CN107916099A - Alkali-free, which sticks, plays surface activator composition and its preparation method and application - Google Patents
Alkali-free, which sticks, plays surface activator composition and its preparation method and application Download PDFInfo
- Publication number
- CN107916099A CN107916099A CN201610878259.5A CN201610878259A CN107916099A CN 107916099 A CN107916099 A CN 107916099A CN 201610878259 A CN201610878259 A CN 201610878259A CN 107916099 A CN107916099 A CN 107916099A
- Authority
- CN
- China
- Prior art keywords
- alkali
- surfactant
- surface activator
- composition
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012190 activator Substances 0.000 title claims abstract description 44
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000000203 mixture Substances 0.000 title claims description 54
- 239000004094 surface-active agent Substances 0.000 claims abstract description 85
- 238000006073 displacement reaction Methods 0.000 claims abstract description 42
- 239000003513 alkali Substances 0.000 claims abstract description 34
- 235000016068 Berberis vulgaris Nutrition 0.000 claims abstract description 33
- 241000335053 Beta vulgaris Species 0.000 claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 23
- 230000035699 permeability Effects 0.000 claims abstract description 22
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 12
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 7
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 43
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 25
- 238000006243 chemical reaction Methods 0.000 claims description 20
- 229960003237 betaine Drugs 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 18
- 230000003213 activating effect Effects 0.000 claims description 13
- -1 carbon chain carboxylate Chemical class 0.000 claims description 13
- 239000003153 chemical reaction reagent Substances 0.000 claims description 13
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical group C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 claims description 10
- 230000009435 amidation Effects 0.000 claims description 8
- 238000007112 amidation reaction Methods 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 4
- 125000000129 anionic group Chemical group 0.000 claims description 4
- 238000002347 injection Methods 0.000 claims description 4
- 239000007924 injection Substances 0.000 claims description 4
- 238000006467 substitution reaction Methods 0.000 claims description 3
- LNETULKMXZVUST-UHFFFAOYSA-N 1-naphthoic acid Chemical class C1=CC=C2C(C(=O)O)=CC=CC2=C1 LNETULKMXZVUST-UHFFFAOYSA-N 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 125000001118 alkylidene group Chemical group 0.000 claims 1
- 229940077388 benzenesulfonate Drugs 0.000 claims 1
- 150000008107 benzenesulfonic acids Chemical group 0.000 claims 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical group OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims 1
- 150000005171 halobenzenes Chemical class 0.000 claims 1
- 230000008595 infiltration Effects 0.000 claims 1
- 238000001764 infiltration Methods 0.000 claims 1
- 239000003921 oil Substances 0.000 abstract description 61
- 238000011084 recovery Methods 0.000 abstract description 11
- 239000002280 amphoteric surfactant Substances 0.000 abstract description 4
- 239000010729 system oil Substances 0.000 abstract 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 238000011156 evaluation Methods 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- FBUKVWPVBMHYJY-UHFFFAOYSA-N noncarboxylic acid Natural products CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 8
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 239000003292 glue Substances 0.000 description 6
- 150000001450 anions Chemical class 0.000 description 5
- 239000002585 base Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000000284 extract Substances 0.000 description 4
- UQDUPQYQJKYHQI-UHFFFAOYSA-N methyl laurate Chemical compound CCCCCCCCCCCC(=O)OC UQDUPQYQJKYHQI-UHFFFAOYSA-N 0.000 description 4
- IJXHLVMUNBOGRR-UHFFFAOYSA-N methyl nonanoate Chemical compound CCCCCCCCC(=O)OC IJXHLVMUNBOGRR-UHFFFAOYSA-N 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 239000011435 rock Substances 0.000 description 4
- 241001044369 Amphion Species 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- VHOCUJPBKOZGJD-UHFFFAOYSA-N n-triacontanoic acid Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O VHOCUJPBKOZGJD-UHFFFAOYSA-N 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- FDRCDNZGSXJAFP-UHFFFAOYSA-M sodium chloroacetate Chemical compound [Na+].[O-]C(=O)CCl FDRCDNZGSXJAFP-UHFFFAOYSA-M 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- ODIGIKRIUKFKHP-UHFFFAOYSA-N (n-propan-2-yloxycarbonylanilino) acetate Chemical compound CC(C)OC(=O)N(OC(C)=O)C1=CC=CC=C1 ODIGIKRIUKFKHP-UHFFFAOYSA-N 0.000 description 2
- UWLMQFDPGCYPBE-UHFFFAOYSA-N 3-chloropropanoic acid;sodium Chemical compound [Na].OC(=O)CCCl UWLMQFDPGCYPBE-UHFFFAOYSA-N 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- 208000003098 Ganglion Cysts Diseases 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 230000000875 corresponding effect Effects 0.000 description 2
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 2
- ZYNDJIBBPLNPOW-UHFFFAOYSA-N eurucic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCCCCCC(=O)OC ZYNDJIBBPLNPOW-UHFFFAOYSA-N 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- ZYNDJIBBPLNPOW-KHPPLWFESA-N methyl erucate Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(=O)OC ZYNDJIBBPLNPOW-KHPPLWFESA-N 0.000 description 2
- DILRJUIACXKSQE-UHFFFAOYSA-N n',n'-dimethylethane-1,2-diamine Chemical compound CN(C)CCN DILRJUIACXKSQE-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- QEYMMOKECZBKAC-UHFFFAOYSA-N 3-chloropropanoic acid Chemical compound OC(=O)CCCl QEYMMOKECZBKAC-UHFFFAOYSA-N 0.000 description 1
- 244000056139 Brassica cretica Species 0.000 description 1
- 235000003351 Brassica cretica Nutrition 0.000 description 1
- 235000003343 Brassica rupestris Nutrition 0.000 description 1
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 description 1
