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CN107915875A - A kind of environment-protective rubber material - Google Patents

A kind of environment-protective rubber material Download PDF

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Publication number
CN107915875A
CN107915875A CN201711447643.0A CN201711447643A CN107915875A CN 107915875 A CN107915875 A CN 107915875A CN 201711447643 A CN201711447643 A CN 201711447643A CN 107915875 A CN107915875 A CN 107915875A
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CN
China
Prior art keywords
parts
rubber
environment
nano
abrasion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201711447643.0A
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Chinese (zh)
Inventor
李季
戴宇辉
魏巍
李俊
李志远
梁天也
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Anhui Wei Wei Environmental Protection Technology Co Ltd
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Anhui Wei Wei Environmental Protection Technology Co Ltd
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Priority to CN201711447643.0A priority Critical patent/CN107915875A/en
Publication of CN107915875A publication Critical patent/CN107915875A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2203Oxides; Hydroxides of metals of lithium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/001Conductive additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of environment-protective rubber material, is made of the raw material of following parts by weight:75 85 parts of natural rubber, 30 40 parts of phenyl siloxane rubber, 8 18 parts of bamboo fibre, 26 parts of nano-titanium dioxide, 15 parts of lignocellulosic, 26 parts of turpentine oil, 26 parts of age resister, 17 parts of conductive fiber, 13 parts of antistatic additive, 0.5 1.5 parts of lithia, 0.5 1.5 parts of zinc oxide, 0.5 1.5 parts of boron oxide, 0.5 1.5 parts of tellurium dioxide, 15 parts of abrasion-resistant powder, 35 parts of resin acid type thermal stabilizing agent, 59 parts of accelerating agent, 5 12 parts of nano fumed silica, 28 parts of ZnOw, 10 30 parts of nanoclay, 48 parts of fire retardant, 28 parts of Wax-for preventing rubber.Ingredient of the present invention is more environmentally-friendly, the development trend of composite environmental-friendly, and the present invention adds a certain amount of phenyl siloxane rubber in natural rubber so that high- and low-temperature resistance performance is good, and good permeability, intensity are high, good combination property;The addition of abrasion-resistant powder so that wearability, machining property are good.

Description

A kind of environment-protective rubber material
Technical field
The present invention relates to rubber manufacturing field, is specifically a kind of environment-protective rubber material.
Background technology
Raw rubber is the material of main part of rubber manufacture.Rubber is a kind of flexible polymer, according to mode is made Difference, rubber can be divided into two class of synthetic rubber and natural rubber.Natural rubber is mainly derived from para ruber, when this rubber When the epidermis of gum tree is cut open, will flow out milky juice, be known as latex, latex through agglomerating, washing, being molded, it is dry i.e. Obtain natural rubber.Prepared by synthetic rubber is by artificial synthesis, can synthesize variety classes using different raw materials Rubber, such as butadiene rubber, neoprene, butadiene-styrene rubber, nitrile rubber.
Existing elastomeric material, which is commonly incorporated into environment, the heavy metals such as the lead, cadmium, sexivalent chromium of larger infringement, mercury, is unsatisfactory for pair The requirement of environmental protection.
The content of the invention
It is an object of the invention to provide a kind of environment-protective rubber material, to solve the problems mentioned in the above background technology.
To achieve the above object, the present invention provides following technical solution:
A kind of environment-protective rubber material, is made of the raw material of following parts by weight:
It is 75-85 parts of natural rubber, 30-40 parts of phenyl siloxane rubber, 8-18 parts of bamboo fibre, 2-6 parts of nano-titanium dioxide, wooden 1-5 parts of cellulose, 2-6 parts of turpentine oil, 2-6 parts of age resister, 1-7 parts of conductive fiber, 1-3 parts of antistatic additive, lithia 0.5- 1.5 parts, 0.5-1.5 parts of zinc oxide, 0.5-1.5 parts of boron oxide, 0.5-1.5 parts of tellurium dioxide, 1-5 parts of abrasion-resistant powder, resin acid class heat 3-5 parts of stabilizer, 5-9 parts of accelerating agent, 5-12 parts of nano fumed silica, 2-8 parts of ZnOw, nanoclay 10-30 Part, 4-8 parts of fire retardant, 2-8 parts of Wax-for preventing rubber.
A kind of environment-protective rubber material, is made of the raw material of following parts by weight:
75 parts of natural rubber, 30 parts of phenyl siloxane rubber, 8 parts of bamboo fibre, 2 parts of nano-titanium dioxide, 1 part of lignocellulosic, 2 parts of turpentine oil, 2 parts of age resister, 1 part of conductive fiber, 1 part of antistatic additive, 0.5 part of lithia, 0.5 part of zinc oxide, boron oxide 0.5 part, 0.5 part of tellurium dioxide, 1 part of abrasion-resistant powder, 3 parts of resin acid type thermal stabilizing agent, 5 parts of accelerating agent, nano fumed silica 5 Part, 2 parts of ZnOw, 10 parts of nanoclay, 4 parts of fire retardant, 2 parts of Wax-for preventing rubber.
A kind of environment-protective rubber material, is made of the raw material of following parts by weight:
85 parts of natural rubber, 40 parts of phenyl siloxane rubber, 18 parts of bamboo fibre, 6 parts of nano-titanium dioxide, 5 parts of lignocellulosic, 6 parts of turpentine oil, 6 parts of age resister, 7 parts of conductive fiber, 3 parts of antistatic additive, 1.5 parts of lithia, 1.5 parts of zinc oxide, boron oxide 1.5 parts, 1.5 parts of tellurium dioxide, 5 parts of abrasion-resistant powder, 5 parts of resin acid type thermal stabilizing agent, 9 parts of accelerating agent, nano fumed silica 12 Part, 8 parts of ZnOw, 30 parts of nanoclay, 8 parts of fire retardant, 8 parts of Wax-for preventing rubber.
A kind of environment-protective rubber material, is made of the raw material of following parts by weight:
80 parts of natural rubber, 33 parts of phenyl siloxane rubber, 13 parts of bamboo fibre, 4 parts of nano-titanium dioxide, 3 parts of lignocellulosic, 4 parts of turpentine oil, 4 parts of age resister, 5 parts of conductive fiber, 2 parts of antistatic additive, 1 part of lithia, 1 part of zinc oxide, 1 part of boron oxide, 1 part of tellurium dioxide, 3 parts of abrasion-resistant powder, 4 parts of resin acid type thermal stabilizing agent, 7 parts of accelerating agent, 8 parts of nano fumed silica, zinc oxide 5 parts of whisker, 20 parts of nanoclay, 6 parts of fire retardant, 5 parts of Wax-for preventing rubber.
The conductive fiber is continuity carbon fiber.
The fire retardant is phosphor nitrogen combustion inhibitor.
The accelerating agent is sulfenamide type accelerators.
The abrasion-resistant powder is made of bamboo charcoal powder, mica particles and montmorillonite particle, bamboo charcoal powder:Mica particles:Montmorillonite Grain is 1:2-4:1-4, by weight, the granularity of montmorillonite is 200 mesh, and the granularity of mica particles is 50 mesh.
Compared with prior art, the beneficial effects of the invention are as follows:
Ingredient of the present invention is more environmentally-friendly, the development trend of composite environmental-friendly, and the present invention adds one in natural rubber Quantitative phenyl siloxane rubber so that obtained elastomeric material high- and low-temperature resistance performance is good, and good permeability, intensity are high, comprehensive performance It is good;Acted on by adding conductive fiber, antistatic additive, ZnOw coordinated so that elastomeric material of the invention has Good antistatic property;The addition of bamboo fibre, lignocellulosic, can not only discharge substantial amounts of anion, and adsorb peculiar smell, Antibacterial and deodorizing capability are strong, while creatively with the addition of lithia, zinc oxide, boron oxide, tellurium dioxide so that obtained rubber Glue material has the advantages that good mechanical properties, corrosion-resistant, electric conductivity is superior, ductility is good;What is added in formula is anti-aging Agent further increases the anti-aging property of the elastomeric material, extends service life, improves quality;The addition of abrasion-resistant powder so that Wearability, machining property are good;Have that material selection is reasonable, each materials compatibility is good at the same time, without have to human and environment compared with The heavy metals such as the lead, cadmium, sexivalent chromium damaged greatly, mercury, meet requirement of the standard to environmental protection, safety and environmental protection.
Embodiment
Embodiment 1
A kind of environment-protective rubber material, is made of the raw material of following parts by weight:
75 parts of natural rubber, 30 parts of phenyl siloxane rubber, 8 parts of bamboo fibre, 2 parts of nano-titanium dioxide, 1 part of lignocellulosic, 2 parts of turpentine oil, 2 parts of age resister, 1 part of conductive fiber, 1 part of antistatic additive, 0.5 part of lithia, 0.5 part of zinc oxide, boron oxide 0.5 part, 0.5 part of tellurium dioxide, 1 part of abrasion-resistant powder, 3 parts of resin acid type thermal stabilizing agent, 5 parts of accelerating agent, nano fumed silica 5 Part, 2 parts of ZnOw, 10 parts of nanoclay, 4 parts of fire retardant, 2 parts of Wax-for preventing rubber.
The conductive fiber is continuity carbon fiber.
The fire retardant is phosphor nitrogen combustion inhibitor.
The accelerating agent is sulfenamide type accelerators.
The abrasion-resistant powder is made of bamboo charcoal powder, mica particles and montmorillonite particle, bamboo charcoal powder:Mica particles:Montmorillonite Grain is 1:2-4:1-4, by weight, the granularity of montmorillonite is 200 mesh, and the granularity of mica particles is 50 mesh.
Embodiment 2
A kind of environment-protective rubber material, is made of the raw material of following parts by weight:
85 parts of natural rubber, 40 parts of phenyl siloxane rubber, 18 parts of bamboo fibre, 6 parts of nano-titanium dioxide, 5 parts of lignocellulosic, 6 parts of turpentine oil, 6 parts of age resister, 7 parts of conductive fiber, 3 parts of antistatic additive, 1.5 parts of lithia, 1.5 parts of zinc oxide, boron oxide 1.5 parts, 1.5 parts of tellurium dioxide, 5 parts of abrasion-resistant powder, 5 parts of resin acid type thermal stabilizing agent, 9 parts of accelerating agent, nano fumed silica 12 Part, 8 parts of ZnOw, 30 parts of nanoclay, 8 parts of fire retardant, 8 parts of Wax-for preventing rubber.
The conductive fiber is continuity carbon fiber.
The fire retardant is phosphor nitrogen combustion inhibitor.
The accelerating agent is sulfenamide type accelerators.
The abrasion-resistant powder is made of bamboo charcoal powder, mica particles and montmorillonite particle, bamboo charcoal powder:Mica particles:Montmorillonite Grain is 1:2-4:1-4, by weight, the granularity of montmorillonite is 200 mesh, and the granularity of mica particles is 50 mesh.
Embodiment 3
A kind of environment-protective rubber material, is made of the raw material of following parts by weight:
80 parts of natural rubber, 33 parts of phenyl siloxane rubber, 13 parts of bamboo fibre, 4 parts of nano-titanium dioxide, 3 parts of lignocellulosic, 4 parts of turpentine oil, 4 parts of age resister, 5 parts of conductive fiber, 2 parts of antistatic additive, 1 part of lithia, 1 part of zinc oxide, 1 part of boron oxide, 1 part of tellurium dioxide, 3 parts of abrasion-resistant powder, 4 parts of resin acid type thermal stabilizing agent, 7 parts of accelerating agent, 8 parts of nano fumed silica, zinc oxide 5 parts of whisker, 20 parts of nanoclay, 6 parts of fire retardant, 5 parts of Wax-for preventing rubber.
The conductive fiber is continuity carbon fiber.
The fire retardant is phosphor nitrogen combustion inhibitor.
The accelerating agent is sulfenamide type accelerators.
The abrasion-resistant powder is made of bamboo charcoal powder, mica particles and montmorillonite particle, bamboo charcoal powder:Mica particles:Montmorillonite Grain is 1:2-4:1-4, by weight, the granularity of montmorillonite is 200 mesh, and the granularity of mica particles is 50 mesh.

Claims (8)

1. a kind of environment-protective rubber material, it is characterised in that be made of the raw material of following parts by weight:
75-85 parts of natural rubber, 30-40 parts of phenyl siloxane rubber, 8-18 parts of bamboo fibre, 2-6 parts of nano-titanium dioxide, wood fibre 1-5 parts plain, 2-6 parts of turpentine oil, 2-6 parts of age resister, 1-7 parts of conductive fiber, 1-3 parts of antistatic additive, lithia 0.5-1.5 Part, 0.5-1.5 parts of zinc oxide, 0.5-1.5 parts of boron oxide, 0.5-1.5 parts of tellurium dioxide, 1-5 parts of abrasion-resistant powder, resin acid class thermostabilization 3-5 parts of agent, 5-9 parts of accelerating agent, 5-12 parts of nano fumed silica, 2-8 parts of ZnOw, 10-30 parts of nanoclay, resistance Fire 4-8 parts of agent, 2-8 parts of Wax-for preventing rubber.
2. environment-protective rubber material according to claim 1, it is characterised in that be made of the raw material of following parts by weight:
75 parts of natural rubber, 30 parts of phenyl siloxane rubber, 8 parts of bamboo fibre, 2 parts of nano-titanium dioxide, 1 part of lignocellulosic, turpentine 2 parts of oil, 2 parts of age resister, 1 part of conductive fiber, 1 part of antistatic additive, 0.5 part of lithia, 0.5 part of zinc oxide, boron oxide 0.5 Part, 0.5 part of tellurium dioxide, 1 part of abrasion-resistant powder, 3 parts of resin acid type thermal stabilizing agent, 5 parts of accelerating agent, 5 parts of nano fumed silica, oxygen Change 2 parts of zinc whisker, 10 parts of nanoclay, 4 parts of fire retardant, 2 parts of Wax-for preventing rubber.
3. environment-protective rubber material according to claim 1, it is characterised in that be made of the raw material of following parts by weight:
85 parts of natural rubber, 40 parts of phenyl siloxane rubber, 18 parts of bamboo fibre, 6 parts of nano-titanium dioxide, 5 parts of lignocellulosic, turpentine 6 parts of oil, 6 parts of age resister, 7 parts of conductive fiber, 3 parts of antistatic additive, 1.5 parts of lithia, 1.5 parts of zinc oxide, boron oxide 1.5 Part, 1.5 parts of tellurium dioxide, 5 parts of abrasion-resistant powder, 5 parts of resin acid type thermal stabilizing agent, 9 parts of accelerating agent, 12 parts of nano fumed silica, 8 parts of ZnOw, 30 parts of nanoclay, 8 parts of fire retardant, 8 parts of Wax-for preventing rubber.
4. environment-protective rubber material according to claim 1, it is characterised in that be made of the raw material of following parts by weight:
80 parts of natural rubber, 33 parts of phenyl siloxane rubber, 13 parts of bamboo fibre, 4 parts of nano-titanium dioxide, 3 parts of lignocellulosic, turpentine 4 parts of oil, 4 parts of age resister, 5 parts of conductive fiber, 2 parts of antistatic additive, 1 part of lithia, 1 part of zinc oxide, 1 part of boron oxide, dioxy Change 1 part of tellurium, 3 parts of abrasion-resistant powder, 4 parts of resin acid type thermal stabilizing agent, 7 parts of accelerating agent, 8 parts of nano fumed silica, ZnOw 5 Part, 20 parts of nanoclay, 6 parts of fire retardant, 5 parts of Wax-for preventing rubber.
5. environment-protective rubber material according to claim 1, it is characterised in that the conductive fiber is continuity carbon fiber.
6. environment-protective rubber material according to claim 1, it is characterised in that the fire retardant is phosphor nitrogen combustion inhibitor.
7. environment-protective rubber material according to claim 1, it is characterised in that the accelerating agent promotes for sulfenamide Agent.
8. environment-protective rubber material according to claim 1, it is characterised in that the abrasion-resistant powder is by bamboo charcoal powder, mica particles Formed with montmorillonite particle, bamboo charcoal powder:Mica particles:Montmorillonite particle is 1:2-4:1-4, by weight, the grain of montmorillonite Spend for 200 mesh, the granularity of mica particles is 50 mesh.
CN201711447643.0A 2017-12-27 2017-12-27 A kind of environment-protective rubber material Withdrawn CN107915875A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711447643.0A CN107915875A (en) 2017-12-27 2017-12-27 A kind of environment-protective rubber material

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Application Number Priority Date Filing Date Title
CN201711447643.0A CN107915875A (en) 2017-12-27 2017-12-27 A kind of environment-protective rubber material

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CN107915875A true CN107915875A (en) 2018-04-17

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109401323A (en) * 2018-10-31 2019-03-01 长沙市佳密封件有限公司 A kind of Rubber seal material of heat-resistant fireproof
CN110669343A (en) * 2019-10-24 2020-01-10 广州赫尔普化工有限公司 Wear-resistant heat-conducting silicone rubber composite material and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106589483A (en) * 2016-12-28 2017-04-26 河南八灵电子科技有限公司 Rubber material with compression-resisting effect and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106589483A (en) * 2016-12-28 2017-04-26 河南八灵电子科技有限公司 Rubber material with compression-resisting effect and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109401323A (en) * 2018-10-31 2019-03-01 长沙市佳密封件有限公司 A kind of Rubber seal material of heat-resistant fireproof
CN110669343A (en) * 2019-10-24 2020-01-10 广州赫尔普化工有限公司 Wear-resistant heat-conducting silicone rubber composite material and preparation method thereof

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