CN107794000A - A kind of glass antidimmer based on primary cellulose acetate and its preparation method and application - Google Patents
A kind of glass antidimmer based on primary cellulose acetate and its preparation method and application Download PDFInfo
- Publication number
- CN107794000A CN107794000A CN201710687584.8A CN201710687584A CN107794000A CN 107794000 A CN107794000 A CN 107794000A CN 201710687584 A CN201710687584 A CN 201710687584A CN 107794000 A CN107794000 A CN 107794000A
- Authority
- CN
- China
- Prior art keywords
- cellulose acetate
- glass
- primary cellulose
- antidimmer
- primary
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000011521 glass Substances 0.000 title claims abstract description 67
- 229920002301 cellulose acetate Polymers 0.000 title claims abstract description 52
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims abstract description 15
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 12
- 239000002904 solvent Substances 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Natural products CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000011259 mixed solution Substances 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- 238000012644 addition polymerization Methods 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 239000003208 petroleum Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 10
- 239000000779 smoke Substances 0.000 abstract description 6
- 230000002411 adverse Effects 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 239000003595 mist Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 229920002521 macromolecule Polymers 0.000 description 3
- 239000005518 polymer electrolyte Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 0 CCC[C@@]([C@](**(C)(C)C[C@](C)(NC)OCC*)[C@](C)(*)C(C)CC)N(C)C Chemical compound CCC[C@@]([C@](**(C)(C)C[C@](C)(NC)OCC*)[C@](C)(*)C(C)CC)N(C)C 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007791 dehumidification Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to glass antidimmer preparing technical field, and in particular to a kind of glass antidimmer based on primary cellulose acetate and its preparation method and application.A kind of glass antidimmer based on primary cellulose acetate of the present invention, the antifoggant are made up of following weight percent composition：Primary cellulose acetate 2~15%, Sodium Polyacrylate 0.1~5%, surplus are solvent.Anti-fog agent for wind-screen of automobile of the present invention is that antifoggant is coated in into glass surface, chemical bond is realized by the amino and glass surface of primary cellulose acetate itself, one layer of hydrophilic film is formed in glass surface, when hydrophilic film runs into water smoke, using its water-wet behavior, water smoke is quickly absorbed, it is antifog for up to 3 months, the demand of application is fully met, while primary cellulose acetate will not produce corrosion or other adverse effects to glass, it is harmless.
Description
Technical field
The present invention relates to glass antidimmer preparing technical field, and in particular to a kind of glass based on primary cellulose acetate
Antifoggant and its preparation method and application.
Background technology
In daily life, mist causes many troubles to us.Such as：In the winter time, we walk from warm interior
When going out outdoor, glasses bear a piece of fog at once, have obscured our sight；When we prepare to eat reeky food, eye
Mirror also has fog generation, and food is sent toward nose the inside by mistake, causes many embarrassments；Also punch the mirror in cool bathroom afterwards
Son；The camera lens etc. of digital camera, telescope.And have more than 5 degree of difference to winter or rainy season, automobile interior exterior temperature, and
And it is in-car when having abundant steam, humidity higher, glass for vehicle window will haze.Especially windscreen windshield and rearview mirror rise
During mist, mist can have a strong impact on the sight of driver, hinder driving safety.If opening air-conditioning for a long time carrys out dispersing fog, effect is simultaneously failed to understand
It is aobvious, it can also increase many oil consumption plus long-term use of air conditioner dehumidification；Especially driver, should not be in order to remove front screen
Mist and wiped in driving procedure using towel, great safe driving hidden danger be present in this.
Currently used automobile anti-fogging agent is surfactant type and the class of polymer electrolyte antifoggant two, and the former is lived by surface
Property agent reduce water surface tension so that water smoke glass surface tiling opens, realize preferably anti-fog effect, be market master
Flow, but the antifog time only has 2~3 days；Polymer electrolyte antifoggant is using hydrophilic radical (carboxyl, amido etc.) in macromolecule to water smoke
Absorption realize it is antifog, can be by antifog time lengthening to 15 days because macromolecule filming is good, but anti-fog effect is poor.It is existing
Antifoggant limits its promotion and application exist in terms of anti-fog effect and anti-fog duration the problem of.Need antifog effect badly in market
Fruit is good, the high-performance long-acting antifoggant of antifog time length.
The content of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of antifog time to grow, the good glass of anti-fog performance
Glass antifoggant.
A kind of glass antidimmer based on primary cellulose acetate of the present invention, wherein the antifoggant is by following weight hundred
Divide and formed than composition：Primary cellulose acetate 2~15%, Sodium Polyacrylate 0.1~5%, surplus are solvent.
Above-mentioned a kind of glass antidimmer based on primary cellulose acetate, wherein the solvent is water, alcohol, acetic acid second
At least one of ester, petroleum ether.