- 208000005400 Synovial Cyst Diseases 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- BIRUBGLRQLAEFF-UHFFFAOYSA-N Triacontanoic acid methyl ester Chemical class CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC(=O)OC BIRUBGLRQLAEFF-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 235000010460 mustard Nutrition 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000002332 oil field water Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- JXKPEJDQGNYQSM-UHFFFAOYSA-M sodium propionate Chemical compound [Na+].CCC([O-])=O JXKPEJDQGNYQSM-UHFFFAOYSA-M 0.000 description 1
- 229960003212 sodium propionate Drugs 0.000 description 1
- 235000010334 sodium propionate Nutrition 0.000 description 1
- 239000004324 sodium propionate Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
- C09K8/584—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2208/00—Aspects relating to compositions of drilling or well treatment fluids
- C09K2208/30—Viscoelastic surfactants [VES]
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mining & Mineral Resources (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Fluid Mechanics (AREA)
- Physics & Mathematics (AREA)
- Geochemistry & Mineralogy (AREA)
- Environmental & Geological Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
The preparation method and applications for playing surfactant are sticked the present invention relates to a kind of alkali-free, mainly solve the problems, such as that existing oil displacement system oil displacement efficiency under the conditions of high temperature LOW PERMEABILITY RESERVOIR is poor.By using including beet alkali surface activator, anion surfactant and water, in the beet alkali surface activator such as following formula shown in (I)；In the anion surfactant such as formula at least one of (II)；Shown in its structure such as formula (I), R1Selected from C8~C29Alkyl, at least one of alkenyl, the R2And R3It is independently chosen from C1~C5Alkylidene, at least one of hydroxyl substituted alkylene, structure formula (II) X is selected from least one of carboxylate radical, sulfonate radical；The molar ratio of the amphoteric surfactant and anion surfactant is 1：0.01~1：100 technical solution, preferably resolves the technical problem, available for being applied in the tertiary oil recovery in oil field.
Description
Technical field
The preparation method and applications for playing surfactant are sticked the present invention relates to the alkali-free in a kind of LOW PERMEABILITY RESERVOIR.
Background technology
In the petroleum-in-place that Sinopec is newly verified, the ratio shared by low-permeability oil deposit reserves is up to 60%~
70%, low-permeability oil deposit by be produced in a considerably long from now on period increasing the storage main resource basis.In recent years, in,
The reduction of high permeability reservoir recoverable reserves, the exploitation of low-permeability oil deposit are increasingly valued by people.Surfactant flooding is demonstrate,proved
Bright is a kind of extremely promising method for improving low-permeability oil recovery rate, becomes the hot spot studied both at home and abroad.In,
High permeability oil reservoir, ganglion is present in the hole of throat radius very little in low-permeability oil pool, remaining under the same terms
The hollow billet resistance of oil droplet is much larger than middle and high permeability oil reservoir, therefore activating these ganglions needs lower oil-water interfaces to open
Power.Secondly, LOW PERMEABILITY RESERVOIR filtrational resistance is big, and only under larger displacement pressure, liquid could flow.Furthermore noted to improve
Water development effectiveness increases injection pressure, but water injection pressure is high, easily cause microcrack unlatching, and water is advanced by leaps and bounds along crack, causes the displacement of reservoir oil
Efficiency reduces, and swept volume is small, and it is serious to cover damage.Research shows that surfactant solution can reduce oil water interfacial tension, subtract
Hollow billet resistance, increase capillary number and the raising oil displacement efficiency of small oleophylic oil reservoir, therefore, suitable surfactant can be preferably
Solve the above problems, screening is applicable in the Main Basiss of oil displacement surfactant, and to be that can it be down to oil water interfacial tension ultralow
(10-3mN/m)。
At present, it is the anion surfactant based on sodium salt to use most surfactant oil displacements both at home and abroad,
This kind of surfactant has the advantages that source is wide, quantity is big, low-cost, and is applied successfully in common oil reservoir
(CN1458219A).But the salt resistant character of anion surfactant is poor, nonionic surfactant is temperature sensitive,
Easily separate out, should not largely use under high temperature.For this reason, people have started the research of amphoteric surfactant, amphion surface
Existing anionic hydrophilic base has cationic hydrophilic base and shows both sexes again in active agent molecule, can substantially reduce non-ionic table
Chromatographic fractionation effect when face activating agent is compounded with anionic surfactant.Since last century the seventies, Ren Menyan
The interaction between amphoteric surfactant and other type surfactants is studied carefully, in document《Surfactants
Detergents》Mentioned in 2010, vol13 isothermal by the surface tension to alpha-decyl betaine (α-DB)/SDS systems
Research, it is found that compound system shows stronger cooperative effect in reduction surface tension, formation micella etc., form one
Kind vermiculate glues.Patent CN201310166961.5 proposes the vermiculate glues that a kind of anion surfactant is formed
Displacement composition, can improve recovery ratio to a certain degree.Vermiculate glues is in a kind of state of dynamic equilibrium, i.e., opposite
Constantly divide in short time scale, polymerize again.Since vermiculate glues has high surface, high viscosity and high shear
Etc. characteristic, have broad application prospects.Therefore, the research and development of the glutinous bullet surfactant with vermiculate glues obtain
People more and more pay attention to and concern, have become one of hot spot of tertiary oil recovery field research.
