CN107864522B - Anion integrated electric hot plate - Google Patents
Anion integrated electric hot plate Download PDFInfo
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- CN107864522B CN107864522B CN201711306205.2A CN201711306205A CN107864522B CN 107864522 B CN107864522 B CN 107864522B CN 201711306205 A CN201711306205 A CN 201711306205A CN 107864522 B CN107864522 B CN 107864522B
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/20—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/02—Details
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
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Abstract
An anion integrated electric hot plate comprises a heating element (1), an insulating layer (2), a heat-insulating layer (3), a moisture-proof layer (4), a heat-radiating base material layer (5) and a UV gloss oil layer (6) containing tourmaline particles; wherein, the heating element (1) is wrapped in the insulating layer (2) and is uniformly arranged in the insulating layer; the heat-insulating layer (3) wraps the insulating layer (2), the moisture-proof layer (4) wraps the insulating layer, the heat-radiating base material layer (5) wraps the moisture-proof layer (4), and the outer surface of the heat-radiating base material layer (5) is coated with a UV gloss oil layer (6) containing tourmaline particles; in the UV gloss oil layer 6 with tourmaline particles, the particle size of the tourmaline particles is 4000-6000 meshes. The anion integrated electric heating plate can simultaneously provide indoor heating and purify indoor PM2.5.
Description
Technical Field
The invention belongs to the field of integrated electric heating plates, particularly relates to an anion integrated electric heating plate, and particularly relates to an anion integrated electric heating plate capable of reducing indoor PM2.5.
Background
The electric heating plate is a common product in the field of electric heating. Typical applications of the electric heating plate include an electric heating wall plate, an electric heating kang plate, an electric heating floor and the like. The electric heating plate is a novel heating form, heating wires are arranged in the electric heating plate to generate heat, and the electric heating plate is used for heating in an electrified heating form and replaces the traditional heating. Compare in traditional heating installation heating, with the advantage of electric hot plate heating: 1. the heating is convenient, the power is on at any time, the temperature can be set at will, and the required heating temperature can be reached in only 5 minutes. 2. Is healthy and environment-friendly, and has no public nuisance, no peculiar smell and no environmental pollution. 3. The specific infrared ray emitted by the electric heating plate can regulate the health of human body. 4. Semi-permanent, can be moved away and reused. 5. From a long-term perspective, economic resources are saved.
PM2.5 means particulate matter having a diameter of 2.5 μm or less, and is composed of fine particles directly discharged into the air and secondary fine particles generated by chemical conversion of gaseous pollutants in the air. The source and generation process of PM2.5 in urban atmosphere is quite complex, including: various combustion processes, such as coal combustion, petroleum combustion, direct emission of motor vehicle exhaust, and the like; "Secondary formation Process" of atmospheric chemical reactions, e.g. photochemical formation of NOx and VOCs in the atmosphere, SO 2 And fine particles of sulfate and nitrate generated in the atmosphere of NOx, etc.
As the outdoor air environment deteriorates, the indoor air environment also deteriorates. About 80% of the life of a person spends indoors, so the quality of indoor environment directly affects the health of the person. Especially, in autumn and winter, the indoor environment has the requirements of heating and heat preservation, and the amount of windows is less, so that the indoor air is more serious.
There are many methods for purifying indoor air, wherein the negative ion technology is also called unipolar ion flow technology, and the generated negative ion flow adsorbs the suspended particles with positive charges in the air, so that the particles are continuously accumulated and become heavy, and the particles are separated from the gas solution state and settled. The anion air purifier utilizes the characteristic of air diffusibility to make the whole room be full of anions, can remove dust and fall dust fast, does not leave the dead angle, and purification effect is comparatively thorough.
Tourmaline (tourmaline) is a multi-element natural mineral, the main chemical component is SiO2 TiO2 CaO K2O LiOAl2O 3B 2O3 MgO Na2O Fe2O3 FeO MnO P2O5, and the main components of tourmaline include more than 10 trace elements such as magnesium, aluminum, iron and boron which are beneficial to human bodies. Mohs hardness of tourmaline is 7-7.5, and specific gravity is 2.98-3.20; piezoelectric and pyroelectric. Tourmaline is a polar crystal with a special structure, can generate electric ions for a long time and permanently releases air negative ions and far infrared rays. Tourmaline powder is obtained by mechanically pulverizing raw tourmaline ore after removing impurities.
