CN107805886A - A kind of graphene basalt fiber composite material and preparation method thereof - Google Patents
A kind of graphene basalt fiber composite material and preparation method thereof Download PDFInfo
- Publication number
- CN107805886A CN107805886A CN201711150791.6A CN201711150791A CN107805886A CN 107805886 A CN107805886 A CN 107805886A CN 201711150791 A CN201711150791 A CN 201711150791A CN 107805886 A CN107805886 A CN 107805886A
- Authority
- CN
- China
- Prior art keywords
- basalt fibre
- graphene
- basalt
- aqueous solution
- graphene oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- 229920002748 Basalt fiber Polymers 0.000 title claims abstract description 112
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 88
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 86
- 239000002131 composite material Substances 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 239000000835 fiber Substances 0.000 claims abstract description 30
- 238000004132 cross linking Methods 0.000 claims abstract description 27
- 238000000576 coating method Methods 0.000 claims abstract description 18
- 239000011248 coating agent Substances 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 15
- 230000008961 swelling Effects 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 5
- 230000009467 reduction Effects 0.000 claims abstract description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 58
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 35
- 238000001035 drying Methods 0.000 claims description 33
- 239000007864 aqueous solution Substances 0.000 claims description 26
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 19
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 17
- 239000004745 nonwoven fabric Substances 0.000 claims description 17
- 239000006185 dispersion Substances 0.000 claims description 14
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 12
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 12
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 10
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- 239000001257 hydrogen Substances 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 239000004575 stone Substances 0.000 claims description 7
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 6
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 6
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 6
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 6
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 6
- 229940071870 hydroiodic acid Drugs 0.000 claims description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 6
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 6
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 6
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 6
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims description 6
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 claims description 5
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 5
- 150000001336 alkenes Chemical class 0.000 claims description 5
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 claims description 4
- MHABMANUFPZXEB-UHFFFAOYSA-N O-demethyl-aloesaponarin I Natural products O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=C(O)C(C(O)=O)=C2C MHABMANUFPZXEB-UHFFFAOYSA-N 0.000 claims description 4
- 229940113088 dimethylacetamide Drugs 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 3
- KBIWNQVZKHSHTI-UHFFFAOYSA-N 4-n,4-n-dimethylbenzene-1,4-diamine;oxalic acid Chemical compound OC(=O)C(O)=O.CN(C)C1=CC=C(N)C=C1 KBIWNQVZKHSHTI-UHFFFAOYSA-N 0.000 claims description 3
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 claims description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Natural products OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 3
- 229930003268 Vitamin C Natural products 0.000 claims description 3
- 235000011054 acetic acid Nutrition 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 3
- 235000019270 ammonium chloride Nutrition 0.000 claims description 3
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 3
- 239000003638 chemical reducing agent Substances 0.000 claims description 3
- 239000002270 dispersing agent Substances 0.000 claims description 3
- 235000019253 formic acid Nutrition 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims description 3
- 150000007524 organic acids Chemical class 0.000 claims description 3
- 235000005985 organic acids Nutrition 0.000 claims description 3
- 239000001103 potassium chloride Substances 0.000 claims description 3
- 235000011164 potassium chloride Nutrition 0.000 claims description 3
- 235000019260 propionic acid Nutrition 0.000 claims description 3
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 3
- 239000011435 rock Substances 0.000 claims description 3
- 239000012279 sodium borohydride Substances 0.000 claims description 3
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 3
- 239000011780 sodium chloride Substances 0.000 claims description 3
- 239000004317 sodium nitrate Substances 0.000 claims description 3
- 235000010344 sodium nitrate Nutrition 0.000 claims description 3
- 239000001488 sodium phosphate Substances 0.000 claims description 3
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 3
- 229940005605 valeric acid Drugs 0.000 claims description 3
- 235000019154 vitamin C Nutrition 0.000 claims description 3
- 239000011718 vitamin C Substances 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 2
- 238000005411 Van der Waals force Methods 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000001110 calcium chloride Substances 0.000 claims description 2
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims 1
- 229910001948 sodium oxide Inorganic materials 0.000 claims 1
- 230000004927 fusion Effects 0.000 abstract description 4
- 229910002804 graphite Inorganic materials 0.000 abstract description 3
- 239000010439 graphite Substances 0.000 abstract description 3
- 239000003431 cross linking reagent Substances 0.000 abstract description 2
- 230000002708 enhancing effect Effects 0.000 abstract description 2
- 230000003993 interaction Effects 0.000 abstract description 2
- 230000004069 differentiation Effects 0.000 abstract 1
- 238000004513 sizing Methods 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 16
- 239000003513 alkali Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 5
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 4
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 241000446313 Lamella Species 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- -1 zero twisted yarn Substances 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000004901 spalling Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B37/00—Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
- C03B37/005—Manufacture of flakes
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/1095—Coating to obtain coated fabrics
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/42—Coatings containing inorganic materials
- C03C25/44—Carbon, e.g. graphite
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Geochemistry & Mineralogy (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of graphene basalt fiber composite material and preparation method thereof, and the crosslinking to basalt fibre can be realized using the swelling and fusion of the graphite oxide ene coatings on basalt fibre surface.Graphene oxide, can be to the uniform coating of basalt fibre as sizing agent and crosslinking agent, and cross-linking process is quick and easy, and cross-link intensity is high.After further reduction, graphene oxide cross-linked layer is changed into graphene cross-linked layer, enhance the interaction between basalt fibre, reduce interfibrous contact resistance, so that basalt fibre shows excellent mechanical property and electrical and thermal conductivity, enhancing phase and differentiation fiber applications available for composite.It is this to be crosslinked the method for basalt fibre with very big researching value using graphene and be widely applied prospect.
Description
Technical field
The invention belongs to composite fibre field, more particularly to a kind of graphene-basalt fiber composite material and its preparation
Method.
Background technology
Basalt fibre is a kind of novel inorganic environment-friendly and green high performance fibre material, it be by silica, aluminum oxide,
The basalt building stones of the oxides such as calcium oxide, magnesia, iron oxide and titanium dioxide composition are fast by bushing after high-temperature fusion
Speed draws what is formed.Compared with glass fibre, basalt fibre not only has that mechanical strength is high, thermal conductivity factor is low and heatproof,
A series of excellent performances such as acid and alkali-resistance, heat-insulated, sound insulation, electric insulation, safe and non-toxic and own wt be light, but also with special
Use temperature range (- 260~700 DEG C).In addition, the production technology of basalt fibre determines that caused discarded object is few, it is right
Environmental pollution is small, and directly can be degraded in the environment after product abandonment, without any harm, thus is a kind of qualified green
Color, environment-friendly materials.China is classified as basalt fibre the big fiber of four given priority to, and (carbon fiber, aramid fiber, super high molecular weight are gathered
One of ethene, basalt fibre), realize industrialized production.Basalt continuous fiber is in fibre reinforced composites, friction
The many aspects such as material, shipbuilding materials, heat-barrier material, automobile industry, high temperature filtration fabric and protection field have obtained extensively
Application.However, the surface property of basalt fibre is poor, easy embrittlement, it is difficult to boundling and surface modification, and due to major part into
It is divided into silica, alkali resistance is bad, and application is poor when facing particular surroundings.
Graphene is a kind of two-dimentional carbon material with monoatomic layer thickness, has low-density, high mechanical strength, heat
Conductance and electrical conductivity and excellent corrosion resistance, and have preferable compatibility between basalt fibre, therefore utilize pure stone
Black alkene is crosslinked basalt fibre, and the boundling and non-woven fabrics of basalt fibre can be realized by non-melt means, can not only
The mechanical strength of maintenance basalt fibre, heat-resisting quantity, corrosion resistance well, and the electrical and thermal conductivity of material can be improved,
Overall proportion is reduced, can be used as the obturator of high-performance composite materials.
The profound of pure graphene crosslinking is prepared using graphene oxide swelling in a solvent and fusion in the present invention
Military rock fiber, the method compared to melting crosslinking can more preferably keep the intensity of basalt fibre in itself, compared to using other changes
Method crosslinking is more simple and easy, green.Due to graphene high conductivity in itself, high-termal conductivity, corrosion resistance etc.
Performance, after being coated to basalt fibre surface, basalt fibre electrical and thermal conductivity in itself and alkali resistance can be lifted, and
Due to the presence of graphene crosslinking, basalt fibre surface can form conductive and heat-conductive network, in the reinforcement for composite
Make more efficiently realize enhancing.
The content of the invention
Due to being difficult to boundling, alkali resistance is poor, and electrical and thermal conductivity is poor, and the application of existing basalt fibre receives limit
System.The purpose of the present invention is to be directed to existing technical deficiency, there is provided a kind of graphene-basalt fiber composite material and its preparation
Method.
The purpose of the present invention is achieved through the following technical solutions：A kind of graphene-basalt fiber composite material, stone
Black alkene is coated on basalt fibre surface, and basalt fibre surface is connected with graphene film by Van der Waals force and hydrogen bond.The Black Warrior
Crosslinking is realized by being coated on the graphene on surface between rock fiber, forms zero twisted yarn, non-woven fabrics or chopped mat.
A kind of preparation method of graphene-basalt fiber composite material, comprises the following steps：
(1) basalt fibre is placed in toluene and is heated to 250 DEG C, be cleaned by ultrasonic 10~30min, remove surface size
And finish, drying.
(2) surface coating is carried out to basalt fibre using graphene oxide dispersion, obtaining surface after drying is coated with
The basalt fibre of graphene oxide.
(3) basalt fibre for coating graphene oxide is placed in progress surface swelling in solvent, then merged fiber
The zero twisted yarn is formed after drying, or fiber is mutually overlapped and forms the non-woven fabrics or chopped mat after drying, dries temperature
Degree is less than 100 degrees Celsius.
(4) graphene-basalt fiber composite material is obtained after reducing.
Further, the concentration of graphene oxide dispersion is 7mg/g in the step (2), and dispersant is water, N, N- bis-
It is NMF, DMAC N,N' dimethyl acetamide, ethanol, ethylene glycol, 1-METHYLPYRROLIDONE, tetrahydrofuran, dimethyl sulfoxide, two sweet
Alcohol, pyridine, dioxane, butanone, isopropanol etc..
Further, basalt fibre is repeatedly coated using graphene oxide dispersion in the step (2), often
Dried after secondary coating, final dried graphene oxide thickness degree is 3 μm.
Further, solvent is water, methanol, ethanol, isopropanol, ethylene glycol, glycerine, diethylene glycol (DEG) in the step (3)
Deng the organic acids such as alcohols, formic acid, acetic acid, propionic acid, butyric acid, valeric acid, ethanedioic acid, malonic acid, succinic acid, acrylic acid, acetone, fourth
Ketone, N,N-dimethylformamide, DMAC N,N' dimethyl acetamide, tetrahydrofuran, dimethyl sulfoxide, 1-METHYLPYRROLIDONE, pyridine, two
The ring of oxygen six, the aqueous solution of sodium chloride, the aqueous solution of calcium chloride, the aqueous solution of sodium nitrate, the aqueous solution of calcium nitrate, the water of sodium phosphate
Solution, the aqueous solution of potassium chloride, the aqueous solution of ammonium chloride, the aqueous solution of potassium hydroxide, sodium hydroxide the aqueous solution or these are molten
The mixed liquor of liquid.
Further, restoring method is to use hydroiodic acid, hydrazine hydrate, Vitamin C, sodium borohydride etc. in the step (4)
Chemical reducing agent is reduced or 100~600 DEG C of thermal reductions.
The beneficial effects of the present invention are：
(1) pure graphene is uniform as basalt fibre surface distributed, and interface adhesive strength is high, and immersion does not take off in a solvent
Fall.
(2) pure graphene is high as the cross-linking agents intensity of basalt fibre.Using graphene oxide in a solvent
Swelling fusion realizes the crosslinking of basalt fibre, and method is simple, time saving, and the solvent environmental protection of use, cross-linking effect is good, compares
Other cross-linking methods have very big application value.
The excellent mechanical property of basalt fibre can be kept using this cross-linking method, and improves its electric conductivity, it is corrosion-resistant
Property, thermal conductivity, so as to further expand the application of basalt fiber material.
Brief description of the drawings
Fig. 1 is the schematic diagram of the basalt fibre non-woven fabrics through graphene of the present invention crosslinking.
Fig. 2 is the non-twist fine schematic diagram of basalt fibre being crosslinked through graphene of the present invention.
Embodiment
The method for preparing graphene-basalt fiber composite material comprises the following steps：
(1) basalt fibre is placed in toluene and is heated to 250 DEG C, be cleaned by ultrasonic 10~30min, remove surface size
And finish, drying.(2) surface coating is carried out to basalt fibre using graphene oxide dispersion, surface painting is obtained after drying
It is covered with the basalt fibre of graphene oxide.The concentration of the graphene oxide dispersion is 7mg/g, and dispersant is water, N, N-
Dimethylformamide, DMAC N,N' dimethyl acetamide, ethanol, ethylene glycol, 1-METHYLPYRROLIDONE, tetrahydrofuran, dimethyl sulfoxide, two
Glycol, pyridine, dioxane, butanone, isopropanol etc..Basalt fibre is repeatedly applied using graphene oxide dispersion
Cover, dried every time after coating, drying temperature is about 25~200 DEG C, and final dried graphene oxide thickness degree is 3 μm.(3)
The basalt fibre for coating graphene oxide is placed in progress surface swelling in solvent, then fiber is merged and formed after drying
The zero twisted yarn, or fiber is mutually overlapped and forms the non-woven fabrics or chopped mat after drying, drying temperature is Celsius less than 100
Degree.The solvent is alcohols, formic acid, acetic acid, propionic acid, the fourths such as water, methanol, ethanol, isopropanol, ethylene glycol, glycerine, diethylene glycol (DEG)
The organic acids such as acid, valeric acid, ethanedioic acid, malonic acid, succinic acid, acrylic acid, acetone, butanone, N,N-dimethylformamide, N, N- bis-
Methylacetamide, tetrahydrofuran, dimethyl sulfoxide, 1-METHYLPYRROLIDONE, pyridine, dioxane, the aqueous solution of sodium chloride, chlorination
The aqueous solution of calcium, the aqueous solution of sodium nitrate, the aqueous solution of calcium nitrate, the aqueous solution of sodium phosphate, the aqueous solution of potassium chloride, ammonium chloride
The aqueous solution, the aqueous solution of potassium hydroxide, the mixed liquor of the aqueous solution of sodium hydroxide or these solution.(4) stone is obtained after reducing
Black alkene-basalt fiber composite material.The restoring method is to be changed using hydroiodic acid, hydrazine hydrate, Vitamin C, sodium borohydride etc.
Reducing agent is reduced or 100~600 DEG C of thermal reductions.
To realize the crosslinking of basalt fibre, graphene oxide is coated to basalt fibre surface by the present invention, aoxidizes stone
The hydroxyl of black alkene and basalt fibre forms hydrogen bond and van der Waals interaction, realizes uniformly firmly coating.Then make basalt fine
Dimension table layer graphene oxide is swelled in a solvent, and lamella obtains the larger free degree, when drying graphene oxide layer due to by
To the π-π active forces between the capillary force and lamella caused by solvent volatilization and spontaneous Close stack, therefore basalt fibre
It is cross-linked with each other, such as Fig. 1, shown in 2, finally gives graphene-basalt fiber composite material, including zero twisted yarn, non-woven fabrics or short
Cut felt etc..The basalt fibre of graphene crosslinking maintains the property such as the mechanical strength of basalt fibre itself, conduction, corrosion-resistant
Can, the thermal conductivity of basalt fibre is improved, there is very big actual application value.
The present invention is specifically described below by embodiment, the present embodiment is served only for doing further the present invention
It is bright, it is impossible to be interpreted as limiting the scope of the invention, those skilled in the art makes one according to the content of foregoing invention
A little nonessential changes and adjustment belong to protection scope of the present invention.
Non-woven fabrics tensile strength refers to national standard GBT 15232-1994.
Embodiment 1：
(1) basalt fibre is placed in toluene and is heated to 250 DEG C, be cleaned by ultrasonic 10min, remove surface size and oil
Agent, drying；
(2) the basalt fibre surface obtained using the aqueous dispersions of graphene oxide to step (1) is coated repeatedly
Dry, cycle-index is 15 times, obtains the basalt fibre that surface is coated with graphene oxide.Graphene oxide thickness degree is 3 μ
m；
(3) basalt fibre for the coating graphene oxide that step (2) obtains is placed in water and carries out surface swelling, then
Fiber is mutually overlapped and forms non-woven fabrics after drying, drying temperature is less than 100 degrees Celsius.
(4) the graphene oxide crosslinking basalt fibre that step (3) obtains is placed in the closed cauldron containing hydrazine hydrate, 80
Reduced 12 hours at DEG C.
Through above step, graphene coated passes through model on basalt fibre surface, basalt fibre surface with graphene film
De Huali connects with hydrogen bond.Between basalt fibre crosslinking, the unordered friendship of composite fibre are realized by being coated on the graphene on surface
It is folded to form nonwoven fabric construct, surface density 86.1g/m2, 6h intensity is soaked in fracture strength 3.24GPa, PH=12 alkali lye
Conservation rate is 89%, and conductance is 1.6 × 104S/m, thermal conductivity 29W/mK.
In addition, graphene oxide concentration and coating layer thickness are the optimal results obtained through repetition test.It can be seen by table 1
Go out, coat under same number, when the concentration of graphene oxide is 7mg/ml, graphite oxide ene coatings are on basalt fibre surface
Thickness is 3 μm, fracture strength, conductance, the thermal conductivity highest of obtained basalt fibre non-woven fabrics, and cross-linking effect is best.Oxygen
The concentration of graphite alkene is smaller, and thickness of the graphene oxide on basalt fibre surface is smaller, obtained basalt fibre nonwoven
Fracture strength, conductance, the thermal conductivity of cloth are smaller, and cross-linking effect is poorer.The concentration of graphene oxide is higher, and graphene oxide exists
Basalt fibre surface thickness is bigger, and thickness distribution is uneven, and cross-link intensity declines, and obtained basalt fibre non-woven fabrics breaks
Resistance to spalling, conductance, thermal conductivity reduce.
Embodiment 2：
(1) basalt fibre is placed in toluene and is heated to 250 DEG C, be cleaned by ultrasonic 10min, remove surface size and oil
Agent, drying；
(2) the basalt fibre table obtained using the N,N-dimethylformamide dispersion liquid of graphene oxide to step (1)
Face is coated drying repeatedly, and cycle-index is 13 times, obtains the basalt fibre that surface is coated with graphene oxide.Aoxidize stone
Black alkene thickness degree is 3 μm；
(3) basalt fibre for the coating graphene oxide that step (2) obtains is placed in water and carries out surface swelling, then
Fiber is mutually overlapped and forms non-woven fabrics after drying, drying temperature is less than 100 degrees Celsius.
(4) the graphene oxide crosslinking basalt fibre that step (3) obtains is placed in the closed cauldron containing hydrazine hydrate, 80
Reduced 12 hours at DEG C.
Through above step, graphene coated passes through model on basalt fibre surface, basalt fibre surface with graphene film
De Huali connects with hydrogen bond.Between basalt fibre crosslinking, the unordered friendship of composite fibre are realized by being coated on the graphene on surface
It is folded to form nonwoven fabric construct, surface density 85.2g/m2, 6h intensity is soaked in fracture strength 3.21GPa, PH=12 alkali lye
Conservation rate is 87%, and conductance is 1.3 × 104S/m, thermal conductivity 28W/mK.
Embodiment 3：
(1) basalt fibre is placed in toluene and is heated to 250 DEG C, be cleaned by ultrasonic 10min, remove surface size and oil
Agent, drying；
(2) the basalt fibre surface obtained using the alcohol dispersion liquid of graphene oxide to step (1) is applied repeatedly
Drying is covered, cycle-index is 16 times, obtains the basalt fibre that surface is coated with graphene oxide.Graphene oxide thickness degree is
3μm；
(3) basalt fibre for the coating graphene oxide that step (2) obtains is placed in water and carries out surface swelling, then
Fiber is mutually overlapped and forms non-woven fabrics after drying, drying temperature is less than 100 degrees Celsius.
(4) the graphene oxide crosslinking basalt fibre that step (3) obtains is placed in the closed cauldron containing hydroiodic acid, 90
Reduced 18 hours at DEG C.
Through above step, graphene coated passes through model on basalt fibre surface, basalt fibre surface with graphene film
De Huali connects with hydrogen bond.Between basalt fibre crosslinking, the unordered friendship of composite fibre are realized by being coated on the graphene on surface
It is folded to form nonwoven fabric construct, surface density 84.6g/m2, 6h intensity is soaked in fracture strength 3.23GPa, PH=12 alkali lye
Conservation rate is 85%, and conductance is 2.1 × 104S/m, thermal conductivity 27W/mK.
Embodiment 4：
(1) basalt long fiber arranged in parallel is placed in toluene and is heated to 250 DEG C, be cleaned by ultrasonic 20min, remove table
Face size and finish, drying；
(2) the basalt fibre surface obtained using the ethylene glycol dispersion liquid of graphene oxide to step (1) is carried out repeatedly
Drying is coated, cycle-index is 12 times, and it is fine to obtain basalt fibre length of the surface coated with graphene oxide.Graphene oxide layer
Thickness is 3 μm；
(3) the long fibre of basalt fibre for the coating graphene oxide that step (2) obtains is placed in ethylene glycol and carries out surface
Swelling, then fiber is merged and forms the zero twisted yarn after drying, drying temperature is less than 100 degrees Celsius, ethylene glycol is volatilized.
(4) the graphene oxide crosslinking basalt fibre length fibre that step (3) obtains is placed in the closed cauldron containing hydroiodic acid
In, reduced 18 hours at 90 DEG C.
Through above step, graphene coated passes through model on basalt fibre surface, basalt fibre surface with graphene film
De Huali connects with hydrogen bond.Between basalt fibre crosslinking, composite fibre parallel are realized by being coated on the graphene on surface
Row form non-twist fine structure, and it is 85% that 6h strength retentions are soaked in fracture strength 3.42GPa, PH=12 alkali lye, conductive
Rate is 3.9 × 104S/m, thermal conductivity 31W/mK.
Embodiment 5：
(1) basalt long fiber arranged in parallel is placed in toluene and is heated to 250 DEG C, be cleaned by ultrasonic 20min, remove table
Face size and finish, drying；
(2) the basalt fibre surface obtained using the aqueous dispersions of graphene oxide to step (1) is coated repeatedly
Dry, cycle-index is 15 times, obtains the basalt fibre that surface is coated with graphene oxide.Graphene oxide thickness degree is 3 μ
m；
(3) basalt fibre for the coating graphene oxide that step (2) obtains is placed in progress surface swelling in ethylene glycol,
Then fiber is merged and forms the zero twisted yarn after drying, drying temperature is less than 100 degrees Celsius, ethylene glycol is volatilized.
(4) the graphene oxide crosslinking basalt fibre length fibre that step (3) obtains is placed in the closed cauldron containing hydroiodic acid
In, reduced 18 hours at 90 DEG C.
Through above step, graphene coated passes through model on basalt fibre surface, basalt fibre surface with graphene film
De Huali connects with hydrogen bond.Between basalt fibre crosslinking, composite fibre parallel are realized by being coated on the graphene on surface
Row form non-twist fine structure, and it is 84% that 6h strength retentions are soaked in fracture strength 3.45GPa, PH=12 alkali lye, conductive
Rate is 4.4 × 104S/m, thermal conductivity 26W/mK.
Claims (6)
1. a kind of graphene-basalt fiber composite material, it is characterised in that graphene coated is profound on basalt fibre surface
Military rock fiber surface is connected with graphene film by Van der Waals force and hydrogen bond.By being coated on the stone on surface between basalt fibre
Black alkene realizes crosslinking, forms zero twisted yarn, non-woven fabrics or chopped mat.
2. a kind of preparation method of graphene-basalt fiber composite material, it is characterised in that comprise the following steps：
(1) basalt fibre is placed in toluene and is heated to 250 DEG C, be cleaned by ultrasonic 10~30min, remove surface size and oil
Agent, drying.
(2) surface coating is carried out to basalt fibre using graphene oxide dispersion, surface is obtained after drying coated with oxidation
The basalt fibre of graphene.
(3) basalt fibre for coating graphene oxide is placed in progress surface swelling in solvent, then merged fiber through dry
The zero twisted yarn is formed after dry, or fiber is mutually overlapped and forms the non-woven fabrics or chopped mat after drying, drying temperature is low
In 100 degrees Celsius.
(4) graphene-basalt fiber composite material is obtained after reducing.
3. according to the method for claim 2, it is characterised in that the concentration of graphene oxide dispersion in the step (2)
For 7mg/g, dispersant is water, DMF, DMA, ethanol, ethylene glycol, N- crassitudes
Ketone, tetrahydrofuran, dimethyl sulfoxide, diethylene glycol (DEG), pyridine, dioxane, butanone, isopropanol etc..
4. according to the method for claim 2, it is characterised in that graphene oxide dispersion pair is used in the step (2)
Basalt fibre is repeatedly coated, and is dried every time after coating, and final dried graphene oxide thickness degree is 3 μm.
5. according to the method for claim 2, it is characterised in that solvent is water, methanol, ethanol, isopropyl in the step (3)
The alcohols such as alcohol, ethylene glycol, glycerine, diethylene glycol (DEG), formic acid, acetic acid, propionic acid, butyric acid, valeric acid, ethanedioic acid, malonic acid, succinic acid,
The organic acids such as acrylic acid, acetone, butanone, N,N-dimethylformamide, DMAC N,N' dimethyl acetamide, tetrahydrofuran, dimethyl sulfoxide,
1-METHYLPYRROLIDONE, pyridine, dioxane, the aqueous solution of sodium chloride, the aqueous solution of calcium chloride, the aqueous solution of sodium nitrate, nitre
The aqueous solution of sour calcium, the aqueous solution of sodium phosphate, the aqueous solution of potassium chloride, the aqueous solution of ammonium chloride, the aqueous solution of potassium hydroxide, hydrogen
The mixed liquor of the aqueous solution of sodium oxide molybdena or these solution.
6. according to the method for claim 2, it is characterised in that restoring method is to use hydroiodic acid, water in the step (4)
The chemical reducing agents such as conjunction hydrazine, Vitamin C, sodium borohydride are reduced or 100~600 DEG C of thermal reductions.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711150791.6A CN107805886A (en) | 2017-11-18 | 2017-11-18 | A kind of graphene basalt fiber composite material and preparation method thereof |
| JP2019565907A JP6952134B2 (en) | 2017-05-27 | 2018-03-13 | Method of manufacturing composite material based on graphene adhesive |
| US16/617,531 US11542411B2 (en) | 2017-05-27 | 2018-03-13 | Method for preparing composites on basis of graphene bonding |
| PCT/CN2018/078765 WO2018219008A1 (en) | 2017-05-27 | 2018-03-13 | Method for preparing composites on basis of graphene bonding |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711150791.6A CN107805886A (en) | 2017-11-18 | 2017-11-18 | A kind of graphene basalt fiber composite material and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104591551A (en) * | 2015-01-16 | 2015-05-06 | 东华大学 | Preparation method of graphene-coated glass fiber composite material |
| CN106948165A (en) * | 2017-04-28 | 2017-07-14 | 浙江大学 | A kind of graphene fiber of fusion certainly and preparation method thereof |
| CN107200867A (en) * | 2017-06-15 | 2017-09-26 | 中北大学 | Basalt fibre nano surface coats the preparation method and application of multi-scale reinforcing body |
| CN107254066A (en) * | 2017-06-15 | 2017-10-17 | 中北大学 | It is a kind of to prepare the method that graphene oxide is grafted basalt fibre multi-scale reinforcing body |
-
2017
- 2017-11-18 CN CN201711150791.6A patent/CN107805886A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104591551A (en) * | 2015-01-16 | 2015-05-06 | 东华大学 | Preparation method of graphene-coated glass fiber composite material |
| CN106948165A (en) * | 2017-04-28 | 2017-07-14 | 浙江大学 | A kind of graphene fiber of fusion certainly and preparation method thereof |
| CN107200867A (en) * | 2017-06-15 | 2017-09-26 | 中北大学 | Basalt fibre nano surface coats the preparation method and application of multi-scale reinforcing body |
| CN107254066A (en) * | 2017-06-15 | 2017-10-17 | 中北大学 | It is a kind of to prepare the method that graphene oxide is grafted basalt fibre multi-scale reinforcing body |
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Application publication date: 20180316 |