For this reason, the present invention provides a kind of steady chemical structure under the conditions of alkali-free, high temperature LOW PERMEABILITY RESERVOIR, can be formed with crude oil
10- 3~10- 4MN/m ultralow interfacial tensions, the new oil displacement system for effectively improving oil recovery factor, i.e., live including glycine betaine surface
The alkali-free of property agent, anion surfactant and water sticks bullet surface activator composition, by control surface activating agent from group
Dress makes body mutually have high viscosity, while surfactant has high interfacial activity in itself, so as to improve adopting for LOW PERMEABILITY RESERVOIR
Yield, is extended in the application in the harsh oil field of the hypotonic grade of high temperature.
The content of the invention
The first technical problem to be solved by the present invention is that the polymer in existing chemical flooding is used for the LOW PERMEABILITY RESERVOIR displacement of reservoir oil
Formation blockage is be easy to cause in journey, injects the problem of difficult, there is provided a kind of composition of new glutinous bullet surfactant, the surface
Activating agent has the characteristics that oil displacement efficiency is high under the conditions of high temperature is hypotonic, is particularly suitable for husky seven oil fields of Jiangsu oilfield.
The second technical problem to be solved by the present invention is to provide a kind of with solving one of technical problem corresponding glutinous bullet
The preparation method of composition of surfactant.
The third technical problem to be solved by the present invention is to provide a kind of with solving one of technical problem corresponding glutinous bullet
The composition of surfactant is used for the flooding method in LOW PERMEABILITY RESERVOIR.The glutinous composition for playing surfactant is suitable for logical
The rock core of normal permeability, in view of the displacement of reservoir oil of low permeability cores faces the difficulty of bigger in this area, the present invention is distinguished by that
Suitable for the rock core of low-permeability.Such as it is 0.1 that above-mentioned technical proposal, which is distinguished by using the core permeability scope,
~500mD；It is 2~40mD to be more distinguished by suitable for the core permeability scope.
To solve one of above-mentioned technical problem, the technical solution adopted by the present invention is as follows：A kind of alkali-free sticks bullet surface-active
Agent composition, including beet alkali surface activator, anion surfactant and water, the beet alkali surface activator and it is cloudy from
The molar ratio of sub- surfactant is 1: 0.01~1: 100；The glycine betaine Surfactant is in the structure as shown in (I) in formula
At least one：
In formula (I), R1Selected from C8~C29Alkyl, at least one of alkenyl, the R2And R3It is independently chosen from C1~
C5Alkylidene, at least one of hydroxyl substituted alkylene, the R4And R5It is independently chosen from C1~C4Alkyl, hydroxyl takes
At least one of substituted alkyl；More preferably R4And R5Methyl is selected from, at this time, the glycine betaine Surfactant is in such as formula
At least one of structure shown in (I ')：
At this time, with acylate combined interface tension force performance more preferably；
The anion surfactant is selected from least one of structure as shown in (II) in formula：
X is selected from least one of carboxylate radical, sulfonate radical in formula (II).
Preferred R in above-mentioned technical proposal1For C12~C25At least one of alkyl or alkenyl, R2For C2~C3Alkylene
At least one of base or hydroxyl substituted alkylene, R3For C1~C3Alkylidene.
The most preferred technique scheme from the angle for improving recovery ratio, above-mentioned technical proposal：R is C16~C22Alkyl
Or at least one of alkenyl, R2For C3Alkylidene or at least one of hydroxyl substituted alkylene, R3For C1~C2Alkylene
Base；Anion surfactant is selected from least one of naphthalene sulfonate and alkyl substitution naphthalene-carboxylic acid salt.
Interfacial tension is reduced from collaboration, improves the consideration of recovery ratio angle, and in above-mentioned technical proposal, the glycine betaine surface is lived
Property agent be selected from it is two or more in structure shown in formula (I) or formula (I '), such as R1The different two or more glycine betaine tables of carbon number
Face activating agent, at this time, R1The different two or more beet alkali surface activators of carbon number have with anion surfactant
Good synergistic function, such as preferred R1For C15~C29Long carbon chain carboxylate beet alkali surface activator and R1For C8~C14
Short carbon chain carboxylate beet alkali surface activator two or more combinations.
In above-mentioned technical proposal, the molar ratio of the amphoteric surfactant and acylate is preferably (1:0.1)~
(1:10)。
In above-mentioned technical proposal, the displacement of reservoir oil further includes water with the composition of Surfactant Used in Viscoelastic Fracturing Fluids, especially suitable for surface
Surfactant waterflood.
To solve the two of above-mentioned technical problem, the technical solution adopted by the present invention is as follows：Described in one of above-mentioned technical problem
The preparation method of the glutinous composition for playing surfactant, comprises the following steps：
A) by aliphatic acid acid or its ester and required amidation reagent when 100~160 DEG C of reactions 3~20 are small；Then plus
Enter carboxylating reagent ZR3COOM in 50~100 DEG C the reaction was continued 2~20 it is small when, obtain the glycine betaine surface-active described in formula (I)
Agent；Wherein, fatty acid methyl ester：Amidation reagent：The molar ratio of carboxylating reagent is 1：(1~3)：(1~4)；Z be selected from hydrogen, hydroxyl,
Any one in halogen, amino, any one of M in alkali metal, alkaline-earth metal, ammonium ion；
B) it is dissolved in water by anion surfactant and according to the obtained beet alkali surface activators of step a),
It is then (1 according to molar ratio：0.1)~(1：10) it is uniformly mixed, obtains the surface activator composition.
