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CN107901543A - A kind of composite material squeezes the preparation method of oiling roller non-woven fabrics - Google Patents

A kind of composite material squeezes the preparation method of oiling roller non-woven fabrics Download PDF

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Publication number
CN107901543A
CN107901543A CN201711148539.1A CN201711148539A CN107901543A CN 107901543 A CN107901543 A CN 107901543A CN 201711148539 A CN201711148539 A CN 201711148539A CN 107901543 A CN107901543 A CN 107901543A
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polyamide
fiber
antistatic agent
fiber material
woven fabric
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Inventor
姚新改
王晓玲
朱小文
白小云
孟华
郭峥嵘
张思盼
詹志远
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Taiyuan University of Technology
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Taiyuan University of Technology
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/028Net structure, e.g. spaced apart filaments bonded at the crossing points
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/266Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by an apertured layer, the apertures going through the whole thickness of the layer, e.g. expanded metal, perforated layer, slit layer regular cells B32B3/12
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326Condensation or reaction polymers
    • D04H1/4334Polyamides
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/587Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/70Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
    • D04H1/74Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being orientated, e.g. in parallel (anisotropic fleeces)
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/055 or more layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/20All layers being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/24All layers being polymeric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/02Coating on the layer surface on fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/26Polymeric coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0261Polyamide fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/536Hardness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/546Flexural strength; Flexion stiffness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/726Permeability to liquids, absorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/762Self-repairing, self-healing

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

本发明涉及无纺布制作领域。一种复合材料挤油辊用无纺布的制备方法,使聚酰胺66纤维材料与室内温度和湿度相同,将Goon881型抗静电整理剂与去离子水以体积比1:10混合配制成抗静电剂溶液,将抗静电剂溶液喷洒在聚酰胺66纤维材料表面,抗静电剂与聚酰胺66纤维材料质量比为1:20;将经过步骤二处理的聚酰胺66纤维材料在梳棉机上梳理,将自交联丙烯酸酯乳液粘合剂与去离子水以体积比0.47:1混合配置成工作液,将工作液喷砂在纤维网上,将烘干好的纤维网置于平板硫化机中,即得到复合材料挤油辊用无纺布材料。The invention relates to the field of non-woven fabric production. A method for preparing non-woven fabrics for oil squeeze rollers made of composite materials. The polyamide 66 fiber material is made to have the same temperature and humidity as the room, and Goon881 type antistatic finishing agent is mixed with deionized water at a volume ratio of 1:10 to prepare an antistatic Antistatic agent solution, antistatic agent solution is sprayed on polyamide 66 fiber material surface, antistatic agent and polyamide 66 fiber material mass ratio are 1:20; The polyamide 66 fiber material processed through step 2 is carded on the carding machine, Mix the self-crosslinking acrylate emulsion adhesive and deionized water at a volume ratio of 0.47:1 to prepare a working fluid, sandblast the working fluid on the fiber web, and place the dried fiber web in a flat vulcanizing machine, that is A non-woven fabric material for a composite squeeze roller is obtained.

Description

一种复合材料挤油辊用无纺布的制备方法A kind of preparation method of non-woven fabric for oil squeeze roller of composite material

技术领域technical field

本发明涉及无纺布制作领域。The invention relates to the field of non-woven fabric production.

背景技术Background technique

在现代化建设中,钢铁工业是国家基础性的原材料工业,轧钢企业生产产品的质量好坏,对我国经济建设有着非常重要的作用。随着市场竞争的日趋激烈,用户对产品的内在性能及表面质量提出了更高的要求。因此,提高轧制后带钢表面的清洁性是提高产品质量的关键环节。In modernization, the iron and steel industry is the country's basic raw material industry, and the quality of products produced by steel rolling enterprises plays a very important role in my country's economic construction. With the increasingly fierce market competition, users have put forward higher requirements for the internal performance and surface quality of products. Therefore, improving the cleanliness of the strip surface after rolling is a key link in improving product quality.

清除带钢表面残留物不但要求材料具有良好的吸油特性,同时要求材料应该具有一定的机械性能,如拉伸强度和硬度,以保证具有良好的轧干效果。为了去除带钢表面残留物,目前我国轧钢生产线上使用最多的是传统橡胶辊,在一定程度上能够去除带钢表面轧制油和残屑,但从发展的要求来看还存在极大差距。主要表现在以下几个方面:易老化和破裂,使用寿命短;无多孔特性,残屑不能被藏入胶辊内,在胶辊挤压力下,随着带钢的运动,残屑对带钢表面划伤严重;难以保证恒定的线压力,油膜厚度不可控,挤油效果不佳。Removing residues on the surface of the strip not only requires the material to have good oil absorption properties, but also requires the material to have certain mechanical properties, such as tensile strength and hardness, to ensure a good rolling effect. In order to remove the residues on the surface of the strip, traditional rubber rollers are currently the most used in my country's steel rolling production lines, which can remove rolling oil and debris on the surface of the strip to a certain extent, but there is still a huge gap in terms of development requirements. It is mainly manifested in the following aspects: easy aging and cracking, short service life; no porosity, debris cannot be hidden in the rubber roller, under the extrusion force of the rubber roller, with the movement of the strip steel, the debris on the belt The steel surface is severely scratched; it is difficult to ensure a constant linear pressure, the thickness of the oil film is uncontrollable, and the oil squeezing effect is not good.

