAJTFOCKOKIN-UHFFFAOYSA-N 0.000 claims description 5
- 150000002216 flavonol derivatives Chemical class 0.000 claims description 5
- 235000011957 flavonols Nutrition 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 229920001451 polypropylene glycol Polymers 0.000 claims description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 4
- 229930003949 flavanone Natural products 0.000 claims description 4
- 235000011981 flavanones Nutrition 0.000 claims description 4
- 150000002208 flavanones Chemical class 0.000 claims description 4
- 150000002213 flavones Chemical class 0.000 claims description 4
- 229930182470 glycoside Natural products 0.000 claims description 4
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 239000004021 humic acid Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 3
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 3
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical class [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims description 3
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 2
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 2
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 claims 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 229930003935 flavonoid Natural products 0.000 claims 1
- 235000017173 flavonoids Nutrition 0.000 claims 1
- DYZZHVWURQZXFC-UHFFFAOYSA-N styrene;triazine Chemical compound C1=CN=NN=C1.C=CC1=CC=CC=C1 DYZZHVWURQZXFC-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 4
- 239000012752 auxiliary agent Substances 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 230000001681 protective effect Effects 0.000 abstract description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 4
- HDWLUGYOLUHEMN-UHFFFAOYSA-N Dinobuton Chemical group CCC(C)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1OC(=O)OC(C)C HDWLUGYOLUHEMN-UHFFFAOYSA-N 0.000 description 4
- 241000425573 Talanes Species 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 230000007794 irritation Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 231100000252 nontoxic Toxicity 0.000 description 3
- 230000003000 nontoxic effect Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical class CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000040710 Chela Species 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 150000008131 glucosides Chemical class 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1233—Carbonates, e.g. calcite or dolomite
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2096—Heterocyclic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
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- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of novel environment friendly chemical industry equipment detergent, it is characterised in that：Including following composition by weight：10 ~ 20 parts of alkylpolyoxyethylene sodium sulphate, 4 ~ 10 parts of sorbitan fatty acid ester, 1 ~ 5 part of soda ash, 0.5 ~ 2 part of sodium citrate, 2 ~ 8 parts of sodium sulfite, 0.5 ~ 1.6 part of chelating agent, 1 ~ 4 part of thickener, 0.5 ~ 2 part of builder, 0.1 ~ 1 part of plants essential oil, 5 ~ 20 parts of ethanol, 10 ~ 30 parts of deionized water, 0 ~ 20 part of silica 1,0.5 ~ 1 part of corrosion inhibiter, 0.5 ~ 2 part of mineral oil, 4 ~ 10 parts of surfactant.The surfactant of the principal status of public economy is wherein occupied using some green, environmentally friendly, harmless materials, and some other addition auxiliary agents in the detergent are also gentle, harmless material, while so ensureing its excellent dirt-removing power, it can play again environmentally safe, harmless good result, is a kind of environmental protective type chemical apparatus decontamination agent well.
Description
Technical field
The present invention relates to chemical industry detergent technology field, more particularly to a kind of novel environment friendly chemical industry equipment detergent.
Background technology
Chemical industry equipment is a big important branch of mechanical equipment, in occupation of considerable effect in Chemical Manufacture,
Many greasy dirt or chemical corrosivity products are inevitably touched in chemical process, these greasy dirt impurity are unclear for a long time
Reason is clean, and the serious normal operation for influencing equipment of meeting, causes important economic loss.It would therefore be desirable to these equipment
Carry out cleaning treatment.
The method that deoiling is cleaned using organic solvent, hot alkaline solution and surfactant solution at present.It is organic
Solvent method is divided into two classes：One kind is using halogenated hydrocarbons as active matter, but dichloroethanes toxicity is larger, and destroys ozone layer, not environmentally；
Another kind of is using stone hydrocarbon as active matter, and using kerosene as main active matter, this method not only waste of energy, also pollutes environment, again
There is security risk.
Therefore, for the economic development of society and the protection of environment, it is necessary to develop a kind of novel environment-friendly chemical industry and set
Standby detergent.
The content of the invention
The present invention is above-mentioned in chemical industry equipment decontamination process in order to solve, and runs into energy waste, environmental pollution, and have peace
A kind of the problem of full hidden danger, there is provided novel environment friendly chemical industry detergent.