In above-mentioned technical proposal, step a) preferred amides reagent is NH2-R2-N(CH3)2；Glycine betaine surface in step b)
Activating agent is (1 with anion surfactant molar ratio preferred scope：0.1)~(1：10).
It is as follows to solve three the technical solution adopted by the present invention of present invention problem：A kind of displacement of reservoir oil in LOW PERMEABILITY RESERVOIR
Method, including the displacement of reservoir oil will be carried out in the displacement composition injection low-permeability oil pool.
Core permeability scope any one of above-mentioned technical proposal is 0.1~500mD；More it is distinguished by applicable
In the core permeability scope be 2~40mD.
Amphion and the surfactant of anion compounding in glutinous bullet surfactant flooding agent prepared by the present invention, by
After anion and zwitterionic surfactant compounding, you can show viscosity rise, the increase of surface-active, critical micell
The advantages that decline of concentration, solubilized effect.This is because the hydrophilic group in anion surfactant is lived with amphion surface
Property agent in positive charge there are electrostatic attraction effect, the repulsive interaction between solution surface like charges can be reduced, and the two is dredged
Water base hydrocarbon interchain also has certain hydrophobic effect, promotes different surfaces active agent molecule to take even closer arrangement mode,
" association that so as to the surface-active with higher, simultaneously because strong electrical function, two kinds of surfactants can form new
After thing ", vermiculate glues is more likely formed in the solution, so as to reduce the critical micelle concentration of compound surfactant so that
Surfactant has certain viscoplasticity, can play the role of polymer in poly- table oil displacement agent and otherwise block narrow and small pore throat,
It is advantageous to improve the oil displacement efficiency of low-permeability oil deposit.Two kinds of surfactants in compound surfactant are ion
Type, built agent also show the feature of ionic surface active agent, i.e., excellent heat resistance.Therefore, which both had
There is excellent heat-resisting property, and there is excellent interfacial activity, surfactant can be solved and be unable to reach 10-3The ultralow interfaces of mN/m
The problem of tension value so that surfactant can still be protected during tertiary oil recovery in the migration process of underground and use table of the present invention
Face surfactant composition, has interfacial activity height.
Technical solution using the present invention, under the conditions of compound surfactant composition dosage is 0.01~1w.t.%,
In salinity in 30,000 mg/L, seven live water of calcium ions and magnesium ions content 400mg/L sand, remain to form 10 with underground crude oil-3~10- 4The ultralow interfacial tension of mN/m；Washing oil ability is strong, improves recovery ratio up to 15.1%；Surface activator composition system is simple
The advantages that, achieve preferable technique effect.
Below by embodiment, the present invention is further elaborated.
Embodiment
【Embodiment 1】
1. prepared by surfactant
(1) erucyl amide carboxyl betaine surfactant (R1=C21, R2=C3、R3=C2) preparation
A) 0.5 mole of methyl erucate and the desired amount of amidation reagent N, N- dimethylated propyl diethylenetriamine are added into reaction kettle
In, when 140 DEG C of reactions 8 are small, vacuum pump is opened, extracts methanol and excessive N that reaction produces, N- dimethylated propyl diethylenetriamines, obtain
To erucic acid acyl group tertiary amine product, the desired amount of sodium chloroacetate is added, when 75 DEG C of reactions 9 are small, is carried with absolute ethyl alcohol recrystallization
Long carbon chain beet alkali surface activator is obtained after pure；Wherein, methyl erucate:N, N- dimethylated propyl diethylenetriamine:Mole of sodium chloroacetate
Than for 1:2.5:1.5.
B) erucyl amide carboxyl betaine surfactant prepared by naphthalene sulfonate and the present invention is dissolved in water,
Stirring 30 minutes, is configured to aqueous solution, then by above-mentioned surfactant according to beet alkali surface activator and anionic surface
Activating agent molar ratio is 1:0.7 is uniformly mixed, and obtains the glutinous composition for playing surfactant.
2. surfactant properties are evaluated
A) viscosity measurement
Using III type viscosimeters of U.S. Brookfield DV-, at 85 DEG C, rotating speed 7.34S-1Under the conditions of, measure is above-mentioned
The oil displacement agent of 0.3% concentration and the viscosity of the husky seven Oil Field water (being shown in Table 3) in Jiangsu the results are shown in Table 2.
B) interfacial tension is evaluated
TX-500C rotating interfacial tensimeters, at 85 DEG C, rotating speed 6000 are produced using Texas ,Usa university
Under the conditions of rev/min, the interfacial tension knot between the dewatered oil in husky seven oil fields of oil displacement agent and Jiangsu for measuring above-mentioned 0.1% concentration
Fruit is shown in Table 2.