In the prior art, an effective means for simultaneously solving indoor heating and purifying indoor particles is not provided, and the existing method has the technical problems of poor purification effect, non-lasting purification effect, secondary pollution, high price and the like, so that the development of equipment which can simultaneously realize heating and particle purification is an important research content in the technical field.
Disclosure of Invention
The invention aims to provide an anion integrated electric heating plate aiming at the technical problems in the prior art, in particular to an anion integrated electric heating plate capable of reducing indoor PM2.5.
The anion integrated electric heating plate disclosed by the invention can simultaneously provide indoor heating and purify indoor particles, is convenient to use, has a good and lasting purification effect, has a higher economic value, and is worthy of wide popularization.
The invention discloses a negative ion integrated electric heating plate in a first aspect, and the technical scheme is as follows.
An anion integrated electric heating plate, in particular to an anion integrated electric heating plate which can reduce indoor PM 2.5; comprises a heating element 1, an insulating layer 2, a heat-insulating layer 3, a moisture-proof layer 4, a heat-radiating base material layer 5 and a UV gloss oil layer 6 containing tourmaline particles;
wherein, the heating element 1 is wrapped in the insulating layer 2 and is uniformly arranged in the insulating layer; the heat-insulating layer 3 is wrapped outside the insulating layer 2, the moisture-proof layer 4 is wrapped outside the insulating layer, the heat-radiating base material layer 5 is wrapped outside the moisture-proof layer 4, and the UV gloss oil layer 6 containing tourmaline particles is coated on the outer surface of the heat-radiating base material layer 5;
one end of the heating element 1 is connected with a first external lead 1-1 of the heating element, the other end of the heating element is connected with a second external lead 1-2 of the heating element, and the first external lead 1-1 of the heating element and the second external lead 1-2 of the heating element are respectively connected with two poles of a power supply.
Preferably, the heating element 1 is one or two of an electrothermal alloy wire or a carbon fiber heating wire; according to application requirements, parameters influencing heating efficiency, such as length, diameter, resistance, heating power and the like of the heating element can be adjusted.
Preferably, the insulating layer 2 comprises an upper insulating layer and a lower insulating layer, and the heating element 1 is positioned between the upper insulating layer and the lower insulating layer; the upper insulating layer and/or the lower insulating layer are/is provided with a groove for accommodating a heating element, and the heating element 1 is positioned in the groove.
Preferably, the heat-insulating layer 3 is a heat-insulating foam layer.
Preferably, the moisture-proof layer 4 is a polypropylene layer.
Preferably, the heat dissipation substrate layer 5 is a metal plate or an organic polymer layer.
Preferably, the metal plate is one or both of a steel plate and an alloy plate.
Preferably, the organic polymer layer is one or more of polyethylene board, polypropylene board, PVC board and bamboo-wood fiber board.
Preferably, in the UV gloss oil layer 6 with tourmaline particles, the particle size of the tourmaline particles is 4000-6000 meshes.
The invention discloses a preparation method of the anion integrated electric heating plate in the second aspect, and the technical scheme is as follows.
A preparation method of an anion integrated electric heating plate comprises the following steps:
step (1), assembling a heating element 1, an insulating layer 2, a heat-insulating layer 3, a moisture-proof layer 4 and a heat-radiating base material layer 5 to form an electric heating plate;
step (2), preparing functional UV gloss oil paint containing tourmaline superfine powder,
wherein the functional UV gloss oil coating comprises UV gloss oil; the particle size of the tourmaline superfine powder is 4000-6000 meshes; calculated by the total mass of the functional UV gloss oil coating, the mass fraction of the tourmaline superfine powder is 5-15%, and the preferred mass fraction is 8-12%;
(3) And (3) uniformly coating the functional UV gloss oil coating prepared in the step (2) on the heat dissipation substrate layer 5 of the electric heating plate in the step (1), and curing to form a UV gloss oil layer with tourmaline particles, wherein the thickness of the UV gloss oil layer is 30-500 mu m, so that the anion integrated electric heating plate is prepared.