In order to reach object above, the present invention provides following technical solution：A kind of novel environment friendly chemical industry equipment detergent, its
It is characterized in that：The novel environment friendly chemical industry equipment detergent includes following composition by weight：Alkylpolyoxyethylene sodium sulphate
10 ~ 20 parts, 4 ~ 10 parts of sorbitan fatty acid ester, 1 ~ 5 part of soda ash, 0.5 ~ 2 part of sodium citrate, 2 ~ 8 parts of sodium sulfite,
0.5 ~ 1.6 part of chelating agent, 1 ~ 4 part of thickener, 0.5 ~ 2 part of builder, 0.1 ~ 1 part of plants essential oil, 5 ~ 20 parts of ethanol, deionization
10 ~ 30 parts of water, 0 ~ 20 part of silica 1,0.5 ~ 1 part of corrosion inhibiter, 0.5 ~ 2 part of mineral oil, 4 ~ 10 parts of surfactant.
Preferably, the novel environment friendly chemical industry equipment detergent includes following composition by weight：Alkylpolyoxyethylene
15 parts of sodium sulphate, 7 parts of sorbitan fatty acid ester, 3 parts of soda ash, 1.5 parts of sodium citrate, 5 parts of sodium sulfite, chelating agent 1.2
Part, 2 parts of thickener, 1 part of builder, 0.5 part of plants essential oil, 13 parts of ethanol, 20 parts of deionized water, 5 parts of silica 1, inhibition
0.75 part of agent, 1.25 parts of mineral oil, 6 parts of surfactant.
Preferably, the chelating agent is one in EDTA tetrasodium salts, organic phosphonate, Sodium Polyacrylate or hydroxycarboxylate
Kind.
Preferably, the thickener includes following composition by weight：20 ~ 40 parts of Paris white, 40 ~ 46 parts of polypropylene glycol are yellow
20 ~ 30 parts of ketone compounds, 10 ~ 20 parts of water.
Preferably, the flavone compound be flavones, flavonols, any one or two kinds or two kinds in flavanones with
On.
Preferably, the builder includes following components by weight percent：70 ~ 120 parts of liquid sodium silicate, 20 ~ 70 parts of alkali, addition
0.2 ~ 5 part of agent, 1 ~ 10 part of solvent.
Preferably, the additive is one or both of brightening agent, buffer.
Preferably, the brightening agent is talan Triazine fluorescent brightening agent VBL, and the buffer is sodium humate
（JSW）Or humic acid alkaline agent（HAS）Or sodium acid carbonate（NaHCO3）.
Preferably, the plants essential oil is cinnamon essential oil.
Preferably, the surfactant includes following parts by weight：1 ~ 5 part of isomeric alcohol polyethenoxy ether carboxylate, alkyl
2 ~ 6 parts of glucosides.
Preferably, the novel environment friendly chemical industry equipment detergent preparation method is：Dispensing is carried out by the parts by weight, first will
Ethanol and deionized water uniformly mix, then at room temperature by soda ash, sodium citrate and sodium sulfite add the ethanol and go from
In the mixed liquor of sub- water, stirring is completely dissolved up to soda ash, sodium citrate and sodium sulfite, is then added successively under stirring
Enter alkylpolyoxyethylene sodium sulphate, sorbitan fatty acid ester, chelating agent, builder, after being uniformly mixed again
Remaining thickener, silica, corrosion inhibiter, mineral oil, surfactant and plants essential oil are added, after being uniformly mixed
Obtain the detergent.