C) oil displacement experiment is evaluated
According to the composite oil-displacing system physical simulation flooding test in SY/T6424-2000 composite oil-displacing system performance test methods
Measure of merit, at 87 DEG C, length 30cm, a diameter of 2.5cm, permeability is to carry out imitation oil displacement experiment on the rock core of 20 millidarcies
Experiment.Water drive is first carried out to aqueous 98%, after water drive, the oil displacement agent of metaideophone 0.3pv (rock pore volume) above-mentioned 0.3%
Afterwards, then water drive to aqueous 100%, improves oil recovery factor and the results are shown in Table 2.
【Embodiment 2】
1. prepared by surfactant
(1) triacontanoic acid amido carboxyl beet alkali surface activator (R1=C29, R2=C2、R3=C2) preparation
A) 0.5 mole of Long carbon chain triacontanoic acid methyl esters and the desired amount of amidation reagent N, N- dimethyl-ethylenediamine are added
In reaction kettle, when 130 DEG C of reactions 6 are small, vacuum pump is opened, extracts methanol and excessive N that reaction produces, N- dimethyl second two
Amine, obtains triacontanoic acid acyl group tertiary amine product, adds the desired amount of sodium chloroacetate, when 85 DEG C of reactions 15 are small, through absolute ethyl alcohol
Long carbon chain beet alkali surface activator is obtained after recrystallization purification；Wherein, triacontanoic acid methyl esters:N, N- dimethyl-ethylenediamine:Chloroethene
The molar ratio of sour sodium is 1:2:1.5.
B) triacontanoic acid amido carboxyl beet alkali surface activator prepared by naphthalene sulfonate and the present invention is dissolved separately in water
In, stir 30 minutes, aqueous solution is configured to, then by above-mentioned surfactant according to beet alkali surface activator and anion table
Face activating agent molar ratio is 1:0.7 is uniformly mixed, and obtains the glutinous composition for playing surfactant.
2. surfactant properties are evaluated
In addition to oil displacement agent composition is different, method of evaluating performance is the same as embodiment 1.For ease of comparing the composition of oil displacement agent
Table 1 is listed in, evaluation result is listed in table 2.
【Embodiment 3】
1. prepared by surfactant
(1) n-nonanoic acid amido carboxyl beet alkali surface activator (R1=C8, R2=C3、R3=C3) preparation
A) 0.5 mole of methyl pelargonate and the desired amount of amidation reagent N, N- dimethylated propyl diethylenetriamine are added into reaction kettle
In, when 135 DEG C of reactions 10 are small, vacuum pump is opened, extracts methanol and excessive N that reaction produces, N- dimethylated propyl diethylenetriamines, obtain
To n-nonanoic acid acyl group tertiary amine product, the desired amount of β-chloropropionic acid sodium is added, when 75 DEG C of reactions 10 are small, is tied again through absolute ethyl alcohol
Long carbon chain beet alkali surface activator is obtained after crystalline substance purification；Wherein, methyl pelargonate:N, N- dimethylated propyl diethylenetriamine:β-chloropropionic acid
The molar ratio of sodium is 1:2:1.6.
B) n-nonanoic acid amido carboxyl beet alkali surface activator prepared by naphthalene sulfonate and the present invention is dissolved in water,
Stirring 30 minutes, is configured to aqueous solution, then by above-mentioned surfactant according to beet alkali surface activator and anionic surface
Activating agent molar ratio is 1:0.7 is uniformly mixed, and obtains the glutinous composition for playing surfactant.
2. surfactant properties are evaluated
In addition to oil displacement agent composition is different, method of evaluating performance is the same as embodiment 1.For ease of comparing the composition of oil displacement agent
Table 1 is listed in, evaluation result is listed in table 2.
【Embodiment 4】
1. prepared by surfactant
(1) lauric amide carboxyl betaine surfactant (R1=C11, R2=C3、R3=C3) preparation
A) 0.5 mole of methyl laurate and the desired amount of amidation reagent N, N- dimethylated propyl diethylenetriamine are added into reaction kettle
In, when 140 DEG C of reactions 10 are small, vacuum pump is opened, extracts methanol and excessive N that reaction produces, N- dimethylated propyl diethylenetriamines, obtain
To laurate acyl group tertiary amine product, the desired amount of β-chloropropionic acid sodium is added, when 75 DEG C of reactions 10 are small, with absolute ethyl alcohol weight
Long carbon chain beet alkali surface activator is obtained after crystallization and purification；Wherein, methyl laurate:N, N- dimethylated propyl diethylenetriamine:β-chloro
The molar ratio of sodium propionate is 1:2.5:1.5.
B) lauric amide carboxyl betaine surfactant prepared by naphthalene sulfonate and the present invention is dissolved separately in water
In, stir 30 minutes, aqueous solution is configured to, then by above-mentioned surfactant according to beet alkali surface activator and anion table
Face activating agent molar ratio is 1:0.7 is uniformly mixed, and obtains the glutinous composition for playing surfactant.
2. surfactant properties are evaluated
In addition to oil displacement agent composition is different, method of evaluating performance is the same as embodiment 1.For ease of comparing the composition of oil displacement agent
Table 1 is listed in, evaluation result is listed in table 2.
【Embodiment 5】
1. prepared by surfactant
By the erucyl amide carboxyl betaine surfactant in embodiment 1, the lauric amide carboxyl sweet tea in embodiment 4
Dish alkali surfactant and naphthalene sulfonate are dissolved in water, and are stirred 30 minutes, aqueous solution are configured to, then by above-mentioned surface
Activating agent is according to the both sexes of erucyl amide carboxybetaine, n-nonanoic acid amido carboxyl beet alkali surface activator and anion surface active
Agent molar ratio is 0.5:0.5:0.7 is uniformly mixed, and obtains the glutinous composition for playing surfactant.