Preferably, the method for preparing the functional UV varnish paint containing tourmaline micropowder of step (2) comprises the following steps: grinding the tourmaline raw material to 4000-6000 meshes to obtain tourmaline superfine powder, adding the tourmaline superfine powder into UV gloss oil, and then adding the mixture into a grinding machine to continuously grind to obtain the functional UV gloss oil coating.
Preferably, the ground tourmaline superfine powder is added into UV gloss oil after surface modification; so as to improve the interface compatibility between the surface of the tourmaline particles and the UV gloss oil; the surface modification method comprises the following steps:
calcining the ground ultrafine powder in a muffle furnace at the calcining temperature of 300-450 ℃ for 1-3h, cooling, soaking in 0.01-1% hydrochloric acid solution for 1-6 h, filtering, taking out, washing with deionized water to be neutral, calcining in the muffle furnace at the calcining temperature of 500-750 ℃ for 0.5-2h, and naturally cooling to room temperature for later use; the purified tourmaline powder has higher negative ion generation amount and far infrared emissivity;
adding gamma- (2, 3-glycidoxy) propyl trimethoxy silicon into n-heptane to prepare a modifier solution, wherein the mass ratio of the gamma- (2, 3-glycidoxy) propyl trimethoxy silicon to the n-heptane is 1-3: 5-10;
heating the superfine powder naturally cooled to room temperature to 50-65 ℃, keeping the temperature for 0.5-1h under the stirring condition, then atomizing the modifier solution into the superfine powder, keeping the temperature for 1-2h under the stirring condition, and naturally cooling after n-heptane is volatilized to obtain modified tourmaline superfine powder; wherein the mass ratio of the superfine powder to the modifier solution is 10: 1-5.
Preferably, the functional UV gloss oil coating also comprises 5-25% of diluent ethylene glycol, 1-5% of cross-linking agent ethylene glycol diglycidyl ether, 1-3% of initiator 2, 2-dimethoxyphenylacetophenone, 1-3% of film forming agent propylene glycol butyl ether and 1-2% of leveling agent carboxymethyl cellulose by weight of the total mass of the functional UV gloss oil coating; wherein, the balance is UV gloss oil.
Preferably, the method for preparing the functional UV varnish paint containing tourmaline micropowder of step (2) comprises the following steps: grinding a tourmaline raw material to 4000-6000 meshes, carrying out surface modification to obtain tourmaline superfine powder, adding the tourmaline superfine powder, a diluent, a cross-linking agent, an initiator, a film-forming agent, namely propylene glycol butyl ether and a flatting agent into UV gloss oil according to a ratio, and then adding the mixture into a grinding machine to continuously grind to obtain the functional UV gloss oil coating.
Preferably, the coating mode in the step (3) is electrostatic coating, air spraying, airless spraying or roller and brush coating.
The third aspect of the invention discloses application of the anion integrated electric heating plate, which is used for floor heating, kang heating and wall heating or used for manufacturing heating pictures.
The technical scheme of the invention has prominent substantive characteristics and obtains remarkable technical effect.
The invention creatively coats the UV varnish coating containing the tourmaline particles in the electric hot plate, and the coating has the advantages of fast curing, good curing effect and stable film forming under the illumination. Particularly, in the invention, the 4000-6000-mesh tourmaline particles are added into the UV gloss oil and then coated on the surface of the electric hot plate to form a UV gloss oil layer, so that the integrated electric hot plate is obtained, when the electric hot plate is electrified and heated (for example, 35-45 ℃), the tourmaline particles in the UV gloss oil layer are heated and then released to release high-concentration negative ions, the negative ions adsorb suspended particulate matters with positive charges in the air, the particulate matters are continuously accumulated and heavy, the particulate matters are separated from an aerosol state and are settled and fall out of the air, the concentration of haze particles in the air is reduced while the electric hot plate is heated, dust can be rapidly removed and fallen, dead corners are not left, the purification effect is thorough, the indoor air environment is improved, the comfort level is improved, the generation of respiratory system diseases is avoided, and the health of a human body is ensured.
The invention creatively uses the gamma- (2, 3-epoxypropoxy) propyl trimethoxy silicon as a surface modifier to modify the surface of the tourmaline particles, improves the interface property of the tourmaline particles and the UV gloss oil, has a unique space structure and active groups and bonding points on the surface, can improve the network structure in the UV gloss oil of trees, ensures that the tourmaline particles are dispersed more uniformly in the UV gloss oil, avoids the agglomeration effect of the tourmaline particles, and particularly improves the capability of releasing negative ions by the interaction of the tourmaline particles and silicon particles generated by the partial decomposition of the gamma- (2, 3-epoxypropoxy) propyl trimethoxy silicon, thereby playing a role in synergy.
In the preferred scheme of the invention, 5-25% of diluent ethylene glycol, 1-5% of cross-linking agent ethylene glycol diglycidyl ether, 1-3% of initiator 2, 2-dimethoxyphenylacetophenone, 1-3% of film-forming agent propylene glycol butyl ether and 1-2% of leveling agent carboxymethyl cellulose are added during the preparation of the functional UV gloss oil coating, so that the coatability, the curing performance and the film-forming stability of the functional UV gloss oil coating are improved, and a remarkable coating and film-forming effect is achieved.
In conclusion, the anion integrated electric heating plate disclosed by the invention can simultaneously provide indoor heating and purify indoor PM2.5, and when tourmaline particles in the UV gloss oil layer are heated, anions with higher concentration are released and released, so that PM2.5 is continuously accumulated and becomes heavier, and is separated from an air solution state and settled. The anion integrated electric heating plate is convenient to use, has a good and lasting purification effect, and has a higher economic value.
Drawings
Fig. 1 is a schematic structural view of an integrated electric heating plate according to the present invention.
In fig. 1, corresponding reference numerals indicate:
the heating element (1) is provided with a heating element,
an insulating layer (2) is provided on the substrate,
the heat-insulating layer (3) is provided with a heat-insulating layer,
the moisture-proof layer 4 is provided with a moisture-proof layer,
a heat-dissipating substrate layer 5 which is,
a UV gloss oil layer 6 of tourmaline particles,
first external lead 1-1
Second outer leads 1-2.
Detailed Description
The technical scheme of the invention is further detailed in the following by combining the drawings and the specific embodiment.
Example 1
With reference to fig. 1, an anion integrated electric hot plate comprises a heating element 1, an insulating layer 2, a heat insulating layer 3, a moisture-proof layer 4, a heat dissipation substrate layer 5 and a UV varnish layer 6 containing tourmaline particles; wherein, the heating element 1 is wrapped in the insulating layer 2 and is uniformly arranged in the insulating layer; the heat-insulating layer 3 is wrapped outside the insulating layer 2, the moisture-proof layer 4 is wrapped outside the insulating layer, the heat-radiating base material layer 5 is wrapped outside the moisture-proof layer 4, and the UV gloss oil layer 6 containing tourmaline particles is coated on the outer surface of the heat-radiating base material layer 5; one end of the heating element 1 is connected with a first external lead 1-1 of the heating element, the other end of the heating element is connected with a second external lead 1-2 of the heating element, and the first external lead 1-1 of the heating element and the second external lead 1-2 of the heating element are respectively connected with two poles of a power supply.
Example 2
With reference to fig. 1, the present embodiment provides an integrated anion electric heating plate capable of reducing PM2.5 in a room; comprises a heating element 1, an insulating layer 2, a heat-insulating layer 3, a moisture-proof layer 4, a heat-radiating substrate layer 5 and a UV gloss oil layer 6 containing tourmaline particles; wherein, the heating element 1 is wrapped in the insulating layer 2 and is uniformly arranged in the insulating layer; the heat-insulating layer 3 is wrapped outside the insulating layer 2, the moisture-proof layer 4 is wrapped outside the insulating layer, the heat-radiating base material layer 5 is wrapped outside the moisture-proof layer 4, and the UV gloss oil layer 6 containing tourmaline particles is coated on the outer surface of the heat-radiating base material layer 5; one end of the heating element 1 is connected with a first external lead 1-1 of the heating element, the other end of the heating element is connected with a second external lead 1-2 of the heating element, and the first external lead 1-1 of the heating element and the second external lead 1-2 of the heating element are respectively connected with two poles of a power supply.
In this embodiment, the heating element 1 may be one or two of an electrothermal alloy wire or a carbon fiber heating wire; according to application requirements, parameters influencing heating efficiency, such as length, diameter, resistance, heating power and the like of the heating element can be adjusted.
In this embodiment, in order to uniformly wrap the heating element, the insulating layer 2 is provided to include an upper insulating layer and a lower insulating layer, and the heating element 1 is located between the upper insulating layer and the lower insulating layer; the upper insulating layer and/or the lower insulating layer are/is provided with a groove for accommodating a heating element, and the heating element 1 is positioned in the groove.
In this embodiment, the insulating layer 3 is a heat insulating foam layer. The moisture-proof layer 4 is a polypropylene layer. The heat dissipation substrate layer 5 is a metal plate or an organic polymer layer. The metal plate is one or two of a steel plate or an alloy plate. The organic polymer layer is one or more of polyethylene board, polypropylene board, PVC board and bamboo-wood fiber board.
In the embodiment, the particle size of the tourmaline particles in the UV gloss oil layer 6 with tourmaline particles is 4000-6000 meshes, so that the tourmaline particles have more efficient negative ion volatilization capacity, and further have better PM2.5 removal performance.
Example 3
A preparation method of an anion integrated electric heating plate comprises the following steps:
step (1), assembling a heating element 1, an insulating layer 2, a heat-insulating layer 3, a moisture-proof layer 4 and a heat-radiating base material layer 5 to form an electric heating plate;
step (2), preparing functional UV gloss oil paint containing tourmaline superfine powder,
wherein the functional UV gloss oil coating comprises UV gloss oil; the particle size of the tourmaline superfine powder is 4000 meshes; calculated by the total mass of the functional UV gloss oil coating, the tourmaline superfine powder accounts for 8 percent by mass;
(3) And (3) uniformly coating the functional UV gloss oil coating prepared in the step (2) on the heat dissipation substrate layer 5 of the electric heating plate in the step (1), and curing to form a UV gloss oil layer with tourmaline particles, wherein the thickness of the UV gloss oil layer is 50 microns, so that the anion integrated electric heating plate is prepared.
Example 4
A preparation method of an anion integrated electric heating plate comprises the following steps:
step (1), assembling a heating element 1, an insulating layer 2, a heat-insulating layer 3, a moisture-proof layer 4 and a heat-radiating base material layer 5 to form an electric heating plate;
step (2), preparing functional UV gloss oil paint containing tourmaline micropowder,
wherein the functional UV gloss oil coating comprises UV gloss oil; the particle size of the tourmaline superfine powder is 6000 meshes; calculated by the total mass of the functional UV gloss oil coating, the tourmaline superfine powder accounts for 12 percent by mass;
(3) And (3) uniformly coating the functional UV gloss oil coating prepared in the step (2) on the heat dissipation substrate layer 5 of the electric heating plate in the step (1), and curing to form a UV gloss oil layer with tourmaline particles, wherein the thickness of the UV gloss oil layer is 500 mu m, so that the anion integrated electric heating plate is prepared. In the embodiment, the method for preparing the functional UV varnish paint containing tourmaline micropowder in step (2) specifically comprises the following steps: grinding a tourmaline raw material to 6000 meshes to obtain tourmaline superfine powder, adding the tourmaline superfine powder into UV gloss oil, and then adding the UV gloss oil and the tourmaline superfine powder into a grinding machine for continuous grinding to obtain the functional UV gloss oil coating.
In order to improve the interface compatibility between the surface of the tourmaline particle and the UV varnish, the embodiment modifies the surface of the ground tourmaline micropowder and then adds the tourmaline micropowder into the UV varnish; the surface modification method comprises the following steps:
calcining the ground ultrafine powder in a muffle furnace at the calcining temperature of 350 ℃ for 1h, cooling, soaking in a hydrochloric acid solution with the mass fraction of 0.01% for 2h, filtering, taking out, washing with deionized water to be neutral, calcining in the muffle furnace at the calcining temperature of 600 ℃ for 0.6h, and naturally cooling to room temperature for later use;
adding gamma- (2, 3-glycidoxy) propyl trimethoxy silicon into n-heptane to prepare a modifier solution, wherein the mass ratio of the gamma- (2, 3-glycidoxy) propyl trimethoxy silicon to the n-heptane is 1: 5;
heating the superfine powder naturally cooled to room temperature to 50 ℃, preserving heat for 0.5h under the stirring condition, then atomizing the modifier solution into the superfine powder, continuously preserving heat for 1h under the stirring condition, and naturally cooling after n-heptane is volatilized to obtain modified tourmaline superfine powder; wherein the mass ratio of the superfine powder to the modifier solution is 10: 1.
In addition, the functional UV varnish in this embodiment further includes, based on the total mass of the functional UV varnish, 5 to 25% of a diluent ethylene glycol, 1 to 5% of a cross-linking agent ethylene glycol diglycidyl ether, 1 to 3% of an initiator 2, 2-dimethoxyphenylacetophenone, 1 to 3% of a film-forming agent propylene glycol butyl ether, and 1 to 2% of a leveling agent carboxymethyl cellulose.
Example 5
A preparation method of an anion integrated electric heating plate comprises the following steps:
step (1), assembling a heating element 1, an insulating layer 2, a heat-insulating layer 3, a moisture-proof layer 4 and a heat-radiating base material layer 5 to form an electric heating plate;
step (2), preparing functional UV gloss oil paint containing tourmaline superfine powder,
grinding a tourmaline raw material to 5000 meshes, carrying out surface modification to obtain tourmaline superfine powder, adding the tourmaline superfine powder, a diluent, a cross-linking agent, an initiator, a film-forming agent, propylene glycol monobutyl ether and a leveling agent into UV gloss oil according to a proportion, and then adding the mixture into a grinding machine for continuous grinding to obtain the functional UV gloss oil coating;
wherein the functional UV gloss oil coating comprises UV gloss oil; calculated by the total mass of the functional UV gloss oil coating, the mass fraction of 5-15% tourmaline superfine powder is 5-25% diluent ethylene glycol, 1-5% cross-linking agent ethylene glycol diglycidyl ether, 1-3% initiator 2, 2-dimethoxy phenyl acetophenone, 1-3% film forming agent propylene glycol butyl ether and 1-2% leveling agent carboxymethyl cellulose;
the surface modification method comprises the following steps:
calcining the ground ultrafine powder in a muffle furnace at the calcining temperature of 450 ℃ for 3h, cooling, soaking in a hydrochloric acid solution with the mass fraction of 1% for 6h, filtering, taking out, washing with deionized water to be neutral, calcining in the muffle furnace at the calcining temperature of 750 ℃ for 2h, and naturally cooling to room temperature for later use; the purified tourmaline powder has higher negative ion generation amount and far infrared emissivity;
adding gamma- (2, 3-epoxypropoxy) propyl trimethoxy silicon into n-heptane to prepare a modifier solution, wherein the mass ratio of the gamma- (2, 3-epoxypropoxy) propyl trimethoxy silicon to the n-heptane is 3: 10;
heating the superfine powder naturally cooled to room temperature to 65 ℃, preserving heat for 1h under the stirring condition, then atomizing the modifier solution and spraying into the superfine powder, continuing preserving heat for 2h under the stirring condition, and naturally cooling after n-heptane volatilizes to obtain modified tourmaline superfine powder; wherein the mass ratio of the superfine powder to the modifier solution is 10: 5.
(3) And (3) uniformly coating the functional UV gloss oil coating prepared in the step (2) on the heat dissipation substrate layer 5 of the electric heating plate in the step (1), and curing to form a UV gloss oil layer with tourmaline particles, wherein the thickness of the UV gloss oil layer is 460 microns, so that the anion integrated electric heating plate is prepared.
In this embodiment, the coating method in step (3) is electrostatic coating, air spraying, airless spraying, or roller and brush coating.
Example 6
A preparation method of an anion integrated electric heating plate comprises the following steps:
step (1), assembling a heating element 1, an insulating layer 2, a heat-insulating layer 3, a moisture-proof layer 4 and a heat-radiating base material layer 5 to form an electric heating plate;
step (2), preparing functional UV gloss oil paint containing tourmaline superfine powder,
grinding a tourmaline raw material to 6000 meshes, carrying out surface modification to obtain tourmaline superfine powder, adding the tourmaline superfine powder, a diluent, a cross-linking agent, an initiator, a film-forming agent propylene glycol monobutyl ether and a flatting agent into UV gloss oil according to a proportion, and then adding the mixture into a grinding machine for continuous grinding to obtain the functional UV gloss oil coating;
wherein the functional UV gloss oil coating comprises UV gloss oil; calculated by the total mass of the functional UV gloss oil coating, the mass fraction of 10 percent of tourmaline superfine powder is 10 percent of diluent ethylene glycol, 2 percent of cross-linking agent ethylene glycol diglycidyl ether, 2 percent of initiator 2, 2-dimethoxy phenyl acetophenone, 3 percent of film forming agent propylene glycol butyl ether and 1 percent of leveling agent carboxymethyl cellulose;
wherein, the surface modification method comprises the following steps:
calcining the ground ultrafine powder in a muffle furnace at the calcining temperature of 300 ℃ for 3h, cooling, soaking in a hydrochloric acid solution with the mass fraction of 0.05% for 6h, filtering, taking out, washing with deionized water to be neutral, calcining in the muffle furnace at the calcining temperature of 750 ℃ for 2h, and naturally cooling to room temperature for later use; the purified tourmaline powder has higher negative ion generation amount and far infrared emissivity;
adding gamma- (2, 3-epoxypropoxy) propyl trimethoxy silicon into n-heptane to prepare a modifier solution, wherein the mass ratio of the gamma- (2, 3-epoxypropoxy) propyl trimethoxy silicon to the n-heptane is 2: 7;
heating the micropowder naturally cooled to room temperature to 55 ℃, keeping the temperature for 0.8h under the stirring condition, then atomizing the modifier solution into the micropowder, keeping the temperature for 1-2h under the stirring condition, and naturally cooling after n-heptane is volatilized to obtain modified tourmaline micropowder; wherein the mass ratio of the superfine powder to the modifier solution is 10: 1.
(3) And (3) uniformly coating the functional UV gloss oil coating prepared in the step (2) on the heat dissipation substrate layer 5 of the electric heating plate in the step (1), and curing to form a UV gloss oil layer with tourmaline particles, wherein the thickness of the UV gloss oil layer is 100 microns, so that the anion integrated electric heating plate is prepared.
An anion integrated electric heating plate of examples 1-2 and an anion integrated electric heating plate prepared in examples 3-6 can be used in floor heating, kang heating, wall heating forms, or for making heating pictures. When tourmaline particles in the UV gloss oil layer are heated, high-concentration negative ions are released, PM2.5 is continuously accumulated and becomes heavy, and the PM separates from an aerosol state and is settled.
Claims (9)
1. An anion integrated electric heating plate is characterized by comprising a heating element (1), an insulating layer (2), a heat-insulating layer (3), a moisture-proof layer (4), a heat-radiating base material layer (5) and a UV gloss oil layer (6) containing tourmaline particles;
the heating elements (1) are wrapped in the insulating layer (2) and are uniformly arranged in the insulating layer; insulating layer (2) outside parcel have heat preservation (3), heat preservation outside parcel have dampproof course (4), dampproof course (4) outside parcel have heat dissipation substrate layer (5), heat dissipation substrate layer (5) surface coating have UV gloss oil layer (6) that contain the tourmaline granule.
2. The anion integrated electric heating plate according to claim 1, wherein one end of the heating element (1) is connected with a first external lead (1-1) of the heating element, the other end is connected with a second external lead (1-2) of the heating element, and the first external lead and the second external lead of the heating element are respectively connected with two poles of a power supply.
3. The anion integrated electric heating plate according to claim 1 or 2, wherein the insulating layer comprises an upper insulating layer and a lower insulating layer, and the heating element is located between the upper insulating layer and the lower insulating layer; the upper insulating layer and/or the lower insulating layer are/is provided with a groove for accommodating a heating element, and the heating element is positioned in the groove.
4. The negative ion integrated electric heating plate according to claim 1, wherein the heat-dissipating substrate layer is a metal plate or an organic polymer layer; the metal plate is one or two of a steel plate or an alloy plate; the organic polymer layer is one or more of polyethylene board, polypropylene board, PVC board and bamboo-wood fiber board.
5. The anion integrated electric hot plate of claim 1, wherein the tourmaline particles have a particle size of 4000-6000 mesh in the UV varnish layer containing the tourmaline particles; the thickness of the UV gloss oil layer containing tourmaline particles is 30-500 μm.
6. A method for preparing an anion integrated electric heating plate according to any one of claims 1 to 5, comprising the steps of:
step (1), assembling a heating element, an insulating layer, a heat-insulating layer, a moisture-proof layer and a heat-radiating base material layer to form an electric heating plate;
step (2), preparing functional UV gloss oil paint containing tourmaline micropowder,
wherein the functional UV gloss oil coating comprises UV gloss oil; the particle size of the tourmaline superfine powder is 4000-6000 meshes; calculated by the total mass of the functional UV gloss oil coating, the tourmaline superfine powder accounts for 5-15% by mass;
(3) Uniformly coating the functional UV gloss oil coating prepared in the step (2) on the heat dissipation substrate layer of the electric heating plate in the step (1), and curing to form a UV gloss oil layer with tourmaline particles, so as to prepare the negative ion integrated electric heating plate;
the method for preparing the functional UV gloss oil coating containing the tourmaline micropowder in the step (2) comprises the following steps: grinding a tourmaline raw material to 4000-6000 meshes, carrying out surface modification to obtain tourmaline superfine powder, adding the tourmaline superfine powder, a diluent, a cross-linking agent, an initiator, a film-forming agent propylene glycol monobutyl ether and a flatting agent into UV gloss oil according to a proportion, then adding the UV gloss oil and the flatting agent into a grinding machine, and continuously grinding to obtain the functional UV gloss oil coating.
7. The preparation method of claim 6, wherein the method for preparing the functional UV varnish containing tourmaline micropowder of step (2) comprises: grinding the tourmaline raw material to 4000-6000 meshes to obtain tourmaline superfine powder, adding the tourmaline superfine powder into UV gloss oil, and then adding the mixture into a grinding machine to continuously grind to obtain the functional UV gloss oil coating.
8. The preparation method according to claim 6 or 7, wherein the ground tourmaline micropowder is surface-modified and then added to UV varnish.
9. Use of an anion integrated electric hot plate according to any of claims 1 to 5 in the form of floor heating, kang heating, wall heating or for making heating pictures.
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CN109688646B (en) * | 2019-02-26 | 2021-12-24 | 广西鼎康科技股份有限公司 | Production process of electric heating plate with negative ion releasing effect |
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CN2619180Y (en) * | 2003-04-17 | 2004-06-02 | 李林林 | Multifunction carbno fiber heating plate |
CN102296774A (en) * | 2011-06-15 | 2011-12-28 | 广州广洋富格丽环保地板有限公司 | Art decorative wall plate and production method thereof |
CN204377166U (en) * | 2014-12-04 | 2015-06-03 | 河北凝辉能源科技有限公司 | A kind of energy-conservation Far infrared carbon fiber heating board |
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CN2619180Y (en) * | 2003-04-17 | 2004-06-02 | 李林林 | Multifunction carbno fiber heating plate |
CN102296774A (en) * | 2011-06-15 | 2011-12-28 | 广州广洋富格丽环保地板有限公司 | Art decorative wall plate and production method thereof |
CN204377166U (en) * | 2014-12-04 | 2015-06-03 | 河北凝辉能源科技有限公司 | A kind of energy-conservation Far infrared carbon fiber heating board |
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