聚合物材料具有良好的韧性、耐疲劳性和可加工性,逐渐替代金属材料成为制造滚动零件的首选材料。非织造布又称无纺布,根据特定制作方法制备的无纺布不仅具有良好的多孔吸油性,而且其拉伸强度和硬度都满足轧钢生产线上的使用要求。将其制作成无纺布挤油辊,具有独特的多孔性和可压缩性的特点,能够将带钢表面残屑藏于其多孔结构内,减少了带钢表面划伤,而且具有自愈性,使用寿命是传统胶辊的数百倍。同时还具有高摩擦系数以及挤油后带钢表面油膜厚度可控的优点,因此,将具有此特殊性能的无纺布用于轧钢生产线能够有效去除带钢表面残留物,减少带钢表面划伤,能够有效提高带钢表面质量。Polymer materials have good toughness, fatigue resistance and machinability, gradually replacing metal materials as the preferred material for manufacturing rolling parts. Non-woven fabrics are also called non-woven fabrics. Non-woven fabrics prepared according to specific production methods not only have good porous oil absorption, but also have tensile strength and hardness that meet the requirements for use in steel rolling production lines. It is made into a non-woven oil squeezing roller, which has unique porosity and compressibility, can hide the scraps on the surface of the strip in its porous structure, reduces scratches on the surface of the strip, and has self-healing properties , the service life is hundreds of times that of traditional rubber rollers. At the same time, it also has the advantages of high friction coefficient and controllable oil film thickness on the strip surface after oil squeezing. Therefore, using non-woven fabrics with this special property in the rolling production line can effectively remove strip surface residues and reduce strip surface scratches , can effectively improve the strip surface quality.

发明内容Contents of the invention

本发明所要解决的技术问题是:如何提供一种环保、高效、挤油效果好的新型复合材料挤油辊用无纺布。The technical problem to be solved by the present invention is: how to provide a new type of composite material non-woven fabric for oil squeezing rollers with environmental protection, high efficiency and good oil squeezing effect.

本发明所采用的技术方案是:一种复合材料挤油辊用无纺布的制备方法,按照如下的步骤进行The technical scheme adopted in the present invention is: a preparation method of non-woven fabric for oil squeeze roller of composite material, carried out according to the following steps

步骤一、将聚酰胺66纤维材料置于温度15℃-30℃相对湿度为30%-60%的环境中24小时或者以上;使聚酰胺66纤维材料与室内温度和湿度相同,便于后续梳理。Step 1. Place the polyamide 66 fiber material in an environment with a temperature of 15°C-30°C and a relative humidity of 30%-60% for 24 hours or more; make the polyamide 66 fiber material the same as the indoor temperature and humidity, which is convenient for subsequent carding.

步骤二、将由东莞市嘉宏有机硅科技有限公司生产的Goon881型抗静电整理剂与去离子水以体积比1:10混合配制成抗静电剂溶液,将抗静电剂溶液喷洒在聚酰胺66纤维材料表面,抗静电剂与聚酰胺66纤维材料质量比为1:20;Step 2. Mix the Goon881 antistatic finishing agent produced by Dongguan Jiahong Silicone Technology Co., Ltd. with deionized water at a volume ratio of 1:10 to prepare an antistatic agent solution, and spray the antistatic agent solution on the polyamide 66 fiber material On the surface, the mass ratio of antistatic agent to polyamide 66 fiber material is 1:20;

步骤三、将经过步骤二处理的聚酰胺66纤维材料在梳棉机上梳理,形成纵向和横向纹理均匀的纤维网;Step 3, carding the polyamide 66 fiber material processed in step 2 on a carding machine to form a fiber web with uniform longitudinal and transverse textures;

步骤四、将由青岛金森达化工有限公司生产的自交联丙烯酸酯乳液粘合剂与去离子水以体积比0.47:1混合配置成工作液,将工作液喷砂在纤维网上,每0.01平方米纤维网上喷洒5-10ml工作液,然后在100℃的干燥箱内烘干5分钟;Step 4. Mix the self-crosslinking acrylate emulsion adhesive produced by Qingdao Jinsenda Chemical Co., Ltd. and deionized water at a volume ratio of 0.47:1 to prepare a working fluid, and sandblast the working fluid on the fiber net, every 0.01 square meters Spray 5-10ml of working fluid on the fiber net, and then dry it in a drying oven at 100°C for 5 minutes;

步骤五、将烘干好的纤维网置于平板硫化机中,保持压力为0.5-5Mpa,温度为25-160℃,持续时间5-25min,即得到复合材料挤油辊用无纺布材料。Step 5. Put the dried fiber web in a flat vulcanizer, keep the pressure at 0.5-5Mpa, the temperature at 25-160°C, and the duration for 5-25min, to obtain the non-woven fabric material for the composite squeeze roller.