2. surfactant properties are evaluated
In addition to oil displacement agent composition is different, method of evaluating performance is the same as embodiment 1.For ease of comparing the composition of oil displacement agent
Table 1 is listed in, evaluation result is listed in table 2.
【Embodiment 6】
1. prepared by surfactant
By the erucyl amide carboxyl betaine surfactant in embodiment 1, the n-nonanoic acid amido carboxyl beet in embodiment 3
Alkali surfactant and naphthalene sulfonate are dissolved in water, and are stirred 30 minutes, are configured to aqueous solution, then above-mentioned surface is lived
Property agent is according to the both sexes of erucyl amide carboxybetaine, n-nonanoic acid amido carboxyl beet alkali surface activator and anion surfactant
Molar ratio is 0.5:0.5:0.7 is uniformly mixed, and obtains the glutinous composition for playing surfactant.
2. surfactant properties are evaluated
In addition to oil displacement agent composition is different, method of evaluating performance is the same as embodiment 1.For ease of comparing the composition of oil displacement agent
Table 1 is listed in, evaluation result is listed in table 2.
【Comparative example 1】
1. prepared by surfactant
Naphthalene sulfonate and docosyl carboxyl betaine surfactant are dissolved in water, stirred 30 minutes,
Aqueous solution is configured to, then by above-mentioned surfactant according to beet alkali surface activator and anion surfactant molar ratio
For 1:1 is uniformly mixed, and obtains the glutinous composition for playing surfactant.
2. surfactant properties are evaluated
In addition to oil displacement agent composition is different, method of evaluating performance is the same as embodiment 1.For ease of comparing the composition of oil displacement agent
Table 1 is listed in, evaluation result is listed in table 2.
【Comparative example 2】
1. prepared by surfactant
According to the method described in patent CN103242816B, the surfactant of synthesis such as lower structure：C11H23CON
(CH2CH2OH)2, naphthalene sulfonate and the surfactant of synthesis are dissolved in water, stirs 30 minutes, is configured to water-soluble
Liquid, is then 1 according to the surfactant and anion surfactant molar ratio of synthesis by above-mentioned surfactant:1 mixing
Uniformly, the glutinous composition for playing surfactant is obtained.
2. surfactant properties are evaluated
In addition to oil displacement agent composition is different, method of evaluating performance is the same as embodiment 1.For ease of comparing the composition of oil displacement agent
Table 1 is listed in, evaluation result is listed in table 2.
【Comparative example 3】
1. prepared by surfactant
By the erucyl amide carboxyl betaine surfactant in embodiment 1, the n-nonanoic acid amido carboxyl beet in embodiment 3
Alkali surfactant is dissolved in water, and is stirred 30 minutes, aqueous solution is configured to, then by above-mentioned surfactant according to mustard
Sour amido carboxyl beet alkali ampholytic, n-nonanoic acid amido carboxyl beet alkali surface activator molar ratio are 1:1 is uniformly mixed, and obtains surface
The composition of activating agent.
2. surfactant properties are evaluated
In addition to oil displacement agent composition is different, method of evaluating performance is the same as embodiment 1.For ease of comparing the composition of oil displacement agent
Table 1 is listed in, evaluation result is listed in table 2.
Surface activator composition composition in 1 embodiment of table and comparative example
Oil displacement agent performance evaluation in 2 embodiment of table and comparative example
| Viscosity (mPa.s) | Interfacial tension (mN/m) | Improve recovery ratio % | |
| Embodiment 1 | 20.7 | 0.0078 | 14.2 |
| Embodiment 2 | 16.7 | 0.0058 | 13.7 |
| Embodiment 3 | 15.8 | 0.0083 | 12.6 |
| Embodiment 4 | 15.7 | 0.0080 | 12.5 |
| Embodiment 5 | 22.5 | 0.00027 | 15.1 |
| Embodiment 6 | 21.6 | 0.00050 | 14.8 |
| Comparative example 1 | 9.5 | 0.012 | 7.9 |
| Comparative example 2 | 2.6 | 0.015 | 5.1 |
| Comparative example 3 | 6.0 | 0.014 | 8.5 |
3 Jiangsu oilfield of table sand, seven live water
| Unit | Na++K+ | Mg2+ | Ca2+ | Cl- | SO4 2- | HCO3 - | TDS |
| mg/L | 8730.8 | 154 | 220 | 10224 | 1507.7 | 5152.5 | 25830 |
Claims (10)
1. a kind of alkali-free sticks bullet surface activator composition, including beet alkali surface activator, anion surfactant, described
The molar ratio of beet alkali surface activator and anion surfactant is 1: 0.01~1: 100；The glycine betaine Surfactant
Selected from least one of structure as shown in (I) in formula：
In formula (I), R1Selected from C8~C29Alkyl, at least one of alkenyl, the R2And R3It is independently chosen from C1~C5's
At least one of alkylidene, hydroxyl substituted alkylene, the R4And R5It is independently chosen from C1~C4Alkyl, hydroxyl substitution
At least one of alkyl；
The anion surfactant is selected from least one of structure as shown in (II) in formula：
X is selected from least one of carboxylate radical, sulfonate radical in formula (II).