Further, above-mentioned a kind of glass antidimmer based on primary cellulose acetate, wherein the antifoggant be by with
Lower weight percent composition composition：Primary cellulose acetate 2%, Sodium Polyacrylate 0.1%, water 97.9%.
Further, above-mentioned a kind of glass antidimmer based on primary cellulose acetate, wherein the antifoggant be by with
Lower weight percent composition composition：Primary cellulose acetate 15%, Sodium Polyacrylate 5%, alcohol 80%.
Further, above-mentioned a kind of glass antidimmer based on primary cellulose acetate, wherein the antifoggant be by with
Lower weight percent composition composition：Primary cellulose acetate 9%, Sodium Polyacrylate 2.5%, ethyl acetate 88.5%.
Above-mentioned a kind of glass antidimmer based on primary cellulose acetate, wherein the structural formula of the primary cellulose acetate
For：
Above-mentioned a kind of glass antidimmer based on primary cellulose acetate, wherein the concentration of the Sodium Polyacrylate is
2.5%.
The present invention also provides a kind of preparation method of the glass antidimmer based on primary cellulose acetate.
A kind of preparation method of above-mentioned glass antidimmer based on primary cellulose acetate, it comprises the following steps：
A, material preparation：According to the proportioning of primary cellulose acetate, Sodium Polyacrylate and solvent, prepare three kinds of raw materials；
B, primary cellulose acetate dissolves：Primary cellulose acetate is scattered in solvent, heated, until it is all molten
Solution, obtains mixed solution；
C, addition polymerization PAA：Ammonium polyacrylate is well mixed with mixed solution, produced.
A kind of above-mentioned application based on the glass antidimmer of primary cellulose acetate on glass is antifog.
Further, above-mentioned a kind of application based on the glass antidimmer of primary cellulose acetate on glass is antifog, institute
It is vehicle glass to state glass, building glass, bathroom glass, at least one of glasses.
The beneficial effects of the invention are as follows：Anti-fog agent for wind-screen of automobile of the present invention is that antifoggant is coated in into glass table
Face, chemical bond is realized by the hydroxyl and glass surface of primary cellulose acetate itself, it is hydrophilic in one layer of glass surface formation
Film, when hydrophilic film runs into water smoke, using its water-wet behavior, water smoke is quickly absorbed, therefore its antifog persistence
Better than the surfactant type (2-3 days) by physical absorption and the antifog time of polymer electrolyte antifoggant (about 15 days), this hair
The bright glass antidimmer based on primary cellulose acetate is antifog for up to 3 months, fully meets the demand of application, while fiber
Plain triacetate will not produce corrosion or other adverse effects to glass, harmless.
Embodiment
Technical scheme is described in further detail with reference to specific embodiment, but protection scope of the present invention is not
It is confined to as described below.
Embodiment 1
A kind of preparation method of the glass antidimmer based on primary cellulose acetate of the present invention is as follows：
A, material preparation：According to the proportioning of primary cellulose acetate, Sodium Polyacrylate and solvent in table 1, prepare three kinds of originals
Material；
B, primary cellulose acetate dissolves：Primary cellulose acetate is scattered in solvent, is heated to 50~90 DEG C, until
It all dissolves, and obtains mixed solution；
C, addition polymerization PAA：Ammonium polyacrylate is well mixed with mixed solution, produced.
The raw material proportioning of table 1
| Raw material | Experimental group 1 | Experimental group 2 | Experimental group 3 |
| Primary cellulose acetate //wt% | 2 | 15 | 9 |
| Sodium Polyacrylate/wt% | 0.1 | 5 | 2.5 |
| Solvent //wt% | 97.9 | 80 | 88.5 |
By the above-mentioned primary cellulose acetate antifoggant being prepared in accordance with the following methods, be painted on respectively vehicle glass,
On bathroom glass mirror and swimming glasses, one layer of hydrophilic film is formed on glass, produces, makes without poisonous and harmful smell during use
With carrying out antifog test at 35~45 DEG C of environment, and it is best with untreated glass substrate (contrast groups 1), existing anti-fog effect
Surfactant type (contrast groups 2) and existing anti-fog effect it is best macromolecule antifoggant (contrast groups 3) contrast, the sample
Antifog positive effect, and can keep not hazing for a long time.Test result is shown in Table 2：
The application effect of 2 glass antidimmer of the present invention of table
| Test group | Use environment | Hydrophilicity | Antifog maximum duration/d | Light transmittance/% |
| Experimental group 1 | Vehicle glass | It is excellent | 92 | 85 |
| Experimental group 2 | Vehicle glass | It is excellent | 99 | 83 |
| Experimental group 3 | Vehicle glass | It is excellent | 95 | 81 |
| Contrast groups 1 | Vehicle glass | It is good | 0.1 | 10 |
| Contrast groups 2 | Vehicle glass | It is good | 4 | 30 |
| Contrast groups 3 | Vehicle glass | It is good | 16 | 58 |
Described above is only the preferred embodiment of the present invention, it should be understood that the present invention is not limited to described herein
Form, the exclusion to other embodiment is not to be taken as, and can be used for various other combinations, modification and environment, and can be at this
In the text contemplated scope, it is modified by the technology or knowledge of above-mentioned teaching or association area.And those skilled in the art are entered
Capable change and change does not depart from the spirit and scope of the present invention, then all should be in the protection domain of appended claims of the present invention
It is interior.
Claims (10)
1. a kind of glass antidimmer based on primary cellulose acetate, it is characterised in that the antifoggant is by following weight hundred
Divide and formed than composition：Primary cellulose acetate 2~15%, Sodium Polyacrylate 0.1~5%, surplus are solvent.
A kind of 2. glass antidimmer based on primary cellulose acetate according to claim 1, it is characterised in that the solvent
For at least one of water, alcohol, ethyl acetate, petroleum ether.
3. a kind of glass antidimmer based on primary cellulose acetate according to claim 2, it is characterised in that described antifog
Agent is made up of following weight percent composition：Primary cellulose acetate 2%, Sodium Polyacrylate 0.1%, water 97.9%.
4. a kind of glass antidimmer based on primary cellulose acetate according to claim 2, it is characterised in that described antifog
Agent is made up of following weight percent composition：Primary cellulose acetate 15%, Sodium Polyacrylate 5%, alcohol 80%.
5. a kind of glass antidimmer based on primary cellulose acetate according to claim 2, it is characterised in that described antifog
Agent is made up of following weight percent composition：Primary cellulose acetate 9%, Sodium Polyacrylate 2.5%, ethyl acetate
88.5%.
6. according to a kind of any one of Claims 1 to 5 glass antidimmer based on primary cellulose acetate, its feature exists
In the structural formula of the primary cellulose acetate is：
7. according to a kind of any one of Claims 1 to 5 glass antidimmer based on primary cellulose acetate, its feature exists
In the concentration of the Sodium Polyacrylate is 2.5%.
8. a kind of any one of claim 1~7 preparation method of the glass antidimmer based on primary cellulose acetate, it is special
Sign is, comprises the following steps：
A, material preparation：According to the proportioning of primary cellulose acetate, Sodium Polyacrylate and solvent, prepare three kinds of raw materials；
B, primary cellulose acetate dissolves：Primary cellulose acetate is scattered in solvent, heated, until it all dissolves, is obtained
To mixed solution；
C, addition polymerization PAA：Ammonium polyacrylate is well mixed with mixed solution, produced.
9. any one of claim 1~7 it is described it is a kind of based on the glass antidimmer of primary cellulose acetate on glass is antifog
Using.
10. to apply according to claim 9, it is characterised in that the glass is vehicle glass, building glass, bathroom glass,
At least one of glasses.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710687584.8A CN107794000A (en) | 2017-08-11 | 2017-08-11 | A kind of glass antidimmer based on primary cellulose acetate and its preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710687584.8A CN107794000A (en) | 2017-08-11 | 2017-08-11 | A kind of glass antidimmer based on primary cellulose acetate and its preparation method and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107794000A true CN107794000A (en) | 2018-03-13 |
Family
ID=61531520
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710687584.8A Pending CN107794000A (en) | 2017-08-11 | 2017-08-11 | A kind of glass antidimmer based on primary cellulose acetate and its preparation method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107794000A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108727247A (en) * | 2018-07-04 | 2018-11-02 | 西安随心呼汽车服务有限公司 | A kind of antifoggant based on indole derivatives |
| CN109705381A (en) * | 2018-11-27 | 2019-05-03 | 新野旭润光电科技有限公司 | Low heat conductivity optical mirror slip |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5814684A (en) * | 1994-10-05 | 1998-09-29 | Daicel Chemical Industries, Ltd. | Anti-fogging agent for thermoplastic resin surface and anti-fogging thermoplastic resin sheet |
| CN105238355A (en) * | 2015-10-26 | 2016-01-13 | 陈麒雅 | Long-acting glass antifog membrane and preparation method thereof |
-
2017
- 2017-08-11 CN CN201710687584.8A patent/CN107794000A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5814684A (en) * | 1994-10-05 | 1998-09-29 | Daicel Chemical Industries, Ltd. | Anti-fogging agent for thermoplastic resin surface and anti-fogging thermoplastic resin sheet |
| CN105238355A (en) * | 2015-10-26 | 2016-01-13 | 陈麒雅 | Long-acting glass antifog membrane and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108727247A (en) * | 2018-07-04 | 2018-11-02 | 西安随心呼汽车服务有限公司 | A kind of antifoggant based on indole derivatives |
| CN109705381A (en) * | 2018-11-27 | 2019-05-03 | 新野旭润光电科技有限公司 | Low heat conductivity optical mirror slip |
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| PB01 | Publication | ||
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| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180313 |
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| RJ01 | Rejection of invention patent application after publication |