作为一种优选方式:步骤三将每25g的聚酰胺66纤维梳理成40-50次的纵向和横向并和,即40-50层,聚酰胺66纤维每层为纵向或者横向,相邻两层一层为纵向梳理则另一层为横向梳理,形成纵向和横向交错的均匀的聚酰胺66纤维网层。As a preferred method: in step 3, card each 25g of polyamide 66 fibers into 40-50 times of longitudinal and transverse combinations, that is, 40-50 layers, each layer of polyamide 66 fibers is longitudinal or transverse, and two adjacent layers One layer is carded longitudinally and the other layer is carded transversely to form a uniform polyamide 66 fiber web layer interlaced longitudinally and transversely.

本发明的有益效果是:无纺布具有良好的吸油特性,同时具有较强的拉伸强度、硬度和耐高温性,同时该方法生产的无纺布具有吸油率高,材料质量轻、易贮存,使用方便的特点,而且加工工艺简单,成本较低,易于工业化生产。本发明制作的无纺布非常适合用于冷轧带钢生产线去除轧钢表面轧制油,可以制成复合材料挤油辊,其挤油效果优于传统胶辊。因为该无纺布具有多孔性,可压缩性和自愈性,能够将带钢表面的碎屑藏进其孔隙中,避免了带钢表面的划伤,提高了带钢表面质量。同时该无纺布较传统橡胶辊具有高的摩擦系数,能够有效去除带钢表面轧制油,减少了轧制油的损耗。The beneficial effects of the invention are: the non-woven fabric has good oil-absorbing properties, and at the same time has strong tensile strength, hardness and high temperature resistance; at the same time, the non-woven fabric produced by the method has high oil-absorbing rate, light material quality and easy storage , easy to use, simple processing technology, low cost, and easy industrial production. The non-woven fabric produced by the invention is very suitable for removing rolling oil on the steel rolling surface in a cold-rolled steel strip production line, and can be made into a composite oil squeezing roller, and its oil squeezing effect is better than that of a traditional rubber roller. Because the non-woven fabric has porosity, compressibility and self-healing properties, it can hide debris on the surface of the strip steel in its pores, avoid scratches on the surface of the strip steel, and improve the surface quality of the strip steel. At the same time, the non-woven fabric has a higher friction coefficient than the traditional rubber roller, which can effectively remove the rolling oil on the surface of the strip and reduce the loss of rolling oil.

具体实施方式Detailed ways

一种复合材料挤油辊用无纺布的制备方法,按照如下的步骤进行A preparation method of non-woven fabric for composite material squeeze roller, according to the following steps

步骤一、将聚酰胺66纤维材料置于温度15℃-30℃相对湿度为30%-60%的环境中24小时或者以上;Step 1. Place the polyamide 66 fiber material in an environment with a temperature of 15°C-30°C and a relative humidity of 30%-60% for 24 hours or more;

步骤二、将由东莞市嘉宏有机硅科技有限公司生产的Goon881型抗静电整理剂与去离子水以体积比1:10混合配制成抗静电剂溶液,将抗静电剂溶液喷洒在聚酰胺66纤维材料表面,抗静电剂与聚酰胺66纤维材料质量比为1:20;Step 2. Mix the Goon881 antistatic finishing agent produced by Dongguan Jiahong Silicone Technology Co., Ltd. with deionized water at a volume ratio of 1:10 to prepare an antistatic agent solution, and spray the antistatic agent solution on the polyamide 66 fiber material On the surface, the mass ratio of antistatic agent to polyamide 66 fiber material is 1:20;

步骤三、称取25g经过步骤二处理的聚酰胺66纤维材料,并铺至小型梳棉机上梳理,梳理后的纤网为45次的纵向和横向(举例说:比如第一次梳理为横向,那么第二次梳理为纵向,第三又为横向,这样直至45次横向和纵向)并和将梳理好的纤维网取样成100mm*100mm试样;Step 3: Weigh 25g of the polyamide 66 fiber material processed in step 2, and lay it on a small carding machine for carding. The fiber web after carding is 45 vertical and horizontal (for example: for example, the first carding is horizontal, Then the second carding is the longitudinal direction, and the third is the transverse direction, so until 45 transverse and longitudinal) and the carded fiber web is sampled into a 100mm*100mm sample;