2. alkali-free according to claim 1 sticks bullet surface activator composition, it is characterised in that the amphoteric surface lives
R in property agent1For C12~C25At least one of alkyl or alkenyl, R2For C2~C3Alkylidene or hydroxyl substituted alkylene in
At least one, R3For C1~C3Alkylidene.
3. alkali-free according to claim 2 sticks bullet surface activator composition, it is characterised in that the amphoteric surface lives
R in property agent1For C16~C22At least one of alkyl or alkenyl, R2For C3Alkylidene or hydroxyl substituted alkylene in extremely
Few one kind, R3For C1~C2Alkylidene.
4. alkali-free according to any one of claim 1 to 3 sticks bullet surface activator composition, it is characterized in that the combination
Thing includes water.
5. alkali-free according to claim 1 sticks bullet surface activator composition, it is characterised in that lives on the glycine betaine surface
Property agent is R1For C15~C29Long carbon chain carboxylate beet alkali surface activator and R1For C8~C14Short carbon chain carboxylate beet
Two or more combinations in alkali surfactant.
6. alkali-free according to claim 1 sticks bullet surface activator composition, it is characterised in that the anionic surface
Activating agent is selected from benzene carboxylic acid salt, halo benzene sulfonate, hydroxyl substituted benzenesulfonic acid salt, naphthalene sulfonate and alkyl substitution naphthalene-carboxylic acid salt
At least one of.
7. alkali-free according to claim 1 sticks bullet surface activator composition, it is characterised in that the composition also wraps
Include water.
8. any alkali-free of claim 1~7 sticks the preparation method for playing surface activator composition, comprise the following steps：
A) by aliphatic acid acid or its ester and required amidation reagent when 100~160 DEG C of reactions 3~20 are small；Then add carboxylic
Change reagent ZR3COOM in 50~100 DEG C the reaction was continued 2~20 it is small when, obtain the beet alkali surface activator described in formula (I)；Its
In, fatty acid methyl ester：Amidation reagent：The molar ratio of carboxylating reagent is 1：(1~3)：(1~4)；Z be selected from hydrogen, hydroxyl, halogen,
Any one in amino, any one of M in alkali metal, alkaline-earth metal, ammonium ion；
B) it is dissolved in water by anion surfactant and according to the obtained beet alkali surface activators of step a), then
It is (1 according to molar ratio：0.1)~(1：10) it is uniformly mixed, obtains the surface activator composition.
9. the flooding method in a kind of LOW PERMEABILITY RESERVOIR, including displacement composition injection any one of claim 1~7 is low
Permeability, which is hidden, carries out the displacement of reservoir oil.
10. the flooding method in LOW PERMEABILITY RESERVOIR according to claim 9, it is characterised in that the infiltration in the LOW PERMEABILITY RESERVOIR
Rate is 1~40mD.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610878259.5A CN107916099B (en) | 2016-10-08 | 2016-10-08 | Alkali-free viscoelastic surfactant composition and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610878259.5A CN107916099B (en) | 2016-10-08 | 2016-10-08 | Alkali-free viscoelastic surfactant composition and preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107916099A true CN107916099A (en) | 2018-04-17 |
| CN107916099B CN107916099B (en) | 2020-08-07 |
Family
ID=61892153
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610878259.5A Active CN107916099B (en) | 2016-10-08 | 2016-10-08 | Alkali-free viscoelastic surfactant composition and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107916099B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108929662A (en) * | 2018-08-08 | 2018-12-04 | 陕西友邦石油工程技术有限公司 | It is a kind of to carry the Profile Control in Injection Well technique that liquid prepares oily sludge blocking agent with cleaning |
| CN112707941A (en) * | 2019-10-25 | 2021-04-27 | 中石化南京化工研究院有限公司 | Environment-friendly glycoside zwitterion foaming agent for foam drilling |
| CN115746815A (en) * | 2021-09-06 | 2023-03-07 | 中石化南京化工研究院有限公司 | Surfactant composition based on anion-cation pair effect and application thereof in well drilling and completion |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1263481A (en) * | 1997-06-10 | 2000-08-16 | 罗狄亚公司 | Fluids containing viscoelastic surfactant and methods for using the same |
| CN1814692A (en) * | 2005-02-03 | 2006-08-09 | 刘春德 | Carboxyl-betaine and sulfosalt surfactant formula system and use in the third oil-production |
| CN101955448A (en) * | 2010-03-19 | 2011-01-26 | 中国石油天然气股份有限公司 | Amide group-containing hydroxysulfobetaine and preparation and application thereof |
| CN102851017A (en) * | 2012-08-16 | 2013-01-02 | 四川西普化工股份有限公司 | Viscous-elastic clean fracturing fluid containing erucic acid betaines |
| CN104073235A (en) * | 2014-06-19 | 2014-10-01 | 西安石油大学 | Long-carbon-chain amide glycine betaine clean fracturing fluid and preparation method thereof |
| CN104109518A (en) * | 2013-04-16 | 2014-10-22 | 中国石油化工股份有限公司 | Oil displacement composition used for low permeability oil reservoirs, and preparation method thereof |
| CN104277807A (en) * | 2013-07-09 | 2015-01-14 | 中国石油化工股份有限公司 | Alkali-free oil displacement system suitable for high-temperature high wax-bearing oil reservoirs and application thereof |
-
2016