The beneficial effects of the invention are as follows：
1）Alkylpolyoxyethylene sodium sulphate is a kind of anion surfactant, such surfactant has in water
Good wetting, infiltration, emulsification, scattered and dirt-removing power, alkali resistance is higher, and biodegradability is good, without carcinogenic arylamine with
Heavy metal ion, is harmful to human health；
2）Sorbitan fatty acid ester is a kind of nonionic surfactant, have good emulsification, wetting, infiltration, diffusion,
Stablize, thicken, antistatic, compliance, it is especially nontoxic nonirritant, it is safe and harmless surfactant；
3）In general, the cleaning ability of alkaline detergent is higher, so to keep the alkalescence of detergent, it will usually add
Alkaline matter, such as sodium hydroxide, potassium hydroxide, but the alkalescence such as sodium hydroxide, potassium hydroxide is too strong, has to skin strong
Irritation, and compared to sodium hydroxide, potassium hydroxide etc., the alkalescence of soda ash is more gentle, small to the irritation of skin, and
By the control of its content under relatively low degree, its irritation can be turn avoid while the alkalescence of detergent is ensured；
4）Sodium citrate is that one kind is in weakly alkaline sodium salt, safe and non-toxic, has biological degradability, environmentally safe, and
Sodium citrate has excellent stability, anti-corrosive properties and ph modulabilities, soluble easily in water, is a kind of auxiliary agent well；
5）The chelating agent goes back easily biological-degradable while its excellent sequestering power, nontoxic, will not cause dirt to environment
Dye;
6）A kind of novel environment friendly chemical industry equipment detergent provided by the invention, wherein the surfactant for occupying the principal status of public economy uses
Be some green, environmentally friendly, harmless materials, and some other addition auxiliary agents in the detergent are also gentle, harmless
Material, while so ensureing its excellent dirt-removing power, and environmentally safe, harmless good knot can be played
Fruit, is a kind of environmental protective type chemical apparatus decontamination agent well；
7）Novel environment friendly chemical industry equipment detergent preparation method of the present invention is simple, is easy to get, and reaction condition is gentle, favourable energy saving
Consumption reduction, cost is low, quick.
Embodiment
Embodiment 1：The novel environment friendly chemical industry equipment detergent includes following composition by weight：Alkylpolyoxyethylene
10 ~ 20 parts of sodium sulphate, 4 parts of sorbitan fatty acid ester, 5 parts of soda ash, 0.5 part of sodium citrate, 8 parts of sodium sulfite, chela
0.5 part of mixture, 4 parts of thickener, 0.5 part of builder, 1 part of plants essential oil, 5 parts of ethanol, 30 parts of deionized water, silica 10
Part, 1 part of corrosion inhibiter, 0.5 part of mineral oil, 10 parts of surfactant.
The chelating agent is EDTA tetrasodium salts.
The thickener includes following composition by weight：20 parts of Paris white, 46 parts of polypropylene glycol, flavone compound 20
Part, 20 parts of water.
The flavone compound is composed of flavones and flavonols.
The builder includes following components by weight percent：70 parts of liquid sodium silicate, 70 parts of alkali, 0.2 part of additive, solvent 10
Part.
The additive is brightening agent.
The brightening agent is talan Triazine fluorescent brightening agent VBL, and the buffer is sodium humate（JSW）.
The plants essential oil is cinnamon essential oil.
The surfactant includes following parts by weight：1 part of isomeric alcohol polyethenoxy ether carboxylate, 6 parts of alkyl glycosides.
The novel environment friendly chemical industry equipment detergent preparation method is：Carry out dispensing by the parts by weight, first by ethanol and
Deionized water uniformly mixes, and soda ash, sodium citrate and sodium sulfite then are added the ethanol and deionized water at room temperature
In mixed liquor, stirring is completely dissolved up to soda ash, sodium citrate and sodium sulfite, then sequentially adds 12 under stirring
Pareth sulfate, sorbitan fatty acid ester, chelating agent, builder, add surplus after being uniformly mixed
Remaining thickener, silica, corrosion inhibiter, mineral oil, surfactant and plants essential oil, obtains after being uniformly mixed
The detergent.
Embodiment 2：The novel environment friendly chemical industry equipment detergent includes following composition by weight：Alkylpolyoxyethylene
20 parts of sodium sulphate, 4 parts of sorbitan fatty acid ester, 5 parts of soda ash, 0.5 part of sodium citrate, 8 parts of sodium sulfite, chelating agent
0.5 part, it is 4 parts of thickener, 0.5 part of builder, 1 part of plants essential oil, 5 parts of ethanol, 30 parts of deionized water, 0 part of silica 1, slow
Lose 1 part of agent, 0.5 part of mineral oil, 10 parts of surfactant.
The chelating agent is hydroxycarboxylate.
The thickener includes following composition by weight：40 parts of Paris white, 40 parts of polypropylene glycol, flavone compound 30
Part, 10 parts of water.
The flavone compound is composed of flavonols, flavanones.
The builder includes following components by weight percent：120 parts of liquid sodium silicate, 20 parts of alkali, 5 parts of additive, 1 part of solvent.
The additive is buffer.
The brightening agent is talan Triazine fluorescent brightening agent VBL, and the buffer is humic acid alkaline agent（HAS）.
The plants essential oil is cinnamon essential oil.
The surfactant includes following parts by weight：5 parts of isomeric alcohol polyethenoxy ether carboxylate, 2 parts of alkyl glycosides.
The novel environment friendly chemical industry equipment detergent preparation method is：Carry out dispensing by the parts by weight, first by ethanol and
Deionized water uniformly mixes, and soda ash, sodium citrate and sodium sulfite then are added the ethanol and deionized water at room temperature
In mixed liquor, stirring is completely dissolved up to soda ash, sodium citrate and sodium sulfite, then sequentially adds 12 under stirring
Pareth sulfate, sorbitan fatty acid ester, chelating agent, builder, add surplus after being uniformly mixed
Remaining thickener, silica, corrosion inhibiter, mineral oil, surfactant and plants essential oil, obtains after being uniformly mixed
The detergent.
Embodiment 3：The novel environment friendly chemical industry equipment detergent includes following composition by weight：Alkylpolyoxyethylene
15 parts of sodium sulphate, 7 parts of sorbitan fatty acid ester, 3 parts of soda ash, 1.25 parts of sodium citrate, 5 parts of sodium sulfite, chelating
1.2 parts of agent, 2.5 parts of thickener, 1.25 parts of builder, 0.5 part of plants essential oil, 12 parts of ethanol, 20 parts of deionized water, silica
15 parts, 0.7 part of corrosion inhibiter, 1.2 parts of mineral oil, 7 parts of surfactant.
The chelating agent is hydroxycarboxylate.
The thickener includes following composition by weight：30 parts of Paris white, 43 parts of polypropylene glycol, flavone compound 25
Part, 15 parts of water.
The flavone compound is flavones, flavonols, three kinds of flavanones are composed.
The builder includes following components by weight percent：95 parts of liquid sodium silicate, 45 parts of alkali, 2.5 parts of additive, solvent 5.5
Part.
The additive is brightening agent, combinations of buffers forms.
The brightening agent is talan Triazine fluorescent brightening agent VBL, and the buffer is sodium acid carbonate（NaHCO3）.
The plants essential oil is cinnamon essential oil.
The surfactant includes following parts by weight：3 parts of isomeric alcohol polyethenoxy ether carboxylate, 3 parts of alkyl glycosides.
The novel environment friendly chemical industry equipment detergent preparation method is：Carry out dispensing by the parts by weight, first by ethanol and
Deionized water uniformly mixes, and soda ash, sodium citrate and sodium sulfite then are added the ethanol and deionized water at room temperature
In mixed liquor, stirring is completely dissolved up to soda ash, sodium citrate and sodium sulfite, then sequentially adds 12 under stirring
Pareth sulfate, sorbitan fatty acid ester, chelating agent, builder, add surplus after being uniformly mixed
Remaining thickener, silica, corrosion inhibiter, mineral oil, surfactant and plants essential oil, obtains after being uniformly mixed
The detergent.
The foregoing is only a preferred embodiment of the present invention, is not intended to limit the invention, although with reference to foregoing reality
Apply example the present invention is described in detail, for those skilled in the art, it still can be to foregoing each implementation
Technical solution described in example is modified, or equivalent substitution, all essences in the present invention are carried out to which part technical characteristic
With within principle, any modification, equivalent replacement, improvement and so on, should all be included in the protection scope of the present invention god.
Claims (10)
- A kind of 1. novel environment friendly chemical industry equipment detergent, it is characterised in that：Including following composition by weight：Dodecyl polyoxyethylene 10 ~ 20 parts of ether sodium sulfate, 4 ~ 10 parts of sorbitan fatty acid ester, 1 ~ 5 part of soda ash, 0.5 ~ 2 part of sodium citrate, sodium sulfite 2 ~ 8 parts, 0.5 ~ 1.6 part of chelating agent, 1 ~ 4 part of thickener, 0.5 ~ 2 part of builder, 0.1 ~ 1 part of plants essential oil, 5 ~ 20 parts of ethanol, 10 ~ 30 parts of deionized water, 0 ~ 20 part of silica 1,0.5 ~ 1 part of corrosion inhibiter, 0.5 ~ 2 part of mineral oil, 4 ~ 10 parts of surfactant.
- A kind of 2. novel environment friendly chemical industry equipment detergent according to claim 1, it is characterised in that：The chelating agent is One kind in EDTA tetrasodium salts, organic phosphonate, Sodium Polyacrylate or hydroxycarboxylate.
- A kind of 3. novel environment friendly chemical industry equipment detergent according to claim 1, it is characterised in that：The thickener includes Following composition by weight：20 ~ 40 parts of Paris white, 40 ~ 46 parts of polypropylene glycol, 20 ~ 30 parts of flavone compound, 10 ~ 20 parts of water.
- A kind of 4. novel environment friendly chemical industry equipment detergent according to claim 3, it is characterised in that：The flavonoids Compound is flavones, flavonols, any one or two or more in flavanones.
- A kind of 5. novel environment friendly chemical industry equipment detergent according to claim 1, it is characterised in that：The builder bag Include following components by weight percent：70 ~ 120 parts of liquid sodium silicate, 20 ~ 70 parts of alkali, 0.2 ~ 5 part of additive, 1 ~ 10 part of solvent.
- A kind of 6. novel environment friendly chemical industry equipment detergent according to claim 5, it is characterised in that：The additive is increasing One or both of white agent, buffer.
- A kind of 7. novel environment friendly chemical industry equipment detergent according to claim 6, it is characterised in that：The brightening agent is two Styrene Triazine fluorescent brightening agent VBL, the buffer are sodium humate（JSW）Or humic acid alkaline agent（HAS）Or bicarbonate Sodium（NaHCO3）.
- A kind of 8. novel environment friendly chemical industry equipment detergent according to claim 1, it is characterised in that：The plants essential oil For cinnamon essential oil.
- A kind of 9. novel environment friendly chemical industry equipment detergent according to claim 1, it is characterised in that：The surface-active Agent includes following parts by weight：1 ~ 5 part of isomeric alcohol polyethenoxy ether carboxylate, 2 ~ 6 parts of alkyl glycosides.
- A kind of 10. preparation method of novel environment friendly chemical industry equipment detergent according to claim 1, it is characterised in that：Institute Stating novel environment friendly chemical industry equipment detergent preparation method is：Dispensing is carried out by the parts by weight, it is first that ethanol and deionized water is equal Even mixing, then soda ash, sodium citrate and sodium sulfite are added in the ethanol and the mixed liquor of deionized water, stir at room temperature Mix until soda ash, sodium citrate and sodium sulfite be completely dissolved, dodecyl polyoxy second is then sequentially added under stirring Alkene ether sodium sulfate, sorbitan fatty acid ester, chelating agent, builder, added after being uniformly mixed remaining thickener, Silica, corrosion inhibiter, mineral oil, surfactant and plants essential oil, obtain the decontamination after being uniformly mixed Agent.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711298797.8A CN107916183A (en) | 2017-12-08 | 2017-12-08 | A kind of novel environment friendly chemical industry equipment detergent |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109294756A (en) * | 2018-11-26 | 2019-02-01 | 庄雪芸 | A kind of dish washing liquid formula with bactericidal effect |
| CN115746969A (en) * | 2022-09-28 | 2023-03-07 | 郑州洁灵科技有限公司 | Train outer surface cleaning agent and preparation method thereof |
-
2017
- 2017-12-08 CN CN201711298797.8A patent/CN107916183A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109294756A (en) * | 2018-11-26 | 2019-02-01 | 庄雪芸 | A kind of dish washing liquid formula with bactericidal effect |
| CN115746969A (en) * | 2022-09-28 | 2023-03-07 | 郑州洁灵科技有限公司 | Train outer surface cleaning agent and preparation method thereof |
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