步骤四、将由青岛金森达化工有限公司生产的自交联丙烯酸酯乳液粘合剂与去离子水以体积比0.47:1混合配置成工作液,将工作液喷砂在纤维网上,每0.01平方米纤维网上喷洒5-10ml工作液,然后在100℃的干燥箱内烘干5分钟;Step 4. Mix the self-crosslinking acrylate emulsion adhesive produced by Qingdao Jinsenda Chemical Co., Ltd. and deionized water at a volume ratio of 0.47:1 to prepare a working fluid, and sandblast the working fluid on the fiber net, every 0.01 square meters Spray 5-10ml of working fluid on the fiber net, and then dry it in a drying oven at 100°C for 5 minutes;

步骤五、将烘干好的纤维网置于平板硫化机中,保持压力为0.5Mpa,温度为160℃,持续时间10min,即得到复合材料挤油辊用无纺布材料。Step 5, place the dried fiber web in a flat vulcanizer, keep the pressure at 0.5 MPa, the temperature at 160° C., and last for 10 minutes to obtain the non-woven fabric material for the composite squeeze roller.

制得的无纺布拉伸强力平均值为19.310kgf,硬度平均值为73.6A,吸油率平均值为45.2%。The average tensile strength of the prepared nonwoven fabric was 19.310kgf, the average hardness was 73.6A, and the average oil absorption rate was 45.2%.

Claims (2)

1.一种复合材料挤油辊用无纺布的制备方法,其特征在于:按照如下的步骤进行1. A preparation method for a non-woven fabric for a composite oil squeezing roller, characterized in that: carry out according to the following steps 步骤一、将聚酰胺66纤维材料置于温度15℃-30℃相对湿度为30%-60%的环境中24小时或者以上;Step 1. Place the polyamide 66 fiber material in an environment with a temperature of 15°C-30°C and a relative humidity of 30%-60% for 24 hours or more; 步骤二、将Goon881型抗静电整理剂与去离子水以体积比1:10混合配制成抗静电剂溶液,将抗静电剂溶液喷洒在聚酰胺66纤维材料表面,抗静电剂与聚酰胺66纤维材料质量比为1:20;Step 2: Mix Goon881 type antistatic finishing agent with deionized water to prepare an antistatic agent solution at a volume ratio of 1:10, spray the antistatic agent solution on the surface of polyamide 66 fiber material, antistatic agent and polyamide 66 fiber The material mass ratio is 1:20; 步骤三、将经过步骤二处理的聚酰胺66纤维材料在梳棉机上梳理,使的纵向和横向纹理均匀的纤维网;Step 3, carding the polyamide 66 fiber material processed through step 2 on a carding machine to make a fiber web with uniform longitudinal and transverse textures; 步骤四、将自交联丙烯酸酯乳液粘合剂与去离子水以体积比0.47:1混合配置成工作液,将工作液喷砂在纤维网上,每0.01平方米纤维网上喷洒5-10ml工作液,然后在100℃的干燥箱内烘干5分钟;Step 4. Mix the self-crosslinking acrylate emulsion adhesive and deionized water at a volume ratio of 0.47:1 to prepare a working solution, sandblast the working solution on the fiber net, and spray 5-10ml of the working solution per 0.01 square meters of fiber net , and then dried in a drying oven at 100°C for 5 minutes; 步骤五、将烘干好的纤维网置于平板硫化机中,保持压力为0.5-5Mpa,温度为25-160℃,持续时间5-25min,即得到复合材料挤油辊用无纺布材料。Step 5. Put the dried fiber web in a flat vulcanizer, keep the pressure at 0.5-5Mpa, the temperature at 25-160°C, and the duration for 5-25min, to obtain the non-woven fabric material for the composite squeeze roller. 2.根据权利要求1所述的一种复合材料挤油辊用无纺布的制备方法,其特征在于:步骤三中将每25g的聚酰胺66纤维梳理成40-50次的纵向和横向并和。2. the preparation method of a kind of composite material squeezer nonwoven fabric according to claim 1, is characterized in that: in step 3, the polyamide 66 fiber of every 25g is carded into 40-50 times of longitudinal and transverse parallelism and.
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CN112080854A (en) * 2020-08-14 2020-12-15 西安工程大学 Manufacturing method of high-acid-alkali-resistance non-woven material for drying roller
CN114351349A (en) * 2021-12-14 2022-04-15 江苏奥特隆新材料有限公司 Preparation method and equipment of degradable non-woven fabric

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CN202707785U (en) * 2012-08-16 2013-01-30 咸阳大田机械有限责任公司 Multi-purpose roller for non-woven fabrics
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CN112080854A (en) * 2020-08-14 2020-12-15 西安工程大学 Manufacturing method of high-acid-alkali-resistance non-woven material for drying roller
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Application publication date: 20180413