- 2016-10-08 CN CN201610878259.5A patent/CN107916099B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1263481A (en) * | 1997-06-10 | 2000-08-16 | 罗狄亚公司 | Fluids containing viscoelastic surfactant and methods for using the same |
| CN101757874A (en) * | 1997-06-10 | 2010-06-30 | 罗狄亚公司 | Viscoelastic surfactant fluids and related methods of use |
| CN1814692A (en) * | 2005-02-03 | 2006-08-09 | 刘春德 | Carboxyl-betaine and sulfosalt surfactant formula system and use in the third oil-production |
| CN101955448A (en) * | 2010-03-19 | 2011-01-26 | 中国石油天然气股份有限公司 | Amide group-containing hydroxysulfobetaine and preparation and application thereof |
| CN102851017A (en) * | 2012-08-16 | 2013-01-02 | 四川西普化工股份有限公司 | Viscous-elastic clean fracturing fluid containing erucic acid betaines |
| CN104109518A (en) * | 2013-04-16 | 2014-10-22 | 中国石油化工股份有限公司 | Oil displacement composition used for low permeability oil reservoirs, and preparation method thereof |
| CN104277807A (en) * | 2013-07-09 | 2015-01-14 | 中国石油化工股份有限公司 | Alkali-free oil displacement system suitable for high-temperature high wax-bearing oil reservoirs and application thereof |
| CN104073235A (en) * | 2014-06-19 | 2014-10-01 | 西安石油大学 | Long-carbon-chain amide glycine betaine clean fracturing fluid and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108929662A (en) * | 2018-08-08 | 2018-12-04 | 陕西友邦石油工程技术有限公司 | It is a kind of to carry the Profile Control in Injection Well technique that liquid prepares oily sludge blocking agent with cleaning |
| CN108929662B (en) * | 2018-08-08 | 2020-12-01 | 陕西友邦石油工程技术有限公司 | Water injection well profile control process for preparing oil-containing sludge plugging agent by using clean carrier fluid |
| CN112707941A (en) * | 2019-10-25 | 2021-04-27 | 中石化南京化工研究院有限公司 | Environment-friendly glycoside zwitterion foaming agent for foam drilling |
| CN112707941B (en) * | 2019-10-25 | 2023-01-31 | 中石化南京化工研究院有限公司 | Environment-friendly glycoside zwitterion foaming agent for foam drilling |
| CN115746815A (en) * | 2021-09-06 | 2023-03-07 | 中石化南京化工研究院有限公司 | Surfactant composition based on anion-cation pair effect and application thereof in well drilling and completion |
| CN115746815B (en) * | 2021-09-06 | 2023-12-12 | 中石化南京化工研究院有限公司 | Surfactant composition based on anion-cation pair effect and application thereof in well drilling and completion |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107916099B (en) | 2020-08-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Tackie-Otoo et al. | Alternative chemical agents for alkalis, surfactants and polymers for enhanced oil recovery: Research trend and prospects | |
| CN101310093B (en) | Methods for recovering oil from an oil reservoir | |
| AU2011306712B2 (en) | Tethered polymers used to enhance the stability of microemulsion fluids | |
| CN102952531B (en) | Surfactant for displacing oil of offshore oilfield and preparation method thereof | |
| CN103422840B (en) | Use the flooding method of anions and canons complexed surfactant | |
| CN104277807B (en) | It is adapted to alkali-free oil displacement system and its application of high temperature high-content wax oil reservoir | |
| CN104109518B (en) | Displacement composition for low-permeability oil deposit and preparation method thereof | |
| CN114196389A (en) | Ultralow interfacial tension self-assembly carbon dioxide foam oil displacement agent suitable for low-permeability oil reservoir, and preparation method and application thereof | |
| CN110317598A (en) | Improve compact reservoir CO2Drive the aqueous solution of effect and its preparation method and application method | |
| CN104119852A (en) | Fracturing acidizing nano emulsion cleanup additive and preparation method thereof | |
| CN104694103A (en) | A Surfactant Compound System with Reservoir Adaptability | |
| EP0037699B1 (en) | Polymer microemulsion complexes and their use for the enhanced recovery of oil | |
| CN106593373B (en) | The method that low cost improves oil recovery factor | |
| CN107916099A (en) | Alkali-free, which sticks, plays surface activator composition and its preparation method and application | |
| CN104818008B (en) | The vesica oil displacement agent and application that a kind of anion surfactant compound system is formed | |
| CN107916098A (en) | Displacement of reservoir oil Surfactant Used in Viscoelastic Fracturing Fluids composition and its preparation method and application | |
| CN113292982B (en) | Viscoelastic surfactant foam system and preparation method and application thereof | |
| CN107916096A (en) | The displacement of reservoir oil Surfactant Used in Viscoelastic Fracturing Fluids composition and preparation method and application | |
| CN109679627B (en) | Oil displacement composition containing carboxyl betaine surfactant, preparation method and application thereof | |
| CN114437703A (en) | Efficient composite foaming cleanup additive for fracturing and preparation method thereof | |
| CN107603582A (en) | A kind of air foam displacement of reservoir oil efficient foaming agent and preparation method thereof | |
| CN107916101A (en) | Alkali-free, which sticks, plays surfactant and preparation method and applications | |
| CN107916097B (en) | Viscoelastic betaine surfactant composition for oil displacement | |
| CN107916100A (en) | Viscoelasticity beet alkali surface activator and its preparation method and application | |
| CN109666473A (en) | Surfactant binary built flooding method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |